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Influence of Al2O3 atomic-layer deposition temperature on positive-bias instability of metal/Al2O3/β-Ga2O3 capacitors Al2O3 原子层沉积温度对金属/Al2O3/β-Ga2O3 电容器正偏压不稳定性的影响
Pub Date : 2024-01-01 DOI: 10.1116/6.0003186
A. Hiraiwa, K. Horikawa, Hiroshi Kawarada, M. Kado, K. Danno
The influence of Al2O3 atomic-layer deposition (ALD) temperature on the electric characteristics of Al/Al2O3/(2¯01) β-Ga2O3 capacitors was investigated focusing on the positive-bias instability (PBI) of the capacitors. The current in the capacitors increased with ALD temperature, mostly because of the reduced energy barrier height for the electron field emission from the substrate and less negative Al2O3 charge, as revealed by the analysis conducted assuming a space-charge-controlled field emission process. The PBI tests were conducted for cumulative voltage stressing times vastly ranging from 3 × 10−6 to 4 × 105 s. The capacitance–voltage (C–V) characteristics of the capacitors for an ALD temperature of 100 °C displayed negative shifts in the middle of voltage stressing, unlike those for the other ALD temperatures. The bias stability of the capacitors was found to be considerably improved by high-temperature (450 °C) ALD. Additionally, the C–V characteristic shifts caused by the voltage stressing were theoretically reproduced quite accurately, assuming a model proposed in this study. In the simulations, the trap distributions in the Al2O3 films were assumed to be uniform both spatially and energetically. Importantly, the experimental results for various stressing voltages were excellently fitted by the simulations that assumed the same trap distribution. The trap densities in the Al2O3 films thus estimated reduced from 1.2 × 1020 to 2.2 × 1019 cm−3 eV−1 for ALD temperatures of 100–450 °C. This reduction in the trap densities was a major cause of the bias stability enhancement for high-temperature ALD. Moreover, the trap density as a function of ALD temperature qualitatively agreed with the aforementioned Al2O3 charge generated by the current measurements. This agreement provides a strong basis for the validity of the PBI model proposed in this study.
我们研究了 Al2O3 原子层沉积(ALD)温度对 Al/Al2O3/(2¯01) β-Ga2O3 电容器电气特性的影响,重点是电容器的正偏压不稳定性(PBI)。电容器中的电流随着 ALD 温度的升高而增大,这主要是因为从基底发射电子场的能量势垒高度降低以及 Al2O3 负电荷减少,这是在假设空间电荷控制场发射过程的情况下进行的分析所揭示的。PBI 测试的累积电压应力时间范围从 3 × 10-6 到 4 × 105 秒不等。与其他 ALD 温度不同的是,ALD 温度为 100 ℃ 时电容器的电容-电压 (C-V) 特性在电压应力中间出现负偏移。高温(450 °C)ALD 大大提高了电容器的偏置稳定性。此外,假设采用本研究提出的模型,电压应力引起的 C-V 特性偏移在理论上得到了相当准确的再现。在模拟中,假定 Al2O3 薄膜中的陷阱分布在空间和能量上都是均匀的。重要的是,假设阱分布相同,各种应力电压下的实验结果都能很好地与模拟结果拟合。据此估算,在 ALD 温度为 100-450 °C 时,Al2O3 薄膜中的陷阱密度从 1.2 × 1020 降至 2.2 × 1019 cm-3 eV-1。陷阱密度的降低是高温 ALD 偏压稳定性增强的主要原因。此外,作为 ALD 温度函数的陷阱密度与上述电流测量产生的 Al2O3 电荷在性质上是一致的。这种一致性为本研究提出的 PBI 模型的有效性提供了坚实的基础。
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引用次数: 0
Electron emission properties of titanium nitride coated volcano-structured silicon emitters 氮化钛涂层火山结构硅发射器的电子发射特性
Pub Date : 2024-01-01 DOI: 10.1116/6.0003234
H. Murata, K. Murakami, Masayoshi Nagao
Volcano-structured field emitter arrays (FEAs) have achieved high-beam focusing and have been applied in electron beam lithography and image sensors. However, high current operation on the order of milliamperes is necessary for applications such as x-ray sources and traveling wave tubes. Thus, this study applied a TiN coating to a volcano-structured Si-FEA, which has a high melting point favorable for high-current operation. Transmission electron microscopy and x-ray photoelectron spectroscopy revealed that TiN was uniformly deposited on the Si tip by DC magnetron sputtering with the atomic ratio of Ti to N being 1:1. The TiN-coated volcano-structured FEA exhibited excellent electron emission property (7.7 mA/1027 tips) and an electron emission stability of >6 mA for 60 min in pulse operation. These results are expected to aid in the development of next-generation electron sources that can realize high-current operations under high-beam-focusing conditions.
火山结构场发射器阵列(FEA)实现了高光束聚焦,并已应用于电子束光刻和图像传感器。然而,在 X 射线源和行波管等应用中,需要毫安级的大电流运行。因此,本研究将 TiN 涂层应用于火山结构的 Si-FEA,其熔点高,有利于大电流操作。透射电子显微镜和 X 射线光电子能谱显示,TiN 是通过直流磁控溅射均匀沉积在硅尖端的,Ti 与 N 的原子比为 1:1。涂有 TiN 的火山结构 FEA 表现出优异的电子发射特性(7.7 mA/1027个尖端),在脉冲操作中,电子发射稳定性大于 6 mA,持续 60 分钟。这些结果有望帮助开发新一代电子源,实现高光束聚焦条件下的大电流运行。
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引用次数: 0
Development of “GaSb-on-silicon” metamorphic substrates for optoelectronic device growth 开发用于光电器件生长的 "硅基砷化镓 "变质衬底
Pub Date : 2024-01-01 DOI: 10.1116/6.0003211
F. F. Ince, Mega Frost, D. Shima, Thomas J. Rotter, S. Addamane, C. Canedy, S. Tomasulo, C. Kim, W. Bewley, I. Vurgaftman, J. Meyer, Ganesh Balakrishnan
The epitaxial development and characterization of metamorphic “GaSb-on-silicon” buffers as substrates for antimonide devices is presented. The approach involves the growth of a spontaneously and fully relaxed GaSb metamorphic buffer in a primary epitaxial reactor, and use of the resulting “GaSb-on-silicon” wafer to grow subsequent layers in a secondary epitaxial reactor. The buffer growth involves four steps—silicon substrate preparation for oxide removal, nucleation of AlSb on silicon, growth of the GaSb buffer, and finally capping of the buffer to prevent oxidation. This approach on miscut silicon substrates leads to a buffer with negligible antiphase domain density. The growth of this buffer is based on inducing interfacial misfit dislocations between an AlSb nucleation layer and the underlying silicon substrate, which results in a fully relaxed GaSb buffer. A 1 μm thick GaSb layer buffer grown on silicon has ∼9.2 × 107dislocations/cm2. The complete lack of strain in the epitaxial structure allows subsequent growths to be accurately lattice matched, thus making the approach ideal for use as a substrate. We characterize the GaSb-on-silicon wafer using high-resolution x-ray diffraction and transmission electron microscopy. The concept’s feasibility is demonstrated by growing interband cascade light emitting devices on the GaSb-on-silicon wafer. The performance of the resulting LEDs on silicon approaches that of counterparts grown lattice matched on GaSb.
本文介绍了作为锑化硅器件基底的变质 "硅基砷化镓 "缓冲器的外延开发和特性分析。该方法包括在一级外延反应器中生长自发和完全松弛的硅镓锑变质缓冲器,并使用由此产生的 "硅基硅镓锑 "晶片在二级外延反应器中生长后续层。缓冲区的生长包括四个步骤--硅衬底制备以去除氧化物、硅上铝锑成核、硅镓缓冲区的生长,以及最后覆盖缓冲区以防止氧化。在切割不当的硅衬底上采用这种方法,可以得到反相域密度几乎可以忽略不计的缓冲区。这种缓冲区的生长基于在 AlSb 成核层和底层硅衬底之间诱导界面错配位错,从而形成完全松弛的 GaSb 缓冲区。在硅上生长的 1 μm 厚的 GaSb 层缓冲区具有 ∼9.2 × 107dislocations/cm2 的位错。由于外延结构中完全没有应变,因此后续生长可以实现精确的晶格匹配,从而使这种方法成为用作衬底的理想选择。我们使用高分辨率 X 射线衍射和透射电子显微镜对硅基砷化镓晶片进行了表征。通过在硅基掺镓晶片上生长带间级联发光器件,证明了这一概念的可行性。在硅片上生长出的 LED 性能接近于在 GaSb 上生长出的晶格匹配的同类产品。
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引用次数: 0
New method of fabrication of suspended metallic single electron transistor (SET) 制造悬浮金属单电子晶体管(SET)的新方法
Pub Date : 2024-01-01 DOI: 10.1116/6.0003025
Mohammad Istiaque Rahaman, G. Szakmany, A. O. Orlov, G. L. Snider
Charge sensing applications utilizing single electron transistors (SETs) as electrometers face challenges due to nearby background charge movements. In this study, we present an innovative fabrication method for creating suspended Al-AlOx-Al SETs positioned above a cavity. These suspended SETs exhibit significantly reduced flicker noise with 1fα noise spectral density when compared to their substrate-based counterparts. This noise reduction can be attributed to the elimination of the substrate beneath the SET island. Consequently, our fabricated suspended SETs are highly suitable for demanding charge sensing applications and provide a promising platform for in-depth investigations into the sources of charge noise in such devices.
由于附近的背景电荷运动,利用单电子晶体管(SET)作为电量计的电荷传感应用面临着挑战。在这项研究中,我们提出了一种创新的制造方法,用于制造位于空腔上方的悬浮式 Al-AlOx-Al SET。与基于基底的同类器件相比,这些悬浮 SET 的闪烁噪声(噪声谱密度为 1fα)明显降低。这种噪声降低可归因于 SET 岛下方消除了基底。因此,我们制造的悬浮 SET 非常适合要求苛刻的电荷传感应用,并为深入研究此类器件中的电荷噪声源提供了一个前景广阔的平台。
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引用次数: 0
Evaluation of the pumping performance of combinations of Ti–Zr–V–Hf alloy nonevaporable getter coatings with different morphologies, activation protocols controlled at cryogenic temperatures 评估具有不同形态的 Ti-Zr-V-Hf 合金非蒸发获取器涂层组合的泵送性能以及在低温下控制的活化方案
Pub Date : 2024-01-01 DOI: 10.1116/6.0003152
Paul Smith, Sam Lodge, Andrew Chew
The pumping performance of a range of Ti, V, Zr, and Hf alloy nonevaporable getter (NEG) coatings of order 5 μm thickness and with different modular structures has been investigated. For equal atomic percent Ti–Zr–V–Hf quaternary alloys, dual (columnar layer on the dense layer) coatings gave higher sticking probabilities than columnar and dense morphologies. The same alloy provided the highest sticking probability, followed by the Ti–Zr–V tertiary alloy, and then singular Zr. For a 24 h activation time, single element Zr coatings were shown to require an activation temperature of 300 vs 250 °C for the other alloys. H2 and N2 sticking probabilities increased by a factor of 100 and N2 terminal capacities by a factor of 1000, in the range 150–300 °C. For the dual coated Ti–Zr–V–Hf quaternary alloy at an activation temperature of 140 °C, H2 sticking probabilities increased by a factor of 2 when the activation time increased from 1 to 7 days and that of N2 increased by a factor of 6. The factor of 100 increase in measured sticking probability at LN2 temperature, compared to room temperature, to a value of 0.5 for H2, is transient in nature. Further investigations into this behavior are planned.
研究了一系列厚度为 5 μm 左右、具有不同模块结构的 Ti、V、Zr 和 Hf 合金非蒸发获取器 (NEG) 涂层的泵送性能。对于原子百分比相等的钛-锆-钒-铪四元合金,双层(致密层上的柱状层)涂层比柱状和致密形态的涂层具有更高的粘附概率。同种合金的粘附概率最高,其次是 Ti-Zr-V 三元合金,然后是单一 Zr。在 24 小时的活化时间内,单元素 Zr 涂层所需的活化温度为 300 °C,而其他合金为 250 °C。在 150-300 °C 范围内,H2 和 N2 的粘附概率增加了 100 倍,N2 的终端容量增加了 1000 倍。对于活化温度为 140 ℃ 的双涂层 Ti-Zr-V-Hf 四元合金,当活化时间从 1 天增加到 7 天时,H2 的粘滞概率增加了 2 倍,N2 的粘滞概率增加了 6 倍。 与室温相比,在 LN2 温度下测得的粘滞概率增加了 100 倍,H2 的值为 0.5,这是瞬态性质的。计划对这种行为进行进一步研究。
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引用次数: 0
Temperature effects on electrospray current from an externally wetted EMI-Im ionic liquid ion source 温度对外部润湿 EMI-Im 离子液体离子源电喷雾电流的影响
Pub Date : 2023-12-01 DOI: 10.1116/6.0003088
Y. Fujiwara
Ionic liquid ion sources are expected to be used in a wide range of applications such as space electric propulsion and focused ion beam micromachining. It is known that the backstreaming of secondary charged species generated by ion beam impacts can cause unexpected temperature rise and chemical changes in ionic liquids. This paper reports on results of heating experiments using a sharp needle emitter wetted with an ionic liquid, 1-ethyl-3-methyl imidazolium bis(trifluoromethanesulfonyl)amide, at temperatures in a range from room temperature to 120 °C. Current measurements show that positive and negative electrospray currents from the heated emitter increased as the temperature increased. Time-of-flight (TOF) mass spectrometric measurements reveal that the beam composition changed significantly with increasing temperature, indicating that charged droplets as well as ions were emitted from the heated emitter. The TOF data show that a significant fraction of the current is due to droplets at higher temperatures. On the basis of the results obtained, the size and charge of the emitted droplets are discussed. The beam is roughly estimated to contain charged droplets with a diameter of around 20 nm at 120 °C.
离子液体离子源有望广泛应用于太空电力推进和聚焦离子束微加工等领域。众所周知,离子束撞击产生的二次带电物质的逆流会导致离子液体发生意想不到的温升和化学变化。本文报告了使用离子液体 1-乙基-3-甲基咪唑鎓双(三氟甲磺酰基)酰胺润湿的尖针发射器在室温至 120 ℃ 范围内进行加热实验的结果。电流测量结果表明,随着温度的升高,来自加热发射器的正电喷射电流和负电喷射电流都在增加。飞行时间(TOF)质谱测量显示,光束成分随着温度的升高发生了显著变化,这表明加热发射器发射出了带电液滴和离子。TOF 数据显示,在较高温度下,相当一部分电流是由液滴产生的。根据所获得的结果,对发射液滴的大小和电荷进行了讨论。据粗略估计,在 120 °C 时,光束中包含的带电液滴直径约为 20 nm。
{"title":"Temperature effects on electrospray current from an externally wetted EMI-Im ionic liquid ion source","authors":"Y. Fujiwara","doi":"10.1116/6.0003088","DOIUrl":"https://doi.org/10.1116/6.0003088","url":null,"abstract":"Ionic liquid ion sources are expected to be used in a wide range of applications such as space electric propulsion and focused ion beam micromachining. It is known that the backstreaming of secondary charged species generated by ion beam impacts can cause unexpected temperature rise and chemical changes in ionic liquids. This paper reports on results of heating experiments using a sharp needle emitter wetted with an ionic liquid, 1-ethyl-3-methyl imidazolium bis(trifluoromethanesulfonyl)amide, at temperatures in a range from room temperature to 120 °C. Current measurements show that positive and negative electrospray currents from the heated emitter increased as the temperature increased. Time-of-flight (TOF) mass spectrometric measurements reveal that the beam composition changed significantly with increasing temperature, indicating that charged droplets as well as ions were emitted from the heated emitter. The TOF data show that a significant fraction of the current is due to droplets at higher temperatures. On the basis of the results obtained, the size and charge of the emitted droplets are discussed. The beam is roughly estimated to contain charged droplets with a diameter of around 20 nm at 120 °C.","PeriodicalId":282302,"journal":{"name":"Journal of Vacuum Science & Technology B","volume":"53 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139015124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optical properties of copper oxide thin films implanted with chromium ions 植入铬离子的氧化铜薄膜的光学特性
Pub Date : 2023-12-01 DOI: 10.1116/6.0003135
K. Ungeheuer, K. W. Marszalek
Copper oxides are nontoxic semiconductors with good stability and abundance of raw materials. In each of the applications, it is advisable to look for a method to improve the properties of thin films of these materials, such as electrical conductivity or light absorption. In this work, thin films were prepared by reactive magnetron sputtering and doped with chromium using the ion implantation method. The samples were implanted with chromium ions with energy of 10–25 keV and various doses ranging from 1 × 1014 to 1 × 1017 cm−2. Their optical properties were investigated using spectroscopic ellipsometry and spectrophotometry with absorption measurement. Multilayer models of the dielectric function of materials were established based on oscillator equations to obtain the values of optical parameters such as refractive index and extinction coefficient. Measurements using the ellipsometer allowed us to examine the homogeneity of the samples after deposition, as well as after the implantation process, by measuring 4 × 4 mm2 maps of the pseudorefractive index of the samples. Ion implantation affects the optical properties of copper oxides, and these changes are expected to come from the top thickness of the implanted films, i.e., the range in which the implanted ions penetrate. Using multilayer models to analyze the results of spectroscopic ellipsometry, it was possible to estimate the thickness of the layer that has the greatest impact on the optical properties of the oxides.
氧化铜是一种无毒半导体,具有良好的稳定性和丰富的原材料。在每一种应用中,最好都能找到一种方法来改善这些材料薄膜的特性,如导电性或光吸收性。在这项工作中,采用反应磁控溅射法制备了薄膜,并利用离子注入法掺杂了铬。样品被植入能量为 10-25 keV、剂量为 1 × 1014 至 1 × 1017 cm-2 的铬离子。使用分光椭偏仪和带吸收测量的分光光度计对它们的光学特性进行了研究。根据振荡器方程建立了材料介电函数的多层模型,以获得折射率和消光系数等光学参数值。通过使用椭偏仪测量样品的 4 × 4 平方毫米伪折射率图,我们可以检查沉积后和植入过程后样品的均匀性。离子注入会影响铜氧化物的光学特性,而这些变化预计来自植入薄膜的顶部厚度,即植入离子的穿透范围。利用多层模型分析光谱椭偏仪的结果,可以估算出对氧化物光学特性影响最大的层厚度。
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引用次数: 0
3D structure of box-and-grid electron multiplier with higher electron collection efficiency 具有更高电子收集效率的三维结构箱栅式电子倍增器
Pub Date : 2023-12-01 DOI: 10.1116/6.0003162
Zhangcong Xia, Yunrong Wang, Youwei Peng, Jie Li, Wenbo Hu, Xin Zhong, Shengli Wu
In this paper, the electron collection efficiency of dynodes in different electron multiplier (EM) structures is analyzed using Computer Simulation Technology. Three main factors that lead to low efficiency in electronic collection have been identified as crossing, trapped, and blocked electrons. The proportions of these three types of electrons are investigated to illustrate the characteristics of EMs with different structures. It is observed that the optimized 3D structure outperforms all 2D structures, and the reasons for this improvement are also discussed. The spiral EM is designed to achieve an average collection efficiency of 98.9% at the optimal parameters. By adopting the proposed structure, not only the size of the EM can be reduced, but also the gain of the EM can be significantly improved. Consequently, this will allow for a reduction in the operating voltage of the EM and prolong its lifetime.
本文利用计算机仿真技术分析了不同电子倍增器(EM)结构中 dynodes 的电子收集效率。导致电子收集效率低的三个主要因素被确定为交叉电子、陷落电子和阻塞电子。研究了这三类电子的比例,以说明不同结构的 EM 的特点。据观察,优化后的三维结构优于所有二维结构,并讨论了这种改进的原因。在最佳参数下,螺旋 EM 的平均收集效率达到 98.9%。通过采用所建议的结构,不仅可以减小电磁元件的尺寸,还能显著提高电磁元件的增益。因此,这可以降低电磁炉的工作电压,延长其使用寿命。
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引用次数: 0
An Invar-based dual Fabry–Perot cavity refractometer for assessment of pressure with a pressure independent uncertainty in the sub-mPa region 基于英华尔的双法布里-珀罗腔折射仪,用于评估压力,压力不确定度在亚兆帕(mPa)以下区域
Pub Date : 2023-12-01 DOI: 10.1116/6.0003149
I. Silander, J. Zakrisson, M. Zelan, O. Axner
An updated version of an Invar-based dual Fabry–Perot cavity refractometer utilizing the gas modulation methodology has been characterized with regard to its ability to assess gas pressure in the low pressure regime, defined as the regime in which the instrumentation is mainly limited by the constant term a in the [(a)2+(b×P)2]1/2 expression for the uncertainty. It is first concluded that this ability is predominantly limited by three entities, viz., the empty cavity repeatability, the residual gas pressures in the evacuated (measurement) cavity, and the contamination of the gas residing in the measurement cavity that originates from leaks and outgassing. We then present and utilize methods to separately estimate the uncertainty of the updated refractometer from these entities. It was found that, when utilizing gas modulation cycles of 100 s and when addressing nitrogen, the system can assess pressure in the low pressure regime with an expanded uncertainty (k=2) of 0.75 mPa, mainly limited by the empty cavity repeatability and outgassing of hydrogen. This is more than 1 order of magnitude below the previously assessed low pressure performance of the instrumentation.
采用气体调制方法的英发双法布里-珀罗腔折射仪的更新版,在低压状态下评估气体压力的能力得到了鉴定,低压状态是指仪器主要受限于不确定度表达式[(a)2+(b×P)2]1/2 中常数 a 的状态。我们首先得出结论,这种能力主要受到三个实体的限制,即空腔重复性、抽空(测量)腔中的残余气体压力以及测量腔中的气体污染(源于泄漏和放气)。然后,我们提出并利用各种方法,分别从这些实体中估算出更新折射仪的不确定性。我们发现,在使用 100 秒的气体调制周期和氮气时,系统可以评估低压状态下的压力,扩展不确定度 (k=2) 为 0.75 mPa,主要受限于空腔重复性和氢气放气。这比之前评估的仪器低压性能低 1 个数量级以上。
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引用次数: 0
Preface for the Special Topic Collection Honoring Dr. Gary McGuire’s Research and Leadership as Editor of the Journal of Vacuum Science & Technology for Three Decades 为纪念 Gary McGuire 博士三十年来作为《真空科技》杂志编辑所从事的研究和领导工作而出版的专题集作序
Pub Date : 2023-12-01 DOI: 10.1116/6.0003134
O. Shenderova, Susan Burkett
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引用次数: 0
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Journal of Vacuum Science & Technology B
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