Energy Storage Materials最新文献

英文中文

Towards high-performance sodium-ion batteries: A comprehensive review on NaxNiyFezMn1−(y+z)O2 cathode materials

IF 18.9 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Energy Storage Materials

Pub Date : 2025-04-01 DOI: 10.1016/j.ensm.2025.104212

Alibi Namazbay , Maksat Karlykan , Lunara Rakhymbay , Zhumabay Bakenov , Natalia Voronina , Seung-Taek Myung , Aishuak Konarov

Sodium-ion batteries (SIBs) are potential candidates for next-generation grid-scale energy storage owing to their safety as well as the abundance of sodium resources. Further progress in SIB technology demands the advancement of cathode materials with outstanding performance. Among various cathode materials, layered transition metal oxides based on Ni, Fe, and Mn (NaNFM) have recently received great attention by combining the positive features of each of them. This review focuses on the most current developments in the study and design of NaNFM (Na_xNi_yFe_zMn_{1−(_y+}_z₎O₂) as a cathode material for SIBs, including synthesis methods, crystal structure/structural evolution during charge–discharging, and the effect of different molar ratios. Adjusting the transition elements enables formation in several phases that promote Na-ion diffusion, resulting in high-rate capability and cycle stability. Moreover, key strategies to improve the electrochemical performance through doping and surface modifications are discussed. Future optimization of these materials shows potential for enormous opportunities for implementing cost-effective and high-performance energy -storage technologies.

{"title":"Towards high-performance sodium-ion batteries: A comprehensive review on NaxNiyFezMn1−(y+z)O2 cathode materials","authors":"Alibi Namazbay , Maksat Karlykan , Lunara Rakhymbay , Zhumabay Bakenov , Natalia Voronina , Seung-Taek Myung , Aishuak Konarov","doi":"10.1016/j.ensm.2025.104212","DOIUrl":"10.1016/j.ensm.2025.104212","url":null,"abstract":"<div><div>Sodium-ion batteries (SIBs) are potential candidates for next-generation grid-scale energy storage owing to their safety as well as the abundance of sodium resources. Further progress in SIB technology demands the advancement of cathode materials with outstanding performance. Among various cathode materials, layered transition metal oxides based on Ni, Fe, and Mn (NaNFM) have recently received great attention by combining the positive features of each of them. This review focuses on the most current developments in the study and design of NaNFM (Na<em><sub>x</sub></em>Ni<em><sub>y</sub></em>Fe<em><sub>z</sub></em>Mn<sub>1−(<em><sub>y</sub></em>+</sub><em><sub>z</sub></em><sub>)</sub>O<sub>2</sub>) as a cathode material for SIBs, including synthesis methods, crystal structure/structural evolution during charge–discharging, and the effect of different molar ratios. Adjusting the transition elements enables formation in several phases that promote Na-ion diffusion, resulting in high-rate capability and cycle stability. Moreover, key strategies to improve the electrochemical performance through doping and surface modifications are discussed. Future optimization of these materials shows potential for enormous opportunities for implementing cost-effective and high-performance energy -storage technologies.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"77 ","pages":"Article 104212"},"PeriodicalIF":18.9,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143723843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Polymer dielectrics intercalated with a non-contiguous granular nanolayer for high-temperature pulsed energy storage

IF 18.9 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Energy Storage Materials

Pub Date : 2025-04-01 DOI: 10.1016/j.ensm.2025.104213

Peng Yin , Li Lei , Qingyang Tang , Davoud Dastan , Yao Liu , Hong Wang , Zhicheng Shi

Polymer dielectrics suffer from significant degradation in energy density and charge–discharge efficiency at high temperatures, and incorporating inorganic nanofillers into polymer is the most straightforward and effective approach to ameliorate this behavior. However, the nanofillers are prone to form aggregated state driven by surface energy and electrostatic forces, compromising high-temperature energy storage performance of dielectrics. Here, we propose a unique non-contiguous granular intercalation strategy to solve the nanofiller aggregation problem. Specifically, an intercalation consisting of non-contiguous distributed aluminum@alumina (Al@AlO_x) core–shell nanoparticles is introduced into polyetherimide (PEI) matrix via sputtering reaction. It should be noted that the non-contiguous distribution of nanoparticles within the intercalation ensures discontinuous charge transport, which prevents the formation of conductive network within the nanocomposite. Additionally, benefiting from charge trap induced by wide-bandgap AlO_x shell and Coulomb blockade effect of Al core, the charge transport is significantly suppressed. The nanocomposite achieves ultrahigh energy densities of 9.0 J cm⁻³ at 150 °C and 6.2 J cm⁻³ at 200 °C, with charge–discharge efficiencies ≥ 90 %. This work offers a promising pathway for the design of high-temperature energy storage dielectrics and holds huge potential for scalable fabrication.

{"title":"Polymer dielectrics intercalated with a non-contiguous granular nanolayer for high-temperature pulsed energy storage","authors":"Peng Yin , Li Lei , Qingyang Tang , Davoud Dastan , Yao Liu , Hong Wang , Zhicheng Shi","doi":"10.1016/j.ensm.2025.104213","DOIUrl":"10.1016/j.ensm.2025.104213","url":null,"abstract":"<div><div>Polymer dielectrics suffer from significant degradation in energy density and charge–discharge efficiency at high temperatures, and incorporating inorganic nanofillers into polymer is the most straightforward and effective approach to ameliorate this behavior. However, the nanofillers are prone to form aggregated state driven by surface energy and electrostatic forces, compromising high-temperature energy storage performance of dielectrics. Here, we propose a unique non-contiguous granular intercalation strategy to solve the nanofiller aggregation problem. Specifically, an intercalation consisting of non-contiguous distributed aluminum@alumina (Al@AlO<sub>x</sub>) core–shell nanoparticles is introduced into polyetherimide (PEI) matrix via sputtering reaction. It should be noted that the non-contiguous distribution of nanoparticles within the intercalation ensures discontinuous charge transport, which prevents the formation of conductive network within the nanocomposite. Additionally, benefiting from charge trap induced by wide-bandgap AlO<sub>x</sub> shell and Coulomb blockade effect of Al core, the charge transport is significantly suppressed. The nanocomposite achieves ultrahigh energy densities of 9.0 J cm⁻<sup>3</sup> at 150 °C and 6.2 J cm⁻<sup>3</sup> at 200 °C, with charge–discharge efficiencies ≥ 90 %. This work offers a promising pathway for the design of high-temperature energy storage dielectrics and holds huge potential for scalable fabrication.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"77 ","pages":"Article 104213"},"PeriodicalIF":18.9,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143767710","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advanced design strategies for enhancing the thermal stability of Ni-rich co-free cathodes towards high-energy power lithium-ion batteries

IF 18.9 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Energy Storage Materials

Pub Date : 2025-04-01 DOI: 10.1016/j.ensm.2025.104216

Hao Ge , Bei Huang , Chaoyue Wang , Longhui Xie , Ruicong Pan , Xiaoman Cao , Zhijia Sun

The global market share of electric vehicles has rapidly grown from ∼10 % in 2022 to ∼18 % in 2024. However, safety issue is a crucial obstacle hindering the commercialization of high-energy lithium-ion batteries. The inferior thermal stability exhibited by high-energy Ni-rich cathodes has severely affected their practical application in LIBs. Particularly, Co in Ni-rich cathodes promotes lattice oxygen release, leading to reduced structural and thermal stability. Therefore, the development of Ni-rich Co-free cathode materials (NRCFs) is promising. Herein, the detrimental effects of Co on the thermal stability of Ni-rich layered oxides are demonstrated. Thereafter, we summarize in detail the popular modification strategies and mechanisms for enhancing the thermal stability of NRCFs. Finally, conclusions and future challenges and prospects for boosting the thermal stability of NRCFs are presented. Notably, synergistic modification strategies combining high-entropy doping and surface coating in single-crystal cathode materials is an efficient approach to significantly improve the thermal stability. Understanding the thermal stability of NRCFs has become urgent for the large-scale application of high-energy LIBs. More effective thermal safety strategies will be aroused to promote the development of next-generation power LIBs. This review aims to inspire further exploration of safer NRCFs featuring higher reversible capacity, attracting interest from both academic and industrial communities to accelerate the commercialization of NRCFs and promote the sustainable development of high-energy LIBs.

{"title":"Advanced design strategies for enhancing the thermal stability of Ni-rich co-free cathodes towards high-energy power lithium-ion batteries","authors":"Hao Ge , Bei Huang , Chaoyue Wang , Longhui Xie , Ruicong Pan , Xiaoman Cao , Zhijia Sun","doi":"10.1016/j.ensm.2025.104216","DOIUrl":"10.1016/j.ensm.2025.104216","url":null,"abstract":"<div><div>The global market share of electric vehicles has rapidly grown from ∼10 % in 2022 to ∼18 % in 2024. However, safety issue is a crucial obstacle hindering the commercialization of high-energy lithium-ion batteries. The inferior thermal stability exhibited by high-energy Ni-rich cathodes has severely affected their practical application in LIBs. Particularly, Co in Ni-rich cathodes promotes lattice oxygen release, leading to reduced structural and thermal stability. Therefore, the development of Ni-rich Co-free cathode materials (NRCFs) is promising. Herein, the detrimental effects of Co on the thermal stability of Ni-rich layered oxides are demonstrated. Thereafter, we summarize in detail the popular modification strategies and mechanisms for enhancing the thermal stability of NRCFs. Finally, conclusions and future challenges and prospects for boosting the thermal stability of NRCFs are presented. Notably, synergistic modification strategies combining high-entropy doping and surface coating in single-crystal cathode materials is an efficient approach to significantly improve the thermal stability. Understanding the thermal stability of NRCFs has become urgent for the large-scale application of high-energy LIBs. More effective thermal safety strategies will be aroused to promote the development of next-generation power LIBs. This review aims to inspire further exploration of safer NRCFs featuring higher reversible capacity, attracting interest from both academic and industrial communities to accelerate the commercialization of NRCFs and promote the sustainable development of high-energy LIBs.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"77 ","pages":"Article 104216"},"PeriodicalIF":18.9,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143734486","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Engineering high-performance argyrodite sulfide electrolytes via metal halide doping for all-solid-state lithium metal batteries

IF 18.9 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Energy Storage Materials

Pub Date : 2025-04-01 DOI: 10.1016/j.ensm.2025.104221

Yang Li , Gang Wu , Xiaomeng Fan , Dabing Li , Hong Liu , Xiaoxue Zhao , Wanqing Ren , Peng Lei , Xianyi Zhao , Xun Wang , Guoxu Wang , Lei Gao , Ce-Wen Nan , Li-Zhen Fan

Solid-state electrolytes (SSEs) play a crucial role in the operation of all-solid-state lithium metal batteries (ASSLMBs). Among them, sulfide SSEs have attracted particular attention due to their high ionic conductivity. However, the incompatibility of sulfide SSEs with lithium anodes and the inherent air instability severely impact battery cycling performance. Here, we successfully synthesize halogen-rich lithium argyrodites with the general formula Li_5.5 ₊ _3xP_1−xCu_xS_4.5Cl_1.5 ₋ _2xBr_2x. The incorporation of Cu and Br alter the spatial arrangement and electronic distribution of structure. Given that the anion disorder positively affects Li-ion dynamics, the ultrahigh ionic conductivity of 10.3 mS cm⁻¹ at room temperature has been achieved in Li_5.8P_0.9Cu_0.1S_4.5Cl_1.3Br_0.2 (LPSC-CB). Importantly, benefiting from the robust and stable interlayer, the lithium symmetric batteries deliver prolonged plating/stripping over 3000 h at 0.2 mA cm⁻². Furthermore, the density functional theory calculations were used to prove the mechanisms of high chemical stability. Notably, the LPSC-CB electrolyte has remarkable applicability in ASSLMBs. The full batteries of FeS₂/LPSC-CB/Li deliver outstanding discharge-specific capacities of 788.9 mAh g⁻¹ and robust cycling stability (>4.02 mAh cm⁻² after 200 cycles). The versatile CuBr₂ substitution in the most promising argyrodite electrolytes is considered as a valid strategy to realize high ionic conductivity and air-stabilized sulfide SSEs for large-scale applications.

{"title":"Engineering high-performance argyrodite sulfide electrolytes via metal halide doping for all-solid-state lithium metal batteries","authors":"Yang Li , Gang Wu , Xiaomeng Fan , Dabing Li , Hong Liu , Xiaoxue Zhao , Wanqing Ren , Peng Lei , Xianyi Zhao , Xun Wang , Guoxu Wang , Lei Gao , Ce-Wen Nan , Li-Zhen Fan","doi":"10.1016/j.ensm.2025.104221","DOIUrl":"10.1016/j.ensm.2025.104221","url":null,"abstract":"<div><div>Solid-state electrolytes (SSEs) play a crucial role in the operation of all-solid-state lithium metal batteries (ASSLMBs). Among them, sulfide SSEs have attracted particular attention due to their high ionic conductivity. However, the incompatibility of sulfide SSEs with lithium anodes and the inherent air instability severely impact battery cycling performance. Here, we successfully synthesize halogen-rich lithium argyrodites with the general formula Li<sub>5.5</sub> <sub>+</sub> <sub>3x</sub>P<sub>1−x</sub>Cu<sub>x</sub>S<sub>4.5</sub>Cl<sub>1.5</sub> <sub>−</sub> <sub>2x</sub>Br<sub>2x</sub>. The incorporation of Cu and Br alter the spatial arrangement and electronic distribution of structure. Given that the anion disorder positively affects Li-ion dynamics, the ultrahigh ionic conductivity of 10.3 mS cm<sup>−1</sup> at room temperature has been achieved in Li<sub>5.8</sub>P<sub>0.9</sub>Cu<sub>0.1</sub>S<sub>4.5</sub>Cl<sub>1.3</sub>Br<sub>0.2</sub> (LPSC-CB). Importantly, benefiting from the robust and stable interlayer, the lithium symmetric batteries deliver prolonged plating/stripping over 3000 h at 0.2 mA cm<sup>−2</sup>. Furthermore, the density functional theory calculations were used to prove the mechanisms of high chemical stability. Notably, the LPSC-CB electrolyte has remarkable applicability in ASSLMBs. The full batteries of FeS<sub>2</sub>/LPSC-CB/Li deliver outstanding discharge-specific capacities of 788.9 mAh g<sup>−1</sup> and robust cycling stability (>4.02 mAh cm<sup>−2</sup> after 200 cycles). The versatile CuBr<sub>2</sub> substitution in the most promising argyrodite electrolytes is considered as a valid strategy to realize high ionic conductivity and air-stabilized sulfide SSEs for large-scale applications.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"77 ","pages":"Article 104221"},"PeriodicalIF":18.9,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143737274","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Achieving superior high-temperature capacitance performance in aromatic polyetherimide with bulky fluorine substituent

IF 18.9 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Energy Storage Materials

Pub Date : 2025-04-01 DOI: 10.1016/j.ensm.2025.104206

Xinru Yang, Yang Feng, Peiyan Liu, Liuhao Jiang, Shuo Zhang, Yifan Wu, Shengtao Li

The rapid development of electronic and electrical power equipment has increased the demand for dielectric materials with high-temperature energy storage performances. However, the mutual restrictions imposed by the glass transition temperature (T_g) and bandgap (E_g) limit the use of commercial polyetherimide (PEI) under extreme conditions. In this work, we propose a strategic modular structure design to balance a high T_g and large E_g by modulating the substituents in the biphenyl structure of modified PEI. Both experimental results and theoretical simulations indicates that owing to its electron-withdrawing nature, a bulky -CF₃ substituent not only increases the bandgap but also decreases the conjugation effect of the biphenyl structure, while having a minimal effect on T_g. This significantly shortens the hopping distance of the carriers, ultimately improving the high-temperature breakdown strength (E_b) and thus the capacitance performance of PEI. The modified PEI with the bulky -CF₃ achieves a discharge energy density (U_e) of 8.01 J/cm³ with an efficiency (η) of 91.9 % at 150 °C and an U_e of 5.3 J/cm³ with an η of 90.4 % at 200 °C, which exceeds the performance of most of current high-temperature dielectric polymers. The results of this study provide technical support for the developing of high-performance, flexible dielectric capacitors.

{"title":"Achieving superior high-temperature capacitance performance in aromatic polyetherimide with bulky fluorine substituent","authors":"Xinru Yang, Yang Feng, Peiyan Liu, Liuhao Jiang, Shuo Zhang, Yifan Wu, Shengtao Li","doi":"10.1016/j.ensm.2025.104206","DOIUrl":"10.1016/j.ensm.2025.104206","url":null,"abstract":"<div><div>The rapid development of electronic and electrical power equipment has increased the demand for dielectric materials with high-temperature energy storage performances. However, the mutual restrictions imposed by the glass transition temperature (<em>T</em><sub>g</sub>) and bandgap (<em>E</em><sub>g</sub>) limit the use of commercial polyetherimide (PEI) under extreme conditions. In this work, we propose a strategic modular structure design to balance a high <em>T</em><sub>g</sub> and large <em>E</em><sub>g</sub> by modulating the substituents in the biphenyl structure of modified PEI. Both experimental results and theoretical simulations indicates that owing to its electron-withdrawing nature, a bulky -CF<sub>3</sub> substituent not only increases the bandgap but also decreases the conjugation effect of the biphenyl structure, while having a minimal effect on <em>T</em><sub>g</sub>. This significantly shortens the hopping distance of the carriers, ultimately improving the high-temperature breakdown strength (<em>E</em><sub>b</sub>) and thus the capacitance performance of PEI. The modified PEI with the bulky -CF<sub>3</sub> achieves a discharge energy density (<em>U</em><sub>e</sub>) of 8.01 J/cm<sup>3</sup> with an efficiency (<em>η</em>) of 91.9 % at 150 °C and an <em>U</em><sub>e</sub> of 5.3 J/cm<sup>3</sup> with an <em>η</em> of 90.4 % at 200 °C, which exceeds the performance of most of current high-temperature dielectric polymers. The results of this study provide technical support for the developing of high-performance, flexible dielectric capacitors.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"77 ","pages":"Article 104206"},"PeriodicalIF":18.9,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143695827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Plasma-enhanced vacancy engineering for sustainable high-performance recycled silicon in lithium-ion batteries

IF 18.9 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Energy Storage Materials

Pub Date : 2025-04-01 DOI: 10.1016/j.ensm.2025.104231

Dingyi Zhang , Hong Gao , Jiayi Li , Yiwen Sun , Zeshen Deng , Xinyao Yuan , Congcong Li , Tianxiao Chen , Xingwang Peng , Chao Wang , Yi Xu , Lichun Yang , Xin Guo , Yufei Zhao , Peng Huang , Yong Wang , Guoxiu Wang , Hao Liu

Silicon, renowned for its exceptional theoretical capacity, is a promising lithium-ion battery (LIB) anode material, yet its practical application is hindered by severe lithiation-induced volume expansion, structural instability, and high production costs. This study introduces a sustainable strategy to address these challenges by repurposing recycled photovoltaic (PV) silicon through a plasma-assisted vacancy engineering approach. By combining dielectric barrier discharge plasma-assisted milling with bismuth (Bi) modification, controlled vacancy defects are introduced into silicon microparticles, enhancing ion transport and mitigating internal stress. Bi further stabilizes the anode by absorbing mechanical stress and facilitating lithium-ion accommodation at vacancy sites. The resulting plasma induced silicon/carbon/bismuth composite demonstrates outstanding cycling stability and high-rate performance, retaining 1442 mA h g⁻¹ after 300 cycles at 0.5 A g⁻¹ and 525 mA h g⁻¹ after 1000 cycles at 7 A g⁻¹. This scalable and eco-friendly method not only overcomes the inherent limitations of silicon anodes but also transforms PV waste into high-performance LIB materials, advancing sustainable energy storage technologies.

{"title":"Plasma-enhanced vacancy engineering for sustainable high-performance recycled silicon in lithium-ion batteries","authors":"Dingyi Zhang , Hong Gao , Jiayi Li , Yiwen Sun , Zeshen Deng , Xinyao Yuan , Congcong Li , Tianxiao Chen , Xingwang Peng , Chao Wang , Yi Xu , Lichun Yang , Xin Guo , Yufei Zhao , Peng Huang , Yong Wang , Guoxiu Wang , Hao Liu","doi":"10.1016/j.ensm.2025.104231","DOIUrl":"10.1016/j.ensm.2025.104231","url":null,"abstract":"<div><div>Silicon, renowned for its exceptional theoretical capacity, is a promising lithium-ion battery (LIB) anode material, yet its practical application is hindered by severe lithiation-induced volume expansion, structural instability, and high production costs. This study introduces a sustainable strategy to address these challenges by repurposing recycled photovoltaic (PV) silicon through a plasma-assisted vacancy engineering approach. By combining dielectric barrier discharge plasma-assisted milling with bismuth (Bi) modification, controlled vacancy defects are introduced into silicon microparticles, enhancing ion transport and mitigating internal stress. Bi further stabilizes the anode by absorbing mechanical stress and facilitating lithium-ion accommodation at vacancy sites. The resulting plasma induced silicon/carbon/bismuth composite demonstrates outstanding cycling stability and high-rate performance, retaining 1442 mA h g⁻¹ after 300 cycles at 0.5 A g⁻¹ and 525 mA h g⁻¹ after 1000 cycles at 7 A g⁻¹. This scalable and eco-friendly method not only overcomes the inherent limitations of silicon anodes but also transforms PV waste into high-performance LIB materials, advancing sustainable energy storage technologies.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"77 ","pages":"Article 104231"},"PeriodicalIF":18.9,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143776214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advances in electrode and electrolyte materials of fiber-shaped supercapacitors for electrochemical performance improvement and applications extension

IF 18.9 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Energy Storage Materials

Pub Date : 2025-04-01 DOI: 10.1016/j.ensm.2025.104222

Yuchang Xue , Zhaolun Zhang , Ding Liu , Xiao Yang , Chunyang Wang , Haisheng Chen , Xinghua Zheng , Qihong Li , Ting Zhang

In wearable electronics, fiber-shaped supercapacitors (FSCs) have attracted significant attention due to their excellent flexibility and rapid charge-discharge rates. FSCs can not only conform to the body's contours during large deformations, such as twisting and stretching, but also exhibit faster charge-discharge rates and longer cycle life compared to other energy storage devices, such as lithium-ion fiber batteries and zinc-ion fiber batteries. These characteristics are critical for the durability and short-term response of wearable devices. This paper systematically reviews the latest research progress on fiber electrode materials and gel electrolytes in FSCs, providing an in-depth analysis of their advantages and limitations. To address the limitation of low energy density in FSCs, five effective strategies for optimizing electrochemical performance are discussed, with a focus on both the electrode and electrolyte systems. Furthermore, this paper summarizes recent developments and future trends in integrating multifunctionality (e.g., stretchability, biocompatibility, freeze resistance, fluorescence) and complex systems (e.g., energy harvesting and sensing systems) into single fiber devices.

{"title":"Advances in electrode and electrolyte materials of fiber-shaped supercapacitors for electrochemical performance improvement and applications extension","authors":"Yuchang Xue , Zhaolun Zhang , Ding Liu , Xiao Yang , Chunyang Wang , Haisheng Chen , Xinghua Zheng , Qihong Li , Ting Zhang","doi":"10.1016/j.ensm.2025.104222","DOIUrl":"10.1016/j.ensm.2025.104222","url":null,"abstract":"<div><div>In wearable electronics, fiber-shaped supercapacitors (FSCs) have attracted significant attention due to their excellent flexibility and rapid charge-discharge rates. FSCs can not only conform to the body's contours during large deformations, such as twisting and stretching, but also exhibit faster charge-discharge rates and longer cycle life compared to other energy storage devices, such as lithium-ion fiber batteries and zinc-ion fiber batteries. These characteristics are critical for the durability and short-term response of wearable devices. This paper systematically reviews the latest research progress on fiber electrode materials and gel electrolytes in FSCs, providing an in-depth analysis of their advantages and limitations. To address the limitation of low energy density in FSCs, five effective strategies for optimizing electrochemical performance are discussed, with a focus on both the electrode and electrolyte systems. Furthermore, this paper summarizes recent developments and future trends in integrating multifunctionality (e.g., stretchability, biocompatibility, freeze resistance, fluorescence) and complex systems (e.g., energy harvesting and sensing systems) into single fiber devices.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"77 ","pages":"Article 104222"},"PeriodicalIF":18.9,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143737280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advances in aqueous dual-ion batteries: Anion storage mechanisms, challenges and electrolyte design

IF 18.9 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Energy Storage Materials

Pub Date : 2025-04-01 DOI: 10.1016/j.ensm.2025.104225

Yanxin Liao , Chun Yang , Linghao Sun , Jie Bai , Qichun Zhang , Lingyun Chen

Aqueous dual-ion batteries (ADIBs) represent an innovative energy storage system utilizing dual-ion (anion/cation) charge carriers. These systems exhibit inherent safety, environmental benignity, economic viability, and rapid reaction kinetics, demonstrating significant potential for large-scale energy storage applications. Nevertheless, the intricate anion storage mechanisms, coupled with a range of critical challenges arising from the constrained electrochemical stability window (ESW) of aqueous media, electrode-associated parasitic reactions, the low specific capacity or operating voltage of cathode materials, and dramatic volume changes, pose significant obstacles to their practical application. This review explores the mechanisms of anion storage, the challenges faced, and the design of electrolytes in ADIBs. It elucidates anion storage pathways, including intercalation/deintercalation, coordination/dissociation, conversion reactions, conversion-intercalation, and analyzes limitations such as the narrow ESW, unsatisfactory coulombic efficiency, limited energy density, and poor cycling performance. Strategies for electrolyte design to enhance ADIBs performance are discussed with emphasis on the impact of electrolyte composition on solvation structures, hydrogen-bond networks, insertion potential, and the electrode-electrolyte interface. The review concludes with personal insights into ADIBs development, offering a roadmap for advancing anion reaction chemistry and electrolyte optimization in future research endeavors.

{"title":"Advances in aqueous dual-ion batteries: Anion storage mechanisms, challenges and electrolyte design","authors":"Yanxin Liao , Chun Yang , Linghao Sun , Jie Bai , Qichun Zhang , Lingyun Chen","doi":"10.1016/j.ensm.2025.104225","DOIUrl":"10.1016/j.ensm.2025.104225","url":null,"abstract":"<div><div>Aqueous dual-ion batteries (ADIBs) represent an innovative energy storage system utilizing dual-ion (anion/cation) charge carriers. These systems exhibit inherent safety, environmental benignity, economic viability, and rapid reaction kinetics, demonstrating significant potential for large-scale energy storage applications. Nevertheless, the intricate anion storage mechanisms, coupled with a range of critical challenges arising from the constrained electrochemical stability window (ESW) of aqueous media, electrode-associated parasitic reactions, the low specific capacity or operating voltage of cathode materials, and dramatic volume changes, pose significant obstacles to their practical application. This review explores the mechanisms of anion storage, the challenges faced, and the design of electrolytes in ADIBs. It elucidates anion storage pathways, including intercalation/deintercalation, coordination/dissociation, conversion reactions, conversion-intercalation, and analyzes limitations such as the narrow ESW, unsatisfactory coulombic efficiency, limited energy density, and poor cycling performance. Strategies for electrolyte design to enhance ADIBs performance are discussed with emphasis on the impact of electrolyte composition on solvation structures, hydrogen-bond networks, insertion potential, and the electrode-electrolyte interface. The review concludes with personal insights into ADIBs development, offering a roadmap for advancing anion reaction chemistry and electrolyte optimization in future research endeavors.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"77 ","pages":"Article 104225"},"PeriodicalIF":18.9,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143785057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Research Progress on the Mechanisms of MOF/COF and Their Derivatives in Zinc−Ion Batteries

IF 18.9 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Energy Storage Materials

Pub Date : 2025-04-01 DOI: 10.1016/j.ensm.2025.104220

Hai Ni , Zengyuan Fan , Jiawei Wang , Yunpeng Wu

The rapid depletion of fossil fuels and growing concerns about environmental issues is driving the demand for renewable energy storage systems. Zinc−ion batteries (ZIBs) have emerged as a promising alternative due to their cost−effectiveness, safety, and environmental compatibility. However, practical applications of ZIBs are hindered by challenges such as zinc dendrite formation, hydrogen evolution reactions (HER), and cathode material dissolution. To address these issues, metal−organic framework (MOF) and covalent organic framework (COF) have emerged as promising solutions, owing to their high porosity, tunable structures, and excellent ionic conductivity. This paper provides a comprehensive overview of the latest advancements in MOF/COF and their derivatives in ZIBs. It also examines their roles in cathodes, anodes, electrolytes, and separators, with a particular focus on the relationship between material structure and electrochemical performance, as well as reaction mechanisms. Finally, the paper identifies the challenges faced by MOF/COF and their derivatives, and explores potential molecular−level strategies for overcoming these issues.

{"title":"Research Progress on the Mechanisms of MOF/COF and Their Derivatives in Zinc−Ion Batteries","authors":"Hai Ni , Zengyuan Fan , Jiawei Wang , Yunpeng Wu","doi":"10.1016/j.ensm.2025.104220","DOIUrl":"10.1016/j.ensm.2025.104220","url":null,"abstract":"<div><div>The rapid depletion of fossil fuels and growing concerns about environmental issues is driving the demand for renewable energy storage systems. Zinc−ion batteries (ZIBs) have emerged as a promising alternative due to their cost−effectiveness, safety, and environmental compatibility. However, practical applications of ZIBs are hindered by challenges such as zinc dendrite formation, hydrogen evolution reactions (HER), and cathode material dissolution. To address these issues, metal−organic framework (MOF) and covalent organic framework (COF) have emerged as promising solutions, owing to their high porosity, tunable structures, and excellent ionic conductivity. This paper provides a comprehensive overview of the latest advancements in MOF/COF and their derivatives in ZIBs. It also examines their roles in cathodes, anodes, electrolytes, and separators, with a particular focus on the relationship between material structure and electrochemical performance, as well as reaction mechanisms. Finally, the paper identifies the challenges faced by MOF/COF and their derivatives, and explores potential molecular−level strategies for overcoming these issues.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"77 ","pages":"Article 104220"},"PeriodicalIF":18.9,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143737277","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High-stability zinc anodes modulated by solvation structure and interface chemistry toward printable zinc-ion capacitors

IF 18.9 1区材料科学 Q1 CHEMISTRY, PHYSICAL

Energy Storage Materials

Pub Date : 2025-04-01 DOI: 10.1016/j.ensm.2025.104214

Quancai Li, Weinan Tang, Guilin Tang, Qian Wang, Qun Liu, Hehe Ren, Panwang Guo, Ke Zheng, Ziyi Gong, Jing Liang, Wei Wu

Despite the well-known advantages of aqueous zinc-ion energy storage devices, their development is hindered by challenges such as zinc dendrite formation and side reactions. Moreover, reducing costs and improving efficiency are essential to achieving their commercialization. This study addresses the issues associated with conventional zinc sulfate electrolytes by introducing a safe and moderate concentration of glycerophosphocholine (G) as an additive. Experimental characterization and theoretical calculations show that additive G molecules regulate the solvation structure of zinc ions and modify the adsorption behavior of zinc metal at the electrolyte interface. This dual action suppresses the decomposition of active water molecules and guides the oriented deposition of zinc ions. From the perspective of practical application, high-performance zinc-ion hybrid capacitors are fabricated using fully printed electrodes via a cost-effective and scalable screen-printing method and possess a high capacity retention of 87.09 % after 6000 cycles. These devices demonstrate exceptional electrochemical performance and can accelerate the lab-to-fab translation process, showing great potential for commercialization.

{"title":"High-stability zinc anodes modulated by solvation structure and interface chemistry toward printable zinc-ion capacitors","authors":"Quancai Li, Weinan Tang, Guilin Tang, Qian Wang, Qun Liu, Hehe Ren, Panwang Guo, Ke Zheng, Ziyi Gong, Jing Liang, Wei Wu","doi":"10.1016/j.ensm.2025.104214","DOIUrl":"10.1016/j.ensm.2025.104214","url":null,"abstract":"<div><div>Despite the well-known advantages of aqueous zinc-ion energy storage devices, their development is hindered by challenges such as zinc dendrite formation and side reactions. Moreover, reducing costs and improving efficiency are essential to achieving their commercialization. This study addresses the issues associated with conventional zinc sulfate electrolytes by introducing a safe and moderate concentration of glycerophosphocholine (G) as an additive. Experimental characterization and theoretical calculations show that additive G molecules regulate the solvation structure of zinc ions and modify the adsorption behavior of zinc metal at the electrolyte interface. This dual action suppresses the decomposition of active water molecules and guides the oriented deposition of zinc ions. From the perspective of practical application, high-performance zinc-ion hybrid capacitors are fabricated using fully printed electrodes via a cost-effective and scalable screen-printing method and possess a high capacity retention of 87.09 % after 6000 cycles. These devices demonstrate exceptional electrochemical performance and can accelerate the lab-to-fab translation process, showing great potential for commercialization.</div></div>","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":"77 ","pages":"Article 104214"},"PeriodicalIF":18.9,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143723844","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

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