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A Study of Stress Intensity Factors in Lozenge Pattern of Joints 关节菱形形应力强度因子的研究
K. Hithendra, R. Prakash
Riveted joints are very crucial in many industrial applications. Several studies have been carried out to understand the response of lap joints and butt joints with single and double row of rivets emphasizing on total fatigue life and residual stress evaluation. Studies that deal with initial crack and stress intensity factors (SIF) during its progress are very less. In addition, there is very less data on joints formed with Lozenge pattern. The present work aims to bridge this gap with studies on the Lozenge pattern of rivets with focus on the SIF in strap plates, given the fact that the initial cracks appear on them when the strap thickness is less than or equal to the plate thickness. The strap plate considered has six joints in Lozenge pattern in 3-2-1 fashion. Cracks were induced at different joint locations and variation of the stress intensity factor with progress in crack size was evaluated using Finite Element Analysis. Studies were conducted for various interference levels of practical interest. The most critical location of the crack and the most beneficial levels of interference were identified. Limits of interference, beyond which SIF increases drastically, were identified. Combined influence of interference and neighboring geometrical aspects such as holes and boundaries was recorded. Studies were also conducted to evaluate if there is a need for uniform interference at all joint locations. Also, to simulate the real world scenario, several combinations of random interference were induced at the joints and the SIF results were compared with that of uniform interference values. Finally, the effect of change in back pitch of the joints was also studied.
铆接在许多工业应用中是非常重要的。为了了解单排和双排铆钉搭接和对接的响应,已经开展了一些研究,重点是总疲劳寿命和残余应力评估。对于初始裂纹及其过程中的应力强度因子的研究很少。此外,关于菱形图案形成的节理的资料很少。目前的工作旨在通过对铆钉菱形图案的研究来弥合这一差距,重点关注带板中的SIF,因为当带厚度小于或等于板厚度时,它们会出现初始裂纹。所考虑的带板有六个关节,呈菱形,3-2-1。在不同节点位置诱发裂纹,利用有限元分析方法对应力强度因子随裂纹尺寸的变化规律进行了评价。针对实际兴趣的各种干扰水平进行了研究。确定了裂纹的最关键位置和最有利的干扰水平。确定了干扰的限制,超过该限制SIF会急剧增加。记录了干涉和邻近几何方面如孔和边界的综合影响。还进行了研究,以评估是否需要在所有关节位置进行均匀干扰。此外,为了模拟真实场景,在节点处诱导了几种随机干扰组合,并将SIF结果与均匀干扰值的结果进行了比较。最后,还研究了关节后节距变化的影响。
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引用次数: 0
Fabrication of Bioinspired Micro/Nano Textured Rough Surfaces Through the Scalable Roll Coating Process 利用可伸缩滚涂工艺制备仿生微/纳米纹理粗糙表面
S. Chockalingam, J. Ryu, Md. Didarul Islam, Myers Harbinson
Bioinspired Micro/Nano textured rough topography of a surface has many applications in super-hydrophobicity, self-cleaning surface, anti-icing coatings, anti-biofouling, and drag reduction surfaces. The role of hierarchical and complex surface topography in nature is to amplify the hydrophobicity and maximize the fouling resistance. Thus, a similar micro- and nano-scale 3-D topographic surfaces inspired from the nature were fabricated using a simple and scalable two roll coating process. This process was based on the ribbing instabilities associated with the shearing of non-Newtonian fluids between two rollers. The polymer composite retains the deformed shape due to the recovery of high-viscosity after removing the shear stress. The relationship between the process conditions and the textured structure were studied with the shear rate, capillary number and the surface roughness parameters (e.g., Wenzel factor and density of peaks). The results showed that the samples’ Wenzel roughness factor increased with the increase in shear rate up to a particular value and then decreased. Similarly, the density of peaks in the sample increased with an increase in capillary number up to a particular value and then decreased. These bioinspired surfaces with hierarchical textured patterns produced using two roll coating process show a tremendous potentiality to be used in super-hydrophobic, anti-biofouling, and drag reduction applications.
仿生微/纳米表面纹理粗糙形貌在超疏水性、自清洁表面、防冰涂层、防生物污垢和减阻表面等方面有许多应用。自然界中层次复杂的表面形貌的作用是放大疏水性,最大限度地提高抗污能力。因此,一个类似的微纳米级的三维地形表面的灵感来自大自然,使用一个简单的和可扩展的两辊涂层工艺。这一过程是基于与两个滚筒之间的非牛顿流体剪切有关的罗纹不稳定性。聚合物复合材料在去除剪切应力后,由于高粘度的恢复而保持了变形的形状。通过剪切速率、毛细数和表面粗糙度参数(如Wenzel因子和峰密度)研究了工艺条件与织构结构的关系。结果表明:试样的Wenzel粗糙度系数随剪切速率的增加而增大,达到一定值后减小;同样,样品中的峰密度随着毛细管数的增加而增加,直到特定值,然后减小。这些具有分层纹理图案的仿生表面采用双辊涂层工艺生产,在超疏水、抗生物污垢和减阻应用中显示出巨大的潜力。
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引用次数: 0
On the Fatigue Properties of 3D Steel Structures Welded Onto Ceramics 陶瓷焊接三维钢结构的疲劳性能研究
S. Allameh, D. Alexander, Roger A. Miller, Avery Lenihan, H. Allameh
Fabrication of prototypes and custom-made parts, made of various metals, has become possible by additive manufacturing. Like any new technology, reliability of the products is of utmost importance, especially, when it comes to life-sustaining structures or for applications where human life is at stake. A less common method of making 3D metallic object is by 3D welding. This method is more appropriate for structures where dimensional and esthetic characteristics of the structures are of secondary importance. An example is steel rebar in concrete where it requires rough corrugated surfaces of the rebars. This walled metallic structures, used especially for loadbearing applications, where load is not fixed will require investigation of fatigue properties. Conventional testing methods may not be appropriate for small cross sections. To address this problem, microtensile testing allows characterization of mechanical properties of small structures as thin as a few millimeters. Past work on the monotonic and cyclic properties of microsamples extracted from weldments made on metallic substrates has shown superior tensile strength and enhanced fatigue resistance compared to the base metal. It is interesting to see how the results would be different if ceramic substrates were used. This study utilizes a gantry type 3D printer, equipped with the gun of a MIG welding machine to fabricate steel weldments on ceramics using 3D welding technique. The process involves starting of the arc from a grounded piece of metal, then continue the motion of the gun and guide the motion of the molten metal pool in desired direction, maintaining the continuity through the solidifying bead. Weldment samples fabricated by this technique are then machined by a CNC mill to extract microscale dog-bone-shaped samples with a width of 200 micron and a gage length of 1000 micron. The top and bottom surfaces of the samples are polished to a mirror finish and subsequently the microsamples are mounted in the grippers of an Electropulse 1000 Instron load frame. Monotonic and cyclic loading mechanical tests in tensile mode are conducted and data are collected and plotted in terms of stress-strain as well as stress-life curves. These results are then compared with those of samples made by 3D welding of steel-on-steel substrate. Since the cooling rate of molten metal on steel substrates differs from that of ceramic substrate, fatigue properties may be different too. The implications of the reliability of reinforcement steel bars printed by 3D welding will be discussed.
通过增材制造,各种金属制成的原型和定制部件已经成为可能。与任何新技术一样,产品的可靠性至关重要,特别是当涉及到维持生命的结构或人命攸关的应用时。制造3D金属物体的一种不太常见的方法是通过3D焊接。这种方法更适合于结构的尺寸和美学特征是次要的。一个例子是混凝土中的钢筋,它需要钢筋粗糙的波纹表面。这种带壁的金属结构,特别用于承载应用,在负载不固定的情况下,需要研究疲劳性能。传统的测试方法可能不适用于小截面。为了解决这个问题,微拉伸测试可以表征薄至几毫米的小结构的机械性能。过去对从金属基板上制作的焊缝中提取的微样品的单调和循环性能的研究表明,与母材相比,这种材料具有优越的抗拉强度和增强的抗疲劳性能。有趣的是,如果使用陶瓷衬底,结果会有什么不同。本研究利用龙门式3D打印机,配以MIG焊机的焊枪,利用3D焊接技术在陶瓷上制作钢焊缝。该过程包括从接地的金属片开始电弧,然后继续枪的运动并引导熔融金属池沿所需方向运动,通过固化头保持连续性。然后通过CNC铣床加工该技术制造的焊件样品,以提取宽度为200微米,量规长度为1000微米的微尺度狗骨形样品。样品的顶部和底部表面抛光至镜面光洁度,随后将微样品安装在Electropulse 1000 Instron负载框架的夹具中。在拉伸模式下进行单调加载和循环加载力学试验,收集数据并绘制应力-应变曲线和应力-寿命曲线。然后将这些结果与钢对钢基板三维焊接样品的结果进行了比较。由于金属液在钢基体和陶瓷基体上的冷却速度不同,疲劳性能也可能不同。本文将讨论三维焊接打印钢筋的可靠性问题。
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引用次数: 0
Compressive Stress Relaxation (CSR) Testing of Elastomers 弹性体的压缩应力松弛(CSR)试验
Dilip Menon, R. Michael, David Gee
This paper presents Compressive Stress Relaxation (CSR) results for various elastomer samples to ascertain their performance in sealing applications. The paper presents results of percent retained sealing force (%RSF) behavior and its relationship with compression set and hardness. Materials studied are used in critical piping and medical seal applications. CSR methodology is used to benchmark various materials in terms of sealing performance. Potential problems with the current standard of testing have also been identified that can affect the resolution and variability of the test. The paper details all the steps involved to perform accurate CSR testing and discusses advantages and disadvantages CSR testing might have over conventional tests used to verify seal performance such as compression set. This is only an introductory study and requires further tests with the same elastomers subjected to other process conditions, such as heat aging are also studied to understand how they affect %RSF. This can also be expanded to other materials to build a database of standard %RSF behavior under identical conditions.
本文介绍了各种弹性体样品的压缩应力松弛(CSR)结果,以确定它们在密封应用中的性能。本文介绍了保留密封力百分比(%RSF)性能及其与压缩集和硬度的关系。所研究的材料用于关键管道和医疗密封应用。CSR方法用于对各种材料的密封性能进行基准测试。目前测试标准的潜在问题也已被确定,这些问题可能影响测试的分辨率和可变性。本文详细介绍了执行准确的CSR测试所涉及的所有步骤,并讨论了CSR测试与用于验证密封性能(如压缩集)的传统测试相比可能具有的优点和缺点。这只是一个介绍性的研究,需要在其他工艺条件下对相同的弹性体进行进一步的测试,例如热老化,以了解它们如何影响%RSF。这也可以扩展到其他材料,以建立在相同条件下标准%RSF行为的数据库。
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引用次数: 0
Thermal Expansion Simulation of Bi-Directional Taper Formation in Composite Hydrodynamic Thrust Bearings 复合流体动力推力轴承双向锥度形成的热膨胀模拟
Isaiah Yasko, A. Lutfullaeva, C. Fais, Muhammad Ali, K. Alam
Tapered-land hydrodynamic thrust bearings require taper depths of approximately 20–100 μm to operate efficiently within the hydrodynamic regime. Machining the tapers in traditionally manufactured bearings increase production time and costs. The thermo-mechanical analysis presented in this work shows that the utilization of composite laminas in place of taper machining may be used to provide taper formation in hydrodynamic bearings by exploiting the thermal expansion produced from frictional heating. Thermal expansion of three different carbon/epoxy composite layups (AS-4/3501-6, IM7/3501-6, T-300/3501-6) was analyzed using ABAQUS/CAE composite module. The analysis shows that the composites provide bidirectional taper depths of 24.25 μm, 23.7 μm, and 22.27 μm while being subjected to in-service film pressures and temperatures.
锥形土地流体动力推力轴承要求锥度深度约为20-100 μm,才能在流体动力范围内有效运行。在传统制造的轴承中加工锥度增加了生产时间和成本。本文的热力学分析表明,利用复合材料薄片代替锥度加工,可以利用摩擦加热产生的热膨胀,在流体动力轴承中形成锥度。利用ABAQUS/CAE复合材料模块分析了三种不同碳/环氧复合材料层(as /3501-6、IM7/3501-6、T-300/3501-6)的热膨胀性能。分析表明,复合材料在服役膜压力和温度作用下的双向锥度深度分别为24.25 μm、23.7 μm和22.27 μm。
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引用次数: 0
Influence of Welding Sequence on Residual Stress Evolution in SUS304/Q235 Bimetallic Clad Plate Butt-Welded Joints 焊接顺序对SUS304/Q235双金属复合板对接接头残余应力演化的影响
Min Zhu, Yansong Zhang, Qiao Zheng, Wei Wu, Weifang Qian, Baosen Wang
Residual stress prediction and controlling is important for structural integrity assessment of weldments. In current work, finite element and experimental methods were integrated to study the influence of welding sequence on the SUS304/Q235 bimetallic clad plate joints during multi-layer and multi-pass welding. The results show that the peak residual stress values on flyer plate surface are weakly affected by welding sequences but the width of high surficial longitudinal stress area of joint with base layer welded first is bigger. Meanwhile, welding sequence has a great influence on the longitudinal residual stress evolution law inside joints. When base seam layer is welded first, the highest stress concentration appears in the transition layer. However, it would be transferred into the first base seam layer due to martensite phase transformation when flyer seam layer is welded first. Residual stress controlling in the bimetallic clad plate joint should attract more attention from researchers.
残余应力预测与控制是焊接件结构完整性评价的重要内容。本文采用有限元和实验相结合的方法,研究了SUS304/Q235双金属复合板多层多道次焊接过程中焊接顺序对焊接接头的影响。结果表明:焊接顺序对飞片表面峰值残余应力值的影响较小,但基层先焊的接头表面高纵向应力区宽度较大;同时,焊接顺序对接头内部纵向残余应力演化规律有较大影响。当基缝层先焊接时,过渡层应力集中最大。而先焊飞翼层时,由于马氏体相变,会转移到第一基缝层。双金属复合板节点的残余应力控制是目前研究的热点。
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引用次数: 1
Imaging-Based Fatigue Mechanism Investigation of Additively Manufactured Ti-6Al-4V 增材制造Ti-6Al-4V的成像疲劳机理研究
Jie Chen, Changyu Meng, Yongming Liu
The fatigue characterization of additively manufactured Ti-6Al-4V plays a vital role in ensuring the structural safety. This study focuses on image based surface characterization and the fatigue mechanical property investigation of as-built additively manufactured Ti-6Al-4V. Three sets of processing parameters (the absorbed laser power, scan velocity, building orientation) are adopted corresponding to the EOS nominal settings, lack-of-fusion and keyhole regimes. Before the fatigue testing, the specimens are scanned using X-ray micro-computed tomography (microCT) and the complete surface morphology is obtained. During fatigue testing, the specimen is scanned using microCT after certain numbers of loading cycles to capture the fatigue crack initiation locations and trace the crack growth trajectories. After the fatigue testing is completed, the fractured specimen is scanned by both microCT and scanning electron microscope (SEM). Based on the experimental investigation, vertically built specimens have lower average surface roughness than angled specimens along the transverse direction. Along longitudinal direction, the average surface roughness does not very significantly among all specimens. The fatigue crack may initiate from near surface pores or external rough surface. Cracks initiating from different locations at the similar height coalesce while propagating. Fracture surfaces present tortuous or tearing features, which corresponds to shorter and longer fatigue lives under the same fatigue loading, respectively.
增材制造Ti-6Al-4V材料的疲劳特性对保证结构安全起着至关重要的作用。本文主要研究了基于图像的增材制造Ti-6Al-4V的表面表征和疲劳力学性能研究。采用三组加工参数(激光吸收功率、扫描速度、建筑方向)分别对应EOS标称设置、不融合状态和锁孔状态。在疲劳试验前,对试样进行x射线微计算机断层扫描(microCT),获得完整的表面形貌。在疲劳试验中,试样经过一定次数的加载循环后,用微ct扫描试样,以捕捉疲劳裂纹的起裂位置并追踪裂纹的扩展轨迹。疲劳试验完成后,对断裂试样进行微ct和扫描电镜扫描。实验研究表明,垂直构建的试件在横向上的平均表面粗糙度要低于倾斜构建的试件。在纵向上,各试样的平均表面粗糙度差异不显著。疲劳裂纹可由近表面孔隙或外部粗糙表面引发。在相同高度的不同位置产生的裂缝在传播过程中汇合。断裂面呈现弯曲或撕裂特征,在相同的疲劳载荷下,分别对应较短和较长的疲劳寿命。
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引用次数: 0
A Study on the Onset of Secondary Hydriding in Defective Zr-2 Fuel for Boiling Water Reactors 沸水堆缺陷Zr-2燃料二次氢化发生的研究
Doctor Enivweru, Qingyu Wang, A. Ayodeji, Ayouba Moussa Hassane
One of the most common threats to the integrity of reactor fuel cladding is the geometric imperfections such as the missing pellet surface (MPS) that produces a remarkable surge in the local fuel-clad gap. The cooling water could occupy this gap leading to secondary hydriding (SH) and hydrogen embrittlement. Most studies on this subject have identified extensive radiolysis in boiling water reactors (BWRs) to be responsible for hydrogen evolution during accident conditions. However, the quantitative determination of hydrogen and how it affects zircaloy-2 during normal reactor operation has not been given adequate attention. To bridge this gap and to better predict the onset of cladding failure, this study investigates secondary hydriding and its characteristic phenomenon in a fuel cladded with zircaloy-2. Multiphysics model is used to model diffusion of heat and hydrogen, then the effect of an intermediary porous/non-protective oxide layer and the impact of dose rate from different types of radiation are studied. The contributions of the source term due to radiolysis of neutrons (n), gamma (γ), alpha (α) and beta (β) radiations are also considered. Results showed that neutrons, having a maximum dose rate of 39.9 kGy/s accounts for over 99% of ZrH precipitation in a UO2 fuel with MPS. The effect of oxide (ZrO2) thickness in SH, and the derivative of oxide thickness are also discussed.
对反应堆燃料包壳完整性最常见的威胁之一是几何缺陷,如缺失的球团表面(MPS),它会在局部燃料包壳间隙中产生显著的激增。冷却水可以占据这一空隙,导致二次氢化(SH)和氢脆。关于这一主题的大多数研究已经确定沸水反应堆(BWRs)中广泛的放射性衰变是事故条件下析氢的原因。然而,氢的定量测定及其在正常反应堆操作过程中对锆-2的影响并没有得到足够的重视。为了弥补这一空白并更好地预测包层失效的开始,本研究研究了锆合金-2包层燃料中的二次氢化及其特征现象。采用多物理场模型对热氢扩散过程进行了模拟,研究了中间多孔/非保护性氧化层的影响以及不同类型辐射剂量率的影响。源项由于中子(n)、γ (γ)、α (α)和β (β)辐射的辐射分解所作的贡献也被考虑在内。结果表明,在具有MPS的UO2燃料中,最大剂量率为39.9 kGy/s的中子占ZrH沉淀的99%以上。讨论了氧化锆(ZrO2)厚度的影响,以及氧化锆厚度的导数。
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引用次数: 0
Study of Flexural Strength and Fracture of Additive Manufactured Parts With Stiffeners 加筋增材制造零件抗弯强度及断裂研究
S. Regalla, P. Shyam, Sampath Mylavarapu, Sai Harshini Irigineni, P. Shrivastava
The authors have developed trans-tibial prosthetic sockets using additive manufacturing. These sockets made with mono-material thermoplastics such as Acrylonitrile Butadiene Styrene (ABS) and Polylactic Acid (PLA) at lower thicknesses were found to fracture within a few days of use by the amputees. The fracture was repeatedly found to occur at specific locations such as the lobe corners and the socket’s lower one-third zone. The most probable causes of crack initiation are lack of fusion (LOF) sites and voids. The causes of crack propagation are the lower interlayer bond strength compared to intra-layer bond strength. However, no scientific work exists that clearly explains these phenomena and methods to prevent such potential crack initiation sites and arrest the propagation of such fracture in additively manufactured polymeric structures. Therefore, in the present work, the investigation was carried out into possible enhancement in the resistance to fracture by different strength-enhancing post-processing techniques. In the first technique, the placement of stiffener features at selected locations on the socket was investigated. Three-point bending tests were carried out on D790 standard ABS specimens with different stiffeners introduced on the bottom face. The study focused on fracture characteristics in the stiffener-based topologically optimized geometric design of plate structures made by Fused Deposition Modeling (FDM) under flexural loading. The D790 three-point bending specimens were provided with differently shaped stiffeners, namely, triangular, prismatic, cuboidal, and pyramidal, extending all along the specimen’s length and spread with differential gaps in the width direction. In the second method, thermosetting epoxy resin coatings were applied on the three-point bending specimens of ABS, and the effect of the coating on the flexural strength was investigated. Bending tests were done on three specimens, the first specimen without any coating, the second specimen with only the epoxy resin coating, and the third specimen with two different coating layers. The first of the two coating layers on the third specimen was with primer and the second layer was with epoxy resin. Scanning electron microscope (SEM) and energy dispersion spectroscopy (EDS) scanning analyses were conducted on the fractured specimens. The scanning images indicated that both the primer and resin materials showed a tendency to diffuse into the substrate of ABS, thereby weakening the extreme fibers of material on the specimen’s tension side, resulting in premature crack initiation and propagation. Significant gain in the flexural strength was observed in both the strength enhancement techniques compared to plain specimens.
作者利用增材制造技术开发了经胫骨假体骨臼。这些由单材料热塑性塑料制成的插座,如丙烯腈丁二烯苯乙烯(ABS)和聚乳酸(PLA),厚度较低,在截肢者使用几天内就会断裂。骨折反复发生在特定位置,如瓣角和窝的下三分之一区。裂纹萌生最可能的原因是缺乏熔合(LOF)点和空隙。裂纹扩展的原因是层间结合强度低于层内结合强度。然而,目前还没有科学研究能够清楚地解释这些现象,以及如何在增材制造的聚合物结构中防止这些潜在的裂纹起裂位点并阻止此类裂纹的扩展。因此,在本工作中,研究了通过不同的强度增强后处理技术来增强抗断裂能力的可能性。在第一种技术中,研究了在插座上选定位置的加劲特征的放置。对D790标准ABS试件进行了三点弯曲试验,并在试件底面引入了不同的加强筋。研究了基于加强筋的熔融沉积建模(FDM)板结构弯曲载荷拓扑优化几何设计中的断裂特征。在D790三点弯曲试件上设置不同形状的加强筋,分别为三角形、棱柱形、立方形和锥体形,加强筋沿试件长度全部延伸,并在宽度方向上有不同的间隙分布。第二种方法是在ABS三点弯曲试件上涂覆热固性环氧树脂涂层,研究涂层对ABS三点弯曲强度的影响。在三个试件上进行了弯曲试验,第一个试件没有任何涂层,第二个试件只有环氧树脂涂层,第三个试件有两种不同的涂层。第三个样品的两层涂层中的第一层是底漆,第二层是环氧树脂。对断裂试样进行了扫描电镜(SEM)和能谱(EDS)扫描分析。扫描图像表明,底漆和树脂材料都有向ABS基体扩散的趋势,从而削弱了试样拉伸侧材料的极端纤维,导致裂纹过早萌生和扩展。与普通试样相比,在两种强度增强技术中都观察到弯曲强度的显著增加。
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引用次数: 0
Protic Ionic Liquids as Lubricant Additives 作为润滑剂添加剂的质子离子液体
Om Saran, Brandon Stoyanovich, Hong Guo, P. Iglesias
Protic ionic liquids (PILs) are an emerging class of environmentally friendly lubricants and lubricant additives PILs can be easily synthesized through proton transfer from a Brønsted acid to a Brønsted base and exhibit significant potential as lubricant additives on account of their high thermal stability, non-flammability, low melting points, lack of vapor pressure, low cost, and biodegradability. This research covers the tribological performance of three halogen-free protic ionic liquids, 2-hydroxyethylammonium 2-ethylhexanoate (Eet), 2-hydroxyethylammonium p-toluenesulfonate (Ets), and 2-hydroxyethylammonium 4-dodecylbenzenesulfonate (Eds) which are designed and synthesized using the same base (ethanolamine) but different acids of varying acidity and alkyl chain length. The relationship among their ionicity, molecular structures, and tribological properties are investigated when these protic ionic liquids are used as lubricant additives to water. Each PIL was evaluated as a lubricant additive in a 1 wt.% aqueous solution. The solutions were tested using a ball-on-flat reciprocating tribometer under room temperature for steel-ceramic contact using distilled water was used as a base line lubricant. PIL solutions yielded significant reductions in frictional coefficients and wear volumes. The wear mechanisms and surface interactions were also discussed in terms of PIL-steel surface interactions from SEM and EDX data.
质子离子液体(pil)是一类新兴的环保润滑剂和润滑剂添加剂,它可以通过质子从Brønsted酸转移到Brønsted碱而轻松合成,并且由于其高热稳定性、不易燃、低熔点、无蒸汽压、低成本和可生物降解性而具有巨大的作为润滑剂添加剂的潜力。研究了以相同碱(乙醇胺)、不同酸(不同酸度和不同烷基链长)设计合成的2-羟乙基2-乙基己酸铵(Eet)、2-羟乙基对甲苯磺酸铵(Ets)和2-羟乙基4-十二烷基苯磺酸铵(Eds)三种无卤素质子离子液体的摩擦学性能。研究了这些质子离子液体作为水润滑剂添加剂时,它们的离子性、分子结构和摩擦学性能之间的关系。每个PIL作为润滑剂添加剂在1 wt.%的水溶液中进行评估。在室温下,用球-平往复摩擦计对钢-陶瓷接触溶液进行测试,使用蒸馏水作为基线润滑剂。PIL解决方案显著降低了摩擦系数和磨损量。从SEM和EDX数据的角度分析了PIL-steel表面相互作用的磨损机理和表面相互作用。
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引用次数: 1
期刊
Volume 3: Advanced Materials: Design, Processing, Characterization, and Applications
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