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Formation of nanoparticles by short and ultra-short laser pulses 短和超短激光脉冲形成纳米粒子
Pub Date : 2008-05-08 DOI: 10.1117/12.782711
K. Gouriet, T. Itina, S. Noël, J. Hermann, M. Sentis, L. Zhigilei
The main objective of this study is to explain the experimental observations. To simulate material ablation, plume formation and its evolution, we developed a combined molecular dynamics (MD) and direct simulation Monte Carlo (DSMC) computational study of laser ablation plume evolution. The first process of the material ablation is described by the MD method. The expansion of the ejected plume is modelled by the DSMC method. To better understand the formation and the evolution of nanoparticles present in the plume, we first used separate MD simulations to analyse the evolution of a cluster in the presence of background gas with different properties (density, temperature). In particular, we examine evaporation and growth reactions of a cluster with different size and initial temperature. As a result of MD calculations, we determinate the influence of the background gas parameters on the nanoparticles. The reactions rates such as evaporation/condensation, which are obtained by MD simulations, are directly transferred to the DSMC part of our combined model. Finally, several calculations performed by using MD-DSMC model demonstrate both plume dynamics and longer-time cluster evolution. Calculations results are compared with experimental findings.
本研究的主要目的是解释实验观察结果。为了模拟物质烧蚀、羽流形成及其演化过程,采用分子动力学(MD)和直接模拟蒙特卡罗(DSMC)相结合的方法对激光烧蚀羽流演化过程进行了计算研究。用MD方法描述了材料烧蚀的第一个过程。用DSMC方法模拟了喷发羽流的膨胀过程。为了更好地理解羽流中纳米颗粒的形成和演化,我们首先使用单独的MD模拟来分析具有不同性质(密度、温度)的背景气体存在下星团的演化。特别地,我们研究了不同尺寸和初始温度的团簇的蒸发和生长反应。通过MD计算,我们确定了背景气体参数对纳米粒子的影响。由MD模拟得到的蒸发/冷凝等反应速率直接传递到组合模型的DSMC部分。最后,利用MD-DSMC模型进行了一些计算,证明了羽流动力学和较长时间的簇演化。计算结果与实验结果进行了比较。
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引用次数: 2
Ultrafast laser irradiation vs cluster ion impact: molecular-dynamics comparison of materials processes in highly energized solids 超快激光照射与簇离子冲击:高能量固体中材料过程的分子动力学比较
Pub Date : 2008-05-08 DOI: 10.1117/12.784270
H. Urbassek, Christian Anders, Luis Sandoval, A. Upadhyay
The physical mechanisms and processes underlying the erosion of a surface induced by cluster bombardment or short-pulse laser irradiation are highlighted. When the average energy delivered per atom in the vicinity of the surface becomes comparable to the cohesive energy of the solid, sputtering from a so-called spike may result. Such a spike leads to abundant sputtering (surface erosion) and crater formation. Direct atomization in the region of highest energy deposition, as well as melt flow and gas flow contribute to the erosion. The materials phenomena occurring after ultra-fast laser irradiation of a metal in the ps- or fs-regime are reviewed. With increasing laser fluence, the film melts, voids are formed, the film tears (spallation), and finally fragments to form a multitude of clusters. These processes are universal in the sense that they occur in widely differing materials such as metals or van-der-Waals bonded materials. We investigate a Lennard-Jones solid as well as four different metals (Al, Cu, Ti, W), which vary widely in their cohesive energy, melting temperature, bulk modulus, and crystal structure. When the energy transfer starting the process is scaled to the cohesive energy of the material, the thresholds of these processes adopt similar values. A comparison of the similarities and differences of the mechanisms underlying surface erosion under cluster ion impact and ultrafast laser irradiation will be drawn.
强调了由簇轰击或短脉冲激光照射引起的表面侵蚀的物理机制和过程。当表面附近每个原子传递的平均能量与固体的内聚能相当时,就会产生所谓的尖峰溅射。这样的尖峰会导致大量的溅射(表面侵蚀)和陨石坑的形成。在最高能量沉积区域的直接雾化,以及熔体流动和气体流动都有助于侵蚀。综述了超快激光辐照金属在ps-或fs-态下发生的材料现象。随着激光能量的增加,薄膜熔化,形成空洞,薄膜撕裂(剥落),最后碎片形成大量的团簇。这些过程是普遍的,因为它们发生在广泛不同的材料中,如金属或范德华键合材料。我们研究了Lennard-Jones固体以及四种不同的金属(Al, Cu, Ti, W),它们在结合能,熔化温度,体积模量和晶体结构方面差异很大。当将启动该过程的能量传递缩放为材料的内聚能时,这些过程的阈值采用相似的值。比较了簇离子冲击和超快激光照射下表面侵蚀机理的异同。
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引用次数: 0
Designing laser-induced refractive index changes in "thermal" glasses 热玻璃中激光诱导折射率变化的设计
Pub Date : 2008-05-08 DOI: 10.1117/12.783449
R. Stoian, A. Mermillod-Blondin, C. Mauclair, N. Huot, É. Audouard, I. M. Burakov, N. Bulgakova, Y. P. Meschcheryakov, A. Rosenfeld, A. Husakou, I. Hertel
Ultrafast lasers emerged as promising tools to process refractive index changes in band-gap materials, resulting in waveguiding functions. Positive refractive index changes were often reported in fused silica matrices. However, in glasses characterized by slow electronic relaxation and high thermal expansion, the refractive index change is usually negative, detrimental for waveguide writing. This relates to the formation of hot regions, where, due to thermal expansion, material is quenched in low-density phases. We discuss control mechanisms related to spatio-temporal heat-source design which may be tuned by temporally shaped laser radiation. Programmable temporal tailoring of pulse envelopes triggers transitions from thermal expansion to directional inelastic flow. Consequently, material compaction leads to a positive refractive index change and guiding structures may thus be created. From an application perspective, the structuring quality degrades with the focusing depth due to wavefront distortions generated at the air-dielectric interface inducing spatial energy dispersion. Spatial beam tailoring corrects beam propagation distortion, improving the structuring accuracy. The corrective process is becoming important when laser energy has to be transported without losses at arbitrary depths, with the purpose of triggering mechanisms of positive index change.
超快激光器是处理带隙材料折射率变化的有前途的工具,从而产生波导功能。正的折射率变化经常报道熔融二氧化硅基质。然而,在以慢电子弛豫和高热膨胀为特征的玻璃中,折射率变化通常为负,不利于波导写入。这与热区的形成有关,在那里,由于热膨胀,材料在低密度相中淬火。我们讨论了与时空热源设计相关的控制机制,时空热源设计可以通过时间形状的激光辐射进行调谐。脉冲包络的可编程时间剪裁触发从热膨胀到定向非弹性流动的转变。因此,材料压实导致正折射率变化,从而可以创建导向结构。从应用角度来看,由于在空气-介质界面处产生的波前畸变引起空间能量色散,结构质量随着聚焦深度的增加而下降。空间光束裁剪可校正光束传播畸变,提高结构精度。当激光能量必须在任意深度无损失地传输时,校正过程变得越来越重要,其目的是触发正指数变化的机制。
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引用次数: 5
Equation of state of matter irradiated by short laser pulse and geometry of spalled cupola 短脉冲激光照射下的物质状态方程及剥落冲天炉的几何形状
Pub Date : 2008-05-08 DOI: 10.1117/12.782612
Y. Petrov, V. Zhakhovskiĭ, N. Inogamov, S. Ashitkov, V. Khokhlov, Arun K. Upadhyay, M. Agranat, S. Anisimov, K. Nishihara, B. Rethfeld, H. Urbassek
The motion of both Lennard-Jones solids and metals induced by ultrashort laser irradiation near the ablation threshold is investigated by molecular dynamics simulation. The universality of the ablation threshold fluence with respect to the cohesion energy of solids irradiated by femtosecond laser pulses is demonstrated for Lennard-Jones solid and metals simulated by many-body EAM potentials.
采用分子动力学模拟方法研究了超短激光辐照在烧蚀阈附近引起的Lennard-Jones固体和金属的运动。对于多体EAM势模拟的Lennard-Jones固体和金属,证明了飞秒激光脉冲辐照固体内聚能的烧蚀阈值影响的普适性。
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引用次数: 8
Correlation between early-stage expansion and spectral emission of a nanosecond laser-induced plasma from organic material 有机材料中纳秒激光诱导等离子体早期膨胀与光谱发射的关系
Pub Date : 2008-05-08 DOI: 10.1117/12.785218
M. Baudelet, Myriam G. Boueri, Jin Yu, X. Mao, R. Russo
Laser-Induced Breakdown Spectroscopy (LIBS) has been used since 40 years on typical samples such as metals, alloys, rocks. Detection of organic hazards or analysis of biological compounds under atmospheric pressure with LIBS represents a new challenge. For this purpose, we need better understandings of the physico-chemical properties of the plasma in atmosphere and their influences on the LIBS signal. As a model sample of organic materials, Nylon 6-6 has been studied under nanosecond ablation at different wavelengths (1064 nm and 266 nm) and energies (from 1 to 5 mJ) in order to observe the influence of these parameters. Shadowgraph technique is used to image the plasma at its early stage of expansion (0 to 40 ns). Time-resolved LIBS signal is recorded for longer times (50 ns to 5 μs). In the infrared regime, the expansion of the plume is faster along the laser axis, perpendicular to the sample surface. On the contrary, for UV ablation, the expansion of the plume is quite isotropic. We can also observe different regimes of expansion due to Laser-Supported Detonation Waves (LSDW) above 3 mJ in the UV regime. In particular, these observations provide us ideas to understand the kinetics of the CN emission in the LIBS signal. In the IR regime, a formation of CN due to carbon present in the sample and nitrogen in the air via the reaction 2C + N2 → 2CN can be observed. In the UV regime, the direct ablation of CN bonds is clearly seen but other effects like screening and recombination due to LSDW have also been observed.
激光诱导击穿光谱(LIBS)在金属、合金、岩石等典型样品上的应用已有40年的历史。利用LIBS检测有机危害或分析常压下的生物化合物是一个新的挑战。为此,我们需要更好地了解大气中等离子体的物理化学性质及其对LIBS信号的影响。以尼龙6-6为模型材料,在不同波长(1064 nm和266 nm)和能量(1 ~ 5 mJ)的纳秒烧蚀条件下,研究了这些参数对尼龙6-6的影响。在等离子体膨胀的早期阶段(0 ~ 40ns),采用阴影成像技术对等离子体进行成像。时间分辨LIBS信号记录时间较长(50 ns ~ 5 μs)。在红外波段,羽流沿垂直于样品表面的激光轴膨胀更快。相反,对于紫外烧蚀,羽流的膨胀是各向同性的。我们还可以观察到不同的膨胀制度,由于激光支持的爆炸波(LSDW)超过3mj的紫外制度。特别是,这些观测结果为我们理解LIBS信号中CN发射的动力学提供了思路。在红外光谱下,可以观察到样品中的碳和空气中的氮通过2C + N2→2CN反应形成CN。在紫外线下,可以清楚地看到CN键的直接消融,但也观察到其他效应,如LSDW的筛选和重组。
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引用次数: 4
Electron generation in laser-irradiated insulators: theoretical descriptions and their application 激光辐照绝缘体中的电子产生:理论描述及其应用
Pub Date : 2008-05-08 DOI: 10.1117/12.784630
B. Rethfeld, S. Linden, L. Englert, M. Wollenhaupt, L. Haag, C. Sarpe-Tudoran, T. Baumert
Transparent solids may absorb energy from a laser beam of sufficient high intensity. Several models are under consideration to describe the evolution of the free-electron density. Some of these models keep track of the energy distribution of the electrons. In this work we compare different models and give rules to estimate which one is applicable. We present the inclusion of a term in the multiple rate equation approach, recently introduced, describing fast recombination processes to exciton states. Moreover, we present experimental results with temporally asymmetric femtosecond laser pulses, impinging on a surface of fused silica. We found different thresholds for surface material modification with respect to an asymetric pulse and its time reversed counterpart. This difference is due to a different time-and-intensity dependence of the main ionization processes, which can be controlled with help of femtosecond shaped laser pulses.
透明固体可以从足够高强度的激光束中吸收能量。人们正在考虑几种模型来描述自由电子密度的演化。其中一些模型跟踪电子的能量分布。在这项工作中,我们比较了不同的模型,并给出了规则来估计哪一个是适用的。我们提出了在最近引入的多速率方程方法中包含一个术语,用于描述激子态的快速重组过程。此外,我们给出了时间不对称飞秒激光脉冲撞击熔融二氧化硅表面的实验结果。我们发现,相对于不对称脉冲及其时间反转的对应物,表面材料改性的阈值不同。这种差异是由于主要电离过程的时间和强度依赖不同,这可以通过飞秒形状的激光脉冲来控制。
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引用次数: 2
Multi-megajoule NIF: ushering in a new era in high energy density science 兆焦耳NIF:开启高能量密度科学的新时代
Pub Date : 2008-05-08 DOI: 10.1117/12.782724
E. Moses
This paper describes the status of the stadium-sized National Ignition Facility (NIF), the world's largest laser system and first operational multi-megajoule laser. The 192-beam NIF, located at Lawrence Livermore National Laboratory (LLNL), is 96% complete and scheduled for completion in March 2009. The NIF laser will produce nanosecond laser pulses with energies up to approximately 4 MJ in the infrared (laser wavelength = 1.053-μm) and 2MJ in the ultraviolet (laser wavelength = 0.35-μ m). With these energies NIF will access conditions of pressure and temperature not previously available on earth, allowing it to conduct experiments in support of the nation's national security, energy, and fundamental science goals. First ignition experiments at NIF are scheduled for FY2010. This paper will provide an overview of the NIF laser and the ignition, energy, and fundamental science activities at NIF.
本文介绍了体育场大小的国家点火装置(NIF)的现状,这是世界上最大的激光系统和第一个运行的兆焦耳激光器。位于劳伦斯利弗莫尔国家实验室(LLNL)的192束NIF已经完成了96%,计划于2009年3月完工。NIF激光器将产生纳秒激光脉冲,其红外(激光波长= 1.053-μm)和紫外(激光波长= 0.35-μ m)的能量高达约4兆焦耳,利用这些能量,NIF将进入以前在地球上无法获得的压力和温度条件,使其能够进行实验,以支持国家安全,能源和基础科学目标。NIF的首次点火实验计划在2010财年进行。本文将介绍NIF激光器的概况,以及NIF的点火、能量和基础科学活动。
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引用次数: 8
Metal colorization with femtosecond laser pulses 飞秒激光脉冲金属着色
Pub Date : 2008-05-08 DOI: 10.1117/12.782699
A. Vorobyev, Chunlei Guo
Recently, using a femtosecond laser surface structuring technique we turned highly reflective metals to highly absorptive, creating the so-called "black metals". In this study, we made an even more significant advancement. Here, we demonstrate that our femtosecond laser structuring technique not only allows us to create black metals but also gray and even color metals. We show that our technique essentially provides a controllable modification of optical properties of metals from the UV to THz spectral range via surface structuring on the nano-, micro-, and submillimeter-scales.
最近,利用飞秒激光表面结构技术,我们将高反射金属变成了高吸收金属,创造了所谓的“黑色金属”。在这项研究中,我们取得了更重大的进展。在这里,我们证明了我们的飞秒激光结构技术不仅可以让我们创造黑色金属,还可以创造灰色甚至彩色金属。我们表明,我们的技术本质上提供了一种可控的金属光学性质的修改,从紫外到太赫兹光谱范围内,通过表面结构在纳米,微,亚毫米尺度。
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引用次数: 23
Improved production of O2(a1Δ) in transverse radio-frequency discharges 改进了横向射频放电中O2的产生(a1Δ)
Pub Date : 2008-05-08 DOI: 10.1117/12.782665
B. Woodard, J. W. Zimmerman, J. Verdeyen, D. Carroll, T. Field, G. Benavides, A. Palla, W. Solomon
Experimental investigations of radio-frequency discharges in O2/He/NO mixtures in the pressure range of 1-100 Torr and power range of 0.1-2.5 kW have indicated that O2(a1Δ) production is a strong function of geometry, pressure and diluent ratio. The goal of these investigations was maximization of both the yield and flow rate (power flux) of O2(a1Δ) in order to produce favorable conditions for application to an electric oxygen-iodine laser (EOIL). As pressure is increased, yield performance is dominated by the influence of geometry and diluent ratio. Numerous measurements of O2(a1Δ), oxygen atoms, and discharge excited states are made in order to describe the discharge performance dependence on various parameters.
在压力为1 ~ 100 Torr、功率为0.1 ~ 2.5 kW的O2/He/NO混合物中射频放电的实验研究表明,O2(a1Δ)的生成是几何、压力和稀释比的重要函数。这些研究的目标是最大化O2(a1Δ)的产率和流量(功率通量),以便为应用于氧碘电激光器(EOIL)创造有利条件。随着压力的增加,产率性能主要受几何形状和稀释比的影响。对O2(a1Δ)、氧原子和放电激发态进行了大量测量,以描述对各种参数的放电性能依赖。
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引用次数: 9
Ultrashort pulse lasers applied to propulsion/control in space- and atmospheric-flight 应用于空间和大气飞行推进/控制的超短脉冲激光器
Pub Date : 2008-05-08 DOI: 10.1117/12.786468
K. Kremeyer
An impulse measurement device and analysis package was conceived, designed, constructed, tested, and demonstrated to be capable of: measuring nanoNewton-seconds to milliNewton-seconds of impulse due to laser-ablation; being transported as carry-on baggage; set-up and tear-down times of less than an hour; target exchange times of less than two minutes (targets can be ablated at multiple positions for thousands of shots); measurements in air and in vacuum; error of just a few percent; repeatability over a wide range of potential systematic error sources; and time between measurements, including ring-down and analysis, of less than 30 seconds. The instrument consists of a cantilever (i.e. leaf spring), whose time-dependent displacement/oscillation is measured and analyzed to determine the impulse imparted by a laser pulse to a target. These shapes are readily/commercially available, and any target material can be used, provided it can be fashioned in the form of a cantilever, or as a coating/film/tape, suitable for mounting on a cantilever of known geometry. The instrument was calibrated both statically and dynamically, and measurements were performed on brass, steel, and Aluminum, using laser pulses of ~7ns, ~500ps, and ~500fs. The results agree well with those published in the literature, with surface effects, atmosphere, and pre-/post-pulses demonstrating interesting effects and indicating areas for further study. In addition to exploring space-propulsion applications, measurements were performed to explore the strong beneficial effects of depositing lines of energy ahead of supersonic and hypersonic vehicles. This deposition creates a low-density channel, through which a vehicle can travel with dramatically reduced drag. Temperature and pressure are both also reduced on the front surfaces of the vehicle, while density and pressure are increased at the vehicle base. When applied off-center, this technique can be used to control the vehicle, employing the entire body as the control surface and eliminating the need for actuators. Numerical results for drag-reduction, temperature-reduction, and control forces are indicated here.
构思、设计、构建、测试并证明了脉冲测量设备和分析包能够测量激光烧蚀引起的纳牛顿秒到毫牛顿秒的脉冲;作为随身行李运输的;安装和拆卸时间少于一小时;换靶时间不超过2分钟(可在多个位置烧靶上千次);空气和真空测量;误差只有几个百分点;在大范围的潜在系统误差源上的可重复性;测量之间的时间间隔,包括振荡和分析,小于30秒。该仪器由一个悬臂梁(即钢板弹簧)组成,测量和分析其随时间变化的位移/振荡,以确定激光脉冲传递给目标的脉冲。这些形状很容易/商业上可用,并且任何目标材料都可以使用,只要它可以以悬臂的形式成型,或者作为涂层/薄膜/胶带,适合安装在已知几何形状的悬臂上。该仪器进行了静态和动态校准,并使用~7ns, ~500ps和~500fs的激光脉冲对黄铜,钢和铝进行了测量。结果与文献中发表的结果一致,地表效应、大气效应和前后脉冲都显示出有趣的效应,并指出了进一步研究的领域。除了探索空间推进应用之外,还进行了测量,以探索超音速和高超音速飞行器前方沉积能量线的强大有益效果。这种沉积形成了一个低密度的通道,通过这个通道,车辆可以大大减少阻力。车辆前表面的温度和压力都降低了,而车辆底部的密度和压力则增加了。当应用偏离中心时,该技术可用于控制车辆,采用整个车身作为控制面,消除了对执行器的需要。这里给出了减阻、降温和控制力的数值结果。
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引用次数: 2
期刊
High-Power Laser Ablation
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