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Graphene as an Active Material for Supercapacitors: A Machine Learning Approach 石墨烯作为超级电容器的活性材料:一种机器学习方法
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.76678
Anif Jamaluddin, Annisa Dwi Nursanti, Anafi Nur'aini, Rekyan Regasari M Putri, Muhammad Usama Arshad

Graphene is a promising material for supercapacitors due to its unique properties, which influence the device's supercapacitor. This study aims to investigate the key factor of graphene properties in supercapacitors (, with the goal of improving their performance. Also, we observe the machine learning models for predicting capacitance of supercapacitor including four algorithms of machine learning: Linear Regression (LR), lazy IBK, Decision Table (DT), and Random Forest (RF). Machine learning model showed that the RF model demonstrated the highest correlation value of 0.745, surpassing other models. Also, the study revealed that graphene has a high specific surface area and highly porous structure, which enhanced the high capacitance values. Finally, these machine learning models are suitable to apply in materials sciences field for understanding the materials properties in supercapacitor.

<p class="摘要">石墨烯是一种很有前途的超级电容器材料,由于其独特的性质,影响设备的超级电容器。本研究旨在探讨石墨烯在超级电容器中性能的关键因素,以提高其性能。此外,我们还观察了用于超级电容器电容预测的机器学习模型,包括四种机器学习算法:线性回归(LR)、懒惰IBK、决策表(DT)和随机森林(RF)。机器学习模型显示,RF模型的相关值最高,为0.745,超过其他模型。此外,研究表明石墨烯具有高比表面积和高多孔结构,从而增强了高电容值。最后,这些机器学习模型适合应用于材料科学领域,以了解超级电容器中的材料特性。</p>
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引用次数: 0
First-Principle Investigation of La0.7Ba0.3Mn(1-x)FexO3 Structural Properties Using CASTEP La0.7Ba0.3Mn(1-x)FexO3结构性质的CASTEP第一性原理研究
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.77031
Sitti Ahmiatri Saptari, Sarah Aulia, Ryan Rizaldy, Anugrah Azhar

We conducted first-principles Density Functional Theory (DFT) calculations using the CASTEP software package to investigate the crystal structure and mechanical properties of Fe3+-doped La0.7Ba0.3MnO3 material at the Mn3+ site, with doping concentrations ranging up to 50%. Through geometry optimization, we simulated the X-ray diffraction (XRD) pattern. We observed that the doping of Fe did not result in a shift in the peak positions of the diffraction pattern. However, it led to an increase in intensity at the [012] peak and the splitting of peaks [104] and [110]. Regarding the mechanical properties, we examined the elastic constants and observed a reduction in the Bulk, Shear, and Young's modulus values. The Shear and Bulk modulus and Poisson's ratio indicated that La0.7Ba0.3Mn(1-x)FexO3 becomes less ductile with increased Fe3+ doping content. Furthermore, we performed calculations for the Debye temperature, which revealed a decrease in the thermal conductivity of the La0.7Ba0.3Mn(1-x)FexO3 material.

我们使用CASTEP软件包进行第一性原理密度泛函数理论(DFT)计算,研究Fe<sup>3+</sup>掺杂La<sub>0.7</sub>Ba<sub>0.3</sub>MnO<sub>3</sub>材料在Mn<sup>3+</sup>现场,掺杂浓度可达50%。通过几何优化,模拟了x射线衍射(XRD)模式。我们观察到Fe的掺杂并没有导致衍射图峰位的移位。然而,它导致了[012]峰强度的增加以及[104]和[110]峰的分裂。关于力学性能,我们检查了弹性常数,并观察到体积,剪切和杨氏模量值的减少。剪切和体积模量及泊松比表明:La<sub>0.7</sub>Ba<sub>0.3</sub>Mn<sub>(1-x)</sub>Fe<sub>x</sub>O<sub>3</sub>随着Fe<sup>3+</sup>掺杂的内容。此外,我们对Debye温度进行了计算,结果显示La<sub>0.7</sub> ba>0.3</sub>Mn<sub>(1-x)</sub>Fe<sub>x</sub>O<sub>3</sub>物质。;/ p> & lt; p类=“抽象”比;& lt; / p>
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引用次数: 0
Transition Temperature in Thermochromic Liquid Crystals using Second-Order Features Extraction 基于二阶特征提取的热致变色液晶转变温度研究
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.73552
Cindyawati Cindyawati, Risti Suryantari

Liquid crystals are a type of substance that has solid and liquid properties. One of the types of it is cholesteric. Cholesteric liquid crystals have a characteristic which is called pitch. Pitch is very sensitive to changes in temperature. The pitch will reflect different colors depending on the wavelength at a particular temperature. Thermochromic Liquid Crystals (TLC) is the cholesteric liquid crystals material sold commercially. At the transitional temperature, the texture of TLC changes, so the reflected color will also change. Second-order feature extraction was chosen to determine the change in texture with the transition temperature. The TLC layer was made by thickness of 100 µm. This layer was heated and observed using a polarizing microscope with an angle between the polarizer and analyzer of 90o. The obtained result are cross patterns emerged at anisotropic transition temperature and higher temperature on TLC will lead to an isotropic phase.

液晶是一种具有固体和液体性质的物质。其中一种是胆固醇。胆甾型液晶有一种称为节距的特性。沥青对温度的变化很敏感。在特定温度下,根据波长的不同,音高会反射出不同的颜色。热致变色液晶(TLC)是市面上销售的胆甾液晶材料。在过渡温度下,TLC的质地发生变化,因此反射的颜色也会发生变化。采用二阶特征提取来确定纹理随转变温度的变化。薄层厚度为100µm。将该层加热,用偏光显微镜观察,偏光镜与分析仪夹角为90<sup> 0< /sup>得到的结果是在各向异性转变温度下出现交叉图案,TLC上较高的温度将导致各向同性相。<em></em>
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引用次数: 0
Analysis of Microtremor Data for Identification of Sediment Layer Thickness Based on Ground Profile Vs in Solok City, West Sumatera 基于地面剖面v的西苏门答腊索洛市沉积物层厚识别微震数据分析
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.42609
Cahya Damayanti

Research has been carried out to analyze the thickness of the sediment layer based on the value of the ground profile Vs (S-wave velocity) from microtremor measurement data sources in Solok City. The thickness of the sediment layer is one of the parameters that affect the amplification or amplification of incoming waves when an earthquake occurs. This study aimed to determine the sediment thickness level in Solok City based on the Vs value in the ground profile model from microtremor data sources. So that the analysis of sediment layers can be used as a form of disaster mitigation caused by tectonic activities such as earthquakes. Single station and array microtremor data were collected, then processed using a combination of HVSR and SPAC methods. The data processing results indicate that the value of S-wave velocity (Vs) derived from microtremor data analysis can be used to determine the thickness of the sediment layer (h), and vs values in Solok City ranged from 126.15-193.35 m/s with depths between 7.23-19.06 m. For areas with unseparated volcanic rock (QTau) lithology, the Vs value is 182.41 m/s. Meanwhile, for areas with geological conditions like alluvium (Qal), the Vs value is 161.66 m/s. The area with a thick layer of sediment, which is 62.74 m, is in the center of the northeastern part of Solok City, covering most of Vi Suku, Nan Balimo, and Javanese Village with alluvium (Qal) lithology and low topography through which rivers flow. Meanwhile, the thin layer of sediment, which is 23.12 m, is located in the western part of Solok City, precisely in Tanah Garam, with undivided volcanic rock lithology (QTau) and high topography in hilly areas.

<p class="Abstract"><span lang="EN-US">基于索洛市微震测量数据源的地面剖面v(横波速度)值进行了沉积层厚度分析研究。沉积层的厚度是地震发生时影响入射波放大或放大的参数之一。本研究旨在利用微震数据源地面剖面模型中的v值确定索洛市的沉积物厚度水平。因此,沉积层的分析可以作为一种减轻地震等构造活动造成的灾害的形式。采集单站和阵列微震数据,采用HVSR和SPAC相结合的方法进行处理。数据处理结果表明,利用微震数据分析得到的横波速度(Vs)值可以确定沉积层厚度(h),索洛克市纵深为7.23 ~ 19.06 m,纵深为126.15 ~ 193.35 m/s。对于未分离火山岩(QTau)岩性地区,v值为182.41 m/s。同时,对于具有冲积层(Qal)等地质条件的地区,Vs值为161.66 m/s。沙层厚62.74 m的区域位于索洛克市东北部的中心,覆盖了维苏库、南巴利莫和爪哇村的大部分地区,具有冲积(Qal)岩性和低地形,河流流经。同时,薄层沉积物位于索洛市西部,即Tanah Garam,厚度为23.12 m,火山岩岩性(QTau)未划分,地势高,为丘陵地区。
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引用次数: 0
Pneumonia Classification Based on GLCM Features Extraction using K-Nearest Neighbor 基于k -最近邻GLCM特征提取的肺炎分类
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.77120
Suharyana Suharyana, Fuad Anwar, Armylia Chandra Dewi, Mohtar Yunianto, Umi Salamah, Rifai Chai

Pneumonia has been detected using Machine learning. The stages in this study began with preprocessing in 4 stages: resizing, cropping, filtering using a high pass filter, and Adaptive Histogram Equalization. The feature extraction process continued with 22 Gray Level Co-occurrence Matrix (GLCM) features and classification using K-Nearest Neighbor (KNN). The image used was 150 data sets for training on the classification of 3 classes with a ratio of 50:50:50 while training on two classes was 50 bacterial pneumonia and 50 viral pneumonia. The most optimal training data accuracy results were obtained using the angle direction on the GLCM, namely 135o with the KNN classification (k = 3). For the classification of two classes Using 40 data sets, an accuracy of 91% was obtained, while testing for three classes with 60 data sets was 83.3%.

<p class="摘要">利用机器学习检测肺炎。本研究的阶段从预处理开始,分为4个阶段:调整大小,裁剪,使用高通滤波器滤波,以及自适应直方图均衡化。继续对22个灰度共生矩阵(GLCM)特征进行特征提取,并使用k -最近邻(KNN)进行分类。使用的图像是150个数据集,以50:50:50的比例进行3类分类的训练,而两个类的训练是50个细菌性肺炎和50个病毒性肺炎。使用GLCM上的角度方向得到了最优的训练数据准确率结果,即1350与KNN分类(k = 3)。对于使用40个数据集的两类分类,准确率为91%,而对于使用60个数据集的三类,准确率为83.3%。</p>
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引用次数: 0
Identification of Geothermal Distribution in The Banyu Biru Hot Water Source using The Magnetic Method 利用磁法识别半玉碧玉热水源地热分布
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.72305
Ahmad Luthfin, Nur Amilatu Jubaidah

The geothermal phenomenon in Banyu Biru hot springs in Gondangwetan Village, Jatikalen District, Nganjuk Regency, has the potential to be developed into a tourist spot and an alternative renewable energy source that is environmentally friendly; for example, a geothermal power plant. So it is necessary to know the distribution of geothermal reservoirs and how much potential energy is contained. This research aims to determine the distribution of geothermal energy in the research area and its geological structure. This study used the Magnetic Method for secondary data obtained from NOAA satellite data. Data acquisition with an area of 2000 meters x 2000 meters obtained 100 data with a spacing of 200 meters. Based on research results, geothermal bursts have a low anomaly value of -50 nT to 25 nT. The low anomaly distribution can be used to determine the geothermal distribution in the area, assuming that areas with the same anomaly value indicate the presence of geothermal energy. The geology of the study area has five layers, namely: Topsoil (soil) has a susceptibility value of 0.0000377 SI, Alluvium has a susceptibility value of 0.00144513 SI, Tufan Clay has a susceptibility value of 0.00692407 SI, Limestone Tuff has a susceptibility value of 0.125713399 SI and Breccia (Andesite and Basalt) has a susceptibility value 0.0126292 SI. The depth of the geothermal source in the study area is ± 250 meters below the surface.

<p class="摘要">位于Nganjuk县Jatikalen区Gondangwetan村的Banyu Biru温泉的地热现象具有开发成为旅游景点和环境友好型替代可再生能源的潜力;例如,地热发电厂。因此,有必要了解地热储层的分布和所含势能的大小。本研究旨在确定研究区地热能分布及其地质构造。本研究使用磁法对NOAA卫星数据获得的二次数据进行分析。数据采集面积为2000米× 2000米,获得100条数据,间距为200米。根据研究结果,地温爆发具有-50 nT ~ 25 nT的低异常值,根据低异常分布可以判断该区域的地热分布,假设具有相同异常值的区域表明地热能存在。研究区地质有5层,即表土(土)的敏感性值为0.0000377 SI,冲积层的敏感性值为0.00144513 SI,吐凡粘土的敏感性值为0.00692407 SI,灰岩凝灰岩的敏感性值为0.125713399 SI,角砾岩(安山岩和玄武岩)的敏感性值为0.0126292 SI。研究区地热源深度为地表以下±250 m。
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引用次数: 0
Compressibility Effects on Turbulent Heat Transfer of Natural Convection in a Square Cavity 可压缩性对方形腔内自然对流湍流换热的影响
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.75790
Rida Siti Nur'aini Mahmudah, Restu Widiatmono, Denny Darmawan
Heat transfer in turbulent flows is one of the essential topics in power plants and thermal-based engineering. This study aims to analyze the effects of density changes due to heat transfer in a turbulent environment—which is usually neglected because it can cause instability in a simulation. We simulate an available experimental case of turbulent heat transfer of air with OpenFOAM: one with an incompressible approach (no density change) and another with a compressible treatment. The simulation geometry is a 0.75 × 0.75 m2 square cavity, where its left and right walls are kept at a temperature difference of 40 K. We compare and analyze the temperature, velocity, and turbulence kinetic energy profiles of both simulation results against the experimental data. We found that from all qualitative and quantitative comparisons, the change in density plays a vital role in turbulent heat transfer. The compressible treatment gives better results than the incompressible: the neglection of density change causes a significant difference with the experimental data. Thus, we strongly recommended incorporating compressibility in simulating heat transfer in turbulent flows.
紊流中的传热是电厂和热力工程中的重要课题之一。本研究旨在分析湍流环境中由于传热引起的密度变化的影响,这一影响通常被忽视,因为它会导致模拟中的不稳定性。我们用OpenFOAM模拟了一个可用的紊流空气传热实验案例:一个采用不可压缩方法(无密度变化),另一个采用可压缩处理。模拟几何形状为0.75 × 0.75 m<sup>2</sup>方形腔,其左右壁保持40 K的温差。我们将两种模拟结果的温度、速度和湍流动能分布与实验数据进行了比较分析。我们发现,从所有定性和定量的比较中,密度的变化在湍流传热中起着至关重要的作用。可压缩处理的结果优于不可压缩处理,忽略密度变化导致与实验数据的显著差异。因此,我们强烈建议将可压缩性纳入紊流传热模拟中。
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引用次数: 0
Utilization of Satellite Gravimetric Data to Estimate the Location of the Magma Chamber of Slamet Volcano, Central Java, Indonesia 利用卫星重力数据估算印尼中爪哇斯拉梅特火山岩浆库位置
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.73923
Sehah Sehah, Sorja Koesuma, Urip Nur Wijayanto Prabowo, Aina Zahra Ikhwana
Satellite gravimetric data can be utilized to map the gravity anomaly on the earth's surface, especially for difficult, extreme, and large areas. In this study, satellite gravimetric data has been used to estimate the location of the magma chamber of Slamet volcano, Indonesia. Information on the magma chamber is very useful for knowing the volcanic characteristics and activity, thus helping pre-mitigation efforts to catastrophic eruptions that occur. The stages in the study which have been carried out include data access, correction, reduction, modeling, and interpretation. The satellite gravimetric data that has been accessed is GGMplus data. After several corrections and reductions are done, the complete Bouguer anomalies (CBA) data are obtained with values ranging from 11.889 – 117.429 mGal. Filtering process using the upward continuation has been applied to obtain regional anomalies data. The regional anomalies data are corrected to the CBA data, so that the residual gravity anomalies data are obtained. The lowest gravity anomaly value is located at positions of 109.21967 E and 7.24281 S which is interpreted to be the location of the magma chamber of Slamet Volcano that is currently still active. The result of modeling of the residual gravity anomalies data indicate that the position of the magma chamber of Slamet Volcano is estimated to be relatively under the cone with a density lower than the surrounding rock densities, i.e. 1.50 – 1.75 g/cm3. The study results have a good match with the geological map of the study area.
利用卫星重力数据可以绘制地球表面重力异常,特别是在困难、极端和大面积的情况下。在这项研究中,卫星重力数据已被用于估计印尼Slamet火山岩浆库的位置。关于岩浆房的信息对于了解火山特征和活动非常有用,从而有助于对发生的灾难性喷发进行预减灾工作。研究的各个阶段包括数据获取、校正、简化、建模和解释。已访问的卫星重力数据是GGMplus数据。经过多次校正和缩减,得到了完整的布格异常(CBA)数据,其值范围为11.889 ~ 117.429 mGal。采用向上延拓的滤波方法获取区域异常数据。将区域异常数据校正为CBA数据,得到剩余重力异常数据。重力异常值最低的位置为109.21967颈椎E和7.24281颈椎S,解释为目前仍在活动的Slamet火山岩浆房所在位置。对残差重力异常数据的建模结果表明,估计拉末特火山岩浆房的位置相对于锥下,密度低于围岩密度,约为1.50 ~ 1.75 g/cm3。研究结果与研究区地质图吻合较好。
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引用次数: 0
Experimental Study of Storing Electrical Energy Generated by an Acoustic Energy Harvester Into a Supercapacitor 将声能收集器产生的电能存储在超级电容器中的实验研究
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.67671
Ikhsan Setiawan, Bagas Wahyu Wibowo, Rizki Dwi Prasetya

Acoustic energy harvester is a device used to convert environmental noise into electrical energy. Many researches on acoustic energy harvesting have been carried out, but most of them have not yet reached the stage of storing the electrical energy produced. This paper presents an experimental study of storing electrical energy generated by an acoustic energy harvester into a supercapacitor. The acoustic energy harvester in this study used a 4-inch woofer loudspeaker as a noise converter into electricity, equipped with a straight cylindrical resonator, a cylindrical housing, and an electric current rectifier unit. The supercapacitor used has a specification of 100F/2.7V. Experiments were carried out by using several variations of the sound frequency with three variations of sound pressure level (SPL) namely 90 dB, 95 dB, and 100 dB, and by measuring the supercapacitor voltage in a charging time of 60 minutes. It was found that the supercapacitor voltage reached 368 mV which was obtained from noise sound with an SPL of 100 dB and a frequency of 54 Hz which gave an initial charging electric current of about 12 mA. In the last five minutes of charging, the increase in supercapacitor voltage was still linear with time at a rate of about 5.2 mV/min. Therefore, the supercapacitor voltage can still significantly increase if the charging continues.

<p class="摘要">声能采集器是一种将环境噪声转化为电能的装置。关于声能量收集的研究已经开展了很多,但大多数还没有达到将产生的电能存储起来的阶段。本文介绍了一种将声波能量收集器产生的电能存储在超级电容器中的实验研究。本研究的声能量采集器采用4英寸低音扬声器作为噪声转换成电能,配备直圆柱谐振器、圆柱外壳和电流整流单元。使用的超级电容器规格为100F/2.7V。实验采用声压级(SPL)为90 dB、95 dB和100 dB的几种声频变化,并在充电时间为60分钟的情况下测量超级电容器的电压。实验发现,超级电容器电压达到368 mV,该电压来自声压级为100 dB,频率为54 Hz的噪声,初始充电电流约为12 mA。在充电的最后5分钟,超级电容器电压仍以约5.2 mV/min的速率随时间线性增加。因此,如果继续充电,超级电容器电压仍然可以显著增加。</p>
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引用次数: 0
Low Temperature Calcination of TiO2 and ZnO Particle Film and Evaluation of Their Photocatalytic Activity TiO2和ZnO颗粒膜的低温煅烧及其光催化活性评价
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.76028
Inovasari Islami, Lutfi Naufal Ramadhika, Lusi Safriani, Ayi Bahtiar, Fitrilawati Fitrilawati, Nowo Riveli, Annisa Aprilia

In this study, TiO2, ZnO, and TiO2/ZnO films were prepared under low calcination temperature and characterized to observe their properties related to photocatalytic performance. The samples were prepared by mixing the gel phase of ZnO precursor, TiO2 anatase powder, triton-x 100, and acetylacetone to produce a paste form for the deposition process. The resulting paste was then deposited by screen printing onto a glass substrate and subjected to calcination at 250C to facilitate the ZnO crystallization and remove other additive materials. XRD analysis confirms that the formation of ZnO and TiO2 crystals was assisted, although their crystallinity was lower than corresponding particulate forms. The lower crystallinity seems to be related by additive materials remains. The surface morphology of each sample was observed by scanning electron microscopy (SEM) imaging, Brunauer–Emmett–Teller (BET), and contact angle examination. Interestingly, both TiO2 and ZnO layers tend to have a hydrophobic surface meanwhile TiO2/ZnO has a hydrophilic surface. BET analysis revealed that ZnO has the highest specific surface area due to a nanosized. FTIR spectra confirmed the presence of appropriate chemical bonds in the ZnO and TiO2 and other additive materials, such as alkyl groups. The photoluminescence (PL) spectrum shows a blue emission associated with intrinsic defects such as vacancies and interstitials of Zn and Ti in all samples. Differences in the photocatalytic performance of film and particulate form for each material were observed and analyzed. All samples' structures, morphology, and PL characteristics were then correlated to their photocatalyst behavior for methylene blue degradation.

本研究在低煅烧温度下制备了TiO<sub>2</sub> ZnO和TiO<sub>2</sub>/ZnO薄膜,并对其进行了表征,观察其与光催化性能相关的性能。样品是通过混合ZnO前驱体TiO<sub>2</sub>锐钛矿粉,triton-x 100,和乙酰丙酮,以产生糊状的沉积过程。然后通过丝网印刷将得到的糊状物沉积在玻璃基板上,并在250℃下进行煅烧,以促进ZnO的结晶并去除其他添加剂。XRD分析证实ZnO和TiO<sub>2</sub>晶体是辅助的,尽管它们的结晶度低于相应的颗粒形式。结晶度较低似乎与添加剂残留有关。采用扫描电镜(SEM)成像、布鲁诺尔-埃米特-泰勒(BET)法和接触角法观察各样品的表面形貌。有趣的是,TiO<sub>2</sub>而TiO<sub>2</sub>/ZnO则具有亲水性表面。BET分析表明,ZnO具有最高的比表面积。FTIR光谱证实ZnO和TiO<sub>2</sub>和其他添加剂材料,如烷基。所有样品的光致发光(PL)光谱都显示出与锌和钛的空位和间隙等本征缺陷有关的蓝色发射。观察和分析了不同材料的光催化膜和颗粒形式的差异。然后将所有样品的结构、形态和PL特性与其降解亚甲基蓝的光催化剂行为相关联。
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引用次数: 0
期刊
Indonesian Journal of Applied Physics
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