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Removal of lanthanum and cerium from aqueous solution using chitosan-functionalized magnetite-pectin 利用壳聚糖功能化磁铁矿-pectin 去除水溶液中的镧和铈
Pub Date : 2024-01-09 DOI: 10.1007/s43832-023-00054-w
Abdoul-Rachid Chaibou Yacouba, Alp Oral, Şenol Sert, İ. G. Kaptanoğlu, I. Natatou, S. Yusan, Ş. Aytaş
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引用次数: 0
Potential toxic effects linked to taurine interactions with alkanolamines and diisopropylamine. 牛磺酸与烷醇胺和二异丙基胺相互作用的潜在毒性效应。
Pub Date : 2024-01-01 Epub Date: 2024-10-18 DOI: 10.1007/s43832-024-00146-1
Erica Pensini, Caitlyn Hsiung, Nour Kashlan

Diisopropylamine (DIPA), aminomethyl propanol (AMP), amino ethoxy ethanol (AEE), diethanolamine (DEA), ethanolamine (EA), pyridine (PYR) and methyl diethanolamine (MDEA) are used for carbon capture and to sweeten sour gas, and are found in groundwater. They are also used in cosmetic products. Taurine is abundant in the body, with key biological functions linked to its charged SO groups. Interactions between SO and amines have not been studied, but can strongly affect the biological function of taurine. Fourier transform infrared spectroscopy indicates SO…HN hydrogen bonding between taurine and DIPA, AMP, AEE, DEA, EA and MDEA. These interactions induce the formation of hydrophobic amine-taurine clusters, thus decreasing amine miscibility in water, as revealed by light scattering. This effect is most marked for DIPA, leading to turbid mixtures indicative of micron-sized droplets. PYR and taurine likely interact via S…N bonding. This study offers insights regarding potential mechanisms of amine toxicity to humans.

Graphical abstract:

Supplementary information: The online version contains supplementary material available at 10.1007/s43832-024-00146-1.

二异丙基胺 (DIPA)、氨基甲基丙醇 (AMP)、氨基乙氧基乙醇 (AEE)、二乙醇胺 (DEA)、乙醇胺 (EA)、吡啶 (PYR) 和甲基二乙醇胺 (MDEA) 可用于碳捕获和酸性气体甜味剂,并存在于地下水中。它们还用于化妆品。牛磺酸在人体内含量丰富,其主要生物功能与其带电的 SO 基团有关。目前尚未对 SO 与胺之间的相互作用进行研究,但这种相互作用会对牛磺酸的生物功能产生重大影响。傅立叶变换红外光谱显示,牛磺酸与 DIPA、AMP、AEE、DEA、EA 和 MDEA 之间存在 SO...HN 氢键。光散射显示,这些相互作用导致形成疏水性胺-牛磺酸簇,从而降低了胺在水中的混溶性。这种效应在 DIPA 中最为明显,导致混合物浑浊,显示出微米大小的液滴。PYR和牛磺酸可能通过S...N键相互作用。这项研究为了解胺对人体毒性的潜在机制提供了启示:在线版本包含补充材料,可查阅 10.1007/s43832-024-00146-1。
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引用次数: 0
Flood risk assessment under the shared socioeconomic pathways: a case of electricity bulk supply points in Greater Accra, Ghana. 共享社会经济路径下的洪水风险评估:以加纳大阿克拉地区的电力大宗供应点为例。
Pub Date : 2024-01-01 Epub Date: 2024-10-07 DOI: 10.1007/s43832-024-00140-7
Ebenezer K Siabi, Akwasi Adu-Poku, Nathaniel Oppong Otchere, Edward A Awafo, Amos T Kabo-Bah, Nana S A Derkyi, Komlavi Akpoti, Geophrey K Anornu, Eunice Akyereko Adjei, Francis Kemausuor, Mashael Yazdanie

This study evaluates flood susceptibility and risk on Bulk Supply Points in the Greater Accra region (GAR) using a Frequency Ratio model based on 15 flood conditioning factors. The model explores the influence of natural, meteorological and anthropogenic factors on flooding occurrences under the Shared Socioeconomic Pathway (SSP) scenarios and assesses flood risks at Bulk Supply Points (BSPs). Flood susceptibility mapping was conducted for both current and future periods under various SSP scenarios. Results reveal that elevation, slope, soil type, distance from urban areas, and SPI are the most influential factors contributing to flooding susceptibility in the region. The current flood map, about 37% of the total area of GAR categorized under the moderate flood-susceptible zone category followed by about 30% categorized under the low flood-vulnerable zone. However, about 16% was categorized under the very high flood-vulnerable zone. The study projects increasing flood susceptibility under the SSP scenarios with intensification under SSP2 and SSP3 scenarios. For instance, the areas categorized as high and very high flood susceptibility zones are projected to expand to approximately 32% and 26% each by 2055 under SSP3. The study also assesses flood risks at Bulk Supply Points (BSPs), highlighting the escalating susceptibility of power assets to flooding under different scenarios. For instance, in the very high scenario, flooding is estimated to reach 640 h in 2045 and exceed 800 h in 2055-more than double the 2020 baseline. The analysis shows the bulk supply points face increasing flood susceptibility, with risks escalating most sharply under the severe climate change SSP3 and SSP5 scenarios. Over 75% of BSPs are expected to fall in the low- to medium-risk categories across SSPs while more than 50% of BSPs are within medium- to high-risk categories in all scenarios except SSP1, reflecting the impact of climate change. SSP3 and SSP5 stand out with over 60% of BSPs facing high or very high flooding risks by 2055. It indicates moderate resilience with proper adaptation but highlights potential disruptions in critical infrastructure, such as BSPs, during persistent flooding. The findings of the study are expected to inform Ghana's contributions towards addressing Sustainable Development Goals (SDGs) 7, 11 and 13 in Ghana.

本研究利用基于 15 个洪水影响因素的频率比模型,评估了大阿克拉地区(GAR)大宗商品供应点的洪水易感性和风险。该模型探讨了共同社会经济路径 (SSP) 情景下自然、气象和人为因素对洪水发生的影响,并评估了大宗货物供应点 (BSP) 的洪水风险。在各种 SSP 情景下,对当前和未来时期的洪水易发性进行了测绘。结果显示,海拔、坡度、土壤类型、与城市地区的距离和 SPI 是造成该地区洪水易发性的最大影响因素。在当前的洪水地图上,GAR 总面积的约 37% 被归类为中度易受洪水影响区域,约 30% 被归类为低度易受洪水影响区域。然而,约有 16% 的地区被归类为极易受洪水影响地区。研究预测,在可持续发展战略计划情景下,洪水易受影响程度将不断增加,在可持续发展战略计划 2 和可持续发展战略计划 3 情景下,洪水易受影响程度将进一步加剧。例如,根据 SSP3,预计到 2055 年,被归类为高洪水易发区和极高洪水易发区的地区将分别扩大到约 32% 和 26%。该研究还评估了大宗供应点 (BSP) 的洪水风险,强调了在不同情景下电力资产易受洪水影响的程度不断上升。例如,在极高情景下,预计 2045 年洪水将达到 640 小时,2055 年将超过 800 小时--是 2020 年基线的两倍多。分析表明,大宗供应点面临的洪水风险越来越大,在严重气候变化 SSP3 和 SSP5 情景下,风险升级最为剧烈。在所有 SSP 中,预计超过 75% 的散装物料供应点属于中低风险类别,而在除 SSP1 以外的所有情景中,超过 50% 的散装物料供应点属于中高危类别,这反映了气候变化的影响。中级战略计划 3 和中级战略计划 5 尤为突出,到 2055 年,超过 60% 的基准点面临较高或极高的洪水风险。这表明,在适当适应的情况下,会有一定的抗灾能力,但在持续洪灾期间,关键基础设施(如基础服务设施)可能会受到破坏。研究结果有望为加纳实现可持续发展目标(SDGs)7、11 和 13 做出贡献。
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引用次数: 0
Fresh water management in coastal Bangladesh: preparedness and adaptation 孟加拉国沿海地区的淡水管理:准备与适应
Pub Date : 2023-12-18 DOI: 10.1007/s43832-023-00052-y
M. S. Khan, S. K. Paul
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引用次数: 0
Revisioning and reinvigorating a hydrogeology distinguished lecture tour through learner-engaged workshops 通过学习者参与式讲习班修订和振兴水文地质杰出巡回讲座
Pub Date : 2023-11-28 DOI: 10.1007/s43832-023-00051-z
Abraham E. Springer, Sierra Heimel, Jill L. Riddell, Trevor Dwyer, Marissa Fichera, Michael Jones, E. Kutsienyo, Sara Lilley, David Baude
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引用次数: 0
Flow alterations due a constructed reservoir in the Menik Ganga basin, Sri Lanka 斯里兰卡梅尼克甘加河流域修建水库造成的水流变化
Pub Date : 2023-11-17 DOI: 10.1007/s43832-023-00049-7
Sajana Pramudith Hemakumara, M. Gunathilake, Upaka S. Rathnayake
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引用次数: 0
Assessment of sachet water quality in Kumasi, Ghana 加纳库马西的小袋水质评估
Pub Date : 2023-11-14 DOI: 10.1007/s43832-023-00048-8
Nathaniel Owusu Boadi, Selina Ama Saah, Mercy Badu, Frimpomah Baa-Poku, Felix Odame, Patrick Opare Sakyi
Abstract This study assessed the physicochemical and microbiological quality of sachet drinking water samples in Kumasi, a major city in Ghana. Samples were collected from various sources within the city. Physicochemical properties, including pH, total dissolved solids, and concentrations of calcium, sodium, potassium, and magnesium ions, were analyzed following established protocols. Additionally, fluoride concentration was determined. The assessment criteria for water quality were based on the World Health Organization’s and the Ghana Standards Authority’s recommended standards for drinking water. The samples were also subjected to microbial analysis to detect the presence of E. coli and coliforms, and to evaluate microbial quality. The findings indicated that most physicochemical properties of the samples met the World Health Organization’s standards for safe drinking water, except for the slightly acidic pH. Total dissolved solids and the concentrations of calcium, sodium, potassium, fluoride and magnesium ions were within acceptable ranges. Strong positive correlations were observed among various physicochemical parameters of sachet water. However, microbial analysis revealed that 67% of the samples were contaminated with pathogenic microorganisms, including E. coli and coliforms, indicating poor microbiological quality. While sachet water samples generally meet physicochemical safety standards, addressing microbial quality is essential to ensure the safety of drinking water in Kumasi.
摘要:本研究对加纳主要城市库马西袋装饮用水样品的理化和微生物质量进行了评价。样本是从城市内的不同来源收集的。物理化学性质,包括pH值、总溶解固体、钙、钠、钾和镁离子浓度,按照既定方案进行分析。同时测定氟化物浓度。水质评估标准是根据世界卫生组织和加纳标准局推荐的饮用水标准制定的。样品还进行了微生物分析,以检测大肠杆菌和大肠菌群的存在,并评估微生物质量。调查结果表明,除ph值微酸性外,这些样品的大多数理化性质均符合世界卫生组织的安全饮用水标准。溶解固体总量以及钙、钠、钾、氟和镁离子浓度均在可接受范围内。包水各理化参数之间存在较强的正相关关系。然而,微生物分析显示,67%的样品被致病性微生物污染,包括大肠杆菌和大肠菌群,表明微生物质量较差。虽然小袋水样品通常符合物理化学安全标准,但解决微生物质量问题对于确保库马西饮用水的安全至关重要。
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引用次数: 0
Blockage slope and ratio effects on box culvert hydraulics 堵塞坡度和比例对箱涵水力学的影响
Pub Date : 2023-11-06 DOI: 10.1007/s43832-023-00045-x
Mahmoud Zayed
Abstract Culvert blockage at the inlet can dramatically alter the local hydraulic characteristics that often increase backwater rise, change the flow patterns, and thereby increase the risk of upstream flooding. The impact of culvert blockage is not usually included in the initial hydraulic design, although it can cause significant losses once the culvert becomes blocked. Culvert hydraulics including backwater rise with respect to blockage slope and ratio has been neglected in the studies conducted so far. In this study, we conducted a series of narrow flume tests to investigate the effects of four bottom blockage slope angles and five blockage ratios on the hydraulic characteristics of box culverts, including backwater rise, and upstream mean velocity at various Froude numbers. The results showed that Froude number, blockage ratio, and slope angle were regarded as the controlling variables for culvert backwater rise. Backwater rise increased dramatically with increasing blockage ratio and Froude number. Compared to blockage ratio B = 0.20, ΔH/h u increased by 2, 5, 9, and 13 times for B = 0.40, 0.60, 0.80, and 1, respectively. However, when the blockage slope angle decreased, the backwater rise reduced and upstream mean velocity increased in compared with vertical blockage. The relative backwater rise reduced from 0.32 to 0.29, when blockage slope angle decreased from 90° to 18.44° at B = 1 and F o = 0.10. In addition, the length and maximum depth of water surface depression inside the culvert itself were larger with increasing blockage ratio and Froude number. For F o = 0.10, d/h o = 0.13 and L/h o = 0.94 for B = 0.20 compared to d/h o = 0.32 and L/h o = 4.34 for B = 1. The results were also combined to develop an equation to predict backwater rise in the range 0.10 ≤ F o ≤ 0.25, 0 ≤ B ≤ 1, and 18.44° ≤ α ≤ 90°. To enhance the accuracy, it is recommended to apply the equation for ΔH/h u ˃ 0.10. It is useful and practical in applications to add the probability of backwater rise or losses owing to culvert blockage within accounting of losses during the hydraulic design of culverts, especially in channels exposed to debris.
进水口涵洞堵塞会极大地改变当地的水力特性,往往会增加回水上升,改变水流形态,从而增加上游洪水发生的风险。涵洞堵塞的影响通常不包括在最初的水力设计中,尽管一旦涵洞堵塞会造成重大损失。涵洞水力学包括回水上升对堵塞坡度和比的影响,在目前的研究中被忽略。在本研究中,我们进行了一系列窄水槽试验,研究了四种底部堵塞坡角和五种堵塞比对箱涵水力特性的影响,包括回水上升和不同弗劳德数下的上游平均流速。结果表明,弗劳德数、堵塞比和坡角是涵洞回水上升的控制变量。随着堵塞比和弗劳德数的增加,回水上升幅度显著增大。与堵塞比B = 0.20相比,当B = 0.40、0.60、0.80和1时ΔH/h u分别提高了2倍、5倍、9倍和13倍。与垂直堵塞相比,当堵塞坡角减小时,回水上升幅度减小,上游平均流速增大。当B = 1, F = 0.10时,堵塞坡角由90°减小至18.44°,相对回水上升由0.32减小至0.29。此外,随着堵塞比和弗劳德数的增加,涵洞内部水面凹陷的长度和最大深度也越大。当F = 0.10时,B = 0.20时d/h o = 0.13, L/h o = 0.94,而B = 1时d/h o = 0.32, L/h o = 4.34。结果还结合起来建立了一个方程,用于预测0.10≤F≤0.25,0≤B≤1和18.44°≤α≤90°范围内的回水上升。为提高计算精度,建议采用ΔH/h u 0.10的公式。在涵洞的水力设计中,特别是在有碎石的沟渠中,在计算涵洞的损失时,加入因涵洞堵塞而引起的回水上升或损失的概率,在实际应用中是有用的。
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引用次数: 0
Zonation of groundwater quality in terms of drinkability, using Fuzzy Logic and Schoeller deterministic method for Northern Dezful - Andimeshk Plain, Iran 基于模糊逻辑和Schoeller确定性方法的伊朗北部Dezful - Andimeshk平原地下水可饮用性水质分区
Pub Date : 2023-11-02 DOI: 10.1007/s43832-023-00046-w
Sedigheh Shakour, Manouchehr Chitsazan, Seyed Yahya Mirzaee
Abstract In the Northern Dezful-Andimeshk Plain, the primary source of drinking water is groundwater, which has low quality in some places. Thus, groundwater quality in this area needs an accurate evaluation. In this research, the fuzzy and Schoeller deterministic method assessed the Northern Dezful-Andimeshk Plain drinking water, and the results of both methods were used to zone and compare the drinking quality of the plain groundwater in the Arc GIS environment. The deterministic method classifies drinking water quality from good to bad. According to this method, 56.81% of the total area of the plain has good quality, 20.83% of the total area is acceptable, 18.77% of the total area has inappropriate quality, and 3.57% of the total area has bad quality. However, in the fuzzy method, groundwater in 21.6% of the total area of the plain with a confidence percentage of 70% to 81% is desirable, in 75.23% of the total area of the plain with a confidence percentage of 32% to 70% is acceptable, and 3.69% of the total area of the plain with drinking confidence of 20% to 22% is nonacceptable. The results showed that the fuzzy method is better than the Schoeller deterministic method because it reduces uncertainties, increases accuracy in the evaluation, increases flexibility in the threshold limits of water quality parameters, and provides a quantitative and qualitative assessment of drinking water. Also the zoning map obtained from this method is more compatible with environmental and pollution realities. Graphical Abstract
摘要德德梅西克平原北部地区饮用水的主要来源是地下水,部分地区地下水水质较差。因此,需要对该地区的地下水水质进行准确的评价。本研究采用模糊和Schoeller确定性评价方法对德德富-安迪梅斯克北部平原饮用水进行评价,并利用两种方法的评价结果对arcgis环境下平原地下水的饮用质量进行分区和比较。确定性方法将饮用水水质从好到坏进行分类。根据该方法,平原总面积中质量优良的占56.81%,质量尚可的占20.83%,质量不合格的占18.77%,质量差的占3.57%。然而,在模糊方法中,平原总面积的21.6%的地下水在70% ~ 81%的置信区间内是适宜的,平原总面积的75.23%的地下水在32% ~ 70%的置信区间内是可接受的,平原总面积的3.69%的地下水在20% ~ 22%的置信区间内是不可接受的。结果表明,模糊评价方法减少了不确定性,提高了评价的准确性,增加了水质参数阈值的灵活性,能够对饮用水进行定量和定性评价,优于Schoeller确定性评价方法。该方法得到的分区图也更符合环境和污染的实际情况。图形抽象
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引用次数: 0
Sorghum stover and winery solid wastes co-digestion: application of iron oxide nanoparticles for biogas yield optimisation 高粱秸秆和酒厂固体废物共消化:氧化铁纳米颗粒用于沼气产量优化的应用
Pub Date : 2023-11-02 DOI: 10.1007/s43832-023-00047-9
Carrelle G. Ossinga, Vincent I. Okudoh, Mahabubur R. Chowdhury
Abstract One approach to addressing energy security issues is to produce renewable and sustainable bioenergy using abundant waste resources through anaerobic co-digestion (AcoD). However, the lignocellulosic nature of these biomass resources makes them recalcitrant, and pretreatment is required to make them more amenable to conversion. Iron oxide nanoparticles (ION) have been shown to increase methane yield significantly when added to biomass resources. This study aimed to investigate the effect of ION application on Sorghum stover (SS) and Winery solid waste (WSW) under mesophilic conditions. Hydrothermal synthesis was used to obtain Fe 3 O 4 nanoparticles. Biomethane potential (BMP) tests were carried out in semi-continuous batch reactors with and without ION singly and combined SS: WSW (1:1) during a 30-day retention period. The results showed that the ION application on WSW delivered a higher biogas yield (380 mL), indicating an increase of 162% in biogas production compared to the sample without ION (145 mL). In addition, CH4 generation went from 30 to 114 mLCH4, indicating a 280% increase. However, adding ION to SS inhibited CH4 production. The study found that ION addition significantly improved biogas yield, especially with WSW, where the increase was more than triple, of interest to bioenergy and waste management practitioners. Graphic Abstract
摘要利用丰富的废弃物资源,通过厌氧共消化(AcoD)生产可再生和可持续的生物能源是解决能源安全问题的途径之一。然而,这些生物质资源的木质纤维素性质使它们具有顽固性,并且需要预处理以使它们更易于转化。氧化铁纳米颗粒(ION)添加到生物质资源中可以显著提高甲烷产量。本试验旨在研究中温条件下离子对高粱秸秆(SS)和酒庄固体废弃物(WSW)的处理效果。采用水热合成法制备了纳米fe3o4。生物甲烷势(BMP)在半连续间歇式反应器中进行,在30天的保留期内,分别有和没有离子,以及混合SS: WSW(1:1)。结果表明,离子在WSW上的应用产生了更高的沼气产量(380 mL),与没有离子的样品(145 mL)相比,沼气产量增加了162%。此外,CH4代从30 mLCH4增加到114 mLCH4,增加了280%。然而,向SS中添加离子抑制了CH4的产生。研究发现,离子的添加显著提高了沼气产量,尤其是WSW,其产量增加了三倍以上,这引起了生物能源和废物管理从业者的兴趣。图形抽象
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