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Effects of raw water quality on the adsorptive removal of 2-methylisoborneol by powdered activated carbon under non-equilibrium conditions 原水水质对非平衡条件下粉状活性炭吸附去除2-甲基异龙脑的影响
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-05-17 DOI: 10.2166/aqua.2023.077
Yasuhiro Asada, Shunichi Hayasaka, T. Miyoshi, Marina Tokuyasu, M. Akiba
Natural organic matter contained in natural water inhibits the adsorptive removal of 2-methylisoborneol (2-MIB) by powdered activated carbon (PAC). We investigated the relationship between water-quality indices and the adsorptive removal of 2-MIB by PAC. We collected three different raw water (i.e., two lake water and one river water) samples twice per month for 10 months. We characterized the raw water using total organic carbon concentration, ultraviolet absorption at 254 nm, electrical conductivity, and excitation–emission matrix analysis. The results were compared with 2-MIB removal rates evaluated from PAC adsorption experiments and revealed that there was no universal indicator that could explain the trends of the 2-MIB removal rate during the overall experimental period. The correlation trends between 2-MIB removal rates and water-quality indices differed significantly between the high and low water-temperature periods. Several water-quality indices related to the organic matter associated with biological processes, especially algal activities (i.e., soluble microbial products, chlorophylls, and phycocyanin), exhibited strong correlations with the 2-MIB removal rates (|R| > 0.7) under certain conditions (e.g., high lake-water temperature). Both the parallel factor (PARAFAC) analysis and fluorescence regional integration (FRI) method could evaluate such behaviors after including the regions associated with algal organic matter in the calculation.
天然水中含有的天然有机物抑制了粉状活性炭(PAC)对2-甲基异龙脑(2-MIB)的吸附去除。我们研究了水质指标与PAC吸附去除2-MIB之间的关系。我们每月两次收集三种不同的原水(即两种湖水和一种河水)样品,持续10个月。我们利用总有机碳浓度、254 nm紫外吸收、电导率和激发发射矩阵分析对原水进行了表征。将结果与PAC吸附实验评估的2-MIB去除率进行比较,发现没有通用指标可以解释整个实验期间2-MIB去除率的趋势。2-MIB去除率与水质指标的相关趋势在高、低水温时期差异显著。与生物过程相关的有机物有关的几个水质指标,特别是藻类活动(即可溶性微生物产物、叶绿素和藻蓝蛋白),在某些条件下(如高湖水温),与2-MIB去除率(|R| > 0.7)表现出很强的相关性。平行因子分析法(PARAFAC)和荧光区域积分法(FRI)在计算中加入与藻类有机质相关的区域后,都可以评价藻类的这种行为。
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引用次数: 0
Effect of vegetation on flow hydraulics in compound open channels with non-prismatic floodplains 植被对非棱柱形洪泛平原复合明渠水流水力学的影响
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-05-11 DOI: 10.2166/aqua.2023.043
A. S. Rahim, H. Yonesi, H. Rahimi, B. Shahinejad, H. T. Podeh, H. M. Azamattulla
The present paper aims to evaluate the effect of emergent rigid vegetation density on the flow's turbulence structure and hydraulic parameters at the non-prismatic floodplains. The experiments were performed using the physical model of the asymmetric non-prismatic compound channel. The results show that the velocity distribution in the vegetation flow is more influenced by the drag force caused by the vegetation than by the bed shear stress and does not follow the law of logarithmic velocity distribution throughout the non-prismatic section. The intense velocity gradient at the interface of the main channel and the floodplain leads to the development of strong secondary currents, increased Reynolds shear stresses, apparent shear stresses and momentum exchange in this region. Vegetation also decreases mean kinetic energy in the floodplain and increases it in the main channel. The mean turbulence exchange coefficient for the non-prismatic compound channels without vegetation was 0.23 and for the divergent and convergent compound channels was 0.035 and 0.020, respectively. The comparison of the local drag coefficient results shows that the fluctuations of this parameter are greater in the divergent section than in the convergent section due to the strong secondary currents in the interface.
本文旨在评价非棱柱形洪泛区突发性刚性植被密度对水流湍流结构和水力参数的影响。实验采用非对称非棱柱形复合通道的物理模型进行。结果表明:植被流的速度分布受植被阻力的影响大于河床剪应力的影响,且在非棱柱剖面上不遵循对数速度分布规律;主河道与漫滩交界处的速度梯度较大,导致该区域次级流发育强烈,雷诺剪应力、视剪应力和动量交换增大。植被降低了河漫滩的平均动能,增加了主河道的平均动能。无植被的非棱柱形复合通道湍流交换系数均值为0.23,发散型和收敛型复合通道湍流交换系数均值分别为0.035和0.020。局部阻力系数结果的比较表明,由于界面中有较强的二次流,该参数在发散截面的波动要大于收敛截面。
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引用次数: 1
Optimization of batch study parameters for the adsorption of lead(II) ions onto spent tea grains 茶渣吸附铅(II)离子的批量研究参数优化
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-05-11 DOI: 10.2166/aqua.2023.020
S. Chauhan, P. Dikshit
The present study aims to investigate the use of response surface methodology (RSM) modelling and experimental investigation for the optimization of lead(II) adsorption onto spent tea grains (STG). Independent process variables were optimized and found to be in the range of 38.75 mg/l (initial concentration), 5.20655 (pH), 119.32 rpm (stirring speed), and 3.25 g/l (STG dose) for a contact time of 135.05 min. The optimum adsorption capacity was found to be 8.9087 mg/g through RSM modelling with a maximum of 18.146 mg/g. The batch study was performed by varying different parameters: pH (2.0–7.0), initial concentration (5–50 mg/l), dose (0.1–1 g/100 ml), contact time (15–180 min), and stirring speed (30–200 rpm). The characterization STG was done by proximate and ultimate analysis, Fourier Transform Infrared (FTIR) Spectroscopy, X-ray diffraction (XRD) analysis, thermogravimetric analysis (TGA), and SEM-EDX. By fitting equilibrium data for lead(II) ions adsorption onto STG using the Langmuir isotherm model, the maximum adsorption capacity was found to be 24.272 mg/g. The optimum pH found for lead(II) adsorption onto STG was 5. At optimum conditions, the maximum removal efficiency of STG for lead(II) ions’ adsorption is 94.33%. Based on the findings it is safe to conclude that the STG could be used as a potential adsorbent.
本研究旨在利用响应面法(RSM)建模和实验研究优化铅(II)在废茶颗粒(STG)上的吸附。在接触时间为135.05 min的条件下,对独立的工艺变量进行了优化,分别为38.75 mg/l(初始浓度)、5.20655 mg/l (pH)、119.32 rpm(搅拌速度)和3.25 g/l (STG剂量),通过RSM建模得到最佳吸附量为8.9087 mg/g,最大吸附量为18.146 mg/g。通过pH(2.0-7.0)、初始浓度(5-50 mg/l)、剂量(0.1-1 g/100 ml)、接触时间(15-180 min)、搅拌速度(30-200 rpm)进行批量研究。通过近似和极限分析、傅里叶变换红外(FTIR)光谱、x射线衍射(XRD)分析、热重分析(TGA)和SEM-EDX对STG进行了表征。利用Langmuir等温线模型拟合STG吸附铅离子的平衡数据,得到STG的最大吸附量为24.272 mg/g。STG吸附铅(II)的最佳pH为5。在最佳条件下,STG对铅(II)离子的最大去除率为94.33%。基于这些发现,可以有把握地得出结论,STG可以作为一种潜在的吸附剂。
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引用次数: 0
Design and modeling of vertical tube evaporator in a thermal-driven multiple effect distillation system 热驱动多效蒸馏系统中垂直管式蒸发器的设计与建模
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-05-10 DOI: 10.2166/aqua.2023.116
Pravesh Chandra, A. Mudgal, J. Patel
The scarcity of freshwater is one of the biggest issues in the world, as a result of which more attention is given to the thermal distillation process for seawater and as well as brackish water distillation which removes almost all types of contaminants. Distillation is a phase change process in which steam is used as a heat source for evaporating the feed water. Multiple-effect distillation makes the process economical by recycling the latent heat of vaporization. In this paper, the vertical tube evaporator (VTE) design and modeled for MED for estimating the overall heat transfer coefficient by using the developed correlations of the Bell method, Kandlikar, and Kutateladze and compared its previous work in literature. The result shows good agreement with previous work and reliability in design. The developed model can be used to design the VTE for estimating the dimension for large-scale to micro-scale MED plant.
淡水短缺是世界上最大的问题之一,因此人们越来越关注海水的热蒸馏过程,以及去除几乎所有类型污染物的微咸水蒸馏。蒸馏是一种相变过程,其中蒸汽被用作热源来蒸发给水。多效蒸馏通过回收汽化潜热,使蒸馏过程经济。本文采用Bell方法、Kandlikar方法和Kutateladze方法建立了垂直管式蒸发器(VTE)的总体传热系数估算模型,并比较了前人的研究成果。计算结果与前人的工作结果吻合良好,设计可靠。所建立的模型可用于大型到微型MED装置尺寸估计的VTE设计。
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引用次数: 0
Development of suitability map for managed aquifer recharge: case study, West Delta, Egypt 开发含水层补给管理的适宜性图:案例研究,埃及西三角洲
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-05-10 DOI: 10.2166/aqua.2023.177
Heba Mohamed Hani, Mohamed M. Nour El Din, A. Khalifa, Ezzat Elalfy
Managed aquifer recharge (MAR) is considered an innovative method for storing water in the subsurface. In this work, multi-criteria decision analysis (MCDA) was used to delineate potential groundwater recharge areas for MAR implementation in Western Delta using reclaimed wastewater. By employing geographical information systems (GIS) and pairwise comparison matrix (PCM), a modified approach was utilized for the development of the suitability map by capturing the interlinkages between a specified MAR technique (spreading methods) and MAR suitability mapping processes. The developed approach was created with a range of constraining and factorial considerations. Based on the findings, MAR potential recharge zones included four main suitability classes. The presence of high-suitability areas was mainly delineated in the northeast part, particularly around the left side of the Nile River valley. Areas of low suitability were located around the west-north side where the hydrological criterion seems to hinder the implementation due to the low productivity of the hydrogeologic layer. The developed methodology reflected the importance of specific determining factors (i.e., slope and depth to depth to the water table) that govern the successful implementation of infiltration basins and maximize the benefits from soil aquifer treatments effects when taken into account with other hydrogeological and socio-economic variables.
含水层管理补给(MAR)被认为是地下蓄水的一种创新方法。在这项工作中,采用多准则决策分析(MCDA)来划定西部三角洲利用再生废水实施MAR的潜在地下水补给区。利用地理信息系统(GIS)和配对比较矩阵(PCM),通过捕捉特定的MAR技术(传播方法)与MAR适宜性制图过程之间的相互联系,采用一种改进的方法来开发适宜性图。开发的方法是在考虑了一系列约束和因子的情况下创建的。根据研究结果,MAR潜在补给区包括四个主要的适宜性等级。高适宜性区主要分布在东北部,尤其是尼罗河流域左侧。低适宜性区域位于西北侧附近,由于水文地质层的低生产力,水文标准似乎阻碍了实施。所制订的方法反映了具体的决定因素(即地下水位的坡度和纵深)的重要性,这些因素在考虑到其他水文地质和社会经济变量的情况下,决定了渗透盆地的成功实施和土壤含水层处理效果的最大效益。
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引用次数: 0
Heavy metals in agricultural cultivated products irrigated with wastewater in India: a review 印度废水灌溉农产品重金属研究进展
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-05-10 DOI: 10.2166/aqua.2023.122
B. Mohanty, Anirban Das
Indiscriminate industrialization and urbanization have negatively impacted our environment. One of the common environmental problems in semi-urban areas in India is the discharge of inefficiently treated municipal, industrial, and domestic wastewater into the environment, resulting in the degradation of soil and water qualities. Depleting freshwater resources have led Indian farmers to look for an easily available, cheaper, and nutrient-rich source of irrigation water in the form of wastewater; however, this also led to increased pollutant transfer to the soils. Known as persistent pollutants, heavy metals such as cadmium (Cd), copper (Cu), chromium (Cr), lead (Pb), mercury (Hg), and a few others are potentially hazardous due to their nonbiodegradable nature, extended biological half-lives, and biological interactions. These heavy metals can bind to soil surfaces and then be absorbed by plant tissues.
不加区分的工业化和城市化对我们的环境造成了负面影响。印度半城市地区常见的环境问题之一是将未经有效处理的市政、工业和家庭废水排放到环境中,导致土壤和水质退化。淡水资源的枯竭促使印度农民以废水的形式寻找一种容易获得、更便宜、营养丰富的灌溉水源;然而,这也导致了污染物向土壤转移的增加。镉(Cd)、铜(Cu)、铬(Cr)、铅(Pb)、汞(Hg)等重金属被称为持久性污染物,由于其不可生物降解的性质、延长的生物半衰期和生物相互作用,它们具有潜在的危害。这些重金属可以附着在土壤表面,然后被植物组织吸收。
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引用次数: 2
Magnetic nanocomposites prepared from red mud and durian husk as an effective bio-adsorbent for methylene blue adsorption 以红泥和榴莲壳为原料制备的磁性纳米复合材料对亚甲基蓝的有效吸附
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-05-09 DOI: 10.2166/aqua.2023.051
N. Bui, T. Hoang, P. N. Nguyen, Nguyen Le My Linh, Q. Trieu, T. H. Bui
An increasing interest in nanocomposites prepared from agricultural/industrial byproducts has been paid for environmental remediation, especially in water treatment. This study reports the facile preparation of a low-cost magnetic biocomposite of magnetic Fe3O4 nanoparticles (NPs) incorporated with biopolymers extracted from durian husk, called bp-Fe3O4 and examined in the removal of methylene blue (MB) dye. Here, Fe2O3 NPs were first recovered from red mud waste and then converted to magnetic nanostructured Fe3O4 using a one-pot process via carbon combustion. The bp-Fe3O4 inherited the characteristics of each constituent component, while showing slightly higher saturation magnetization than the bare Fe3O4 NPs (19.84 and 18.66 emu/g, respectively), allowing for easy separation from the aqueous solution using a suitable magnet. The MB adsorption on bp-Fe3O4 reached an equilibrium state within 60 min reaction and achieved >90% of removal (at 50 mg/L MB) at an optimal pH range of 6–8. The effective adsorption of MB dye was attributed to both the hydroxylated-Fe3O4 NPs and biopolymers. The material showed excellent reusability tested up to the seventh MB adsorption cycle (decreased by <2% of adsorption efficiency). Overall, the outstanding magnetic properties and low-cost bp-Fe3O4 rendered them easily manipulated and separated, and reusable for water/wastewater treatment of MB dye.
从农业/工业副产品制备纳米复合材料的兴趣日益增加,用于环境修复,特别是水处理。本研究报道了一种低成本的磁性Fe3O4纳米颗粒(NPs)与从榴莲壳中提取的生物聚合物(bp-Fe3O4)结合的磁性生物复合材料的制备,并对其去除亚甲基蓝(MB)染料进行了研究。本研究首先从赤泥废料中回收Fe2O3 NPs,然后利用碳燃烧一锅法将其转化为磁性纳米Fe3O4。bp-Fe3O4继承了各组成成分的特性,同时表现出比裸Fe3O4 NPs略高的饱和磁化强度(分别为19.84和18.66 emu/g),允许使用合适的磁铁易于从水溶液中分离。在6 ~ 8的最佳pH范围内,bp-Fe3O4对MB的吸附在60 min内达到平衡状态,在50 mg/L MB的条件下,MB的去除率达到90%。羟基化fe3o4 NPs和生物聚合物对MB染料的有效吸附作用。该材料在第7次MB吸附循环中表现出良好的可重复使用性(吸附效率下降<2%)。总体而言,bp-Fe3O4优异的磁性能和低成本使其易于操作和分离,并且可重复用于MB染料的水/废水处理。
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引用次数: 0
Hydraulic optimization simulation for reducing confluence and controlling the overflow pollution of storage ponds based on the Storm Water Management Model and Non-dominated Sorting Genetic Algorithm-II 基于雨水管理模型和非支配排序遗传算法的蓄水池降合流控制溢流污染的水力优化仿真——ⅱ
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-05-09 DOI: 10.2166/aqua.2023.195
Cuntian Jin
The Storm Water Management Model (SWMM) was established to simulate rainfall–runoff dynamically, and the internal runoff component of the SWMM was used to simulate rainfall operation in each watershed, including rainfall–runoff and scour pollution load. Then, using the routing component in the SWMM, the properties of runoff into the tank system are calculated through pipelines and other facilities to obtain the optimal tank volume. The coupling optimization model was established, and the algebraic function of the storage capacity, total runoff, and total cost was established by using the multiple linear regression method, which was transformed into the optimization model aiming at the minimum total runoff and total cost. The NSGA-II is improved by using a reverse learning mechanism. By solving the optimization model, the non-dominant solution of the proxy model is obtained. The non-dominant solution was substituted into the SWMM, and the rationality of the optimization results was analyzed. The experimental results show that the reservoir volume determined by this method can effectively accept the pollutants brought by the initial rain, so as to reduce the hydraulic pollution caused by the confluence overflow and the overflow pollution of the urban integrated pipe network.
建立了动态模拟降雨径流的暴雨水管理模型(SWMM),并利用SWMM的内部径流分量模拟各流域的降雨运行,包括降雨径流和冲刷污染负荷。然后,利用SWMM中的路由组件,通过管道和其他设施计算进入储罐系统的径流的特性,以获得最佳储罐容积。建立了耦合优化模型,利用多元线性回归方法建立了库容、总径流量和总成本的代数函数,并将其转化为以总径流量和总成本最小为目标的优化模型。NSGA-II通过使用反向学习机制得到改进。通过求解优化模型,得到了代理模型的非主导解。将非优势解代入SWMM,分析了优化结果的合理性。实验结果表明,该方法确定的水库容积能够有效地接受初雨带来的污染物,从而减少汇流溢流造成的水力污染和城市综合管网溢流污染。
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引用次数: 0
Study of acidic air pollutant (SO2 and NO2) tolerance of microalgae with sodium bicarbonate as growth stimulant 碳酸氢钠促生长微藻对酸性空气污染物(SO2和NO2)的耐受性研究
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-05-06 DOI: 10.2166/aqua.2023.013
Saurabh Srivastava, P. J. Omar, Shiwanshu Shekhar, Sneha Gupta
The major environmental toxicity of acidic pollutant in the fossil fuel gas substances has long been well known. Macro and microalgae are biological sources with large range of biotechnological uses, for e.g., bioremediation, bio-fuel, air pollutant absorber, and many more. This study addressing the use of Chlamydomonas sp. an effective biomaterial in their tolerance against 2 and 5% of the SO2 & NO2. Improve their growth kinetics by the addition of sodium bicarbonate to the culture conical media. SO2 and NO2 were provided to culture media by the use of Sodium meta-bisulfite and Nitrous acid. The control combination of SO2 and NO2 is providing: 2% SO2, 5% SO2, 2% NO2, 5% NO2, (2% SO2 + 2% NO2), (5% SO2 + 5% NO2) at the seventh day of incubation. The optimum pH ranges in between 7.1 and 8.6 when the exposure of the gas. Results suggested that the growth kinetics of Chlamydomonas sp. is greater in SO2 and some low in the 5% exposure of NO2. The maximum absorbing concentration of SO2 and NO2 was 921.625 μg/ml and 906.25 μg/ml respectively for Chlamydomonas sp. This work highlighting the potential of algae in tolerance to NO2 & SO2 from the polluted air.
化石燃料气体物质中酸性污染物的主要环境毒性早已为人所知。巨藻和微藻是具有广泛生物技术用途的生物资源,例如,生物修复、生物燃料、空气污染物吸收剂等等。本研究探讨了衣藻对2%和5% SO2和NO2的耐受性的有效生物材料。通过在锥形培养基中添加碳酸氢钠来改善它们的生长动力学。利用亚亚硫酸氢钠和亚硝酸向培养基中提供SO2和NO2。在培养第7天,SO2和NO2的对照组合为:2% SO2、5% SO2、2% NO2、5% NO2、(2% SO2 + 2% NO2)、(5% SO2 + 5% NO2)。当气体暴露时,最佳pH值范围在7.1至8.6之间。结果表明,衣藻在SO2条件下生长动力学较大,在5% NO2条件下生长动力学较低。衣藻对SO2和NO2的最大吸收浓度分别为921.625 μg/ml和906.25 μg/ml,说明了藻类对污染空气中NO2和SO2的耐受潜力。
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引用次数: 0
Persistence of heavy metals and human health risk assessment in the South Indian industrial area 南印度工业区重金属持续存在与人类健康风险评估
IF 1.9 4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-05-05 DOI: 10.2166/aqua.2023.210
K. Arunakumari, Farveen Begum, L. Surinaidu, M. J. Nandan, Umamaheswari Alapati
The present study provided a comprehensive evaluation of heavy metal contamination from soil to groundwater and the associated risk to human health in an industrial area situated in Telangana state, South India. Soils at three depth levels (0, 20, and 80 cm) and groundwater samples at 32 locations have been collected in the area. The samples have been analyzed for trace metals (Mn, B, Zn, Cr, Pb, Ni, Hg, Cd, and As) to understand the heavy metal contamination. Furthermore, geo-accumulation (Igeo) of heavy metals, contamination factor, pollution index, and human health risks due to prolonged exposure to contaminated water are estimated. The results indicated that soils are moderately contaminated at 18.5, 25.9, 7.4, 14.8, and 7.1% of locations by B, Zn, Cr, Pb, Ni, and Cd, respectively, as per Igeo at 80-cm depth. However, the contamination factor indicated that 14.8% of the locations were contaminated by Mn and Zn and 7.4, 70.3, 66.6, 74, and 3.7% by B, Cr, Pb, Ni, and Cd, respectively. However, groundwater is only contaminated when groundwater levels are less than 3 m below ground level. The results also indicated higher carcinogenetic health risks if groundwater is used for a longer time.
本研究对位于印度南部特伦甘纳邦的一个工业区从土壤到地下水的重金属污染及其对人类健康的相关风险进行了全面评价。在该地区收集了三个深度(0、20和80厘米)的土壤和32个地点的地下水样本。对样品进行了微量金属(Mn, B, Zn, Cr, Pb, Ni, Hg, Cd和As)分析,以了解重金属污染情况。此外,还估计了重金属的地质累积(Igeo)、污染因子、污染指数以及长期暴露于受污染的水所造成的人类健康风险。结果表明,在80 cm深度,18.5%、25.9%、7.4、14.8%和7.1%的土壤受到B、Zn、Cr、Pb、Ni和Cd的中度污染。然而,污染因子表明,14.8%的地点受到Mn和Zn的污染,7.4、70.3、66.6、74和3.7%的地点受到B、Cr、Pb、Ni和Cd的污染。然而,地下水只有在地下水位低于地面3米时才会受到污染。研究结果还表明,地下水使用时间越长,致癌健康风险越高。
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引用次数: 0
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