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Effect of fullerene-like nanoparticles at low concentrations on the anti-wear properties of motor fuels 低浓度类富勒烯纳米颗粒对汽车燃料抗磨性能的影响
Pub Date : 2022-06-24 DOI: 10.31891/2079-1372-2022-104-2-49-54
V. S. Pyliavsky, Y. Polunkin, O. Haidai, O. B. Yanchenko
Motor fuels are the source of energy for internal combustion engines, and also a lubricant for friction units of the fuel equipment of automobile, aircraft and ship engines. The reliability and service life of the entire mechanism depend on the antiwear properties of fuels. Traditional anti-wear additives containing sulfur, phosphorus, chlorine, etc., are not applicable in motor fuels due to restrictions on emissions of toxic compounds. To improve the antiwear properties of lubricants, it is possible to use a new class of spatial carbon compounds - fullerene-like nanoparticles (FLNs). This work shows that modification of liquid hydrocarbon motor fuels with fullerene-like nanoparticles (FLNs) increases the antiwear properties of fuels
发动机燃料是内燃机的能量来源,也是汽车、飞机和船舶发动机燃料设备摩擦单元的润滑剂。整个机构的可靠性和使用寿命取决于燃料的抗磨性能。传统的含硫、磷、氯等抗磨添加剂,由于对有毒化合物排放的限制,已不适用于车用燃料。为了提高润滑油的抗磨性能,有可能使用一类新的空间碳化合物——类富勒烯纳米颗粒(FLNs)。这项工作表明,用类富勒烯纳米颗粒(FLNs)改性液态烃发动机燃料可以提高燃料的抗磨性能
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引用次数: 1
Contact melting and structure formation in the system: α-iron-nanomaterials - common quality carbon steel 体系中α-铁纳米材料-普通优质碳钢的接触熔化和结构形成
Pub Date : 2022-06-24 DOI: 10.31891/2079-1372-2022-104-2-13-19
V. Savulyak, А.А. Osadchuk
In this paper, processes of contact melting between steel plates, which arises after feeding the contact pulse of a contact welding machine, are studied, for cases when nanomaterials in the form of carbon nanofibers and powders of refractory metals are being located between the plates. It was established that the addition of carbon nanotubes allows to ensure the passage of contact melting with lower energy costs and to obtain high carbonaceous layers of considerable hardness, and the addition of doping elements makes it possible to control the structure, grainy and physical and mechanical properties of the formed material.
本文研究了接触焊机输入接触脉冲后钢板间的接触熔化过程,其中以纳米碳纤维和难熔金属粉末形式存在于钢板之间。结果表明,碳纳米管的加入可以以较低的能量成本确保接触熔化的通过,并获得具有相当硬度的高碳质层,而掺杂元素的加入可以控制形成材料的结构、晶粒和物理机械性能。
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引用次数: 0
Nanostructural glass composite coatings 纳米结构玻璃复合涂层
Pub Date : 2022-06-24 DOI: 10.31891/2079-1372-2022-104-2-35-41
S. Kharchenko, O. Kharchenko
The results of the study of glass-composite nanostructured self-lubricating coatings are presented. The developed glass composite is an antifriction material with an ultrafine structure. The structural components of these coatings significantly affect the graphitization process and provide an antifriction surface layer of α-graphite. The formation of this layer makes it possible to significantly minimize the contact parameters in the friction region. The developed antifriction nanostructured glass-ceramic self-lubricating coatings containing magnesium carbide and structural components that promote surface graphitization do not contain expensive and scarce components, meet environmental safety requirements, and have high performance characteristics. A significant effect of aluminoborosilicate in the form of a glass phase on the tribological properties of coatings is noted. An increase in adhesive strength is achieved by forming a surface layer of glassy sodium silicate. Using X-ray phase analysis, it was found that the intercalating elements in the subsurface zone-graphite system at the initial stage of the process were Mg2+, Al3+, Cu2+ ions, which randomly penetrated into the interlayer space of the graphite matrix. At sliding speeds of more than 3.0 m/s, intercalates of binary molecular compounds of these elements with oxygen were found in the layered system of graphite. Their intercalation is accompanied by a sequence of repetitive stages, which are reversible with a change in tribological parameters and are characterized by a specific transformation of the structure and, above all, by an increase in the distance between layers due to the influence of various types of interlayer defects and the introduction of intercalants. The presence of near-surface particles in the graphite layer does not affect the tribotechnical characteristics of the coatings. The developed glass-composite nanostructured self-lubricating coatings have high antifriction characteristics throughout the entire load-speed range
介绍了玻璃复合纳米结构自润滑涂层的研究结果。所研制的玻璃复合材料是一种具有超细结构的减摩材料。这些涂层的结构组分显著影响石墨化过程,并提供α-石墨的减摩表面层。该层的形成使摩擦区域的接触参数显著最小化成为可能。所研制的含碳化镁和促进表面石墨化的结构组分的纳米微晶玻璃自润滑涂层不含昂贵和稀缺组分,满足环境安全要求,具有高性能的特点。注意到玻璃相形式的硼硅铝对涂层摩擦学性能的显著影响。粘接强度的增加是通过形成玻璃状硅酸钠的表层来实现的。通过x射线相分析发现,在该过程的初始阶段,亚表面区-石墨体系中的插层元素是Mg2+、Al3+、Cu2+离子,它们随机渗透到石墨基体的层间空间中。当滑动速度大于3.0 m/s时,在石墨层状体系中发现了这些元素与氧的二元分子化合物的插层。它们的嵌入伴随着一系列重复的阶段,这些阶段随着摩擦学参数的变化是可逆的,其特征是结构的特定转变,最重要的是,由于各种层间缺陷的影响和插入剂的引入,层间距离的增加。石墨层中近表面颗粒的存在不影响涂层的摩擦技术特性。所研制的玻璃复合材料纳米结构自润滑涂层在整个负载-转速范围内具有较高的抗摩擦性能
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引用次数: 0
Thermodynamic substantiation of the direction of nonequilibrium processes in triadconjugations of machine parts based on the principles of maximum and minimum entropy 基于最大和最小熵原理的机械零件三共轭非平衡过程方向的热力学证实
Pub Date : 2022-06-24 DOI: 10.31891/2079-1372-2022-104-2-55-63
V. Aulin, S. Lysenko, A. Hrynkiv, D. Holub
The article gives a thermodynamic substantiation of the direction of nonequilibrium processes in tribocouples of machine parts, in tribosystems, based on the principles of maximum and minimum entropy. It is clarified how nonequilibrium processes can be substantiated on the basis of the minimum and maximum function of entropy production: linear and nonlinear nonequilibrium processes and their different thermodynamics. The entropy production function is considered as a function of thermodynamic force flows and thermodynamic flows. The theory of nonequilibrium processes is based on the Liouville equation for classical tribosystems, taking into account external influences or perturbations. It is shown that in thermodynamic processes in tribosystems the principle of entropy maximization is realized as the second principle of synergetics.
本文根据最大和最小熵原理,给出了摩擦系统中机械零件摩擦偶非平衡过程方向的热力学证明。阐明了如何在熵产生的最小和最大函数的基础上证实非平衡过程:线性和非线性非平衡过程及其不同的热力学。熵产生函数被认为是热力学力流和热力学流的函数。非平衡过程理论是基于经典摩擦系统的刘维尔方程,考虑了外部影响或扰动。结果表明,在摩擦系统的热力学过程中,熵最大化原理作为协同学的第二原理得以实现。
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引用次数: 0
Increasing warning resistance of engine valves by gas nitrogenization method 用气体氮化法提高发动机气门的报警阻力
Pub Date : 2022-06-24 DOI: 10.31891/2079-1372-2022-104-2-20-27
D. Marchenko, K. Matvyeyeva
The article presents the results of tribological research on the most promising way to restore and increase the wear resistance of engine valves by developing a method of gas nitriding. It is established that with increasing operating time the guide bushings of the outlet connections wear out with the displacement of the axis of the forming surfaces of the hole. Characteristic significant displacement of the axes of the inlet connections is not detected, ie. their wear on the diameter of the hole is 1.5 ... 3 times less than the wear of the exhaust bushings, the values of the displacement of the axes are within the error of the measuring instrument. The average value of ovality is greater in the exhaust seats - the maximum beating values of the intake seats are 0.34 mm, exhaust - 0.22 mm. It is proved that the non-uniformity of the wear of the sleeve hole is determined by the balance of acting forces, which, in turn, are determined by deviations from the optimal ratios μ and e. the side of the rocker arm axis. Distortions of the valve in the longitudinal axis of the engine contribute to an earlier reduction in the tightness of the valve pairs. Redistribution of the valve end material with the formation of a wavy concentric surface, the shape of the contact spot on the rocker arm and the corresponding direction of wear of the saddle chamfer was observed in 43% of the studied connections. Technological means and methods for improving the quality of repair, measuring instruments for accurate study of the parameters of parts and connections of the valve group are given. The results of laboratory and operational tests are presented. A method of gas nitriding with an installation for its implementation has been developed, which provides an environmentally friendly method of low-temperature and high-temperature hardening, obtaining deeper and well-developed layers of the diffusion near-surface zone and reduces training, technological time in the process of strengthening and reducing energy consumption
本文介绍了通过开发气体氮化方法来恢复和提高发动机气门耐磨性的最有前途的方法的摩擦学研究结果。已经确定,随着操作时间的增加,出口连接的导套随着孔的成形表面的轴线的位移而磨损。未检测到入口连接轴的显著特征位移,即它们对孔直径的磨损比排气套管的磨损小1.5…3倍,轴的位移值在测量仪器的误差范围内。排气座的椭圆度平均值较大-进气座的最大跳动值为0.34 mm,排气座为0.22 mm。事实证明,套筒孔磨损的不均匀性是由作用力的平衡决定的,而作用力的平衡又是由与摇臂轴侧的最佳比值μ和e的偏差决定的。气门在发动机纵轴上的扭曲有助于提前降低气门对的密封性。在43%的研究连接中,观察到阀端材料的重新分布,形成了波浪形同心表面、摇臂上接触点的形状以及鞍形倒角的相应磨损方向。给出了提高维修质量的技术手段和方法,以及精确研究阀组零件和连接件参数的测量仪器。给出了实验室和运行试验的结果。开发了一种带装置的气体氮化方法,该方法提供了一种环境友好的低温和高温硬化方法,获得了更深、更发达的近表面扩散层,并减少了强化过程中的培训和技术时间,降低了能耗
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引用次数: 0
Tribological properties of anode-spark coatings on aluminum alloys 铝合金阳极火花涂层的摩擦学性能
Pub Date : 2022-06-24 DOI: 10.31891/2079-1372-2022-104-2-28-34
O. Dykha, O. Babak, O. Makovkin, S. Posonskiy
It is established that at present the technology of anode-spark coatings in general is well studied. However, the lack of recommendations for the choice of modes of technological processes and tribological characteristics in different operating conditions limit the widespread introduction of this technology. The task of this work was to analyze the processes of anode-spark coatings, improve technology and study the wear resistance of samples processed by this and traditional anode technology. The development of technology for the application of protective coatings on valve metals in the conditions of spark discharge included the choice of electrolyte and mode of operation of the bath: voltage, current density, hydrodynamic conditions and other parameters. Wear resistance tests were performed on a special installation. Structurally, the installation is made in two positions, which allows you to test two samples with different load conditions at a constant sliding speed. The design of the installation implements the friction scheme of the liner shaft. The study of anode-spark coatings in the mode of limiting lubrication was studied in the environment of industrial oil. The wear criterion was the weight wear of the samples according to the results of weight measurements before and after wear. It is established that prolonged electrolysis in the conditions of sparking leads to the formation of anode coatings that exceed in their properties the films obtained by non-sparking oxidation. Comparative studies of the wear resistance of anode-spark coatings and galvanic anode coatings under the same test conditions showed that the wear of anode-spark coatings is almost twice lower for the entire load range. The considered technology is recommended for increase of wear resistance of elements of devices from the aluminum alloys working in the conditions of corrosion and mechanical wear
研究表明,目前阳极-火花涂层技术总体上得到了较好的研究。然而,由于缺乏对不同操作条件下的工艺流程和摩擦学特性的选择模式的建议,限制了该技术的广泛推广。本工作的任务是分析阳极火花涂层的工艺过程,改进工艺,并研究该工艺与传统阳极工艺处理样品的耐磨性。火花放电条件下阀门金属防护涂层应用技术的发展包括电解液的选择和镀液的操作方式:电压、电流密度、流体动力条件和其他参数。在一个特殊的装置上进行了耐磨性测试。在结构上,安装在两个位置,允许您在恒定滑动速度下测试不同负载条件下的两个样品。安装设计采用衬轴摩擦方案。在工业用油环境下,研究了极限润滑模式下阳极火花涂层的性能。磨损标准是根据磨损前后的重量测量结果对样品进行重量磨损。在有火花的条件下长时间电解会导致阳极镀层的形成,其性能超过无火花氧化得到的镀层。在相同的测试条件下,对阳极火花涂层和电阳极涂层的耐磨性进行了对比研究,结果表明,在整个负载范围内,阳极火花涂层的磨损几乎降低了两倍。所考虑的技术被推荐用于提高在腐蚀和机械磨损条件下工作的铝合金元件的耐磨性
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引用次数: 0
Estimation of tribotechnical parameters of composite polymer with metal filler 金属填料复合聚合物摩擦学参数的估算
Pub Date : 2022-06-24 DOI: 10.31891/2079-1372-2022-104-2-42-48
О.О. Skvortsov, Оksana Mikosianchyk
Р The use of composition material based on the polyamide (caprolon) Ertalon 4.6 as an anti-friction material in the sliding units in the aviation industry is considered. Low carbon electrotechnical sheet steel 21864 of different concentrations was used as filler of composite material. The article presents the thermal calculation of plain bearings with polymer insert in different operating modes. It is determined that the addition of a metal filler to polyamide causes a temperature decrease in the friction zone due to the effective heat exchange from the shaft to the bearing housing. The article conducts a study of tribo-technical properties of the proposed composite material on installation PT-4C under sliding conditions according to the scheme “cylinder-plane”, as well as modeling of the support unit in the software complex DS SolidWorks. It has been experimentally determined that the addition of finely dispersed steel filler enhances the antifriction properties of the Ertalon 4.6 polymer and extends the temperature range of the composite insert performance. Increasing the filler concentration to 20% results in a reduction of the friction coefficient by an average of 3.6 times and an increase in the temperature range of composite material use to 100 °C. The load-bearing capacity of the composite material bushing is increased to 25 MPa at a 20% filler concentration respectively. The practical significance of the work lies in the analysis of the antifriction properties of the polymer with metallic filler in comparison with the polymer without filler, which will prove the effectiveness of the use of such polymers in friction units instead of non-ferrous metals (bronze, babbitt).
Р考虑在航空工业滑动装置中使用基于聚酰胺(卡普隆)Ertalon 4.6的组合材料作为抗摩擦材料。采用不同浓度的低碳电工钢板21864作为复合材料的填料。本文介绍了聚合物嵌套滑动轴承在不同工况下的热计算。确定在聚酰胺中添加金属填料会导致摩擦区温度降低,这是由于从轴到轴承壳的有效热交换。本文按照“圆柱-平面”方案对所提出的复合材料在PT-4C安装件滑动条件下的摩擦技术性能进行了研究,并在DS SolidWorks软件综合体中对支撑单元进行了建模。实验结果表明,细分散钢填料的加入提高了Ertalon 4.6聚合物的抗摩擦性能,并扩大了复合材料嵌套性能的温度范围。将填料浓度提高到20%,摩擦系数平均降低3.6倍,复合材料的使用温度范围提高到100℃。填料浓度为20%时,复合材料衬套的承载能力分别提高到25 MPa。本文的实际意义在于分析了含金属填料的聚合物与不含金属填料的聚合物的抗摩擦性能,从而证明了这种聚合物在摩擦单元中代替有色金属(青铜、巴氏合金)的有效性。
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引用次数: 0
Creation of new technological methods for surface engineering based on broaching 基于拉削的表面工程新技术方法的创新
Pub Date : 2022-06-17 DOI: 10.31891/2079-1372-2022-104-2-6-12
I. Shepelenko, E. Posviatenko, Y. Nemyrovskyi, V. Cherkun, I.P. Rybak
The article is devoted to the creation of new processing technologies through the use of drawing. It is determined that the most effective processes of surface engineering of machine parts are hybrid technologies. The advantages of such technologies due to obtaining a new effect from the impact on the part by two or more dissimilar processes belonging to one or different groups of surface engineering methods are noted. It is proved that the use of hybrid technologies on the basis of stretching allows to combine the advantages of different methods, first of all cold plastic deformation methods, in combination with others. The use of deforming drawing provides in the surface layer favorable for the part of the compressive residual stresses, increase the wear resistance of the surface, as well as the strength of the part. The results of the research allowed to classify the deforming drawing as a class of surface engineering methods. On the example of processing of cylinder liners of internal combustion engines the combined technology containing operations of deforming drawing and finishing antifrictional non-abrasive processing is developed. It is shown that the use of deforming drawing has significantly improved the quality of antifriction coating. The use of deforming drawing to the component of the hybrid method with the subsequent pulsed nitriding is considered.It is established that when nitriding cutting tool products, hybrid process modes should be set in order to create the most effective nitride zone. In the case of processing of road vehicle parts, special attention should be paid to obtaining a diffusion layer. The efficiency of the offered technologies on the basis of stretching is established. Determining the prospects for further use of deforming drawing as an integral part of hybrid technologies
本文致力于通过使用绘图来创造新的加工技术。确定了机械零件表面工程中最有效的工艺是混合工艺。这些技术的优点是,由于属于一个或不同的表面工程方法组的两个或多个不同的过程对零件的影响而获得新的效果。事实证明,在拉伸的基础上使用混合技术可以结合不同方法的优点,首先是冷塑性变形方法,与其他方法相结合。采用变形拉深提供了在表层有利的零件的压残余应力,增加了表面的耐磨性,以及零件的强度。研究结果允许将变形拉伸分类为一类表面工程方法。以内燃机汽缸套加工为例,开发了含变形、拉伸和精加工的无磨料减摩加工组合工艺。结果表明,采用变形拉深工艺可以显著提高涂层的质量。考虑了将变形拉深法与后续脉冲渗氮相结合的方法应用于复合方法的部件。提出了刀具产品氮化时,应设置混合工艺模式,以形成最有效的氮化区。在道路车辆零件加工的情况下,应特别注意获得扩散层。在拉伸的基础上,确定了所提供技术的效率。确定变形拉伸作为混合技术组成部分的进一步应用前景
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引用次数: 0
Substantiation of conditions of effective working capacity of tribocouples of the details made of polymeric composite materials with high-modulus fillers 高模量填充聚合物复合材料细部摩擦偶有效工作能力条件的证实
Pub Date : 2022-03-30 DOI: 10.31891/2079-1372-2022-103-1-82-91
V. Aulin, A. Hrynkiv, S. Ly, O. Livitskyi
This work is devoted to the study of the conditions of effective performance of triad couplings of parts made of polymeric composite materials. The stress state of the material is associated with the characteristics of the accumulation of dislocations, the energy of activation of their movement. The average stress, friction stress is determined. Based on this, expressions for estimating critical stresses and loads on tribocouple parts are obtained. The distribution of the force on the tribocoupling of parts is determined taking into account the quality characteristics of the friction surfaces, modulus of elasticity and Poisson's constant of the components of the polymer composite material. This problem is considered for tribocouples of parts of various kinds. Expressions for calculation of nominal pressures at different types of contact of material of details of tribocoupling are received, and also the equations on which it is possible to estimate in them values of nominal critical pressure are resulted. The conditions for efficient operation of tribocoupling of parts made of polymer composite materials are clarified. It is determined that a significant increase in the nominal critical pressure on the tribocoupling is possible with the use of high-modulus fillers, the modulus of elasticity of which is greater than the modulus of elasticity of the polymer matrix
本工作致力于研究聚合物复合材料零件三元联轴器的有效性能条件。材料的应力状态与位错积累的特征、位错运动的激活能量有关。确定了平均应力、摩擦应力。在此基础上,得到了估计摩擦副零件临界应力和载荷的表达式。在考虑摩擦表面的质量特性、聚合物复合材料部件的弹性模量和泊松常数的情况下,确定零件摩擦耦合上的力的分布。这个问题适用于各种零件的摩擦副。接收了摩擦耦合细节的材料在不同类型接触下的标称压力的计算表达式,并得出了可以在其中估计标称临界压力值的方程。阐明了由聚合物复合材料制成的零件的摩擦耦合有效操作的条件。已经确定,使用弹性模量大于聚合物基体弹性模量的高模量填料可以显著增加摩擦耦合上的标称临界压力
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引用次数: 0
Determination of the dynamic hardness of greases as a characteristic of deformation properties in a tribocontact 摩擦接触中作为变形特性的润滑脂动态硬度的测定
Pub Date : 2022-03-29 DOI: 10.31891/2079-1372-2022-103-1-65-75
O. Dykha, A. Staryi, V. Dytyniuk, M. Dykha
The efficiency of plastic oil is determined by the duration of its retention on the surface. Evaluation of the effectiveness of plastic lubricants depends on their mechanical properties. It is proposed to use the dependence of hardness on time when pressing a spherical indenter as one of the basic characteristics of the mechanical properties of plastic oils. The method of determining the function of oil hardness is based on the mechanics of contact interaction of a solid ball and a plane presented in this work, which has the property of creep according to the flow theory. One of the main methods of testing the deformation properties of plastic lubricants is to determine the number of penetrations. The number of oil penetrations is determined by the depth of indentation of the indenter; more informative for such a process is the ultimate pressure (hardness), which actually reflects the phenomenon of resistance to indenter indentation in the material. For uniform distribution of pressure under a spherical indenter the technique of construction of function of dynamic hardness of plastic materials is defined and on the basis of tests results of construction of dynamic hardness are received. Tests on contact creep of plastic lubricants are carried out, functions of dynamic hardness are received and the analysis of influence of character of change of dynamic hardness on wear processes in the presence of lubricants is carried out. To analyze the influence of deformation properties on the tribological properties of lubricants, comparative tests of the two above-mentioned types of lubricants on a four-ball friction device were performed. It was found that Litol-24 oil has the best wear resistance. The nonlinear period of running-in for this oil is practically absent that, obviously, under the given conditions of tests is connected with more stable in time deformation properties.
塑料油的效率由其在表面上的停留时间决定。塑料润滑剂的有效性评估取决于其机械性能。提出将压球面压头时硬度随时间的变化作为塑料油力学性能的基本特征之一。确定油硬度函数的方法是基于本文提出的固体球与平面的接触相互作用力学,该力学根据流动理论具有蠕变性质。测试塑料润滑剂变形性能的主要方法之一是确定渗透次数。油渗透的数量由压头的压痕深度决定;对于这种过程,更具信息性的是极限压力(硬度),它实际上反映了材料中对压头压痕的阻力现象。为了使球形压头下的压力均匀分布,定义了塑性材料动态硬度函数的构造技术,并在试验的基础上获得了动态硬度的构造结果。对塑料润滑剂的接触蠕变进行了试验,得到了动态硬度的函数,并分析了润滑剂存在下动态硬度变化特性对磨损过程的影响。为了分析变形性能对润滑剂摩擦学性能的影响,在四球摩擦装置上对上述两种润滑剂进行了对比试验。结果表明,Litol-24润滑油具有最佳的耐磨性。这种油的非线性磨合期实际上是不存在的,显然,在给定的试验条件下,它与更稳定的时间变形特性有关。
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引用次数: 0
期刊
Problemi tribologii
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