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Bifunctional Materials for CO₂ Adsorption: Short Review 二氧化碳吸附双功能材料综述
Pub Date : 2021-11-21 DOI: 10.15282/jceib.v7i2.7021
S. M. Yusof, L. P. Teh
In recent years, there has been growing interest in adsorbents with high surface area, high porosity, high stability and high selectivity for CO2 adsorption. By the incorporation of the additive on the supports such as zeolite, silica, and carbon, the physicochemical properties of the adsorbent and CO2 adsorption performance can be enhanced. In this review, we focus on the overview of bifunctional materials (BFMs) for CO2 adsorption. The findings of this study suggests that the high surface area and high porosity of the support provide a good medium for high dispersion and accessibility of additives (amine or metal oxide), enhancing the CO2 adsorption efficiency. The excessive additive however may lead to a decrease of CO2 adsorption performance due to pore blockage and the decrease of active sites for CO2 interactions. The synergistic relationship of the supporting material and additive is significant towards the enhancement of CO2 adsorption.
近年来,高表面积、高孔隙率、高稳定性和高选择性吸附CO2的吸附剂越来越受到人们的关注。通过在载体上掺入沸石、二氧化硅、碳等添加剂,可以提高吸附剂的理化性能和CO2吸附性能。本文综述了双功能材料(BFMs)在CO2吸附方面的研究进展。研究结果表明,载体的高表面积和高孔隙率为添加剂(胺或金属氧化物)的高分散性和可及性提供了良好的介质,提高了CO2吸附效率。然而,过量的添加剂可能会导致孔隙堵塞和CO2相互作用活性位点的减少,从而降低CO2的吸附性能。载体材料与添加剂的协同作用对提高CO2吸附性能具有重要意义。
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引用次数: 0
Simulation of Lovastatin Production in Solid-State Fermentation via Oil Palm Frond 油棕叶固态发酵生产洛伐他汀的模拟
Pub Date : 2021-11-21 DOI: 10.15282/jceib.v7i2.6755
N. A. Nata, F. Mohd Said, S. Md Shaarani@Md Nawi, N. Harun
Lovastatin is a potent drug for lowering the blood cholesterol. It is a competitive inhibitor of 3-hyroxy3-methyl glutaryl coenzyme A (HMG-CoA) reductase, which is a key enzyme in the cholesterol production pathway. Lovastatin increases the good cholesterol or high-density lipoproteins to prevent the formation of plaque inside the blood vessels. This study aims to develop a process model of lovastatin production, produced by Monascus purpureus under solid-state fermentation using oil palm frond. SuperPro Design V9.5 software was used to develop and simulate the process model. Three parameters which are initial moisture content, composition of peptone and potassium, were varied to investigate their effects on lovastatin production. The optimum condition simulated using the process model at pH 7 with 60% initial moisture content, 0.0075 kg/hr of potassium, and 0.0075 kg/hr of peptone was able to produce 0.0288 kg/kg of lovastatin. The simulated results show good agreement with experimental work, with low percentage error of 5.77%, and provide a good approximation on the production of lovastatin under various process operating conditions.
洛伐他汀是一种有效的降低血液胆固醇的药物。它是3-羟基3-甲基戊二酰辅酶a (HMG-CoA)还原酶的竞争性抑制剂,是胆固醇生成途径中的关键酶。洛伐他汀增加有益胆固醇或高密度脂蛋白,以防止血管内斑块的形成。本研究旨在建立以油棕叶为原料,由红曲霉固态发酵生产洛伐他汀的工艺模型。采用SuperPro Design V9.5软件进行工艺模型的开发和仿真。研究了初始水分、蛋白胨和钾的组成对洛伐他汀生产的影响。在pH为7、初始含水量为60%、钾用量为0.0075 kg/hr、蛋白胨用量为0.0075 kg/hr的条件下,优化后的洛伐他汀产率为0.0288 kg/kg。模拟结果与实验结果吻合较好,误差为5.77%,为不同工艺条件下洛伐他汀的生产提供了较好的近似。
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引用次数: 1
The Effects of Additives on the Pelletization of Raw and Torrefied Food Waste 添加剂对生的和冷冻的食物垃圾成球的影响
Pub Date : 2021-11-21 DOI: 10.15282/jceib.v7i2.6521
R. Abdul Rasid, G. Elamparithy, M. Ismail, N. Harun
This study evaluates the effect of various binders on the pelletization of raw and torrefied food waste (FW) towards its physical properties, including density, moisture reabsorption, and tensile strength of the formed pellets. Three binders; starch, lignin, and vegetable oil, were used to make the raw and torrefied FW pellets. It was found that the addition of lignin helps to improve the density of both, raw and torrefied FW pellets by 40% for raw FW pellets and up to 27% improvement for the torrefied FW pellets. In addition, increasing the concentration of lignin may also reduce moisture reabsorption from 48% to 40% of raw FW pellets, and the sorption was further reduced for the torrefied FW pellets. The addition of lignin improves the tensile strength, mainly the torrefied FW pellets. Results show that lignin inclusion demonstrates significant enhancement to the physical properties of FW pellets.
本研究评估了各种粘合剂对生的和固化的食物垃圾(FW)的球团化对其物理性能的影响,包括密度,水分吸收率和形成的球团的拉伸强度。三个绑定;采用淀粉、木质素、植物油等原料制备粗粉球团。研究发现,木质素的添加有助于提高生豆浆和碳化豆浆颗粒的密度,生豆浆颗粒的密度提高40%,碳化豆浆颗粒的密度提高27%。此外,增加木质素的浓度也可使生料颗粒的吸湿率从48%降低到40%,并且碳化颗粒的吸湿率进一步降低。木质素的加入提高了颗粒的抗拉强度,主要是提高了碳化颗粒的抗拉强度。结果表明,木质素包合物对FW颗粒的物理性能有显著的增强作用。
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引用次数: 0
Formulation of Plant Nutrient with Synbiotic Enhancement 具有合成增强作用的植物营养素配方研究
Pub Date : 2021-11-21 DOI: 10.15282/jceib.v7i2.3747
S. Ananthan, N. Ahmad, S. Noor, M. Munaim, S. Alias, H. Hamid, M. Mohammed, A. Romli
Oleochemical wastewater discharge from the industry into water sources is one of the main causes of water pollution. A proper treatment is required before the effluent is discharged to the environment. Since the oleochemical wastewater contains nutrients and probiotics that are good for plants, it could be used as a nutrient provider for the plants instead. Therefore, the formulation of synbiotic plant nutrients from this effluent is an effective way of using the oleochemical effluent. This study aimed to formulate the plant nutrients by using industrial wastewater, which contains the synbiotic enhancement and validating the significance of the formulated plant nutrients into three types of plants; Abelmoschus esculentus (Okra), Solanum Melongena (Brinjal), and Capsicum annuum (Chilli peppers). Synbiotic is a combination of both prebiotics and probiotics that benefit the host by stimulating the growth of a limited number of health-promoting bacteria. To formulate the plant nutrient, the wastewater was filtered using a cotton cloth before the pre-biotics solution was added. Sample A (filtered wastewater was mixed with Sample B (prebiotics solution) by different percentages, namely  F1 (100%:0%), F2 (75%:25%), F3 (50%:50%), F3 (25%:75%), 0%:100% (Sample A to Sample B respectively) and lastly, 50%:50%  (Sample C (unfiltered wastewater) to Sample B respectively). The height of the plant and the number of leaves are measured weekly for four months. From the data, it can be seen that F3 gave significant results for the okra plant, in which it gains the highest height of plant compared to the other two plants. On the other hand, F6 give the best results for both the brinjal and the chilli plant where their leaves grow the highest from the second until the fourth month of plant growth. Hence, this research gives an added value to the wastewater, whereas the wastewater is used as the synbiotic plant nutrient enhancer and work best for the plants.
工业向水源排放油化废水是造成水污染的主要原因之一。在将废水排放到环境之前,需要进行适当的处理。油化废水中含有对植物有益的营养物质和益生菌,可以作为植物的营养源。因此,从该废水中提取合成植物营养物是利用油化废水的有效途径。本研究旨在利用工业废水配制植物营养物,其中含有合成增强作用,并验证所配制的植物营养物对三类植物的意义;秋葵(Abelmoschus esculentus)、茄子(Solanum Melongena)和辣椒(Capsicum annuum)。益生菌是益生元和益生菌的结合,通过刺激有限数量的促进健康的细菌的生长而使宿主受益。在加入益生元溶液之前,先用棉布过滤废水,以形成植物营养物。样品A(过滤后的废水)与样品B(益生元溶液)按不同比例混合,分别为F1(100%:0%)、F2(75%:25%)、F3(50%:50%)、F3(25%:75%)、0%:100%(样品A到样品B)和50%:50%(样品C(未过滤的废水)到样品B)。在四个月的时间里,每周测量一次植株的高度和叶片的数量。从数据中可以看出,F3对秋葵植株的效果显著,相比其他两种植株,它获得了最高的植株高度。另一方面,F6对茄子和辣椒都有最好的效果,从植株生长的第二个月到第四个月,它们的叶片生长最快。因此,该研究为废水提供了附加价值,而废水则用作合成植物营养增强剂,对植物最有效。
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引用次数: 0
Adsorption Of Methylene Blue By Imperata Cylindrica: Reaction Optimization By Response Surface Methodology (RSM) 响应面法优化白茅对亚甲基蓝的吸附
Pub Date : 2021-11-21 DOI: 10.15282/jceib.v7i2.7020
N. M. Salleh, F. F. Asmori, N. M. Shukri, S. F. M. Hanafiah
Imperata Cylindrica (IC) is a solid waste that is readily available throughout the year known as one of the most important weed in the world and frequently causes major disposal issues. As a result, using IC as a low-cost adsorbent is beneficial from both, economic and environmental standpoint to remove colors from wastewater of textile industry. This work studies the reaction optimization of methylene blue (MB) removal using IC by response surface methodology (RSM). The RSM experiments were designed with 4 independent variables (initial adsorbent dosage, initial pH, initial dye concentration, and initial temperature) and 1 response variable (percent removal of MB). According to the pareto figure, the initial pH demonstrated the greatest impact on the percent removal of MB. The RSM data predicted the optimum condition of MB removal up to 86.61% using IC, by utilizing adsorbent dosage of 1.458 g/L, at 42 oC, initial pH of 6.8 and MB concentration of 235 ppm. The chacterization analysis revealed the physicochemical properties of IC in the adsoprtion process.
白茅是一种固体废物,一年四季都可以得到,是世界上最重要的杂草之一,经常引起重大的处理问题。因此,采用集成电路作为一种低成本的吸附剂来去除纺织工业废水中的颜色,从经济和环境的角度来看都是有益的。本文采用响应面法(RSM)对IC去除亚甲基蓝(MB)的反应进行了优化研究。RSM实验设计了4个自变量(初始吸附剂用量、初始pH、初始染料浓度和初始温度)和1个响应变量(MB去除率)。由pareto图可知,初始pH对MB去除率的影响最大。RSM数据预测,当吸附剂用量为1.458 g/L,温度为42℃,初始pH为6.8,MB浓度为235 ppm时,IC对MB的去除率可达86.61%。表征分析揭示了IC在吸附过程中的物理化学性质。
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引用次数: 0
KAPOK AS AN ADSORBENT FOR INDUSTRIAL WASTEWATER 木棉作为工业废水的吸附剂
Pub Date : 2020-04-08 DOI: 10.15282/JCEIB.V5I2.3727
Alief Uzair Naharudin, S. Shaarani, Li Rou, N. Hamidi, Noormazlinah Ahmad, R. A. Rasid
The study focuses on investigating kapok fiber as an adsorbent for oily industrial wastewater. Kapok fiber, KF (Ceiba Pentandra) is a natural plant fiber that poses excellent hydrophobic-oleophilic characteristics, due to the presence of penetrable   hollow   lumen   structure   and   waxy   material on its surface. The objectives of this study are to investigate the morphology of raw and treated kapok fiber (KF) before and after adsorption of wastewater as well as to study the sorption capacity of KF (including raw KF, ethanol-treated KF and chloroform-treated KF) in wastewater. Hence, the morphology of raw KF and KF treated with oil are analysed using scanning electron microscopy (SEM). Besides, the sorption condition of different types of wastewater including emulsified wastewater, immiscible oil-and-liquid wastewater and non-oily wastewater on raw KF are studied in this experiment. From the study, the raw KF shows the best sorption capacity of oil (29.00g/g) compared to the ethanol-treated KF (18.22g/g) and Chloroform-treated KF (16.58g/g) as the treated KF has larger amount of cellulosic content (hydroxyl group) present on the wall of kapok, making it less oleophilic. On the other hand, raw KF has the lowest sorption capacity of water (0.59g/g) followed by ethanol-treated KF (3.05g/g) and chloroform-treated KF (3.20g/g) on non-oily wastewater. Kapok fiber shows great potential as oil sorbent on any type of oil owing to its excellent hydrophobicity-oleophilicity characteristic. In conclusion, the raw KF shows the best sorption capacity of oil compared to the ethanol-treated KF and chloroform-treated KF because the effectiveness is resulted from the hydrophobic waxy coating on the kapok surface. Besides that, the lower sorption capacity of water than oil is due to the incomplete removal of wax from the wall of kapok, making it a little hydrophilic (likes water) as compared to oleophilic (likes oil).
研究了木棉纤维作为含油工业废水的吸附剂。木棉纤维,KF (Ceiba Pentandra)是一种天然植物纤维,由于其表面存在可穿透的中空腔结构和蜡质材料,具有优异的疏水亲油特性。本研究的目的是研究生木棉纤维(KF)和处理木棉纤维(KF)吸附废水前后的形态,并研究KF(包括生木棉、乙醇处理的木棉和氯仿处理的木棉)在废水中的吸附能力。因此,使用扫描电子显微镜(SEM)分析了原始KF和经油处理的KF的形貌。此外,本实验还研究了乳化废水、不混相油液废水和不含油废水等不同类型的废水在原料KF上的吸附条件。从研究结果来看,与乙醇处理的KF (18.22g/g)和氯仿处理的KF (16.58g/g)相比,未经处理的KF表现出最好的吸油能力(29.00g/g),因为处理后的KF在木棉壁上有更多的纤维素含量(羟基),使其亲油性降低。另一方面,生KF对非含油废水的吸附能力最低(0.59g/g),其次是乙醇处理的KF (3.05g/g)和氯仿处理的KF (3.20g/g)。木棉纤维具有优异的疏水亲油特性,在任何类型的油上都显示出巨大的吸油潜力。综上所述,与乙醇处理的KF和氯仿处理的KF相比,生木棉的吸油能力最好,这是因为木棉表面的疏水性蜡涂层产生了吸油效果。除此之外,水的吸附能力低于油是由于木棉壁蜡的不完全去除,使得木棉的亲水性(喜欢水)略高于亲油性(喜欢油)。
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引用次数: 3
ELEMENTAL AND CHEMICAL COMPOSITION OF Moringa oleifera HUSK EXTRACTS 辣木皮提取物的元素和化学成分
Pub Date : 2019-05-01 DOI: 10.15282/JCEIB.V5I1.3897
M. Jami, M. Ahmad, Olalere Olusegun Abayomi, Mohammed Ngabura
Moringa oleifera is a well-known tropical plant with myriads medicinal and nutritional benefits. Its nutraceutical functions are due to the presence of mineral element and phytochemical components which necessitate their profiling. In this study, the elemental and chemical profiles of husk wastes from Moringa oleifera plants were elucidated using Liquid Chromatography equipped with an electrospray time-of-flight mass spectrometer (LCMS-QToF) and X-ray Fluorescence analyser. The confirmation of 493 bioactive compounds and two higher concentrations of micronutrients (calcium and potassium) indicated the potential of the Moringa oleifera extracts for medicinal and nutritional purposes. Also, the minimal presence of trace elements such as Cu, Si, Mo and Sr showed that they are non-toxic and can therefore be used as food supplement for both human and in animal feed. The result of this researchcould therefore provide lead for future investigation.
辣木是一种著名的热带植物,具有多种药用和营养价值。它的营养功能是由于矿物质元素和植物化学成分的存在,这就需要它们的谱图。采用电喷雾飞行时间质谱仪(LCMS-QToF)和x射线荧光分析仪对辣木果皮废弃物进行了元素和化学分析。证实了493种生物活性化合物和两种较高浓度的微量营养素(钙和钾),表明辣木提取物具有药用和营养用途的潜力。此外,微量元素如Cu, Si, Mo和Sr的存在表明它们是无毒的,因此可以用作人类和动物饲料的食品补充剂。因此,这项研究的结果可以为未来的研究提供线索。
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引用次数: 0
ETHNO-MEDICINAL POTENTIALS AND PHYTOCHEMICAL PROPERTIES OF Aloe vera: A REVIEW 芦荟的民族药用潜力及植物化学性质研究进展
Pub Date : 2019-05-01 DOI: 10.15282/JCEIB.V5I1.3896
J. A. Alara, O. R. Alara
Aloe vera is a perennial ethno-medicinal potential plant with a xerophytic characteristic, but not a cactus. It has a famous history owing to its phytopharmaceutical properties and this had made it useful in the pharmaceutical, cosmetic and food industries. Studies had shown the positive effects of its extract against bacteria, organisms. The phytochemical properties of A. vera have fungi, virus and parasitic been exploited for various economic and commercial purposes. This review contributes literature on the bioactive potential composition, processing and the pharmaceutical potential uses, an adverse side-effect that might spring up in case of over dosage and important safety precautions are summarized. More scientific innovations and developments in the aspect of analytical chemistry are on the way to provide more acceptable, purified chemical characterization of A. vera using sophisticated laboratory equipment and machines.
芦荟是一种具有旱生特性的多年生民族药用植物,而不是仙人掌。由于其植物药物特性,它有一个著名的历史,这使得它在制药,化妆品和食品工业中很有用。研究表明其提取物对细菌和生物体有积极作用。芦荟的植物化学特性已被开发用于各种经济和商业用途,包括真菌、病毒和寄生虫。本文综述了其生物活性成分、加工方法、潜在的药用价值、过量可能产生的不良反应以及重要的安全注意事项。在分析化学方面,更多的科学创新和发展正在进行中,利用先进的实验室设备和机器提供更可接受的、纯化的芦荟化学特性。
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引用次数: 2
NUMERICAL SIMULATION ON THE EFFECT OF CONCENTRATION ON PREMIXED CH4/CO2/AIR EXPLOSION CHARACTERISTICS 浓度对预混ch4 / co2 /空气爆炸特性影响的数值模拟
Pub Date : 2019-05-01 DOI: 10.15282/JCEIB.V5I1.3893
Nur Aqidah Muhammad Harinder Khan, S. Z. Sulaiman, I. Izhab, S. K. A. Mudalip, R. C. Man, S. Shaarani, Z. Arshad, R. Kasmani, S. Sulaiman
In this study, a numerical simulation on the premixed CH4/CO2/Air (methane/carbon dioxide/air) mixture explosion characteristics was conducted by using the Flame Acceleration Simulator (FLACs) software. The domain used in the 20 L spherical vessel with 0.808 m diameter. The effect of various equivalence ratios on the explosion characteristics such as the explosion pressure, Pex, maximum explosion overpressure, Pmax, the maximum rate of the pressure rise, (dP/dt)max and gas deflagration index, KG, were studied. For this purpose, the mixture concentrations range from equivalence ratio (ER) 0.8 to 1.5 (9.6 to 18% vol/vol) were considered. From this study, the explosion pressure, Pex, maximum explosion overpressure, Pmax, and the maximum rate of pressure rise, (dP/dt)max, at various ER was the maximum at a slightly rich concentration (ER=1.2). At lean and rich mixtures, the Pex, Pmax, (dP/dt)max and KG decreases. It can be said that, at ER=1.2, the role of thermal-diffusive instability and its effect on the flame speed during the pressure development process had causes the diffused methane, CH4, to react further into the flame front, which significantly increases the mixture mass burning rate and flame was also found to propagates the fastest at ER=1.2 due to the incompletecombustion process caused by the insufficient and excess CH4 present in the lean and rich mixtures. The CH4/CO2/air mixtures studied in this study were also found to have the highest level of hazard potential when exploded.
本研究利用火焰加速模拟器(FLACs)软件对CH4/CO2/Air(甲烷/二氧化碳/空气)预混混合物的爆炸特性进行了数值模拟。该域用于直径0.808 m的20 L球形容器。研究了不同当量比对爆炸压力Pex、最大爆炸超压Pmax、最大升压速率(dP/dt)max和气体爆燃指数KG等爆炸特性的影响。为此,考虑混合物浓度范围为等效比(ER) 0.8 ~ 1.5 (9.6 ~ 18% vol/vol)。从本研究可以看出,在不同的ER下,爆炸压力Pex、最大爆炸超压Pmax和最大压力上升速率dP/dt max在略富浓度(ER=1.2)时最大。贫、富混合料的Pex、Pmax、(dP/dt)max和KG均降低。可以说,在ER=1.2时,压力发展过程中热扩散不稳定性的作用及其对火焰速度的影响使得扩散的甲烷CH4进一步反应到火焰前缘,从而显著提高了混合气质量燃烧速率,并且在ER=1.2时,由于贫混合气和富混合气中CH4的不足和过剩导致燃烧过程不完全,火焰传播速度最快。本研究中所研究的CH4/CO2/空气混合物也被发现在爆炸时具有最高水平的潜在危害。
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引用次数: 0
ASSESSMENT OF MORINGA OLEIFERA CAKE RESIDUES (MOCR) AS ECO-FRIENDLY BIO- COAGULANT 辣木饼渣(mocr)作为环保型生物混凝剂的评价
Pub Date : 2019-05-01 DOI: 10.15282/JCEIB.V5I1.3888
A. Zaid, S. Ghazali, N. S. A. Mutamim, Olalere Olusegun Abayomi, N. H. Abdurahman
Inrecent times, the consumption of water for domestic and industrial use has been on an increasing trend with a rise in demand. Therefore, a need for a plant-based alternative of water treatment process at a lower cost using an environmentally friendly approach. Moringa olifeira is an example ogf the plant-based materials usually grown in developing countries with a natural coagulating property. In this study, the Jar test was conducted to evaluate the performance of Moringa olifeira cake residue (MOCR) as biocoagulant for the treatment of water for safe drinking. The result obtained showed the lowest turbidity, pH, TDS, and water conductivity value as 4.7 NTU (0.75 mg/L), 5.2 (2.5 mg/L), 40 ppm (1.0 mg/L), and 50us/cm (0.50 mg/L), respectively. Moreover, the standards COD and BOD values were less than the recommended Malaysian Standard of Water Quality of 250 mg/L and 100 mg/L, respectively. Hence, MOCR therefore is a potential source for plant-based coagulating agent for water treatment for domestic drinking water.
近年来,随着用水需求的增加,家庭和工业用水的消耗量呈上升趋势。因此,需要一种以植物为基础的水处理工艺的替代品,以更低的成本使用环保的方法。辣木是一种植物基材料,通常生长在发展中国家,具有天然凝固特性。本研究通过罐子试验对辣木饼渣(MOCR)作为生物混凝剂处理饮用水的性能进行了评价。结果表明,浊度、pH、TDS和水电导率的最低值分别为4.7 NTU (0.75 mg/L)、5.2 (2.5 mg/L)、40 ppm (1.0 mg/L)和50us/cm (0.50 mg/L)。此外,标准COD和BOD值分别低于推荐的马来西亚水质标准250 mg/L和100 mg/L。因此,MOCR因此是用于生活饮用水水处理的植物基混凝剂的潜在来源。
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引用次数: 2
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Journal of Chemical Engineering and Industrial Biotechnology
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