Environmental Science and Ecotechnology最新文献

Advanced oxidation processes (AOPs) utilizing persulfate (PS) offer great potential for wastewater treatment. Yet, the dependency on energy and chemical-intensive activation techniques, such as ultraviolet radiation and transition metal ions, constrains their widespread adoption. Recognizing this limitation, researchers are turning towards the piezoelectric effect—a novel, energy-efficient method for PS activation that capitalizes on the innate piezoelectric characteristics of materials. Intriguingly, this method taps into weak renewable mechanical forces omnipresent in nature, ranging from wind, tides, water flow, sound, and atmospheric forces. In this perspective, we delve into the burgeoning realm of piezoelectric/PS-AOPs, elucidating its fundamental principles, the refinement of piezoelectric materials, potential mechanical force sources, and pertinent application contexts. This emerging technology harbors significant potential as a pivotal element in wastewater pretreatment and may spearhead innovations in future water pollution control engineering.

Increasing energy demands and environmental pollution concerns press for sustainable and environmentally friendly technologies. Soil microbial fuel cell (SMFC) technology has great potential for carbon-neutral bioenergy generation and self-powered electrochemical bioremediation. In this study, an in-depth assessment on the effect of several carbon-based cathode materials on the electrochemical performance of SMFCs is provided for the first time. An innovative carbon nanofibers electrode doped with Fe (CNFFe) is used as cathode material in membrane-less SMFCs, and the performance of the resulting device is compared with SMFCs implementing either Pt-doped carbon cloth (PtC), carbon cloth, or graphite felt (GF) as the cathode. Electrochemical analyses are integrated with microbial analyses to assess the impact on both electrogenesis and microbial composition of the anodic and cathodic biofilm. The results show that CNFFe and PtC generate very stable performances, with a peak power density (with respect to the cathode geometric area) of 25.5 and 30.4 mW m⁻², respectively. The best electrochemical performance was obtained with GF, with a peak power density of 87.3 mW m⁻². Taxonomic profiling of the microbial communities revealed differences between anodic and cathodic communities. The anodes were predominantly enriched with Geobacter and Pseudomonas species, while cathodic communities were dominated by hydrogen-producing and hydrogenotrophic bacteria, indicating H₂ cycling as a possible electron transfer mechanism. The presence of nitrate-reducing bacteria, combined with the results of cyclic voltammograms, suggests microbial nitrate reduction occurred on GF cathodes. The results of this study can contribute to the development of effective SMFC design strategies for field implementation.

Seasonal or permanent water scarcity in off-grid communities can be alleviated by recycling water in decentralized wastewater treatment systems. Nature-based solutions, such as constructed wetlands (CWs), have become popular solutions for sanitation in remote locations. Although typical CWs can efficiently remove solids and organics to meet water reuse standards, polishing remains necessary for other parameters, such as pathogens, nutrients, and recalcitrant pollutants. Different CW designs and CWs coupled with electrochemical technologies have been proposed to improve treatment efficiency. Electrochemical systems (ECs) have been either implemented within the CW bed (ECin-CW) or as a stage in a sequential treatment (CW + EC). A large body of literature has focused on ECin-CW, and multiple scaled-up systems have recently been successfully implemented, primarily to remove recalcitrant organics. Conversely, only a few reports have explored the opportunity to polish CW effluents in a downstream electrochemical module for the electro-oxidation of micropollutants or electro-disinfection of pathogens to meet more stringent water reuse standards. This paper aims to critically review the opportunities, challenges, and future research directions of the different couplings of CW with EC as a decentralized technology for water treatment and recovery.

The industrial adoption of microbial electrosynthesis (MES) is hindered by high overpotentials deriving from low electrolyte conductivity and inefficient cell designs. In this study, a mixed microbial consortium originating from an anaerobic digester operated under saline conditions (∼13 g L⁻¹ NaCl) was adapted for acetate production from bicarbonate in galvanostatic (0.25 mA cm⁻²) H-type cells at 5, 10, 15, or 20 g L⁻¹ NaCl concentration. The acetogenic communities were successfully enriched only at 5 and 10 g L⁻¹ NaCl, revealing an inhibitory threshold of about 6 g L⁻¹ Na⁺. The enriched planktonic communities were then used as inoculum for 3D printed, three-chamber cells equipped with a gas diffusion biocathode. The cells were fed with CO₂ gas and operated galvanostatically (0.25 or 1.00 mA cm⁻²). The highest production rate of 55.4 g m⁻² d⁻¹ (0.89 g L⁻¹ d⁻¹), with 82.4% Coulombic efficiency, was obtained at 5 g L⁻¹ NaCl concentration and 1 mA cm⁻² applied current, achieving an average acetate production of 44.7 kg MWh⁻¹. Scanning electron microscopy and 16S rRNA sequencing analysis confirmed the formation of a cathodic biofilm dominated by Acetobacterium sp. Finally, three 3D printed cells were hydraulically connected in series to simulate an MES stack, achieving three-fold production rates than with the single cell at 0.25 mA cm⁻². This confirms that three-chamber MES cells are an efficient and scalable technology for CO₂ bio-electro recycling to acetate and that moderate saline conditions (5 g L⁻¹ NaCl) can help reduce their power demand while preserving the activity of acetogens.

Microplastics (MPs), an emerging group of pollutants, not only have direct toxic effects on aquatic organisms but also cause combined toxicity by absorbing other pollutants. Triphenyltin (TPT), one of the most widely used organotin compounds, has adverse effects on aquatic organisms. However, little is known about the combined toxicity of MPs and TPT to aquatic organisms. To investigate the individual and combined toxicity of MPs and TPT, we selected the common carp (Cyprinus carpio) for a 42-day exposure experiment. Based on the environmental concentrations in a heavily polluted area, the experimental concentrations of MPs and TPT were set at 0.5 mg L⁻¹ and 1 μg L⁻¹, respectively. The effects of MPs combined with TPT on the carp gut–brain axis were evaluated by detecting gut physiology and biochemical parameters, gut microbial 16S rRNA, and brain transcriptome sequencing. Our results suggest that a single TPT caused lipid metabolism disorder and a single MP induced immunosuppression in carp. When MPs were combined with TPT, the involvement of TPT amplified the immunotoxic effect induced by MPs. In this study, we also explored the gut–brain axis relationship of carp immunosuppression, providing new insights for assessing the combined toxicity of MPs and TPT. At the same time, our study provides a theoretical basis for evaluating the coexistence risk of MPs and TPT in the aquatic environment.

It is well recognized that carbon dioxide and air pollutants share similar emission sources so that synergetic policies on climate change mitigation and air pollution control can lead to remarkable co-benefits on greenhouse gas reduction, air quality improvement, and improved health. In the context of carbon peak, carbon neutrality, and clean air policies, this perspective tracks and analyzes the process of the synergetic governance of air pollution and climate change in China by developing and monitoring 18 indicators. The 18 indicators cover the following five aspects: air pollution and associated weather-climate conditions, progress in structural transition, sources, inks, and mitigation pathway of atmospheric composition, health impacts and benefits of coordinated control, and synergetic governance system and practices. By tracking the progress in each indicator, this perspective presents the major accomplishment of coordinated control, identifies the emerging challenges toward the synergetic governance, and provides policy recommendations for designing a synergetic roadmap of Carbon Neutrality and Clean Air for China.

To efficiently remove organic and inorganic pollutants from leachate concentrate, an in situ coagulation-electrochemical oxidation (CO-EO) system was proposed using Ti/Ti₄O₇ anode and Al cathode, coupling the “super-Faradaic” dissolution of Al. The system was evaluated in terms of the removal efficiencies of organics, nutrients, and metals, and the underlying cathodic mechanisms were investigated compared with the Ti/RuO₂–IrO₂ and graphite cathode systems. After a 3-h treatment, the Al-cathode system removed 89.0% of COD and 36.3% of total nitrogen (TN). The TN removal was primarily ascribed to the oxidation of both ammonia and organic-N to N₂. In comparison, the Al-cathode system achieved 3–10-fold total phosphorus (TP) (62.6%) and metal removals (>80%) than Ti/RuO₂–IrO₂ and graphite systems. The increased removals of TP and metals were ascribed to the in situ coagulation of Al(OH)₃, hydroxide precipitation, and electrodeposition. With the reduced scaling on the Al cathode surface, the formation of Al³⁺ and electrified Al(OH)₃ lessened the requirement for cathode cleaning and increased the bulk conductivity, resulting in increased instantaneous current production (38.9%) and operating cost efficiencies (48.3 kWh kg_COD⁻¹). The present study indicated that the in situ CO-EO process could be potentially used for treating persistent wastewater containing high levels of organic and inorganic ions.

Due to the accumulation of an enormous amount of plastic waste from municipal and industrial sources in landfills, landfill leachate is becoming a significant reservoir of microplastics. The release of microplastics from landfill leachate into the environment can have undesirable effects on humans and biota. This study provides the state of the science regarding the source, detection, occurrence, and remediation of microplastics in landfill leachate based on a comprehensive review of the scientific literature, mostly in the recent decade. Solid waste and wastewater treatment residue are the primary sources of microplastics in landfill leachate. Microplastic concentration in raw and treated landfill leachate varied between 0–382 and 0–2.7 items L⁻¹. Microplastics in raw landfill leachate are largely attributable to local plastic waste production and solid waste management practices. Polyethylene, polystyrene, and polypropylene are the most prevalent microplastic polymers in landfill leachate. Even though the colors of microplastics are primarily determined by their parent plastic waste, the predominance of light-colored microplastics in landfill leachate indicates long-term degradation. The identified morphologies of microplastics in leachate from all published sources contain fiber and fragments the most. Depending on the treatment method, leachate treatment processes can achieve microplastic removal rates between 3% and 100%. The review also provides unique perspectives on microplastics in landfill leachate in terms of remediation, final disposal, fate and transport among engineering systems, and source reduction, etc. The landfill–wastewater treatment plant loop and bioreactor landfills present unique difficulties and opportunities for managing microplastics induced by landfill leachate.