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Room temperature gas sensor based on porous NiO nanoplates modified with rGO nanosheets and SnO2 nanoparticles for accurate and rapid ppb-level NO2 detection 基于还原氧化石墨烯纳米片和SnO2纳米颗粒修饰的多孔NiO纳米板的室温气体传感器,用于精确和快速的ppb级NO2检测
IF 17.9 2区 材料科学 Q1 Engineering Pub Date : 2025-01-10 DOI: 10.1016/j.nanoms.2024.12.006
Haineng Bai , Cheng Feng , Yiru Chen , Yunxiao Du , Yamin Feng , Kuili Liu , Yali Yan , Jia Liu , Baohua Zhang , Jin Wang , Dunjun Chen , Youdou Zheng , Fuqiang Guo
The porous NiO nanoplates modified with rGO nanosheets and SnO2 nanoparticles are developed for accurate and rapid ppb-level NO2 detection. The developed SnO2/NiO/rGO sensor towards 50 ​ppm NO2 gas demonstrates an excellent gas-sensing response of 14.8 ​at 23 ​°C, which is 3.03 times that of NiO/rGO sensor (4.89) and 6.49 times that of NiO sensor (2.28), respectively. The developed SnO2/NiO/rGO sensor exhibits faster response/recovery speed (12.7/32.8 ​s @5 ​ppm), with extra-low theoretical detection limit of 0.15 ​ppb at room temperature. More fascinatingly, our sensors indicate great sensitivity, outstanding repeatability and long-term stability for longer than 7 weeks. Additionally, it also suggests that 1 ​°C and 1 % relative humidity have the same effect on the SnO2/NiO/rGO sensor signal as approximately 13 ​ppb and 7.0 ​ppb NO2 gas change, respectively. Such excellent properties are mainly attributed to the large surface-to-volume ratio, which provides active sites to NO2 gas spread, adsorption and diffusion on material surface in redox reaction. Moreover, the ternary heterojunctions formed by NiO, rGO and SnO2 may serve as highly conductive channels to accelerate carrier transfer and abundant oxygen vacancies to reduce the adsorption energy for O2 and NO2 gas, thus further improving performance of the sensors.
采用还原氧化石墨烯纳米片和SnO2纳米颗粒修饰的多孔NiO纳米板,用于精确、快速的ppb级NO2检测。所研制的SnO2/NiO/rGO传感器对50 ppm NO2气体的气敏响应在23℃时达到了14.8,分别是NiO/rGO传感器(4.89)和NiO传感器(2.28)的3.03倍和6.49倍。所开发的SnO2/NiO/rGO传感器具有更快的响应/恢复速度(12.7/32.8 s @5 ppm),室温下的超低理论检测限为0.15 ppb。更令人着迷的是,我们的传感器具有很高的灵敏度,出色的可重复性和超过7周的长期稳定性。此外,它还表明,1°C和1%的相对湿度对SnO2/NiO/rGO传感器信号的影响分别为大约13 ppb和7.0 ppb的NO2气体变化。这种优异的性能主要归功于大的表面体积比,为氧化还原反应中NO2气体在材料表面的扩散、吸附和扩散提供了活性位点。此外,由NiO、rGO和SnO2形成的三元异质结可以作为高导电通道加速载流子转移和丰富的氧空位,从而降低对O2和NO2气体的吸附能,从而进一步提高传感器的性能。
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引用次数: 0
Application of nanomaterials in antifouling: A review 纳米材料在防污中的应用:综述
IF 9.9 2区 材料科学 Q1 Engineering Pub Date : 2024-12-01 DOI: 10.1016/j.nanoms.2024.01.009
Nan Wang , Ruiyong Zhang , Kunpeng Liu , Yuxin Zhang , Xin Shi , Wolfgang Sand , Baorong Hou
With the continuous development of the marine economy and the upgrading of marine infrastructure, the increasing marine engineering equipment is facing a serious problem of marine fouling. However, developing marine antifouling materials and antifouling technologies is extremely difficult due to the complexity of the marine environment and the biodiversity of the fouling. Therefore, it is the key breakthrough to develop advanced materials for solving marine fouling problems. Nanomaterials with small dimensions and controlled micro-structure have outstanding antifouling efficiency and great promise for various antifouling fields. Herein, the development of antifouling nanomaterials and technologies in recent years are reviewed for aspects of types of antifouling nanomaterials, technologies of antifouling, and potential application of antifouling. The antifouling nanomaterials are categorized as non-metal-based nanomaterials, metal-based nanomaterials, polymeric nanomaterials, composite nanomaterials, and others. Additionally, the potential applications of antifouling nanomaterials, including marine antifouling, water treatment, and medical antifouling are discussed. Finally, we proposed the perspectives of research and development trends of the antifouling nanomaterials. This overview may promote the development of new efficient antifouling nanomaterials and develop their potential commercial applications.
随着海洋经济的不断发展和海洋基础设施的不断升级,日益增多的海洋工程装备面临着严重的海洋污损问题。然而,由于海洋环境的复杂性和污损生物的多样性,开发海洋防污材料和防污技术极为困难。因此,开发先进材料是解决海洋污损问题的关键突破口。尺寸小、微结构可控的纳米材料具有优异的防污效率,在各种防污领域大有可为。本文从防污纳米材料的种类、防污技术、防污的潜在应用等方面综述了近年来防污纳米材料和技术的发展。防污纳米材料分为非金属基纳米材料、金属基纳米材料、聚合物纳米材料、复合纳米材料和其他材料。此外,还讨论了防污纳米材料的潜在应用,包括海洋防污、水处理和医疗防污。最后,我们提出了防污纳米材料的研究和发展趋势展望。本综述可促进新型高效防污纳米材料的开发及其潜在的商业应用。
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引用次数: 0
2D SnSe2 micro-flower decorated with 0D In2O3 nanoparticles for low-temperature low-concentration TEA detection 用 0D In2O3 纳米粒子装饰的二维 SnSe2 微花,用于低温低浓度三乙醇胺检测
IF 9.9 2区 材料科学 Q1 Engineering Pub Date : 2024-12-01 DOI: 10.1016/j.nanoms.2024.02.010
Li Wang , Jianpeng Li , Cheng Xu , Ziqin Yang , Xiangyun Tan , Zhihu Dong , Li Xu , Dongwei Zhang , Chunqing He
Triethylamine, a crucial industrial raw material, poses significant threats to both the ecosystem and human health. However, detecting lower concentrations of TEA remains an arduous task. In this study, we report the facile hydrothermal and ultrasonic treatment synthesis of 2D SnSe2 micro-flower modified with 0D In2O3 nanoparticles to form SnSe2/In2O3 heterojunctions for the first time. The SnSe2/In2O3 sensor has a response value of 4.86 for 10 ​ppm TEA gas at 120 ​°C, with response and recovery times of 18 ​s and 79 ​s respectively, and detection limits as low as 100 ​ppb. In addition, the SnSe2/In2O3 sensor is essentially unaffected by humidity in the 30% RH to 60% RH range, and the SnSe2/In2O3 sensor response value decreases slightly in the 70% RH to 97% RH range, demonstrating excellent humidity tolerance. More importantly, the sensor maintained excellent cyclic-stability performance during a four-month cyclic stability test. The improved gas-sensitive performance can be attributed to the large number of n-n heterojunctions in the SnSe2/In2O3 material, which enhances the interfacial charge transfer, as well as the active-sites on the material surface. This work serves as a valuable complement to the TEA gas sensor and holds significant potential for detecting low concentrations of TEA at low temperatures in environmental sensing applications.
三乙胺是一种重要的工业原料,对生态系统和人类健康都构成重大威胁。然而,检测较低浓度的三乙胺仍然是一项艰巨的任务。在这项研究中,我们首次报道了用 0D InO 纳米粒子修饰二维 SnSe 微花,形成 SnSe/InO 异质结的简便水热和超声处理合成方法。SnSe/InO 传感器在 120 °C 下对 10 ppm 三乙醇胺气体的响应值为 4.86,响应时间和恢复时间分别为 18 秒和 79 秒,检测限低至 100 ppb。此外,在 30% 相对湿度至 60% 相对湿度范围内,SnSe/InO 传感器基本上不受湿度的影响,而在 70% 相对湿度至 97% 相对湿度范围内,SnSe/InO 传感器的响应值会略有下降,这表明该传感器具有出色的耐湿性。更重要的是,该传感器在为期四个月的循环稳定性测试中保持了出色的循环稳定性能。气敏性能的提高可归因于 SnSe/InO 材料中大量的 n-n 异质结增强了界面电荷转移,以及材料表面的活性位点。这项工作是对三乙醇胺气体传感器的重要补充,在环境传感应用中低温检测低浓度三乙醇胺方面具有巨大潜力。
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引用次数: 0
Recent advances in self-lubricating metal matrix nanocomposites reinforced by carbonous materials: A review 碳材料增强的自润滑金属基纳米复合材料的最新进展:综述
IF 9.9 2区 材料科学 Q1 Engineering Pub Date : 2024-12-01 DOI: 10.1016/j.nanoms.2024.02.007
Wenting Ye , Yeran Shi , Qing Zhou , Mingda Xie , Haifeng Wang , Benyebka Bou-Saïd , Weimin Liu
Metal matrix self-lubricating materials lie at the core of cutting-edge aerospace, mechanical, and electrical industries, which demand technological performances that cannot be met by traditional liquid lubricants. Rapid innovation in nanocarbon materials in recent years enabled rapid development of advanced nanocomposites for applications in structural engineering and functional devices. Carbonous materials (e.g., graphite, graphene and carbon nanotubes), exhibit a wide range of unique electrical, mechanical, and thermal properties, which are also considered ideal lubricating reinforcements for metal matrix nanocomposites (MMCs) with superior mechanical and tribological properties. In this review, we first showcase the distinctive features of the constituents commonly employed in self-lubricating MMCs, encompassing the high-strength metallic matrix and nano-carbonous reinforcement. Then, we present a comprehensive overview of the recent advancements in preparation techniques for these advanced MMCs, followed by an in-depth discussion on their corresponding tribological properties and wear mechanisms. We close this review by outlining key problems to be solved and the future trend of the development in self-lubricating MMCs.
金属基自润滑材料是尖端航空航天、机械和电气工业的核心,其技术性能要求是传统液体润滑剂无法满足的。近年来,纳米碳材料的快速创新使得应用于结构工程和功能设备的先进纳米复合材料得以迅速发展。碳材料(如石墨、石墨烯和碳纳米管)具有多种独特的电学、机械和热学特性,被认为是金属基纳米复合材料(MMC)的理想润滑增强材料,具有优异的机械和摩擦学特性。在这篇综述中,我们首先展示了自润滑 MMC 中常用成分的显著特点,包括高强度金属基体和纳米碳增强材料。然后,我们全面概述了这些先进 MMC 制备技术的最新进展,并深入探讨了其相应的摩擦学特性和磨损机理。最后,我们概述了自润滑 MMC 需要解决的关键问题和未来的发展趋势。
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引用次数: 0
Multilayer laminated Cu coil/CaO–Li2O–B2O3–SiO2 glass-ceramic preparation via a novel insulation packaging strategy for flat wire motor applications 通过新型绝缘封装策略制备多层叠层铜线圈/CaO-Li2O-B2O3-SiO2 玻璃陶瓷,用于扁线电机应用
IF 9.9 2区 材料科学 Q1 Engineering Pub Date : 2024-12-01 DOI: 10.1016/j.nanoms.2024.02.002
Haitao Zhu , Yanyu Song , Guangyou Pan , Naibin Chen , Xiaoguo Song , Long Xia , Duo Liu , Shengpeng Hu
A new insulation packaging strategy for the stator windings of flat wire motors based on LTCC technology was studied for the first time. The study aimed to replace traditional plastic packaging methods and avoid aging issues by fabricating a novel multilayer laminated Cu coil/CaO–Li2O–B2O3–SiO2 glass-ceramic structure. The analysis of the interface microstructure of the laminated structure revealed that the CaO–Li2O–B2O3–SiO2 glass-ceramic matrix consisted of a crystalline phase of CaSiO3 and an amorphous phase of SiO2. The interface between the Cu coil and CaO–Li2O–B2O3–SiO2 glass-ceramic exhibited good bonding with no formation of secondary phases. Additionally, the strong bonding between the Cu coil and CaO–Li2O–B2O3–SiO2 glass-ceramic was attributed to the diffusion of Cu atoms at the interface. The novel multilayer laminated structure based on LTCC technology proposed in this study can help achieve high-reliability insulation packaging for the stator windings of future high-power density and miniaturized flat wire motors.
首次研究了基于 LTCC 技术的扁线电机定子绕组新型绝缘封装策略。该研究旨在通过制造一种新型多层层叠铜线圈/CaO-LiO-BO-SiO 玻璃陶瓷结构,取代传统的塑料封装方法并避免老化问题。对层压结构界面微观结构的分析表明,CaO-LiO-BO-SiO 玻璃陶瓷基体由 CaSiO 结晶相和 SiO 非晶相组成。铜线圈和 CaO-LiO-BO-SiO 玻璃陶瓷之间的界面结合良好,没有形成次生相。此外,Cu 线圈与 CaO-LiO-BO-SiO 玻璃陶瓷之间的牢固粘结还归因于界面上 Cu 原子的扩散。本研究提出的基于 LTCC 技术的新型多层层压结构有助于实现未来高功率密度和微型扁线电机定子绕组的高可靠性绝缘封装。
{"title":"Multilayer laminated Cu coil/CaO–Li2O–B2O3–SiO2 glass-ceramic preparation via a novel insulation packaging strategy for flat wire motor applications","authors":"Haitao Zhu ,&nbsp;Yanyu Song ,&nbsp;Guangyou Pan ,&nbsp;Naibin Chen ,&nbsp;Xiaoguo Song ,&nbsp;Long Xia ,&nbsp;Duo Liu ,&nbsp;Shengpeng Hu","doi":"10.1016/j.nanoms.2024.02.002","DOIUrl":"10.1016/j.nanoms.2024.02.002","url":null,"abstract":"<div><div>A new insulation packaging strategy for the stator windings of flat wire motors based on LTCC technology was studied for the first time. The study aimed to replace traditional plastic packaging methods and avoid aging issues by fabricating a novel multilayer laminated Cu coil/CaO–Li<sub>2</sub>O–B<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub> glass-ceramic structure. The analysis of the interface microstructure of the laminated structure revealed that the CaO–Li<sub>2</sub>O–B<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub> glass-ceramic matrix consisted of a crystalline phase of CaSiO<sub>3</sub> and an amorphous phase of SiO<sub>2</sub>. The interface between the Cu coil and CaO–Li<sub>2</sub>O–B<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub> glass-ceramic exhibited good bonding with no formation of secondary phases. Additionally, the strong bonding between the Cu coil and CaO–Li<sub>2</sub>O–B<sub>2</sub>O<sub>3</sub>–SiO<sub>2</sub> glass-ceramic was attributed to the diffusion of Cu atoms at the interface. The novel multilayer laminated structure based on LTCC technology proposed in this study can help achieve high-reliability insulation packaging for the stator windings of future high-power density and miniaturized flat wire motors.</div></div>","PeriodicalId":33573,"journal":{"name":"Nano Materials Science","volume":"6 6","pages":"Pages 775-779"},"PeriodicalIF":9.9,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140154975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The microstructural evolution and relaxation strengthening for nano-grained Ni upon low-temperature annealing 纳米晶粒镍低温退火后的微观结构演变和弛豫强化
IF 9.9 2区 材料科学 Q1 Engineering Pub Date : 2024-12-01 DOI: 10.1016/j.nanoms.2023.12.007
Ze Chai , Bo Peng , Xukai Ren , Kaiyuan Hong , Xiaoqi Chen
The microstructural evolution and relaxation strengthening of nano-grained Ni annealed at a temperature range of 493–553 ​K were studied by in situ X-ray diffraction technique, transmission electron microscopy, and microhardness evaluation. Upon low-temperature annealing, the rather limited variations of anisotropic grain size and root-mean-square strain, conforming to an exponential relaxation model, yield a consistent activation energy of approximately 0.5 ​eV, which corresponds to the localized, rapid diffusion of excess vacancies on nonequilibrium surfaces/interfaces and/or defective lattice configurations. Microstructure examinations confirm the grain boundary ordering and excess defect reduction. The relaxation-induced strength enhancement can be attributed to the linear strengthening in the regime of small elastic lattice strains. This study provides an in-depth understanding of low-temperature nanostructural relaxation and its relation to strengthening.
采用原位x射线衍射、透射电镜和显微硬度评价等方法研究了493 ~ 553 K退火后纳米Ni的组织演变和弛豫强化。在低温退火后,各向异性晶粒尺寸和均方根应变的变化相当有限,符合指数松弛模型,产生约0.5 eV的一致活化能,这对应于非平衡表面/界面和/或缺陷晶格构型上多余空位的局部快速扩散。显微组织检查证实晶界有序,多余缺陷减少。松弛引起的强度增强可归因于小弹性晶格应变下的线性强化。本研究为纳米结构的低温弛豫及其与强化的关系提供了深入的认识。
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引用次数: 0
Beyond contribution of ionic liquids in nanostructuring polyaniline morphology; its effect on the properties of the polymerization medium 离子液体在纳米聚苯胺形态结构中的作用及其对聚合介质性质的影响
IF 9.9 2区 材料科学 Q1 Engineering Pub Date : 2024-12-01 DOI: 10.1016/j.nanoms.2023.12.001
Fatima Al-Zohbi , Fouad Ghamouss , Bruno Schmaltz , Mohamed Abarbri , Khalil Cherry , Mohamad fadel Tabcheh , François Tran-Van
In the present work, the focus has been shifted to the relationship between the PANI morphology and the physicochemical properties, controlled by the amount of added ionic liquids, of the polymerization medium instead of focusing on the structure of the ionic liquids as used to be in the litterature. For that reason, PANI has been synthesized in different weight ratio of [Pyrr][PTS]/water following the standard experimental process. The addition of [Pyrr][PTS] into the polymerization medium controls the morphology of PANI without affecting its structure. Moreover, [Pyrr][PTS] promotes a viscous reaction system without the need of an external source. The viscosity of the polymerization system restricts the diffusion of species that leads to the predominance of the homogeneous nucleation mode during the course of polymerization and, thus, nanostructuring of PANI morphology. As for the ionic conductivity, it reflects the mobility of the ions of the polymerization medium and, thus, the way of its interference with the formed PANI that affects the arrangement and the shape of formed PANI fibers. This relationship between PANI morphology and the physicochemical properties, adjusted by adding ionic liquids, of the polymerization medium is prelaminar and promising. The effect of the ionic liquids on the viscosity as well as on the mobility of the polymerization medium have to be taken into consideration to choose the ionic liquids, which lead to the PANI with desired morphology.
在本研究中,研究的重点从以往文献中关注离子液体的结构转向聚苯胺的形态与聚合介质的物理化学性质之间的关系(由离子液体的加入量控制)。为此,按照标准实验流程,以[Pyrr][PTS]/水的不同重量比合成聚苯胺。在聚合介质中加入[Pyrr][PTS]可以控制聚苯胺的形态而不影响其结构。此外,[Pyrr][PTS]在不需要外部源的情况下促进了粘性反应体系。聚合体系的粘度限制了物质的扩散,从而导致聚合过程中均质成核模式的优势,从而导致聚苯胺形态的纳米结构。离子电导率反映了聚合介质中离子的迁移率,从而反映了离子对聚苯胺形成的干扰方式,从而影响聚苯胺纤维的排列和形状。聚苯胺的形态与聚合介质的物理化学性质之间的这种关系,通过加入离子液体来调节,是一种层状的、有前途的关系。在选择离子液体时,必须考虑离子液体对聚合介质粘度和迁移率的影响,从而得到符合要求形貌的聚苯胺。
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引用次数: 0
High-performance self-driven broadband photoelectrochemical photodetector based on reduced graphene oxide/Bi2Te3 heterojunction 基于还原氧化石墨烯/Bi2Te3 异质结的高性能自驱动宽带光电化学光电探测器
IF 9.9 2区 材料科学 Q1 Engineering Pub Date : 2024-12-01 DOI: 10.1016/j.nanoms.2023.12.008
Chenchen Zhao , Yangyang Liu , Dongbo Wang , Wen He , Bingke Zhang , Jingwen Pan , Zhi Zeng , Donghao Liu , Sihang Liu , Shujie Jiao , Xuan Fang , Dan Fang , Liancheng Zhao , Jinzhong Wang
Attributed to its excellent physicochemical properties, graphene (GR) has very active applications in the fields of catalysis, optoelectronic devices, and battery electrode materials. However, until now, regulating the type and density of carriers in GR is still crucial for its practical applications. Here, reduced graphene oxide (RGO)-Bi2Te3 heterojunctions doped with different contents were prepared by a simple one-step method. The Bi2Te3 materials containing different RGO were made into broadband (365–850 ​nm) photoelectrochemical-type detectors, and the effects of the doping amount of RGO on the optoelectronic behavior of the devices and the intrinsic operation mechanism of the devices were investigated in detail. The results show that the values of Iph/Idark, Ri, and D of Bi2Te3/RGO heterojunction devices obtained with 1 ​mg of RGO doping are 412, 6.072 ​mA/W, and 2.406 ​× ​1010 Jones, respectively. It is anticipated that this work will provide a research basis for future quantitative tuning of the performance of micro-nano devices by GR.
由于其优异的物理化学性质,石墨烯在催化、光电器件、电池电极材料等领域有着非常活跃的应用。然而,到目前为止,调控GR中载流子的类型和密度仍然是GR实际应用的关键。本文采用简单的一步法制备了掺杂不同含量的还原氧化石墨烯(RGO)-Bi2Te3异质结。将含有不同RGO的Bi2Te3材料制作成宽带(365 ~ 850 nm)光电型探测器,详细研究了RGO掺杂量对器件光电行为的影响以及器件的内在运行机制。结果表明,当RGO掺杂1 mg时,Bi2Te3/RGO异质结器件的Iph/Idark、Ri和D *分别为412、6.072 mA/W和2.406 × 1010 Jones。预计本工作将为未来利用GR定量调谐微纳器件的性能提供研究基础。
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引用次数: 0
Construction of 3D aerogels consisting of cellulose and BNNSs bridged by AgNPs for enhancing thermal and tribological properties of polyurethane composites 用 AgNPs 桥接纤维素和 BNNSs 构建三维气凝胶,提高聚氨酯复合材料的热性能和摩擦学性能
IF 9.9 2区 材料科学 Q1 Engineering Pub Date : 2024-12-01 DOI: 10.1016/j.nanoms.2024.02.004
Yu He , Yuanya Zhang , Yongjun Zhou , Junya Yuan , Xuehu Men
Waterborne polyurethane (WPU) is attracting widespread attention in the friction field, but pure WPU cannot meet the wear resistance requirements due to poor thermal and self-lubricating properties. Herein, a novel cellulose/BNNSs-AgNPs aerogel (CBAg) composed of zero-dimensional silver nanoparticles (AgNPs), one-dimensional cellulose and two-dimensional boron nitride nanosheets (BNNSs) was successfully fabricated. Specifically, AgNPs were loaded onto the surface of BNNSs, which could serve as bridges to connect adjacent BNNSs. Cellulose was used to construct a 3D skeleton structure for stabilizing better dispersion of inorganic fillers. Finally, the thermal and tribological properties of CBAg-WPU were improved compared to pure WPU, with a 69% increase in thermal conductivity and an 89% reduction in wear rate. This was attributed to the load-bearing capacity of cellulose and outstanding thermal and lubricant capability of BNNSs-AgNPs. In addition, BNNSs and AgNPs inside the aerogel were transferred to the sliding interface and participated in the formation of high-quality friction transfer film, further endowing CBAg-WPU composites prominent tribological performance. Therefore, the novel design of 3D hybrid aerogels provided a promising avenue to improve the tribological performance of WPU composites.
水性聚氨酯(WPU)在摩擦领域受到广泛关注,但由于热性能和自润滑性能较差,纯 WPU 无法满足耐磨性要求。本文成功制备了一种新型纤维素/BNNSs-AgNPs 气凝胶(CBAg),该气凝胶由零维银纳米粒子(AgNPs)、一维纤维素和二维氮化硼纳米片(BNNSs)组成。具体来说,AgNPs 被负载到 BNNSs 表面,可作为连接相邻 BNNSs 的桥梁。纤维素被用来构建三维骨架结构,以更好地稳定无机填料的分散。最后,与纯 WPU 相比,CBAg-WPU 的热性能和摩擦学性能得到了改善,热导率提高了 69%,磨损率降低了 89%。这归功于纤维素的承载能力和 BNNSs-AgNPs 出色的导热和润滑能力。此外,气凝胶中的 BNNSs 和 AgNPs 被转移到滑动界面,参与形成了高质量的摩擦传递膜,进一步赋予了 CBAg-WPU 复合材料突出的摩擦学性能。因此,三维混合气凝胶的新颖设计为改善WPU复合材料的摩擦学性能提供了一条很有前景的途径。
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引用次数: 0
Nanoarchitectonics of point-of-care diagnostics for sweat biomarkers analysis 用于汗液生物标记分析的床旁诊断纳米架构
IF 9.9 2区 材料科学 Q1 Engineering Pub Date : 2024-12-01 DOI: 10.1016/j.nanoms.2024.01.010
Xuan Lin , Arya Vasanth , Aditya Ashok , Hoang-Phuong Phan , Kevin M. Koo , Mohammed A. Amin , Yusuf Valentino Kaneti , Carlos Salomon , Md Shahriar A. Hossain , Yusuke Yamauchi , Mostafa Kamal Masud
Sweat contains numerous vital biomarkers such as metabolites, electrolytes, proteins, nucleic acids and antigens that reflect hydration status, exhaustion, nutrition, and physiological changes. Conventional healthcare diagnosis relies on disease diagnostics in sophisticated centralized laboratories with invasive sample collection (e.g., chemical analyses, plasma separation via centrifugation, tissue biopsy, etc.). Cutting-edge point-of-care diagnostics for sweat biomarker analysis allow for non-invasive monitoring of physiologically related biomarkers in sweat and real-time health status tracking. Moreover, using advanced nanoarchitectures, including nanostructured platforms and nanoparticles, can enhance the specificity, sensitivity, wearability and widen the sensing modality of sweat biosensors. Herein, we comprehensively review the secretory mechanisms, clinical uses of sweat biomarkers, and the design, principle, and latest technologies of sweat biosensors. With an emphasis on cutting-edge technologies for sweat biomarker analysis, this review chronicles the issues associated with the current sweat biomarkers analysis of sweat biomarkers and provides insights into strategies for enhancing the translation of such biosensors into routine clinical practice.
汗液中含有大量重要的生物标记物,如代谢物、电解质、蛋白质、核酸和抗原,可反映水合状态、疲惫程度、营养状况和生理变化。传统的医疗诊断依赖于在精密的中央实验室进行疾病诊断,并采集侵入性样本(如化学分析、血浆分离离心、组织活检等)。用于汗液生物标志物分析的尖端床旁诊断技术可对汗液中与生理相关的生物标志物进行无创监测,并实时跟踪健康状况。此外,利用先进的纳米结构,包括纳米结构平台和纳米颗粒,可以提高汗液生物传感器的特异性、灵敏度、耐磨性并拓宽传感模式。在此,我们全面综述了汗液生物标记物的分泌机制、临床用途以及汗液生物传感器的设计、原理和最新技术。这篇综述以汗液生物标志物分析的前沿技术为重点,记录了当前汗液生物标志物分析中的相关问题,并对加强此类生物传感器转化为常规临床实践的策略提出了见解。
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引用次数: 0
期刊
Nano Materials Science
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