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Optimization of hybrid renewable energy systems: Reliability, cost, and environmental trade-offs using PSO and GJO algorithms 混合可再生能源系统的优化:使用PSO和GJO算法的可靠性、成本和环境权衡
IF 6.5 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-08 DOI: 10.1016/j.clet.2025.101131
Rawan Alsaqqar, Ahmad Abuelrub
Hybrid Renewable Energy Systems (HRES) provide a sustainable and reliable solution for electrification in remote regions while reducing dependence on fossil fuels and minimizing environmental impact. This study develops an integrated optimization framework for designing an HRES composed of photovoltaic generation, diesel backup, and hydrogen storage components. The framework employs the emerging Golden Jackal Optimization (GJO) algorithm and compares its performance with the established Particle Swarm Optimization (PSO) method used as a benchmark. The optimization minimizes the Total Net Present Cost (TNPC) while satisfying reliability and renewable energy portion (REP) constraints. Results show that GJO achieves slightly lower TNPC and improved convergence compared to PSO, demonstrating higher efficiency and robustness. Increasing REP from 0.1 to 0.9 enhances system sustainability by significantly reducing CO2 emissions, although it raises TNPC by 39 %. The proposed framework provides a practical and scalable approach for cost-reliable design of hydrogen-integrated hybrid energy systems supporting Jordan's renewable energy goals.
混合可再生能源系统(HRES)为偏远地区的电气化提供了可持续和可靠的解决方案,同时减少了对化石燃料的依赖,并最大限度地减少了对环境的影响。本研究开发了一个集成优化框架,用于设计由光伏发电、柴油备用和储氢组件组成的HRES。该框架采用了新兴的Golden Jackal Optimization (GJO)算法,并将其性能与已有的Particle Swarm Optimization (PSO)方法进行了比较。该优化在满足可靠性和可再生能源部分(REP)约束的同时,使总净当前成本(TNPC)最小化。结果表明,与PSO相比,GJO的TNPC略低,收敛性有所提高,具有更高的效率和鲁棒性。将REP从0.1提高到0.9,通过显著减少二氧化碳排放来增强系统的可持续性,尽管这会使TNPC提高39%。提出的框架为氢集成混合能源系统的成本可靠设计提供了一种实用且可扩展的方法,支持约旦的可再生能源目标。
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引用次数: 0
The role of biodegradable plastics in a sustainable economy: Progress and challenges 可生物降解塑料在可持续经济中的作用:进展与挑战
IF 6.5 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-08 DOI: 10.1016/j.clet.2025.101129
Tina Kegl , Yee Van Fan , Lidija Čuček
The widespread use of plastics has resulted in significant environmental challenges, including pollution, landfill accumulation, and harm to ecosystems and human health. As concerns over plastic waste intensify, biodegradable plastics have emerged as promising alternatives that can decompose under specific conditions and contribute to a circular economy. This review examines how biodegradable plastics can help address these issues, beginning with the distinction between biodegradable polymers, which are long-chain molecules, and biodegradable plastics, which are end-use materials created by blending these polymers with additives and fillers. It explores common biodegradable polymers, their origins, production processes, and key physical and chemical properties. Further, the review covers both the compounding stage, in which polymers and additives are combined, and the subsequent product development and processing steps involved in manufacturing of biodegradable plastics. A criterion is proposed to assess and rank biodegradable plastics based on their biodegradability. The review also discusses applications and the sustainability of their value chains. Key challenges to widespread adoption, such as technological limitations, economic concerns, and environmental or health risks, are highlighted. Finally, the review stresses the importance of advancing biomass cultivation, polymer development, processing techniques, and degradation methods to unlock the full potential of biodegradable plastics. Overall, it emphasizes the need for continued innovation to promote sustainable materials and improve plastic waste management.
塑料的广泛使用导致了重大的环境挑战,包括污染、垃圾填埋场堆积以及对生态系统和人类健康的危害。随着人们对塑料垃圾的担忧加剧,可生物降解塑料已成为有希望的替代品,它们可以在特定条件下分解,并有助于循环经济。这篇综述探讨了生物可降解塑料如何帮助解决这些问题,从生物可降解聚合物和生物可降解塑料的区别开始,生物可降解聚合物是长链分子,生物可降解塑料是通过将这些聚合物与添加剂和填料混合而产生的最终用途材料。它探讨了常见的可生物降解聚合物,它们的起源,生产过程,以及关键的物理和化学性质。此外,该综述涵盖了复合阶段,其中聚合物和添加剂相结合,以及随后的产品开发和加工步骤,涉及到制造可生物降解塑料。提出了一种基于生物降解性对生物降解塑料进行评价和排序的标准。该评论还讨论了应用及其价值链的可持续性。强调了广泛采用的主要挑战,如技术限制、经济问题以及环境或健康风险。最后,综述强调了推进生物质培养、聚合物开发、加工技术和降解方法的重要性,以释放生物降解塑料的全部潜力。总体而言,它强调需要不断创新,以促进可持续材料和改善塑料废物管理。
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引用次数: 0
Design and development of a low-cost and energy-efficient container farm for leafy greens 设计和开发一个低成本和节能的绿叶蔬菜集装箱农场
IF 6.5 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-08 DOI: 10.1016/j.clet.2025.101135
Thomas Xiong , Guanzheng Chen , Wenyi Cai , Lingyan Zha , Guangliu Xu , Aojiang Wang , Yuan Wei , Xiangyue Lu , Shiwei Wei , Dayi Lai , Jingjin Zhang , Hua Bao
Plant Factories with Artificial Lighting (PFALs) are crucial for year-round, climate-resilient urban agriculture, addressing food security and sustainability challenges. However, the high construction costs and energy demands limit its wide application. In this work, we design and tested a low-cost and energy efficient container farm, through mobile racks with reflective materials, an adaptive environmental control system, and an IoT framework (RS485, Modbus RTU) for automated operation, costing $ 900 m−2 in terms of building area (at a construction cost of $ 12,500 for a 14.09 m2 of building area). This container farm achieves efficient use of light, heat, and water, while providing photoperiod-synchronized environmental control to support leafy greens cultivation. The measured yield over a 50-day trial produced 95 kg of Frillice lettuce across 15.56 m2 of cultivation area with an energy consumption of 43 kWh·day−1 (72 % LEDs, 14 % HVAC, 14 % other) and demonstrated 11.4 L·day−1 water recovery via HVAC condensate (measured during seedling phase only). Our works provide a scalable, cost-effective approach for PFAL deployment, opening up possibilities for sustainable urban food production.
人工照明植物工厂(pfal)对于全年气候适应型城市农业至关重要,可应对粮食安全和可持续性挑战。然而,高昂的建设成本和能源需求限制了其广泛应用。在这项工作中,我们设计并测试了一个低成本和节能的集装箱农场,通过带有反射材料的移动机架,自适应环境控制系统和用于自动化操作的物联网框架(RS485, Modbus RTU),在建筑面积方面耗资9亿美元(14.09平方米建筑面积的建筑成本为12,500美元)。这个集装箱农场实现了光、热和水的有效利用,同时提供光周期同步的环境控制,以支持绿叶蔬菜的种植。在为期50天的试验中,在15.56平方米的种植面积上生产了95公斤的Frillice莴苣,能耗为43千瓦时·天−1 (72% led, 14%暖通空调,14%其他),并通过暖通空调冷凝水显示了11.4 L·天−1的水回收率(仅在苗期测量)。我们的工作为PFAL的部署提供了一种可扩展的、具有成本效益的方法,为可持续的城市粮食生产开辟了可能性。
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引用次数: 0
Hydrothermal carbonisation of solid recovered fuel – a model material approach 固体回收燃料的水热碳化-一种模型材料方法
IF 6.5 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-01 DOI: 10.1016/j.clet.2025.101127
Tilia Dahou, Lwhathanysh Urbaez Terrero, Lisa Gribal, Sylvie Valin
In order to facilitate gasification of heterogeneous waste such as solid recovered fuel (SRF), a pre-treatment by hydrothermal carbonisation (HTC) is considered. This study uses a model material approach to represent SRF and study its behaviour during HTC, and in particular the hydrochar properties (yield, ash content, LHV, apparent density, carbon concentration, fixed carbon, inorganic content). HTC experiments were conducted at temperatures between 200 and 280 °C on one SRF and seven model materials (waste wood, cardboard, polyethylene, PET, polyamide, PVC and waste tyres) selected to represent the variety of materials and compositions. When comparing HTC behaviours of the resources, various profiles appear: biomass-based, reactive plastics (PET and PVC) and non-reactive plastics (PA, PE, waste tyres), which however show some physical transformations (melting, formation of powder). Results show that HTC of SRF is mainly controlled by the degradation of lignocellulosic molecules (in particular cellulose and hemicellulose), but that degradation is itself enhanced by the increase in acidity induced by the degradation of plastics (PET and PVC). The LHV and C content of SRF hydrochar are higher than those of the initial SRF (increase by 48 and 36 percentage points after HTC at 240 °C, respectively), while fixed carbon is not significantly affected in these conditions. The apparent density is improved (doubled after HTC at 240 °C) due to an increase of the apparent density of most of the model materials, including non-reactive ones. All these changes could be positive for an easier gasification of the hydrochar compared to the initial SRF. Finally, N content is unchanged (it leaves the solid in the same proportions as C), and Cl and S contents decrease, as for model materials.
为了促进非均质废物如固体回收燃料(SRF)的气化,考虑了水热碳化(HTC)的预处理。本研究使用模型材料方法来表示SRF,并研究其在HTC过程中的行为,特别是烃类性质(产率、灰分含量、LHV、表观密度、碳浓度、固定碳、无机含量)。HTC实验在200至280°C的温度下对一种SRF和七种模型材料(废木材,纸板,聚乙烯,PET,聚酰胺,PVC和废轮胎)进行,以代表材料和成分的多样性。当比较资源的HTC行为时,出现了不同的概况:生物质基,反应性塑料(PET和PVC)和非反应性塑料(PA, PE,废轮胎),但它们表现出一些物理转变(熔化,形成粉末)。结果表明,SRF的HTC主要受木质纤维素分子(特别是纤维素和半纤维素)的降解控制,但降解本身因塑料(PET和PVC)降解引起的酸度增加而增强。SRF烃类的LHV和C含量高于初始SRF(在240℃下HTC后分别增加48和36个百分点),而固定碳在这些条件下没有明显影响。由于大多数模型材料(包括非反应性材料)的表观密度增加,表观密度得到了改善(在240℃HTC后增加了一倍)。与初始SRF相比,所有这些变化对于更容易气化的烃类都是积极的。最后,与模型材料相比,N含量保持不变(与C的比例相同),Cl和S含量降低。
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引用次数: 0
Effect of silane-treated jute/sisal cellulose reinforcement on the mechanical, tribological, and hydrophobic behavior of polyester composites 硅烷处理的黄麻/剑麻纤维素增强剂对聚酯复合材料力学、摩擦学和疏水性的影响
IF 6.5 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-01 DOI: 10.1016/j.clet.2025.101122
N. Lakshmaiya , T. Raja , D. Yuvarajan
Natural fiber–reinforced composites are attracting attention as sustainable alternatives to synthetic materials, but improving their strength, wear resistance, and water stability remains challenging. The present study focuses on developing silane-treated jute–sisal hybrid fiber-reinforced polyester composites enhanced with plant-derived cellulose microfillers to improve their mechanical, tribological, and hydrophobic performance. The main objective was to strengthen fiber–matrix interfacial bonding and enhance overall composite durability by combining hybrid natural fibers with chemical surface modification. The novelty of this work lies in the integration of silane surface treatment with cellulose microfiller reinforcement, which establishes strong Si–O–Si and Si–O–C bonds that improve adhesion, reduce voids, and minimize water diffusion—an approach not widely reported for hybrid natural fiber composites. The composites were fabricated by hand lay-up with cellulose contents of 0–6 wt%, followed by curing at 120 °C. Among all configurations, the G3 composite (4 wt% cellulose) exhibited the highest tensile strength (115.5 MPa), flexural strength (137.2 MPa), interlaminar shear strength (28.8 MPa), and impact energy (5.16 J), showing a 51 % improvement over the untreated system. The G4 composite (6 wt% cellulose) demonstrated the lowest wear rate (0.38 mm3 N−1 m−1) and coefficient of friction (0.014), while fracture toughness improved by 340 % and energy release rate by 224 % compared with neat polyester. Water absorption decreased to 23.2 %, indicating enhanced interfacial sealing and moisture resistance. The correlation between fiber hybridization, silane bonding, and filler dispersion confirms a strong synergistic effect. The developed composites offer a sustainable, high-strength, and wear-resistant material suitable for lightweight structural and tribological applications in automotive, aerospace, and defense sectors.
天然纤维增强复合材料作为合成材料的可持续替代品正引起人们的关注,但提高其强度、耐磨性和水稳定性仍然具有挑战性。本研究的重点是开发硅烷处理的黄麻杂化纤维增强聚酯复合材料,并用植物源性纤维素微填料增强,以改善其机械性能、摩擦学性能和疏水性。主要目的是通过将混合天然纤维与化学表面改性相结合,加强纤维-基体界面结合,提高复合材料的整体耐久性。这项工作的新颖之处在于硅烷表面处理与纤维素微填料增强的整合,它建立了强大的Si-O-Si和Si-O-C键,提高了附着力,减少了空隙,并最大限度地减少了水的扩散——这是一种未被广泛报道的混合天然纤维复合材料的方法。采用纤维素含量为0-6 wt%的手工铺层法制备复合材料,然后在120℃下固化。在所有配置中,G3复合材料(4 wt%纤维素)表现出最高的抗拉强度(115.5 MPa),抗弯强度(137.2 MPa),层间剪切强度(28.8 MPa)和冲击能(5.16 J),比未处理的体系提高了51%。与纯聚酯相比,G4复合材料(6 wt%纤维素)的磨损率(0.38 mm3 N−1 m−1)和摩擦系数(0.014)最低,断裂韧性提高340%,能量释放率提高224%。吸水率下降到23.2%,表明界面密封性和抗湿性增强。纤维杂化、硅烷键和填料分散之间的相关性证实了一种很强的协同效应。开发的复合材料提供了一种可持续的、高强度的、耐磨的材料,适用于汽车、航空航天和国防领域的轻量化结构和摩擦学应用。
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引用次数: 0
Environmental assessment of refractories in the steel industry: A comprehensive LCA framework with an innovative data retrieval approach 钢铁工业中耐火材料的环境评估:具有创新数据检索方法的综合LCA框架
IF 6.5 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-01 DOI: 10.1016/j.clet.2025.101128
Md Jubayed , Kinga Malgorzata Klima , Md Rubel , Rinus Siebring , Angélique Léonard
Refractory materials are essential for sustaining high-temperature industrial processes, with the steel industry being the largest consumer. This study proposes a comprehensive life cycle assessment framework for refractories in the steel industry, addressing key methodological challenges, particularly those concerning various post-use refractory management strategies. Collecting inventory for refractory production is challenging due to confidentiality concerns and suppliers' reluctance to share information. To overcome this, an innovative method is developed to retrieve essential inventory data from the refractory's product definition. The framework is applied through a case study comparing two magnesia-carbon bricks used for steel ladle slag lining: one produced in China and the other in the Netherlands. Inventories for brick production are derived from the respective product definitions. Results reveal that the Netherlands brick performs better in climate change and acidification, while the Chinese brick shows lower impacts in other assessed categories. Electricity consumption during magnesia production and thermal energy demand for ladle heating are identified as the major environmental hotspots. Energy transition scenarios demonstrate the potential for significant improvements. Replacing national grid electricity and natural gas with renewable electricity and green hydrogen leads to more than 30 % reductions in most impact categories. Climate change impacts, for instance, decrease from 1.89 to 0.97 kg CO2 eq for the Chinese brick and from 1.67 to 0.77 kg CO2 eq for the Netherlands brick. Sensitivity analysis shows that magnesia production strongly influences environmental performance, while uncertainty associated with product-definition-derived data is generally minor.
耐火材料对于维持高温工业过程至关重要,钢铁工业是最大的消费者。本研究提出了钢铁行业耐火材料的全面生命周期评估框架,解决了关键的方法挑战,特别是那些涉及各种使用后耐火材料管理策略的挑战。由于保密问题和供应商不愿共享信息,收集耐火材料生产库存具有挑战性。为了克服这一点,开发了一种创新的方法,从耐火材料的产品定义中检索必要的库存数据。该框架通过对两种用于钢包渣衬的镁碳砖的案例研究进行了应用:一种是中国生产的,另一种是荷兰生产的。砖生产的库存来源于各自的产品定义。结果表明,荷兰砖在气候变化和酸化方面表现更好,而中国砖在其他评估类别中表现出较低的影响。氧化镁生产过程中的电力消耗和钢包加热的热能需求是主要的环境热点。能源转型情景展示了重大改进的潜力。用可再生电力和绿色氢取代国家电网的电力和天然气,在大多数影响类别中减少了30%以上。例如,中国砖对气候变化的影响从1.89千克二氧化碳当量减少到0.97千克二氧化碳当量,荷兰砖从1.67千克二氧化碳当量减少到0.77千克二氧化碳当量。敏感性分析表明,氧化镁生产对环境绩效影响很大,而与产品定义衍生数据相关的不确定性通常较小。
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引用次数: 0
Corrigendum to “Enhancing construction supply chain sustainability: The synergistic role of big data analytics and organizational culture using SEM” [Clean. Eng. Technol. 27 (2025) 101025] “提高建筑供应链的可持续性:使用SEM的大数据分析和组织文化的协同作用”的勘误表[清洁。Eng。科技. 27 (2025)101025]
IF 6.5 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-01 DOI: 10.1016/j.clet.2025.101095
Amir Mohammad Norouzzadeh , Seyed Pendar Toufighi , Abolfazl Edalatipour , Jan Vang , Mooud Dabaghiroodsari
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引用次数: 0
Zero waste initiatives in Slovenian municipalities: A material flow and life cycle assessment analyses 斯洛文尼亚市政当局的零废物倡议:物料流和生命周期评估分析
IF 6.5 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-01 DOI: 10.1016/j.clet.2025.101120
Kristijan Brglez , Rebeka Kovačič Lukman , Roman Gumzej
The European Union (EU) has implemented several strategies, including the zero-waste initiative, to minimize waste generation and enhance resource efficiency. Slovenia demonstrates this policy with the “Zero Waste Municipalities” project, which has shown notable success, but also highlights opportunities for further improvement. This study assesses the effectiveness of zero-waste initiatives and municipal solid waste management (MSWM) strategies across Slovenian municipalities using Material Flow Analysis (MFA) and Life Cycle Assessment (LCA). MFA results from eight municipalities indicate that biowaste (averaging 42.49 %) and paper (21.78 %) constitute the largest fractions of collected municipal waste. LCA results highlight that, on a per capita basis, environmental impacts in urban areas are generally lower than in rural areas for glass, wood, biowaste, and plastic waste streams, but higher for metal and paper. Scenario modelling for Ljubljana demonstrates that meeting the EU recycling targets for 2025 and 2030 would lead to substantial reductions in environmental impacts—especially in terms of Global Warming Potential (GWP) and Abiotic Depletion Potential (ADP). Specifically, achieving the 2030 targets could reduce CO2 emissions from paper, plastic, and wood waste by 52 %, 25 %, and 77 %, respectively, compared to current baseline recycling ratios. The integration of MFA and LCA provides a comprehensive and quantitative assessment and insight into current waste management practices in Slovenian municipalities, accelerating a transition towards zero waste and circular municipalities. The findings offer valuable information for decision-makers, researchers and stakeholders aligning local waste management strategies with broader EU objectives.
欧洲联盟(欧盟)实施了若干战略,包括零废物倡议,以尽量减少废物产生和提高资源效率。斯洛文尼亚通过“零废物城市”项目证明了这一政策,该项目取得了显著成功,但也突出了进一步改进的机会。本研究利用物料流分析(MFA)和生命周期评估(LCA)评估了斯洛文尼亚各城市零废物倡议和城市固体废物管理(MSWM)战略的有效性。八个城市的MFA结果表明,生物废物(平均为42.49%)和纸张(21.78%)构成收集的城市废物的最大部分。LCA的结果强调,按人均计算,城市地区对玻璃、木材、生物废物和塑料废物流的环境影响一般低于农村地区,但对金属和纸张的影响较高。卢布尔雅那的情景模型表明,达到欧盟2025年和2030年的回收目标将大大减少对环境的影响,特别是在全球变暖潜能值(GWP)和非生物耗竭潜能值(ADP)方面。具体来说,与目前的基准回收率相比,实现2030年目标可以将纸张、塑料和木材废弃物的二氧化碳排放量分别减少52%、25%和77%。MFA和LCA的整合为斯洛文尼亚各城市目前的废物管理做法提供了全面和定量的评估和洞察,加速向零废物和循环城市过渡。这些发现为决策者、研究人员和利益相关者提供了有价值的信息,使当地的废物管理战略与更广泛的欧盟目标保持一致。
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引用次数: 0
Advantages of natural polymer yarn encoding technology for traceability in the textile industry 天然高分子纱线编码技术在纺织行业可追溯性中的优势
IF 6.5 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-01 DOI: 10.1016/j.clet.2025.101121
Micheline Maia Teixeira , Luiz Fernando Rodrigues Pinto , Valquíria Demarchi Arns , Angelino dos Santos Ernesto , Geraldo Cardoso de Oliveira Neto , Marlene Amorim , Francesco Facchini
Ensuring transparency in textile production, particularly in addressing environmental and social issues, has driven the development of technologies such as smart tags, encrypted labels, blockchain, and fibre DNA. However, full traceability from raw material extraction to the finished product remains a challenge, especially due to chemically aggressive processes like dyeing and washing. This study adopted a case study approach to evaluate a yarn tracking technology that embeds a code directly into the textile product, remaining functional throughout its life cycle. The assessment combined technical tests, payback-based economic analysis, and environmental evaluation using the Mass Intensity Total (MIT) metric. Conducted in a Brazilian textile company, the study validated the coding system's durability and feasibility. The code remained readable after industrial processing, enabling traceability across all process stages. Results revealed annual cost saving of USD 5639.00 and a payback period of approximately 5.4 years. The implementation also led to a reduction of 8.5 million kilograms in MIT, indicating substantial environmental benefits. The system facilitates the identification of leftover fabric cuts, supporting waste reduction and material conservation. Additionally, by geolocating production steps, it helps monitor working conditions and mitigate risks of labour analogous to slavery. By ensuring durable, embedded traceability, this research advances biopolymer tracking and contributes to more transparent, circular, and socially responsible practices in the textile sector. The adoption of this technology may assist companies in aligning operations with transparency goals, legal compliance, and sustainability standards.
确保纺织品生产的透明度,特别是在解决环境和社会问题方面,推动了智能标签、加密标签、区块链和纤维DNA等技术的发展。然而,从原材料提取到成品的完全可追溯性仍然是一个挑战,特别是由于染色和洗涤等化学侵蚀性过程。本研究采用案例研究的方法来评估纱线跟踪技术,该技术将代码直接嵌入纺织品中,并在其整个生命周期中保持功能。评估结合了技术测试、基于回报的经济分析和使用质量强度总(MIT)指标的环境评估。该研究在巴西一家纺织公司进行,验证了编码系统的耐用性和可行性。在工业处理之后,代码仍然是可读的,支持跨所有过程阶段的可追溯性。结果显示,每年可节省成本5639.00美元,投资回收期约为5.4年。该项目的实施还使麻省理工学院的温室气体排放量减少了850万公斤,表明了巨大的环境效益。该系统有助于识别剩余的织物切割,支持减少浪费和节约材料。此外,通过对生产步骤进行地理定位,它有助于监测工作条件,减轻类似奴隶制的劳动风险。通过确保耐用,嵌入式可追溯性,这项研究推进了生物聚合物跟踪,并有助于纺织行业更加透明,循环和社会责任的实践。采用该技术可以帮助公司将操作与透明度目标、法律遵从性和可持续性标准相一致。
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引用次数: 0
Optimizing the recovery of rare earth elements from acid mine water: A sustainable approach using selective precipitation 优选从酸性矿井水中回收稀土元素:采用选择性沉淀的可持续方法
IF 6.5 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-11-27 DOI: 10.1016/j.clet.2025.101123
Óscar Crespo , Mehrez Hermassi , Oriol Gibert , Jordi Cama , José Luis Cortina
This study focuses on the recovery of rare earth elements (REEs) from acid mine water (AMW) through a two-step selective process, which consists of a selective extraction with ion exchange followed by a precipitation stage using oxalic acid. Optimization of the effective REE recovery from sulphuric ion-exchange concentrates results in sustainable AMW management, providing a secondary resource for critical metals towards green transition. Experimental results indicate that (1) the use of oxalic acid facilitates the formation of REE-oxalate crystals, yielding recovery efficiencies in light rare earth elements (LREEs) much higher than for heavy rare earth elements (HREEs) at specific excess doses, and that (2) LREEs act as precursors for HREE precipitation. Moreover, REE-oxalate crystallization depends on the oxalic acid dose, pH, and precipitation time (PT). The longer the PT, the larger the crystals, which are economically advantageous. The study highlights that AMW is a potential secondary source for the REE recovery, which contributes to sustainable mining practices and provides confidence for further optimization of REE recovery processes.
本文研究了采用离子交换选择性萃取和草酸沉淀两步法从酸性矿水中回收稀土元素(ree)。从硫交换精矿中有效回收稀土元素的优化可实现可持续的无机废水管理,为关键金属向绿色转型提供了二次资源。实验结果表明:(1)草酸的使用促进了稀土-草酸盐晶体的形成,在特定过量剂量下,轻稀土元素(lree)的回收效率远高于重稀土元素(HREE);(2)轻稀土元素是HREE沉淀的前体。此外,ree -草酸盐结晶取决于草酸剂量、pH和沉淀时间(PT)。PT越长,晶体越大,具有经济上的优势。该研究强调,AMW是稀土元素回收的潜在二次来源,有助于可持续采矿实践,并为进一步优化稀土元素回收过程提供信心。
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Cleaner Engineering and Technology
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