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Entropy-Stabilized Engineering Enables Stable High-Voltage Phosphate Cathode Materials for Sodium-Ion Batteries 熵稳定工程为钠离子电池提供稳定的高压磷酸盐正极材料
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-04 DOI: 10.1016/j.ensm.2026.104964
Xiaohao Liu, Xiaoyue Zhang, Longhai Zhang, Xin Tan, Li Li, Weibo Hua, Chaofeng Zhang, Shulei Chou
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引用次数: 0
A Farewell Message from the Founding Editor-in-Chief, Prof. Hui-Ming Cheng 创刊总编辑郑慧明教授的告别辞
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-04 DOI: 10.1016/j.ensm.2026.104962
Hui-Ming Cheng
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引用次数: 0
Tailored Material Design and Scalable Integration of 3D-Printed Flexible Batteries for Wearable Electronics: A Comprehensive Review 可穿戴电子产品3d打印柔性电池的定制材料设计和可扩展集成:综合综述
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-04 DOI: 10.1016/j.ensm.2026.104966
Wenting Li, Diquan Xu, Rui Wang, Mohsen Shakouri, Huan Pang
The burgeoning field of wearable flexible electronics has generated a pressing need for electrochemical energy storage (EES) systems that combine high electrochemical performance with excellent mechanical compliance. Additive manufacturing (AM), also known as 3D printing, has emerged as a transformative approach, offering unparalleled advantages in structural design freedom, material efficiency, and device customization. These capabilities make AM a disruptive technology for the production of next-generation flexible batteries. This article systematically reviews recent advancements in 3D-printed flexible energy storage devices, providing a comprehensive overview of the most widely used AM techniques in the field of flexible electronics. Each technique is rigorously evaluated in terms of its technological distinctiveness and suitability for specific applications. Furthermore, the review discusses material selection strategies for 3D-printed flexible batteries, with critical assessment of advanced functional materials for use in electrodes, separators, and electrolytes. Finally, based on persistent challenges—such as the limited synergy between materials and processes, and the trade-off between printing resolution and efficiency—future research directions are proposed.
随着可穿戴柔性电子领域的蓬勃发展,对兼具高电化学性能和优异机械顺应性的电化学储能系统产生了迫切的需求。增材制造(AM),也被称为3D打印,已经成为一种变革性的方法,在结构设计自由度、材料效率和设备定制方面具有无与伦比的优势。这些能力使增材制造成为生产下一代柔性电池的颠覆性技术。本文系统回顾了3d打印柔性储能器件的最新进展,全面概述了柔性电子领域应用最广泛的增材制造技术。每种技术都严格评估其技术独特性和特定应用的适用性。此外,该综述还讨论了3d打印柔性电池的材料选择策略,并对用于电极、分离器和电解质的先进功能材料进行了关键评估。最后,基于材料和工艺之间有限的协同作用以及打印分辨率和效率之间的权衡等持续存在的挑战,提出了未来的研究方向。
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引用次数: 0
Frustrated Oxygen Loss Enabled by Magnesium Migration in O3-Type Anionic Redox Cathodes for Sodium-Ion Batteries 镁在钠离子电池o3型阴离子氧化还原阴极中的迁移使氧损失减小
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-04 DOI: 10.1016/j.ensm.2026.104963
Shaoyu Yang, Pu Yan, Qinzhe Liu, Zhipeng Chen, Yixiao Qiu, Guangsu Tan, Hao Chen, WenChang Hou, Yiyang Qu, Renshu Wang, Bo Zhang, Zhengyan Lun, Kecheng Cao, Xuerong Liu, Chao Xu
O3-type manganese-based anionic redox cathode materials, characterized by high initial sodium content, high capacity, and low cost, are promising candidates for advanced sodium-ion batteries. However, achieving controllable oxygen anionic redox remains challenging due to complex synthesis and a limited understanding of irreversible degradation during cycling. This work introduces a series of O3-type Na1-xLi1/3-xMgxMn2/3O2 (NLMMO, x = 0, 1/12, and 1/6) cathodes exhibiting anionic redox activity, synthesized via precise control over sodium stoichiometry, calcination temperature and atmosphere. Importantly, the partial substitution of magnesium for lithium markedly improves the reversibility of oxygen redox, as evidenced by a significant decrease in oxygen release during charging. Owing to the unique characteristic of these O3-type materials—the absence of phase transitions—the beneficial effect is ascribed to magnesium interlayers migration, which kinetically impedes manganese intralayer migration and vacancy clustering. Limiting the excessive formation of Mn3+ for NLMMO-1/6 leads to excellent cycling stability, demonstrating 85.5% capacity retention over 120 cycles in full cells, a significant improvement compared to the 36.5% retention observed without Mg substitution. These insights advance fundamental understanding of synthesizing O3-type anionic redox cathodes and their redox mechanism, guiding the design of next-generation sodium-ion batteries.
o3型锰基阴离子氧化还原正极材料具有初始钠含量高、容量大、成本低等特点,是先进钠离子电池的理想材料。然而,由于复杂的合成和对循环过程中不可逆降解的有限了解,实现可控氧阴离子氧化还原仍然具有挑战性。本文介绍了一系列具有阴离子氧化还原活性的o3型Na1-xLi1/3-xMgxMn2/3O2 (NLMMO, x = 0,1 /12和1/6)阴极,通过精确控制钠化学计量、煅烧温度和气氛合成。重要的是,镁部分取代锂显著提高了氧氧化还原的可逆性,这一点可以从充电过程中氧气释放的显著减少中得到证明。由于这些o3型材料的独特特性——没有相变——镁的层间迁移是有益的,它在动力学上阻碍了锰的层内迁移和空位聚集。限制NLMMO-1/6中Mn3+的过量形成导致了优异的循环稳定性,在满电池中120次循环中显示出85.5%的容量保持率,与没有Mg取代的36.5%的容量保持率相比有显着提高。这些发现促进了对o3型阴离子氧化还原阴极的合成及其氧化还原机制的基本理解,指导了下一代钠离子电池的设计。
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引用次数: 0
Smoothing S8 Redox Conversions in Lean Ester Electrolytes by Nucleophilic Shielding and Polar ZnS Electrovalent Mediation: toward Near-Practical S Cathodes 通过亲核屏蔽和极性ZnS电介质平滑贫酯电解质中的S8氧化还原转化:接近实用的S阴极
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-03 DOI: 10.1016/j.ensm.2026.104958
Zhihao Yan, Chunyan Ye, Jianhui Zhu, Lu Zhang, Junxiang Wang, Maowen Xu, Jian Jiang
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引用次数: 0
Bioinspired Aerogel-Confined Phase Change Materials for High-Performance Thermal Rectification and Device Cooling 用于高性能热整流和器件冷却的生物气凝胶约束相变材料
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-03 DOI: 10.1016/j.ensm.2026.104961
Zubair Ashraf, Akbar Bashir, Ali Usman, Mulin Qin, Atif Nazir, Haiwei Han, Kaihang Jia, Sadia Noreen, Waseem Aftab, Zhenghui Shen, Ruqiang Zou
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引用次数: 0
Localized insight into potential-switched structure and hierarchical transport of water-in-salt electrolyte at electrified interfaces 电化界面上盐包水电解质的电位开关结构和分层输运的局部研究
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-03 DOI: 10.1016/j.ensm.2026.104959
Water-in-salt (WIS) electrolytes offer high energy density and excellent stability in energy conversion and storage. A precise assessment of their str…
盐包水(WIS)电解质具有高能量密度和优异的能量转换和储存稳定性。对他们能力的精确评估……
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引用次数: 0
Tree Frog–Inspired Indoor Architectural Skin: Scalable, Leak–Proof, Bondable Thermal Energy Storage Wood for Low–Carbon Buildings 受树蛙启发的室内建筑表皮:可伸缩、防漏、可粘合的低碳建筑储热木材
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-03 DOI: 10.1016/j.ensm.2026.104948
Zhichen Ba, Fanjun Yu, Haobo Fan, Zengcheng He, Xinyan Fan, Yimin Shi, Yaobo Wang, Xi Li, Yongzheng Li, Dumindu Peththa Wadu, Daxin Liang, Yonggui Wang, Hao Zhang, Chunlin Xu, Zefang Xiao, Zhe Qiu, Haigang Wang, Yanjun Xie
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引用次数: 0
Tailoring electrochemical interface to regulate competition between Zn deposition and hydrogen evolution in aqueous rechargeable batteries 调整电化学界面以调节水可充电电池中锌沉积和析氢之间的竞争
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-03 DOI: 10.1016/j.ensm.2026.104960
Minhyung Kwon, Seungyun Jeon, Uichan Hwang, Eunji Kwon, Hee-Kang Shin, Seungho Yu, Dong-Ik Kim, Jihyun Hong, Minah Lee
The practical implementation of aqueous Zn-ion batteries (AZIBs) is hindered by the irreversibility of Zn metal anodes, which suffer from heterogeneous electrodeposition coupled with parasitic hydrogen evolution reactions (HER). While substrate engineering is essential to address this issue, the HER activity of substrates and its modulation to achieve homogeneous Zn nucleation and growth have been largely overlooked. Here, we investigate the interplay between HER suppression and Zn deposition behavior by tailoring surface chemistry of Cu current collectors. Specifically, we introduce a deep eutectic solvent (DES) treatment that simultaneously removes native oxides and forms a choline-derived organic nanolayer on Cu surface as an alternative to conventional acid or thermal pretreatments. This unique interface not only inhibits proton reduction but also promotes conformal Cu–Zn alloy formation, thereby enhancing Zn binding and further suppressing HER. Such dynamic surface evolution collectively mitigates insulating byproducts formation and enables dense Zn growth with enlarged grains (>2 μm) and a thickness closely matching that of Zn foil (106%). Consequently, Zn anodes deposited on DES-treated Cu deliver a cumulative capacity of 5.8 Ah cm-2 at 30% depth of discharge (DOD) and retain 2.2 Ah cm-2 even at 50% DOD, highlighting their potential for practical, high-performance AZIBs.
锌金属阳极受非均相电沉积和寄生析氢反应的影响,其不可逆性阻碍了水溶液锌离子电池(AZIBs)的实际应用。虽然衬底工程对于解决这一问题至关重要,但衬底的HER活性及其调制以实现均匀的Zn成核和生长在很大程度上被忽视了。在这里,我们通过调整Cu集流器的表面化学来研究HER抑制和Zn沉积行为之间的相互作用。具体来说,我们介绍了一种深度共晶溶剂(DES)处理,它可以同时去除天然氧化物,并在铜表面形成胆碱衍生的有机纳米层,作为传统酸或热预处理的替代方法。这种独特的界面不仅抑制了质子还原,还促进了Cu-Zn共形合金的形成,从而增强了Zn的结合,进一步抑制了HER。这种动态的表面演化共同减轻了绝缘副产物的形成,使致密的Zn生长,晶粒扩大(>2 μm),厚度与Zn箔(106%)非常接近。因此,沉积在des处理过的Cu上的Zn阳极在30%放电深度(DOD)下的累积容量为5.8 Ah cm-2,即使在50%放电深度下也保持2.2 Ah cm-2,这突出了它们作为实用的高性能azib的潜力。
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引用次数: 0
Review on single-crystalline oxide cathode materials for next-generation Na-ion batteries 新一代钠离子电池单晶氧化物正极材料研究进展
IF 20.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-02-02 DOI: 10.1016/j.ensm.2026.104957
Guang-Xu Wei, Xu Zhu, Xin-Yu Zhang, Mengting Liu, Peng-Fei Wang
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引用次数: 0
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Energy Storage Materials
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