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Formation of nanoparticles by short and ultra-short laser pulses 短和超短激光脉冲形成纳米粒子
Pub Date : 2008-05-08 DOI: 10.1117/12.782711
K. Gouriet, T. Itina, S. Noël, J. Hermann, M. Sentis, L. Zhigilei
The main objective of this study is to explain the experimental observations. To simulate material ablation, plume formation and its evolution, we developed a combined molecular dynamics (MD) and direct simulation Monte Carlo (DSMC) computational study of laser ablation plume evolution. The first process of the material ablation is described by the MD method. The expansion of the ejected plume is modelled by the DSMC method. To better understand the formation and the evolution of nanoparticles present in the plume, we first used separate MD simulations to analyse the evolution of a cluster in the presence of background gas with different properties (density, temperature). In particular, we examine evaporation and growth reactions of a cluster with different size and initial temperature. As a result of MD calculations, we determinate the influence of the background gas parameters on the nanoparticles. The reactions rates such as evaporation/condensation, which are obtained by MD simulations, are directly transferred to the DSMC part of our combined model. Finally, several calculations performed by using MD-DSMC model demonstrate both plume dynamics and longer-time cluster evolution. Calculations results are compared with experimental findings.
本研究的主要目的是解释实验观察结果。为了模拟物质烧蚀、羽流形成及其演化过程,采用分子动力学(MD)和直接模拟蒙特卡罗(DSMC)相结合的方法对激光烧蚀羽流演化过程进行了计算研究。用MD方法描述了材料烧蚀的第一个过程。用DSMC方法模拟了喷发羽流的膨胀过程。为了更好地理解羽流中纳米颗粒的形成和演化,我们首先使用单独的MD模拟来分析具有不同性质(密度、温度)的背景气体存在下星团的演化。特别地,我们研究了不同尺寸和初始温度的团簇的蒸发和生长反应。通过MD计算,我们确定了背景气体参数对纳米粒子的影响。由MD模拟得到的蒸发/冷凝等反应速率直接传递到组合模型的DSMC部分。最后,利用MD-DSMC模型进行了一些计算,证明了羽流动力学和较长时间的簇演化。计算结果与实验结果进行了比较。
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引用次数: 2
Ultrafast laser irradiation vs cluster ion impact: molecular-dynamics comparison of materials processes in highly energized solids 超快激光照射与簇离子冲击:高能量固体中材料过程的分子动力学比较
Pub Date : 2008-05-08 DOI: 10.1117/12.784270
H. Urbassek, Christian Anders, Luis Sandoval, A. Upadhyay
The physical mechanisms and processes underlying the erosion of a surface induced by cluster bombardment or short-pulse laser irradiation are highlighted. When the average energy delivered per atom in the vicinity of the surface becomes comparable to the cohesive energy of the solid, sputtering from a so-called spike may result. Such a spike leads to abundant sputtering (surface erosion) and crater formation. Direct atomization in the region of highest energy deposition, as well as melt flow and gas flow contribute to the erosion. The materials phenomena occurring after ultra-fast laser irradiation of a metal in the ps- or fs-regime are reviewed. With increasing laser fluence, the film melts, voids are formed, the film tears (spallation), and finally fragments to form a multitude of clusters. These processes are universal in the sense that they occur in widely differing materials such as metals or van-der-Waals bonded materials. We investigate a Lennard-Jones solid as well as four different metals (Al, Cu, Ti, W), which vary widely in their cohesive energy, melting temperature, bulk modulus, and crystal structure. When the energy transfer starting the process is scaled to the cohesive energy of the material, the thresholds of these processes adopt similar values. A comparison of the similarities and differences of the mechanisms underlying surface erosion under cluster ion impact and ultrafast laser irradiation will be drawn.
强调了由簇轰击或短脉冲激光照射引起的表面侵蚀的物理机制和过程。当表面附近每个原子传递的平均能量与固体的内聚能相当时,就会产生所谓的尖峰溅射。这样的尖峰会导致大量的溅射(表面侵蚀)和陨石坑的形成。在最高能量沉积区域的直接雾化,以及熔体流动和气体流动都有助于侵蚀。综述了超快激光辐照金属在ps-或fs-态下发生的材料现象。随着激光能量的增加,薄膜熔化,形成空洞,薄膜撕裂(剥落),最后碎片形成大量的团簇。这些过程是普遍的,因为它们发生在广泛不同的材料中,如金属或范德华键合材料。我们研究了Lennard-Jones固体以及四种不同的金属(Al, Cu, Ti, W),它们在结合能,熔化温度,体积模量和晶体结构方面差异很大。当将启动该过程的能量传递缩放为材料的内聚能时,这些过程的阈值采用相似的值。比较了簇离子冲击和超快激光照射下表面侵蚀机理的异同。
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引用次数: 0
Designing laser-induced refractive index changes in "thermal" glasses 热玻璃中激光诱导折射率变化的设计
Pub Date : 2008-05-08 DOI: 10.1117/12.783449
R. Stoian, A. Mermillod-Blondin, C. Mauclair, N. Huot, É. Audouard, I. M. Burakov, N. Bulgakova, Y. P. Meschcheryakov, A. Rosenfeld, A. Husakou, I. Hertel
Ultrafast lasers emerged as promising tools to process refractive index changes in band-gap materials, resulting in waveguiding functions. Positive refractive index changes were often reported in fused silica matrices. However, in glasses characterized by slow electronic relaxation and high thermal expansion, the refractive index change is usually negative, detrimental for waveguide writing. This relates to the formation of hot regions, where, due to thermal expansion, material is quenched in low-density phases. We discuss control mechanisms related to spatio-temporal heat-source design which may be tuned by temporally shaped laser radiation. Programmable temporal tailoring of pulse envelopes triggers transitions from thermal expansion to directional inelastic flow. Consequently, material compaction leads to a positive refractive index change and guiding structures may thus be created. From an application perspective, the structuring quality degrades with the focusing depth due to wavefront distortions generated at the air-dielectric interface inducing spatial energy dispersion. Spatial beam tailoring corrects beam propagation distortion, improving the structuring accuracy. The corrective process is becoming important when laser energy has to be transported without losses at arbitrary depths, with the purpose of triggering mechanisms of positive index change.
超快激光器是处理带隙材料折射率变化的有前途的工具,从而产生波导功能。正的折射率变化经常报道熔融二氧化硅基质。然而,在以慢电子弛豫和高热膨胀为特征的玻璃中,折射率变化通常为负,不利于波导写入。这与热区的形成有关,在那里,由于热膨胀,材料在低密度相中淬火。我们讨论了与时空热源设计相关的控制机制,时空热源设计可以通过时间形状的激光辐射进行调谐。脉冲包络的可编程时间剪裁触发从热膨胀到定向非弹性流动的转变。因此,材料压实导致正折射率变化,从而可以创建导向结构。从应用角度来看,由于在空气-介质界面处产生的波前畸变引起空间能量色散,结构质量随着聚焦深度的增加而下降。空间光束裁剪可校正光束传播畸变,提高结构精度。当激光能量必须在任意深度无损失地传输时,校正过程变得越来越重要,其目的是触发正指数变化的机制。
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引用次数: 5
Equation of state of matter irradiated by short laser pulse and geometry of spalled cupola 短脉冲激光照射下的物质状态方程及剥落冲天炉的几何形状
Pub Date : 2008-05-08 DOI: 10.1117/12.782612
Y. Petrov, V. Zhakhovskiĭ, N. Inogamov, S. Ashitkov, V. Khokhlov, Arun K. Upadhyay, M. Agranat, S. Anisimov, K. Nishihara, B. Rethfeld, H. Urbassek
The motion of both Lennard-Jones solids and metals induced by ultrashort laser irradiation near the ablation threshold is investigated by molecular dynamics simulation. The universality of the ablation threshold fluence with respect to the cohesion energy of solids irradiated by femtosecond laser pulses is demonstrated for Lennard-Jones solid and metals simulated by many-body EAM potentials.
采用分子动力学模拟方法研究了超短激光辐照在烧蚀阈附近引起的Lennard-Jones固体和金属的运动。对于多体EAM势模拟的Lennard-Jones固体和金属,证明了飞秒激光脉冲辐照固体内聚能的烧蚀阈值影响的普适性。
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引用次数: 8
Correlation between early-stage expansion and spectral emission of a nanosecond laser-induced plasma from organic material 有机材料中纳秒激光诱导等离子体早期膨胀与光谱发射的关系
Pub Date : 2008-05-08 DOI: 10.1117/12.785218
M. Baudelet, Myriam G. Boueri, Jin Yu, X. Mao, R. Russo
Laser-Induced Breakdown Spectroscopy (LIBS) has been used since 40 years on typical samples such as metals, alloys, rocks. Detection of organic hazards or analysis of biological compounds under atmospheric pressure with LIBS represents a new challenge. For this purpose, we need better understandings of the physico-chemical properties of the plasma in atmosphere and their influences on the LIBS signal. As a model sample of organic materials, Nylon 6-6 has been studied under nanosecond ablation at different wavelengths (1064 nm and 266 nm) and energies (from 1 to 5 mJ) in order to observe the influence of these parameters. Shadowgraph technique is used to image the plasma at its early stage of expansion (0 to 40 ns). Time-resolved LIBS signal is recorded for longer times (50 ns to 5 μs). In the infrared regime, the expansion of the plume is faster along the laser axis, perpendicular to the sample surface. On the contrary, for UV ablation, the expansion of the plume is quite isotropic. We can also observe different regimes of expansion due to Laser-Supported Detonation Waves (LSDW) above 3 mJ in the UV regime. In particular, these observations provide us ideas to understand the kinetics of the CN emission in the LIBS signal. In the IR regime, a formation of CN due to carbon present in the sample and nitrogen in the air via the reaction 2C + N2 → 2CN can be observed. In the UV regime, the direct ablation of CN bonds is clearly seen but other effects like screening and recombination due to LSDW have also been observed.
激光诱导击穿光谱(LIBS)在金属、合金、岩石等典型样品上的应用已有40年的历史。利用LIBS检测有机危害或分析常压下的生物化合物是一个新的挑战。为此,我们需要更好地了解大气中等离子体的物理化学性质及其对LIBS信号的影响。以尼龙6-6为模型材料,在不同波长(1064 nm和266 nm)和能量(1 ~ 5 mJ)的纳秒烧蚀条件下,研究了这些参数对尼龙6-6的影响。在等离子体膨胀的早期阶段(0 ~ 40ns),采用阴影成像技术对等离子体进行成像。时间分辨LIBS信号记录时间较长(50 ns ~ 5 μs)。在红外波段,羽流沿垂直于样品表面的激光轴膨胀更快。相反,对于紫外烧蚀,羽流的膨胀是各向同性的。我们还可以观察到不同的膨胀制度,由于激光支持的爆炸波(LSDW)超过3mj的紫外制度。特别是,这些观测结果为我们理解LIBS信号中CN发射的动力学提供了思路。在红外光谱下,可以观察到样品中的碳和空气中的氮通过2C + N2→2CN反应形成CN。在紫外线下,可以清楚地看到CN键的直接消融,但也观察到其他效应,如LSDW的筛选和重组。
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引用次数: 4
Electron generation in laser-irradiated insulators: theoretical descriptions and their application 激光辐照绝缘体中的电子产生:理论描述及其应用
Pub Date : 2008-05-08 DOI: 10.1117/12.784630
B. Rethfeld, S. Linden, L. Englert, M. Wollenhaupt, L. Haag, C. Sarpe-Tudoran, T. Baumert
Transparent solids may absorb energy from a laser beam of sufficient high intensity. Several models are under consideration to describe the evolution of the free-electron density. Some of these models keep track of the energy distribution of the electrons. In this work we compare different models and give rules to estimate which one is applicable. We present the inclusion of a term in the multiple rate equation approach, recently introduced, describing fast recombination processes to exciton states. Moreover, we present experimental results with temporally asymmetric femtosecond laser pulses, impinging on a surface of fused silica. We found different thresholds for surface material modification with respect to an asymetric pulse and its time reversed counterpart. This difference is due to a different time-and-intensity dependence of the main ionization processes, which can be controlled with help of femtosecond shaped laser pulses.
透明固体可以从足够高强度的激光束中吸收能量。人们正在考虑几种模型来描述自由电子密度的演化。其中一些模型跟踪电子的能量分布。在这项工作中,我们比较了不同的模型,并给出了规则来估计哪一个是适用的。我们提出了在最近引入的多速率方程方法中包含一个术语,用于描述激子态的快速重组过程。此外,我们给出了时间不对称飞秒激光脉冲撞击熔融二氧化硅表面的实验结果。我们发现,相对于不对称脉冲及其时间反转的对应物,表面材料改性的阈值不同。这种差异是由于主要电离过程的时间和强度依赖不同,这可以通过飞秒形状的激光脉冲来控制。
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引用次数: 2
Multi-megajoule NIF: ushering in a new era in high energy density science 兆焦耳NIF:开启高能量密度科学的新时代
Pub Date : 2008-05-08 DOI: 10.1117/12.782724
E. Moses
This paper describes the status of the stadium-sized National Ignition Facility (NIF), the world's largest laser system and first operational multi-megajoule laser. The 192-beam NIF, located at Lawrence Livermore National Laboratory (LLNL), is 96% complete and scheduled for completion in March 2009. The NIF laser will produce nanosecond laser pulses with energies up to approximately 4 MJ in the infrared (laser wavelength = 1.053-μm) and 2MJ in the ultraviolet (laser wavelength = 0.35-μ m). With these energies NIF will access conditions of pressure and temperature not previously available on earth, allowing it to conduct experiments in support of the nation's national security, energy, and fundamental science goals. First ignition experiments at NIF are scheduled for FY2010. This paper will provide an overview of the NIF laser and the ignition, energy, and fundamental science activities at NIF.
本文介绍了体育场大小的国家点火装置(NIF)的现状,这是世界上最大的激光系统和第一个运行的兆焦耳激光器。位于劳伦斯利弗莫尔国家实验室(LLNL)的192束NIF已经完成了96%,计划于2009年3月完工。NIF激光器将产生纳秒激光脉冲,其红外(激光波长= 1.053-μm)和紫外(激光波长= 0.35-μ m)的能量高达约4兆焦耳,利用这些能量,NIF将进入以前在地球上无法获得的压力和温度条件,使其能够进行实验,以支持国家安全,能源和基础科学目标。NIF的首次点火实验计划在2010财年进行。本文将介绍NIF激光器的概况,以及NIF的点火、能量和基础科学活动。
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引用次数: 8
Reflection Fourier transform infrared spectroscopy of polymer targets for CO2 laser ablation CO2激光烧蚀聚合物靶的反射傅里叶变换红外光谱研究
Pub Date : 2008-05-08 DOI: 10.1117/12.782436
J. Sinko, C. A. Schlecht
One of the many challenges faced by laser propulsion is the long-term performance of the propellant. The chemical changes that can take place at the propellant surface during ablation can greatly modify the in-flight performance characteristics. For stable regimes for propulsion, such chemical action should be minimized. A TEA (Transverse Electrical discharge in gas at Atmospheric pressure) CO2 laser of 10.6 μm wavelength, 300 ns pulse length, and up to 20 J pulse energy was used to ablate several types of polymer targets with a range of observable chemical changes at the surface following ablation. After 10 subsequent shots, the target samples were measured using Attenuated Total Reflectance Fourier Transform Infrared (ATR FTIR) spectroscopy then compared to unablated samples of the same polymer. An analysis of the results was made with an emphasis on laser propulsion applications, with a comparison of the propulsion performance of the targets, specifically regarding the ablated mass per spot area (Δma). Chemical reaction pathways for combustion and vaporization are discussed on the basis of the differences observed in the FTIR spectra, and the consequences for using such materials as laser propulsion propellants are explored.
激光推进面临的诸多挑战之一是推进剂的长期性能。在烧蚀过程中推进剂表面发生的化学变化可以极大地改变飞行中的性能特征。为了稳定的推进机制,这种化学作用应该最小化。利用波长10.6 μm、脉冲长度300 ns、脉冲能量高达20 J的TEA (Atmospheric pressure横放电气体)CO2激光器对几种聚合物靶材进行了烧蚀,烧蚀后表面发生了一系列可观察到的化学变化。在随后的10次射击后,使用衰减全反射傅里叶变换红外(ATR)光谱对目标样品进行测量,然后与未衰减的相同聚合物样品进行比较。对结果进行了分析,重点是激光推进应用,比较了目标的推进性能,特别是关于每个光斑面积的烧蚀质量(Δma)。根据观察到的红外光谱差异,讨论了燃烧和汽化的化学反应途径,并探讨了使用激光推进推进剂等材料的后果。
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引用次数: 1
Magnetic field for efficient exhaustion of CO2 laser-produced Sn plasma in EUV light source 在极紫外光源中有效耗尽CO2激光产生的锡等离子体的磁场
Pub Date : 2008-05-08 DOI: 10.1117/12.782475
Y. Ueno, G. Soumagne, T. Suganuma, T. Yabu, M. Moriya, H. Komori, T. Abe, A. Endo, A. Sumitani
We are developing a laser produced plasma light source for high volume manufacturing (HVM) EUV lithography. The light source is based on a high power, high repetition rate CO2 laser (10.6μm) system, a tin (Sn) target and a magnetic ion guiding for Sn treatment. We evaluated the characteristics of Sn debris generated by a CO2 laser produced plasma. Experiments were performed with bulk Sn-plate targets and Mo/Si multilayer mirror samples were used for debris analysis. We observed very thin and uniform Sn layers of nano/sub-nano size debris particles. The layer deposition rate at 120mm from the plasma is, without magnetic field, about 30nm per million shots. The fast Sn ion flux was measured with Faraday cups and the signal decreased by more than 3 orders of magnitude on application of a magnetic field of 1T. The Sn deposition on the Mo/Si multilayer mirror decreased in small magnetic field space by a factor of 5. In a large magnetic field space, the effectiveness of the magnetic guiding of Sn ions is examined by monitoring the fast Sn ions. The ion flux from a Sn plasma was confined along the magnetic axis with a maximum magnetic field of 2T.
我们正在开发一种用于大批量制造(HVM) EUV光刻的激光等离子体光源。该光源基于高功率、高重复率CO2激光(10.6μm)系统、锡(Sn)靶和用于锡处理的磁离子引导。我们评估了由CO2激光产生的等离子体产生的锡碎片的特性。实验采用大块锡板靶,Mo/Si多层镜样品进行碎片分析。我们观察到非常薄且均匀的纳米/亚纳米大小的Sn碎片颗粒层。在没有磁场的情况下,距离等离子体120mm处的层沉积速率约为每百万次30nm。用法拉第杯测量了快速锡离子通量,施加1T磁场时,信号降低了3个数量级以上。在小磁场空间中,Mo/Si多层反射镜上的锡沉积减少了5倍。在较大的磁场空间中,通过对快速Sn离子的监测,考察了Sn离子磁导的有效性。锡等离子体的离子通量沿磁轴方向受限,最大磁场为2T。
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引用次数: 3
Diode pumped alkali lasers (DPALs): an overview 二极管抽运碱激光器(DPALs):概述
Pub Date : 2008-05-08 DOI: 10.1117/12.782466
W. Krupke
The concept of power-scalable, high beam-quality diode pumped alkali lasers was introduced in 2003 [Krupke, US Patent No. 6,643,311; Opt. Letters, 28, 2336 (2003)]. Since then several laboratory DPAL devices have been reported on, confirming many of the spectroscopic, kinetic, and laser characteristics projected from literature data. This talk will present an overview of the DPAL concept, summarize key relevant properties of the cesium, rubidium, and potassium alkali vapor gain media so-far examined, outline power scaling considerations, and highlight results of published DPAL laboratory experiments.
功率可扩展的高光束质量二极管抽运碱激光器的概念于2003年提出[Krupke,美国专利号6,643,311;光学通讯,28,2336(2003)]。从那时起,几个实验室DPAL装置被报道,证实了许多光谱、动力学和激光特性从文献数据预测。本讲座将概述DPAL的概念,总结目前为止所研究的铯、铷和钾碱蒸汽增益介质的关键相关特性,概述功率缩放的考虑,并重点介绍已发表的DPAL实验室实验的结果。
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引用次数: 35
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High-Power Laser Ablation
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