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Ultrafiltration study of the polysulfone membrane modified with branched polyethyleneimine 支化聚乙烯亚胺改性聚砜膜的超滤研究
IF 1.9 4区 环境科学与生态学 Q2 ENGINEERING, CIVIL Pub Date : 2023-08-17 DOI: 10.2166/aqua.2023.098
Smit Vala, S. Gawali, Surendra Sasi Kumar Jampa, M. Sinha, Snigdha Khuntia
This work discussed the fabrication of polysulfone (PSF) ultrafiltration membranes with hydrophilic behaviour by adding branched polyethyleneimine (PEI) as an additive. By directly blending the base polymer and the additive in the organic solvent, the casting solution is prepared. An asymmetric ultrafiltration membrane was fabricated by the phase inversion method. The presence of PEI was confirmed by comparing the IR spectra of the plain PSF membrane and the modified PSF membrane. A scanning electron microscope was used for the comparison of morphological changes in plain and modified membranes. The membrane was characterised with respect to bovine serum albumin (BSA) adsorption, pure water flux, permeability, compaction factor, humic acid (HA) rejection, and water uptake. The fouling resistance behaviour is prompted due to the presence of hydrophilic PEI chains in the membrane. As a result, pure water flux and flux recovery ratio increased from 28.84 to 326.54 L/m2h and from 0.526 to 0.954 L/m2hkPa for the modified membrane with respect to the plain membrane, respectively.
本文讨论了以支化聚乙烯亚胺(PEI)为添加剂制备具有亲水性的聚砜(PSF)超滤膜。将基体聚合物与添加剂在有机溶剂中直接共混,制备出浇铸液。采用相反转法制备了不对称超滤膜。通过比较PSF膜和改性后的PSF膜的红外光谱,证实了PEI的存在。用扫描电镜比较了普通膜和改性膜的形态变化。对膜进行了吸附牛血清白蛋白(BSA)、纯水通量、渗透性、压实因子、腐植酸(HA)排斥和吸水等方面的表征。由于膜中亲水性PEI链的存在,促进了抗污行为。结果表明,与普通膜相比,改性膜的纯水通量由28.84提高到326.54 L/m2h,通量回收率由0.526提高到0.954 L/m2hkPa。
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引用次数: 0
A comparison of the performance of SWAT and artificial intelligence models for monthly rainfall–runoff analysis in the Peddavagu River Basin, India SWAT与人工智能模型在印度佩德瓦古河流域月降雨径流分析中的性能比较
IF 1.9 4区 环境科学与生态学 Q2 ENGINEERING, CIVIL Pub Date : 2023-08-14 DOI: 10.2166/aqua.2023.048
Padala Raja Shekar, Aneesh Mathew, A. Pandey, Avadhoot Bhosale
Rainfall–runoff (R–R) analysis is essential for sustainable water resource management. In the present study focusing on the Peddavagu River Basin, various modelling approaches were explored, including the widely used Soil and Water Assessment Tool (SWAT) model, as well as seven artificial intelligence (AI) models. The AI models consisted of six data-driven models, namely support vector regression, artificial neural network, multiple linear regression, Extreme Gradient Boosting (XGBoost) regression, k-nearest neighbour regression, and random forest regression, along with one deep learning model called long short-term memory (LSTM). To evaluate the performance of these models, a calibration period from 1990 to 2005 and a validation period from 2006 to 2010 were considered. The evaluation metrics used were R2 (coefficient of determination) and NSE (Nash–Sutcliffe Efficiency). The study's findings revealed that all eight models yielded generally acceptable results for modelling the R–R process in the Peddavagu River Basin. Specifically, the LSTM demonstrated very good performance in simulating R–R during both the calibration period (R2 is 0.88 and NSE is 0.88) and the validation period (R2 is 0.88 and NSE is 0.85). In conclusion, the study highlighted the growing trend of adopting AI techniques, particularly the LSTM model, for R–R analysis.
降雨径流(R-R)分析对可持续水资源管理至关重要。本研究以佩德瓦古河流域为研究对象,探索了多种建模方法,包括广泛使用的水土评估工具(SWAT)模型,以及7种人工智能(AI)模型。人工智能模型包括6个数据驱动模型,即支持向量回归、人工神经网络、多元线性回归、极端梯度增强(XGBoost)回归、k近邻回归和随机森林回归,以及一个名为长短期记忆(LSTM)的深度学习模型。为了评估这些模型的性能,我们考虑了1990 - 2005年的校准期和2006 - 2010年的验证期。使用的评价指标为R2(决定系数)和NSE(纳什-萨克利夫效率)。该研究的结果表明,所有8个模型在模拟佩德瓦古河流域的R-R过程时都产生了普遍可接受的结果。具体而言,LSTM在校正期(R2为0.88,NSE为0.88)和验证期(R2为0.88,NSE为0.85)均表现出非常好的R-R模拟性能。总之,该研究强调了采用人工智能技术,特别是LSTM模型进行R-R分析的日益增长的趋势。
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引用次数: 1
Geospatial mitigation of the effect of undulating terrain on efficient water distribution network: a case study in Enugu Urban, South-Eastern Nigeria 起伏地形对高效配水网络影响的地理空间缓解:以尼日利亚东南部埃努古城市为例研究
IF 1.9 4区 环境科学与生态学 Q2 ENGINEERING, CIVIL Pub Date : 2023-08-09 DOI: 10.2166/aqua.2023.304
A. Ugwuoti, O. C. Ojinnaka, E. Ibem, V. Uzodinma
Undulating terrain has continued to aggravate pipe-borne water supply challenges in the Enugu Urban area. The rapid increase in urbanization has worsened the situation. This, therefore, calls for the deployment of systems that can support the effective planning of surface and underground facilities for the development of an efficient water distribution network in this region. Remote Sensing, Geographic Information Systems (GIS), Hydrographic Survey, and Geophysical Survey collectively referred to as geospatial technologies have been combined in different ways by developed nations to resolve challenges facing surface and underground facilities. This study, therefore, demonstrates the application of this technology in designing an efficient water distribution network for urban areas with undulating terrain. The spot heights dataset extracted from Light Detection and Ranging (LiDAR) satellite imagery offered the bases for the re-structure of the existing water distribution network map to accommodate the undulation of the topography. This was integrated into a GIS tool to synergize the topography with the radial and dead-end standard water distribution patterns. The result was a sub-division of the Enugu Urban Area into 12 zones with reservoirs at the most elevated points to facilitate water reticulation by gravity. The efficacy of this distribution network map was confirmed suitable with EPANET software.
起伏的地形继续加剧了埃努古城区管道供水的挑战。城市化的快速发展使这种情况更加恶化。因此,这要求部署能够支持有效规划地面和地下设施的系统,以便在该地区发展一个有效的配水网络。遥感、地理信息系统(GIS)、水文测量和地球物理测量统称为地理空间技术,发达国家以不同的方式将其结合起来,以解决地面和地下设施面临的挑战。因此,本研究展示了该技术在地形起伏的城市地区高效配水网络设计中的应用。光探测与测距(LiDAR)卫星图像提取的点高度数据集为现有配水网络图的重构提供了基础,以适应地形的波动。这被整合到一个GIS工具中,以协同地形与径向和死角标准水分布模式。其结果是将埃努古城区划分为12个区域,并在海拔最高的地方设有水库,以促进重力作用下的水网。通过EPANET软件验证了该配电网图的有效性。
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引用次数: 0
Self-adaptive metaheuristic optimization technique for multi-objective reservoir operation 水库多目标调度的自适应元启发式优化技术
IF 1.9 4区 环境科学与生态学 Q2 ENGINEERING, CIVIL Pub Date : 2023-08-09 DOI: 10.2166/aqua.2023.197
Vijendra Kumar, Kul Vaibhav Sharma, S. Yadav, Arpan Deshmukh
Multi-objective reservoir operation presents a number of critical challenges that must be overcome for efficient management of water resources. The inherent contradiction between several goals, such as satisfying irrigation demand and maximizing hydropower generation, is one of the major issues. Trade-offs and compromises must be carefully considered to balance these objectives. To solve this problem, a study was carried out to optimize the operation of multi-objective reservoirs with two primary goals: minimizing irrigation deficits and maximizing hydropower generation. This study employs the self-adaptive multipopulation multi-objective Jaya algorithm (SAMP-MOJA), an improved version of the Jaya algorithm, to construct an optimal Pareto Front utilizing an a priori approach. The performance of SAMP-MOJA is compared to that of other algorithms such as multi-objective particle swarm optimization, multi-objective invasive weed optimization, and multi-objective Jaya algorithm. The results of this study demonstrate that the hydropower generated by the developed model surpasses 80% of the actual generation. The study's findings will aid in designing the most effective Pareto front possible.
多目标水库运行提出了一些必须克服的关键挑战,以实现水资源的有效管理。满足灌溉需求和最大化水力发电等几个目标之间的内在矛盾是主要问题之一。必须仔细考虑权衡和妥协,以平衡这些目标。为解决这一问题,以灌溉亏缺最小和水力发电量最大为主要目标,开展了多目标水库优化调度研究。本文采用自适应多种群多目标Jaya算法(SAMP-MOJA),即Jaya算法的改进版本,利用先验方法构建最优Pareto Front。将SAMP-MOJA算法与多目标粒子群优化、多目标入侵杂草优化、多目标Jaya算法等算法进行性能比较。研究结果表明,所建模型的水力发电量超过实际发电量的80%。这项研究的发现将有助于设计最有效的帕累托前线。
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引用次数: 0
Sustainable green synthesis of ZnFe2O4@ZnO nanocomposite using Oleaster tree bark methanolic extract for photocatalytic degradation of aqueous humic acid in the presence of UVc irradiation uv照射下油橄榄树皮甲醇提取物光催化降解腐殖酸纳米复合材料ZnFe2O4@ZnO的可持续绿色合成
IF 1.9 4区 环境科学与生态学 Q2 ENGINEERING, CIVIL Pub Date : 2023-08-09 DOI: 10.2166/aqua.2023.313
M. Asri, A. Naghizadeh, A. Hasani, Sobhan Mortazavi, A. Javid, F. Masoudi
One of the most important humic substances in water is humic acid. These substances enter water sources through soils, sediments of aquatic animals, plants and sewage. Therefore, removing them from water sources is very important. In this study, the photocatalytic removal of humic acid was investigated using zinc ferrite nanoparticles loaded with zinc oxide (ZnFe2O4@ZnO). This research was conducted in an experimental-interventional way in a batch reactor on a laboratory scale. A novel and facile method was applied for catalyst synthesis in different conditions, and it was structurally and morphologically characterized by XRD, FT-IR, SEM, DLS and EDS mapping techniques. The effects of pH (3–11), nanoparticle dose (0.005–0.1 g/L), and humic acid concentration (2–15 mg/L) were examined up to 120 min of time. The results showed that the efficiency of humic acid degradation by ZnFe2O4@ZnO reached 95% in optimal conditions. Also, it was found that this nanocomposite has an acceptable reusability and recovery after being tested in five stages.
水中最重要的腐植酸物质之一是腐植酸。这些物质通过土壤、水生动物、植物的沉积物和污水进入水源。因此,将它们从水源中移除是非常重要的。在这项研究中,研究了负载氧化锌的铁酸锌纳米颗粒光催化去除腐植酸(ZnFe2O4@ZnO)。本研究是在实验室规模的间歇式反应器中以实验介入方式进行的。采用一种新颖、简便的方法在不同条件下合成催化剂,并通过XRD、FT-IR、SEM、DLS和EDS图谱等技术对催化剂进行了结构和形貌表征。考察pH(3-11)、纳米颗粒剂量(0.005-0.1 g/L)和腐植酸浓度(2-15 mg/L)在120 min内的影响。结果表明,在最佳条件下ZnFe2O4@ZnO对腐植酸的降解效率可达95%。经过5个阶段的测试,发现该纳米复合材料具有良好的可重用性和可恢复性。
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引用次数: 0
The sustainability of groundwater in semi-arid regions: the case of Makutupora Basin in Tanzania 半干旱地区地下水的可持续性:以坦桑尼亚马库图波拉盆地为例
IF 1.9 4区 环境科学与生态学 Q2 ENGINEERING, CIVIL Pub Date : 2023-08-08 DOI: 10.2166/aqua.2023.056
Z. H. Mseli, Alfred Said, G. Sankaranna, W. Mwegoha
Groundwater sustainability ensures groundwater development and uses to meet current and future beneficial purposes without causing unacceptable environmental, economic, or social consequences. In semi-arid regions, water resources are typically limited, and water management is critical to ensure a sustainable water supply. Groundwater sustainability indexing is vital for meaning groundwater management. The study used four indicators in six dimensions, i.e., quantitative and qualitative hydrogeology, environmental, social-economic, and political factors, to evaluate the sustainability of the aquifer in Makutupora basin, Dodoma, Tanzania. The resulting aquifer sustainability index is 0.59, with a 95% confidence interval between 0.3856 and 0.7944, showing that the aquifer is satisfactory sustainable. The hydrogeological analysis revealed that groundwater sustainability is promising, although groundwater use per capita is alarming. This study also recommends effective water management strategies, including improving water use efficiency, promoting water conservation, implementing policies to limit water withdrawals, and promoting alternative water sources such as recycled wastewater, especially for agricultural activities.
地下水的可持续性确保地下水的开发和使用满足当前和未来的有益目的,而不会造成不可接受的环境、经济或社会后果。在半干旱地区,水资源通常是有限的,水管理对于确保可持续供水至关重要。地下水可持续性指标对地下水管理意义重大。本研究利用水文地质、环境、社会经济、政治等6个维度的4个指标,对坦桑尼亚多马马库图波拉盆地含水层的可持续性进行了评价。所得含水层可持续性指数为0.59,95%置信区间在0.3856 ~ 0.7944之间,表明该含水层可持续性较好。水文地质分析显示,尽管人均地下水使用量令人担忧,但地下水的可持续性是有希望的。本研究还建议采取有效的水资源管理战略,包括提高水资源利用效率、促进节约用水、实施限制取水的政策以及推广利用再生废水等替代水源,特别是用于农业活动。
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引用次数: 0
Comprehensive evaluation of the effect of regional groundwater overexploitation restoration 区域地下水超采恢复效果综合评价
IF 1.9 4区 环境科学与生态学 Q2 ENGINEERING, CIVIL Pub Date : 2023-08-08 DOI: 10.2166/aqua.2023.041
M. Ling, Jiangyu Chen, Fei Liu, Lili Yu, Fengkai Li, Qinyuan Xia
The traditional groundwater overexploitation restoration only considers the impact on groundwater, on the basis of which, this paper also comprehensively considers the impact on economic society and the ecological environment. Based on analyzing the effect of groundwater overexploitation restoration on the groundwater–economic society–ecological environment (GESEE) system, an evaluation indicator system covering the GESEE system was constructed, an evaluation method for the effect of groundwater overexploitation restoration was established, and the effects were evaluated for Hebei Province, China, from 2014 to 2019. The results showed that the effect of groundwater overexploitation restoration in Hebei Province was obvious, and the grade of the groundwater overexploitation restoration effect improved from fair to good. The grade of the groundwater overexploitation restoration effect in most cities was improved to good. The measures that most affected the effect of groundwater overexploitation restoration in Hebei Province are strict control of extraction and reduction of consumption, while measures such as the replacement of water sources also play a significant role. An evaluation indicator system constructed in this paper can help to promote sophisticated effect evaluation of groundwater overexploitation restoration and improve the understanding and management of groundwater overexploitation restoration.
传统地下水超采修复只考虑对地下水的影响,在此基础上,本文还综合考虑了对经济、社会和生态环境的影响。在分析地下水超采修复对地下水-经济-社会-生态环境(GESEE)系统影响的基础上,构建了覆盖GESEE系统的评价指标体系,建立了地下水超采修复效果评价方法,并对河北省2014 - 2019年地下水超采修复效果进行了评价。结果表明:河北省地下水超采恢复效果明显,地下水超采恢复效果等级由一般提高到较好;大部分城市地下水超采恢复效果等级提高到良好。河北省地下水超采恢复效果影响最大的措施是严格控制采掘和减少耗用,水源替代等措施也发挥了重要作用。本文构建的评价指标体系有助于推进地下水超采恢复效果的精细评价,提高对地下水超采恢复的认识和管理。
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引用次数: 0
Recent advancement in NiFe2O4-based nanocomposites for the photocatalytic degradation of pollutants in aqueous solutions: a comprehensive systematic review nife2o4基纳米复合材料光催化降解水中污染物的研究进展
IF 1.9 4区 环境科学与生态学 Q2 ENGINEERING, CIVIL Pub Date : 2023-08-07 DOI: 10.2166/aqua.2023.316
E. Derakhshani, A. Naghizadeh
Nanocomposites have modified properties such as uniform size distribution, small size, high surface-to-volume ratio, high absorbability, porosity, and various potential roles, including in catalytic and biological activities. The purpose of this research study was to systematically review all research studies on the photocatalytic decomposition of pollutants by NiFe2O4-based nanocomposites and evaluate the optimal laboratory conditions and the results of these studies. The present systematic review was conducted by searching Scopus, PubMed, and Web of Science databases until March 2022. The parameters of nanocatalyst type and size, synthesis methods, pollutant type, optimal pH, optimal initial pollutant concentration, optimal catalyst concentration, optimal time, radiation, and removal efficiency were investigated. 454 studies were screened and using the inclusion and exclusion criteria, in total, 31 studies met our inclusion criteria and provided the information necessary for the photocatalytic degradation of pollutants by NiFe2O4-based nanocomposites. In the investigated studies, the percentage of photocatalytic degradation of pollutants by NiFe2O4-based nanocomposites was reported to be above 70%, and in some studies, the removal efficiency had reached 100%. From the results of this systematic review, it was concluded that the photocatalytic process using NiFe2O4-based nanocomposites has a high effect on the degradation of aqueous solution pollutants.
纳米复合材料具有尺寸分布均匀、体积小、高表面体积比、高吸附性、多孔性等特性,具有催化和生物活性等多种潜在作用。本研究的目的是系统地回顾了nife2o4基纳米复合材料光催化分解污染物的所有研究成果,并评价了这些研究的最佳实验室条件和结果。本系统评价是通过检索Scopus、PubMed和Web of Science数据库进行的,检索时间截止到2022年3月。考察了纳米催化剂类型和粒径、合成方法、污染物类型、最佳pH、最佳初始污染物浓度、最佳催化剂浓度、最佳时间、辐射和去除效率等参数。使用纳入和排除标准筛选了454项研究,总共有31项研究符合我们的纳入标准,为nife2o4基纳米复合材料光催化降解污染物提供了必要的信息。在所调查的研究中,有报道称nife2o4基纳米复合材料光催化降解污染物的百分比在70%以上,在一些研究中,去除率达到100%。本系统综述的结果表明,基于nife2o4的纳米复合材料的光催化工艺对水中污染物的降解具有很高的效果。
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引用次数: 0
Assessing flash flood inundation from extreme rainfall event: case study: Wadi Al Jizzi Oman 评估极端降雨事件造成的山洪泛滥:案例研究:阿曼阿尔吉兹河
IF 1.9 4区 环境科学与生态学 Q2 ENGINEERING, CIVIL Pub Date : 2023-08-07 DOI: 10.2166/aqua.2023.100
E. Abushandi, Moza Al Sarihi, O. Ibrahim
Flash floods present a significant risk to urbanized arid regions, and assessing their inundation patterns is crucial for effective disaster management. Extreme hydrologic events due to aridity and climate change are shaping human lives and major activities in numerous countries at an unprecedented pace. This study aims to assess flash floods from extreme storm events in an arid catchment using high-resolution data. The study applied two models on the event of a single storm, namely the IHACRES and AHP models. The observed flow was used for models' validation. The average flow output determined with the IHACRES model was approximately 0.47 m3/s while the flow output resulting from the AHP model was 0.45 m3/s. The efficiency showed that the IHACRES performed better in evaluating extreme events with an average of 0.88 while the AHP model showed an efficiency of 0.68. Nonetheless, the quantitative simulation outputs of both models are likely to have good applicability for simulating single storm events in arid catchments. The validated IHACRES and AHP models offer valuable tools for simulating flash flood. The study's outcomes have implications for flood management policy and infrastructure planning, ensuring a more resilient response to extreme flood events in arid regions globally.
山洪暴发给城市化干旱地区带来了重大风险,评估其淹没模式对有效的灾害管理至关重要。干旱和气候变化导致的极端水文事件正以前所未有的速度影响着许多国家的人类生活和重大活动。本研究旨在利用高分辨率数据评估干旱流域极端风暴事件引发的山洪暴发。本研究对单个风暴事件应用了两种模式,即ihaacres和AHP模式。观察到的流动被用于模型的验证。ihaacres模型确定的平均流量输出约为0.47 m3/s,而AHP模型确定的流量输出为0.45 m3/s。效率表明,IHACRES模型对极端事件的平均评价为0.88,AHP模型的平均评价效率为0.68。尽管如此,两种模式的定量模拟结果对于模拟干旱流域的单次风暴事件可能具有良好的适用性。经过验证的IHACRES和AHP模型为模拟山洪暴发提供了有价值的工具。该研究的结果对洪水管理政策和基础设施规划具有启示意义,从而确保对全球干旱地区的极端洪水事件作出更有弹性的反应。
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引用次数: 0
Reservoir operation management using a new hybrid algorithm of Invasive Weed Optimization and Cuckoo Search Algorithm 基于入侵杂草优化和布谷鸟搜索算法的水库调度管理
IF 1.9 4区 环境科学与生态学 Q2 ENGINEERING, CIVIL Pub Date : 2023-08-04 DOI: 10.2166/aqua.2023.106
M. Trivedi, R. Shrivastava
Water scarcity throughout the world has led to major difficulties and complexities in managing water demands. These challenges gravitate towards the development of efficient methods for optimal reservoir operation. The present study aims to introduce a hybrid approach which integrates Invasive Weed Optimization (IWO) and Cuckoo Search Algorithm (CSA), with an objective to minimize the deficits for Indira Sagar Reservoir (ISR), India. To prevail over the limitations of the Weed Optimization Algorithm (WOA) and CSA, a critical comparison has been made in the study. The hybrid approach has improved the performance by 5 and 9% as compared to WOA and CSA, respectively. For the reservoir system, the Cv for 10 random runs was computed to be 0.0303 using the hybrid model, whereas for WOA and CSA, Cv was 0.22034 and 0.30698, respectively. Based on the performance measuring indices, results revealed that the hybrid model is more reliable and sustainable with the minimum error between release and demand. In addition, results reveal that the deficits have been reduced by 62% on average for the considered study period using the hybrid approach. Therefore, the results show that the proposed hybrid model has considerable potential to be used as an optimizer for complex reservoir operation problems.
世界各地的水资源短缺给管理用水需求带来了重大困难和复杂性。这些挑战促使开发有效的方法来优化油藏作业。本研究旨在介绍一种结合入侵杂草优化(IWO)和布谷鸟搜索算法(CSA)的混合方法,以最大限度地减少印度Indira Sagar水库(ISR)的损失。为了克服杂草优化算法(WOA)和CSA算法的局限性,在研究中进行了关键的比较。与WOA和CSA相比,混合方法的性能分别提高了5%和9%。对于储层系统,使用混合模型计算出10次随机运行的Cv为0.0303,而WOA和CSA的Cv分别为0.22034和0.30698。基于性能度量指标,结果表明该混合模型具有更强的可靠性和可持续性,且释放与需求之间的误差最小。此外,结果显示,在考虑的研究期间,使用混合方法的赤字平均减少了62%。结果表明,该混合模型在复杂油藏运行问题的优化方面具有较大的应用潜力。
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引用次数: 1
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