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Foam Stability Enhanced Technology For Mobility Control Of CO2 EOR 提高泡沫稳定性的CO2 EOR流动性控制技术
Pub Date : 2018-11-21 DOI: 10.3997/2214-4609.201802982
H. Yonebayashi, Katsumo Takabayashi, Y. Miyagawa, Takumi Watanabe
ery and prevention of early breakthrough. From CCUS point of views, the delay of gas breakthrough has a significant advantage in underground storage of industry-originated CO2. The reviews highlighted that various types of nano-additives have been investigated to develop further advanced foam technology. Key points to be focused on are how achieving more robust foam stability. Even a conventional CO2 foam generated with surfactant agents might be deteriorated in short period, those additives can extend foam half-life time. As additives, the recent researches have paid attention to nano-particles, polymer, viscoelastic surfactant, etc. The investigation measured half-life, viscosity, and differential pressure in core flood as key performance indicators. In addition, “high temperature (HT)” and “high salinity (HS)” are keywords in their researches. Namely, screening criteria of experimental conditions are aiming to more harsh conditions. However, the reviewed reports have not covered up to our target conditions in typical Middle East region. Thus, we have been concentrating to develop nano-additive enhancing CO2 foam technology in HTHS.
Ery和预防早期突破。从CCUS的角度来看,天然气突破的延迟在工业二氧化碳的地下储存中具有显著的优势。综述强调了各种类型的纳米添加剂的研究,以进一步发展先进的泡沫技术。重点是如何实现更坚固的泡沫稳定性。使用表面活性剂生成的常规CO2泡沫也会在短时间内变质,而这些添加剂可以延长泡沫的半衰期。作为添加剂,近年来的研究主要集中在纳米颗粒、聚合物、粘弹性表面活性剂等。该研究测量了岩心注水的半衰期、粘度和压差作为关键性能指标。此外,“高温(HT)”和“高盐度(HS)”是他们研究的关键词。即实验条件的筛选标准是针对更苛刻的条件。然而,经过审查的报告并没有涵盖我们在典型中东地区的目标情况。因此,我们一直致力于开发纳米添加剂增强二氧化碳泡沫技术。
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引用次数: 1
CO2 Flow, Alteration And Geomechanical Response In Confining Units – An Experimental Approach 围封单元中的CO2流动、蚀变和地质力学响应——一种实验方法
Pub Date : 2018-11-21 DOI: 10.3997/2214-4609.201802959
E. Skurtveit, Anja Sundal, M. Soldal, G. Sauvin, T. Bjørnarå
Seal integrity during injection operations is a topic of great interest both within the CO2 storage community, for wastewater injection and traditional reservoir pressure support. The Little Grand Wash fault, central Utah, USA, provides an excellent location for studying seal bypass systems in a siliciclastic sedimentary sequence. Two mode I siltstone fractures with significantly different apertures and varying degree of sample bleaching due to alterations from reactive fluid flow are studied together with two intact rock reference samples from the same depth level in the core. The experimental work addresses fracture flow and stiffness relationships. Observed differences in fracture closure trends may be explained as a rapid decrease in stiffness and flow for altered samples due to the fluid rock interaction process altering the fracture surface contact area for this sample.
注入作业期间的密封完整性是二氧化碳储存界、废水注入界和传统油藏压力支持界非常感兴趣的话题。美国犹他州中部的小大沃什断层为研究硅屑沉积层序中的密封旁通系统提供了一个绝佳的位置。利用岩心同一深度的2个完整岩石参考样品,研究了2条孔径差异明显、样品因反应性流体变化而发生不同程度白化的ⅰ型粉砂岩裂缝。实验工作解决了断裂流动和刚度的关系。观察到的裂缝闭合趋势的差异可以解释为,由于流体与岩石的相互作用过程改变了该样品的裂缝表面接触面积,改变后样品的刚度和流量迅速下降。
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引用次数: 0
Identifying Hidden Risk Elements For CO2 Storage From Reprocessed Seismic Data 从再处理地震数据中识别二氧化碳储存的潜在风险因素
Pub Date : 2018-11-21 DOI: 10.3997/2214-4609.201802950
S. Carpentier, H. Abidin, P. Steeghs, H. Veldkamp
CO2 storage needs economic business cases through cost-effective exploration and production and needs license-to-operate through public support. Re-interpretation and reprocessing of vintage geophysical data is a means to achieve cost-effective exploration whereas de-risking and conformance control of storage operations is a means to obtain public support. Seismic exploration should identify risk elements for CO2 storage such as the risk of leakage, risk of pressure build-ups or drops, unexpected increase or decrease of storage capacity and spill points to name a few. These risks elements are often caused by hidden features such as a failing overburden seal, closed or open faults in either reservoir or seal and high- or low-permeability streaks in the reservoir. We have investigated a seismic reprocessing workflow for imaging and de-risking CO2 storage reservoirs and seals. The workflow includes statics, demultiple, velocity modeling, Prestack Time Migration, high resolution sparse spike deconvolution and Non Local Means filtering. Non Local Means filtering increases signal to noise ratio while preserving edges and the sparse spike deconvolution produces results with superior vertical and lateral resolution. This workflow manages at low cost to considerably de-risk the CO2 storage reservoirs and seals by identifying previously hidden faults, seal-reservoir contacts and thin reservoir streaks. © 2018 European Association of Geoscientists and Engineers, EAGE. All rights reserved.
二氧化碳储存需要通过具有成本效益的勘探和生产来实现经济的商业案例,并需要通过公共支持获得运营许可证。古地球物理数据的重新解释和再处理是实现经济有效勘探的一种手段,而存储操作的降低风险和一致性控制是获得公众支持的一种手段。地震勘探应确定二氧化碳储存的风险因素,如泄漏风险、压力上升或下降的风险、储存能力的意外增加或减少以及泄漏点等。这些风险因素通常是由隐蔽特征引起的,如覆盖层密封失效、储层或密封中的闭合或张开断层、储层中的高渗透或低渗透条纹。我们研究了一种地震再处理流程,用于成像和降低二氧化碳储层和密封的风险。工作流包括静态、解多重、速度建模、叠前时间偏移、高分辨率稀疏尖峰反卷积和非局部均值滤波。非局部均值滤波在保留边缘的同时增加信噪比,稀疏尖峰反褶积产生具有优越的垂直和横向分辨率的结果。该工作流程通过识别以前隐藏的断层、密封-储层接触面和薄储层条纹,以低成本大大降低了二氧化碳储层和密封的风险。©2018欧洲地球科学家和工程师协会,EAGE。版权所有。
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引用次数: 0
Quantifying The Risk Of CO2 Leakage Along Fractures Using An Integrated Experimental, Multiscale Modelling And Monitoring Approach 利用综合实验、多尺度建模和监测方法量化CO2沿裂缝泄漏的风险
Pub Date : 2018-11-21 DOI: 10.3997/2214-4609.201802963
K. Bisdom, M. Dean, J. Snippe, N. Kampman, A. Busch, S. Zihms, F. Doster, R. March, P. Bertier, H. Claes, R. Fink, B. Krooss, S. Hurst, A. Lidstone, P. V. Rossum
To verify and demonstrate successful long-term geological CO2 storage to regulatory bodies and the public, it is critical to improve our understanding of the potential for CO2 migration from storage reservoirs along natural pathways. Currently, there are significant gaps in our understanding of multi-phase fluid migration in faulted and fractured caprocks. Caprocks are typically fine-grained mudstones, carbonates or evaporites, with low matrix permeability and high geochemical reactivity. Potential leakage rates depend on pressure gradients, fluid densities, viscosities and saturations, and the flow properties of the fracture networks. Fracture permeability is highly sensitive to fluid pressure and stress regime, and physical and chemical interactions taking place in the fracture network, including mineral dissolution and precipitation, swelling or shrinkage of clay minerals and hydro-mechanically driven fracture propagation. These combined effects can result in an increase or decrease in fracture permeability and network connectivity over different temporal and spatial scales. The highly coupled nature of these processes makes experimental parameterization and predictive modelling highly challenging, especially at the large temporal and spatial scales relevant to CO2 storage. Although some fundamental laboratory and modelling studies are available in the literature, an integrated study, involving a complete life cycle risk assessment of CO2 leakage through fractured caprocks is lacking. Risk analysis is further complicated by the fact that a leak can only be detected and quantified when geophysical or chemical monitoring tools are able to distinguish relevant changes in gas saturation, pressures or compositions compared to baseline levels. The DETECT research program, cofunded by the European Union and national governments as part the ACT initiative, intends to determine realistic flow rates across fractured and faulted mudstone caprocks, and aims to identify existing monitoring tools capable of detecting such fluid migration. For this purpose, the monitoring performance of state-of-the-art technologies will be compared with flow rate predictions from coupled hydro-mechanical flow and reactive transport simulations at single fracture, fracture network and reservoir-scales, which in turn have incorporated insights from a comprehensive laboratory study of stress and reactivity dependent fracture permeability. This improved understanding of the potential flow rates will feed into an integrated life cycle risk assessment using the established bowtie method to provide an overall picture of the natural paths via which CO2 leaks could occur from subsurface storage reservoirs. The bowtie model will be expanded to include quantitative risk assessment, with the goal of calculating the probability/likelihood of leakage across the caprock and estimating the risk reduction provided by monitoring.
为了向监管机构和公众验证和展示成功的长期地质二氧化碳储存,提高我们对二氧化碳从储存水库沿自然途径迁移的潜力的理解至关重要。目前,我们对断裂盖层多相流体运移的认识还存在较大的空白。盖层通常为细粒泥岩、碳酸盐岩或蒸发岩,基质渗透率低,地球化学反应性强。潜在的泄漏速率取决于压力梯度、流体密度、粘度和饱和度以及裂缝网络的流动特性。裂缝渗透率对流体压力和应力状态以及裂缝网络中发生的物理和化学相互作用高度敏感,包括矿物溶解和沉淀、粘土矿物的膨胀或收缩以及水力驱动的裂缝扩展。在不同的时间和空间尺度上,这些综合效应会导致裂缝渗透率和网络连通性的增加或减少。这些过程的高度耦合性质使得实验参数化和预测建模极具挑战性,特别是在与二氧化碳储存相关的大时空尺度上。尽管文献中有一些基础的实验室和模型研究,但缺乏一项涉及裂缝盖层CO2泄漏的完整生命周期风险评估的综合研究。只有当地球物理或化学监测工具能够区分出与基线水平相比的气体饱和度、压力或成分的相关变化时,才能检测和量化泄漏,这使得风险分析更加复杂。DETECT研究项目由欧盟和各国政府共同资助,作为ACT计划的一部分,旨在确定裂缝和断层泥岩盖层的实际流速,并旨在确定能够检测此类流体运移的现有监测工具。为此,最先进技术的监测性能将与单裂缝、裂缝网络和储层尺度下的耦合水力力学流动和反应性运移模拟的流量预测进行比较,后者又结合了对应力和反应性相关裂缝渗透率的综合实验室研究的见解。通过对潜在流量的进一步了解,可以利用现有的bowtie方法进行综合生命周期风险评估,从而全面了解二氧化碳从地下储层泄漏的自然路径。弓形结模型将扩展到包括定量风险评估,其目标是计算整个盖层泄漏的概率/可能性,并估计通过监测提供的风险降低。
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引用次数: 0
Reservoir Simulation And Feasibility Study For Seismic Monitoring At CaMI.FRS, Newell County, Alberta 储层模拟及CaMI地震监测可行性研究。阿尔伯塔省纽厄尔县的FRS
Pub Date : 2018-11-21 DOI: 10.3997/2214-4609.201802980
M. Macquet, D. Lawton
We present the results of reservoir simulations and feasibility study of surface seismic monitoring applied to the CO2 sequestration at the CaMI Field Research Station (FRS). We first test the influence of injection parameters, as reservoir temperature, maximum bottom-hole pressure and of the ratio vertical permeability over horizontal permeability on the amount of CO2 you can inject and on the gas plume shape. We demonstrate that if the reservoir temperature has a very small influence on the injectivity, the maximum bottom-hole pressure and the ratio of permeabilities play a key role on the gas injection. The next step is fluid substitution, necessitated to estimate the variation in elastic parameters induced by the gas injection. We test different methods to compute the bulk modulus of the fluid (Reuss, Voigt, HRV and Brie) and compare their results. We finally use a 3D finite difference modeling to simulate the seismic response in the elastic models generated for the baseline, for 1 year of injection and for 5 years of injection.
本文介绍了CaMI野外研究站(FRS)储层模拟和地表地震监测应用于CO2封存的可行性研究结果。我们首先测试了注入参数,如储层温度、最大井底压力以及垂直渗透率与水平渗透率之比对CO2注入量和气柱形状的影响。研究表明,当储层温度对注气能力的影响很小时,最大井底压力和渗透率比对注气能力起关键作用。下一步是流体替代,这是估计注气引起的弹性参数变化所必需的。我们测试了不同的方法来计算流体的体积模量(Reuss, Voigt, HRV和Brie),并比较了它们的结果。最后,我们使用三维有限差分建模来模拟基线弹性模型中的地震响应,分别为1年和5年的注入。
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引用次数: 4
Laboratory-Scale Study On The Swelling Behaviour Of Coal Due To CO2 Injection 煤因CO2注入而膨胀特性的实验室规模研究
Pub Date : 2018-11-21 DOI: 10.3997/2214-4609.201802960
F. Bertrand, O. Buzzi, F. Collin
Sorption- and stress-induced coal permeability alteration may occur considering injection of carbon dioxide in coal seams for CCS. To take into account properly these phenomena, a microscale model was developed for the modelling of injection experiments carried out in laboratory. This work presents this model and first experimental results obtained from an injection test.
考虑到煤中注入二氧化碳进行碳捕集和封存,煤的渗透性可能发生吸附和应力引起的改变。为了适当地考虑到这些现象,开发了一个微尺度模型,用于模拟在实验室进行的注射实验。本文介绍了该模型和从注射试验中获得的第一个实验结果。
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引用次数: 0
Predictive Modelling Of CO2 Storage In Aquifers: Integrating The Effects Of Boundary Conditions And Saturation Functions 含水层中CO2储存的预测模型:整合边界条件和饱和函数的影响
Pub Date : 2018-11-21 DOI: 10.3997/2214-4609.201802974
M. Onoja, S. Shariatipour
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引用次数: 0
Experimental And Theoretical Investigation Of Natural Convection In CCS: Onset Time, Mass-Transfer Rate, Capillary Transition Zone, And Heat Of Dissolution CCS中自然对流的实验和理论研究:开始时间、传质速率、毛细过渡区和溶解热
Pub Date : 2018-11-21 DOI: 10.3997/2214-4609.201802958
A. Eftekhari, R. Farajzadeh, J. Bruining
We study the enhanced mass transfer of CO2 in water for a CO2 saturated layer on top of a water saturated porous medium, experimentally and theoretically. A relatively large experimental set-up with a length of 0.5 m and a diameter of 0.15 m is used in pressure decay experiments to minimize the error of pressure measurement due to temperature fluctuations and small leakages. The experimental results were compared to the theoretical result in terms of onset time of natural convection and rate of mass transfer of CO2 in the convection dominated process. In addition, a non-isothermal multicomponent flow model in porous media, is solved numerically to study the effect of the heat of dissolution of CO2 in water on the rate of mass transfer of CO2. The effect of the capillary transition zone on the rate of mass transfer of CO2 is also studied theoretically. The simulation results including the effect of the capillary transition zone show a better agreement with experimental results compared to the simulation result without considering a capillary transition zone. The simulation results also show that the effect of heat of dissolution on the rate of mass transfer is negligible
本文从实验和理论两方面研究了饱和水多孔介质上CO2饱和层对水中CO2传质增强的影响。压力衰减实验采用长度为0.5 m、直径为0.15 m的较大实验装置,以尽量减少温度波动和小泄漏造成的压力测量误差。将实验结果与理论结果在自然对流发生时间和对流主导过程中CO2的传质速率方面进行了比较。此外,对多孔介质中非等温多组分流动模型进行了数值求解,研究了CO2在水中的溶解热对CO2传质速率的影响。从理论上研究了毛细管过渡区对CO2传质速率的影响。与不考虑毛细过渡区的模拟结果相比,考虑毛细过渡区的模拟结果与实验结果更加吻合。模拟结果还表明,溶解热对传质速率的影响可以忽略不计
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引用次数: 2
Opening Versus Self-Sealing Behaviour Of Single Fractures In Mudstone Caprocks During CO2 Migration CO2运移过程中泥岩盖层单裂缝的开闭与自闭行为
Pub Date : 2018-11-21 DOI: 10.3997/2214-4609.201802967
N. Kampman
Reactions between CO2 and CO2-charged brines and mudrocks may inhibit CO2 leakage via the precipitation of carbonate minerals or via swelling of clay minerals or enhance leakage via the corrosion of carbonate cements. The timescales for the potential self-sealing behaviour, and/or the magnitudes of the permeability enhancements are uncertain. Laboratory experiments can provide constraints on the intrinsic fracture permeabilities, but the quantification of permeability changes following reaction or under conditions of multiphase flow is challenging in the laboratory. Reactive transport modelling (RTM) provides a numerical laboratory in which the intrinsic permeabilities of rough fractures, and the coupling of the flow and reaction processes, can be investigated. A modified local cubic law (MLCL) is used to model rough fracture permeability, and coupling of permeability-porosity changes to mineralization and clay swelling. The results show that the intrinsic permeability of self-affine fractures is primarily dependent on the roughness and degree of correlation between the two fracture surfaces, and that with increasing roughness the simulated fracture permeabilities are systematically lower than permeabilities predicted from the fracture aperture mean using a cubic law. The dependence of fracture permeabilities on reactions is investigated, and the relationship between mineralization behaviour and fluid residence time is discussed.
CO2与带CO2电荷的盐水和泥岩之间的反应可以抑制CO2通过碳酸盐矿物的沉淀或粘土矿物的膨胀而泄漏,或通过碳酸盐胶结物的腐蚀而增加泄漏。潜在的自密封行为的时间尺度和/或渗透率增强的幅度是不确定的。实验室实验可以提供裂缝固有渗透率的约束条件,但在实验室中,对反应后或多相流条件下渗透率变化的量化具有挑战性。反应输运模型(RTM)提供了一个数值实验室,可以研究粗糙裂缝的固有渗透率以及流动和反应过程的耦合。采用改进的局部立方定律(MLCL)来模拟粗裂缝渗透率,以及渗透率-孔隙度变化与矿化和粘土膨胀的耦合关系。结果表明,自仿射裂缝的固有渗透率主要取决于裂缝表面的粗糙度和两裂缝表面之间的相关程度,随着粗糙度的增加,模拟的裂缝渗透率系统地低于利用三次定律从裂缝孔径平均值预测的渗透率。研究了裂缝渗透率对反应的依赖性,并讨论了成矿行为与流体停留时间的关系。
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引用次数: 1
Investigating The Impact Of Relative Permeability Curves On Cold CO2 Injection 研究相对渗透率曲线对冷注CO2的影响
Pub Date : 2018-11-21 DOI: 10.3997/2214-4609.201802966
M. Abbaszadeh, S. Shariatipour
Different injection methods have been already proposed by different researchers to improve the solubility of CO2 in the formation brine. In this study an injection technique is presented to cool down (liquefy) the supercritical CO2 in the wellbore by the use of a downhole cooler equipment. CO2 with a higher temperature enters the cooling equipment and exits the equipment with a lower temperature at the down-stream in a same injection pressure. The colder (liquid) CO2 has a higher solubility in brine, higher density and viscosity which increases the security of CO2 storage. With this method the supercritical CO2 is cooled down to a liquid phase to increase the solubility at the wellbore and thus it eliminated the risk of phase change or pressure and rate fluctuation in liquid CO2 injection from the surface. To simulate this technique two cases have been considered by changing the relative permeability curves. The results show that using the combination of CO2STORE and THERMAL options shows a higher dissolution compared with only inserting the relative permeability curves corresponding the injection condition.
不同的研究人员已经提出了不同的注入方法来提高CO2在地层盐水中的溶解度。在这项研究中,提出了一种注入技术,通过使用井下冷却设备来冷却(液化)井筒中的超临界CO2。在相同的喷射压力下,温度较高的CO2进入冷却设备,从下游温度较低的设备排出。较冷的(液态)CO2在盐水中的溶解度更高,密度和粘度更高,这增加了CO2储存的安全性。通过这种方法,超临界CO2被冷却为液相,以增加在井筒中的溶解度,从而消除了从地面注入液态CO2时发生相变或压力和速率波动的风险。为了模拟该技术,通过改变相对渗透率曲线考虑了两种情况。结果表明,与仅插入相应注入条件的相对渗透率曲线相比,采用CO2STORE和THERMAL相结合的方案具有更高的溶解效果。
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引用次数: 0
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Fifth CO2 Geological Storage Workshop
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