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Optimization of the First and Second Hyperpolarizabilities of Organic Dyes 有机染料一、二阶超极化率的优化
Pub Date : 1993-10-06 DOI: 10.1364/otfa.1993.wc.1
G. Bourhill, J. Brédas, L. Cheng, A. Friedli, C. Gorman, S. Marder, F. Meyers, J. Perry, B. Pierce, J. Skindhøj, B. Tiemann
We have been attempting to correlate hyperpolarizabilities with bond-length alternation (BLA), which is defined as the difference in the average length between adjacent carbon-carbon bonds in a polymethine ((CH)n) chain.(1, 2) Polyenes have alternating double and single bonds (bond length equal to 1.34 Å and 1.45 Å, respectively), and thus show a high degree of bond-length alternation (BLA=-0.11Á). In donor-acceptor polyenes, this parameter is related to the degree of ground-state polarization in the molecule. To better understand this correlation, it is illustrative to discuss the wave function of the ground state in terms of a linear combination of the two limiting charge-transfer resonance structures. For substituted polyenes with weak donors and acceptors, the neutral resonance form dominates the ground-state wavefunction, and the molecule has a high degree of (conventionally negative) bond-length alternation. With stronger donors and acceptors, the contribution to the ground state, of the charge-separated resonance form increases and simultaneously, BLA decreases in absolute value. When the two resonance structures contribute equally, as in a symmetrical cyanine, the molecule exhibits essentially no bond-length alternation. Finally, if the charge-separated form dominates the ground-state wave function, the molecule acquires a positive bond-length alternation. Neutral molecules with aromatic rings have a diminished contribution of the charge-separated form to the ground-state wave function, due to the energetic price associated with the loss of aromaticity in that form.(3) As a result, push-pull molecules with aromatic ground states tend to be more bond-length alternated for a given donor and acceptor pair than for a polyene of comparable length.
我们一直试图将超极化性与键长交替(BLA)联系起来,它被定义为聚甲基(CH)n)链中相邻碳-碳键之间的平均长度差异。(1,2)多烯具有交替的双键和单键(键长分别为1.34 Å和1.45 Å),因此显示出高度的键长交替(BLA=-0.11Á)。在供体-受体多烯中,该参数与分子中基态极化的程度有关。为了更好地理解这种相关性,用两个极限电荷转移共振结构的线性组合来讨论基态的波函数是有说明意义的。对于具有弱供体和弱受体的取代多烯,中性共振形式主导基态波函数,并且分子具有高度(通常为负的)键长交替。供体和受体越强,电荷分离共振形式对基态的贡献越大,同时,BLA绝对值减小。当两种共振结构的作用相同时,如对称的菁氨酸,分子基本上没有键长交替。最后,如果电荷分离形式主导基态波函数,则分子获得正键长交替。具有芳香环的中性分子的电荷分离形式对基态波函数的贡献减少,这是由于这种形式的芳香性损失所带来的能量代价。(3)因此,具有芳香基态的推挽分子对于给定的供体和受体对的键长交替比具有相同长度的多烯的键长交替。
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引用次数: 0
Absorption and Scattering in Nonlinear Optical Polymeric Systems 非线性光学聚合物系统中的吸收和散射
Pub Date : 1993-02-01 DOI: 10.1063/1.109618
A. Skumanich, M. Jurich, J. Swalen
Nonlinear organic systems often consist of a polymer matrix with a optical chromophore as a guest or an attached side chain. For enhanced optical nonlinearity, the chromophore absorption band should be located near the desired operating wavelength, but with no absorption. Good optical transmission is critical, and both the absorption and the scattering need to be minimized. Since the films are usually thin and weakly absorbing, it is difficult to determine either of these two material properties. By using the highly sensitive absorption technique of photothermal deflection spectroscopy (PDS), it is possible to obtain the fundamental optical spectrum of the nonlinear optical (NLO) systems over a wide energy range, and separate the absorption from the scattering. With this information, one can then select optimal polymer-chromophore systems. The absorption data indicates what the intrinsic waveguide loss should be for any given wavelength. For materials with low absorption, if there is high waveguide loss, either improved processing is necessary to lower the scattering, or insertion losses need to be reduced.
非线性有机系统通常由带有光学发色团作为客体或附加侧链的聚合物基体组成。为了增强光学非线性,生色团吸收带应位于所需工作波长附近,但不吸收。良好的光传输是至关重要的,吸收和散射都需要最小化。由于薄膜通常很薄,吸收能力很弱,因此很难确定这两种材料的性能。利用光热偏转光谱(PDS)的高灵敏度吸收技术,可以在较宽的能量范围内获得非线性光学系统的基本光谱,并将吸收与散射分离开来。有了这些信息,人们就可以选择最佳的聚合物-发色团体系。吸收数据表明,对于任何给定波长,本征波导损耗应该是多少。对于低吸收的材料,如果存在高波导损耗,要么需要改进工艺来降低散射,要么需要降低插入损耗。
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引用次数: 41
New Device Concepts in Polymer Optical Fibers 聚合物光纤中的新器件概念
Pub Date : 1900-01-01 DOI: 10.1364/otfa.1993.thd.1
M. Kuzyk, Q. Li, D. Welker, P. Young, S. Zhou, C. Dirk
The fact that light induces a refractive index change in a material is the basis of an all-optical switching or logic device - where one beam of light affects its own propagation or the propagation of a second beam of light. There are many mechanisms that result in such a light- induced refractive index change. The heating mechanisms, for example, results when the refractive index changes in response to the density change that accompanies thermal heating when light energy is absorbed by a material. By virtue of the conductive nature of heating, the thermal effects are slow (approximately ≈ Is time scale). The fast electronic mechanism, on the other hand, results in refractive index changes due to electronic cloud deformation. When the excitations are far off any material resonances, electron cloud distortion does not result in real excitations of the atoms or molecules and is thus a fast response (≈ 10-15s).
光在材料中引起折射率变化的事实是全光开关或逻辑器件的基础,其中一束光影响其自身的传播或第二束光的传播。造成这种光致折射率变化的机制有很多。例如,当光能被材料吸收时,折射率随密度变化而变化时,就会产生加热机制。由于加热的导电性,热效应是缓慢的(大约≈Is的时间尺度)。另一方面,快速电子机制由于电子云变形导致折射率变化。当激发远离任何物质共振时,电子云畸变不会导致原子或分子的实际激发,因此是一个快速响应(≈10-15s)。
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引用次数: 0
Excited State Dynamics of the Third Order Nonlinear Optical Susceptibility in Conjugated Linear Chains 共轭线性链中三阶非线性光磁化率的激发态动力学
Pub Date : 1900-01-01 DOI: 10.1364/otfa.1993.tha.1
W.D. Chen, D. C. Rodenberger, R. Shi, Q. Zhou, A. Garito
We have earlier presented theoretical and experimental results demonstrating that the nonresonant third order optical susceptibility χ(3)(−ω;ω,ω,−ω) can be enhanced for nonlinear optical processes originating from real population of electronic excited states in conjugated linear chains[1,2]. Compared with the ground state, χ(3)(−ω;ω,ω,−ω) of π-conjugated linear chains can be enhanced by orders of magnitude when the first S1 or second S2 π-electron excited state is optically pumped and then populated for times long enough to perform nonresonant measurements of χ(3)(−ω;ω,ω,−ω) at frequencies different from the resonant pump frequency. In this paper, a dynamical model is developed for the time evolution of the nonresonant microscoopic degenerate four wave mixing (DFWM) susceptibility γ(-ω;ω,ω,-ω) for the excited state enhancement mechanism. The model is applied to the case of the six site chain, diphenylhexatriene (DPH).
我们之前已经提出了理论和实验结果,证明非共振三阶光学磁化率χ(3)(−ω;ω,ω,−ω)可以在共轭线性链中由电子激发态的实际居群引起的非线性光学过程中得到增强[1,2]。与基态相比,当第一个S1或第二个S2 π电子激发态被光抽运并填充足够长的时间以在不同于共振泵浦频率的频率下对χ(3)(−ω;ω,ω,−ω)进行非共振测量时,π共轭线性链的χ(3)(−ω;ω,ω,−ω)可以提高几个数量级。本文建立了非共振微观简并四波混频(DFWM)磁化率γ(-ω;ω,ω,-ω)的时间演化动力学模型,用于激发态增强机制。该模型适用于六位点链二苯基己三烯(DPH)。
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引用次数: 0
Nonlinear Optical Activity in Second-Harmonic Generation from a Chiral Surface 手性曲面二次谐波产生中的非线性旋光性
Pub Date : 1900-01-01 DOI: 10.1364/otfa.1993.pd.2
A. Persoons, T. Verbiest, M. Kauranen
We have observed that the efficiency of second-harmonic generation from a monolayer of chiral molecules depends on the handedness of the incoming fundamental beam. This circular-difference effect is observed both in reflection and transmission of the second-harmonic radiation. Analogous to linear optical activity, we show that these effects can be explained by including contributions of magnetic-dipole transitions to the second-order nonlinear susceptibility.
我们观察到单层手性分子产生二次谐波的效率取决于入射基束的手性。这种圆差效应在二次谐波辐射的反射和透射中都可以观察到。与线性光学活性类似,我们表明这些效应可以通过包括磁偶极子跃迁对二阶非线性磁化率的贡献来解释。
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引用次数: 0
Anisotropic Self-Alignment of Supramolecular Amylose Inclusion of Chromophores for Second-Order Nonlinear Optical Materials 二阶非线性光学材料中超分子直链淀粉包裹体的各向异性自取向
Pub Date : 1900-01-01 DOI: 10.1364/otfa.1995.md.31
O. Kim, L. Choi, He-Yi Zang, Xue He, Yan-Hua Shih
Anisotropic alignment of nonlinear chromophores and their dipolar stability are the key issues1 of nonlinear optical (NLO) materials. Poling is a usual means in guest-host systems to bring about such an alignment2-4. Since poling is carried out around the glass transition temperature(Tg) of hosts5, and the temporal stability of chromophores depends primarily on Tg values of hosts, matrix materials for high-temperature stability are required to have high Tg such as with polyimides. However, the high-temperature poling causes problems in nonlinear chromophores, such as bleaching6-7, decomposition8,9 or loss of dipolar alignment10, unless they have very high decomposition temperatures. Also, a related problelm is a plasticizing effect8,11 of chromophores which lowers the Tg of the matrix with increasing chromophore concentration.
非线性发色团的各向异性排列及其偶极稳定性是非线性光学材料研究的关键问题。轮询是主客系统中实现这种对齐的常用方法2-4。由于极化是在宿主体的玻璃化转变温度(Tg)附近进行的,而发色团的时间稳定性主要取决于宿主体的Tg值,因此需要具有高Tg(如聚酰亚胺)的高温稳定性基质材料。然而,高温极化会引起非线性发色团的问题,如漂白6-7、分解8、9或偶极排列的丧失10,除非它们具有很高的分解温度。此外,一个相关的问题是生色团的塑化效应8,11,随着生色团浓度的增加,母体的Tg降低。
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引用次数: 0
Dependence of the Performance of Vacuum Deposited Organic Light Emitting Diodes on Layer Thickness and Composition 真空沉积有机发光二极管的性能与层厚度和组成的关系
Pub Date : 1900-01-01 DOI: 10.1364/otfa.1993.wb.2
P. Burrows, S. Forrest, F. So
Efficient green electroluminescence from an organic double-layer device between two electrodes was first reported by Tang and Van Slyke [1,2]. Subsequently, there has been considerable interest in using various fluorescent organic molecules in similar structures to produce electroluminescence in different spectral regions. Also, more complex, triple layer "double heterostructure" devices have been reported[3]. However, although devices emitting throughout the visible spectrum have been successfully fabricated [1,4,5], there is a lack of quantitative information relating the organic layer thickness and heterojunction properties to device performance.
Tang和Van Slyke首次报道了两个电极之间的有机双层器件的高效绿色电致发光[1,2]。随后,人们对利用各种结构相似的荧光有机分子在不同光谱区域产生电致发光产生了相当大的兴趣。此外,还报道了更复杂的三层“双异质结构”器件[3]。然而,尽管已经成功地制造了发射整个可见光谱的器件[1,4,5],但缺乏有机层厚度和异质结特性与器件性能相关的定量信息。
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引用次数: 0
Second-order nonlinear optical properties and thermal stability of the amino-sulfone chromophore containing polymers 含氨基砜发色团聚合物的二阶非线性光学性质和热稳定性
Pub Date : 1900-01-01 DOI: 10.1364/otfa.1993.wa.3
P. Ranon, Yongqiang Shi, W. Steier, Chenghuang Xu, Bochang Wu, L. Dalton
The second-order nonlinear optical (NLO) properties of azo compounds containing amino-donor and sulfone-acceptor groups have been reported by several research groups.1 Their studies demonstrated that these amino-sulfone chromophores have a sizable nonlinearity and can be functionalized at both ends of the molecule for either polymerization or crosslinking. In this paper, we report our study of several side chain and main chain polymers which focused on anchoring both ends of the chromophores within a polymer matrix to improve the thermal stability of the molecular alignment. In particular, we report our study of two new classes of amino-sulfone chromophore containing polymers.
含有氨基给体和砜受体基团的偶氮化合物的二阶非线性光学性质已被一些研究小组报道他们的研究表明,这些氨基砜发色团具有相当大的非线性,可以在分子的两端官能化,用于聚合或交联。在本文中,我们报道了几种侧链和主链聚合物的研究,重点是在聚合物基质中锚定发色团的两端,以提高分子排列的热稳定性。特别地,我们报告了我们的研究两类新的氨基砜含发色团聚合物。
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引用次数: 1
High Efficiency White and Colored Organic Electroluminescence 高效白色和彩色有机电致发光
Pub Date : 1900-01-01 DOI: 10.1364/otfa.1995.thc.1
R. H. Jordan, A. Dodabalapur, M. Strukelj, L. Rothberg, R. Slusher, T. M. Miller
The need for light weight, low power multicolor displays and backlights has spurred interest in thin-film, organic electroluminescent (EL) devices. A typical organic EL device consists of an indium-tin oxide anode (ITO) layer on a glass substrate, and sequential layers of bis(triphenyl)diamine (TAD, hole transporter), tris(8-hydroxyquinoline)aluminum (A1Q, electron transporter and green light-emitter), and a low work function metal cathode (e.g., Al or Mg:Ag).1 Device efficiency, stability, and spectral output can be tailored by incorporating intermediate layers of organic hole-blockers2 or blue-emitters,3 or doping A1Q with narrow spectral linewidth organic dyes.4 Cavity resonance effects have been employed in lithographically patterned optical microcavities to select single5or multiple6 colors out of broad spectrum organic emitters like A1Q. Device efficiency is a critical parameter, especially for liquid crystal display backlight applications. We will describe an approach for white light EL and an approach for enhancing device efficiency.
对重量轻、功耗低的多色显示器和背光的需求激发了人们对薄膜有机电致发光(EL)器件的兴趣。典型的有机电致发光器件由玻璃衬底上的氧化铟锡阳极(ITO)层、双(三苯基)二胺(TAD,空穴传输子)、三(8-羟基喹啉)铝(A1Q,电子传输子和绿光发射器)和低功函数金属阴极(例如Al或Mg:Ag)组成器件的效率、稳定性和光谱输出可以通过结合有机空穴阻挡剂s2或蓝色发射器3的中间层或掺杂A1Q与窄谱线宽有机染料来定制腔共振效应已被用于光刻图像化的光学微腔中,以从广谱有机发射体(如A1Q)中选择单色或多色。器件效率是一个关键参数,特别是对于液晶显示背光应用。我们将描述一种白光EL的方法和一种提高器件效率的方法。
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引用次数: 0
TN and GHLCDs Fabricated by Non-Rubbing Techniques and an Overview of LCDs in Japan 非摩擦技术制备TN和ghlcd及日本lcd综述
Pub Date : 1900-01-01 DOI: 10.1364/otfa.1995.tuc.2
S. Kobayashi, Y. Iimura, T. Saitoh, H. Suzuki, T. Hashimoto, T. Sugiyama, K. Katoh
Amorphous TN(twisted by 90°) and amorphous highly twisted chiral nematic (N*)(twisted by 300°) are utilized for fabricating TN and GHLCDs, respectively, and furthermore, photopolymer films are utilized for fabricating TNLCD and hybrid aligned N-LCD. These NLC alignment techniques are non-rubbing techniques and they make it possible to overcome the disadvantages of current rubbing technique. An overview of LCDs in Japan is also given.
利用非晶态TN(扭曲90°)和非晶态高扭曲手性向列(N*)(扭曲300°)分别制备TN和ghlcd,并利用光聚合物薄膜制备TNLCD和杂化排列N- lcd。这些NLC对准技术是非摩擦技术,它们使克服当前摩擦技术的缺点成为可能。对日本液晶显示器的发展进行了概述。
{"title":"TN and GHLCDs Fabricated by Non-Rubbing Techniques and an Overview of LCDs in Japan","authors":"S. Kobayashi, Y. Iimura, T. Saitoh, H. Suzuki, T. Hashimoto, T. Sugiyama, K. Katoh","doi":"10.1364/otfa.1995.tuc.2","DOIUrl":"https://doi.org/10.1364/otfa.1995.tuc.2","url":null,"abstract":"Amorphous TN(twisted by 90°) and amorphous highly twisted chiral nematic (N*)(twisted by 300°) are utilized for fabricating TN and GHLCDs, respectively, and furthermore, photopolymer films are utilized for fabricating TNLCD and hybrid aligned N-LCD. These NLC alignment techniques are non-rubbing techniques and they make it possible to overcome the disadvantages of current rubbing technique. An overview of LCDs in Japan is also given.","PeriodicalId":246676,"journal":{"name":"Organic Thin Films for Photonic Applications","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116155285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Organic Thin Films for Photonic Applications
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