首页 > 最新文献

The European Physical Journal Applied Physics最新文献

英文 中文
On the Meniscus Shape and Marangoni Flow in Capillary Tubes with Noncircular Cross-Section Shapes 非圆形毛细管中半月板形状和马兰戈尼流动的研究
Pub Date : 2022-09-06 DOI: 10.1051/epjap/2022220208
Aiqiang Chen, Haoyan Zhang, Jianfei Song, Bin Liu, Chensi Zhang, P. Theodorakis
The liquid–vapor interface remains a key point for improving the heat transfer efficiency of heat exchangers. In this paper, we report experimental results on the evaporation of ethanol in capillary tubes of different internal cross-sections as the bulk meniscus recedes inside the tube, since the chosen conditions allow for the development of a liquid film along tube's internal corners due to the presence of capillary forces. To achieve our aims, we used 3D video microscopy to monitor the behavior of the meniscus during evaporation and, also, calculated the capillary pressures for three channels with different cross-sectional shapes each, namely circular, square and equilateral triangle cross-sections, for three solid–liquid contact angles, i.e., 30°, 60°, and 90°. At the same time, we have combined infrared thermal imaging technology with particle imaging velocimetry (PIV) visualization technology to analyze the severe Marangoni convection at the included angle. To this end, the interfacial temperature distribution of Marangoni convection was measured by means of an infrared camera and the flow pattern by means of PIV, respectively, through the plane in various views. For capillary tubes with included angle, the temperature gradient at the meniscus reaches its maximum at the included angle. Moreover, both temperature and convective gradients exist in the liquid film with included angle. When the angle of the capillary tube is smaller, the capillary effect will increase, leading to the formation of a thicker film. Our investigation constitutes an "extreme" experiment of Marangoni flow at the corners of the capillary tube. Due to the capillary forces, liquid films can rise in the corners of polygonal tubes up to the entrance of the tubes. Furthermore, the wetting force of ethanol at the angle of the triangle tube is much larger than that in the case of the square tube. Finally, the Marangoni vortex flows from the relatively high-temperature region in the center of the liquid towards the included angle, where evaporation is faster and the recharge of material and energy is more concentrated. We anticipate that our study sheds light into the meniscus shape and Marangoni flow in capillary tubes of with cross-sections of different shapes, which is of fundamental importance for various applications and in particular microfluidic systems.
汽液界面是提高换热器换热效率的关键。在本文中,我们报告了乙醇在不同内部横截面的毛细管中蒸发的实验结果,因为所选择的条件允许由于毛细管力的存在而沿着管的内角形成液体膜。为了实现我们的目标,我们使用3D视频显微镜来监测半月板在蒸发过程中的行为,并计算了三个不同横截面形状的通道的毛细管压力,即圆形、正方形和等边三角形横截面,三个固液接触角,即30°、60°和90°。同时,我们将红外热成像技术与粒子成像测速(PIV)可视化技术相结合,对夹角处的剧烈马兰戈尼对流进行了分析。为此,利用红外摄像机和PIV分别测量了马兰戈尼对流在不同视角下的界面温度分布和流态。对于具有夹角的毛细管,半月板处的温度梯度在夹角处达到最大。此外,含角液膜中同时存在温度梯度和对流梯度。当毛细管的角度越小,毛细管效应就会增大,导致形成较厚的膜。我们的研究构成了毛细管角落马兰戈尼流动的“极端”实验。由于毛细力的作用,液体膜可以在多角形管的角部上升到管的入口。此外,乙醇在三角形管角度处的润湿力比在方形管角度处的润湿力大得多。最后,Marangoni涡旋从液体中心相对高温的区域向夹角方向流动,在夹角处蒸发更快,物质和能量的补给更集中。我们期望我们的研究能够揭示不同形状横截面毛细管的半月板形状和马兰戈尼流,这对于各种应用,特别是微流体系统具有重要的基础意义。
{"title":"On the Meniscus Shape and Marangoni Flow in Capillary Tubes with Noncircular Cross-Section Shapes","authors":"Aiqiang Chen, Haoyan Zhang, Jianfei Song, Bin Liu, Chensi Zhang, P. Theodorakis","doi":"10.1051/epjap/2022220208","DOIUrl":"https://doi.org/10.1051/epjap/2022220208","url":null,"abstract":"The liquid–vapor interface remains a key point for improving the heat transfer efficiency of heat exchangers. In this paper, we report experimental results on the evaporation of ethanol in capillary tubes of different internal cross-sections as the bulk meniscus recedes inside the tube, since the chosen conditions allow for the development of a liquid film along tube's internal corners due to the presence of capillary forces. To achieve our aims, we used 3D video microscopy to monitor the behavior of the meniscus during evaporation and, also, calculated the capillary pressures for three channels with different cross-sectional shapes each, namely circular, square and equilateral triangle cross-sections, for three solid–liquid contact angles, i.e., 30°, 60°, and 90°. At the same time, we have combined infrared thermal imaging technology with particle imaging velocimetry (PIV) visualization technology to analyze the severe Marangoni convection at the included angle. To this end, the interfacial temperature distribution of Marangoni convection was measured by means of an infrared camera and the flow pattern by means of PIV, respectively, through the plane in various views. For capillary tubes with included angle, the temperature gradient at the meniscus reaches its maximum at the included angle. Moreover, both temperature and convective gradients exist in the liquid film with included angle. When the angle of the capillary tube is smaller, the capillary effect will increase, leading to the formation of a thicker film. Our investigation constitutes an \"extreme\" experiment of Marangoni flow at the corners of the capillary tube. Due to the capillary forces, liquid films can rise in the corners of polygonal tubes up to the entrance of the tubes. Furthermore, the wetting force of ethanol at the angle of the triangle tube is much larger than that in the case of the square tube. Finally, the Marangoni vortex flows from the relatively high-temperature region in the center of the liquid towards the included angle, where evaporation is faster and the recharge of material and energy is more concentrated. We anticipate that our study sheds light into the meniscus shape and Marangoni flow in capillary tubes of with cross-sections of different shapes, which is of fundamental importance for various applications and in particular microfluidic systems.","PeriodicalId":301303,"journal":{"name":"The European Physical Journal Applied Physics","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126909184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance of a dual piezoceramic cantilever for low frequency energy harvesting applications: modeling and experiment verification 用于低频能量收集的双压电悬臂梁的性能:建模和实验验证
Pub Date : 2022-09-02 DOI: 10.1051/epjap/2022220105
M. Yessari, Najoua Fangachi, I. Salhi, M. Rguiti, A. Hajjaji
Vibration-based energy harvesting is a growing field for generating low-power electricity to use in wireless electronic devices. These applications are usually in an environment of abundant low frequency vibration, which can be collected through an appropriate energy conversion structure. However, traditional energy conversion architectures such as cantilever-cantilever type or spring-mass type have the problem of high working frequency and narrow bandwidth (limiting its use and far from the frequency found in the surrounding environment). To overcome these challenges, this work proposes a study of a piezoelectric vibration energy harvester based on a dual cantilever structure. The energy harvesting system is designed, analyzed and verified with the finite element analysis method and an experimental study. The results show that the bandwidth is enlarged of 30 Hz and a power is generated and equals to the sum of the power generated by each cantilever (190 nW) with an output voltage supplying a resistive load of 110 KΏ.
基于振动的能量收集是一个不断发展的领域,用于产生用于无线电子设备的低功耗电力。这些应用通常是在低频振动丰富的环境中,可以通过适当的能量转换结构来收集低频振动。然而,传统的能量转换架构,如悬臂-悬臂式或弹簧-质量式,存在工作频率高、带宽窄的问题(限制了它的使用,远离周围环境的频率)。为了克服这些挑战,本工作提出了一种基于双悬臂结构的压电振动能量采集器的研究。利用有限元分析方法和实验研究对能量收集系统进行了设计、分析和验证。结果表明,带宽增加了30 Hz,产生的功率等于每个悬臂梁产生的功率之和(190 nW),输出电压为110 KΏ提供电阻性负载。
{"title":"Performance of a dual piezoceramic cantilever for low frequency energy harvesting applications: modeling and experiment verification","authors":"M. Yessari, Najoua Fangachi, I. Salhi, M. Rguiti, A. Hajjaji","doi":"10.1051/epjap/2022220105","DOIUrl":"https://doi.org/10.1051/epjap/2022220105","url":null,"abstract":"Vibration-based energy harvesting is a growing field for generating low-power electricity to use in wireless electronic devices. These applications are usually in an environment of abundant low frequency vibration, which can be collected through an appropriate energy conversion structure. However, traditional energy conversion architectures such as cantilever-cantilever type or spring-mass type have the problem of high working frequency and narrow bandwidth (limiting its use and far from the frequency found in the surrounding environment). To overcome these challenges, this work proposes a study of a piezoelectric vibration energy harvester based on a dual cantilever structure. The energy harvesting system is designed, analyzed and verified with the finite element analysis method and an experimental study. The results show that the bandwidth is enlarged of 30 Hz and a power is generated and equals to the sum of the power generated by each cantilever (190 nW) with an output voltage supplying a resistive load of 110 KΏ.","PeriodicalId":301303,"journal":{"name":"The European Physical Journal Applied Physics","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129016978","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural, dielectric, and electrical study of bismuth ferrite-lithium vanadate 铋铁氧体-钒酸锂的结构、电介质和电学研究
Pub Date : 2022-08-29 DOI: 10.1051/epjap/2022220031
Meena Kumari Sahu, P. Mallick, S. K. Satpathy, B. Behera
The composite, BiFeO3-LiVO3 was synthesized through a solid-state reaction technique. The X-ray diffraction (XRD) confirmed the formation of the tetragonal structure at room temperature. The dielectric constant and dielectric loss increases with rise in temperature. The Nyquist plot projected the contribution of bulk effect and a slight indication of grain boundary effect. The presence of a temperature-dependent relaxation process occurred in the material. Electrical modulus confirmed the non-Debye type and indicated the asymmetric peak broadening for the spread of relaxation times. The activation energies were calculated from the ac conductivity by linear fitting. The activation energy calculated from the complex impedance plot and the fitted Johnscher power law was very close which implied a similar type of charge carrier which exists in the conduction mechanism for the system. Thermistor parameters were evaluated using the grain resistance for different temperatures.
采用固相反应技术合成了BiFeO3-LiVO3复合材料。x射线衍射(XRD)证实了在室温下形成的四方结构。介电常数和介电损耗随温度的升高而增大。Nyquist图预测了体效应的贡献,并有一点晶界效应的指示。材料中出现了温度相关的弛豫过程。电模量证实了非debye型,并显示了弛豫时间扩散的不对称峰展宽。用线性拟合的方法,从交流电导率计算活化能。由复阻抗图计算得到的活化能与拟合的Johnscher幂定律非常接近,表明该体系的传导机制中存在相似类型的载流子。利用晶粒电阻对不同温度下的热敏电阻参数进行了评估。
{"title":"Structural, dielectric, and electrical study of bismuth ferrite-lithium vanadate","authors":"Meena Kumari Sahu, P. Mallick, S. K. Satpathy, B. Behera","doi":"10.1051/epjap/2022220031","DOIUrl":"https://doi.org/10.1051/epjap/2022220031","url":null,"abstract":"The composite, BiFeO3-LiVO3 was synthesized through a solid-state reaction technique. The X-ray diffraction (XRD) confirmed the formation of the tetragonal structure at room temperature. The dielectric constant and dielectric loss increases with rise in temperature. The Nyquist plot projected the contribution of bulk effect and a slight indication of grain boundary effect. The presence of a temperature-dependent relaxation process occurred in the material. Electrical modulus confirmed the non-Debye type and indicated the asymmetric peak broadening for the spread of relaxation times. The activation energies were calculated from the ac conductivity by linear fitting. The activation energy calculated from the complex impedance plot and the fitted Johnscher power law was very close which implied a similar type of charge carrier which exists in the conduction mechanism for the system. Thermistor parameters were evaluated using the grain resistance for different temperatures.","PeriodicalId":301303,"journal":{"name":"The European Physical Journal Applied Physics","volume":"44 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121979905","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hybrid Nanofluids Multi performance optimizations for the Cooling System coupling with Hybrid Photovoltaic Thermal Collectors 混合纳米流体与混合光伏集热器耦合冷却系统的多重性能优化
Pub Date : 2022-08-26 DOI: 10.1051/epjap/2022220117
Khadija Chakar, C. Ennawaoui, M. El Mouden, A. Hajjaji
Hybrid photovoltaic thermal (PVT) collectors have assumed considerable importance for their dual-energy applicability which is presented in thermal and electrical form. The thermal behavior of the hybrid collector plays an ameliorative role in dissipating the heat generated in the cell, and this increases the electrical efficiency accordingly with the help of a coolant fluid (nanofluids).The contribution of this study is to evaluate the potential interest of nanofluids in the cooling system of a photovoltaic thermal system (PVT) by modeling and comparing the thermal conductivity of TiO2-Water, Cu-Water nanofluids and of TiO2/Cu-Water hybrid nanofluid, also their thermal capacity and viscosity. Programs have been developed with volume concentrations from 0% to 4% and from 0% to 10% with constant temperature and nanoparticles diameter. The results show that all thermophysical properties characterizing the heat transfer are more important in a hybrid nanofluid compared to the simple nanofluid, such us for a nanoparticle volume fraction of 3%, the thermal conductivity and thermal capacity increased by 32% and 0.23% respectively, for a volume fraction range of 0 to 10%, while they show an increase of 12% and 0.22% respectively, for a range of 0 to 4%. Eventually the model agreed with experimental results.
混合光电热(PVT)集热器以热和电两种形式表现出双能适用性,因此具有相当重要的意义。混合集热器的热行为在消散电池中产生的热量方面起着改善作用,并在冷却液(纳米流体)的帮助下相应地提高了电效率。本研究的贡献是通过模拟和比较TiO2-水、cu -水纳米流体和TiO2/ cu -水混合纳米流体的导热性、热容量和粘度,来评估纳米流体在光伏热系统(PVT)冷却系统中的潜在价值。在恒定温度和纳米颗粒直径下,体积浓度从0%到4%和从0%到10%的程序已经开发出来。结果表明,与简单纳米流体相比,混合纳米流体中表征传热的所有热物理性质都更为重要,例如当纳米颗粒体积分数为3%时,在体积分数为0 ~ 10%的范围内,导热系数和热容量分别增加32%和0.23%,而在体积分数为0 ~ 4%的范围内,导热系数和热容量分别增加12%和0.22%。最终,模型与实验结果一致。
{"title":"Hybrid Nanofluids Multi performance optimizations for the Cooling System coupling with Hybrid Photovoltaic Thermal Collectors","authors":"Khadija Chakar, C. Ennawaoui, M. El Mouden, A. Hajjaji","doi":"10.1051/epjap/2022220117","DOIUrl":"https://doi.org/10.1051/epjap/2022220117","url":null,"abstract":"Hybrid photovoltaic thermal (PVT) collectors have assumed considerable importance for their dual-energy applicability which is presented in thermal and electrical form. The thermal behavior of the hybrid collector plays an ameliorative role in dissipating the heat generated in the cell, and this increases the electrical efficiency accordingly with the help of a coolant fluid (nanofluids).The contribution of this study is to evaluate the potential interest of nanofluids in the cooling system of a photovoltaic thermal system (PVT) by modeling and comparing the thermal conductivity of TiO2-Water, Cu-Water nanofluids and of TiO2/Cu-Water hybrid nanofluid, also their thermal capacity and viscosity. Programs have been developed with volume concentrations from 0% to 4% and from 0% to 10% with constant temperature and nanoparticles diameter. The results show that all thermophysical properties characterizing the heat transfer are more important in a hybrid nanofluid compared to the simple nanofluid, such us for a nanoparticle volume fraction of 3%, the thermal conductivity and thermal capacity increased by 32% and 0.23% respectively, for a volume fraction range of 0 to 10%, while they show an increase of 12% and 0.22% respectively, for a range of 0 to 4%. Eventually the model agreed with experimental results.","PeriodicalId":301303,"journal":{"name":"The European Physical Journal Applied Physics","volume":"30 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129492429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Examples of SVD decomposition contributions to the non-destructive testing of cultural heritage mural paintings using stimulated infrared thermography SVD分解对利用受激红外热成像技术无损检测文物壁画的贡献
Pub Date : 2022-08-25 DOI: 10.1051/epjap/2022220088
Jean Luc Bodnar, K. Mouhoubi, Jean Marc Vallet
Stimulated infrared thermography has already shown its possibilities concerning the heritage mural paintings conservation. However, the different colors of the pictorial layer can, in certain unfavorable cases, lead to artefacts detection. Moreover, the fragility of these works of art requires the least energetic analyzes possible. In the work presented here, we show that the association of an SVD analysis with stimulated infrared thermography, seems to allow on the one hand, a notable reduction of this disturbing optical effect. We show on the other hand, that it seems to allow an early detection of these defects and therefore a lower energy deposit on studied works of art.
受激红外热成像技术在文物壁画保护方面已经显示出了它的可能性。然而,在某些不利的情况下,图像层的不同颜色可能导致伪影检测。此外,这些艺术品的脆弱性需要尽可能少的精力分析。在这里提出的工作中,我们表明SVD分析与受激红外热成像的关联,似乎一方面允许显著减少这种令人不安的光学效应。另一方面,我们表明,它似乎允许早期发现这些缺陷,因此较低的能量沉积在研究的艺术作品。
{"title":"Examples of SVD decomposition contributions to the non-destructive testing of cultural heritage mural paintings using stimulated infrared thermography","authors":"Jean Luc Bodnar, K. Mouhoubi, Jean Marc Vallet","doi":"10.1051/epjap/2022220088","DOIUrl":"https://doi.org/10.1051/epjap/2022220088","url":null,"abstract":"Stimulated infrared thermography has already shown its possibilities concerning the heritage mural paintings conservation. However, the different colors of the pictorial layer can, in certain unfavorable cases, lead to artefacts detection. Moreover, the fragility of these works of art requires the least energetic analyzes possible. In the work presented here, we show that the association of an SVD analysis with stimulated infrared thermography, seems to allow on the one hand, a notable reduction of this disturbing optical effect. We show on the other hand, that it seems to allow an early detection of these defects and therefore a lower energy deposit on studied works of art.","PeriodicalId":301303,"journal":{"name":"The European Physical Journal Applied Physics","volume":"124 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123199680","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of the corrosion inhibition of C38 steel in a 1M HCl medium by the etanoic extract of Rumex Nervosus Vahl leaves 芦笋叶乙酸提取物在1M HCl介质中对C38钢的缓蚀作用研究
Pub Date : 2022-08-23 DOI: 10.1051/epjap/2022220130
Hefdh aldeen Al-sharabi, F. Bouhlal, Khalid Bouiti, Meriem Bensmlali, N. Labjar, Ghita Amine Benabdellah, Abdelwahed Dahrouch, S. Laasri, M. El Mahi, El Mostapha Lotfi, Bouchaib El Otmani, S. El hajjaji
The efficacy of Rumex Nervosus Vahl Leaves Ethanolic extract (RNVLE) to inhibit C38 steel corrosion in one molar hydrochloric acid medium was examined using electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. Polarization measurements revealed mixed-type inhibitor behavior. The inhibitory efficacy assessed by both polarization and (EIS) techniques was consistent, with an IE value of (96.0 %) and (95.5 %) at 2g/L of RNVLE, respectively. The RNVLE adsorption on the C38 metal surfaces in 1M HCl follows the Langmuir adsorption isotherm. The calculated free energy (G°ads equal to -16.1 KJ mol-1) explained that RNVLE controls the corrosion process by physisorption. The effect of immersion time was also investigated. This study demonstrated that RNVLE can be considered an excellent inhibitor up to 6 hours and after this time; it is considered a lower quality inhibitor although it still has sufficient inhibitory ability. SEM-EDX (Scanning Electron Microscopy and X-ray Energy Dispersive Spectroscopy) analysis revealed that the extract molecules adsorb on the metal's surface. These findings indicate that RNVLE can be used as an effective corrosion inhibitor for C38 steel in 1M HCl solution.
采用电化学阻抗谱法(EIS)和动电位极化法研究了荆刺叶乙醇提取物(RNVLE)在一摩尔盐酸介质中对C38钢的腐蚀作用。极化测量显示混合型抑制剂的行为。极化法和EIS法测定的抑制效果一致,在2g/L RNVLE下,IE值分别为96.0%和95.5%。在1M盐酸溶液中,RNVLE在C38金属表面的吸附遵循Langmuir吸附等温线。计算得到的自由能(G°ads = -16.1 KJ mol-1)说明RNVLE通过物理吸附控制腐蚀过程。研究了浸渍时间的影响。该研究表明,RNVLE可以被认为是长达6小时及之后的优秀抑制剂;虽然它仍有足够的抑制能力,但被认为是一种质量较低的抑制剂。SEM-EDX(扫描电子显微镜和x射线能量色散光谱)分析显示,提取物分子吸附在金属表面。结果表明,RNVLE可作为C38钢在1M HCl溶液中的有效缓蚀剂。
{"title":"Study of the corrosion inhibition of C38 steel in a 1M HCl medium by the etanoic extract of Rumex Nervosus Vahl leaves","authors":"Hefdh aldeen Al-sharabi, F. Bouhlal, Khalid Bouiti, Meriem Bensmlali, N. Labjar, Ghita Amine Benabdellah, Abdelwahed Dahrouch, S. Laasri, M. El Mahi, El Mostapha Lotfi, Bouchaib El Otmani, S. El hajjaji","doi":"10.1051/epjap/2022220130","DOIUrl":"https://doi.org/10.1051/epjap/2022220130","url":null,"abstract":"The efficacy of Rumex Nervosus Vahl Leaves Ethanolic extract (RNVLE) to inhibit C38 steel corrosion in one molar hydrochloric acid medium was examined using electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization. Polarization measurements revealed mixed-type inhibitor behavior. The inhibitory efficacy assessed by both polarization and (EIS) techniques was consistent, with an IE value of (96.0 %) and (95.5 %) at 2g/L of RNVLE, respectively. The RNVLE adsorption on the C38 metal surfaces in 1M HCl follows the Langmuir adsorption isotherm. The calculated free energy (G°ads equal to -16.1 KJ mol-1) explained that RNVLE controls the corrosion process by physisorption. The effect of immersion time was also investigated. This study demonstrated that RNVLE can be considered an excellent inhibitor up to 6 hours and after this time; it is considered a lower quality inhibitor although it still has sufficient inhibitory ability. SEM-EDX (Scanning Electron Microscopy and X-ray Energy Dispersive Spectroscopy) analysis revealed that the extract molecules adsorb on the metal's surface. These findings indicate that RNVLE can be used as an effective corrosion inhibitor for C38 steel in 1M HCl solution.","PeriodicalId":301303,"journal":{"name":"The European Physical Journal Applied Physics","volume":"27 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122419888","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tuning half metallic ferromagnetic character in Rh and Tc doping Cerium dioxide for spintronic applications 自旋电子应用中Rh和Tc掺杂二氧化铈半金属铁磁特性的调谐
Pub Date : 2022-08-17 DOI: 10.1051/epjap/2022220197
D. Drissi, F. Goumrhar, R. Ahl Laamara
In this paper, we investigate, for the rst time, the effect of Rhoduim (Rh) and Technetium (Tc) on the electronic and magnetic properties of dilute magnetic semiconductor CeO2 using the Korringa-Kohn-Rostoker (KKR) method combined with the generalized gradient approximation (GGA). Three differents concentrations (x = 0:05; 0:10; 0:15) are considered. The energy diagram of density of states reveals that the dopent changes CeO2 from a non magnetic semaicondtor to ferromegnetic half metals. Furthermore, the energy variation ensures the stability of the ferromagnetic phase due to double exchange mechanism. The Curie of temperature are evaluated and are ell found to be above room temperature. The present findings model new potential candidates for spintronics.
本文首次利用Korringa-Kohn-Rostoker (KKR)方法结合广义梯度近似(GGA)研究了铑(Rh)和锝(Tc)对稀磁性半导体CeO2的电子和磁性能的影响。三种不同的浓度(x = 0:05;0:10;0:15)被考虑。态密度能量图表明,掺杂使CeO2由非磁性半导体转变为铁磁性半金属。此外,由于双交换机制,能量的变化保证了铁磁相的稳定性。计算了温度的居里曲线,发现温度高于室温。目前的发现为自旋电子学建立了新的潜在候选模型。
{"title":"Tuning half metallic ferromagnetic character in Rh and Tc doping Cerium dioxide for spintronic applications","authors":"D. Drissi, F. Goumrhar, R. Ahl Laamara","doi":"10.1051/epjap/2022220197","DOIUrl":"https://doi.org/10.1051/epjap/2022220197","url":null,"abstract":"In this paper, we investigate, for the rst time, the effect of Rhoduim (Rh) and Technetium (Tc) on the electronic and magnetic properties of dilute magnetic semiconductor CeO2 using the Korringa-Kohn-Rostoker (KKR) method combined with the generalized gradient approximation (GGA). Three differents concentrations (x = 0:05; 0:10; 0:15) are considered. The energy diagram of density of states reveals that the dopent changes CeO2 from a non magnetic semaicondtor to ferromegnetic half metals. Furthermore, the energy variation ensures the stability of the ferromagnetic phase due to double exchange mechanism. The Curie of temperature are evaluated and are ell found to be above room temperature. The present findings \u0000model new potential candidates for spintronics.","PeriodicalId":301303,"journal":{"name":"The European Physical Journal Applied Physics","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133018680","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Angular Distribution of Particles Sputtered from the Vanadium Target by 5 keV Kr Ions: Simulation Study 5 keV氪离子溅射钒靶颗粒角分布的模拟研究
Pub Date : 2022-08-09 DOI: 10.1051/epjap/2022220201
K. Bria, M. Ait El Fqih, A. Afkir, L. Jadoual, A. Kaddouri
The sputtering of vanadium particles at normal incidence wassimulated. The SRIM-code combined to a new ANGULAIR and SDTrimSPsimulation was employed to obtain the sputtering yields and the angular distribution of the atoms. The simulation was made for a large number of incident Kr+ions with 5 keV energy, letting the computer count the number of emitted particles in the solid angle. The angular distribution of differential sputtering yields of vanadium shows an over-cosine tendency.
对正常入射下钒颗粒的溅射进行了模拟。采用strim -code结合新的ANGULAIR和SDTrimSPsimulation模拟得到了溅射产率和原子的角分布。对大量5kev能量的Kr+离子入射进行了模拟,让计算机计算出在实体角发射粒子的数量。钒的微分溅射产率的角分布呈过余弦趋势。
{"title":"Angular Distribution of Particles Sputtered from the Vanadium Target by 5 keV Kr Ions: Simulation Study","authors":"K. Bria, M. Ait El Fqih, A. Afkir, L. Jadoual, A. Kaddouri","doi":"10.1051/epjap/2022220201","DOIUrl":"https://doi.org/10.1051/epjap/2022220201","url":null,"abstract":"The sputtering of vanadium particles at normal incidence wassimulated. The SRIM-code combined to a new ANGULAIR and SDTrimSPsimulation was employed to obtain the sputtering yields and the angular distribution of the atoms. The simulation was made for a large number of incident Kr+ions with 5 keV energy, letting the computer count the number of emitted particles in the solid angle. The angular distribution of differential sputtering yields of vanadium shows an over-cosine tendency.","PeriodicalId":301303,"journal":{"name":"The European Physical Journal Applied Physics","volume":"12 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126676922","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrical properties of Ba0.85Ca0.15Zr0.1Ti0.9O3 ceramics with TiO2 addition 添加TiO2后Ba0.85Ca0.15Zr0.1Ti0.9O3陶瓷的电学性能
Pub Date : 2022-08-04 DOI: 10.1051/epjap/2022220151
Xianwei Wang, Shuying Chen, Yifan Liang, Bihui Zhang, Xiaoling Shi, Ruoyu Zhang, Yujia Shi, Ziyi Ren, R. Liu, Yanchun Hu, J. Shang, Shaoqian Yin
The crystal structure, microstructure, dielectric properties and energy storage properties of Ba0.85Ca0.15Zr0.1Ti0.9O3 (BCZT) ceramics with various TiO2 (0%, 1%, 8%, 40%, 50%, 60%) addition ceramics were discussed. Although the perovskite structure remained in samples with low content of TiO2, the secondary phase Ba2Ti5.5O13 appeared in samples with high TiO2 content. According to SEM results, the addition of TiO2 resulted in a significant decrease in the average grain size. Wtih the addition of TiO2, the phase transition temperature, corresponding to Curie temperature (Tc) of BCZT ceramics shifts to lower temperature. Compared with the pure BCZT ceramic, the higher impedance and slimmer hysteresis loops were realized in ceramics with high TiO2 content. The relatively large energy storage density (Wrec ~0.52 J/cm3) together with energy storage efficiency (η ~74.84%) were achieved in ceramic with 40% TiO2 content. When the contentration of TiO2 further increases, the energy storage efficiency increased, but the energy storage density declined. The present research provides a method to improve the energy storage performance of BCZT ceramics.
研究了不同TiO2添加量(0%、1%、8%、40%、50%、60%)的Ba0.85Ca0.15Zr0.1Ti0.9O3 (BCZT)陶瓷的晶体结构、微观结构、介电性能和储能性能。在TiO2含量低的样品中,钙钛矿结构仍然存在,而在TiO2含量高的样品中,出现了二次相Ba2Ti5.5O13。SEM结果显示,TiO2的加入使平均晶粒尺寸明显减小。随着TiO2的加入,BCZT陶瓷的相变温度,即居里温度(Tc)向更低的温度移动。与纯BCZT陶瓷相比,高TiO2含量的陶瓷具有更高的阻抗和更细的磁滞回线。当TiO2含量为40%时,陶瓷具有较大的储能密度(Wrec ~0.52 J/cm3)和储能效率(η ~74.84%)。当TiO2浓度进一步增加时,储能效率提高,但储能密度下降。本研究为提高BCZT陶瓷的储能性能提供了一种方法。
{"title":"Electrical properties of Ba0.85Ca0.15Zr0.1Ti0.9O3 ceramics with TiO2 addition","authors":"Xianwei Wang, Shuying Chen, Yifan Liang, Bihui Zhang, Xiaoling Shi, Ruoyu Zhang, Yujia Shi, Ziyi Ren, R. Liu, Yanchun Hu, J. Shang, Shaoqian Yin","doi":"10.1051/epjap/2022220151","DOIUrl":"https://doi.org/10.1051/epjap/2022220151","url":null,"abstract":"The crystal structure, microstructure, dielectric properties and energy storage properties of Ba0.85Ca0.15Zr0.1Ti0.9O3 (BCZT) ceramics with various TiO2 (0%, 1%, 8%, 40%, 50%, 60%) addition ceramics were discussed. Although the perovskite structure remained in samples with low content of TiO2, the secondary phase Ba2Ti5.5O13 appeared in samples with high TiO2 content. According to SEM results, the addition of TiO2 resulted in a significant decrease in the average grain size. Wtih the addition of TiO2, the phase transition temperature, corresponding to Curie temperature (Tc) of BCZT ceramics shifts to lower temperature. Compared with the pure BCZT ceramic, the higher impedance and slimmer hysteresis loops were realized in ceramics with high TiO2 content. The relatively large energy storage density (Wrec ~0.52 J/cm3) together with energy storage efficiency (η ~74.84%) were achieved in ceramic with 40% TiO2 content. When the contentration of TiO2 further increases, the energy storage efficiency increased, but the energy storage density declined. The present research provides a method to improve the energy storage performance of BCZT ceramics.","PeriodicalId":301303,"journal":{"name":"The European Physical Journal Applied Physics","volume":"51 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-08-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115699220","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Improving dielectric properties of composites thin films with polylactic acid and PZT microparticles induced by interfacial polarization 界面极化诱导聚乳酸- PZT复合薄膜介电性能的改善
Pub Date : 2022-08-02 DOI: 10.1051/epjap/2022220110
El mahdi Bouiri, R. Farhan, N. Chakhchaoui, K. Oumghar, Cenk Denktaş, A. Eddiai, M. Meddad, M. Mazroui, O. Cherkaoui, Lhaj El Hachemi Omari
Although polylactic acid (PLA) is widely identified as a biodegradable polymer, its use is limited due to the inherently poor mechanical properties. Therefore, the strengthening of PLA with microscale particles like lead zirconate titanate (PZT) is a promising field of research that has only just begun to be explored. Piezoelectric polymer-PZT films are encouraging materials for modern applications. PLA/PZT composites have been elaborated with diverse content of PZT employing a solvent casting technique. The mechanical characteristics and dielectric properties of the considered films were investigated. X-ray Diffraction (XRD). Fourier Transform Infrared (FTIR) Spectroscopy and Scanning Electron Microscopy (SEM) were used to examine the influence of these fillers at the molecular level, crystal structural change, micro charges dispersion inside the polymer matrix, and Thermogravimetric Analysis (TGA) was used to examine the stability and thermal degradation of the films. The change in these properties as a function of content (0.1–1 wt. %) of PZT has also been investigated. It is found that the PZT incorporation induces a considerable influence on the transformation of the α→β phase. The result can lead to a significant improvement in the dielectric and piezoelectric properties of PLA/PZT composite.
虽然聚乳酸(PLA)被广泛认为是一种可生物降解的聚合物,但由于其固有的较差的力学性能,其应用受到限制。因此,用锆钛酸铅(PZT)等微尺度颗粒增强PLA是一个很有前景的研究领域,目前才刚刚开始探索。压电聚合物- pzt薄膜是一种具有现代应用前景的材料。采用溶剂铸造技术制备了不同PZT含量的PLA/PZT复合材料。研究了所考虑薄膜的力学特性和介电性能。x射线衍射(XRD)。利用傅里叶变换红外光谱(FTIR)和扫描电镜(SEM)分析了这些填料在分子水平、晶体结构变化、聚合物基体内部微电荷分散等方面的影响,并用热重分析(TGA)分析了膜的稳定性和热降解性。这些性质随PZT含量(0.1-1 wt. %)的变化也进行了研究。结果表明,PZT的掺入对α→β相的转变有较大的影响。该结果可显著改善PLA/PZT复合材料的介电和压电性能。
{"title":"Improving dielectric properties of composites thin films with polylactic acid and PZT microparticles induced by interfacial polarization","authors":"El mahdi Bouiri, R. Farhan, N. Chakhchaoui, K. Oumghar, Cenk Denktaş, A. Eddiai, M. Meddad, M. Mazroui, O. Cherkaoui, Lhaj El Hachemi Omari","doi":"10.1051/epjap/2022220110","DOIUrl":"https://doi.org/10.1051/epjap/2022220110","url":null,"abstract":"Although polylactic acid (PLA) is widely identified as a biodegradable polymer, its use is limited due to the inherently poor mechanical properties. Therefore, the strengthening of PLA with microscale particles like lead zirconate titanate (PZT) is a promising field of research that has only just begun to be explored. Piezoelectric polymer-PZT films are encouraging materials for modern applications. PLA/PZT composites have been elaborated with diverse content of PZT employing a solvent casting technique. The mechanical characteristics and dielectric properties of the considered films were investigated. X-ray Diffraction (XRD). Fourier Transform Infrared (FTIR) Spectroscopy and Scanning Electron Microscopy (SEM) were used to examine the influence of these fillers at the molecular level, crystal structural change, micro charges dispersion inside the polymer matrix, and Thermogravimetric Analysis (TGA) was used to examine the stability and thermal degradation of the films. The change in these properties as a function of content (0.1–1 wt. %) of PZT has also been investigated. It is found that the PZT incorporation induces a considerable influence on the transformation of the α→β phase. The result can lead to a significant improvement in the dielectric and piezoelectric properties of PLA/PZT composite.","PeriodicalId":301303,"journal":{"name":"The European Physical Journal Applied Physics","volume":"9 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129585935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
期刊
The European Physical Journal Applied Physics
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1