Mohson Al Hello, D. Burris, Mahdi Chitsaz, Lisa A. Rodenburg
Data on polycyclic aromatic hydrocarbons (PAHs) measured in surface sediment and cores in the New York/New Jersey Harbour under the Contamination Assessment and Reduction Project (CARP) was examined via Positive Matrix Factorization (PMF), which revealed six sources. Two represented the higher and lower molecular weight (MW) fractions of coal tar and/or creosote (pyrogenic) sources and explained 49% of PAH mass in the sediment samples. Two sources were related to uncombusted petroleum (petrogenic) sources, such as heavy fuel oil and crude oil, and explained 30% of PAH mass. The final two sources were related to combustion (pyrogenic) sources such as gasoline‐ and diesel‐fuelled vehicles and explained 21% of the PAH mass. Sediment cores revealed that Σ22PAH increased from the pre‐industrial period until about 1980 and then decreased because of efforts to control water pollution via mechanisms such as the Clean Water Act.
{"title":"Source apportionment of polycyclic aromatic hydrocarbons in New York/New Jersey Harbour sediment","authors":"Mohson Al Hello, D. Burris, Mahdi Chitsaz, Lisa A. Rodenburg","doi":"10.1111/wej.12856","DOIUrl":"https://doi.org/10.1111/wej.12856","url":null,"abstract":"Data on polycyclic aromatic hydrocarbons (PAHs) measured in surface sediment and cores in the New York/New Jersey Harbour under the Contamination Assessment and Reduction Project (CARP) was examined via Positive Matrix Factorization (PMF), which revealed six sources. Two represented the higher and lower molecular weight (MW) fractions of coal tar and/or creosote (pyrogenic) sources and explained 49% of PAH mass in the sediment samples. Two sources were related to uncombusted petroleum (petrogenic) sources, such as heavy fuel oil and crude oil, and explained 30% of PAH mass. The final two sources were related to combustion (pyrogenic) sources such as gasoline‐ and diesel‐fuelled vehicles and explained 21% of the PAH mass. Sediment cores revealed that Σ22PAH increased from the pre‐industrial period until about 1980 and then decreased because of efforts to control water pollution via mechanisms such as the Clean Water Act.","PeriodicalId":23753,"journal":{"name":"Water and Environment Journal","volume":null,"pages":null},"PeriodicalIF":2.0,"publicationDate":"2023-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48851056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiaoying Chen, Lin Chen, Xin-guo Yang, Minlan Li, N. Song
The spatial distribution of water is mainly controlled by the vegetation canopy, which determines the partitioning of rainfall into interception, throughfall (TF) and stemflow. TF is known to be a critical component of hydrological and biogeochemical cycles. Spatiotemporal patterns of TF have been studied in different ecosystems, although the majority of studies focused on forests. Few reports on small‐scale TF variability and drivers in semi‐arid desert steppes have been published. Herein, we investigated the variability of TF of two morphologically distinct artificial revegetation shrubs (Caragana liouana and Salix psammophila) within a semi‐arid desert steppe, synthesized the data and analysed the characteristics of TF distribution and drivers at the rainfall event scales. We found that (1) morphological differences were sufficient to generate significant (p < 0.05) differences in TF between the two shrub species under the same rainfall and meteorological conditions, with a TF percentage of 70.22% for C. liouana and 79.87% for S. psammophila; (2) a linear outward radical increase in TF was identified with increasing distance from the base of the isolated shrubs. Wind speed had a greater effect on the distribution of TF beneath the shrub structure for C. liouana, whereas the distribution of TF beneath the shrub structure for S. psammophila was more affected by wind direction; and (3) canopy architecture, in particular the stem angle and canopy base area, which affected the openness of the canopy and played an important role in the distribution of TF in the two shrubs. The results reveal the key factors driving water use under rainfall during revegetation and the TF utilization mechanism in semi‐arid areas and highlight the complementary effect of different species on ecosystem hydrological functions.
{"title":"Spatial distribution and drivers of throughfall beneath shrub canopies in a semi‐arid desert steppe","authors":"Xiaoying Chen, Lin Chen, Xin-guo Yang, Minlan Li, N. Song","doi":"10.1111/wej.12853","DOIUrl":"https://doi.org/10.1111/wej.12853","url":null,"abstract":"The spatial distribution of water is mainly controlled by the vegetation canopy, which determines the partitioning of rainfall into interception, throughfall (TF) and stemflow. TF is known to be a critical component of hydrological and biogeochemical cycles. Spatiotemporal patterns of TF have been studied in different ecosystems, although the majority of studies focused on forests. Few reports on small‐scale TF variability and drivers in semi‐arid desert steppes have been published. Herein, we investigated the variability of TF of two morphologically distinct artificial revegetation shrubs (Caragana liouana and Salix psammophila) within a semi‐arid desert steppe, synthesized the data and analysed the characteristics of TF distribution and drivers at the rainfall event scales. We found that (1) morphological differences were sufficient to generate significant (p < 0.05) differences in TF between the two shrub species under the same rainfall and meteorological conditions, with a TF percentage of 70.22% for C. liouana and 79.87% for S. psammophila; (2) a linear outward radical increase in TF was identified with increasing distance from the base of the isolated shrubs. Wind speed had a greater effect on the distribution of TF beneath the shrub structure for C. liouana, whereas the distribution of TF beneath the shrub structure for S. psammophila was more affected by wind direction; and (3) canopy architecture, in particular the stem angle and canopy base area, which affected the openness of the canopy and played an important role in the distribution of TF in the two shrubs. The results reveal the key factors driving water use under rainfall during revegetation and the TF utilization mechanism in semi‐arid areas and highlight the complementary effect of different species on ecosystem hydrological functions.","PeriodicalId":23753,"journal":{"name":"Water and Environment Journal","volume":null,"pages":null},"PeriodicalIF":2.0,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41413296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shukran Alizada, Fakhreddin Eminli, Amir Reza Vakhshouri
A major problem coming across humanity in the early 21st century is related to environmental crises, including shortage and pollution of water sources. For this reason, extensive studies have been conducted to find effective techniques for purifying water from industrial pollutants. Advanced oxidation process (AOP) has lately caught the attention of researchers, which is an efficient, clean and contemporary method to remedy wastewater effluents. However, primitive versions of AOP methods lacked several aspects like strict pH requirements and involvement of sediments, which is why further modifications to the technique have been developed, including an electrochemical catalytic degradation approach, namely, electro‐Fenton and similar processes. This study will look through a set of novel papers investigating the application of various electrodes for the electrochemical treatment of solutions contaminated with phenol and phenolic compounds, which tried to address several shortcomings of more outdated practices and optimize the method for a set of different scenarios.
{"title":"A review of novel electrode materials and techniques for electro‐Fenton process applied to the degradation of phenolic compounds","authors":"Shukran Alizada, Fakhreddin Eminli, Amir Reza Vakhshouri","doi":"10.1111/wej.12854","DOIUrl":"https://doi.org/10.1111/wej.12854","url":null,"abstract":"A major problem coming across humanity in the early 21st century is related to environmental crises, including shortage and pollution of water sources. For this reason, extensive studies have been conducted to find effective techniques for purifying water from industrial pollutants. Advanced oxidation process (AOP) has lately caught the attention of researchers, which is an efficient, clean and contemporary method to remedy wastewater effluents. However, primitive versions of AOP methods lacked several aspects like strict pH requirements and involvement of sediments, which is why further modifications to the technique have been developed, including an electrochemical catalytic degradation approach, namely, electro‐Fenton and similar processes. This study will look through a set of novel papers investigating the application of various electrodes for the electrochemical treatment of solutions contaminated with phenol and phenolic compounds, which tried to address several shortcomings of more outdated practices and optimize the method for a set of different scenarios.","PeriodicalId":23753,"journal":{"name":"Water and Environment Journal","volume":null,"pages":null},"PeriodicalIF":2.0,"publicationDate":"2023-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43369332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Aly Al-sayed, M. Hellal, Mona T. Al-Shemy, Gamal K. Hassan
In this study, flat sheet submerged MBR (FS‐SMBR) was investigated under 6 and 4 h hydraulic retention times (HRT) and 40 days solid retention time with real municipal wastewater. The implementation of the treatment system was evaluated in terms of physico‐chemical and microbial analysis as well as sludge characterization. The permeate of FS‐SMBR complied with the standards for reuse and non‐detectable levels of faecal coliform was achieved at 6 and 4 h HRTs, with pore‐blocking resistances (Rt) of 28 × 1011 and 40 × 1011/m, respectively. Examining another dominant factor, that is, sludge viscosity, the best results were acquired using HRT 4 h for domestic wastewater. Furthermore, the results obtained were validated and calibrated using the GPS‐X software simulator, and the results of modelled data were completely matched with the experimental data under the same conditions.
{"title":"Performance evaluation of submerged membrane bioreactor for municipal wastewater treatment: Experimental study and model validation with GPS‐X software simulator","authors":"Aly Al-sayed, M. Hellal, Mona T. Al-Shemy, Gamal K. Hassan","doi":"10.1111/wej.12852","DOIUrl":"https://doi.org/10.1111/wej.12852","url":null,"abstract":"In this study, flat sheet submerged MBR (FS‐SMBR) was investigated under 6 and 4 h hydraulic retention times (HRT) and 40 days solid retention time with real municipal wastewater. The implementation of the treatment system was evaluated in terms of physico‐chemical and microbial analysis as well as sludge characterization. The permeate of FS‐SMBR complied with the standards for reuse and non‐detectable levels of faecal coliform was achieved at 6 and 4 h HRTs, with pore‐blocking resistances (Rt) of 28 × 1011 and 40 × 1011/m, respectively. Examining another dominant factor, that is, sludge viscosity, the best results were acquired using HRT 4 h for domestic wastewater. Furthermore, the results obtained were validated and calibrated using the GPS‐X software simulator, and the results of modelled data were completely matched with the experimental data under the same conditions.","PeriodicalId":23753,"journal":{"name":"Water and Environment Journal","volume":null,"pages":null},"PeriodicalIF":2.0,"publicationDate":"2023-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47643117","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Desalter effluent (DE) is typically discharged into a petroleum wastewater treatment plant, but its high salt concentration deteriorates the biological treatment. This study used various dilution rates to investigate the treatment of a synthetic DE containing dodecane under saline conditions using a halotolerant yeast, Debaryomyces hansenii, to determine the optimum substrate concentration for use in continuous stirred‐tank reactors (CSTRs). A literature review indicated that this study was the first to examine the biological treatment of DE using D. hansenii in a CSTR system. At a low dodecane substrate concentration, DE did not inhibit D. hansenii growth, and the experimental data approached the Monod model, with μmax and Ks selected as 0.08 h−1 and 1575 mg L−1, respectively. The optimum removal of chemical oxygen demand (95.7% and 85%) was obtained at dilution rates of 0.007 and 0.026 d−1. Using D. hansenii in a CSTR system appeared to be a sustainable approach for the biological treatment of DE. Scale‐up of these laboratory findings to the industrial scale is required to confirm that petroleum DE can be treated using equalization and filtration tanks as a continuous bioreactor. Adjusting the dilution rate can provide sufficient time for biodegradation and hydrocarbon removal from high salt DE by halotolerant yeasts like D. hansenii.
脱盐出水是石油废水处理中常见的污水，其高含盐量影响了生物处理效果。本研究采用不同的稀释率，研究了在盐水条件下使用耐盐酵母汉斯德巴氏酵母(Debaryomyces hansenii)处理含十二烷的合成DE的方法，以确定连续搅拌槽反应器(cstr)中使用的最佳底物浓度。文献综述表明，本研究首次研究了在CSTR系统中使用汉斯氏杆菌对DE的生物治疗。在低十二烷底物浓度下，DE对汉斯氏菌的生长没有抑制作用，实验数据接近Monod模型，μmax和Ks分别为0.08 h−1和1575 mg L−1。稀释率分别为0.007和0.026 d - 1时，化学需氧量去除率最高(95.7%和85%)。在CSTR系统中使用D. hansenii似乎是一种可持续的生物处理DE的方法。需要将这些实验室研究结果扩大到工业规模，以证实石油DE可以使用平衡池和过滤池作为连续生物反应器进行处理。调节稀释率可以为耐盐酵母如汉斯氏酵母对高盐DE的生物降解和脱烃提供足够的时间。
{"title":"Continuous cultivation of Debaryomyces hansenii (LAF‐3 10 U) on dodecane in synthetic desalter effluent at varying dilution rates on dodecane","authors":"Leila Azimian","doi":"10.1111/wej.12850","DOIUrl":"https://doi.org/10.1111/wej.12850","url":null,"abstract":"Desalter effluent (DE) is typically discharged into a petroleum wastewater treatment plant, but its high salt concentration deteriorates the biological treatment. This study used various dilution rates to investigate the treatment of a synthetic DE containing dodecane under saline conditions using a halotolerant yeast, Debaryomyces hansenii, to determine the optimum substrate concentration for use in continuous stirred‐tank reactors (CSTRs). A literature review indicated that this study was the first to examine the biological treatment of DE using D. hansenii in a CSTR system. At a low dodecane substrate concentration, DE did not inhibit D. hansenii growth, and the experimental data approached the Monod model, with μmax and Ks selected as 0.08 h−1 and 1575 mg L−1, respectively. The optimum removal of chemical oxygen demand (95.7% and 85%) was obtained at dilution rates of 0.007 and 0.026 d−1. Using D. hansenii in a CSTR system appeared to be a sustainable approach for the biological treatment of DE. Scale‐up of these laboratory findings to the industrial scale is required to confirm that petroleum DE can be treated using equalization and filtration tanks as a continuous bioreactor. Adjusting the dilution rate can provide sufficient time for biodegradation and hydrocarbon removal from high salt DE by halotolerant yeasts like D. hansenii.","PeriodicalId":23753,"journal":{"name":"Water and Environment Journal","volume":null,"pages":null},"PeriodicalIF":2.0,"publicationDate":"2023-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46667236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Bisphenol A (BPA), a chemical additive in polycarbonate plastics and epoxy resins, is suspected to be an endocrine‐disrupter. Extensive use and irregular treating methods have led to frequent detection of BPA in wastewater, raising demand for their removal by efficient nanomaterials‐based technique. Nanocomposite CuO@NiHCF was synthesized via green method using Citrus aurantium peel extract. Crystalline structure (particle size <50 nm) of CuO@NiHCF was analysed by microscopic and spectroscopic analysis. This nanocomposite showed 97% degradation of BPA (50 mg L−1) at neutral pH in sunlight. Moreover, improved particle stability (zeta potential: −56.2 mV; 2.0 eV) and high surface area, pore volume (81 m2g−1, 13.9 nm) resulted from synergism of NiHCF (−26.3 mV; 2.4 eV), and CuO (−11.5 mV; 1.9 eV) led to efficient photodegradation of BPA. Degradation of BPA was found photo‐adsorptive. Moreover, degradation was carried out by OH radicals based with ring‐opening mechanisms by GC–MS. High efficiency and sustainability of CuO@NiHCF were revealed by its multiple reusability (n = 10), leading to a promising and sustainable photocatalyst.
{"title":"Efficient photocatalytic degradation of bisphenol A by green synthesized CuO decorated nickel hexacyanoferrate nanocomposite","authors":"Meenu, M. Rani, U. Shanker","doi":"10.1111/wej.12847","DOIUrl":"https://doi.org/10.1111/wej.12847","url":null,"abstract":"Bisphenol A (BPA), a chemical additive in polycarbonate plastics and epoxy resins, is suspected to be an endocrine‐disrupter. Extensive use and irregular treating methods have led to frequent detection of BPA in wastewater, raising demand for their removal by efficient nanomaterials‐based technique. Nanocomposite CuO@NiHCF was synthesized via green method using Citrus aurantium peel extract. Crystalline structure (particle size <50 nm) of CuO@NiHCF was analysed by microscopic and spectroscopic analysis. This nanocomposite showed 97% degradation of BPA (50 mg L−1) at neutral pH in sunlight. Moreover, improved particle stability (zeta potential: −56.2 mV; 2.0 eV) and high surface area, pore volume (81 m2g−1, 13.9 nm) resulted from synergism of NiHCF (−26.3 mV; 2.4 eV), and CuO (−11.5 mV; 1.9 eV) led to efficient photodegradation of BPA. Degradation of BPA was found photo‐adsorptive. Moreover, degradation was carried out by OH radicals based with ring‐opening mechanisms by GC–MS. High efficiency and sustainability of CuO@NiHCF were revealed by its multiple reusability (n = 10), leading to a promising and sustainable photocatalyst.","PeriodicalId":23753,"journal":{"name":"Water and Environment Journal","volume":null,"pages":null},"PeriodicalIF":2.0,"publicationDate":"2023-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48066257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yıldız Şahin, Sedanur Selay Kasap, Gokçe Akyol, N. Akyol
Within the scope of the study, the effectiveness of the experimental conditions was tested by performing a multi‐response Taguchi experimental design for the optimization of the minimum cost remediation performance with Tween 80, Methyl beta cyclodextrine (MCD) and Sodium dodecyl sulfate (SDS) from tetrachloroethylene (PCE) contaminated porous media. Tween 80, MCD and SDS were extensively used in cosmetic industry as emulsifier. Both time of remediation and cost of remediation were studied as two separate response variables in three replicate experiments conducted according to the Taguchi L9 orthogonal experimental design. In the multi‐response Taguchi analysis, the sensitivity analysis was performed by systematically changing the weights determined for two separate response variables in the calculation of total loss of quality (TNQLj). Optimum experimental conditions were determined with the help of the calculated multi‐response signal/noise (S/N) ratios (MRSN). The results show that the type of Flushing Agent is the most important factor in optimizing the remediation time and remediation cost for the removal of dense non‐aqueous phase liquid (DNAPL) PCE mass. Flushing rate is considered to be the least contributing factor. Furthermore, the results of the analysis of variance (ANOVA) showed that all parameters used in the system had a significant effect on the experimental results and the Taguchi method could explain 97.15% of the Remediation Time and 92.03% of the Remediation Cost. Afterwards, the data obtained from the experiments performed according to the experimental design were modelled using Artificial Neural Network (ANN) to estimate the remediation performance and remediation cost without performing new experiments.
{"title":"Multi‐response optimization of process parameters for remediation of tetrachloroethylene pools by surfactants: Application of Taguchi design of experiment and Artificial Neural Network","authors":"Yıldız Şahin, Sedanur Selay Kasap, Gokçe Akyol, N. Akyol","doi":"10.1111/wej.12849","DOIUrl":"https://doi.org/10.1111/wej.12849","url":null,"abstract":"Within the scope of the study, the effectiveness of the experimental conditions was tested by performing a multi‐response Taguchi experimental design for the optimization of the minimum cost remediation performance with Tween 80, Methyl beta cyclodextrine (MCD) and Sodium dodecyl sulfate (SDS) from tetrachloroethylene (PCE) contaminated porous media. Tween 80, MCD and SDS were extensively used in cosmetic industry as emulsifier. Both time of remediation and cost of remediation were studied as two separate response variables in three replicate experiments conducted according to the Taguchi L9 orthogonal experimental design. In the multi‐response Taguchi analysis, the sensitivity analysis was performed by systematically changing the weights determined for two separate response variables in the calculation of total loss of quality (TNQLj). Optimum experimental conditions were determined with the help of the calculated multi‐response signal/noise (S/N) ratios (MRSN). The results show that the type of Flushing Agent is the most important factor in optimizing the remediation time and remediation cost for the removal of dense non‐aqueous phase liquid (DNAPL) PCE mass. Flushing rate is considered to be the least contributing factor. Furthermore, the results of the analysis of variance (ANOVA) showed that all parameters used in the system had a significant effect on the experimental results and the Taguchi method could explain 97.15% of the Remediation Time and 92.03% of the Remediation Cost. Afterwards, the data obtained from the experiments performed according to the experimental design were modelled using Artificial Neural Network (ANN) to estimate the remediation performance and remediation cost without performing new experiments.","PeriodicalId":23753,"journal":{"name":"Water and Environment Journal","volume":null,"pages":null},"PeriodicalIF":2.0,"publicationDate":"2023-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46439151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Tuomikoski, E. Sauvola, Marko Riponiemi, U. Lassi, J. Pesonen
Struvite is a suitable fertilizer, and electrochemical precipitation of nutrients from industrial waters provides one answer to the circular economy. Molar ratio between ammonium and phosphate is crucial: Water suitable for the precipitation includes more or at least the same amount ammonium than phosphate. That kind of water typically does not exist in industry. Therefore, ammonium‐rich industrial water was mixed with phosphorus‐rich water to obtain a suitable molar ratio for struvite precipitation. Parameters were studied to determine their effect on removal‐% and struvite yield. 100% struvite yield was obtained under several conditions even without pH control with pH 7–9. The highest phosphate removal (99.7%) was occurred with the molar ratio 1.7:2:1 for Mg:NH4:PO4 (pH 9.0). Waters dilution prevents magnesium anode corrosion. Formed struvite has potential as recycled fertilizer due to low bioavailability of metals and high leachability of nutrients studied by four‐stage sequential leaching.
{"title":"Usage of phosphoric acid plant's circulate pond waters in struvite precipitation—Effect of conditions","authors":"S. Tuomikoski, E. Sauvola, Marko Riponiemi, U. Lassi, J. Pesonen","doi":"10.1111/wej.12848","DOIUrl":"https://doi.org/10.1111/wej.12848","url":null,"abstract":"Struvite is a suitable fertilizer, and electrochemical precipitation of nutrients from industrial waters provides one answer to the circular economy. Molar ratio between ammonium and phosphate is crucial: Water suitable for the precipitation includes more or at least the same amount ammonium than phosphate. That kind of water typically does not exist in industry. Therefore, ammonium‐rich industrial water was mixed with phosphorus‐rich water to obtain a suitable molar ratio for struvite precipitation. Parameters were studied to determine their effect on removal‐% and struvite yield. 100% struvite yield was obtained under several conditions even without pH control with pH 7–9. The highest phosphate removal (99.7%) was occurred with the molar ratio 1.7:2:1 for Mg:NH4:PO4 (pH 9.0). Waters dilution prevents magnesium anode corrosion. Formed struvite has potential as recycled fertilizer due to low bioavailability of metals and high leachability of nutrients studied by four‐stage sequential leaching.","PeriodicalId":23753,"journal":{"name":"Water and Environment Journal","volume":null,"pages":null},"PeriodicalIF":2.0,"publicationDate":"2023-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41286151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. Makhtar, J. Idris, M. Musa, Y. Andou, K. Hamid, S. W. Puasa, Rafidah Husen
The effect of the interaction factor between pH and dosage is important in leachate wastewater treatment. This study aims to remove leachate pollutants such as turbidity, total suspended solid (TSS), chemical oxygen demand (COD) and colour using simultaneous factors of plant‐based Tacca leontopetaloides biopolymer flocculant (TBPF) dosage and leachate pH. The flocculation process was carried out through jar test by applying the perikinetic theory and statical analysis (face‐centred central composite design). The results found that the optimum leachate pH and TBPF dosage were pH 3 and 150 mg/L, respectively. The highest removal of leachate pollutants reached up to 69% with a second‐order perikinetic model; R2 = 0.9545 and k = 9 × 10−6 L/mg/min were obtained. Simultaneous interaction factors between leachate pH and TBPF dosage on turbidity and TSS removal were found significant and hence can be applied in the actual leachate wastewater treatment industry, particularly at the primary stage using the proposed model.
{"title":"Removal of leachate pollutants using flocculation method at simultaneous factors of optimum pH and Tacca leontopetaloides biopolymer flocculant (TBPF) dosage via face‐centred central composite design","authors":"N. Makhtar, J. Idris, M. Musa, Y. Andou, K. Hamid, S. W. Puasa, Rafidah Husen","doi":"10.1111/wej.12846","DOIUrl":"https://doi.org/10.1111/wej.12846","url":null,"abstract":"The effect of the interaction factor between pH and dosage is important in leachate wastewater treatment. This study aims to remove leachate pollutants such as turbidity, total suspended solid (TSS), chemical oxygen demand (COD) and colour using simultaneous factors of plant‐based Tacca leontopetaloides biopolymer flocculant (TBPF) dosage and leachate pH. The flocculation process was carried out through jar test by applying the perikinetic theory and statical analysis (face‐centred central composite design). The results found that the optimum leachate pH and TBPF dosage were pH 3 and 150 mg/L, respectively. The highest removal of leachate pollutants reached up to 69% with a second‐order perikinetic model; R2 = 0.9545 and k = 9 × 10−6 L/mg/min were obtained. Simultaneous interaction factors between leachate pH and TBPF dosage on turbidity and TSS removal were found significant and hence can be applied in the actual leachate wastewater treatment industry, particularly at the primary stage using the proposed model.","PeriodicalId":23753,"journal":{"name":"Water and Environment Journal","volume":null,"pages":null},"PeriodicalIF":2.0,"publicationDate":"2023-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47772637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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