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Utilization of Welding Electrode Waste To Purify Biogas From Hydrogen Sulfide Impurities 利用焊条废料净化沼气中的硫化氢杂质
Pub Date : 2023-05-31 DOI: 10.32497/eksergi.v19i2.4451
Timotius Anggit Kristiawan, Andryana Dwiandara Wibowo, T. Setiyawan, Nanang Apriandi

Abstract— The biogas desulphurization process has a crucial role in the widespread use of biogas due to the toxic and corrosive nature of the element hydrogen sulfide on equipment. This study investigated the potential use of waste welding electrodes as a biogas purification medium. Variables in the form of feed biogas flow rates of 1, 2, and 3 liters/minute were studied for their effects. As a result, the most optimum performance was obtained in the test with a feed biogas flow rate of 1 liter/minute, with an average reduction percentage of hydrogen sulfide content in the biogas of 27.12%.

摘要-由于硫化氢元素对设备的毒性和腐蚀性,沼气脱硫工艺在沼气的广泛使用中起着至关重要的作用。本研究探讨了废焊条作为沼气净化介质的潜在用途。研究了饲料沼气流量为1、2和3升/分钟的变量形式的影响。结果表明,当进料沼气流量为1 l /min时,试验效果最佳,沼气中硫化氢含量平均降低率为27.12%。
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引用次数: 0
Color Degradation of Napthol Jeans with TiO2-SiO2 Photocatalyst from Karangwuni Beach Sand, Kulon Progo 用二氧化钛-二氧化硅光催化剂降解萘酚牛仔裤的颜色
Pub Date : 2023-03-02 DOI: 10.31315/e.v20i1.8990
Shinta Amelia, Lukhi Mulia Shitopyta, M. W., Ida Sriyana
: The industries that produce the most liquid waste in Indonesia are the batik and textile industries. Napthol dyes are the most widely used dyes as dyes or batik dyes which are completely non-biodegradable and can cause cancer, digestive disorders, and weakening of the body's resistance due to disease and environmental pollution. One of the processing methods currently being developed to degrade color in liquid waste is the photocatalyst method. The photocatalyst method can use a photocatalyst semiconductor in the form of TiO 2 with a supporting material in the form of SiO 2 . SiO 2 as a supporting material can be obtained from the utilization of the local potential of Karangwuni Kulon Progo beach sand. Dye processing was carried out by varying the irradiation time and concentration of Naphtol Jeans. The degradation process was applied to a 25 ml sample solution with the addition of 5 gr/L catalyst for 24 hours, 48 hours, 72 hours, 96 hours, and 120 hours of irradiation. This study resulted in the highest reduction in naphtol concentration at the concentration variable of 100 ppm with a percentage of 44.4687% and a long irradiation time of 120 hours.
在印度尼西亚,产生最多废液的工业是蜡染和纺织工业。萘酚染料是作为染料或蜡染染料使用最广泛的染料,它是完全不可生物降解的,会导致癌症、消化系统紊乱,以及因疾病和环境污染而导致人体抵抗力减弱。目前正在开发的一种降解废液颜色的处理方法是光触媒法。光触媒方法可以使用二氧化钛形式的光触媒半导体和二氧化硅形式的支撑材料。利用Karangwuni Kulon Progo海滩砂的当地潜力可以获得二氧化硅作为支撑材料。通过改变萘酚辐照时间和辐照浓度对染料进行染色处理。在25 ml样品溶液中加入5 gr/L催化剂,辐照24小时、48小时、72小时、96小时和120小时。结果表明,在100 ppm浓度变量下,萘酚浓度降低率最高,为44.4687%,辐照时间为120小时。
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引用次数: 1
Kinetic and Thermodynamic Studies in Cellulose Acetate-Polybutylene Succinate(CA-PBS)/Single Solvent/Water System for Desalination Membrane 醋酸纤维素-聚丁二酸酯(CA-PBS)/单溶剂/水体系脱盐膜的动力学和热力学研究
Pub Date : 2023-03-02 DOI: 10.31315/e.v20i1.8820
R. D. Nyamiati, S. Nurkhamidah, Y. Rahmawati, W. Meka
The most important part of the membrane synthesis process so that it has the desired pores is the solidification process of the membrane, the process begins with a change from one liquid phase into two liquid phases (liquid-liquid demixing). At a certain period during demixing, the polymer-rich phase solidifies; thus, a dense membrane matrix is formed. Parameters that determine the mechanism of membrane formation are based on thermodynamics including phase separation of Solvent-Polymer-Non-solvent which is explained through a phase diagram (Flory-Huggins Theory). This study aims to determine the initial prediction of the formation of CA-PBS membranes with various solvents used and variations of non-solvents in the best system, which is proven by its characteristics and performance when applied to desalination membranes which include ternary diagrams using cloud point data, solubility parameters with Hansesn solubility, the solvent-non-solvent diffusivity using the Tyn Calus Equation approach and the morphological proofing of the membrane through SEM photos, and the performance of the resulting membrane through salt rejection and permeate flux. The results of the difference in solubility parameters are can be predicted that using DMF solvent on the CA-PBS membrane can reduce the pore size and eliminate voids and macrovoids in the membrane morphology.
膜合成过程中使其具有所需孔隙的最重要部分是膜的固化过程,该过程从一个液相变为两个液相(液-液脱混)开始。在脱混过程的某一时期,富聚合物相凝固;这样就形成了致密的膜基质。决定膜形成机理的参数基于热力学,包括溶剂-聚合物-非溶剂的相分离,并通过相图(Flory-Huggins理论)进行解释。本研究旨在确定最佳体系中不同溶剂和非溶剂变化对CA-PBS膜形成的初步预测,并通过其特性和性能在应用于脱盐膜时得到证明,其中包括使用云点数据的三元图,溶解度参数与汉森溶解度,利用Tyn Calus方程计算了溶剂-非溶剂的扩散系数,并通过SEM照片对膜进行了形态验证,并通过盐截留和渗透通量对所得膜的性能进行了验证。溶解度参数差异的结果可以预测,在CA-PBS膜上使用DMF溶剂可以减小膜的孔径,消除膜形态上的空隙和大空隙。
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引用次数: 0
The Effect of Concentration and Type of Immersion Media (Water, Alcohol, Salt, and Vinegar Acid) on Decreasing Oxalate Levels in Porang 浸渍介质(水、酒精、盐和醋酸)浓度和类型对降低Porang草酸含量的影响
Pub Date : 2023-03-02 DOI: 10.31315/e.v20i1.8733
B. Sugiarto, Adhi Setyawan, Octavia Nurmalitasari, RR Endang Sulistyowati
Porang tubers (Amorphophallus oncophyllus) contain very high levels of glucomannan and have many benefits in various fields of health, pharmaceuticals, industry, and food. Apart from having great benefits, porang tubers contain calcium oxalate which can cause itching if consumed directly, irritation, and kidney stones. This study aimed to determine the decrease in oxalate levels in porang tubers using various concentrations and types of immersion media in porang. The types of immersion media are water, salt, alcohol, and vinegar. Water immersion was carried out at 30°C, 40°C, 50°C, 60°C, and 70°C. Immersion with salt was carried out at concentrations of 6%, 8%, 10%, 12%, and 14%. Immersion with alcohol was carried out at concentrations of 20%, 30%, 40%, 50%, and 60%. The vinegar immersion was carried out at concentrations of 10%, 15%, 20%, 25%, and 30%. Oxalate levels were analyzed by the permanganate titration method. The results of immersion porang with dice and long slices in this study showed that water with a temperature of 50°C in the 5th immersion, alcohol with a concentration of 60% in the 5th immersion, salt solution with a concentration of 14% in the 5th immersion, and acetic acid with a concentration of 30% in the 5th immersion is the optimal result.
茯苓块茎(魔芋)含有非常高水平的葡甘聚糖,在健康、制药、工业和食品的各个领域都有很多好处。除了有很大的好处外,茯苓块茎还含有草酸钙,如果直接食用会引起瘙痒、刺激和肾结石。本研究旨在确定在porang中使用不同浓度和类型的浸泡介质对porang块茎中草酸水平的降低。浸泡介质的类型有水、盐、酒精和醋。在30°C、40°C、50°C、60°C和70°C下进行浸水。用盐浸渍在6%、8%、10%、12%和14%的浓度下进行。以20%、30%、40%、50%和60%的浓度进行酒精浸渍。醋浸泡在10%、15%、20%、25%和30%的浓度下进行。草酸盐含量通过高锰酸盐滴定法进行分析。本研究中用骰子和长片浸泡波朗的结果表明,第5次浸泡温度为50°C的水、第5次浸入浓度为60%的酒精、第5次浸入浓度为14%的盐溶液和第5次浸渍浓度为30%的乙酸是最佳结果。
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引用次数: 0
Conversion of Glycerol to Ethanol by Integrating Ultrasonic and Ni/ZSM-5 Catalyst 超声与Ni/ZSM-5催化剂联合催化甘油制乙醇
Pub Date : 2023-03-02 DOI: 10.31315/e.v20i1.8167
Devi Indrasari Mustopa Putri, S. Sumari, Handoko Darmokoesomo, G. Supriyanto, N. Nugroho
: The increased production of biodiesel which is used as an alternative fuel has led to an increase in the by-product in the form of glycerol. This glycerol byproduct can be utilized by converting it into other compounds such as ethanol. The production of ethanol from glycerol requires a catalyst that can break down the molecular size of glycerol, one of which is zeolite. One type of zeolite that is good to use is ZSM-5, because this type of zeolite has a high degree of thermal stability, acid stability and selectivity. The catalytic properties of ZSM-5 can be improved by impregnating metals from the transition group, in this study using Ni (nickel). The results obtained that the catalyst Ni/ZSM-5 has a total acidity value of 0.920 mmol/g and has a specific surface area of 138.754 m 2 /g. The highest ethanol product was produced at 4 hours of sonication, which was 20.362%.
:用作替代燃料的生物柴油产量增加,导致甘油形式的副产品增加。这种甘油副产物可以通过将其转化为其他化合物如乙醇来利用。从甘油生产乙醇需要一种可以分解甘油分子大小的催化剂,沸石就是其中之一。一种很好使用的沸石是ZSM-5,因为这种类型的沸石具有高度的热稳定性、酸稳定性和选择性。ZSM-5的催化性能可以通过浸渍过渡基团的金属来改善,在本研究中使用Ni(镍)。结果表明,催化剂Ni/ZSM-5的总酸度为0.920mmol/g,比表面积为138.754m2/g。在超声处理4小时时产生最高的乙醇产物,为20.362%。
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引用次数: 0
Simulation of A Solar Drier for Iroko Wood (Chlorophora Excelsa) in A Tropical Environment 热带环境下太阳能干燥机对绿木(Chlorophora Excelsa)的模拟
Pub Date : 2023-03-02 DOI: 10.31315/e.v20i1.8166
Fesa Putra Kristianto, Mercusuar Kemall Gibran Salim
: In a previous study conducted by Simo Tagne to designing a solar dryer based on mathematical equations for iroko wood in Cameroon, Africa. However, there is no complete simulation of the drying process on the tool, resulting in the lack of detailed elaboration of the iroko wood drying process. The purpose of this study is to simulate in detail the drying process on the tool using an ANSYS simulation. The model used in this simulation still uses the same mathematical model that has been studied before. This research begins by setting up the ANSYS application with the previous mathematical model, environmental conditions, and tool specifications. Furthermore, simulations are carried out using the ANSYS application with measurements of pressure, temperature, velocity and mass transfer. From this simulation obtained results for the distribution of pressure, temperature, velocity, and mass transfer. From all these distributions, it is sufficient to describe the drying process of the tool according to the mathematical model that has been studied previously.
:在Simo Tagne之前的一项研究中,他根据非洲喀麦隆iroko木材的数学方程设计了一台太阳能烘干机。然而,由于没有对工具上的干燥过程进行完整的模拟,因此缺乏对iroko木材干燥过程的详细阐述。本研究的目的是使用ANSYS模拟详细模拟工具上的干燥过程。该模拟中使用的模型仍然使用以前研究过的相同数学模型。本研究首先利用先前的数学模型、环境条件和工具规格建立ANSYS应用程序。此外,还使用ANSYS应用程序进行了模拟,测量了压力、温度、速度和传质。从这个模拟中获得了压力、温度、速度和传质分布的结果。根据所有这些分布,根据之前研究的数学模型来描述工具的干燥过程就足够了。
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引用次数: 0
Supporting Second Generation Biofuel Development: Thermophilic Anaerobic Digestion of Vinasse for Harmonizing with Molasses Based Bioethanol Plant Capacity 支持第二代生物燃料的发展:与糖蜜生物乙醇工厂产能相协调的嗜热厌氧消化酒糟
Pub Date : 2023-03-02 DOI: 10.31315/e.v20i1.9076
Nina Anggita Wardani, W. Budhijanto
First-generation biofuel is environmental quandary due to its impact to the forest conversion into plantation area. Not only environmental sector, first-generation biofuel has other issues on socioeconomic sector. It consumes crops as its feedstock which will be a conflict between food and energy source. This conflict will impact the vulnerable people as the raising food price. Molasses-based bioethanol is second-generation biofuel which more beneficial from environmental, economic, and social aspect. Molasses-based bioethanol production process generates waste named vinasse. Vinasse can’t be directly discharged to the environment due to its high organic matter concentration which is harmful to the waterbody, soil, and air. On the other hand, high organic matter contained in vinasse can be converted into biogas and is higher potential for molasses-based bioethanol plant. This study was preliminary study for processing vinasse using thermophilic anaerobic digestion specifically by temperature direct escalation and starvation method to the mesophilic originated inoculum. The result shows robust performance of thermophilic microbia which is an averment of compatible method for enriching thermophilic anaerobic microbia in mesophilic originated inoculum.
第一代生物燃料因其对森林转化为人工林的影响而陷入环境困境。第一代生物燃料不仅在环境方面,在社会经济方面也存在其他问题。它消耗农作物作为原料,这将是食物和能源之间的冲突。这场冲突将影响弱势群体,如粮食价格上涨。糖蜜生物乙醇是具有环境、经济和社会效益的第二代生物燃料。以糖蜜为基础的生物乙醇生产过程产生的废物称为酒糟。酒渣油中有机物含量高,对水体、土壤和空气有害,不能直接排放到环境中。另一方面,酒渣中所含的高有机质可以转化为沼气,在糖蜜生物乙醇厂中具有较高的潜力。本研究是利用嗜热厌氧消化法处理酒糟的初步研究,特别是采用温度直接升高和饥饿法对嗜热菌源接种物进行处理。结果表明,嗜热微生物具有良好的性能,这是在嗜温菌源接种物中富集嗜热厌氧微生物的一种相容方法。
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引用次数: 0
Solar Cell Outdoor Bench Design In Open Public Space For Gadged Charging Station 开放式公共空间充电式太阳能电池户外长椅设计
Pub Date : 2023-02-15 DOI: 10.32497/eksergi.v19i01.4134
Abdul Hamid, Muhammad Yusuf, Rianti Setyarini, Eritrian Bisma Primayanda, Naila Sa'adatil Muna

Abstract—The increase in electrical energy is increasing along with the needs of rapidly developing technology. However electricity technology also produces negative impacts such as air and noise pollution caused by power plants. Electrical energy generation is still mostly generated from fossil fuels. A solution that can overcome this problem is to switch to more environmentally friendly electricity technology, such as solar panels. This solar powet plant can be used as an option as a charging energy source in a smart furniture. This research aims to make Solar Cell Powered Outdoor Charging Bench technology.  This bench has several important components, namely: Solar Panel, Solar Charging Controller (SSC), inverter, and battery. This Outdoor Bench is placed in an open place such as a park, Public Open Space and so on which will be used as a charging place for cellphones or laptops. The way this bench works starts with the absorption of solar heat by solar panels on the roof of the bench which is converted into low-voltage electrical energy, then this energy is stored in a dry battery (battery) through SSC, low-voltage electricity is converted through an inverter, and this inverter channels electricity to the socket, so that the charging bench can be used properly.

摘要——随着技术的快速发展,电能的增长也在增加。然而,电力技术也会产生负面影响,如发电厂造成的空气和噪音污染。电能发电仍然主要来自化石燃料。可以克服这个问题的解决方案是转向更环保的电力技术,例如太阳能电池板。这种太阳能发电厂可以作为智能家具的充电能源。本研究旨在开发太阳能电池驱动的户外充电台技术。该工作台有几个重要部件,即:太阳能电池板、太阳能充电控制器(SSC)、逆变器和电池。这款户外长椅放置在公园、公共开放空间等开放场所,用作手机或笔记本电脑的充电场所。这种工作台的工作方式首先是通过工作台顶部的太阳能电池板吸收太阳能,将其转化为低压电能,然后通过SSC将这些能量存储在干电池(电池)中,低压电通过逆变器进行转换,该逆变器将电能输送到插座,以便充电工作台能够正常使用。
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引用次数: 0
Analysis of the Utilization of Organic Waste into Biogas Alternative 有机废弃物转化为沼气替代品的分析
Pub Date : 2023-02-15 DOI: 10.32497/eksergi.v19i01.4043
Firdaus Nur Rahmat, S. Sudarti, Y. Yushardi

Abstract— Waste is the main problem experienced by somepeople in Indonesia. The population is getting higher in the spanof a year. Unable with the presence of waste consisting of varioustypes of waste, this problem can be felt, namely negative impactson the surrounding environment, for example the slumenvironment, becoming a source of disease nests, and being atrigger for global warming caused by waste. This study has theaim of analyzing the use of the type of organic waste used foralternative energy, namely Biogas. In this study, we used aliterature review approach. An approach similar to the one usedhere is used to collect various data from previously conductedresearch on topics related to those being discussed here. Animalwaste, fruit and vegetable waste, and other forms of organicwaste can be converted into biogas faster than inorganic waste.For the production of biogas, mixing vegetables together isbetter than cutting them. Biogas that has been processed can beused as alternative energy that can benefit various sectors. Theuse of organic waste into biogas can reduce the problem of wastein Indonesia. 

摘要——废物是印尼一些人遇到的主要问题。人口在一年的时间里越来越多。由于存在由各种类型的废物组成的废物,可以感受到这个问题,即对周围环境的负面影响,例如污泥环境,成为疾病巢穴的来源,以及废物引起的全球变暖的诱因。本研究旨在分析用于替代能源的有机废物,即沼气的用途。在这项研究中,我们使用了一种评估方法。一种类似于此处使用的方法用于从先前进行的与此处讨论的主题相关的搜索中收集各种数据。动物粪便、水果和蔬菜废物以及其他形式的有机废物比无机废物更快地转化为沼气。对于沼气的生产来说,把蔬菜混合在一起比切菜要好。经过处理的沼气可以用作替代能源,使各个部门受益。将有机废物用于沼气可以减少印尼的废物问题。
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引用次数: 0
Evaluation Of Refrigerating Load And Air Flow Performance In Air Conditioning Unit at Hospital Z Z医院空调机组制冷负荷及风量性能评价
Pub Date : 2023-02-15 DOI: 10.32497/eksergi.v19i01.4253
Nur Fatowil Aulia, Dwiana Hendrawati, M. Hanif, Baktiyar Mei H, Ahmad Hamim S, F. Sumarno, M. Surindra

This research was conducted to evaluate air conditioning systems in pharmaceutical warehouses against the ANSI/ASHRAE/ASHE ventilation standards 170 – 2008 and SNI-03-6572-2001. The method used is to calculate the cooling load on the FCU (Fan Coil Unit) using the CLTD (Cooling Load Temperature Difference) method and calculate the External Static Pressure on the ducting system. The analysis is carried out by comparing the results of calculating the FCU requirements with the actual specifications that have been implemented. Furthermore, the measurement results of the existing room air condition are compared with the standards for pharmaceutical warehouse applications. The calculation results show that the pharmaceutical warehouse has a cooling load of 47,472.72 Btu/hr, and has an external static pressure of 123 Pa. While the selected FCU (Fan Coil Unit) has a capacity of 78,771 Btu/hr and a maximum external static pressure of 130 Pa with a rated airflow of 4000 m3/hr. After 9 years of use, it is known that the rated airflow has decreased by around 37% of the FCU capacity. Existing room air conditions obtained the extreme temperature and RH of 23.36°C and 72%, respectively.

本研究针对ANSI/ASHRAE/ASHE通风标准170 - 2008和SNI-03-6572-2001对制药仓库的空调系统进行了评估。采用CLTD (cooling load Temperature Difference)法计算风机盘管的冷负荷,并计算风管系统的外部静压。通过将FCU需求的计算结果与已实施的实际规范进行比较,进行分析。此外,将现有房间空调的测量结果与药品仓库应用的标准进行了比较。计算结果表明,该药库的冷负荷为47,472.72 Btu/hr,外部静压为123 Pa。而选择的FCU(风机盘管)容量为78,771 Btu/hr,最大外部静压为130 Pa,额定气流为4000 m3/hr。经过9年的使用,已知额定气流减少了约37%的FCU容量。现有室内空气条件下的极端温度为23.36℃,相对湿度为72%。
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引用次数: 0
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