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VOLATILE ORGANIC COMPOUNDS AND METALS ADSORPTION CAPACITY OF WOOD BARK-BASED ACTIVATED CARBONS 树皮基活性炭对挥发性有机物和金属的吸附性能
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-04-26 DOI: 10.37763/wr.1336-4561/68.2.360375
Young-Kyu Lee, O. Kwon, Won-Sil Choi, Myoungcheol Moon, J. So, Vilasit Thithai, J. Choi, Da-Yeong Kim, IN Yang
This study was conducted to investigate the applicability of wood bark-based activated carbon (AC) for the adsorption of metal ions and volatile organic compounds (VOC) from the atmosphere. Contents of Fe and Al in the AC made with coconut shell, and the bark of larch and cork oak (CSA, LBA and COA, respectively) were higher than those of the unexposed AC and increased with the exposure to various indoor/outdoor spaces when compared to the unexposed AC. However, Fe and Al contents of the exposed AC, which is a coal-based one used as a control (SAA), were lower and scarcely higher than the unexposed SAA. From the results, it is evident that the wood bark-based AC examined in this study is more effective to adsorb metals than SAA. The SEM-EDS analysis exhibited prominent metal-adsorptivity of COA, although its total surface area and pore volume were lower than those of SAA. Total VOC-adsorptivity was the highest in COA followed by CSA, CBA (cypress bark activated carbon), LBA and SAA. In conclusion, wood bark-based AC can be utilized as an effective adsorbent for the removal of metals and VOC from the atmosphere. The optimum AC is COA, an industrial by-product, in view of the techno-economic aspect.
本研究旨在研究树皮基活性炭(AC)吸附大气中金属离子和挥发性有机化合物(VOC)的适用性。用椰子壳制成的AC以及落叶松和软木橡树皮(分别为CSA、LBA和COA)中的Fe和Al含量高于未暴露AC,并且与未暴露AC相比,随着暴露于各种室内/室外空间而增加,低于且几乎不高于未暴露的SAA。从结果中可以明显看出,本研究中检测的树皮基AC比SAA更有效地吸附金属。SEM-EDS分析显示COA具有显著的金属吸附性,尽管其总表面积和孔体积低于SAA。总VOC吸附率在COA中最高,其次是CSA、CBA、LBA和SAA。总之,树皮基AC可以作为一种有效的吸附剂去除大气中的金属和VOC。从技术经济角度来看,最佳AC是工业副产品COA。
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引用次数: 0
EFFECTS OF PYROLYSIS PROCESS ON PRODUCTS YIELD OF PLYWOOD FROM ABANDONED FURNITURE 热解过程对废弃家具胶合板产率的影响
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-04-26 DOI: 10.37763/wr.1336-4561/68.2.348359
Xinyou Liu, Changjun Zhang, Shufan Yang, A. Varodi
In this paper, the plywood obtained from dismantling discarded furniture was selected as pyrolysis experimental materials. Pyrolysis was performed at a heating rate of 100°C/h, 150°C/h and 200°C/h and pyrolysis temperatures of 400°C, 500°C, and 600°C to evaluate the effects of pyrolysis process on products yield and the products features. The results show that the yield of solid products gradually decreases with the increase of pyrolysis temperature and heating rate while liquid products and non-condensing gases' yield gradually increases. The carbon content in solid products reached 80.76 - 94.35%. Carbon content gradually decreases with pyrolysis temperature, but the proportion of C/H and C/N gradually increases. The pyrolysis solution is weakly acidic due to the adhesives in pyrolysis material.
本文选取废旧家具拆解所得的胶合板作为热解实验材料。在升温速率为100℃/h、150℃/h和200℃/h,热解温度为400℃、500℃和600℃的条件下进行热解,评价热解工艺对产物收率和产物特性的影响。结果表明:随着热解温度和升温速率的升高,固体产物的产率逐渐降低,而液体产物和非冷凝气体的产率逐渐增加;固体产品含碳量达到80.76 ~ 94.35%。随着热解温度的升高,碳含量逐渐降低,而C/H和C/N的比例逐渐升高。热解液因热解材料中存在黏合剂而呈弱酸性。
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引用次数: 1
CHEMICAL COMPOSITION AND POTENTIAL USES OF LEUCAENA LEUCOCEPHALA STEM BARK 银合欢茎皮的化学成分及潜在用途
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-04-26 DOI: 10.37763/wr.1336-4561/68.2.241256
R. Salim, J. Asik, M. Sarjadi, Liew Kang Chiang
Leucaena leucocephala stem bark that was eleven years old was studied for its chemical composition and usage. The samples were subjected to chemical analyses based on ASTM standard procedures after being air-dried for several days. The results found that the bark of L. leucocephala has a pH value of 6.04 and that the solubility of the bark in 1% NaOH alkali is the highest compared to the solubility in hot water (14.45%) and cold water (14.36%), while the chemical composition of the bark of L. leucocephala was ash (15.76%); extractives (8.39%); holocellulose (132.85%); hemicellulose (103.66%); cellulose (29.19%) and lignin (38.24%). Based on the findings, L. leucocephala bark was less acidic. When used as a source of carbohydrates, bark has a high solubility, and its chemical composition may have an impact on how quickly it burns when it is pyrolysed.
对11年生银合欢茎皮的化学成分和用途进行了研究。样品在风干几天后,根据ASTM标准程序进行化学分析。结果发现,白头马树皮的pH值为6.04,白头马树皮在1% NaOH碱中的溶解度最高,在热水中的溶解度为14.45%,在冷水中的溶解度为14.36%,白头马树皮的化学成分为灰分(15.76%);抽提(8.39%);全纤维素(132.85%);半纤维素(103.66%);纤维素(29.19%)和木质素(38.24%)。根据研究结果,白头草树皮的酸性较低。当用作碳水化合物的来源时,树皮具有很高的溶解度,其化学成分可能会影响其热解时的燃烧速度。
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引用次数: 0
EVOLUTION AND DISTRIBUTION OF SHAKES IN LARCH LOGS DURING AIR DRYING 落叶松原木风干过程中振动的演化与分布
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-04-26 DOI: 10.37763/wr.1336-4561/68.2.208223
Sidong Wang, Fenghao Zhang, Dongsheng Chen, Jing-hui Jiang
This paper analyzed the length, width, and location of shakes in the air-drying process of larch log (Larix principis-rupprechtii Mayr) 1 m long and 66% initial moisture content. The development law and distribution characteristics of shakes during log drying of larch were studied and shake generation and development law were analyzed from two aspects of microstructure and growth defects. The variation of dry shrinkage deformation along the radial direction and knot influence on it was analyzed using the split-shaped stress test strips. At the cellular level, the cell wall shrinkage behavior of heartwood and sapwood and the microstructure of knots were observed. The results showed a significant relationship between eccentricity and shake distribution; the IIa region is the most prone to dry shake. The evolution of shakes is closely related to the drying rate. In the high-speed drying stage (MC ≥ 40%), shakes almost do not occur; in the decelerating drying stage (40% ≥ MC ≥ 20%), the amount, length, and width of shakes increase rapidly. In the low-speed drying stage (20% ≥MC), the area of shakes tends to stabilize or even decline. The main reasons for dry shaking are the dry shrinkage difference between tangential and radial cell walls, early and late wood, heartwood and sapwood, and moisture content gradient during the drying process.
本文分析了落叶松(Larix principles rupprechtii Mayr)1m长、初始含水率为66%的原木在空气干燥过程中抖动的长度、宽度和位置。研究了落叶松原木干燥过程中振动的发展规律和分布特征,从微观结构和生长缺陷两个方面分析了振动的产生和发展规律。利用分体式应力测试条,分析了干缩变形沿径向的变化及其结对干缩变形的影响。在细胞水平上,观察了心材和边材的细胞壁收缩行为以及节的微观结构。结果表明,离心率与振动分布之间存在显著关系;IIa区域最容易发生干抖。抖动的演变与干燥速率密切相关。在高速干燥阶段(MC≥40%),几乎不会发生抖动;在减速干燥阶段(40%≥MC≥20%),抖动的数量、长度和宽度迅速增加。在低速干燥阶段(20%≥MC),抖动面积趋于稳定甚至下降。干摇的主要原因是切向和径向细胞壁、早期和晚期木材、心材和边材之间的干缩差异,以及干燥过程中的含水量梯度。
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引用次数: 0
A SYNERGIC EFFECT OF WATER-BASED ACRYLIC RESIN WITH BORIC ACID ON LEACHABILITY 水性丙烯酸树脂与硼酸对浸出力的协同效应
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-04-26 DOI: 10.37763/wr.1336-4561/68.2.268278
Özlem Keleş, Sefa Durmaz
In this study, the Scots pine wood samples were impregnated (single treatment) with boric acid combined with two types of water-based acrylic resin (pure acrylic and semi-translucent acrylic emulsion) to limit the boron leaching and improve the decay resistance. The results showed dimensional stability in anti-swelling efficiency and water absorption improved in wood specimens treated with boric acid and acrylic types. While the leachability was over 90% for only 3% boric acid-impregnated wood (control), it was calculated at 36% for acrylic emulsions-impregnated wood. Although there were no weight losses for the unleached woods, it was up to 9% for leached woods impregnated with acrylic resin and emulsion. The 25% acrylic emulsion had no weight losses after the leaching test for Coniophora puteana and Trametes versicolor. The boric acid combined with acrylic resin can improve the leaching resistance with the synergic effect, enhancing resistance against biological threats.
在本研究中,将硼酸与两种类型的水性丙烯酸树脂(纯丙烯酸和半透明丙烯酸乳液)相结合,对苏格兰松木样品进行浸渍(单次处理),以限制硼的浸出并提高耐腐性。结果表明,用硼酸和丙烯酸处理的木材试样在尺寸稳定性、抗溶胀效率和吸水性方面得到了改善。虽然只有3%硼酸浸渍的木材(对照)的可浸出性超过90%,但丙烯酸乳液浸渍的木材的可浸出率为36%。虽然未经处理的木材没有重量损失,但用丙烯酸树脂和乳液浸渍的浸提木材的重量损失高达9%。25%丙烯酸乳液在对丝兰和云芝的浸出试验后没有重量损失。硼酸与丙烯酸树脂复合可以提高耐浸性,并具有协同作用,增强对生物威胁的抵抗力。
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引用次数: 0
FIXATION OF DYE-TYPE RED AND BLUE INK HANDWRITING ON AGED PAPER 在旧纸上固定染料型红、蓝墨笔迹
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-04-26 DOI: 10.37763/wr.1336-4561/68.2.320333
Linhan Mi, Wei Tan, Ting Wu, Xiaolan Cai, Chenqian Pan, Yanxiong Fang
In this article, red and blue ink handwriting on aged paper was fixed by fixative to prevent handwriting from fading or diffusion during aqueous deacidification. Firstly, four fixatives were selected: polydimethyl ammonium chloride (PDDA), the quaternary ammonium salt of chitosan (HACC), cationic guar gum (CGG), and benzyl triethyl ammonium chloride (TEBAC) alcohol solution, according to their fixation effects on filter paper dyes, and derive the optimal composition ratio of the above four fixatives. Experimentally derived that PDDA has an excellent fixation effect on red ink handwriting, and HACC has an excellent fixation effect on blue ink handwriting. In addition, HACC also has a positive impact on the conservation of handwriting in real archives. The mechanical properties of aged paper were improved, and the paper fibers had no obvious change after the fixation and deacidification processes.
本文采用固定剂对老化纸张上的红蓝墨水字迹进行固定,以防止字迹在水性脱酸过程中褪色或扩散。首先,根据聚二甲基氯化铵(PDDA)、壳聚糖季铵盐(HACC)、阳离子瓜尔胶(CGG)和苄基三乙基氯化铵(TEBAC)醇溶液对滤纸染料的固定效果,筛选出四种固定剂的最佳组成比。实验结果表明,PDDA对红墨水笔迹具有良好的固定效果,HACC对蓝墨水笔迹具有优异的固定效果。此外,HACC还对真实档案中的笔迹保护产生了积极影响。老化纸的力学性能得到改善,纸纤维经过固定和脱酸处理后没有明显变化。
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引用次数: 0
OPTIMIZATION OF THE MANUFACTURING OF METASEQUOIA-BASED THREE-LAYER STRUCTURE PARQUET FLOORING BY A RESPONSE SURFACE METHODOLOGY 基于响应面法的水杉型三层结构拼花地板制造优化
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-04-26 DOI: 10.37763/wr.1336-4561/68.2.376388
Huimin Zhang, Yu Yang, Yu Liu, Yahua Jiang, Renyuan Liu
On the basis of a single-factor experiment, a mathematical model was established by the response surface analysis method based on the Box-Behnken experimental design principle. The effects of three factors, including hot-pressing temperature, hot-pressing time, and hot-pressing pressure, and their interactions on the modulus of rupture (MOR) of Metasequoia-based three-layered structure parquet flooring were studied. The results show that the quadratic polynomial model in the regression equation is significant, and the correlation between the value predicted by the model and the experimental value is 91.17%. The optimized best hot-pressing process parameters are determined to be as follows: hot-pressing temperature of 96.03°C, hot-pressing time of 6.70 min, and hot-pressing pressure of 8 kg·cm-2. Under these conditions, the best MOR are obtained, reaching a value of 102.05 MPa. The theoretically predicted value is in good agreement with the experimental results.
在单因素实验的基础上,根据Box-Behnken实验设计原理,采用响应面分析方法建立了数学模型。研究了热压温度、热压时间和热压压力三个因素及其相互作用对水杉基三层结构镶木地板断裂模量的影响。结果表明,回归方程中的二次多项式模型具有显著性,模型预测值与实验值的相关性为91.17%。确定了最佳热压工艺参数为:热压温度96.03°C,热压时间6.70min,热压压力8kg·cm-2。在这些条件下,获得了最佳MOR,达到102.05MPa。理论预测值与实验结果吻合较好。
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引用次数: 0
WATER RETENTION OF BEECH SHAVINGS HEAT-TREATED AT LOWER TEMPERATURES 低温热处理山毛榉刨花的保水性
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-04-26 DOI: 10.37763/wr.1336-4561/68.2.257267
V. Ihnát, Henrich Lübke
Water retention after 2 hours and 24 hours of soaking in water was determined for beech shavings subjected to heat treatment at temperatures of 120°C, 140°C and 160°C for 2 hours, 4 hours, 6 hours and 8 hours in order to reduce the equilibrium moisture content (EMC) of the wood shavings for use in wood based composites. EMC was determined after 14 days of air conditioning at 23°C and 55% relative humidity. The measured values were compared with the sample dried at 103°C. Water retention was determined after 15 min of centrifugation at 1400 rev.min-1 for a more objective assessment of the wood's ability to retain water in the cell lumens. The results showed that heat treatment reduces the EMC of beech shavings heat-treated at 160°C for 8 hours in the given conditions from 8.7% to 6.19%. The reduction of EMC at lower temperature was not sufficient enough, especially in the shorter treatment duration of up to 6 hours. In parallel, the reduction of water retention from 65.53% to 47.79% was caused by heat treatment for 8 hours at 160°C.
测定了在120°C、140°C和160°C的温度下进行2小时、4小时、6小时和8小时热处理的山毛榉刨花在水中浸泡2小时和24小时后的保水性,以降低用于木质复合材料的刨花的平衡含水量(EMC)。EMC是在23°C和55%相对湿度的空气调节14天后测定的。将测量值与在103°C下干燥的样品进行比较。在1400转min-1离心15分钟后测定保水性,以更客观地评估木材在细胞内腔中保水的能力。结果表明,在给定的条件下,在160°C下热处理8小时的山毛榉刨花的EMC从8.7%降低到6.19%。在较低的温度下,EMC的降低还不够充分,尤其是在长达6小时的较短处理时间内。同时,保水率从65.53%降低到47.79%是由于在160°C下热处理8小时造成的。
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引用次数: 0
DISCOLORATION OF OAK VENEER INDUCED BY METAL IONS 金属离子对橡木单板变色的影响
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-04-26 DOI: 10.37763/wr.1336-4561/68.2.224240
Huachun Qi, Xiangrui Li, Mingli Liu, Chunfeng Li
The 3 mm thick oak veneers were discolored by single ions of Fe2+, Cu2+, and Mn2+ and mixed ions of Fe2+-Cu2+, Fe2+-Mn2+, and Cu2+-Mn2+. The brightness (L*), red-green index (a*), and yellow-blue index (b*) of the veneers changed by varying degrees with the changes in ion mass fraction, temperature, heating time, ion species, and ion mass fraction ratio. The maximum values of total color difference (△E*) of the veneers were 38.94, 11.79, and 9.42 for Fe2+, Cu2+, and Mn2+. Moreover, the total color difference (△E*) values of 24.07, 13.71, and 4.45 were observed for Fe2+-Cu2+, Fe2+-Mn2+, and Cu2+-Mn2+ mixed ions. The veneers showed different degrees of vibrational peaks after discoloration. According to the ultraviolet spectrum, Fe2+ had a red shift in the ultraviolet absorption band of the unsaturated carbonyl compound and benzene ring compound. Moreover, the dark effect of Fe2+, Fe2+-Cu2+, Fe2+-Mn2+, Mn2+, Cu2+-Mn2+, and Cu2+ gradually decreased. The surface of the veneer was flat, without any rupture or deformation, and the pores were clear after treatment.
3mm厚的橡木单板被Fe2+、Cu2+和Mn2+的单一离子以及Fe2+-Cu2+、Fe2+-Mn2+和Cu2+-Mn2+的混合离子变色。单板的亮度(L*)、红绿指数(a*)和黄蓝指数(b*)随着离子质量分数、温度、加热时间、离子种类和离子质量分数比的变化而发生不同程度的变化。总色差的最大值(△对于Fe2+、Cu2+和Mn2+,贴面的E*)分别为38.94、11.79和9.42。此外,总色差(△E*)值分别为24.07、13.71和4.45。单板变色后出现不同程度的振动峰。根据紫外光谱,Fe2+在不饱和羰基化合物和苯环化合物的紫外吸收带上有红移。此外,Fe2+、Fe2+-Cu2+、Fe2+-Mn2+、Mn2+、Cu2+-Mn2+Cu2+的暗效应逐渐减弱。单板表面平整,没有任何断裂或变形,处理后孔隙清晰。
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引用次数: 0
SHORT NOTES: FIRST REPORT OF THE LIGNIVOROUS FUNGUS PAECILOMYCES MAXIMUS IN CEDRUS ATLANTICA M. IN MOROCCO 简记:摩洛哥大西洋玉髓中嗜木质真菌最大拟青霉的首次报道
IF 1.3 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2023-04-26 DOI: 10.37763/wr.1336-4561/68.2.403412
Oussama Chauiyakh, E. El Fahime, Oumaima Ninich, Samar Aarabi, Mustapha Bouziani, A. Chaouch, Aziz ET TAHIR
This study is interested in isolating fungi from the wood parts of cedar trunks withered and identifying these lignivorous fungi. A sample was isolated from the cedar grove of Tazekka National Park located south of the city of Taza in Morocco. The culture and purification of the isolated fungus were done on a water agar medium and then on a PDA medium. After the purification of the fungus, a morphological study by scanning electron microscope allowed us to identify the pathogen Paecilomyces. A molecular characterization identified Paecilomycesmaximus with a coverage percentage of 99% and an identity of 98.77%. To our knowledge, this is the first report of P. maximus in decayed cedar wood.
本研究对从雪松树干枯枝中分离真菌并鉴定这些木质素食用菌感兴趣。样本是从位于摩洛哥塔扎市南部的塔泽卡国家公园的雪松林中分离出来的。分离真菌的培养和纯化分别在水琼脂培养基和PDA培养基上进行。纯化后的真菌,通过扫描电镜形态学研究,使我们能够识别病原体拟青霉。分子鉴定鉴定出最大拟青霉(Paecilomycesmaximus),盖度为99%,鉴定度为98.77%。据我们所知,这是第一次报道在腐烂的雪松木中发现大孢子虫。
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引用次数: 1
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Wood Research
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