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Saving energy at university campus via intervention to reduce elevator usage – a case study from Germany 通过干预减少电梯使用来节约大学校园的能源——来自德国的案例研究
Pub Date : 2023-08-30 DOI: 10.3389/frsus.2023.1196849
Friederike Gölitzer, J. Barbir, João Henrique Paulino Pires Eustachio
Recently, the need for energy saving has become a challenge for German society. Rising prices of energy, and urgent need to mitigate and adapt to climate change, made it necessary to reflect and change behaviors on a population level. Simultaneously, the population faces increased sedentary lifestyle and health system promotes benefits of daily movement and sports. By using stairs, instead of taking the elevator, could be part of the solution for both problems. This applies for buildings, such as universities, which usually have hundreds of students and staff circulating daily. In this sense, this study aims to analyse how an intervention to increase stair usage, by involving motivational stickers and posters, could impact the behavior of students and staff. To achieve its goal, a field study and a questionnaire has been conducted at one German University. The results showed, after the intervention, that the elevator usage decreased by nearly 7%. According to the questionnaire nearly a fifth of all participants felt motivated by the stickers to choose the stairs over the elevator. While before the intervention male participants were 1.76 times more likely than females to take the stairs, the difference in stair usage after the intervention was not statistically significant anymore. Individual students and staff members were 1.44 times more likely to take the stairs than when grouped with others. This difference in stair usage individually or in a group increased from nearly 8% before the intervention to 17% after the intervention. Although short, the intervention showed to be successful and the results indicated that elevator interventions should be utilized in future contexts at a population level to spread the message that by reducing elevator usage, energy can be saved, and human fitness improved.
最近,对节能的需求已经成为德国社会面临的一个挑战。能源价格的上涨,以及减缓和适应气候变化的迫切需要,使得有必要在人口层面上反映和改变行为。同时,人们面临着越来越多的久坐不动的生活方式和健康系统提倡的日常运动和运动的好处。使用楼梯而不是乘坐电梯,可能是解决这两个问题的部分方法。这适用于建筑物,如大学,通常每天有数百名学生和工作人员流动。从这个意义上讲,本研究旨在分析如何通过使用激励性贴纸和海报来增加楼梯的使用,从而影响学生和员工的行为。为了实现这一目标,在一所德国大学进行了实地研究和问卷调查。结果表明,在干预后,电梯使用率下降了近7%。根据调查问卷,近五分之一的参与者认为,这些贴纸促使他们选择走楼梯而不是电梯。而在干预之前,男性参与者走楼梯的可能性是女性的1.76倍,干预后楼梯使用的差异不再具有统计学意义。学生和教职员工单独走楼梯的可能性是集体走楼梯的1.44倍。个人或团体使用楼梯的差异从干预前的近8%增加到干预后的17%。虽然时间很短,但干预措施是成功的,结果表明,电梯干预措施应该在未来的人口层面上加以利用,以传播通过减少电梯的使用,可以节省能源,提高人类健康的信息。
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引用次数: 0
A new generation of consumers? A study on the pro-environmental behavior of the Fridays for Future generation based on the social identity approach 新一代消费者?基于社会认同方法的“未来一代星期五”亲环境行为研究
Pub Date : 2023-08-29 DOI: 10.3389/frsus.2023.1231731
Verena Bauernschmidt, Beatrice Beitz, Hendrik Schröder
Especially for the younger generation, climate change is a threat, and therefore, environmental protection and pro-environmental behavior (PEB) are most important. The Fridays for Future movement speaks up for the young generation. Based on the social identity approach, the study is the first to investigate the role of stereotypes related to identification with the movement as a political expression of youth. Using structural equation modeling (n = 543), the study demonstrates that identification is higher when pupils connect the movement with positive stereotypes, aligning with previous research findings for other activists, such as feminists. Whereby environmental concern has an additionally significant but low impact on identification, pro-material value orientation has no effect. Furthermore, the study investigates the relationship between identification with the movement and different types of PEB. The relationship is strongest with public sphere PEB in the form of future participation in a demonstration of the movement. Nevertheless, there is also a positive relationship with private sphere PEB such as nature-compatible actions in everyday life, for example, a meat-free diet and buying an environmentally friendly product. This is partly additionally confirmed through a conjoint analysis also conducted as part of the study. These findings enhance the understanding of the relationship between activism and different types of PEB among pupils and they contribute to closing this research gap. Finally, the implications and limitations of the work are discussed, along with an outlook for future research.
特别是对年轻一代来说,气候变化是一种威胁,因此,环境保护和亲环境行为(PEB)是最重要的。周五未来运动为年轻一代发声。基于社会认同方法,该研究首次调查了与运动认同相关的刻板印象作为青年政治表达的作用。利用结构方程模型(n = 543),该研究表明,当学生将该运动与积极的刻板印象联系起来时,认同度更高,这与之前对其他活动家(如女权主义者)的研究结果一致。其中,环境关注对识别有显著影响,但影响较小,亲物质价值取向没有影响。此外,本研究还探讨了运动认同与不同类型PEB之间的关系。与公共领域PEB的关系以未来参与运动示威的形式最为密切。然而,与私人领域的PEB也有积极的关系,例如日常生活中的自然兼容行为,例如,无肉饮食和购买环保产品。作为研究的一部分,另一项联合分析也部分地证实了这一点。这些发现增强了对学生行动主义与不同类型的PEB之间关系的理解,并有助于缩小这一研究差距。最后,讨论了研究的意义和局限性,并对未来的研究进行了展望。
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引用次数: 0
A conceptual model to measure and manage the implementation of green initiatives at South African public universities 一个衡量和管理南非公立大学绿色倡议实施的概念模型
Pub Date : 2023-08-24 DOI: 10.3389/frsus.2023.1237514
Lelo Tshivhase, C. Bisschoff
The growing need for environmental awareness accentuated the importance of green and sustainable business practices. This is also true for universities that modernly expanded their green training and research to engage in green operational practices.This article summarises the main principles and factors of implementing green initiatives. Firstly, a generic theoretical approach conceptualizes implementing green initiatives at universities. The investigation analyses existing and current green initiatives at the universities, considers the benefits and barriers of implementing green initiatives, and develops a theoretical model for implementing green initiatives at South African public universities. An adapted conceptual model consisting of twenty significant literature antecedents (p ≤ 0.05) and 13 latent variables (factors) could be hypothesized. This model was tested empirically with reliable data (α = 0.749) from a five-point Likert scale questionnaire administered to 144 responding green managers at eight selected South African public universities.Although the regression model explains satisfactory variance (R2 = 0.862; R2 adjusted = 0.841), only five of the 20 antecedents in the theoretical model are significant. They are Cost of green products (r = 0.527; p ≤ 0.05), Lack of awareness and training (r = 0.435; p ≤ 0.05), Managerial attitude and commitment (r = 0.369; p ≤ 0.05), Digitisation (r = 0.552; p ≤ 0.05), and Management Committee (r = 0.451; p ≤ 0.05). Further analysis revealed that the data possess embedded intelligence. Resultantly, 13 factors were identified, explaining a cumulative variance of 61.8%. However, only six factors are reliable and, therefore, usable (α ≥ 0.57). They are F1: Convenience and efficient workflow, F2: Personnel cooperation, F3: Efficient use of resources, F5: Learning and improvement, F6: Delegation of authority, and F7: Improved management attitude. Cumulatively, the six usable factors explain a cumulative variance of 45.5%.The model aspires to demonstrate and measure the implementation of green initiatives at public universities. Although the theoretical model is detailed, the empirical study showed that not all of the antecedents are usable for measuring and managing the implementation of green initiatives at South African public higher institutions. This study validated five of the antecedents and six factors for immediate use. The model's unvalidated antecedents and unreliable factors require empirical revalidation before operationalizing it fully. Researchers and scholars exploring this avenue of green initiatives implementation models can also benefit from this article.
对环境意识的日益增长的需要突出了绿色和可持续商业做法的重要性。对于那些将绿色培训和研究扩展到绿色运营实践的大学来说,情况也是如此。本文总结了实施绿色倡议的主要原则和因素。首先,一个通用的理论方法概念化在大学实施绿色倡议。该调查分析了大学现有的和当前的绿色倡议,考虑了实施绿色倡议的好处和障碍,并为南非公立大学实施绿色倡议开发了一个理论模型。一个由20个显著文献前因(p≤0.05)和13个潜在变量(因子)组成的适应性概念模型可以假设。该模型用可靠的数据(α = 0.749)进行了实证检验,这些数据来自于对8所选定的南非公立大学的144名绿色管理者进行的五点李克特问卷调查。虽然回归模型解释了令人满意的方差(R2 = 0.862;R2调整= 0.841),理论模型中20个前因中只有5个显著。分别是绿色产品成本(r = 0.527;p≤0.05),缺乏意识和培训(r = 0.435;p≤0.05)、管理态度与承诺(r = 0.369;p≤0.05),数字化(r = 0.552;p≤0.05),管理委员会(r = 0.451;P≤0.05)。进一步分析表明,这些数据具有嵌入式智能。结果,确定了13个因素,解释了61.8%的累积方差。然而,只有6个因素是可靠的,因此是可用的(α≥0.57)。F1:便捷高效的工作流程,F2:人员合作,F3:资源的高效利用,F5:学习和改进,F6:授权,F7:改进的管理态度。累积起来,这六个可用因素解释了45.5%的累积方差。该模型旨在展示和衡量公立大学实施绿色倡议的情况。虽然理论模型是详细的,但实证研究表明,并非所有的前因都可用于衡量和管理南非公立高等院校绿色倡议的实施。本研究验证了五个先行项和六个直接使用的因素。该模型的未验证的前提和不可靠的因素需要在充分操作之前进行经验再验证。探索绿色倡议实施模式的研究人员和学者也可以从本文中受益。
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引用次数: 1
Enhancing the value of comparative exposure assessment in alternatives assessment 提高比较暴露评估在替代方案评估中的价值
Pub Date : 2023-08-24 DOI: 10.3389/frsus.2023.983218
Q. Meng, Xiaoying Zhou
Reducing chemical exposure is a crucial principle in alternatives assessment (AA) frameworks. Since the release of the report, A Framework to Guide Selection of Chemical Alternatives by the National Research Council in 2014, comparative exposure assessment (CEA) has been increasingly viewed as an essential part of selecting safer alternatives to chemicals of concern in consumer products. However, CEA has not been fully integrated into existing AA frameworks. CEA remains merely a technical step, disconnected from other AA components. This paper advocates for the integration of CEA as an essential part of AA, providing a holistic approach to identifying safer alternatives. The paper aims to illustrate the connection between CEA and other AA components, such as problem formulation, hazard assessment, life cycle assessment, economic assessment, and decision-making. It suggests systematic integration of CEA with cross-cutting AA considerations, including transparency, uncertainty, chemical mixtures, and sensitive receptors. This integration will enable the selection of a fit-for-purpose CEA approach based on the decision context and foster a more comprehensive approach to identifying safer alternatives. While the examples provided are not exhaustive, they aim to encourage further discussion on the integration of CEA into AA.
减少化学品接触是替代品评估框架中的一个关键原则。自2014年美国国家研究委员会发布《化学替代品选择指导框架》报告以来,比较暴露评估(CEA)越来越被视为选择更安全的消费品化学品替代品的重要组成部分。然而,CEA并没有完全集成到现有的AA框架中。CEA仍然只是一个技术步骤,与其他AA组件无关。本文主张将CEA整合为AA的重要组成部分,提供一种整体方法来确定更安全的替代方案。本文旨在说明CEA与AA其他组成部分(如问题制定、危害评估、生命周期评估、经济评估和决策)之间的联系。它建议将CEA与跨领域AA考虑系统整合,包括透明度、不确定度、化学混合物和敏感受体。这种集成将使基于决策上下文的适合目的的CEA方法得以选择,并促进更全面的方法来确定更安全的替代方案。虽然所提供的例子并不详尽,但它们旨在鼓励进一步讨论将CEA整合到AA中。
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引用次数: 0
Connection to nature for sustainable development at universities—What should be done? 大学与自然的联系促进可持续发展——应该做些什么?
Pub Date : 2023-08-22 DOI: 10.3389/frsus.2023.1249328
M. Kleespies, P. Dierkes
Universities and institutions of higher education play an important role in today's society. They educate the next generation of decision-makers and therefore have a great influence on the decisions made in society. In today's world, where many people's livelihoods are threatened by environmental issues, it is not only necessary for universities to operate sustainably, but also to motivate students to adopt more sustainable behaviors. We believe that promoting a connection to nature is an important starting point for this, as it is a key influencing factor for sustainable behavior. Due to decreasing contact with nature and increasing urbanization worldwide, connection to nature is currently in decline. In this perspective, we propose six starting points that can help increase the connection to nature of university students: (1) Bringing students to nature, (2) bringing nature to students, (3) environmental education, (4) virtual nature contact, (5) incorporating other human-nature relationships and concepts (6) combining 1–5. For each point, we explain possible recommendations for university decision-makers.
大学和高等教育机构在当今社会中扮演着重要的角色。他们教育下一代决策者,因此对社会决策有很大的影响。在当今世界,许多人的生计受到环境问题的威胁,大学不仅需要可持续经营,而且还需要激励学生采取更可持续的行为。我们认为,促进与自然的联系是一个重要的起点,因为它是可持续行为的关键影响因素。由于与自然接触的减少和全球城市化的增加,与自然的联系目前正在减少。从这个角度来看,我们提出了有助于增加大学生与自然联系的六个出发点:(1)将学生带到自然中,(2)将自然带给学生,(3)环境教育,(4)虚拟自然接触,(5)融入其他人与自然的关系和概念,(6)结合1 - 5。对于每一点,我们都向大学决策者解释了可能的建议。
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引用次数: 0
Dark side of resilience: systemic unsustainability 弹性的阴暗面:系统性的不可持续性
Pub Date : 2023-08-22 DOI: 10.3389/frsus.2023.1241553
J. Lyytimäki, A. Teperi, K. Jylhä, Ricardo da Silva Vieira, Erkki Mervaala
Resilience is often presented as a championing solution for tackling the multi-level environmental, security, health, and financial threats facing the whole humanity or specific ecosystems, communities, institutions, or individuals. However, the popularity of the concept is not proof of its usefulness. Perhaps the greatest problem is that many of the current socio-ecological systems are operating in both resilient and unsustainable ways. The problem turns into a tragedy if resources are used to maintain or advance such unsustainable resilience. We provide a concise review of the use of the concept of resilience in multiple fields. We highlight the dominance of positive connotations of resilience, originating both from theoretical considerations and practice-oriented applications. This optimistic bias masks the fact that unsustainable systems and practices may be highly resilient. In turn, this can lead to poor understanding and inadequate management of risks related to the attempts to create sustainability innovations. We discuss how path-dependencies and shifting baselines can complicate sustainability initiatives. Managing resilience for sustainability involves defining which system states are desirable and managing the pressures that maintain desired and undesired system states. Our conclusion is that active efforts aimed for maintaining resilience should be initiated only if a thorough assessment has shown that the system under consideration can function in a sustainable way.
弹性通常被认为是解决全人类或特定生态系统、社区、机构或个人面临的多层次环境、安全、健康和金融威胁的首要解决方案。然而,这个概念的流行并不能证明它的有用性。也许最大的问题是,当前许多社会生态系统的运行方式既有弹性又不可持续。如果资源被用来维持或推进这种不可持续的韧性,问题就会变成一场悲剧。我们提供了一个简明的回顾使用弹性的概念在多个领域。我们强调了弹性的积极内涵的主导地位,源于理论考虑和面向实践的应用。这种乐观的偏见掩盖了一个事实,即不可持续的系统和做法可能具有很强的复原力。反过来,这可能导致对与创造可持续性创新的尝试有关的风险理解不足和管理不足。我们讨论了路径依赖和基线变化如何使可持续性倡议复杂化。管理可持续性的弹性包括定义哪些系统状态是理想的,以及管理维持理想和不希望的系统状态的压力。我们的结论是,只有在彻底的评估表明所考虑的系统能够以可持续的方式运作时,才应该开始积极努力,以保持弹性。
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引用次数: 0
The CIRCULAR pathway: a new educational methodology for exploratory circular value chain redesign 循环路径:探索循环价值链再设计的新教育方法
Pub Date : 2023-08-15 DOI: 10.3389/frsus.2023.1197659
Cris Garcia-Saravia Ortiz-de-Montellano, A. Ghannadzadeh, Yvonne van der Meer
The circular economy (CE) is gaining global relevance across countries and institutions as a tool to solve some of the most pressing global challenges derived from linear production and consumption systems. However, transitioning to a CE requires significant changes in how businesses and supply chains operate, including redesigning products, processes, and business models. These changes require that future professionals acquire knowledge and skills on the principles of CE, Life Cycle Thinking, and Systems Thinking. However, research on existing higher education programs signals a need for educational resources to develop these skills and knowledge in real-world settings. This paper outlines a new eight-step methodology to introduce students to the principles of CE through the exploratory redesign of a real-world product and value chain in a project-centered learning environment. This methodology was developed in four iterations and was used to teach 251 students from the BSc. Business Engineering at Maastricht University during the academic years 2020–2022. The findings indicate that this method supports students' understanding of complexity, linearity, and the importance of systemic change across the entire value chain, as well as their critical thinking, problem-solving, and decision-making skills. The methodology provided in this paper supports and encourages educational bodies to implement Education for CE in their curricula and further strengthens the complementary fields of Education for Environmental Sustainability and Education for Sustainable Development. Furthermore, educators, professionals and businesses can make use of this tested methodology for exploratory product redesign toward sustainable circularity transitions.
作为解决线性生产和消费系统所带来的一些最紧迫的全球挑战的工具,循环经济正在各国和各机构之间获得全球相关性。然而,向CE过渡需要对业务和供应链的运作方式进行重大改变,包括重新设计产品、流程和业务模型。这些变化要求未来的专业人员掌握有关CE、生命周期思维和系统思维原则的知识和技能。然而,对现有高等教育项目的研究表明,在现实世界中发展这些技能和知识需要教育资源。本文概述了一种新的八步方法,通过在以项目为中心的学习环境中对现实世界的产品和价值链进行探索性重新设计,向学生介绍企业环境管理的原则。该方法经过四次迭代开发,并用于教授来自理学士的251名学生。2020-2022学年马斯特里赫特大学商业工程专业。研究结果表明,这种方法有助于学生理解整个价值链的复杂性、线性和系统性变化的重要性,以及他们的批判性思维、解决问题和决策能力。本文提供的方法支持和鼓励教育机构在其课程中实施行政教育,并进一步加强环境可持续发展教育和可持续发展教育的互补领域。此外,教育工作者、专业人士和企业可以利用这种经过测试的方法对产品进行探索性的重新设计,以实现可持续的循环过渡。
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引用次数: 0
Designing circular innovation ecosystems: insights from stakeholders, values, and investment policies 设计循环创新生态系统:来自利益相关者、价值观和投资政策的见解
Pub Date : 2023-08-14 DOI: 10.3389/frsus.2023.1197688
A. Asgari, R. Asgari
Adopting the circular economy principles as a solution to overcome the challenges of the linear economy is increasing globally. In this regard, the related studies showed that circularity is a property of systems, not individual entities. Therefore, any ecosystem design process, including the implementation of circular innovation ecosystems (CIEs), needs in-depth and comprehensive insights into the design process, transformation of ecosystem components, and transition requirements toward circular ecosystems. This study utilized a two-step research methodology consisting of a systematic literature review on sustainable innovation ecosystems and CIEs alongside using grounded theory coding procedures to analyze 10 interviews based on an analytical ecosystem modeling tool to investigate the transformation of ecosystem components in circular ecosystems. Our findings illustrated that circular ecosystem design needs ecosystem actors' synchronic and incremental evolvement. The results also showed that implementing the CIEs requires broader networks of stakeholders, a new interactive economic model, an open platform for co-innovation and co-creation, transforming ecosystem value propositions, and defining new investment models and policies. The findings also inform policymakers and ecosystem researchers about the requirements of any transition toward CE ecosystems. Accordingly, proper policy-making structures and models for tackling transformation obstacles are provided.
采用循环经济原则作为克服线性经济挑战的解决方案在全球范围内正在增加。在这方面,相关研究表明,循环性是系统的属性,而不是单个实体的属性。因此,任何生态系统设计过程,包括循环创新生态系统(CIEs)的实施,都需要深入全面地了解设计过程、生态系统组件的转换以及向循环生态系统的过渡要求。本研究采用两步研究方法,包括对可持续创新生态系统和CIEs的系统文献综述,以及基于分析生态系统建模工具的扎根理论编码程序,分析了10个访谈,以研究循环生态系统中生态系统成分的转化。我们的研究结果表明,循环生态系统设计需要生态系统参与者的同步和增量进化。研究结果还表明,实施CIEs需要更广泛的利益相关者网络、新的互动经济模式、共同创新和共同创造的开放平台、转变生态系统价值主张以及定义新的投资模式和政策。研究结果还为政策制定者和生态系统研究人员提供了向CE生态系统过渡的要求。因此,提供了处理转型障碍的适当决策结构和模式。
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引用次数: 0
Transitioning toward sustainable consumption at the Swedish local governance level 在瑞典地方治理层面向可持续消费过渡
Pub Date : 2023-08-10 DOI: 10.3389/frsus.2023.1196373
K. Axelsson, Karin André, E. Dawkins, Åsa Gerger Swartling, Maria Xylia
Municipalities have a prominent role to play in the transition to the sustainable society by governing changes at the local level. Based on a quantitative survey of Swedish municipalities, this study has given us a broad perspective on barriers and enablers in Swedish municipalities' efforts to plan, develop, and implement measures for governing the transition to sustainable consumption. By using a classification of municipalities belonging to certain groups, we find that municipalities characterized by having a city at their cores seem to have progressed further in their work to address sustainable consumption than municipalities characterized as more rural or as commuting municipalities near cities or towns. We also find that, though a large share of municipalities in Sweden report working systematically on sustainable consumption, their potential appears to not be fully realized, limited primarily by a lack of political support and key resources. We identify opportunities to establish more responsive governance structures as important for addressing these issues, where interactions at multiple levels are required to achieve successful governance of Sweden's work on sustainable consumption and address the barriers identified by this study. Higher levels of governance should offer greater support and guidance to municipalities in their work. We also advocate for more robust collaborations between municipalities to prevent them from working in isolation, build capacity, and foster greater knowledge exchange between municipality groups. This would strengthen municipalities' ability to catalyze transformational change, which is crucial if they are to meet their own high ambitions related to sustainable consumption and help institute the changes needed to enable the fulfillment of the long-term sustainability challenges we face, such as those articulated in the Paris Agreement and the 2030 Agenda for Sustainable Development.
市政当局可以通过管理地方一级的变革,在向可持续社会过渡的过程中发挥突出作用。基于对瑞典市政当局的定量调查,本研究为我们提供了一个广泛的视角,了解瑞典市政当局在规划、制定和实施管理向可持续消费过渡的措施方面的障碍和推动因素。通过对属于某些群体的城市进行分类,我们发现,以城市为核心的城市在解决可持续消费问题方面的工作似乎比以农村或城市或城镇附近的通勤城市为特征的城市取得了进一步的进展。我们还发现,虽然瑞典有很大一部分市政当局报告系统地开展可持续消费工作,但它们的潜力似乎没有得到充分实现,主要受到缺乏政治支持和关键资源的限制。我们确定了建立更具响应性的治理结构的机会,这对解决这些问题很重要,需要在多个层面上进行互动,以实现瑞典可持续消费工作的成功治理,并解决本研究确定的障碍。更高层次的治理应该对市政工作提供更多的支持和指导。我们还主张加强市政当局之间的合作,以防止它们孤立开展工作,建设能力,并促进市政当局团体之间更多的知识交流。这将加强市政当局促进转型变革的能力,如果市政当局要实现自己在可持续消费方面的宏伟目标,并帮助实施必要的变革,以应对我们面临的长期可持续性挑战,例如《巴黎协定》和《2030年可持续发展议程》所阐述的挑战,这一点至关重要。
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引用次数: 0
Techno-economic analysis of the co-gasification of sewage sludge and petroleum coke 污水污泥与石油焦共气化的技术经济分析
Pub Date : 2023-08-09 DOI: 10.3389/frsus.2023.1234760
I. Adeyemi, Haider Khan, C. Ghenai, I. Janajreh
In this study, the co-gasification of sewage sludge and petroleum coke is assessed with equilibrium and numerical modeling. The gasification process of these binary wastes provides a potential pathway for waste management and environmental sustainability. First, the thermodynamic equilibrium approach is used to calculate the maximum cold gasification efficiency (CGE) at different mixture ratios in an attempt to narrow down and focus on the appropriate composition of the two kinds of feedstock within the entrained flow gasifier. Furthermore, a parametric study is conducted to show the gasification metrics, i.e., CGE and feedstock conversion, and the syngas composition at different gasification conditions. The equilibrium model is based on eight unknowns in the gasification product, namely, H2, CO, CO2, H2O, CH4, O2, Csolid, and the temperature, under variable O2 and H2O molar ratios. Using three elemental mass balances, four equilibrium (Csolid) constant relations, and energy balance, the mathematical model is developed. The model incorporates the solid unburnt carbon in the product species. The temperature of gasification is determined through an iterative process. Using the result of the equilibrium model, a high-fidelity reactive flow model that accounts for the reactor geometry and the devolatilization kinetics is developed. This model accounts for an extended set of reactions covering the char combustion, water and gas shifts, Boudouard and devolatilization. Finally, economic analysis is carried out to assess the conditions when such a process can be deemed to be profitable. The result of the model shows that the maximum CGE is achieved when all the solid carbon is converted into carbon monoxide with nearly all hydrogen present in the feedstock converted into hydrogen gas. The maximum conversion was attained with sewage sludge and petroleum coke ratio of 1 at 1,200°C. The mole fraction of the syngas species obtained is XH2 = 0.4227 and XCO = 0.5774 and a small fraction of XCH4 = 0.0123. Moreover, the cold gasification efficiency (CGE) measures 87.02% for the H2 and CO syngas species and reached 91.11% for the three species, including CH4. The gasification of the sewage sludge and petroleum coke at 50:50 is economically viable at temperatures higher than 950°C. A peak net gain of 0.16 $/kg of fuel blend was achieved at 1,250°C. At temperatures lower than 950°C, net losses were realized. This could be associated with less product gas yield, which is not significant enough to counteract the input costs. For instance, the net losses were −0.03 and −0.17 $/kg of feedstock at 950 and 800°C, respectively.
本文采用平衡法和数值模拟方法对污水污泥与石油焦共气化过程进行了评价。这些二元废物的气化过程为废物管理和环境可持续性提供了一条潜在的途径。首先,采用热力学平衡方法计算不同混合比下的最大冷气化效率(CGE),试图缩小并关注夹带流气化炉内两种原料的适当组成。此外,还进行了参数化研究,以显示不同气化条件下的气化指标,即CGE和原料转化率,以及合成气组成。平衡模型是基于气化产物中H2、CO、CO2、H2O、CH4、O2、Csolid和温度这8个未知量,在不同O2和H2O的摩尔比下建立的。利用三元素质量平衡、四平衡(固体)常数关系和能量平衡建立了数学模型。该模型将未燃烧的固体碳纳入产品种类。气化温度是通过一个迭代过程确定的。利用平衡模型的结果,建立了考虑反应器几何和脱挥发动力学的高保真反应流模型。该模型解释了一组扩展的反应,包括炭燃烧,水和气体的转移,Boudouard和脱挥发。最后,进行经济分析,以评估这种过程可以被认为是有利可图的条件。模型结果表明,当所有固体碳都转化为一氧化碳,而原料中几乎所有的氢都转化为氢气时,CGE达到最大。在1200℃条件下,污泥与石油焦的比例为1,转化率最高。所得合成气的摩尔分数为XH2 = 0.4227, XCO = 0.5774,小部分XCH4 = 0.0123。H2和CO合成气的冷气化效率(CGE)为87.02%,3种合成气(包括CH4)的冷气化效率为91.11%。在高于950℃的温度下,以50:50的比例气化污水污泥和石油焦在经济上是可行的。在1,250°C时,燃料混合物的峰值净收益为0.16美元/公斤。在低于950°C的温度下,实现了净损失。这可能与较低的产品气产量有关,这不足以抵消投入成本。例如,在950°C和800°C时,每公斤原料的净损失分别为- 0.03美元和- 0.17美元。
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Frontiers in Sustainability
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