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Study on recycle of granulated blast-furnace slag as an adsorbent for ammonium remediation in wastewater 粒状高炉渣回收作为废水氨修复吸附剂的研究
Pub Date : 2023-08-02 DOI: 10.15625/2525-2518/16452
Trinh Dinh Minh Viet, N. Tuan, Minh, Nguyen Thi, Phương Thảo, Phung Linh Phuong, T. Tuyen
Blast-furnace slag (BFS) is enormously generated each year and has been considered as hazardous solid waste which is posing a significant pressure on waste treatment in terms of storage and transportation. This study aims to recycle BFS as a material for ammonium adsorption from an aqueous solution. Natural-state BFS and acidic-modified by using HNO3 at various concentration of 0.5M, 1M, and 3M (A-BFS1, A-BFS2, and A-BFS3) was examined. The surface characteristics of the materials were examined by BET analysis and Scanning Electron Microscope. The adsorption of ammonium on the BFS materials was conducted in batch mode at various conditions of contact time, pH level, adsorbent dosage, and initial concentration of ammonium. The results indicated that the HNO3 modification exhibited pore creations and surface enhancement as the A-BFS3 has 25.7 times larger surface area and 10.3 times pore size improvement. The A-BFS3 showed good ammonium adsorption capacity compared to other materials, which is 1.81 mg/g at the optimum conditions of pH 6, contact time of 120 minutes, and dosage of 0.5 g in 50 mL of 20 mg/L ammonium solution. Langmuir and Freundlich adsorption isotherm models of the A-BFS3 material showed a relatively good correlation with R2 values of 0.999 and 0.9625, respectively.
高炉矿渣是一种危害性固体废物,每年产生的矿渣量巨大,给废物处理的储存和运输带来了巨大的压力。本研究旨在回收BFS作为水溶液中吸附铵的材料。考察了自然状态的BFS和不同浓度0.5M、1M和3M的HNO3酸改性(A-BFS1、A-BFS2和A-BFS3)。采用BET分析和扫描电镜对材料的表面形貌进行了表征。在不同的接触时间、pH值、吸附剂用量、铵的初始浓度等条件下,以批处理的方式对BFS材料进行了铵的吸附。结果表明:HNO3改性后,A-BFS3的表面积增大了25.7倍,孔径增大了10.3倍;与其他材料相比,A-BFS3在pH为6、接触时间为120 min、用量为0.5 g、20 mg/L铵溶液为50 mL的条件下,对铵的吸附量为1.81 mg/g。a - bfs3材料的Langmuir吸附等温线模型和Freundlich吸附等温线模型具有较好的相关性,R2分别为0.999和0.9625。
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引用次数: 0
Phytochemical investigation and antimicrobial activity from rhizomes of alocasia odora K. Koch alocasia odora K. Koch 根茎的植物化学研究和抗菌活性
Pub Date : 2023-08-02 DOI: 10.15625/2525-2518/17303
Nguyen Thi Hai Ha, Nguyen Van Tuyen, N. Son, L. Anh, Nguyen Thi Thuy Linh, Pham Minh Quan, Le Thi Hai Yen, Nguyen Van Du
Alocasia odora is a common plant species in Viet Nam. A phytochemical investigation of the ethyl acetate extract (EtOAc) of A. odora rhizomes collected in Tuyen Quang province led to the isolation and determination of five compounds, including three alkaloids, alocasin A (1), hyrtiosin B (2), hyrtiosulawesine (3), one mono-phenol, p-hydroxycinamic acid (4), and one fatty acid, myristic acid (5). The chemical structures of those compounds were determined by 1D and 2D-NMR spectroscopic, MS data and compared with those reported in the literature. Antimicrobial activity against microorganisms was evaluated using the broth microdilution method, showing that alkaloids 1 - 3 exhibited antimicrobial activity against reference strains with MIC values ranging from 8 µg/mL to 128 µg/mL, in which compound 1 was the most active with MIC values calculated between 8 µg/mL and 32 µg/mL. Compound 4-5 did not display antimicrobial activity at the studied concentration, MIC > 128 µg/mL. This is the first time the antimicrobial effect of A. odora has been reported.
Alocasia odora 是越南常见的植物物种。对在 Tuyen Quang 省采集到的 Alocasia odora 根茎乙酸乙酯提取物(EtOAc)进行的植物化学调查分离并测定了五种化合物,包括三种生物碱 alocasin A (1)、hyrtiosin B (2)、hyrtiosulawesine (3),一种单酚 p-hydroxycinamic acid (4) 和一种脂肪酸 myristic acid (5)。通过一维和二维核磁共振光谱、质谱数据确定了这些化合物的化学结构,并与文献中报道的结构进行了比较。使用肉汤微稀释法评估了生物碱对微生物的抗菌活性,结果表明生物碱 1 - 3 对参考菌株具有抗菌活性,MIC 值在 8 µg/mL 至 128 µg/mL 之间,其中化合物 1 的活性最高,MIC 值在 8 µg/mL 至 32 µg/mL 之间。化合物 4-5 在研究浓度(MIC > 128 µg/mL)下没有显示出抗菌活性。这是首次报道 A. odora 的抗菌效果。
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引用次数: 0
Simultaneous determination of paracetamol and diclofenac in wastewater by high-performance liquid chromatography method 高效液相色谱法同时测定废水中扑热息痛和双氯芬酸的含量
Pub Date : 2023-08-01 DOI: 10.15625/2525-2518/16418
N. Thanh, N. Dong, Thi Thu, Trang, N. Việt, Hoang Pham Tuan, Pham Thi Linh, Yen
In this study, a simple, selective, and accurate analysis method was developed for the simultaneous determination of anti-inflammatory drugs (paracetamol and diclofenac) existing inlet and outlet of the wastewater treatment system. This method used solid-phase extraction (SPE) and reversed-phase high-performance liquid chromatography with a photodiode array detector (HPLC-PDA). Separation was performed using an HSR C18 column (250 mm × 4.6 mm; 5 µm) with a mobile phase consisting of acetonitrile: sodium dihydrogen orthophosphate in the ratio 60:40 v/v. The flow rate was 1 ml/min, and PDA was detected at 243 nm with paracetamol and 276 nm with diclofenac. The duration of paracetamol and diclofenac was 2.39 and 4.39 min, respectively. The developed method was validated in terms of accuracy, precision, and linearity for two drugs found in the range of 0.01 - 1 µg/ml, and 0.02 - 1 µg/ml for paracetamol, and diclofenac, respectively. The limits of detection for paracetamol and diclofenac were 0.003 µg/ml and 0.006 µg/ml, respectively, whereas the limits of quantification were 0.01 µg /ml and 0.02 µg/ml, respectively. The recoveries for paracetamol and diclofenac were greater than 95 %. The described method also has been applied to determine paracetamol and diclofenac simultaneously in the wastewater of the treatment system.
本研究建立了一种简便、选择性、准确的分析方法,用于同时测定废水处理系统中存在的消炎药(扑热息痛和双氯芬酸)的含量。该方法采用固相萃取法(SPE)和反相高效液相色谱法(HPLC-PDA)。采用HSR C18色谱柱(250 mm × 4.6 mm;5µm),流动相为乙腈:正磷酸二氢钠,比例为60:40 v/v。流速为1 ml/min,对乙酰氨基酚和双氯芬酸分别在243 nm和276 nm检测PDA。对乙酰氨基酚和双氯芬酸的持续时间分别为2.39 min和4.39 min。结果表明,所建立的方法在0.01 ~ 1µg/ml和0.02 ~ 1µg/ml范围内对扑热息痛和双氯芬酸的含量具有良好的准确度、精密度和线性关系。对乙酰氨基酚和双氯芬酸的检出限分别为0.003µg/ml和0.006µg/ml,定量限分别为0.01µg/ml和0.02µg/ml。对乙酰氨基酚和双氯芬酸的加样回收率均大于95%。所述方法还用于同时测定处理系统废水中的扑热息痛和双氯芬酸。
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引用次数: 0
Assessment of influence of silane modified zirconia nanoparticle content on weather resistance of water-borne acrylic coating 评估硅烷改性氧化锆纳米粒子含量对水性丙烯酸涂料耐候性的影响
Pub Date : 2023-08-01 DOI: 10.15625/2525-2518/16686
Nguyen Thuy Chinh, Dao Phi Hung, Nguyen Xuan Thai, Nguyen Anh Hiep, T. Hoang
Water-borne acrylic resin has attracted much attention thanks to its environmetally  friendly, high weather stability, good mechanical properties, high toughness. It is widely used in coatings, ships, bridges, locomotives, etc. In this work, the effect of ZrO2 nanoparticles content which were modified with (3-glycidyloxypropyl)triethoxysilane (GPTS) on the weather resistance of the acrylic emulsion coatings was tested and discussed. The change in functional groups, carbonyl index value, gloss, weight and morphology of the coatings before and after accelerated weathering test was investigated. The obtained results showed that the GPTS modified ZrO2 nanoparticle content had a significant effect on the characteristics of acrylic emulsion coatings. The 2 wt.% content of GPTS modified ZrO2 nanoparticles exhibited a highest efficiency in improvement of weather resistance of acrylic emulsion coatings. This result indicated that acrylic emulsion coating filled by the GPTS modified ZrO2 nanoparticles is potential for outdoor applications.
水性丙烯酸树脂因其环保、耐候性强、机械性能好、韧性高而备受关注。它被广泛应用于涂料、船舶、桥梁、机车等领域。本研究测试并讨论了用(3-缩水甘油氧丙基)三乙氧基硅烷(GPTS)改性的 ZrO2 纳米粒子含量对丙烯酸乳液涂料耐候性的影响。研究了加速耐候试验前后涂料的官能团、羰基指数值、光泽、重量和形态的变化。结果表明,GPTS 改性 ZrO2 纳米粒子的含量对丙烯酸乳液涂料的特性有显著影响。GPTS 改性 ZrO2 纳米粒子含量为 2 wt.% 时,对丙烯酸乳液涂料耐候性的改善效率最高。这一结果表明,由 GPTS 改性的 ZrO2 纳米粒子填充的丙烯酸乳液涂料具有户外应用的潜力。
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引用次数: 0
Dynamics of functionally graded beams carrying a moving load with influence of porosities and partial foundation support 考虑孔隙率和部分基础支撑影响的功能梯度梁动载动力学
Pub Date : 2023-08-01 DOI: 10.15625/2525-2518/17507
Vu Thi, An Ninh
The novelty of the present work is to study the simultaneous influence of porosities and partial Pasternak foundation support on dynamics of functionally graded (FG) beams carrying a moving load. The beams are made from an open-cell steel foam with symmetric and asymmetric porosity distributions in the thickness direction. Based on a refined third-order shear deformation theory, a two-node beam element with ten degrees of freedom is derived and employed to construct the discretized equation of motion for the beams. Dynamic characteristics, including the time histories for mid-span deflection, dynamic magnification factor (DMF) and the stress distribution, are computed with the aid of the Newmark method. The numerical result reveals that the foundation supporting length has an important role on the dynamics of the beams, and the dependence of the DMF upon the porosity coefficient is governed by the foundation supporting length.  It is also found that the asymmetric porosity distribution has more impact on the dynamic response of the beams than the symmetric one does, and the difference between the DMFs obtained from the two porosity distributions is more significant for the beam with a higher porosity coefficient. The effects of the porosities, the foundation support and the moving load velocity on the dynamic behavior of the beams are examined in detail and highlighted
本研究的新颖之处在于同时研究了孔隙率和部分帕斯捷尔纳克基础支撑对承载移动荷载的功能梯度梁动力学的影响。梁由开孔泡沫钢制成,在厚度方向上具有对称和不对称孔隙率分布。基于改进的三阶剪切变形理论,导出了十自由度双节点梁单元,并利用该单元建立了梁的离散化运动方程。采用Newmark法计算了桥梁的动力特性,包括跨中挠度时程、动力放大系数(DMF)和应力分布。数值计算结果表明,基础支护长度对梁的动力特性有重要影响,且DMF对孔隙率系数的依赖关系受基础支护长度的支配。非对称孔隙率分布对梁动力响应的影响大于对称孔隙率分布,且孔隙率系数越高,两种孔隙率分布对梁动力响应的影响越显著。详细分析了孔隙率、基础支撑和移动荷载速度对梁动力性能的影响
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引用次数: 0
Fast finite-time backstepping controller for a quadrotor UAV under state constraints 状态约束下四旋翼无人飞行器的快速有限时间反步进控制器
Pub Date : 2023-06-30 DOI: 10.15625/2525-2518/18131
Nguyen Mung Xuan, Lanh Le Thanh, The Mich Nguyen
Quadrotors have gained popularity in a wide range of applications. In this paper, a new approach for solving the tracking control problem of quadrotors with full-state constraints is presented. The proposed method involves a backstepping control scheme integrated with a fast finite-time filter. First, necessary state transformations are performed to support the design of the finite-time filter and controller. Next, the controller is formulated based on the backstepping technique. All the state constraints are taken into consideration in the controller. However, it is well-known that the backstepping control design can lead to the “explosion of complexity” when calculating time derivatives of certain nonlinear functions. Therefore, the proposed filter comes to provide a solution for estimating the time derivatives with the estimation errors converging to zero in finite time. The closed-loop system's finite-time stability is rigorously proved using the Lyapunov theory, despite the state constraints. Simulation results demonstrate the feasibility and efficacy of the proposed method.
四旋翼飞行器已在广泛的应用中得到普及。本文提出了一种解决具有全状态约束的四旋翼飞行器跟踪控制问题的新方法。所提出的方法涉及一种集成了快速有限时间滤波器的反步进控制方案。首先,进行必要的状态变换以支持有限时间滤波器和控制器的设计。然后,根据反步进技术制定控制器。控制器考虑了所有的状态约束。然而,众所周知,在计算某些非线性函数的时间导数时,反步法控制设计会导致 "复杂性爆炸"。因此,所提出的滤波器提供了一种估算时间导数的解决方案,估算误差在有限时间内趋于零。尽管存在状态约束,但利用 Lyapunov 理论严格证明了闭环系统的有限时间稳定性。仿真结果证明了所提方法的可行性和有效性。
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引用次数: 0
Preliminary assessment of microplastic pollution in commercial freshwater fish species collected from four districts in Bac Ninh province 北宁省四个区商业淡水鱼中微塑料污染的初步评估
Pub Date : 2023-06-23 DOI: 10.15625/2525-2518/17926
H. Mai, Thi Thao Ngo, Danh Thien Nguyen, V. Bui, T. D. Dao, Thi Thom Dang, V. M. Do
Microplastics (MPs) are of emerging widespread concern, but amount of research done in freshwater environments and organisms is scarce compared to that in marine environments. Thus, the MPs identification in four freshwater fish at four districts of Bac Ninh  province were documented, including common carp (Cyprynus carpio), grass carp (Ctenopharyngodon idella), tilapia (Oreochromis niloticus), and red-tilapia (Oreochromis sp.). MPs were found in the gastrointestinal tracts (GIT) of 100% of examined fish. MPs abundances have significant differences between all freshwater fish collected from ponds and local markets (except for red-tilapia), while no difference by individual of each species neither in pond nor in local markets. The median sizes of microplastics ranged from 1410 µm to 2706 µm. The MPs were dominated by purple in color (in pond with average 38%; in local market with average 33%). µ-FTIR analysis showed that polymers found in fish GIT mainly were polyethylene terephthalate, polyethylene, polypropylene and nylon. These results showed that the microplastics was widely ingested by freshwater fish and help to aware people which fish are more contaminated with MPs to human consumption in Bac Ninh province.
微塑料(MPs)引起了广泛关注,但与海洋环境相比,在淡水环境和生物中进行的研究数量很少。因此,对北宁省4个地区的4种淡水鱼,包括鲤鱼(cyynus carpio)、草鱼(Ctenopharyngodon idella)、罗非鱼(Oreochromis niloticus)和红罗非鱼(Oreochromis sp.)的MPs鉴定进行了记录。在所有被检查的鱼的胃肠道(GIT)中都发现了MPs。从池塘和当地市场采集的所有淡水鱼(红罗非鱼除外)之间的MPs丰度存在显著差异,而在池塘和当地市场中每个物种的个体之间都没有差异。微塑料的中位数尺寸从1410µm到2706µm不等。MPs以紫色为主(池塘中平均占38%;在当地市场平均为33%)。微傅里叶红外光谱分析显示,鱼类GIT中发现的聚合物主要是聚对苯二甲酸乙二醇酯、聚乙烯、聚丙烯和尼龙。这些结果表明,微塑料被淡水鱼广泛摄入,有助于人们了解北宁省哪些鱼受MPs污染更严重。
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引用次数: 0
Characteristics of fly ash from the municipal solid waste incineration plant in Can Tho 芹苴城市生活垃圾焚烧厂飞灰特性研究
Pub Date : 2023-06-20 DOI: 10.15625/2525-2518/17538
Ngo Tra Mai, Van Huu Tap, Nguyen Duy Hai, Phan Thi Thanh Hang, Trinh Thi Tham, Vu Duc Toan, Nguyen Thi Thuy Hang, Khuat Thi Hong, Nghiem Thi Ha Lien, Vu B. Duong, Do Quang Hoa, Nguyen Trong Nghia, Nguyen Thi Hoa, Do Thi Lan Chi, Dao Thanh Duong
In this study, 16 seasonal fly ash samples of municipal solid waste incinerator (MSWI) were collected in from waste-to energy power plant Cantho city to analysis the physical properties and heavy metals content. The results showed that the fly ash samples are very alkaline with porous and spherical shape, and the particle size of 1-100 µm. The analytical results disclosed that in these fly ash samples, the Zn, Pb, Al, Fe and Cr metals were found at high content range from 0.36-19.05 mg/kg while the toxic metals Ni and Hg are also found in fly ash, with the content from 0.141 to 0.51 mg/kg. Thus, fly ash is not hazardous waste and can be used for reuse in industries or land reclamation. The analysis results of SEM/EDX and XRF were quite similar with a difference of below 5%, indicating that both methods can be applied to research heavy metals. The findings in this study can guide the management, treatment and reuse of fly ash from MSWI incineration plants in Vietnam.
本研究收集了16个城市生活垃圾焚烧炉(MSWI)的季节性飞灰样本,分析了其物理性质和重金属含量。结果表明:粉煤灰样品呈多孔球形,碱性强,粒径为1 ~ 100µm;分析结果表明,粉煤灰样品中Zn、Pb、Al、Fe和Cr金属含量较高,为0.36 ~ 19.05 mg/kg,有毒金属Ni和Hg含量为0.141 ~ 0.51 mg/kg。因此,粉煤灰不是有害废物,可用于工业或土地复垦。SEM/EDX和XRF的分析结果非常相似,相差在5%以下,表明这两种方法都可以应用于重金属的研究。本研究结果可指导越南城市生活垃圾焚烧厂飞灰的管理、处理和再利用。
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引用次数: 0
APPLICATION OF FUZZY LOGIC IN THE ROBOT CONTROL FOR MECHANICAL PROCESSING 模糊逻辑在机械加工机器人控制中的应用
Pub Date : 2023-06-09 DOI: 10.15625/2525-2518/18069
P. Khoi
Robot application in mechanical machining is growing day by day because it has many advantages over conventional machines such as high flexibility, large working space, and high repeatability. Many degrees of freedom of motion give robots the ability to perform complex technological operations, but also because of that, methods of controlling robots based on dynamic models have difficulties. Applying fuzzy logic to robot control can partially or completely exclude the calculation of the robot's dynamic model as well as overcome other uncertainties of the whole technological system. The variables and parameters of the fuzzy logic-based controller are modeled in a linguistic form, called linguistic variables, and are defined by the linguistic semantic values. Fuzzy rules are an important basis for the performance of operations defining the control quantities of the controller. Fuzzy rules are constructed by natural human inference and are based on expert intelligence. The main tasks of applying fuzzy logic control include “Fuzzification” to determine fuzzy parameters in the form of fuzzy sets of input-output data; “Fuzzy Rules and Fuzzy Inference Mechanism” to perform fuzzy operations defining control quantities, and finally “Defuzzification” to convert control quantities from linguistic values to physical values for controller operation. There have been many types of research on applying fuzzy logic to control robots in general, but the percentage of fuzzy control research work for mechanical machining robots is still limited. The article is based on published works on fuzzy control for robots in general and mechanical processing robots to analyze the applicability of fuzzy control for mechanical machining robots. The article provides detailed information on fuzzy controller design, on determining input and output variables, proportional mapping to determine the number of fuzzy sets and the corresponding type of membership function. The construction of fuzzy rule base system and fuzzy inference mechanism is presented, and finally defuzzification. Prospects for the use of methods to perfect and develop fuzzy control systems for mechanical machining robots are also presented. Collectively, the information in this document is intended to guide the implementation of fuzzy logic-based controller designs for application to machining robots, as well as to general robot control.
机器人具有灵活性高、工作空间大、重复性高等优点,在机械加工中的应用日益广泛。许多运动自由度赋予机器人执行复杂技术操作的能力,但也正因为如此,基于动态模型的机器人控制方法存在困难。将模糊逻辑应用到机器人控制中,可以部分或完全排除机器人动力学模型的计算,克服整个技术系统的其他不确定性。基于模糊逻辑的控制器的变量和参数以语言形式建模,称为语言变量,并由语言语义值定义。模糊规则是确定控制器控制量的操作性能的重要依据。模糊规则是由自然的人类推理和基于专家智能构建的。应用模糊逻辑控制的主要任务包括“模糊化”,以输入输出数据的模糊集的形式确定模糊参数;“模糊规则和模糊推理机制”进行模糊运算,定义控制量,最后进行“去模糊化”,将控制量从语言值转换为控制器操作的物理值。一般来说,将模糊逻辑应用于机器人控制的研究已经有很多种,但机械加工机器人的模糊控制研究工作所占的比例仍然有限。本文以已发表的关于一般机器人模糊控制和机械加工机器人模糊控制的著作为基础,分析了模糊控制在机械加工机器人中的适用性。本文详细介绍了模糊控制器的设计、输入输出变量的确定、比例映射确定模糊集的个数和对应的隶属函数类型。提出了模糊规则库系统的构建和模糊推理机制,并进行了去模糊化。展望了利用模糊控制方法完善和发展机械加工机器人模糊控制系统的前景。总的来说,本文档中的信息旨在指导基于模糊逻辑的控制器设计的实现,以应用于加工机器人以及一般机器人控制。
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引用次数: 0
DESTINATION SEQUENCED DISTANCE VECTOR ROUTING TAKING INTO ACCOUNT SIGNAL TO NOISE FOR FLYING AD HOC NETWORK 考虑信噪比的飞行AD hoc网络目的地序列距离矢量路由
Pub Date : 2023-06-09 DOI: 10.15625/2525-2518/17355
Tu Vo Thanh, Le Huu Binh, Vu Phan Dinh Nguyen
Flying ad hoc network (FANET) is becoming more popular in both military and civilian applications. The primary characteristic of the FANET is high mobility, which results in a constantly changing topology. This is a significant challenge for protocols that control data transmission from nodes to base stations. As a result, many research groups have recently been attracted to the study of data transmission control protocols in FANET, typically routing protocols. This paper presents the application of the Destination Sequenced Distance Vector (DSDV) routing protocols for FANET. We improve the DSDV routing protocol by considering signal-to-noise ratio (SNR) when discovering new routes. The simulation results show that the improved DSDV algorithm outperforms the traditional DSDV algorithm in terms of network throughput, end-to-end delay and SNR.
飞行自组织网络(FANET)在军事和民用应用中越来越受欢迎。FANET的主要特点是高移动性,这导致了不断变化的拓扑结构。对于控制从节点到基站的数据传输的协议来说,这是一个重大挑战。因此,近年来吸引了许多研究小组对FANET中数据传输控制协议的研究,特别是路由协议。介绍了目的序列距离矢量(Destination sequence Distance Vector, DSDV)路由协议在FANET中的应用。我们改进了DSDV路由协议,在发现新路由时考虑了信噪比。仿真结果表明,改进的DSDV算法在网络吞吐量、端到端时延和信噪比方面都优于传统的DSDV算法。
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引用次数: 0
期刊
Vietnam Journal of Science and Technology
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