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Coupled cellular automata-crystal plasticity modeling of microstructure-sensitive damage and fracture behaviors in deformation of α-titanium sheets affected by grain size 受晶粒尺寸影响的α-钛片变形中微结构敏感损伤和断裂行为的细胞自动机-晶体塑性耦合建模
IF 9.4 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-09-24 DOI: 10.1016/j.ijplas.2024.104138
Concerning the micro-scale deformation of titanium metal sheets, the number of grains in the sheet thickness direction decreases, and their formability exhibits a strong grain size sensitivity. Meanwhile, the twinning-induced dynamic recrystallization (TDRX) associated with grain size significantly affects the fracture behavior in the microforming of titanium sheets. Therefore, an accurate prediction of formability to improve manufacturing reliability remains challenging in the microforming of miniaturized titanium components. To address this issue, an in-depth understanding of the grain size-dependent TDRX behavior and its role in damage and fracture development in the microforming of α-titanium sheets is critical, and a coupled cellular automata-crystal plasticity (CA-CP) modeling framework was thus developed as an approach providing efficient solutions and insightful comprehensions of the issue. For the proposed modeling framework, a kinematic model for TDRX was established and integrated into the CP model by the CA algorithm. As a result, the microstructure evolution caused by TDRX was regarded as an intrinsic part of the constitutive behavior to connect heterogeneous plastic deformation and damage evolution through data transmission between the CP model and the CA algorithm. Additionally, the coupled CA-CP modeling framework was validated with the internal defect morphologies and deformation microstructures characterized by X-ray computed tomography (X-CT) and electron backscattered diffraction (EBSD). Experiment and simulation results demonstrated that the fine recrystallized (DRXed) grains were generated after the twin fragmentation when the dislocation density at twin boundaries reached a threshold of 9.2 × 1013 /m2. After TDRX, the dislocation density and the stress concentration intensity in recrystallization regions were revealed to decrease, accounting for the ductility improvement. Nevertheless, the dislocation density at twin boundaries was determined to decrease with the increase of grain size, leading to less twin fragmentation and the absence of TDRX. The uncoordinated deformation between fine DRXed grains motivated defects to grow spherically into microvoids, thereby preventing premature intergranular cracks along twins/grain boundaries. Ultimately, the deformation microstructures resulting from TDRX with the decrease of grain size were confirmed to control the brittle to ductile fracture transition of α-titanium sheets. The presented modeling framework and simulation procedure were validated to be able to predict the material integrity affected by crystalline microstructure in the deformation of titanium metal sheets.
在钛金属薄片的微尺度变形中,薄片厚度方向上的晶粒数量会逐渐减少,其成型性对晶粒尺寸具有很强的敏感性。同时,与晶粒大小相关的孪晶诱导动态再结晶(TDRX)会显著影响钛金属板微成形过程中的断裂行为。因此,在微型钛部件的微成形中,准确预测成形性以提高制造可靠性仍然是一项挑战。为了解决这个问题,深入了解晶粒尺寸相关的 TDRX 行为及其在 α 钛板材微成型过程中的损伤和断裂发展中的作用至关重要,因此开发了细胞自动机-晶体塑性(CA-CP)耦合建模框架,作为提供高效解决方案和深入理解该问题的一种方法。在所提出的建模框架中,建立了 TDRX 的运动模型,并通过 CA 算法将其集成到 CP 模型中。因此,TDRX 引起的微观结构演变被视为构成行为的固有部分,通过 CP 模型和 CA 算法之间的数据传输,将异质塑性变形和损伤演变联系起来。此外,还利用 X 射线计算机断层扫描(X-CT)和电子反向散射衍射(EBSD)表征的内部缺陷形态和变形微结构验证了 CA-CP 耦合建模框架。实验和模拟结果表明,当孪晶边界的位错密度达到 9.2 × 1013 /m2 的临界值时,孪晶破碎后会产生细小的再结晶(DRXed)晶粒。在 TDRX 之后,再结晶区域的位错密度和应力集中强度都有所下降,这也是延展性改善的原因。然而,孪晶边界的位错密度随着晶粒尺寸的增大而减小,导致孪晶破碎减少和 TDRX 的缺失。细小的 DRX 化晶粒之间的不协调变形促使缺陷球形生长为微空洞,从而防止了沿孪晶/晶粒边界过早出现晶间裂纹。最终,随着晶粒尺寸的减小,TDRX 产生的变形微结构被证实可以控制 α 钛片从脆性到韧性断裂的转变。所提出的建模框架和模拟程序经过验证,能够预测钛金属板变形过程中受结晶微结构影响的材料完整性。
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引用次数: 0
A variational framework for Cahn–Hilliard-type diffusion coupled with Allen–Cahn-type multi-phase transformations in elastic and dissipative solids 弹性和耗散固体中卡恩-希利亚德型扩散与艾伦-卡恩型多相转变的变分框架
IF 9.4 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-09-24 DOI: 10.1016/j.ijplas.2024.104131
This article presents a variational framework for coupled chemo-mechanical solids undergoing irreversible micro-structural changes at infinitesimal strains. The coupled problem is characterised by phenomena such as phase transitions, micro-structure coarsening and swelling. It is an extension of our previous work on variational inelasticity for a conserved chemo-mechanical setting to a unified conserved and non-conserved setting which include multi-phase transformations. The variational framework, again governed by continuous-time, discrete-time and discrete-space–time incremental variational principles, is outlined for coupled diffusion-phase transformation phenomena in elastic and dissipative solids. For the sake of simplicity, focus is restricted to isothermal conditions. It is shown that the governing macro- and micro-balance equations of the coupled problem appear as Euler equations of these minimisation and saddle point principles. In contrast to our previous work, extended variational principles (with the gradient of the chemical potential and phase fractions) are constructed that account for diffusion-phase transformation coupling. This is achieved by Legendre transformations. Note that the local–global solution strategy is still preserved and the resulting system of symmetric non-linear algebraic equations are solved by Newton–Raphson-type iterative methods. The applicability of the proposed framework is demonstrated by numerical simulations that qualitatively characterise lower bainitic micro-structure.
本文提出了一个变分框架,用于研究在无穷小应变下发生不可逆微观结构变化的耦合化学机械固体。耦合问题的特征是相变、微结构粗化和膨胀等现象。它是我们之前针对化学机械守恒设置的变分非弹性问题所做工作的延伸,将守恒和非守恒设置统一起来,其中包括多相转变。变分框架同样受连续-时间、离散-时间和离散-时空增量变分原理的支配,概述了弹性和耗散固体中的耦合扩散-相变现象。为简单起见,重点仅限于等温条件。研究表明,耦合问题的宏观和微观平衡方程是作为这些最小化和鞍点原理的欧拉方程出现的。与我们之前的工作不同的是,我们构建了扩展的变分原理(具有化学势梯度和相分数),其中考虑到了扩散和相变耦合。这是通过 Legendre 变换实现的。需要注意的是,仍然保留了局部-全局求解策略,由此产生的对称非线性代数方程系统采用牛顿-拉斐尔迭代法求解。通过数值模拟对下贝氏体微观结构进行定性分析,证明了所提框架的适用性。
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引用次数: 0
Tailoring multi-type nanoprecipitates in high-entropy alloys towards superior tensile properties at cryogenic temperatures 定制高熵合金中的多型纳米沉淀物,实现低温下的优异拉伸性能
IF 9.4 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-09-23 DOI: 10.1016/j.ijplas.2024.104132
In this work, the quasi-static tensile properties in the face-centered cubic-based Al0.5Cr0.9FeNi2.5V0.2 HEAs containing two types of heterogeneous nanoprecipitates, i.e., dual-lamellar and spherical nanoprecipitates, at ambient (293 K) and liquid nitrogen (77 K) temperatures are thoroughly investigated. The microstructure formed by aging at 873 K comprises L12 and body-centered cubic dual-lamellar (DL) nanoprecipitates. In contrast, aging at 773 K results in solely spherical L12 nanoparticles. Both nanoprecipitates enhance mechanical strength as temperatures drop to 77 K; however, the DL nanoprecipitates additionally boost the work hardening rate, whereas the spherical nanoparticles notably improve ductility. To investigate the underlying deformation mechanisms, we perform interrupted mechanical tests and microstructure characterizations at various strains. The DL nanoprecipitates are observed to go through a multistage work hardening rate response by gradually introducing new boundaries to block dislocation motion, activating the stacking fault (SF) networks, and forming Lomer–Cottrell locks. A combination of interface hardening, dislocation hardening, SF-induced hardening, and precipitation hardening in DL samples leads to stronger hetero-deformation-induced hardening at cryogenic temperatures. In comparison, while samples with only spherical nanoparticles exhibit a monotonous decrease in the work-hardening rate, the spherical nanoparticles can be sheared by dislocations, effectively alleviating strain concentration and thereby enhancing ductility at cryogenic temperatures. Overall, this work provides practical design principles of nanoprecipitates for fine-tuning the balance of strength and ductility in FCC-based HEAs at cryogenic temperatures.
本文深入研究了面心立方基 Al0.5Cr0.9FeNi2.5V0.2 HEA 在环境温度(293 K)和液氮温度(77 K)下的准静态拉伸性能,该 HEA 含有两种类型的异质纳米沉淀物,即双层和球形纳米沉淀物。在 873 K 温度下老化形成的微观结构包括 L12 和体心立方双层(DL)纳米沉淀物。相比之下,在 773 K 下老化形成的只有球形的 L12 纳米颗粒。当温度降至 77 K 时,两种纳米沉淀物都能提高机械强度;然而,DL 纳米沉淀物还能提高加工硬化率,而球形纳米颗粒则能显著改善延展性。为了研究其潜在的变形机制,我们在不同应变下进行了间断机械测试和微观结构表征。我们观察到 DL 纳米沉淀物通过逐渐引入新的边界来阻止位错运动、激活堆积断层(SF)网络并形成 Lomer-Cottrell 锁,从而经历了多级加工硬化率响应。在 DL 样品中,界面硬化、位错硬化、SF 诱导的硬化和沉淀硬化相结合,在低温条件下产生了更强的异质变形诱导硬化。相比之下,虽然只有球形纳米粒子的样品表现出单调的加工硬化率下降,但球形纳米粒子可以被位错剪切,有效缓解应变集中,从而提高低温下的延展性。总之,这项工作为微调低温下基于催化裂化的 HEA 的强度和延展性平衡提供了实用的纳米沉淀物设计原则。
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引用次数: 0
Tailoring thickness debit for high-temperature fatigue resistance of Inconel 718 superalloy fabricated by laser powder bed fusion 利用激光粉末床熔融技术制造的 Inconel 718 超合金的高温抗疲劳性的厚度调试碎片
IF 9.4 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-09-23 DOI: 10.1016/j.ijplas.2024.104137
The thickness debit often leads to uncertainty regarding the fatigue performance of laser powder bed fusion (LPBF)-fabricated Inconel 718 thin-walled components and restricts the structural design of these components. Aiming to address this issue, fatigue properties of LPBF-fabricated Inconel 718 homogenized at various temperatures were investigated at 650 °C using specimens with different thicknesses. The results reveal a pronounced influence of both the thickness debit and the intricate interplay between the microstructural and geometrical scales of the thin-walled specimens on their fatigue life at 650 °C. The fatigue life of the thin-walled specimens with the same microstructural scale reduces with decreasing the ratio (t/d) of the specimen thickness (t) to the grain length (d). The coupling effect is described by a mechanism model correlated with the geometrical and microstructural scales of the specimens, in which continuous damage mechanics (CDM) and calculation of the yield strength have been considered. Based on the model, a criterion of t/d > 6.2 for the LPBF-fabricated Inconel 718 specimens homogenized at 1100 °C, and t/d > 8.8 for those homogenized at 1065 °C are proven to be satisfied to ensure a longer and more stable fatigue life of the thin-walled specimens serving at 650 °C. Elevating the homogenization temperature from 1065 °C to 1100 °C results in an extension of the fatigue life for specimens of the same thickness. This enhancement is attributed to the improved ability of grains to coordinate local deformation, as well as the reduced prevalence of elongated Laves and other phases, which typically serve as preferential sites for crack initiation and propagation. The finding suggests that the thickness debit in high-temperature fatigue resistance of LPBF-fabricated components can be minimized by tailoring the heat treatment strategy.
厚度差异经常导致激光粉末床熔化(LPBF)制造的 Inconel 718 薄壁部件的疲劳性能不确定,并限制了这些部件的结构设计。为了解决这个问题,研究人员使用不同厚度的试样,在 650 °C 下研究了不同温度下均质的 LPBF 制成的 Inconel 718 的疲劳性能。结果表明,薄壁试样的厚度差异以及微观结构和几何尺度之间错综复杂的相互作用对其在 650 °C 下的疲劳寿命有明显影响。具有相同微观结构尺度的薄壁试样的疲劳寿命随着试样厚度(t)与晶粒长度(d)之比(t/d)的减小而降低。耦合效应由一个与试样几何和微观结构尺度相关的机理模型来描述,其中考虑了连续损伤力学(CDM)和屈服强度计算。根据该模型,在 1100 ℃ 下均质的 LPBF 制成的 Inconel 718 试样的 t/d > 标准为 6.2,而在 1065 ℃ 下均质的试样的 t/d > 标准为 8.8。将均质温度从 1065 °C 提高到 1100 °C,可延长相同厚度试样的疲劳寿命。这种延长归因于晶粒协调局部变形的能力提高,以及拉长的 Laves 和其他相的减少,这些相通常是裂纹产生和扩展的首选部位。这一研究结果表明,通过调整热处理策略,可以最大限度地减少 LPBF 制成部件高温抗疲劳性能的厚度差异。
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引用次数: 0
Rapid assessment of the creep rupture life of metals: A model enabling experimental design 快速评估金属的蠕变断裂寿命:有助于实验设计的模型
IF 9.4 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-09-21 DOI: 10.1016/j.ijplas.2024.104133
Prediction of the creep rupture life of engineering metals is critical for qualification and design of new materials. The use of long-term creep tests and the need to quantify the performance variability in a priori similar systems hinder the rapid creep assessment of a given material. Therefore, it is essential to develop methods that can extrapolate the long-term performance of alloys and the associated variability from short-term experiments. To this end, this study introduces a new model which enables the estimation of the rupture life of a material for a given stress and temperature. This model relies on two components. First, a new relation for the minimum creep rate (MCR) of materials is introduced. It includes a stress dependent stress exponent allowing the model to capture the variation of MCR across a wide range of temperatures and stresses. Second, employing the Monkman-Grant (MG) law, we establish a relation between stress, temperature and creep rupture life. Together, these two elements yield a new closed-form mathematical expression for the Larson Miller parameter as a function of stress and temperature. This expression captures the creep rupture time for many metals (Gr91, Copper, Gr122 and 347H) and compares favorably with alternate empirical approaches. The model is then used to assess the minimum duration of creep rates necessary to qualify the material up to 100000h. It is found that depending on the material system, creep tests as few as five limited to 5000 h for steels (Gr91, Gr122, 347H) and 100 h for copper are sufficient to model creep lifetimes. Finally, using a Bayesian inference-based approach to calibrate the model, we demonstrate that variability in rupture life can be captured via the quantification of the uncertainty in the model parameters and extrapolated from a limited number of short to moderately short creep tests; thereby paving the way for accelerated creep testing.
工程金属的蠕变断裂寿命预测对于新材料的鉴定和设计至关重要。使用长期蠕变试验以及量化先验类似系统性能变异性的需要,阻碍了对特定材料进行快速蠕变评估。因此,必须开发能够从短期实验中推断合金长期性能和相关变异性的方法。为此,本研究引入了一个新模型,可估算给定应力和温度下材料的断裂寿命。该模型由两部分组成。首先,引入了材料最小蠕变速率(MCR)的新关系。它包括一个与应力相关的应力指数,使模型能够捕捉到 MCR 在各种温度和应力下的变化。其次,利用蒙克曼-格兰特(MG)定律,我们建立了应力、温度和蠕变断裂寿命之间的关系。这两个要素结合在一起,产生了拉森-米勒参数作为应力和温度函数的新闭式数学表达式。该表达式捕捉到了许多金属(Gr91、铜、Gr122 和 347H)的蠕变断裂时间,并与其他经验方法进行了比较。然后,利用该模型评估了使材料合格达 100000 小时所需的最小蠕变速率持续时间。研究发现,根据材料系统的不同,钢材(Gr91、Gr122、347H)的蠕变试验只要限制在 5000 小时以内,铜材的蠕变试验只要限制在 100 小时以内,就足以建立蠕变寿命模型。最后,我们使用基于贝叶斯推理的方法来校准模型,证明可以通过量化模型参数的不确定性来捕捉断裂寿命的变化,并从数量有限的短期至中度短期蠕变试验中推断出来;从而为加速蠕变试验铺平了道路。
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引用次数: 0
The dependence of Zener-Hollomon parameter on softening behavior and dynamic recrystallization mechanism of a biodegradable Zn-Cu-Mg alloy 齐纳-霍洛蒙参数对可生物降解锌-铜-镁合金软化行为和动态再结晶机制的影响
IF 9.4 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-09-21 DOI: 10.1016/j.ijplas.2024.104120
The Zn-Cu-Mg alloy exhibits good strength, ductility, anti-aging and antibacterial properties, which lays the foundation for developing high performance Zn-based biodegradable alloys. However, the constitutive equation and dynamic recrystallization (DRX) behavior of this alloy remain unclear, making the optimization of hot processing parameters almost dependent on trial and error. This work aims to address these issues by investigating the hot compression process. The calculated average activation energy Q of this alloy is 141.338 KJ⋅mol-1, exhibiting excellent heat resistance. The deformed microstructure strongly depends on the Zener-Hollomon parameter (Z=ε˙exp(QRT)). Discontinuous DRX (DDRX) dominates at low lnZ, which has a significantly different orientation from the parent grain. Continuous DRX (CDRX) occurs within the grain and at grain boundaries, and is dominant at middle lnZ, mainly through activation 〈a〉 or/and 〈c+a〉 slip systems. Additionally, the activation of prismatic slip further promote CDRX, and most CDRX grains inherit the 30°[0001] orientation from the parent grains. The volume fraction of DRX demonstrates a decreasing trend followed by an increasing trend with increasing lnZ. At high lnZ, the increase of DRX grains is conducive to weakening the texture, and twin-induced DRX (TDRX) is significantly promoted, leading to an increase in both peak stress and strain hardening rate. Furthermore, the grains with c-axis aligned parallel to the compression direction (CD) are more prone to twinning, while the c-axis perpendicular to CD are the hard orientation of basal slip and compression twins. TEM results reveal that a decrease of c/a value promotes the activation of non-basal slip near the twin boundary, and the highly active 〈c〉 and 〈c+a〉 slips contribute to the increase of strain hardening rate. The results of this study are significant for understanding the workability of Zn-Cu-Mg alloys at high lnZ due to its high efficiency and low cost.
Zn-Cu-Mg 合金具有良好的强度、延展性、抗老化和抗菌性能,这为开发高性能 Zn 基生物可降解合金奠定了基础。然而,这种合金的构成方程和动态再结晶(DRX)行为仍不清楚,使得热加工参数的优化几乎依赖于试验和错误。本研究旨在通过研究热压过程来解决这些问题。计算得出的这种合金的平均活化能 Q 为 141.338 KJ-mol-1,表现出优异的耐热性。变形微观结构在很大程度上取决于齐纳-霍洛蒙参数(Z=ε˙exp(QRT))。在低 lnZ 条件下,不连续 DRX(DDRX)占主导地位,其取向与母晶粒明显不同。连续DRX(CDRX)发生在晶粒内部和晶粒边界,在中lnZ时占主导地位,主要通过激活〈a〉或/和〈c+a〉滑移体系。此外,棱柱滑移的激活进一步促进了CDRX,大多数CDRX晶粒继承了母晶粒的30°[0001]取向。随着 lnZ 的增加,DRX 的体积分数呈先减后增的趋势。在高 lnZ 条件下,DRX 晶粒的增加有利于削弱纹理,而孪生诱导 DRX(TDRX)则显著增加,从而导致峰值应力和应变硬化率的增加。此外,c 轴平行于压缩方向(CD)的晶粒更容易产生孪晶,而与 CD 垂直的 c 轴则是基底滑移和压缩孪晶的硬取向。TEM 结果表明,c/a 值的减小会促进孪晶边界附近非基底滑移的激活,而高度活跃的〈c〉和〈c+a〉滑移有助于提高应变硬化率。这项研究的结果对了解高 lnZ 下 Zn-Cu-Mg 合金的可加工性具有重要意义,因为它效率高、成本低。
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引用次数: 0
Enhancing fatigue crack propagation resistance of heterostructured Al composites and multistage crack mechanisms 增强异质结构铝复合材料的抗疲劳裂纹扩展能力和多级裂纹机制
IF 9.4 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-09-21 DOI: 10.1016/j.ijplas.2024.104136
High tensile strength and low fatigue crack propagation (FCP) rate are hard to achieve simultaneously in aluminium (Al) based materials, which has been a long-lasting topic. It is because the traditional strengthening mechanisms may lead to the increase in FCP rate. In this work, we developed dual-level heterostructures by incorporating the in-situ synthesized TiB2 particles into Al matrix, to create particle-lean zones (PLZs) and particle-rich zones (PRZs) by extrusion. Fine grains were introduced by particle-associated local recrystallization in PRZs. By means of particle and grain size distribution, a heterostructured Al composite featuring with the coarse grains in PLZs and fine grains in PRZs was fabricated. It was found that simultaneous enhancement of both the strength and FCP resistance of Al composite was achieved through the development of heterostructures. During FCP, the PRZs can retard the growth of slip bands and increase crack deflection frequency while the PLZs increase the crack deflection distance and plastic deformation capability at crack tip. The fracture behavior of composite during FCP depended on grain characteristics, particles and stress intensity range. The detailed cracking behavior for typical <100>Al and <111>Al grains in different FCP stages was identified. The associated models were developed for different FCP behaviors. Particularly, the quantitative relationship between Pairs parameters and microstructure features was established, which was critical to understand fatigue properties of Al composite reinforced by small particles. These findings can provide a strategy to design metal materials with an excellent combination of both static and dynamic mechanical properties.
在铝(Al)基材料中很难同时实现高抗拉强度和低疲劳裂纹扩展(FCP)率,这一直是一个持久的话题。这是因为传统的强化机制可能会导致 FCP 率的增加。在这项工作中,我们将原位合成的 TiB2 粒子加入铝基体中,通过挤压形成粒子稀疏区 (PLZ) 和粒子富集区 (PRZ),从而开发出双层异质结构。在 PRZ 中,通过与颗粒相关的局部再结晶引入了细晶粒。通过颗粒和晶粒尺寸分布,制备出了一种异质结构的铝复合材料,其特点是 PLZ 中为粗颗粒,PRZ 中为细颗粒。研究发现,通过发展异质结构,铝复合材料的强度和抗 FCP 能力同时得到了提高。在 FCP 过程中,PRZs 可延缓滑移带的生长并增加裂纹偏转频率,而 PLZs 则可增加裂纹偏转距离和裂纹尖端的塑性变形能力。复合材料在 FCP 期间的断裂行为取决于晶粒特征、颗粒和应力强度范围。确定了典型的 <100>Al 和 <111>Al 晶粒在不同 FCP 阶段的详细开裂行为。针对不同的 FCP 行为建立了相关模型。特别是,建立了配对参数与微结构特征之间的定量关系,这对于理解小颗粒增强的铝复合材料的疲劳特性至关重要。这些发现可为设计兼具静态和动态机械性能的金属材料提供策略。
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引用次数: 0
Achieving superior strength-ductility balance by tailoring dislocation density and shearable GP zone of extruded Al-Cu-Li alloy 通过调整挤压铝-铜-锂合金的位错密度和可剪切 GP 区,实现卓越的强度-电导率平衡
IF 9.4 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-09-17 DOI: 10.1016/j.ijplas.2024.104135
Pre-stretching is commonly employed to accelerate ageing precipitation kinetics in wrought Al-Cu-Li alloys, but uneven precipitation resulting from dislocation pile-ups often degrades ductility. Herein, the strength and ductility of extruded Al-Cu-Li alloy are significantly improved through a novel thermomechanical treatment, involving pre-ageing and pre-stretching, followed by low-temperature interrupted ageing. A superior balance between high yield strength (∼ 657 MPa) and good ductility (elongation to fracture of ∼ 13.5 %) is obtained, with elongation increased by 105 % compared to the conventional T8 temper, while maintaining a respectable yield strength. Microstructure analysis reveals that dense Guinier–Preston (GP) zones induced by pre-ageing effectively dissipate energy from dislocation sliding, resulting in a uniform dislocation configuration even at 8 % pre-stretching. However, the GP zone density is greatly reduced due to their dissolution following pre-stretching. Upon interrupted ageing, the reprecipitation of GP zones forms a homogeneous mixture of δ′, GP zones, and T1 phases. This combination alleviates local stress concentrations and lengthens the dislocation mean free path during tensile testing by shearing the GP zones at multiple sites, thereby improving ductility. Simultaneously, T1 precipitates strengthen the alloy by pinning dislocations and promoting dislocation cross-slip, improving work hardening capacity. The dissolution of GP zones also redistributes the Cu atoms within the matrix, further enhancing the intrinsic ductility of the Al matrix. These findings offer valuable insights for developing high-performance wrought Al-Cu-Li alloys.
预拉伸通常用于加速锻造铝-铜-锂合金的时效析出动力学,但位错堆积导致的不均匀析出往往会降低延展性。在本文中,挤压铝-铜-锂合金的强度和延展性通过一种新的热机械处理方法得到了显著改善,包括预时效和预拉伸,然后是低温间断时效。在高屈服强度(657 兆帕)和良好延展性(断裂伸长率为 13.5%)之间取得了极佳的平衡,与传统的 T8 回火相比,在保持可观的屈服强度的同时,伸长率提高了 105%。显微结构分析表明,预时效诱导的致密吉尼耶-普雷斯顿(GP)区可有效消散位错滑动产生的能量,即使在 8% 预拉伸时也能形成均匀的位错配置。然而,由于预拉伸后 GP 区的溶解,其密度大大降低。间断时效后,GP 区的再沉淀形成了δ′、GP 区和 T1 相的均匀混合物。在拉伸测试过程中,这种组合通过在多个位置剪切 GP 区,缓解了局部应力集中,延长了位错的平均自由路径,从而提高了延展性。同时,T1析出物通过钉住位错和促进位错交叉滑移来强化合金,从而提高加工硬化能力。GP 区的溶解还重新分配了基体中的铜原子,进一步增强了铝基体的内在延展性。这些发现为开发高性能锻造铝-铜-锂合金提供了宝贵的见解。
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引用次数: 0
Crack-tip cleavage/dislocation emission competition behaviors/mechanisms in magnesium: ALEFM prediction and atomic simulation 镁的裂纹尖端裂解/错位发射竞争行为/机制:ALEFM 预测和原子模拟
IF 9.4 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-09-16 DOI: 10.1016/j.ijplas.2024.104134
Structural properties and reliability of materials can be improved by increasing fracture toughness. At the atomic scale, the fracture is a material separation process, and the fracture toughness of materials is associated with the atomic-scale crack-tip behaviors/mechanisms. The crack-tip behaviors are relevant to the energy state of atoms in the system. Atomic thermal oscillation increases with increasing temperature, which may affect/alter the crack tip behaviors. This work is the first to investigate the temperature-dependent crack-tip cleavage/dislocation emitting competition in magnesium (Mg) using anisotropic linear elastic fracture mechanics theory, Density Functional Theory (DFT), and atomic simulation. Crack-tip behaviors are examined using a specially designed ‘K-field’ loads model. DFT calculations show that a single crystal system with lower entropy and higher Gibbs free energy implies stronger interatomic bonding that favors a higher KIc. Changes in the stress distribution initiate a brittle-ductile transition in crack-tip behavior. The ductile crack tip can be blunted by continuous crack-tip dislocations nucleation/slip, and the evolution of the ductile crack-tip geometry from sharp to semicircular structure significantly decreases the stress concentration at the crack tip. A new criterion of the crack-tip force vector is established, which reasonably explains the geometrical evolution of ductile crack tip where the angle θ between the crack plane and the slip plane is 0<θ<90 and θ=90. This work expands the atomic-scale brittle/ductile crack-tip behaviors/mechanisms of Mg, which provides a reference for crack-tip behavior analysis in engineering research.
通过提高断裂韧性可以改善材料的结构特性和可靠性。在原子尺度上,断裂是一种材料分离过程,材料的断裂韧性与原子尺度的裂纹尖端行为/机制有关。裂纹尖端行为与系统中原子的能量状态有关。原子热振荡随温度升高而增加,这可能会影响/改变裂纹尖端行为。本研究首次使用各向异性线性弹性断裂力学理论、密度泛函理论(DFT)和原子模拟研究了镁 (Mg) 中与温度相关的裂纹尖端裂解/位错发射竞争。利用专门设计的 "K-场 "载荷模型对裂纹尖端行为进行了研究。密度泛函理论计算表明,单晶体系统具有较低的熵和较高的吉布斯自由能,这意味着较强的原子间键合有利于较高的 KIc。应力分布的变化引发了裂纹尖端行为的脆性-韧性转变。韧性裂纹尖端可通过连续的裂纹尖端位错成核/滑移而变钝,韧性裂纹尖端的几何形状从尖锐结构演变为半圆形结构可显著降低裂纹尖端的应力集中。建立了一种新的裂纹尖端力矢量准则,合理解释了裂纹平面与滑移平面夹角θ为0∘<θ<90∘和θ=90∘时韧性裂纹尖端的几何演变。这项工作拓展了镁的原子尺度脆性/韧性裂纹尖端行为/机理,为工程研究中的裂纹尖端行为分析提供了参考。
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引用次数: 0
Dislocation accumulation-induced strength-ductility synergy in TRIP-aided duplex stainless steel TRIP 辅助双相不锈钢中位错累积诱导的强度-电导率协同作用
IF 9.4 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-09-12 DOI: 10.1016/j.ijplas.2024.104130

In this study, we investigate the intrinsic mechanism of intensive and progressive transformation-induced plasticity (TRIP) effects and their different strength-ductility synergies using a resource-efficient 15Cr-2Ni duplex stainless steel. The progressive TRIP material exhibits a ductility that is more than twice that of the intensive TRIP material, as well as, a larger product of the ultimate tensile strength and ductility. This is attributed to the dislocation accumulation caused by different grain sizes of strain-induced martensite depending on the stability of the γ phase, which determines the strength and work hardening of steel. When the stability is low, the γ phase is sensitive to loaded stress and transformed into dispersed fine martensite immediately after yielding at a high rate. It induces a sigmoid-shaped dislocation accumulation to an approximately 10-fold increase in the dislocation density at a limited strain, resulting in intensive work hardening and a large ultimate tensile strength. As the stability is adequate, the γ phase is transformed into coarse martensite laths with a high critical load stress, which is initiated from a delayed strain at an extremely low rate and steadily accelerated as the strain increases. This process induces a gradually increased dislocation accumulation to a 2–3-fold increase in the dislocation density at large strains, resulting in progressive work hardening and an excellent ductility.

在本研究中,我们使用一种资源节约型 15Cr-2Ni 双相不锈钢研究了强化和渐进转化诱导塑性(TRIP)效应的内在机制及其不同的强度-延展性协同作用。渐进转化诱导塑性材料的延展性是强化转化诱导塑性材料的两倍多,极限抗拉强度和延展性的乘积也更大。这归因于应变诱导马氏体的晶粒大小不同所导致的位错堆积,这取决于相的稳定性,而相的稳定性决定了钢的强度和加工硬化。当稳定性较低时,该相对加载应力敏感,并在屈服后立即以较高的速度转变为分散的细马氏体。在有限的应变下,它诱导了一个半圆形的位错堆积,使位错密度增加了约 10 倍,从而产生了强烈的加工硬化和较大的极限抗拉强度。当稳定性足够高时,该相转变为具有高临界载荷应力的粗大马氏体板条,它以极低的速率从延迟应变开始,并随着应变的增加而稳步加速。在这一过程中,位错积累逐渐增加,到大应变时,位错密度增加 2-3 倍,从而导致逐步加工硬化和优异的延展性。
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引用次数: 0
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International Journal of Plasticity
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