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A three-dimensional shear transformation zone theory for glassy polymers 玻璃聚合物的三维剪切转变区理论
IF 9.8 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2026-01-31 DOI: 10.1016/j.ijplas.2026.104628
Ji Lin, Wuyang Zhao, Rui Xiao
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引用次数: 0
Investigating Creep Damage Initiation at the Mesoscale Using High-Resolution Electron Microscopy, Crystal Plasticity Modelling, and a Classification Algorithm 利用高分辨率电子显微镜、晶体塑性模型和分类算法研究中尺度蠕变损伤的发生
IF 9.8 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2026-01-29 DOI: 10.1016/j.ijplas.2026.104627
Farhan Ashraf, Nicolò Grilli, Chen Liu, Michael Salvini, Catrin M. Davies, Christopher E. Truman, Mahmoud Mostafavi, David Knowles
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引用次数: 0
Size-Dependent Tensile Behavior of Nanocrystalline HfNbTaTiZr High-Entropy Alloy: Roles of Solid-Solution and Local Chemical Order 纳米晶HfNbTaTiZr高熵合金的尺寸相关拉伸行为:固溶和局部化学秩序的作用
IF 9.8 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2026-01-28 DOI: 10.1016/j.ijplas.2026.104626
Yihan Wu, Gaosheng Yan, Pengfei Yu, Yaohong Suo, Wenshan Yu, Shengping Shen
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引用次数: 0
Adiabatic shear instability mechanisms in BCC TiHfZrTaNb high entropy alloy: insights from microscale experiments and simulations BCC TiHfZrTaNb高熵合金的绝热剪切失稳机制:来自微尺度实验和模拟的见解
IF 9.8 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2026-01-28 DOI: 10.1016/j.ijplas.2026.104625
Jianguo Li, Tianqi Zhou, Xinjie Yang, Zhongbin Tang, Tao Suo
Refractory high-entropy alloys (RHEAs) hold great promise for impact engineering due to their superior dynamic mechanical properties. However, the limited understanding of the adiabatic shear instability mechanism in these alloys restricts their effective design and application for enhanced impact performance. This study provides a comprehensive investigation into the mechanical responses of near-equiatomic TiZrHfNbTa RHEA across a wide range of temperature and strain rate. Upon impact compression to substantial strains, adiabatic shear bands (ASBs) emerge as the predominant failure mode. Utilizing an in situ high-speed “force-heat-deformation” synchronous testing system based on the split Hopkinson pressure bar, we have meticulously characterized the initiation and propagation of ASBs. Our work clearly elucidates the pronounced adiabatic temperature rise associated with localized shear deformation. Moreover, through quasi-in situ microstructural evolution analysis, we have delineated the microscopic evolution wherein local deformation sites expand and interconnect along the most deformable grains, ultimately leading to the formation of through-shear zones. Additionally, we have uncovered the micro-mechanism by which dynamic recrystallization (DRX) within these shear zones induces plastic instability. To quantitatively decouple the specific contributions of thermal softening and dynamic recrystallization softening to dynamic instability, we have developed a crystal plasticity mechanical constitutive model to accurately capture the mechanical responses of the RHEA by incorporating the influence of dynamic recrystallization evolution. Our findings highlight the crucial role of DRX softening in driving local shear instability in the RHEA. By combining full-process microcharacterization with mesoscale crystal plasticity finite element simulations, this work offers a precise analysis of the formation mechanism underlying the dynamic instability in BCC RHEA. This research is expected to provide a robust theoretical foundation for the future design of advanced metallic materials with enhanced impact performance.
耐火高熵合金以其优异的动态力学性能在冲击工程中具有广阔的应用前景。然而,对这些合金的绝热剪切失稳机制的认识有限,限制了它们的有效设计和应用,以提高冲击性能。本研究对近等原子TiZrHfNbTa RHEA在大范围温度和应变速率下的力学响应进行了全面研究。当冲击压缩到大应变时,绝热剪切带(ASBs)成为主要的破坏模式。利用基于Hopkinson压杆的原位高速“力-热变形”同步测试系统,对asb的萌生和扩展进行了细致的表征。我们的工作清楚地阐明了与局部剪切变形相关的显著绝热温升。此外,通过准原位显微组织演化分析,我们描绘了微观演化过程,其中局部变形点沿着最易变形的晶粒扩展并相互连接,最终导致穿过剪切带的形成。此外,我们还揭示了这些剪切区域内动态再结晶(DRX)引起塑性不稳定的微观机制。为了定量解耦热软化和动态再结晶软化对动态失稳的具体贡献,我们建立了一个晶体塑性力学本构模型,通过纳入动态再结晶演变的影响来准确捕捉RHEA的力学响应。我们的研究结果强调了DRX软化在驱动RHEA局部剪切不稳定中的关键作用。通过将全过程微表征与中尺度晶体塑性有限元模拟相结合,本研究对BCC RHEA动态不稳定性的形成机制进行了精确分析。该研究有望为未来设计具有增强冲击性能的先进金属材料提供坚实的理论基础。
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引用次数: 0
Obtaining superior strength-ductility synergy properties in a medium-entropy alloy via dual heterogeneous and TRIP effects 通过双异质效应和TRIP效应在中熵合金中获得优异的强度-塑性协同性能
IF 12.8 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2026-01-23 DOI: 10.1016/j.ijplas.2026.104624
Wenjie Lu , Bin Huang , Rui Hu , Xu-Sheng Yang
Activating additional strain-hardening mechanisms is essential to achieve superior strain hardening capacity and strength-ductility synergy in precipitation-hardened alloys. In this work, we introduce a synergistic strategy that combines dual-heterogeneous structures (DHS) with the transformation-induced plasticity (TRIP) effect in a precipitation-hardened medium-entropy alloy (MEA), thereby enabling multiple strain-hardening mechanisms for the exceptional strength-ductility combination. The tailored alloy showcases a high yield strength of ∼ 1290 MPa, an ultimate tensile strength of ∼ 1737 MPa, and an excellent fracture elongation of ∼ 36.9% at ambient temperature, exhibiting a ∼ 162% increase in yield strength without compromising uniform ductility, compared to its single-phase solid solution counterpart. Microstructural analyses reveal that the enhanced yield strength stems primarily from precipitation hardening and extra hetero-deformation induced (HDI) hardening. Furthermore, plastic deformation mechanism investigations demonstrate that the remarkable work-hardening capacity (> 3 GPa) results from the combined effects of dynamically enhanced HDI hardening and the activated TRIP effect during tensile deformation. These multiple and sustained strain-hardening mechanisms underpin the alloy’s exceptional strength-ductility synergy. Our study provides a promising strategy for designing high-performance structural materials.
激活额外的应变硬化机制对于在析出硬化合金中获得优异的应变硬化能力和强度-塑性协同作用是必不可少的。在这项工作中,我们引入了一种协同策略,将沉淀硬化中熵合金(MEA)的双异相组织(DHS)与转化诱导塑性(TRIP)效应结合起来,从而实现了多种应变硬化机制,实现了卓越的强度-塑性组合。定制合金的屈服强度为~ 1290 MPa,极限抗拉强度为~ 1737 MPa,在室温下的断裂伸长率为~ 36.9%,与单相固溶体相比,屈服强度增加了~ 162%,而不影响均匀延展性。显微组织分析表明,屈服强度的提高主要源于沉淀硬化和超异质变形诱导(HDI)硬化。此外,塑性变形机制研究表明,显著的加工硬化能力(> 3gpa)是拉伸变形过程中动态增强的HDI硬化和激活的TRIP效应共同作用的结果。这些多重和持续的应变硬化机制巩固了合金的卓越的强度和延展性协同作用。我们的研究为高性能结构材料的设计提供了一种有前途的策略。
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引用次数: 0
A data-driven elastoplastic super element method for multiscale modeling of history-dependent responses in metamaterials 数据驱动的超塑性弹塑性超单元法在超材料中历史相关响应的多尺度建模
IF 12.8 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2026-01-21 DOI: 10.1016/j.ijplas.2026.104623
Yongzhen Wang , Shengyu Duan , Chunwang He , Ying Li , Qinglei Zeng , Daining Fang
Mechanical metamaterials have attracted considerable attention due to their exceptional mechanical properties, making them promising candidates for advanced structural applications. However, accurate and efficient prediction of the history-dependent, nonlinear mechanical behavior of elastoplastic metamaterial structures remains challenging. In this work, we propose a data-driven elastoplastic super element (DD-EPSE) framework to model the elastoplastic response of metamaterials. Unlike traditional representative volume element (RVE)-based homogenization that relies on scale separation and equivalent stress-strain relationships, DD-EPSE treats each unit cell as a structural element governed by force-displacement relationships at control points, with nodal forces serving as internal variables. After eliminating rigid-body motions, the incremental force-displacement response is captured by a specially designed artificial neural network framework, which enforces objectivity and equilibrium. A support vector machine (SVM) classifier is incorporated to identify plastic zones within metastructures. The method is validated through extensive numerical simulations and experiments on triply periodic minimal surface (TPMS)-based metamaterials under diverse loading conditions. Results demonstrate that DD-EPSE accurately predicts the force-displacement response and plasticity distribution of large-scale metastructures, while reducing computational cost by several orders of magnitude compared to direct numerical simulations. In addition, its applicability to other metamaterial topologies is validated through transfer learning, exemplified by beam-lattice structures. The DD-EPSE framework provides an efficient tool for modeling and designing of mechanical metamaterials with history-dependent nonlinear behavior.
机械超材料由于其优异的机械性能而引起了人们的广泛关注,使其成为先进结构应用的有希望的候选者。然而,准确和有效地预测弹塑性超材料结构的历史依赖的非线性力学行为仍然具有挑战性。在这项工作中,我们提出了一个数据驱动的弹塑性超单元(DD-EPSE)框架来模拟超材料的弹塑性响应。与传统的基于代表性体积单元(RVE)的均质化(依赖于尺度分离和等效应力-应变关系)不同,DD-EPSE将每个单元单元视为由控制点上的力-位移关系控制的结构单元,节点力作为内部变量。在消除刚体运动后,通过特别设计的人工神经网络框架捕获增量力-位移响应,从而实现客观性和平衡性。采用支持向量机(SVM)分类器识别元结构中的塑性区。通过对三周期最小表面(TPMS)基超材料在不同载荷条件下的大量数值模拟和实验验证了该方法的有效性。结果表明,DD-EPSE能够准确预测大尺度元结构的力-位移响应和塑性分布,与直接数值模拟相比,计算成本降低了几个数量级。此外,通过迁移学习验证了其对其他超材料拓扑的适用性,例如梁晶格结构。DD-EPSE框架为具有历史相关非线性行为的机械超材料的建模和设计提供了一种有效的工具。
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引用次数: 0
Tailoring lightweight refractory high-entropy alloys via Y2O3 additions: Achieving >1.3 GPa yield strength with retained ductility 通过添加Y2O3定制轻质耐火高熵合金:在保持延展性的同时获得>1.3 GPa屈服强度
IF 12.8 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2026-01-21 DOI: 10.1016/j.ijplas.2026.104622
Yongmiao Liu, Yusheng Wang, Mingliang Wang, Yiping Lu
Refractory high-entropy alloys (RHEAs) demonstrate exceptional resistance to softening at elevated temperatures, positioning them as leading candidates for high-temperature structural applications. Nevertheless, state-of-the-art RHEAs still exhibit elevated density and inherent room-temperature brittleness, thereby constraining their industrial deployment. This study systematically investigates a lightweight Ti55Zr10V15Nb10Al10 refractory high-entropy alloy (RHEA) (ρ ≈ 5.3 g/cm³) strengthened with Y2O3 nanoparticles. The alloy achieves an exceptional yield strength of ∼1370 MPa alongside a tensile ductility of ∼15% (with ∼7% uniform elongation), significantly surpassing both its base alloy and most reported RHEAs. This superior strength–ductility synergy originates from semi-coherent Y2O3/BCC interfaces, which provide effective Orowan strengthening while promoting extensive activation of multi-slip deformation dominated by non-screw dislocations. This atypical deformation mode sustains strain hardening and retains ductility in the BCC matrix.This work demonstrates that the introduction of coherent ceramic nanoparticles is a potent strategy to bypass the strength-ductility trade-off in RHEAs.
耐火高熵合金(RHEAs)在高温下表现出优异的抗软化性,使其成为高温结构应用的主要候选材料。然而,最先进的RHEAs仍然表现出较高的密度和固有的室温脆性,从而限制了它们的工业部署。本研究系统地研究了Y2O3纳米颗粒增强的轻质Ti55Zr10V15Nb10Al10耐火高熵合金(RHEA) (ρ≈5.3 g/cm³)。该合金的屈服强度为~ 1370 MPa,拉伸延展性为~ 15%(均匀伸长率为~ 7%),大大超过了其基础合金和大多数报道的RHEAs。这种优异的强度-延性协同作用源于半相干的Y2O3/BCC界面,它提供了有效的Orowan强化,同时促进了由非螺位错主导的多滑移变形的广泛激活。这种非典型变形模式维持了BCC基体的应变硬化并保持了延性。这项工作表明,引入相干陶瓷纳米颗粒是一种有效的策略,可以绕过RHEAs的强度-延性权衡。
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引用次数: 0
Topological defect analysis and phase field study of disclination-assisted twin-grain boundary reactions in HCP-Ti polycrystals HCP-Ti多晶中斜向辅助双晶界反应的拓扑缺陷分析及相场研究
IF 12.8 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2026-01-20 DOI: 10.1016/j.ijplas.2026.104621
Haipeng Li , Yipeng Gao , Yizhen Li , Tao Yu , Chunfeng Du , Yongsi Wei , Yuchao Song , Hui-Yuan Wang
The mechanical behavior of polycrystalline metals is profoundly influenced by the interaction between deformation twins and grain boundaries (GBs), which concurrently induces strengthening and accommodates plastic strain. Particularly in hexagonal close-packed metals, the coexistence and competition of multiple twinning modes at diverse GBs can lead to interface/junction incompatibilities through complex defect reactions. These incompatibilities, mediated by the formation of dislocations and disclinations, result in local stress concentrations that govern subsequent hardening and damage phenomena. However, a theoretical framework for quantitatively determining the stress fields resulting from all types of twin-GB reactions remains underdeveloped. Here, we bridge this gap by integrating topological defect analysis with phase-field simulations to establish a general approach for calculating the defect structures and internal stresses arising from twin-GB reactions. Taking α-Ti as a representative case, we systematically analyze the distributions of dislocations, disclinations, and local stresses across a broad range of twin-GB reactions. Our analysis reveals that twin transmission—a key accommodation mechanism—is governed by the minimization of residual defects and the associated stress concentration from twin-GB reactions. This principle is validated by our phase-field simulations and electron backscatter diffraction characterizations. This work establishes a quantitative, mechanism-based framework for predicting local stress concentrations and plastic accommodation in polycrystalline materials, providing fundamental insights into the role of twin-GB interactions in the macroscopic mechanical response.
变形孪晶与晶界之间的相互作用对多晶金属的力学行为有着深刻的影响,这种相互作用同时诱导强化和容纳塑性应变。特别是在六方密排金属中,多种孪生模式在不同gb上的共存和竞争会通过复杂的缺陷反应导致界面/结不相容。这些不相容,由位错和斜向的形成介导,导致局部应力集中,控制随后的硬化和损伤现象。然而,定量确定所有类型双gb反应产生的应力场的理论框架仍然不发达。在这里,我们通过将拓扑缺陷分析与相场模拟相结合来弥补这一差距,建立了一种计算双gb反应引起的缺陷结构和内应力的通用方法。以α-Ti为代表,系统分析了大范围双gb反应中位错、斜位和局部应力的分布。我们的分析表明,孪晶传递——一种关键的调节机制——是由孪晶反应中残余缺陷的最小化和相关应力集中所控制的。我们的相场模拟和电子背散射衍射表征验证了这一原理。这项工作建立了一个定量的、基于机制的框架,用于预测多晶材料中的局部应力集中和塑性调节,为双gb相互作用在宏观力学响应中的作用提供了基本的见解。
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引用次数: 0
Abnormal twinning mechanisms and martensitic transformation in Fe60Mn12Cr12Ni8Si8 high entropy alloy under cyclic tension-compression loading 循环拉压载荷下Fe60Mn12Cr12Ni8Si8高熵合金的异常孪晶机制及马氏体相变
IF 12.8 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2026-01-15 DOI: 10.1016/j.ijplas.2026.104613
Lin Guo , Jiaxing Wu , Ji Gu , Dechuang Zhang , Cheng Ma , Yilong Dai , Jianguo Lin , Ian Baker , Min Song
Twinning and martensitic transformations are well-understood under monotonic loading, yet how stress reversal and the associated kinematic reversibility, inherent to cyclic deformation, affects these mechanisms remains insufficiently understood. Here, we systematically investigate the microstructural evolution of a metastable high entropy alloy Fe60Mn12Cr12Ni8Si8 under cyclic tension-compression (CTC) loading. Multi-scale characterizations reveal that the cyclic stress reversal fundamentally alters the transformation pathway compared to the monotonic tension. The initial, undeformed material consists of a face-centered cubic γ phase. Monotonic tension primarily activates deformation-induced martensitic transformation, whereas CTC produces markedly different microstructural pathways depending on strain amplitude. At a low strain amplitude (0.5%), short-range glide of Shockley partial dislocations promotes extensive formation of HCP ε-martensite (a fraction of ∼68.3%). In contrast, high-strain-amplitude CTC loading (2.0%) activates an abnormal transformation-mediated twinning mechanism. This process, driven by the reversible motion of Shockley partial dislocation within confined ε-martensite, leads to a refined γ/γtwin/ε nano-laminate structure with a spacing of ∼2.6 nm. Furthermore, we identify unconventional polymorphic transformation pathways accommodating the high local stress concentrations: (i) nucleation of body-centered cubic α′-martensite at a specific interface where the two γ phases maintain an 86° angle between their respective (111¯)γ planes, and (ii) a direct γ to body-centered tetragonal α-martensite transition via continuous lattice shearing along (111)[112¯]γ. These mechanisms are attributed to the unique stress accommodation requirements in the highly confined nano-laminates. The resulting hierarchical microstructure not only relieves local stress concentrations but also contributes to the good cyclic durability. Overall, these findings establish an atomistic mechanistic link between cyclic reversibility and transformation/twinning pathway selection, and suggest a processing-enabled route to engineer heterogeneous γ/γtwin/ε nano-laminate structure in bulk metastable alloys at room temperature.
孪晶和马氏体相变在单调载荷下已经得到了很好的理解,但是应力逆转和相关的运动可逆性,固有的循环变形,如何影响这些机制仍然没有得到充分的了解。本文系统地研究了循环拉伸压缩(CTC)加载下亚稳态高熵合金Fe60Mn12Cr12Ni8Si8的显微组织演变。多尺度特征表明,与单调张力相比,循环应力反转从根本上改变了转变路径。初始的未变形材料由面心立方γ相组成。单调张力主要激活变形诱发的马氏体相变,而CTC则根据应变幅值产生明显不同的微观组织路径。在低应变幅度(0.5%)下,肖克利位错的短程滑动促进了HCP ε-马氏体的广泛形成(约68.3%)。相比之下,高应变幅CTC加载(2.0%)激活了异常转变介导的孪生机制。这一过程由受限ε-马氏体内的Shockley部分位错可逆运动驱动,形成了间距为~ 2.6 nm的细化γ/γ孪晶/ε纳米层状结构。此外,我们确定了适应高局部应力浓度的非常规多晶转变途径:(i)在特定界面上,两个γ相在各自的(111¯)γ(111¯)γ平面之间保持86°夹角,形成体心立方α′-马氏体成核;(ii)通过沿(111)[112¯]γ(111)[112¯]γ连续晶格剪切,直接γ向体心四边形α-马氏体转变。这些机制归因于高度受限的纳米层压板中独特的应力调节要求。由此产生的分层结构不仅缓解了局部应力集中,而且有助于良好的循环耐久性。总的来说,这些发现建立了循环可逆性和转变/孪晶途径选择之间的原子机制联系,并提出了在室温下设计块状亚稳合金非均相γ/γ孪晶/ε纳米层压结构的加工途径。
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引用次数: 0
Deformation behavior and microstructural evolution of Ti-6Al-4 V alloy under compression with confining pressure 围压作用下Ti-6Al-4V合金的变形行为及组织演变
IF 12.8 1区 材料科学 Q1 ENGINEERING, MECHANICAL Pub Date : 2026-01-15 DOI: 10.1016/j.ijplas.2026.104610
Yanxiong Liu , Han Zhang , Lin Hua , Feng Huang , Kaisheng Ji , Yizhe Chen , Junnan Mao
Ti-6Al-4 V alloys have attracted increasing attention as candidates to meet targets for lightweight applications in the automotive, aerospace and other industries. To improve the plastic deformation capacity and mechanical properties of deformed parts, this paper proposes a forming process under superimposed hydrostatic pressure. Ti-6Al-4 V alloys were subjected to compression under liquid at a pressure of 175 MPa, which caused superimposed hydrostatic pressure during the compression process. This study revealed the deformation behavior and microstructural evolution of Ti-6Al-4 V alloys under such loading conditions for the first time through experimental, simulation and theoretical analyses. Multiscale characterization (SEM/XRD/TEM) reveals that hydrostatic pressure induces activation of {101¯1} and {101¯2} α-twins to accommodate deformation, the formation of coherent α/β interfaces and a nonrandom V distribution in the α phase. In comparison to the normal-pressure compression sample, the ultimate compressive strength, hardness, and compression ratio were only 1229.9 MPa, 294.1 HV, and 35%, respectively. The high-pressure compression sample exhibits a superior combination of strength, as evidenced by its ultimate compressive strength (2004.9 MPa), hardness (364.8 HV), and plasticity (42.5% compression ratio). The synergy is attributed to three coupled mechanisms under high pressure: twinning-induced plasticity, interface strengthening and short-range ordering strengthening. Furthermore, theoretical geometrical phase analysis and crystal plasticity simulations reveal that high pressure decreases the stress in the α phase. The resulting significant improvement in both tensile and compressive strains can lead to the formation of a high density of twins. Concurrently, it has been demonstrated to increase the resistance of the β phase to stress, thereby preventing the β phase cracking that is frequently observed in normal pressure compression. These results provide a promising pathway for overcoming the severe engineering challenges caused by the low room-temperature plasticity of Ti-6Al-4 V alloys.
ti - 6al - 4v合金作为满足汽车、航空航天和其他行业轻量化应用目标的候选材料,引起了越来越多的关注。为了提高变形件的塑性变形能力和力学性能,提出了一种叠加静水压力成形工艺。ti - 6al - 4v合金在175 MPa的液体压力下进行压缩,压缩过程中产生了叠加的静水压力。本研究通过实验、模拟和理论分析,首次揭示了ti - 6al - 4v合金在这种载荷条件下的变形行为和显微组织演变。多尺度表征(SEM/XRD/TEM)表明,静水压力诱导{101¯1}和{101¯2}α-孪晶活化,以适应变形,形成相干α/β界面和α相的非随机V分布。与常压压缩试样相比,其极限抗压强度仅为1229.9 MPa,硬度仅为294.1 HV,压缩比仅为35%。高压压缩试样的极限抗压强度(2004.9 MPa)、硬度(364.8 HV)和塑性(42.5%压缩比)均表现出优异的强度组合。高压作用下的协同作用是由三种耦合机制引起的:孪生诱导塑性、界面强化和短程有序强化。此外,理论几何相分析和晶体塑性模拟表明,高压降低了α相的应力。由此产生的拉伸和压缩应变的显著改善可以导致高密度孪晶的形成。同时,它已被证明可以增加β相对应力的抵抗力,从而防止在常压压缩中经常观察到的β相开裂。这些结果为克服ti - 6al - 4v合金的低室温塑性带来的严峻工程挑战提供了一条有希望的途径。
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引用次数: 0
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