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Influence of Coating on High Performance Heat Resistant Textile Curtains 涂料对高性能耐热纺织品窗帘性能的影响
M. Vilarinho, P. Araújo, J. Teixeira, Elisabete Silva, Dionísio Silveira, D. Soares, M. Paiva, Daniel Ribeiro, Marisa Branco
The protection of human life and goods assumes a growing concern in all forms of activities. The fire and smoke curtains act as a physical barrier to prevent the fire from spreading between spaces as well as to staunch the smoke and heat transfer to adjacent areas, while causing minimal interference. Usually, curtains are based on fiber structures that can be coated to enhance their protective capabilities. Also, the fiber structure can be developed into a complex pattern of 2D and 3D threads, with single or multiple materials that can be tailored to optimize its behavior. The thermal and fire protection depends on the fibers, fabric pattern and coatings. The present paper reports the development of novel coated structures of fibers used for fire protection curtains. Basalt and glass fibers are used as yarn materials. Following the certification standards the samples were assessed for their thermal resistance by measuring the temperature differential they provide while their integrity is evaluated. The sample is placed under stress in an attempt to mimic its own weight effect when in service. The temperature is monitored using thermocouples which are placed at both sides of the fabric and the integrity parameter is assessed through the occurrence of fabric rupture and smoke and/or odor release motivated by its deterioration. Regarding the uncoated samples, the one composed of glass-fiber in both directions presents the best thermal performance. The addition of an alumina coating significantly improves the performance of all samples. However, while a thinner (0.05 μm) alumina layer provides better results for the sample with glass-fiber in both warp and weft directions, the behavior of samples composed of glass-fiber and basalt is superior when a thicker (0.3 μm) alumina layer is used. In both cases, an alumina coating application results in an increase of the gradient temperature (between curtain inside/outside temperatures) of about 38.0% (310.0 °C vs. 427.0 °C for the first and 386.0 °C vs. 526.0 °C for the latter.
在所有形式的活动中,对人的生命和财产的保护日益受到关注。防火和防烟帘作为物理屏障,防止火灾在空间之间蔓延,并阻止烟雾和热量传递到邻近区域,同时造成最小的干扰。通常,窗帘是基于纤维结构,可以涂覆以增强其防护能力。此外,纤维结构可以发展成2D和3D螺纹的复杂图案,可以使用单一或多种材料进行定制以优化其性能。隔热和防火性能取决于纤维、织物图案和涂层。本文报道了用于防火窗帘的新型纤维涂层结构的发展。玄武岩纤维和玻璃纤维是纱线的原料。根据认证标准,通过测量样品提供的温差来评估样品的耐热性,同时评估样品的完整性。样品被置于压力下,试图模拟其在使用时的重量效应。使用放置在织物两侧的热电偶来监测温度,并通过织物破裂的发生以及由其劣化引起的烟雾和/或气味释放来评估完整性参数。对于未包覆的样品,双向玻璃纤维组成的样品表现出最好的热性能。氧化铝涂层的加入显著提高了所有样品的性能。然而,当氧化铝层较薄(0.05 μm)时,经向和纬向玻璃纤维样品的性能都较好,而当氧化铝层较厚(0.3 μm)时,玻璃纤维和玄武岩样品的性能都较好。在这两种情况下,氧化铝涂层的应用导致梯度温度(窗帘内外温度之间)增加约38.0%(310.0°C vs. 427.0°C, 386.0°C vs. 526.0°C)。
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引用次数: 0
3D-Printed Hierarchical Re-Entrant Honeycomb With Improved Structural Stability Under Quasi-Static Compressive Loading 准静态压缩载荷下结构稳定性提高的3d打印分层可重入蜂窝
Chi Zhan, Mingzhe Li, R. Mccoy, Linda Zhao, Weiyi Lu
Re-entrant honeycombs with negative Poisson’s ratio have shown great potential as lightweight energy absorbers for various applications. However, due to its bending-dominated behavior, the structural stability and energy absorption capacity of reentrant honeycombs are yet to be further improved. It has been demonstrated that hierarchical structures exhibit a combination of lightweight and superior mechanical properties. We hypothesize that by introducing the triangular hierarchical substructures into the conventional cell walls, the bending-dominated behavior of re-entrant honeycombs can be converted into the stretching-dominated one. Consequently, the overall structural stability of the hierarchical re-entrant honeycombs can be promoted through local deformation of hierarchy, which can potentially benefit the energy absorption capacity of the resulted structure. To test our hypothesis, we first fabricate the hierarchical reentrant honeycombs with length scale ranging from micrometer to centimeter using Polyjet 3D-printing technique. Regular reentrant honeycombs with solid struts have been fabricated as baseline structures. The mechanical performance of the honeycombs has been characterized through uniaxial quasi-static compression tests. Besides, the local deformation mechanisms of the hierarchical structure have been revealed by the Digital Image Correlation (DIC). In comparison to the regular re-entrant honeycomb, the global failure strain of hierarchical re-entrant honeycomb is enhanced by 36%. This is due to the improved structural stability from local fracture and densification of the triangular hierarchy. Both the regular and hierarchical honeycombs exhibit the same specific energy absorption capacity. As predicted by the existing scaling laws, the hierarchical re-entrant honeycomb has great potential to outperform regular one by optimizing the relative density of the structure. A finite element model of the hierarchical re-entrant honeycomb has been developed by using commercial software Abaqus/CAE 2020. The model has been calibrated by the experimental data. Within the elastic region, the simulated deformation modes show good agreement with experimental observations. When the relative density of the regular re-entrant honeycombs equals to the hierarchical ones, the model predicts that the hierarchical re-entrant honeycombs have superior energy absorption performance with enhanced stiffness and yield strength in comparison to the regular ones. In conclusion, this study has demonstrated that by introducing hierarchical structure into re-entrant honeycomb, the structural stability has been improved. Furthermore, the hierarchical structure endows re-entrant honeycomb with lightweight yet competitive energy absorption capacity.
负泊松比重入式蜂窝作为一种轻型吸能器在各种应用中显示出巨大的潜力。然而,由于其弯曲为主的特性,重入式蜂窝的结构稳定性和吸能能力还有待进一步提高。研究表明,分层结构具有轻量化和优异的机械性能。我们假设,通过在常规细胞壁中引入三角形层次子结构,可以将蜂窝式再入蜂窝的弯曲主导行为转化为拉伸主导行为。因此,可以通过分层结构的局部变形来促进分层重入蜂窝结构的整体稳定性,从而潜在地提高结构的能量吸收能力。为了验证我们的假设,我们首先使用Polyjet 3d打印技术制造了长度范围从微米到厘米的分层可重入蜂巢。带实心支柱的常规可重返蜂巢已被制成基准结构。通过单轴准静态压缩试验对蜂窝的力学性能进行了表征。此外,利用数字图像相关(DIC)揭示了分层结构的局部变形机制。与常规重入蜂窝相比,分层重入蜂窝的整体破坏应变提高了36%。这是由于局部断裂和三角层致密化提高了结构稳定性。规则型和分层型蜂窝均表现出相同的比能量吸收能力。根据现有的尺度规律预测,通过优化结构的相对密度,分层重入蜂窝具有超越常规蜂窝的巨大潜力。利用商业软件Abaqus/CAE 2020建立了分层再入蜂窝的有限元模型。用实验数据对模型进行了校正。在弹性区域内,模拟的变形模式与实验结果吻合较好。当规则重入蜂巢的相对密度等于分层重入蜂巢时,该模型预测分层重入蜂巢的吸能性能优于规则重入蜂巢,其刚度和屈服强度均有所提高。综上所述,本研究表明,将分层结构引入再入式蜂窝结构中,可以提高结构稳定性。此外,层次化的结构赋予了可重入式蜂窝轻量化且具有竞争力的能量吸收能力。
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引用次数: 0
X-Ray Computed Tomography (XCT) Scanning Parameters Effects on the Hounsfield Unit (HU) Measurements for AA2011 x射线计算机断层扫描(XCT)扫描参数对AA2011 Hounsfield单元(HU)测量的影响
A. Baydoun, R. Hamade
X-ray computed tomography (XCT) is a powerful technique that can detect internal defects and differentiate between different materials making XCT a valuable non-destructive evaluation (NDE). However, when X-ray CT is employed as an NDE method, the scanning parameters and methodology are often underreported leading to a lack of consensus on the optimal scanning parameters to use when analyzing a particular metal or alloy. In this study, 16-bit X-ray CT scans are employed to characterize AA2011. Four parameters are investigated: scan (voxel) resolution, tube voltage, tube current, and sample size (thickness). Two sample disks are scanned simultaneously at an image bit depth of 16-bit. Mean and standard deviation Hounsfield Unit (HU) values are calculated which are then used to develop a predictive model for these two values. The model equation is used to produce surface plots to determine desired scanning parameters combination for characterizing AA2011 HU mean and standard deviation values. It is concluded that higher scanning resolution (smaller voxel), larger tube voltage and tube current settings, and thicker samples result in smaller of standard deviation HU values and converged mean HU values when scanning AA2011.
x射线计算机断层扫描(XCT)是一种强大的技术,可以检测内部缺陷和区分不同的材料,使XCT成为一种有价值的无损评估(NDE)。然而,当x射线CT被用作无损检测方法时,扫描参数和方法往往被低估,导致在分析特定金属或合金时对使用的最佳扫描参数缺乏共识。在本研究中,采用16位x线CT扫描来表征AA2011。研究了四个参数:扫描(体素)分辨率,管电压,管电流和样品尺寸(厚度)。以16位的图像位深度同时扫描两个样本磁盘。计算平均值和标准偏差霍斯菲尔德单位(HU)值,然后用于开发这两个值的预测模型。利用模型方程生成曲面图,确定表征AA2011 HU均值和标准差值所需的扫描参数组合。结果表明,扫描AA2011时,扫描分辨率越高(体素越小)、管电压和管电流设置越大、样品越厚,其标准差HU值和收敛均值HU值越小。
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引用次数: 0
Detection of Jamming and Filament Breakage in FDM Using Vibration of Feeder Stepper 利用进料器振动检测FDM中的干扰和断丝
Sean P. Rooney, Emil Pitz, K. Pochiraju
In the field of additive manufacturing (AM), mid-print failure is exceedingly common due to user error, bad design, or environmental factors that cannot be readily prepared for. This holds for most if not all types of AM, but perhaps none more so than the popular Filament Deposition Modeling (FDM) method machines. Absent total power failure, the bulk of the common modes of failure in FDM can be expressed as having an immediate impact on the mechanical system, whether that be a head collision due to warping, increased pressure on the stepper as it tries to push jammed filament, etc. The open loop nature of FDM machines does nothing to help the high rate of failure that FDM printers are known for compared to traditional methods of manufacturing. In this paper, a method for predicting failure due to mechanical malfunction of an FDM 3D printer is presented. The method proposed seeks to close the loop on FDM machines by characterizing the vibrations of the stepper motors which comprise an FDM machine. Using the acoustic emissions, a classifier is trained in order to assess the state of a print based off of supervised learning of known modes of failure. The resulting model is able to successfully predict jamming or air printing during a print with 90% training accuracy.
在增材制造(AM)领域,由于用户错误、设计不良或无法随时准备的环境因素,中途打印失败非常常见。这适用于大多数(如果不是所有类型的话)AM,但也许没有比流行的长丝沉积建模(FDM)方法机器更重要的。在没有全部电源故障的情况下,FDM中大部分常见的故障模式可以表示为对机械系统有直接影响,无论是由于翘曲引起的头部碰撞,步进器试图推动卡住的灯丝时压力增加,等等。与传统制造方法相比,FDM机器的开环特性对FDM打印机的高故障率没有任何帮助。本文提出了一种预测FDM 3D打印机机械故障的方法。所提出的方法旨在通过表征组成FDM机器的步进电机的振动来关闭FDM机器上的环路。使用声发射,训练分类器,以便根据已知故障模式的监督学习来评估打印状态。所得到的模型能够成功地预测打印过程中的干扰或空气打印,训练精度为90%。
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引用次数: 1
Crystalline Phase Changes Due to High-Speed Projectiles Impact on HY100 Steel 高速弹丸撞击HY100钢的结晶相变化
Muna Y. Slewa
High yield HY-100 steel is a unique alloy and well known for its employment in heavy construction. HY-100 offers good characteristics like ductility, notch toughness, corrosion resistance, and weldability. The physical characteristics and molecular structure of HY-100 steel are also well known; however, there is little known about the effect of high-velocity projectiles impact on this metal alloy’s crystalline structure and material phase. The effects of high-speed velocity impact on the crystalline structure and material phase changes are studied herein experimentally. The results of an impact on the crystalline structure are assessed by impacting HY-100 steel plates (15.4 × 15.4 × 1.27 cm) with Lexan projectiles. A two-stage light gas gun accelerates these projectiles to a velocity of 6.70 km/s at the point of the impact. The impacted plates’ surfaces are prepared as required for inspection by the Electron Back Scatter Diffraction (EBSD) microscope. Ten regions on each impacted plate area are examined and analyzed after impact. These regions are selected from the area immediately under the impact crater to locations that are not physically affected by the impact. Observations of collected EBSD images show that the predominant phase is Body-Centered Cubic (BCC). Moreover, Face-Centered Cubic (FCC) and Hexagonal-Close-Packed (HCP) phases are also indexed. The samples are also post-impact examined for molecular structure allocation changes. The results were then tabulated according to the regions relative to the impact crater. In this study, traces of HCP were found at some locations in all post-impact stages. This study also indicates that the BCC crystalline structure remained the dominant phase structure after impact, and it is valid with all test samples and all levels of shock loading. At this velocity, the damage zone develops within 5 microseconds due to impacting momentum. HY-100 steel materials go through a reversible phase change when subject to elevated temperature and high quasi-static pressure.
高产量HY-100钢是一种独特的合金,以其在重型建筑中的应用而闻名。HY-100具有良好的延展性、缺口韧性、耐腐蚀性和可焊性。HY-100钢的物理特性和分子结构也是众所周知的;然而,高速弹丸撞击对该金属合金晶体结构和材料相的影响尚不清楚。实验研究了高速冲击对晶体结构和材料相变的影响。通过用Lexan弹丸撞击HY-100钢板(15.4 × 15.4 × 1.27 cm)来评估对晶体结构的影响结果。两级轻气炮在撞击点将这些弹丸加速到6.70公里/秒的速度。对冲击板表面进行了必要的制备,以便用电子背散射衍射(EBSD)显微镜进行检测。撞击后,对每个撞击板区域的10个区域进行了检查和分析。这些区域是从紧接在撞击坑下面的区域中选择出来的,直到没有受到撞击的物理影响的地方。采集的EBSD图像显示,主要相位为体心立方(BCC)。此外,还对面心立方相(FCC)和六边形紧堆积相(HCP)进行了索引。这些样品也在撞击后进行了分子结构分配变化的检查。然后根据与撞击坑相关的区域将结果制成表格。在本研究中,在撞击后所有阶段的一些地点都发现了HCP的痕迹。该研究还表明,BCC晶体结构在冲击后仍然是主要的相结构,并且对所有测试样品和所有水平的冲击载荷都是有效的。在这个速度下,由于冲击动量,损伤区在5微秒内形成。HY-100钢材料在高温和高准静压作用下发生可逆相变。
{"title":"Crystalline Phase Changes Due to High-Speed Projectiles Impact on HY100 Steel","authors":"Muna Y. Slewa","doi":"10.1115/imece2021-69956","DOIUrl":"https://doi.org/10.1115/imece2021-69956","url":null,"abstract":"High yield HY-100 steel is a unique alloy and well known for its employment in heavy construction. HY-100 offers good characteristics like ductility, notch toughness, corrosion resistance, and weldability. The physical characteristics and molecular structure of HY-100 steel are also well known; however, there is little known about the effect of high-velocity projectiles impact on this metal alloy’s crystalline structure and material phase. The effects of high-speed velocity impact on the crystalline structure and material phase changes are studied herein experimentally. The results of an impact on the crystalline structure are assessed by impacting HY-100 steel plates (15.4 × 15.4 × 1.27 cm) with Lexan projectiles. A two-stage light gas gun accelerates these projectiles to a velocity of 6.70 km/s at the point of the impact. The impacted plates’ surfaces are prepared as required for inspection by the Electron Back Scatter Diffraction (EBSD) microscope. Ten regions on each impacted plate area are examined and analyzed after impact. These regions are selected from the area immediately under the impact crater to locations that are not physically affected by the impact. Observations of collected EBSD images show that the predominant phase is Body-Centered Cubic (BCC). Moreover, Face-Centered Cubic (FCC) and Hexagonal-Close-Packed (HCP) phases are also indexed. The samples are also post-impact examined for molecular structure allocation changes. The results were then tabulated according to the regions relative to the impact crater. In this study, traces of HCP were found at some locations in all post-impact stages. This study also indicates that the BCC crystalline structure remained the dominant phase structure after impact, and it is valid with all test samples and all levels of shock loading. At this velocity, the damage zone develops within 5 microseconds due to impacting momentum. HY-100 steel materials go through a reversible phase change when subject to elevated temperature and high quasi-static pressure.","PeriodicalId":23837,"journal":{"name":"Volume 3: Advanced Materials: Design, Processing, Characterization, and Applications","volume":"38 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73665207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Strength and Qualities of Mixed Additive Manufacturing Materials 混合增材制造材料的强度和质量
Seth Addeo, Margaret Nowicki, Kenneth J. McDonald, N. Zander
Filament shredders and extruders greatly expand the additive manufacturing material selection. By using recycled filaments, waste and future costs can be efficiently cut while creating in-house, customizable, filaments. Testing mixed filaments is necessary to determine the physical and chemical benefits and costs of mixing filaments. This work aims to characterize mixtures of Polylactic Acid and Acrylonitrile Butadiene Styrene. Mixtures were characterized through tensile strength testing and differential scanning calorimetry of extruded filament samples. The tested mixed filaments were found to be comparable to purchased filaments, with drastic increases in elasticity and decreases in torsional strength and tensile strength. This study shows that while possible to produce mixed filaments, and in spite of their chemical similarities, mixtures are not comparable in physical strength to pure filaments.
长丝碎纸机和挤出机极大地扩展了增材制造材料的选择。通过使用回收的灯丝,在制造内部定制的灯丝的同时,可以有效地减少浪费和未来的成本。测试混合长丝是必要的,以确定混合长丝的物理和化学效益和成本。本工作旨在表征聚乳酸和丙烯腈-丁二烯-苯乙烯的混合物。通过拉伸强度测试和差示扫描量热法对挤压长丝样品进行了表征。试验发现,混合长丝与购买的长丝相当,弹性急剧增加,扭转强度和拉伸强度下降。这项研究表明,虽然有可能生产混合长丝,尽管它们的化学成分相似,但混合物在物理强度上无法与纯长丝相比。
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引用次数: 0
Mechanical-Electrical Behavior of Multifunctional Energy Storage Composites 多功能储能复合材料的机电性能研究
Anthony Bombik, Sung Yeon Sara Ha, A. Nasrollahi, M. Haider, F. Chang
Multi-functional Energy Storage Composites (MESC) are composite sandwich structures where battery stack layers are placed between two layers of CFRP and sealed by low-density polyethylene (LDPE), forming a unified material. Because the layered Li-ion stacks have negligible out-of-plain shear stiffness, the two CFRP sheets on both sides of the battery are connected using LDPE rivets that pass through holes cut through the battery layers. The shear transfer mechanism of the rivets substantially enhances the shear stiffness and strength of the MESC. As the first step of preparing a guide for MESC design, the highly coupled mechanical and electrical behavior of MESC was studied through experiments. Several MESC cells were tested under three-point-bending loads. The load, deformation, and electric potential of the MESC were measured, and the electrical and mechanical failures were observed. A finite element model was developed to simulate the electro-chemo-mechanical coupling effect in MESC. In this model, a new constitutive relation of the battery material is proposed and verified by the experimental results. The resulting model can be used to simulate MESCs with various configurations and material properties to provide a design guideline of MESCs in multiple applications.
多功能储能复合材料(MESC)是一种复合夹层结构,将电池堆层置于两层CFRP之间,并用低密度聚乙烯(LDPE)密封,形成统一的材料。由于层状锂离子堆具有可忽略不计的平面外剪切刚度,因此电池两侧的两块CFRP片材使用LDPE铆钉连接,铆钉通过在电池层上切割的孔。铆钉的剪切传递机制大大提高了MESC的剪切刚度和强度。作为编制MESC设计指南的第一步,通过实验研究了MESC的高耦合力学和电学行为。几个MESC细胞在三点弯曲载荷下进行了测试。测量了MESC的载荷、变形和电势,并观察了其电气和机械故障。建立了模拟MESC中电化学-力学耦合效应的有限元模型。在此模型中,提出了一种新的电池材料本构关系,并通过实验结果进行了验证。该模型可用于模拟具有不同结构和材料特性的MESCs,为MESCs在多种应用中的设计提供指导。
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引用次数: 0
Multi Response Optimization of Friction Stir Process Parameters on AA2024 / SiC Composite Fabricated Using Friction Stir Processing 搅拌摩擦制备AA2024 / SiC复合材料工艺参数的多响应优化
Akash Manickam, Raman Kuppusamy, Sudha Jayaprakasham, S. Santhanam
Friction Stir processing is used to modify the mechanical properties of the metal by refining the grain structure, which is proven to be effective for selective surface modification and also retaining the properties of bulk. In this present work Aluminium Alloy 2024 is used as a matrix material, which possess poor corrosion resistance and the softness of the material leads to high wear rate. Silicon Carbide (SiC), which has high hardness, high corrosion resistance and withstands high temperature is used as the reinforcement material. The present work aims to enhance the mechanical properties by refining the grain structure, and improvement in the corrosion behavior of AA2024 through surface composite (AA2024/SiC) fabricated using FSP. The Aluminium Metal Matrix Composite is fabricated using Friction Stir Processing by varying the volume fraction of SiC, rotational speed and traverse speed. The process parameters used in this experiment are rotational speed of 1200 rpm, 1500 rpm & 1800 rpm, traverse speed of 44 mm/min, 60 mm/min & 72 mm/min and volume fractions 8%, 16% & 24% of SiC. The experiment is conducted using Taguchi’s L9 Orthogonal array considering three factors at three different levels. A square pin tool of H13 steel with hardness of 60 HRC is designed and fabricated to provide better material flow of the reinforcement particles. The Silicon Carbide (SiC) particulate reinforced Aluminium Metal Matrix Composite (MMC) has been successfully fabricated through single pass FSP. The tensile test were carried out using universal testing machine as per ASTM E8 standards to determine the elongation and the ultimate tensile strength (UTS) of FSPed AA2024/SiC composites and the corrosion rate were evaluated using immersion corrosion testing method by weighing the before and after weights of the samples as per ASTM G31-72, 2004. Grey Relational Analysis (GRA) is performed on the multiple response test results to find the optimum friction stir process parameters. Analysis of Variance (ANOVA) is performed to determine the most significant contributing friction stir process parameters at a 95% confidence level.
搅拌摩擦处理是通过细化晶粒结构来改变金属的力学性能,这种方法被证明是有效的选择性表面改性,同时也保持了金属的整体性能。本研究采用铝合金2024作为基体材料,其耐腐蚀性较差,材料的柔软性导致磨损率高。碳化硅(SiC)是一种硬度高、耐腐蚀、耐高温的增强材料。本工作旨在通过FSP制备表面复合材料(AA2024/SiC),细化AA2024的晶粒组织,提高其力学性能,改善其腐蚀行为。通过改变SiC的体积分数、转速和横移速度,采用搅拌摩擦法制备了铝基复合材料。本实验采用的工艺参数为转速为1200rpm、1500rpm和1800rpm,转速为44mm /min、60mm /min和72mm /min,体积分数为8%、16%和24% SiC。实验采用田口L9正交阵列,在三个不同的水平上考虑三个因素。为提高增强颗粒的材料流动性,设计并制造了硬度为60 HRC的H13钢方销刀具。采用单道FSP法成功制备了碳化硅颗粒增强铝基复合材料。采用ASTM E8标准万能试验机进行拉伸试验,确定了FSPed AA2024/SiC复合材料的伸长率和极限抗拉强度(UTS),并采用浸没腐蚀试验方法,根据ASTM g31 - 72,2004称重试样的前后重量,评估了腐蚀速率。对多响应试验结果进行灰色关联分析(GRA),寻找最佳搅拌摩擦工艺参数。方差分析(ANOVA)在95%的置信水平上进行,以确定最显著的贡献摩擦搅拌过程参数。
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引用次数: 1
Multilayer Separation Effects on MoS2 Membranes in Water Desalination 二硫化钼膜在海水淡化中的多层分离效果
P. Oviroh, S. Oyinbo, Sina Karimzadeh, T. Jen
Climate change and its related effects are imposing severe stress on the current freshwater supplies. This has been exacerbated due to the growth in population, rapid industrialization, and increased energy demand. Increased water requirement is a global challenge. Although more than 70% of the Earth is covered by water, much of it is unusable for human use. Freshwater reservoirs, ponds, and subterranean aquifers account for just 2.5% of the world’s overall freshwater availability. Unfortunately, these water supplies are not very unevenly spread. Therefore, the need to augment these supplies through the desalination of seawater or brackish water. Reverse osmosis (RO) is currently the most widespread method of desalination. However, the unit cost of water is still high partly due to the thin-film composite (TFC) polymer membranes used in the current desalination system. Thus the need for low-cost nanomaterials for Water Desalination and Purification. A promising way to meet this demand is to use two-dimensional (2D) nanoporous materials such as graphene and MoS2 to minimize energy consumption during the desalination process. New nanotechnology methodologies that apply reverse osmosis have been developed. Among some of these technologies is using 2D materials such as graphene and MoS2, which have been studied extensively for water desalination. Single-layer nanoporous 2D materials such as graphene and MoS2 promises better filtrations in the water channel. Although single-layer MoS2 (SL_MoS2) membrane have much promise in the RO desalination membrane, multilayer MoS2 are simpler to make and more cost-efficient. Building on the SL_MoS2 membrane knowledge, we have used the molecular dynamics method (MD) to explore the effects of multilayer MoS2 in water desalination. This comparison is made as a function of the pore size, water flow rate and salt rejection. In addition, we also looked at the effect of the increased interlayer spacing between layers of the nanoporous 2D membrane and then made the comparison. The ions rejection follows the trend trilayer> bilayer> monolayer from results obtained, averaging over all three membrane types studied for the MoS2, the ions rejection follows the trend trilayer > bilayer > monolayer. We find that the thin, narrow layer separation plays a vital role in the successful rejection of salt ions in bilayers and trilayers membranes. These findings will help build and proliferate tunable nanodevices for filtration and other applications.
气候变化及其相关影响对目前的淡水供应造成了严重的压力。由于人口的增长、快速的工业化和能源需求的增加,这种情况已经加剧。用水需求增加是一项全球性挑战。尽管超过70%的地球被水覆盖,但其中大部分是人类无法使用的。淡水水库、池塘和地下含水层仅占世界淡水总量的2.5%。不幸的是,这些水的供应分布并不是很不均匀。因此,需要通过淡化海水或微咸水来增加这些供应。反渗透(RO)是目前应用最广泛的海水淡化方法。然而,水的单位成本仍然很高,部分原因是目前海水淡化系统中使用的薄膜复合(TFC)聚合物膜。因此,需要低成本的纳米材料用于海水淡化和净化。满足这一需求的一个有希望的方法是使用二维(2D)纳米多孔材料,如石墨烯和二硫化钼,以最大限度地减少海水淡化过程中的能源消耗。应用反渗透的新纳米技术方法已经开发出来。其中一些技术是使用二维材料,如石墨烯和二硫化钼,它们已被广泛研究用于海水淡化。单层纳米多孔二维材料,如石墨烯和二硫化钼,有望在水道中获得更好的过滤效果。虽然单层MoS2 (SL_MoS2)膜在反渗透脱盐膜中有很大的发展前景,但多层MoS2膜的制作更简单,成本效益更高。基于SL_MoS2膜的知识,我们利用分子动力学方法(MD)探讨了多层MoS2在海水淡化中的作用。比较了孔隙大小、水流速率和排盐率的函数关系。此外,我们还观察了纳米多孔二维膜层间间距增加的影响,并进行了比较。从得到的结果来看,对MoS2所研究的所有三种膜类型进行平均,离子排斥遵循三层>双层>单层的趋势。我们发现,在双层和三层膜中,薄而窄的层分离对盐离子的成功排斥起着至关重要的作用。这些发现将有助于构建和扩散可调谐的纳米器件,用于过滤和其他应用。
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引用次数: 1
Fabrication, Processing and Characterization of Carbon Fibre Reinforced Laminated Composite Embedded With Graphene Lattice Sheets 石墨烯晶格片碳纤维增强层压复合材料的制备、加工与表征
V. Jadhav, A. Kelkar
This manuscript introduces the challenges in the fabrication of graphene sheet reinforced non-crimp fabric (NCF) composite laminates and their influence on the interlaminar strength of the composite laminates. In the current work, the laminates were fabricated using non-crimp carbon fabric prepreg along with 50,120 and 240 μm thick graphene sheets at the mid-plane. Double Cantilever Beam (DCB) tests are done as per ASTM 5528 using INSTRON electromechanical testing system. Modified Beam Theory method used to compute Mode I fracture toughness, using load, displacement, specimen dimension, and crack opening displacement. The graphene sheets are brittle; little bonding between the graphene and matrix observed during the fabrication process results in a fragile interface. To overcome this problem, graphene sheets were converted into a lattice structure. The lattice structure used in the present research had horizontal, vertical, and square grids. Effects of sheet thickness, grid pattern were evaluated by Mode I fracture toughness, with and without nanoengineered enhanced laminates. Axio Image upright microscope used to compare the bonding at the midplane after the DCB test. The results indicate that the composite laminates fabricated using lattice graphene structure had better interlaminar strength than the laminates fabricated with straight graphene sheets.
本文介绍了石墨烯片增强无卷曲织物(NCF)复合层压板制造中的挑战及其对复合层压板层间强度的影响。在目前的工作中,层压板是用无卷曲的碳织物预浸料和50,120和240 μm厚的石墨烯片在中层制备的。双悬臂梁(DCB)测试按照ASTM 5528使用INSTRON机电测试系统完成。修正梁理论方法采用荷载、位移、试件尺寸和裂纹张开位移计算I型断裂韧性。石墨烯薄片很脆;在制造过程中,石墨烯与基体之间的结合很少,导致界面脆弱。为了克服这个问题,石墨烯片被转换成晶格结构。本研究中使用的点阵结构有水平网格、垂直网格和方形网格。采用I型断裂韧性评价了加和不加纳米工程增强层压板对板厚、网格模式的影响。用Axio Image立式显微镜比较DCB测试后背板的粘结情况。结果表明,采用点阵石墨烯结构制备的复合材料层压板具有较好的层间强度。
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引用次数: 0
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Volume 3: Advanced Materials: Design, Processing, Characterization, and Applications
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