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Construction of α-Ga2O3-ZnO heterojunction for a promoted performance applied in self-powered solar blind photodetector α-Ga2O3-ZnO异质结的构建提高了自供电太阳盲探测器的性能
Pub Date : 2022-07-29 DOI: 10.1051/epjap/2022220183
Wen-jing Liu, Jianrong Deng, Dan Zhang, Lijuan Huang, Zhengrui Hu, Shuren Zhou, Hong Zhang, Lijuan Ye, Yuanqiang Xiong, C. Kong, Honglin Li, Wanjun Li
Gallium oxide-based photoelectrochemical photodetectors (PEC-PDs) have received extensive attention due to their natural self-powered characteristic and detection capability in solar-blind region. In this work, α-Ga2O3 nanorods-ZnO nanoparticles heterojunction (α-Ga2O3-ZnO) are constructed on FTO conductive glass substrates as photoanodes for PEC-PDs. The efficient regulation of performance for α-Ga2O3-ZnO heterojunction PEC-PDs is achieved by varying the ZnO nanoparticles concentration. Experimental results show that all devices exhibit self-powered solar blind detection characteristics and the performance of devices prepared by α-Ga2O3-ZnO heterojunction is better than that of pristine α-Ga2O3. When the concentration of ZnO nanoparticles reaches to a certain value, the responsivity shows the maximum value as high as 32 mA/W, and the response time is as low as 0.25/0.18 s. Combined with first-principles calculations, the mechanism of the improved performance is discuss in detail. The results reveal that that the contact between α-Ga2O3 and ZnO can induce charges transfer, which constitutes a built-in electric field that acts as a driving force to separate the photogenerated carriers into different sections. This process can effectively prevent the recombination of photogenerated carriers, and prolong the lifetime of e--h+, thus improve the overall detection performance finally. This work will provide meaningful guidance for the development of novel high-performance self-powered solar-blind deep-UV photodetectors.
基于氧化镓的光电电化学光电探测器(pec - pd)因其天然的自供电特性和在太阳盲区的探测能力而受到广泛关注。在这项工作中,α-Ga2O3纳米棒- zno纳米异质结(α-Ga2O3- zno)被构建在FTO导电玻璃衬底上作为pec - pd的光阳极。α-Ga2O3-ZnO异质结pec - pd的性能可以通过改变ZnO纳米粒子的浓度来实现。实验结果表明,采用α-Ga2O3- zno异质结制备的器件具有自供电的太阳盲探测特性,性能优于原始α-Ga2O3制备的器件。当ZnO纳米粒子浓度达到一定值时,响应率最高可达32 mA/W,响应时间低至0.25/0.18 s。结合第一性原理计算,详细讨论了性能提高的机理。结果表明,α-Ga2O3与ZnO的接触可诱导电荷转移,并形成一个内置电场,作为驱动力将光生载流子分离成不同的部分。该工艺可以有效防止光生载流子的复合,延长e—h+的寿命,最终提高整体检测性能。该工作将为新型高性能自供电太阳盲深紫外光电探测器的开发提供有意义的指导。
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引用次数: 1
Modeling of nonlinear and hysteretic behaviors in the ferroelectric materials under strong electrical and mechanical driving levels 铁电材料在强电和机械驱动水平下的非线性和滞后行为建模
Pub Date : 2022-07-25 DOI: 10.1051/epjap/2022220091
A. Rjafallah, Y. Tabbai, A. Hajjaji, C. Ennawaoui
The piezo-ceramics have been using in many piezoelectric applications such as transducers, sensors and actuators. Under high mechanical and electrical strengths, the nonlinear behavior observed on these devices can describe by the second order piezoelectric constitutive equations. However, their hysteretic behavior cannot be described by these equations. In this paper, a more general theoretical model was developed to describe the nonlinear and hysteretic behaviors of the piezo-ceramics under high electrical and mechanical strengths. The model, based on the theory of Landau-Devonshire, can simulate the hysteresis cycles under the combined cyclic electric and static mechanical strengths. It can describe the evolution of the relative dielectric permittivity ε33 as a function of the applied electric field. Using the scaling law, it can also describe the evolution of the piezoelectric coefficient d33 as a function of the applied electric field.
压电陶瓷在传感器、传感器和致动器等领域有着广泛的应用。在高机械和电强度下,这些器件的非线性行为可以用二阶压电本构方程来描述。然而,它们的滞后行为不能用这些方程来描述。本文建立了一个更通用的理论模型来描述压电陶瓷在高电强度和机械强度下的非线性和滞后行为。该模型基于Landau-Devonshire理论,能够模拟在静、电复合机械强度作用下的滞回周期。它可以描述相对介电常数ε33随外加电场的变化规律。利用标度律还可以描述压电系数d33随外加电场的变化规律。
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引用次数: 0
Analysis and Experiment of an Airflow Energy Harvester based on Diamagnetic Levitation 基于反磁悬浮的气流能量采集器的分析与实验
Pub Date : 2022-07-20 DOI: 10.1051/epjap/2022220055
Jingyun Zhang, Yufeng Su
This paper proposes a set of energy harvesting structure that can effectively generate electrical power. Diamagnetic levitation structure is reported, with a floating magnet rotor levitated between two pyrolytic graphite plates just using a lifting magnet and airflow. The magnet rotor could be stably suspended under joint action of magnetic forces and diamagnetic forces, being driven to rotate by airflow. Three magnet rotors, with 1.5 mm, 3 mm and 4.5 mm thickness respectively, were adopted in the study so as to investigate the influence of structural parameters of the magnet rotor on the performance of the harvester. Simulation and experiment were carried out for the three magnet rotors. Among the tree magnet rotros, the 1.5mm-thick one has the best output performance , with the lowest dynamic stability. Therefore, the energy harvester is to find tradeoff between output characteristics and dynamics. In this work, it was discovered that the peak output voltage of the energy harvester increased with the square of flowrate. As the flowrate increased to 3000 sccm, the 1.5mm-thick rotor was rotating at a speed of 19729 rpm under standard temperature and pressure, with 1.255V output voltage and 98mW power. The diamagnetic levitation structure is expected to be applied to sensing, energy harvesting and air bearing under actuation of airflow due to its advantages of low friction, high rotation speed and large levitation space.
本文提出了一套能有效产生电能的能量收集结构。本文报道了一种反磁性悬浮结构,它是一种利用提升磁体和气流将浮磁转子悬浮在两个热解石墨板之间的结构。磁体转子在磁力和反磁力的共同作用下稳定悬浮,在气流的驱动下旋转。采用厚度分别为1.5 mm、3 mm和4.5 mm的3个磁性转子,研究磁性转子结构参数对收割机性能的影响。对三磁体转子进行了仿真和实验。在树磁转子中,1.5mm厚的输出性能最好,动态稳定性最低。因此,能量收集器就是要在输出特性和动力学之间找到平衡。在这项工作中,发现能量采集器的输出电压峰值随流量的平方而增加。当流量增加到3000 sccm时,1.5mm厚转子在标准温度和压力下以19729 rpm的转速旋转,输出电压为1.255V,功率为98mW。抗磁性悬浮结构具有摩擦小、转速高、悬浮空间大等优点,有望应用于气流驱动下的传感、能量收集和空气轴承等领域。
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引用次数: 0
Effective optical path length measurement of integrating cavity using time-resolved spectroscopy and tunable diode laser absorption spectroscopy 利用时间分辨光谱和可调谐二极管激光吸收光谱测量积分腔的有效光程长度
Pub Date : 2022-07-19 DOI: 10.1051/epjap/2022220076
Xue Zhou, Haiwei Li, Peng Hu
Integrating cavities are commonly used in trace gas detection and weak absorption measurement. Effective optical path length (EOPL) is an important index to evaluate the ability of increasing optical path length for an integrating cavity. The EOPL has been studied to be related to inner surface reflectivity, cavity shape and dimension, port fraction. For different spectroscopic techniques, whether the EOPL variation tendency is universally valid is investigated in this work. The EOPLs of a cubic integrating cavity in different port fractions have been measured using time-resolved spectroscopy and tunable diode laser absorption spectroscopy (TDLAS) respectively. With the increasing of the port fraction, the EOPL reduces gradually. However, measured EOPL results shows a deviation between the two technique methods. By analyzing, the deviation is caused by a reflectivity difference of the inner coating at different laser wavelength for the two spectral methods. By introduction of the reflectivity correction, the deviation could be eliminated. This demonstrates that EOPL extending law of integrating cavity was universally valid in different spectroscopy application.
积分腔常用于微量气体检测和弱吸收测量。有效光程长度(EOPL)是评价积分腔增加光程长度能力的重要指标。研究了EOPL与内表面反射率、空腔形状和尺寸、端口分数有关。对于不同的光谱技术,本文研究了EOPL的变化趋势是否普遍有效。利用时间分辨光谱和可调谐二极管激光吸收光谱(TDLAS)分别测量了不同端口分数的立方积分腔的eopl。随着端口分数的增加,EOPL逐渐减小。然而,测量的EOPL结果显示了两种技术方法之间的偏差。通过分析,两种光谱方法的偏差是由不同激光波长下内涂层的反射率差异引起的。通过引入反射率校正,可以消除这种偏差。这说明积分腔的EOPL扩展规律在不同的光谱应用中是普遍有效的。
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引用次数: 0
Study of Electrical Properties of Al/Si3N4/n-GaAs MIS capacitors deposited at low and high frequency PECVD 低频和高频PECVD沉积Al/Si3N4/n-GaAs MIS电容器的电学性能研究
Pub Date : 2022-07-19 DOI: 10.1051/epjap/2022220062
Wafaa Zibar, O. Richard, A. Drighil, T. Lachhab, Hasna Mziouek, V. Aimez, Abdellatif Jaouad, Rhma Adhiri
This paper presents a study on the fabrication and optimization of GaAs metal-insulator-semiconductor (MIS) structures, comprising Si3N4 as insulator deposited by the PECVD technique. In the RF plasma, the excitation frequencies used, are 380 KHz for the low frequency and 13.56 MHz for the higher frequency. Thanks to the established protocol, it was possible to develop several structures on n-GaAs substrate, to study effect of the surface treatment with sulfur, the deposition of the insulator by PECVD at low and high frequency, as well as the annealing of these structures. Detailed measurements of the capacitance-voltage and conductance-voltage characteristics of the MIS capacity revealed various anomalies. So, the interface properties the structures (MIS) of semiconductor GaAs with insulation metallic have been investigated. The growth of the Si3N4 layer by LF-PECVD on GaAs substrate treated with sulfur has an effect on the electrical properties of the MIS capacitys studied, leading to good capacitance-voltage (C-V) characteristics. The LF-PECVD was also effective in reducing the frequency dispersion, thus suggesting the removal of traps in n-GaAs located near the dielectric/GaAs interface. In contrast, the Si3N4 layer deposited by HF-PECVD method seems to increase the interfacial density of states near the mid-gap leading to a pinning of the Fermi level. At room temperature of measurement, a hysteresis effect was observed showing injection type effect.
本文研究了以氮化硅为绝缘体,采用PECVD技术沉积的砷化镓金属-绝缘体-半导体(MIS)结构的制备与优化。在射频等离子体中,使用的激励频率为低频380千赫,高频13.56兆赫。由于建立的协议,有可能在n-GaAs衬底上开发几种结构,研究硫表面处理的影响,PECVD在低频和高频下沉积绝缘体,以及这些结构的退火。对MIS容量的电容电压和电导电压特性的详细测量揭示了各种异常。因此,本文研究了半导体砷化镓与绝缘金属的界面特性。在经硫处理的GaAs衬底上通过LF-PECVD生长Si3N4层对MIS电容的电学性能产生了影响,从而获得了良好的电容电压(C-V)特性。LF-PECVD还可以有效地降低频率色散,从而表明去除介电/GaAs界面附近n-GaAs中的陷阱。相反,用HF-PECVD方法沉积的Si3N4层似乎增加了中隙附近的界面态密度,导致了费米能级的钉住。在室温下测量,观察到滞后效应,表现为注射型效应。
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引用次数: 0
Comparative study on thermally evaporated and solution processed cathode modifying layers in organic solar cells 有机太阳能电池中热蒸发和溶液法阴极改性层的比较研究
Pub Date : 2022-06-08 DOI: 10.1051/epjap/2022220143
Shang Feng, Zichen Liu, Hailiang Zhao, Qingqing Yang, Jidong Zhang, D. Qin
Organic solar cells have been fabricated using cathode modifying layers of thermally evaporated bathophenanthroline (Bphen), ytterbium doped Bphen (Bphen:Yb), and solution processed (N,N-dimethyl-ammonium N-oxide)propyl perylene diimide (PDINO). Compared to pristine Bphen, Bphen:Yb shows higher electron mobility and thereby increases fill factor of device, demonstrating the weak n-doping of Yb in Bphen. As a result of Fermi level pinning, Bphen:Yb forms an ohmic contact with photoactive layer, underpinning efficient electron transport and extraction of device. Compared to conventional PDINO, despite lower electron mobility, Bphen:Yb enables increased optical absorption of device and smoother morphology of device, thereby improving power conversion efficiency of device. The current research points out that the integration of thermally evaporated weakly n-doped cathode modifying layer and solution processed photoactive layer is a promising method to fabricate high-efficiency and low-cost organic solar cells.
采用热蒸发酞菲啉(Bphen)、掺镱酞菲啉(Bphen:Yb)和溶液处理(N,N-二甲基铵- N-氧化物)丙基苝二酰亚胺(PDINO)阴极修饰层制备了有机太阳能电池。与原始Bphen相比,Bphen:Yb显示出更高的电子迁移率,从而增加了器件的填充因子,表明Bphen中存在弱n掺杂Yb。由于费米能级的钉住,Bphen:Yb与光活性层形成欧姆接触,支撑了高效的电子传递和器件的提取。与传统的PDINO相比,尽管电子迁移率较低,但Bphen:Yb使器件的光吸收增加,器件的形貌更平滑,从而提高了器件的功率转换效率。目前的研究表明,将热蒸发弱氮掺杂阴极修饰层与溶液处理光活性层相结合是制备高效、低成本有机太阳能电池的一种很有前途的方法。
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引用次数: 1
Fabrication and Characterization of ITO/ZnO/Anthraquinone solid Dye-Sensitized Solar Cells ITO/ZnO/蒽醌固体染料敏化太阳能电池的制备与表征
Pub Date : 2022-06-06 DOI: 10.1051/epjap/2022220065
L. Nkhaili, A. El kissani, C. Liang, C. Naceur Abouloula, S. Hnawi, M. Ait Ali, A. Narjis, A. Outzourhit
The use of natural dyes as sensitizers in organic solar cells is getting more interest due to its green nature, nontoxicity, low cost and ecofriendly materials. In this paper, two antraquinone/zinc oxide-based dye-sensitized solar cells (DSSCs) were prepared by a simple and low cost method. The anthraquinone was extracted from Aloe-vera plant and was deposited as a thin film to study its structural and optical properties. ZnO nanoparticles and nanorods were prepared by the RF sputtering and electrodeposition methods, respectively.Glass/ITO/ZnO/anthraquinone/Al cell gave a remarkable photovoltaic activity.
天然染料因其绿色、无毒、低成本和材料环保等特点,在有机太阳能电池中作为增敏剂越来越受到人们的关注。本文采用简单、低成本的方法制备了两种蒽醌/氧化锌基染料敏化太阳能电池(DSSCs)。从芦荟植物中提取蒽醌并将其制成薄膜,研究其结构和光学性质。采用射频溅射和电沉积法制备了ZnO纳米颗粒和纳米棒。玻璃/ITO/ZnO/蒽醌/铝电池具有显著的光伏活性。
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引用次数: 0
Characterization of Earplugs based on Porous Polyurethane (PU) and Polyvinyl-Chloride (PVC) Polymers for Human Ear Protection 基于多孔聚氨酯(PU)和聚氯乙烯(PVC)聚合物的人耳保护耳塞的表征
Pub Date : 2022-06-06 DOI: 10.1051/epjap/2022220104
Penpen Komgue Lucrece Barbara, S. Assif, A. Faiz, C. Ennawaoui, J. Ducourneau, A. Hajjaji
Personal Ear Protection (PEP) is a device designed to reduce the effects of ambient noise on humans, thus limiting the risk of hearing damage. This damage mainly affects the entire auditory chain (from the tympanic membrane to the cochlea). The aim of this work is to carry out a study of the mechanical properties of the PEP studied to model it subsequently using the finite elements method (FEM). To this end, the aim of this paper will be the study of the morphological and mechanical performance of porous polymers to protect the human ear from vibrations. The influence of air content (Porosity rate, pore size and shape) on the elastic matrix and mechanical properties of porous polymers (Young's modulus and Poisson's ratio) produced from available commercial Polyurethane (PU) and Polyvinyl-Chloride (PVC) were examined and discussed. The authors present a mathematical model that is able to predict the Young’s modulus of porous polymers as a function of matrix characteristics, mechanical excitation and porosity percentage. Porosimeter, Scanning Electron Microscope (SEM) and Light Microscope (LM) techniques are used for morphological characterizations. PU and PVC earplugs are effective for sound reduction, so they can be used for other applications.
个人耳保护(PEP)是一种旨在减少环境噪声对人类影响的设备,从而限制听力损伤的风险。这种损伤主要影响整个听觉链(从鼓膜到耳蜗)。本工作的目的是对所研究的PEP的力学性能进行研究,并随后使用有限元法(FEM)对其进行建模。为此,本文的目的将是研究多孔聚合物的形态和力学性能,以保护人耳免受振动。考察和讨论了空气含量(孔隙率、孔径和形状)对现有商用聚氨酯(PU)和聚氯乙烯(PVC)制备的多孔聚合物弹性基体和力学性能(杨氏模量和泊松比)的影响。作者提出了一个数学模型,该模型能够预测多孔聚合物的杨氏模量作为基质特性、力学激励和孔隙率的函数。孔隙度计,扫描电子显微镜(SEM)和光学显微镜(LM)技术用于形态学表征。PU和PVC耳塞可以有效地减少声音,因此它们可以用于其他应用。
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引用次数: 0
Structural, dielectric and optical properties of Ta2O5-Bi2O3-P2O5 phosphate glasses Ta2O5-Bi2O3-P2O5磷酸盐玻璃的结构、介电和光学性质
Pub Date : 2022-06-01 DOI: 10.1051/epjap/2022220138
M. Laourayed, Y. Alaoui, A. Er-rafai, M. El Mouzahim, M. El Moudane, M. Abid, Mestapha Beraich, A. Guenbour, A. Bellaouchou
Glass with 5Ta2O5, xBi2O3, (95–x)P2O5 for 10≤ x ≤ 20 mol % formula was obtained by the normal melt-quench technique and identified by DRX, DSC analysis, Infrared spectroscopy, and followed by the study of the dielectric and optical properties. Glass transition temperature (Tg) is found to grow linearlywith bismuth oxide concentration and goes from 524°C for x=10 to 582°C for x=20 mol %. The density ρ increases with increasing Bi2O3 content and molar volume (VM) diminish when Bi2O3 content rises. The IR study shows the presence of BiO6 and PO3 structural groups and reveals depolymerization of the phosphate links by the creation of the Bi–O–P groups which are due to the incorporation of Bi–O bonds. The partial replacement of P2O5 by Bi2O3 shows that the variation of ɛr' and tan δ depend on Bi2O3 contents. By UV absorption, optical properties of glasses were found in the wavelength limit from 250 to 800nm. The energy band gap was calculated using the optical absorption spectrum and was interpreted as a reflection of the structural changes that take place in the glasses as the Bi2O3 content increases.
采用熔融淬火法制备了5Ta2O5、xBi2O3、(95-x)P2O5为10≤x≤20 mol %配方的玻璃,通过DRX、DSC分析、红外光谱对其进行了鉴定,并对其介电性能和光学性能进行了研究。玻璃化转变温度(Tg)随氧化铋浓度线性增长,从524°C (x=10 mol %)到582°C (x=20 mol %)。密度ρ随Bi2O3含量的增加而增大,摩尔体积(VM)随Bi2O3含量的增加而减小。红外光谱研究显示了BiO6和PO3结构基团的存在,并揭示了由于Bi-O键的结合而产生的Bi-O - p基团使磷酸键解聚。Bi2O3对P2O5的部分取代表明,ir′和tan δ随Bi2O3含量的变化而变化。通过紫外吸收,在250 ~ 800nm波长范围内发现了玻璃的光学性质。利用光学吸收光谱计算了能带隙,并将其解释为随着Bi2O3含量的增加,玻璃中发生的结构变化的反映。
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引用次数: 0
Effect of coalesce doping of Li and Bi on structural, optical and dielectric properties of TCO anatase TiO2 nanoparticles Li和Bi聚结掺杂对TCO锐钛矿型TiO2纳米颗粒结构、光学和介电性能的影响
Pub Date : 2022-06-01 DOI: 10.1051/epjap/2022220043
A. Dakhel
Anatase (TiO2) ceramic nanoparticle (NPs) powder doped with Bi/Li ions was synthesized by a facial precipitation method. The structural, optical, and electrical properties of the NP powders were studied by X‐Ray diffraction, diffuse reflection spectroscopy (DRS), and the AC dielectric measurements. It was concluded that it is possible to construct a core/shell structure in TiO2 ceramic by doping with Bi ions. Thus, the dielectric measurements show the creation of colossal permittivity (CP) of magnitude ’ ~103 in the frequency range: 1 ≤f ≤100kHz. The CP results were explained within the framework of the core/shell model and doping mechanisms. It was found the present CP phenomenon can be switched off by Li co-doping, which was explained within the framework of doping mechanisms.
采用面相沉淀法合成了掺杂Bi/Li离子的锐钛矿(TiO2)陶瓷纳米颗粒(NPs)。通过X射线衍射、漫反射光谱(DRS)和交流介电测量研究了NP粉末的结构、光学和电学性能。结果表明,在TiO2陶瓷中掺杂Bi离子,可以构建核/壳结构。因此,介电测量表明,在1≤f≤100kHz的频率范围内,产生了巨大的介电常数(CP),其量级为1 ~103。在核/壳模型和掺杂机制的框架内解释了CP结果。研究发现,Li共掺杂可以阻断目前的CP现象,并在掺杂机制框架内解释了这一现象。
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引用次数: 2
期刊
The European Physical Journal Applied Physics
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