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How suitable is the gold-labelling method for the quantification of nanoplastics in natural water? 金标法对天然水中纳米塑料的定量是否合适?
4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-11-13 DOI: 10.2166/aqua.2023.278
Februriyana Pirade, Kim Lompe, Javier Jimenez-Lamana, Sulalit Bandyopadhyay, Katharina Zürbes, Nesrine Bali, Dušan Materić, Jan Willem Foppen
Abstract Nanoplastics are detected in surface water, yet accurately quantifying their particle number concentrations remains a significant challenge. In this study, we tested the applicability of a gold-labelling method to quantify nanoplastics in natural organic matter (NOM) containing water matrices. Gelatin-coated gold nanoparticles (Au-gel NPs) form conjugates with nanoplastics via electrostatic interaction which produces peak signals which can be translated into particle number concentration using single-particle inductively coupled plasma–mass spectrometry (SP-ICP-MS). We used water samples with various NOM concentrations, with and without the addition of 1 × 107 particles L−1 nanoplastics. Our results indicate that nanoplastics in low NOM samples (<1 mg·C L−1) could be successfully quantified. However, in high NOM samples (>15 mg·C L−1), only 13–19% of added nanoplastics were successfully quantified. Further digestion to remove NOM yielded only 10% of spiked nanoplastics. This discrepancy in high NOM samples could likely be attributed to the competition between nanoplastics and NOM existing in the water sample to bind with Au-gel NPs. Our study highlights the suitability of the Au-gel labelling method for quantifying nanoplastics in low NOM water samples. Nevertheless, further optimization, including pre-digestion steps, is essential to apply this method for high NOM water samples effectively.
摘要在地表水中检测到纳米塑料,但准确定量其颗粒数浓度仍然是一个重大挑战。在这项研究中,我们测试了金标记方法在含水基质的天然有机物质(NOM)中量化纳米塑料的适用性。明胶包覆的金纳米粒子(Au-gel NPs)通过静电相互作用与纳米塑料形成偶联物,产生峰值信号,可通过单粒子电感耦合等离子体质谱(SP-ICP-MS)转化为粒子数浓度。我们使用了不同浓度的水样,分别添加和不添加1 × 107个L−1纳米塑料颗粒。我们的研究结果表明,低NOM样品(<1 mg·C L−1)中的纳米塑料可以成功地定量。然而,在高NOM样品(>15 mg·C L−1)中,只有13-19%添加的纳米塑料被成功定量。进一步消化去除NOM只产生了10%的加标纳米塑料。高NOM样品中的这种差异可能归因于纳米塑料与水样中存在的NOM之间的竞争,以与金凝胶NPs结合。我们的研究强调了金凝胶标记方法在低NOM水样中定量纳米塑料的适用性。然而,进一步的优化,包括预消化步骤,是必要的,以有效地将该方法应用于高NOM水样。
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引用次数: 0
Biogas production from water lilies, food waste, and sludge: substrate characterization and process performance 睡莲、食物垃圾和污泥的沼气生产:基质特性和工艺性能
4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-11-13 DOI: 10.2166/aqua.2023.242
Mohammad Aasif Khaja, Shagoofta Rasool Shah, Abas Ahmad, Asiya Khursheed, Shiv Malani
Abstract The potential of water lilies, food waste, and sludge as substrates for biogas production through anaerobic digestion was investigated. We thoroughly characterized these substrates and found that water lilies had a pH of 6.4, total solids (TS) of 18.42%, volatile solids (VS) of 81.46%, and a moisture content of 87%. Food waste exhibited a pH of 7.6, TS at 27.23%, VS at 90.6%, and a moisture content of 75%. Sludge had a pH of 6.5, TS of 6%, VS of 60%, and a moisture content of 95%. Biogas production exhibited variations among the reactors. Reactor 1 reached a cumulative production of 2,527 mL, while Reactor 4 achieved 3,404 mL, with different lag phases. Reactor 4 displayed the highest biogas yield at 262 mL/g VS. Post-digestion tests confirmed efficient digestion, with volatile fatty acids ranging from 140 to 300 mg/L acetic acid and alkalinity levels between 800 and 1,500 mg CaCO3/L. Our study estimated a significant methane content, with the potential to produce 94.32 L of methane from 1 kg of TS.
摘要研究了睡莲、食物垃圾和污泥作为厌氧消化产气底物的潜力。结果表明,睡莲的pH值为6.4,总固形物(TS)为18.42%,挥发性固形物(VS)为81.46%,水分含量为87%。食物垃圾的pH值为7.6,TS为27.23%,VS为90.6%,水分含量为75%。污泥pH为6.5,TS为6%,VS为60%,水分含量为95%。不同反应器的沼气产量存在差异。反应器1的累积产量为2,527 mL,而反应器4的累积产量为3,404 mL,具有不同的滞后期。反应器4显示出最高的沼气产量为262 mL/g,消化后测试证实了有效的消化,挥发性脂肪酸范围为140至300 mg/L乙酸,碱度水平为800至1,500 mg CaCO3/L。我们的研究估计了大量的甲烷含量,从1公斤TS中产生94.32升甲烷的潜力。
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引用次数: 0
Exploring the rise of AI-based smart water management systems 探索基于人工智能的智能水管理系统的兴起
4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-11-10 DOI: 10.2166/aqua.2023.005
Padam Jee Omar, Pankaj Gupta, Qi Wang
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引用次数: 0
Corrigendum: AQUA – Water Infrastructure, Ecosystems and Society 72 (7), 1115–1129: Application of system dynamics model for reservoir performance under future climatic scenarios in Gelevard Dam, Iran, Ali Babolhakami, Mohammad Ali Gholami Sefidkouhi and Alireza Emadi, https://dx.doi.org/10.2166/aqua.2023.193 [j] .中国水利水电工程,2014,(2):1 - 2 .气候变化对三峡库区生态系统的影响
4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-11-10 DOI: 10.2166/aqua.2023.206
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引用次数: 0
Phyto-assisted synthesis of magnetic NiFe2O4 nanocomposite using the Pulicaria gnaphalodes methanolic extract for the efficient removal of an antibiotic from the aqueous solution: a study of equilibrium, kinetics, isotherms, and thermodynamics 植物辅助合成磁性NiFe2O4纳米复合材料,利用白芍甲醇提取物从水溶液中有效去除抗生素:平衡、动力学、等温线和热力学的研究
4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-11-09 DOI: 10.2166/aqua.2023.117
Elham Derakhshani, Ali Naghizadeh, Sobhan Mortazavi-Derazkola
Abstract In this research, the magnetic NiFe2O4 nanocomposite was synthesized using Pulicaria gnaphalodes methanolic extract and applied to remove penicillin G from aqueous solutions. The results of field emission scanning electron microscopy, X-ray powder diffraction, Fourier transform infrared, VSM, and energy-dispersive spectroscopy-mapping analyses showed that this nanocomposite was well synthesized with a size of approximately 50–70 nm. The maximum adsorption capacity of the magnetic NiFe2O4 nanocomposite was 22.95 mg/g under optimal conditions. In addition, the experimental data of penicillin G adsorption by the magnetic NiFe2O4 nanocomposite showed that ΔH and ΔS values were positive and ΔG was negative and were following the Temkin isotherm model with R2 = 0.99 and follows the pseudo-second-order kinetic model.
摘要本研究以白芍甲醇提取物为原料制备了磁性纳米NiFe2O4复合材料,并将其用于去除青霉素G。场发射扫描电镜、x射线粉末衍射、傅里叶变换红外、VSM和能量色散谱图分析结果表明,该纳米复合材料的合成效果良好,尺寸约为50-70 nm。在最佳条件下,磁性NiFe2O4纳米复合材料的最大吸附容量为22.95 mg/g。此外,磁性NiFe2O4纳米复合材料吸附青霉素G的实验数据表明,ΔH和ΔS为正,ΔG为负,符合R2 = 0.99的Temkin等温线模型,符合拟二级动力学模型。
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引用次数: 0
Unraveling air–water two-phase flow patterns in water pipelines based on multiple signals and convolutional neural networks 基于多信号和卷积神经网络的输水管道空气-水两相流动模式研究
4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-11-09 DOI: 10.2166/aqua.2023.319
Peng Zhao, Ziyang Xu, Haixing Liu, Bing Yu
Abstract Flow pattern identification (FPI) is crucial for evaluating air entrapment in water pipelines and ensuring the safety of pipeline operations. The presence of two-phase flow in water pipelines not only leads to pressure fluctuations but also induces pipeline vibration. However, current research has primarily focused on using pressure-related signals for FPI, and the analysis of vibration signals in FPI is rare. In this study, FPI in water pipelines is investigated based on convolutional neural networks (CNNs) using high-frequency vibration signals. The information fusion of vibration signals in FPI is newly proposed via the stacked generalization technique. The proposed method is compared with pressure signal-based FPI methods and the effect of signal sampling parameters on FPI accuracy is discussed. The results show that the performance of vibration signals (including axial or radial acceleration signals) outperforms pressure signals in both time and frequency domains. Moreover, the fusion of vibration signals shows the superior results compared to any univariate signals. The duration of sampling has a more significant impact on the results of FPI than the sampling frequency. This study provides a new way that FPI theory is applied to solve air entrapment evaluation in water pipelines.
摘要流型识别(FPI)是评价输水管道夹带气量、保证管道运行安全的重要手段。输水管道中两相流的存在不仅会引起压力波动,还会引起管道振动。然而,目前的研究主要集中在将压力相关信号用于FPI,而对FPI中振动信号的分析很少。本文研究了基于卷积神经网络(cnn)的高频振动信号在输水管道中的FPI。利用叠加泛化技术,提出了FPI中振动信号的信息融合方法。将该方法与基于压力信号的FPI方法进行了比较,讨论了信号采样参数对FPI精度的影响。结果表明,振动信号(包括轴向或径向加速度信号)在时域和频域的性能都优于压力信号。此外,与任何单变量信号相比,振动信号的融合效果更好。采样时间比采样频率对FPI结果的影响更为显著。本研究为利用FPI理论解决输水管道夹持气评价提供了一条新途径。
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引用次数: 0
An angle-based leak detection method using pressure sensors in water distribution networks 基于角度的配水管网压力传感器泄漏检测方法
4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-11-09 DOI: 10.2166/aqua.2023.202
Huimin Yu, Hua Zhou, Xiaodan Weng, Zhihong Long, Yu Shao, Tingchao Yu
Abstract Leak detection has significant implications for the long-term stable operation of water distribution networks (WDNs). This study presented a novel leak detection method by calculating the angular variance between a pressure vector and other vectors in the database, to evaluate the presence of an anomaly in a network. The top priority for this method was to establish a reliable dataset collected from the pressure sensors, which is generated by EPANET 2.2. Numerous node water demand data in normal conditions were generated by the Monte Carlo method, and leak conditions with various leak flows were simulated by creating leak holes in the pipes. Through learning the composite normal and abnormal data in a certain proportion, the angle-based outlier detection model was employed to identify abnormal events. This angle-based method was applied in an actual WDN and the identification performance for anomalies was compared with that of previous detection methods. The results indicated that the novel method proposed in this study could significantly improve the accuracy and efficiency of leak detection compared to the threshold-based and distance-based detection methods.
泄漏检测对供水管网的长期稳定运行具有重要意义。该研究提出了一种新的泄漏检测方法,通过计算数据库中压力矢量与其他矢量之间的角方差来评估网络中异常的存在。该方法的首要任务是建立由EPANET 2.2生成的压力传感器收集的可靠数据集。采用蒙特卡罗方法生成大量节点正常情况下的需水量数据,并通过在管道上设置漏孔模拟不同泄漏流量下的泄漏情况。通过学习一定比例的正异常复合数据,采用基于角度的离群点检测模型对异常事件进行识别。将这种基于角度的方法应用于实际WDN中,并与以往检测方法的异常识别性能进行了比较。结果表明,与基于阈值和距离的检测方法相比,本文提出的新方法可以显著提高泄漏检测的准确性和效率。
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引用次数: 0
Irrigation water quality from wastewater reuse or groundwater sources: bridging the water–nutrient–food nexus 来自废水再利用或地下水资源的灌溉水质:桥接水-营养-食物关系
4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-11-08 DOI: 10.2166/aqua.2023.390
B. Bharani Baanu, K. S. Jinesh Babu
Abstract A field study is done to analyze the effects of water reuse for irrigation with a focus on seed germination, crop morphology, crop yield, nutritional values of edible parts, fertilizer reduction, and benefit–cost ratio. For the study, three different crops, Lablab bean, tomato, and chilli, are considered and every crop type is irrigated with groundwater (GW), diluted treated wastewater (DTWW), and treated wastewater (TWW). The study reveals that the DTWW is optimal for seed germination. Crops irrigated with the TWW have the highest morphological characteristics. Crop yield is highest for the TWW-irrigated Lablab bean and DTWW-irrigated tomato. Chilli remains unproductive until the end due to thermal stress. Nutritional values of the edible parts of the DTWW- and TWW-irrigated crops are lower than the GW-irrigated crops. Crops irrigated with the DTWW and TWW are applied with the reduced quantities of N, P and K fertilizers. Indeed, even when the dosages are low those crops are able to produce higher yields than the GW-irrigated crops which are applied with full fertilization. As the crop yield is high and fertilizer cost is less, the benefit–cost ratio is higher for water reuse irrigation than the GW irrigation.
摘要通过田间试验,从种子发芽、作物形态、作物产量、可食用部分营养价值、减肥量和效益成本比等方面分析了回用灌溉的效果。在这项研究中,考虑了三种不同的作物,豆角、番茄和辣椒,每种作物类型都用地下水(GW)、稀释处理废水(DTWW)和处理废水(TWW)灌溉。研究表明,DTWW对种子萌发最有利。灌水后的作物形态特征最高。tww灌溉的青豆和番茄产量最高。由于热应激,辣椒直到最后都没有产出。DTWW灌水和tww灌水作物可食用部分的营养价值低于gw灌水作物。用DTWW和TWW灌溉的作物施用少量的N、P、K肥料。事实上,即使用量很低,这些作物的产量也比施用充分施肥的gw灌溉作物高。由于作物产量高,化肥成本低,水回用灌溉的效益成本比GW灌溉高。
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引用次数: 0
Investigation of pressure transients induced on a real water service line by user's activity 用户活动对实际供水管线压力瞬变的影响研究
4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-11-08 DOI: 10.2166/aqua.2023.276
Valentina Marsili, Filippo Mazzoni, Stefano Alvisi, Filomena Maietta, Caterina Capponi, Silvia Meniconi, Bruno Brunone, Marco Franchini
Abstract Recent studies point out that water distribution networks can be affected by long- and short-term pressure oscillations due to the users' activity. However, these transients, generated at the household level, before reaching the water distribution network pass through, and thus affect, the water service line and can contribute to its deterioration. Despite the role of user-induced transients in stressing service lines, few studies in the literature explored the topic, exclusively by means of laboratory tests. The current study is aimed to explore the effects of user's activity on a real service line starting from the field monitoring of pressure data at 500-Hz temporal resolution. Pressure signals are collected both when activating single water devices of the user supplied by the service line and during the ordinary use of domestic devices. The analyses of the acquired data highlight that the domestic service line is subjected to significant pressure variations (which can reach extreme values of −15 and +65 m) based on the device type and distance between the device and the service line and that the use of these devices can continuously stress the water service line.
摘要近年来的研究指出,由于用户的活动,配水管网会受到长期和短期压力波动的影响。然而,在到达配水网络之前,这些在家庭一级产生的暂态会穿过供水服务管道,从而影响供水服务管道,并可能导致其恶化。尽管用户诱导瞬态在强调服务线中的作用,但文献中很少有研究探索该主题,仅通过实验室测试。目前的研究旨在探索用户活动对实际服务线的影响,从现场监测500 hz时间分辨率的压力数据开始。当用户激活由服务管线提供的单个水设备时,以及在日常使用家用设备时,都会收集压力信号。对采集数据的分析强调,根据设备类型和设备与服务管道之间的距离,家庭服务管道受到显著的压力变化(可达到- 15和+65 m的极端值),并且这些设备的使用会持续对供水管道施加压力。
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引用次数: 0
Design and application of soft sensors in rural sewage treatment facilities 农村污水处理设施软传感器的设计与应用
4区 环境科学与生态学 Q2 Environmental Science Pub Date : 2023-11-07 DOI: 10.2166/aqua.2023.062
Bing Li, Siyuan Mao, Tuo Tian, Huaibin Bi, Yuxin Tian, Xueyan Ma, Yong Qiu
Abstract Recently with the growing demand for water quality monitoring, soft measurement sensors have drawn public attention, which can overcome the drawbacks of high cost and long time needed in traditional measurement methods. In this study, a machine learning-based soft monitoring sensor was developed to simultaneously monitor four water quality indicators including COD, NH4+-N, NO3--N, PO43--P. Firstly, specialized experimental equipment and calibration methods were developed to generate a matching dataset that collected over 94,000 data points. Secondly, five models including Multiple Linear Regression, Ridge Regression, AdaBoost, Decision Tree Regression, and Bagging Regression were constructed and compared. The learning accuracy of the models ranged from 0.8860 to 0.9999, among which the predicted value of Bagging Regression is highly fit to the true value. Subsequently, the fuzzy grade method was adopted to reduce the prediction error and strike a balance between efficiency and accuracy. Finally, the designed soft sensor was used for real-time monitoring at three monitoring points in Changzhou, China from September to October 2020, and the results proved the feasibility of the soft sensor in practical application. This study provided a fast and accurate method for water quality measurement, which is of great significance for the management of rural sewage treatment facilities.
近年来,随着人们对水质监测需求的不断增长,软测量传感器逐渐受到人们的关注,它克服了传统测量方法成本高、时间长等缺点。本研究开发了一种基于机器学习的软监测传感器,可同时监测COD、NH4+-N、NO3—N、PO43—P四项水质指标。首先,开发了专门的实验设备和校准方法,生成了收集了94,000多个数据点的匹配数据集。其次,构建多元线性回归、Ridge回归、AdaBoost回归、决策树回归和Bagging回归5种回归模型并进行比较。模型的学习精度在0.8860 ~ 0.9999之间,其中Bagging回归的预测值与真实值拟合度较高。随后,采用模糊分级法减少预测误差,在效率和精度之间取得平衡。最后,将所设计的软传感器于2020年9月至10月在中国常州的三个监测点进行了实时监测,结果证明了软传感器在实际应用中的可行性。本研究提供了一种快速、准确的水质测量方法,对农村污水处理设施的管理具有重要意义。
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引用次数: 0
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