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Exploring TiO2-PP as a Reusable Floating Photocatalyst for Humic Acid and Iron Removal in Peat Water 二氧化钛-聚丙烯作为可重复使用的浮式光催化剂去除泥炭水中腐植酸和铁的研究
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.60342
Bintoro Siswo Nugroho, Asifa Asri, Yudha Arman
In this study, we fabricate TiO2-PP catalyst and analyze its use for peat water photodegradation. The photocatalyst is a thin layer of TiO2 deposited on the surface of polypropylene (PP) grains by the thermal milling method. Scanning electron microscopy (SEM) and energy-dispersive x-ray spectroscopy (EDS) images indicate that the fabrication successfully deposited TiO2 particles on the PP grain surface homogeneously well. The results show that photocatalysis of peat water using TiO2-PP with solar irradiation is more effective than the UV lamp. After photocatalysis for 40 hours with solar irradiation, the humic acid content in peat water decreases significantly, accompanied by a decrease in Fe concentration. When being reused, TiO2-PP photocatalyst shows performance above 92% in the fourth iteration, while in the fifth iteration, the performance decreases to 83%. These results show that TiO2-PP has the potential to be applied as a reusable floating photocatalyst to reduce the humic acid and iron content in peat water.
在本研究中,我们制备了TiO<sub>2</sub>-PP催化剂,并分析了其在泥炭水光降解中的应用。光催化剂是一层薄薄的TiO<sub>2</sub>通过热磨法沉积在聚丙烯(PP)颗粒表面。扫描电镜(SEM)和能量色散x射线能谱(EDS)图像表明,该工艺成功沉积TiO<sub>2</sub>颗粒在PP颗粒表面均匀性好。结果表明,TiO<sub>2</sub>-PP在太阳照射下光催化泥炭水的效果优于紫外灯。在太阳照射下光催化40小时后,泥炭水中腐植酸含量显著降低,同时铁浓度降低。重复使用时,TiO<sub>2</sub>-PP光催化剂在第四次迭代时性能达到92%以上,而在第五次迭代时性能下降到83%。这些结果表明,TiO<sub>2</sub>-PP具有作为可重复使用的浮动光催化剂降低泥炭水中腐植酸和铁含量的潜力。
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引用次数: 0
NMR Characterization of Polymethylhydrosiloxane Synthesized using Dichloromethane and Diethyl Ether as Solvent for Vitreous Substitute 以二氯甲烷和乙醚为溶剂合成聚甲基氢硅氧烷的核磁共振表征
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.72694
Nabillah Fa'diyyah Zahra, Diba Grace Auliya, Vira Fuji Arini, Fitrilawati Fitrilawati, Lusi Safriani, Risdiana Risdiana

Polymethylhydrosiloxane (PMHS) can be synthesized from dichloromethylsilane (DCHS) by the hydrolysis-condensation method. In this synthesis method, a solvent is needed. Dichloromethane (DCM) or diethyl ether (DE) can be used as a solvent in the synthesis of PMHS. These two solvents greatly affect the physical properties of the resulting PMHS. Therefore, studies are needed to look at the characteristics and chemical content of the PMHS synthesized using these two solvents. In this research, we reported the characteristics and content studies of PMHS synthesized using different solvents, DCM and DE, using 1H-NMR and 13C-NMR. It was found that both samples had three peaks (Si-H, Si-CH3, and Si-CH3) on 1H-NMR measurement and one peak (Si-CH3) on 13C-NMR measurement. All of the peaks found were by the characteristics of PMHS and no other elements were found from solvents indicating that the PMHS samples had been successfully synthesized with a high degree of purity. In addition, the possibility of structures formed in the PMHS samples was also obtained.

<p class="摘要">以二氯甲基硅烷(DCHS)为原料,采用水解缩合法可合成聚甲基氢硅氧烷(PMHS)。在这种合成方法中,需要溶剂。二氯甲烷(DCM)或乙醚(DE)可作为溶剂合成PMHS。这两种溶剂极大地影响了所得PMHS的物理性质。因此,需要对使用这两种溶剂合成的PMHS的特性和化学成分进行研究。在本研究中,我们使用<sup>1</sup>H-NMR和<sup>13</sup>C-NMR对不同溶剂DCM和DE合成的PMHS的特性和含量进行了研究。结果发现,两种样品均有三个峰(Si-H, Si-CH<sub>3</sub>和Si-CH<sub>3</sub>)在<sup>1</sup>H-NMR测量上有一个峰(Si-CH<sub>3</sub>)在<sup>13</sup>C-NMR测量上。发现的所有峰都符合PMHS的特征,并且没有从溶剂中发现其他元素,表明PMHS样品已成功合成,纯度很高。此外,还获得了PMHS样品中形成结构的可能性。</p>
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引用次数: 0
The Spatial Arrangement of The Electric Field in the Needle-Plate Electrospinning 针板静电纺丝过程中电场的空间分布
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.67191
Ahmad Kusumaatmaja, Muhamad Nasrudin Manaf, Shiddiq Nur Hidayat, Kuwat Triyana, Farah Rahma, Grandprix T. M. Kadja, Muchammad Yunus

The electric field distribution of the Neddle-Plate (NP) electrospinning set up has reported due to the simple classical electrodynamics solutions. The charge is assumed to distribute uniformly in the needle (nozzle) and the collector (plate). The electric field has an influence only in the early stage of the electrospinning process. The electric field and the viscosity of the jet fluid have caused the bending of the straight jet. The high viscosity of the fluid can preserve the straight jet length much longer. The electric field gives the initial angular momentum of the jet due to the whipping motion of the jet. For the area away from the nozzle, the electric does not influence the whipping motion. Then the whipping motion solely due to the influence from the charge repulsion of the jet fluid and the evaporation of the solvent.

摘要由于经典电动力学解的简单性,已经报道了针板静电纺丝装置的电场分布。假定电荷在针(喷嘴)和收集器(极板)中均匀分布。电场只在静电纺丝过程的初期有影响。电场和射流流体的黏度造成了直射流的弯曲。流体的高粘度可以使直射流长度保持更长时间。由于射流的旋转运动,电场给出了射流的初始角动量。对于远离喷嘴的区域,电不影响搅拌运动。然后,搅拌运动仅受射流的电荷斥力和溶剂蒸发的影响。
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引用次数: 0
Effect of The Composition of TiO2 Additives on The Physical and Magnetic Properties Crystal Structure and Microstructure of BaFe12O19 Magnetic Ceramics TiO2添加剂组成对BaFe12O19磁性陶瓷物理磁性能、晶体结构和微观结构的影响
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.70436
Endah Puspita, Nur Rahmah, Marzuki Naibaho, Ramlan Ramlan

In this research, the manufacture of barium hexaferrite (BaFe12O19) magnetic ceramics and the addition of titanium dioxide (TiO2) additives with variations of 0%: 0.3%: 0.6% and 0.9% used the powder metallurgical method. The characterization used in this study is the measurement of density, porosity, X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), Vibrating Sample Magnetometer (VSM), and Impulse Magnetizer K-Series. Based on the results of density and porosity measurements, the highest values were 4.95 g/cm3 and 5.45%, respectively. XRD results showed the formation of a BaFe12O19 phase with some impurities at 0% (Fe2O3), 0.3% and 0.9% (Ti6O11), and 0.6% (Ti4O7). The SEM results showed that the morphology of TiO2-BaFe12O19 was quite homogeneous, and the size and cavity ranged from 0.5 – 1.5 μm and 0.25 – 0.9 μm, respectively. VSM results show Mr, Ms, Hc, and Bhmax values of 1,489 kG, 3,235 kG, 1,758 kOe, and Bhmax of 0,867 MGOe, respectively. The results of the Impulse Magnetizer K-Series show the maximum and lowest magnetic flux values of 272.65 gauss and 218.10 gauss at 0.6% and 0% variation, respectively.

本研究采用粉末冶金法制备六铁体钡(BaFe<sub>12</sub>O<sub>19</sub>)磁性陶瓷,并添加0%:0.3%:0.6%和0.9%变化的二氧化钛(TiO<sub>2</sub>)添加剂。本研究使用的表征是密度、孔隙度、x射线衍射(XRD)、扫描电子显微镜(SEM)、振动样品磁强计(VSM)和k系列脉冲磁化仪的测量。根据密度和孔隙度测量结果,最高值分别为4.95 g/cm3和5.45%。XRD结果表明:BaFe<sub>12</sub>O<sub>19</sub>阶段有一些杂质在0% (Fe< sub> 2 & lt; / sub> O< sub> 3 & lt; / sub>), 0.3%和0.9% (Ti< sub> 6 & lt; / sub> O< sub> 11 & lt; / sub>),和0.6% (Ti< sub> 4 & lt; / sub> O< sub> 7 & lt; / sub>)。SEM结果表明:TiO<sub>2</sub>-BaFe<sub>12</sub>O<sub>19</sub>晶粒尺寸为0.5 ~ 1.5 μm,空腔尺寸为0.25 ~ 0.9 μm。VSM结果显示,Mr为1489 kG, Ms为3235 kG, Hc为1758 kOe, Bhmax为0867 MGOe。k系列脉冲式磁化器的结果表明,在0.6%和0%的变化下,最大和最低磁通量分别为272.65高斯和218.10高斯。
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引用次数: 0
The Impact of Solvent Composition and Copper (Cu) Ion Doping on Dye Anthocyanin on Increasing Dye-Sensitized Solar Cell (DSSC) Efficiency 溶剂组成及铜离子掺杂染料花青素对提高染料敏化太阳能电池效率的影响
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.66716
Novi Dyah Puspitasari, Fahru Nurosyid, Untung Riyadi, Sophia Dewi Nur Anisa, Kusumandari Kusumandari

The development of Dye Sensitized Solar Cells (DSSC) is increasing fast because fabrication costs are more affordable than silicon solar cells. In this study, anthocyanin pigments were used as a natural dye source. Anthocyanins are a group of flavonoids that can be extracted most proficiently in acidic conditions; therefore, variations in the composition of solvents and acids significantly impact anthocyanin yield. The anthocyanin pigments in this study were extracted from dragon fruit peels using a maceration method with variations in methanol composition and the addition of hydrochloric acid or citric acid (3/0; 3/0.5; 3/1). This study aims to improve the efficiency of DSSC by varying the solvent composition and adding Cu ion doping. The characterizations include measurement of absorbance, functional group, and efficiency using UV-Vis Spectrophotometer, Fourier Transform Infrared (FTIR), and current-voltage, respectively. The results show that anthocyanin dye with a composition of methanol/acid (3/0) and the addition of Cu ion produced the highest absorbance value and efficiency of 0.4102 Ω-1m-1 and 0.016%, respectively.

<p class="摘要">染料敏化太阳能电池(DSSC)的发展迅速,因为制造成本比硅太阳能电池更实惠。在本研究中,<em>花青素pigments< / em>被用作天然染料来源。花青素是一类黄酮类化合物,在酸性条件下最容易提取;因此,溶剂和酸组成的变化显著影响花青素的产量。本研究以火龙果皮为原料,采用不同甲醇组成的浸渍法提取花青素色素,并加入盐酸或柠檬酸(3/0;3/0.5;3/1)。本研究旨在通过改变溶剂组成和添加Cu离子掺杂来提高DSSC的效率。表征包括分别使用紫外-可见分光光度计,傅里叶变换红外(FTIR)和电流-电压测量吸光度,官能团和效率。结果表明:以甲醇/酸(3/0)为配比,加入Cu离子时,花青素染料的吸光度值和效率最高,为0.4102 Ω<sup>-1</sup>和0.016% .</p>
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引用次数: 0
Physics Application in Traditional Archery: Sight-lines Method for Aiming Using a Traditional Bow 物理在传统射箭中的应用:用传统弓瞄准的视线法
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.66525
Ibnu Jihad

The absence of bow sight in a traditional bow can be replaced by introducing sight lines as a reference for accurate elevation angles in archery. Assuming a quadratic drag force acting on the arrow, a sight line can be calculated by using the values of target distances, initial arrow speed, arrow velocity decay, and the stance of the archer. This method can improve shooting accuracy for various target distances.

<p lang="en-AU" align="justify">传统弓上没有瞄准镜,射箭时可以引入瞄准线作为精确仰角的参考。假设有二次阻力作用在箭上,利用目标距离、箭初速度、箭速衰减和射手的姿态值可以计算出瞄准线。这种方法可以提高不同目标距离下的射击精度。
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引用次数: 0
Estimating Surface Current from HIMAWARI-8 SST Data using Particle Image Velocimetry Method (Case Study in The Flores Sea) 利用粒子图像测速法估算HIMAWARI-8海温数据中的表面流(以弗洛雷斯海为例)
Pub Date : 2023-11-02 DOI: 10.13057/ijap.v13i2.76131
Kadek Setiya Wati, Takahiro Osawa, I Wayan Gede Astawa Karang

Four High-Frequency radar systems (HF) have been installed in Indonesia to monitor surface currents. In-situ ocean current observations are relatively expensive and limited by spatial and temporal resolution. Satellite remote sensing enables the estimate of surface current data generally from surface tracer data, including sea surface temperature (SST). Various methodologies have been developed to obtain surface currents. With Himawari-8 SST data, this study examines the accuracy of the resulting estimation. The cross-correlation fields of two identical-sized interrogation windows obtained from sequential images are employed in Particle Image Velocimetry (PIV). The HF radar in Labuan Bajo was used to validate surface current velocity estimates. RMSE, bias, and the Willmott index determined the accuracy. According to the estimates of surface currents made on July 29, 2022, the results follow a monsoon characteristic wind pattern in the Flores Sea. HF radar observations better validate the V component current estimation than the U component current estimation. A study of sea surface currents from SST data is lacking in Indonesian seas, and more repetition is required. As a result, This method has the potential can be employed to observe aquatic environments in other Indonesian areas.

印尼已经安装了四套高频雷达系统(HF)来监测海面洋流。原位海流观测相对昂贵,且受时空分辨率的限制。卫星遥感一般可以从表面示踪剂数据(包括海温)估计表面洋流数据。已经发展了各种方法来获得表面电流。利用Himawari-8海温数据,本研究检验了估算结果的准确性。将序列图像中两个大小相同的询问窗口的相互关场用于粒子图像测速。Labuan Bajo的高频雷达用于验证地表流速估计。均方根误差、偏差和威尔莫特指数决定了准确性。根据2022年7月29日对海面洋流的估计,结果符合弗洛雷斯海的季风特征风型。高频雷达观测比U分量电流估计更能验证V分量电流估计。印度尼西亚海域缺乏根据海温资料对海表流的研究,需要更多的重复研究。因此,该方法具有应用于印度尼西亚其他地区水生环境观测的潜力。</p>
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引用次数: 0
Sistem Pengukuran Detak Jantung Menggunakan Arduino Dan Android Berbasis Fotopletismogram 该系统使用阿都诺和一个基于光电图的Android测量心率
Pub Date : 2023-06-20 DOI: 10.13057/ijap.v13i1.73636
Nuryani Nuryani, Muhammad Farrel Akshya, Nanang Wiyono
Penelitian mengenai perancangan sistem pengukuran detak jantung berhasil dilakukan. Pengukuran detak jantung mandiri dapat membantu dalam menjaga kesehatan. Fotopletismogram atau PPG merupakan metode yang mampu memberi kemudahan dalam pengukuran detak jantung. Sensor PPG Easy Pulse Plugin adalah salah satu sensor PPG dengan modul pengondisi sinyal. Sensor PPG dihubungkan dengan Arduino untuk membaca sinyal dan memberikan perintah pengiriman secara nirkabel ke Android smartphone melalui Bluetooth. Aplikasi pada Android akan menampilkan sinyal dan hasil pengukuran detak jantung. Hasil pengukuran akan disimpan pada penyimpanan internal Android. Perhitungan detak jantung dilakukan berdasarkan interval waktu antar puncak pada sinyal PPG. Algoritma penentuan puncak sinyal PPG asli dapat dilakukan dengan memberikan kombinasi antara threshold dan batas interval pada sinyal PPG. Threshold terbaik adalah 2,13 V dan batas interval terbaik adalah 0,45 detik. Nilai kombinasi ini memberikan error rendah, yaitu 4,26%. Nilai sensitivitas, prediktif positif sekaligus.
关于设计心率测量系统的研究得到了成功。自我心跳测量有助于保持健康。摄影活图或PPG是一种方便测量心率的方法。轻松脉冲插件的PPG传感器是带有信号控制模块的PPG传感器之一。PPG传感器与Arduino连接,通过蓝牙读取信号并无线向Android智能手机发送命令。Android上的应用程序将显示信号和心率测量结果。测量结果将存储在Android内部存储中。心率是根据PPG信号的峰值间隔进行的。最初的PPG信号峰值识别算法可以通过给出第一个threshold和PPG信号间隔限制的组合来实现。最佳顶货舱为2.13 V,间隔限制为0.45秒。这些组合值给出的误差很低,是4.26%。敏感性,同时具有积极的预测。
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引用次数: 0
A Brief Study of Methods to Determine the Electrical Resistivity of Materials 材料电阻率测定方法初探
Pub Date : 2023-04-30 DOI: 10.13057/ijap.v13i1.64742
Inzamam Khalid
Present study deals with the study of methods to calculate the resistivity of materials. Different methods are discussed which determine the resistivity of specific materials on the basis of their shapes and sizes.  Their working, structure, advantages and loopholes are discussed in a brief manner. Materials are categorized according to their magnitude of resistivity. The two probe method is helpful in measuring the resistivity of high resistive samples while four probe methods can be used for materials with low resistance. Pulse probe method measures the resistivity of materials having small physical dimensions. The Montgomery method is useful in finding the individual resistivities of anisotropic materials.
本研究主要研究材料电阻率的计算方法。讨论了根据特定材料的形状和尺寸确定其电阻率的不同方法。简要论述了它们的工作原理、结构、优点和漏洞。根据材料的电阻率大小对其进行分类。双探针法有助于测量高电阻样品的电阻率,而四探针法可用于低电阻材料。脉冲探针法测量具有小物理尺寸的材料的电阻率。Montgomery方法在寻找各向异性材料的单个电阻率方面是有用的。
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引用次数: 0
Identifikasi Daerah Rawan Longsor secara Mikrozonasi di Jalan Alternatif Provinsi menggunakan Metode Simple Additive Weighting (SAW) 用简单的加糖Weighting方法(锯)确定省道替代道路上的低分区滑坡地区
Pub Date : 2023-04-30 DOI: 10.13057/ijap.v13i1.62110
Darmawan Ikhlas Fadli, Arif Ismul Hadi, Zagita Allifya, Septi Anggriani, Rama Ramdani, Beni Syakban Idris, Refrizon Refrizon

The alternative provincial in Bengkulu Tengah Regency is located in a location bordering the Musi Fault segment that is part of the Great Sumatran Fault Zone. This condition makes cross-provincial roads in Central Bengkulu Regency vulnerable to natural disasters such as landslides. The purpose of the study was to determine areas that have the potential for landslides in earthquake-prone areas of Central Bengkulu Regency, Bengkulu Province, Indonesia. We performed the HVSR (horizontal to vertical spectral ratio) analysis and the simple additive weighting (SAW) method to achieve the study purpose. Field data acquisition using the PASI Gemini2 broadband seismometer (triaxial geophone). Next, we analyzed the tremor data recorded in the field using a wave spectrum. From the results of this study, we knew that the possibility of landslides in the survey area classified into three categories that is low, medium and high. Landslide risk should be paid more attention in areas with high potential, especially in densely populated areas. The main threat in the study area is an earthquake along the active Sumatran fault. Earthquakes in areas that are very steep and prone to landslides can increase the risk and cause landslides.

<p class=“摘要文本”> Bengkulu Tengah reggency的另一个省位于Musi断层段的边缘,该断层段是大苏门答腊断裂带的一部分。这种情况使得中明古鲁县的跨省公路容易受到山体滑坡等自然灾害的影响。本研究的目的是确定在印度尼西亚明古鲁省明古鲁中央区地震易发地区可能发生滑坡的地区。我们通过HVSR(水平与垂直光谱比)分析和简单加性加权(SAW)法来达到研究目的。使用PASI Gemini2宽带地震仪(三轴检波器)进行现场数据采集。接下来,我们使用波谱分析了现场记录的地震数据。从研究结果可知,调查区发生滑坡的可能性分为低、中、高三类。滑坡危险性高的地区,特别是人口密集地区,应引起高度重视。研究区域的主要威胁是沿苏门答腊活动性断层发生的地震。在非常陡峭和容易发生山体滑坡的地区发生地震会增加风险,并导致山体滑坡。
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引用次数: 0
期刊
Indonesian Journal of Applied Physics
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