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Advancements in saline water treatment: a review 盐水处理技术进展综述
IF 4.5 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-08-12 DOI: 10.2166/wrd.2023.065
V. Somashekar, A. Anand, V. Hariprasad, E. Elsehly, M. Kapulu
The growing population and increasing water demand necessitate exploring alternative sources of water, including saline water. Saline water treatment technologies have undergone significant advancements in recent years, enabling the production of potable water from seawater and brackish water. This review provides an overview of the current state of saline water treatment technologies, including desalination and membrane-based processes. The advantages and limitations of each technology and their suitability for different applications are discussed. Recent advancements in materials and techniques that have led to improvements in energy efficiency, productivity, and cost-effectiveness of these technologies are highlighted. Finally, the future directions and challenges in the field of saline water treatment are outlined.
随着人口的增长和水需求的增加,有必要探索包括盐水在内的替代水源。近年来,盐水处理技术取得了重大进展,使海水和微咸水能够生产饮用水。这篇综述概述了盐水处理技术的现状,包括脱盐和基于膜的工艺。讨论了每种技术的优点和局限性以及它们对不同应用的适用性。强调了材料和技术的最新进步,这些进步提高了这些技术的能源效率、生产力和成本效益。最后,概述了盐水处理领域的未来方向和挑战。
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引用次数: 0
Gradient-Boosted Decision Tree with used Slime Mould Algorithm (SMA) for wastewater treatment systems 基于黏菌算法的梯度增强决策树在污水处理系统中的应用
IF 4.5 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-07-20 DOI: 10.2166/wrd.2023.046
Jyoti Chauhan, R. M. Rani, V. Prashanthi, H. Almujibah, A. Alshahri, Koppula Srinivas Rao, A. Radhakrishnan
One way to improve the infrastructure, operations, monitoring, maintenance, and management of wastewater treatment systems is to use machine learning modelling to make smart forecasting, tracking, and failure prediction systems. This method aims to use industry data to treat the wastewater treatment model. Gradient-Boosted Decision Tree (GBDT) algorithms were used gradually to predict wastewater plant parameters. In addition, we used the Slime Mould Algorithm (SMA) for feature extraction and other acceptable tuning procedures. The input and effluent Chemical Oxygen Demand (COD) prediction for effluent treatment systems applies to the GBDT approaches employed in this study. GBDT-SMA employs artificial intelligence to provide precise method modelling for complex systems. Several training and model testing techniques were used to determine the best topology for the neural network models and decision trees. The GBDT-SMA model performed best across all methods. With 500 data, GBDT-SMA achieved an accuracy of 96.32%, outperforming other models like Artificial Neural Network (ANN), Convolutional Neural Network (CNN), Deep Convolutional Neural Network (DCNN), and K-neighbours RF, which reached an accuracy of 82.97, 87.45, 85.98, and 91.45%, respectively.
改善污水处理系统的基础设施、运营、监控、维护和管理的一种方法是使用机器学习建模来制作智能预测、跟踪和故障预测系统。该方法旨在利用工业数据对废水处理模型进行处理。逐步采用梯度增强决策树(GBDT)算法对污水厂参数进行预测。此外,我们使用黏菌算法(SMA)进行特征提取和其他可接受的调谐程序。污水处理系统的输入和流出化学需氧量(COD)预测适用于本研究中采用的GBDT方法。GBDT-SMA采用人工智能为复杂系统提供精确的方法建模。使用了几种训练和模型测试技术来确定神经网络模型和决策树的最佳拓扑。GBDT-SMA模型在所有方法中表现最好。在500个数据的情况下,GBDT-SMA的准确率达到96.32%,优于人工神经网络(ANN)、卷积神经网络(CNN)、深度卷积神经网络(DCNN)和k近邻RF等模型,后者的准确率分别为82.97、87.45、85.98和91.45%。
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引用次数: 0
Water reuse for vine irrigation: from research to full-scale implementation 藤蔓灌溉的水再利用:从研究到全面实施
IF 4.5 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-07-19 DOI: 10.2166/wrd.2023.054
Chrystelle Ayache, Y. Poussade, Yves Jaeger, E. Soyeux
Water scarcity is a worldwide problem, which leads to unprecedented pressure on water supply in arid and semi-arid regions. Treating wastewater is an alternative water resource, therefore, its reuse for agricultural irrigation has been growing worldwide since the beginning of the 21st century. In several regions of wine-producing countries (e.g., Australia, California – USA, Spain), wastewater reuse appears to be the most accessible alternative, both financially and technically, for agricultural uses that notably do not require drinking water. From the summer of 2022, vine irrigation full-scale implementation will start with tertiary treated municipal wastewater in the French Languedoc region. This was made possible thanks to a collaborative research project conducted between 2013 and 2018 to address all potential health and environmental risks associated with this process. This research project was conducted in the south of France, with experimental and control plots both equipped with drip irrigation systems. All the results produced during the research project demonstrated the feasibility of applying this process for vine drip irrigation while effectively managing health and environmental risks and complying with the regulation (treated water microbiological quality). A social acceptance and economic study were also performed in order to broaden the scope of the project scalability evaluation.
水资源短缺是一个世界性的问题,它给干旱和半干旱地区的供水带来了前所未有的压力。处理废水是一种可替代的水资源,因此,自21世纪初以来,废水在农业灌溉中的再利用在全球范围内得到了发展。在葡萄酒生产国的几个区域(如澳大利亚、美国加利福尼亚州、西班牙),废水再利用在财政和技术上似乎是最容易获得的替代办法,因为农业用途显然不需要饮用水。从2022年夏天开始,葡萄藤灌溉将在法国朗格多克地区全面实施,使用三级处理的城市废水。这要归功于2013年至2018年间开展的一项合作研究项目,该项目旨在解决与这一过程相关的所有潜在健康和环境风险。该研究项目在法国南部进行,试验田和对照田都配备了滴灌系统。在研究项目中产生的所有结果都表明,在有效管理健康和环境风险并遵守法规(处理后的水微生物质量)的同时,将该工艺应用于葡萄藤滴灌的可行性。为了扩大项目可扩展性评估的范围,还进行了社会接受度和经济研究。
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引用次数: 0
Effects of adsorption and filtration processes on greywater microbiological contamination and the potential human health risk reduction 吸附和过滤工艺对灰水中微生物污染的影响及潜在的人类健康风险降低
IF 4.5 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-07-19 DOI: 10.2166/wrd.2023.029
M. Mortula, K. Fattah, Fatima Iqbal, Zahid Khan
Recycling treated greywater (GW) for onsite, non-potable applications can reduce the potable water demand typically used for non-potable purposes. The conventional methods for GW treatment are limited in their ability to remove wide-ranging pollutants that are inexpensive and use low energy. For this reason, effective and low-cost onsite treatment options are in demand. This study examines the effectiveness of sand filtration (SF), granulated blast furnace slag (GBFS), and activated carbon (AC) in the treatment of GW from a residential apartment building in Sharjah, United Arab Emirates. The study relies on four different pilot-scale experimental setups to investigate the effectiveness of SF, AC, and GBFS in treating microorganisms from GW and evaluate the microbial risk reduction using these treatment processes. A quantitative microbial risk assessment (QMRA) approach is used for risk assessment. Results show that GBFS achieves a higher reduction of total coliform (TC) (0.54–2.05 log removal) and fecal coliform (FC) (1.96–2.30 log removal) than AC. SF improves reduction by 0.13–3.39 log removal and 1.11–3.68 log removal for TC and FC, respectively. The study also reveals substantial FC and Escherichia coli risk reduction by SF, AC and GBFS.
将处理过的灰水(GW)回收用于现场非饮用应用可以减少通常用于非饮用目的的饮用水需求。GW处理的传统方法在去除范围广泛的污染物的能力方面受到限制,这些污染物价格低廉且能耗低。因此,需要有效和低成本的现场治疗方案。本研究考察了砂滤(SF)、高炉矿渣颗粒(GBFS)和活性炭(AC)处理阿拉伯联合酋长国沙迦一栋住宅楼GW的有效性。该研究依赖于四个不同的中试规模实验装置,以调查SF、AC和GBFS在处理GW微生物方面的有效性,并评估使用这些处理过程降低微生物风险的情况。定量微生物风险评估(QMRA)方法用于风险评估。结果表明,与AC相比,GBFS对总大肠菌群(TC)(去除0.54–2.05 log)和粪便大肠杆菌群(FC)(去除1.96–2.30 log)的去除率更高。SF对TC和FC的去除率分别提高了0.13–3.39 log和1.11–3.68 log。该研究还揭示了SF、AC和GBFS显著降低FC和大肠杆菌的风险。
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引用次数: 0
Synthesis and characterization of p-carboxy phenyl amino maleimide-g-cellulose acetate/ZrO2 nanocomposite membrane for water desalination 对羧基苯基氨基马来酰亚胺-g-醋酸纤维素/ZrO2纳米复合海水淡化膜的合成与表征
IF 4.5 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-07-17 DOI: 10.2166/wrd.2023.036
A. Abdel-Naby, Bushra A. Alabdullatif, Sarah Aldulaijan, Yanallah Alqarni
The reaction of p-carboxy phenyl amino maleimide (CHM) with cellulose acetate (CA), led to the formation of a modified cellulose acetate polymer (MCA), which was characterized by UV/Vis, 1H NMR, and 13C NMR. The active sites of the reaction were the –NH group of (CHM) and the OAc of CA. CA was grafted with (CHM) to build branches on its main chains, using benzoyl peroxide as an initiator. The results of 1H NMR and 13C NMR revealed the presence of (CHM) moieties inside the polymeric matrix. The (CA-g-CHM) ZrO2 was fabricated into a membrane, using a phase inversion technique. The effect of ZrO2 content on the water flux was discussed. The SEM/EDS was also used to characterize the membrane contents and morphology. The morphology of the membrane showed the grafted parts and the EDS confirmed the presence of nitrogen atoms in the polymeric matrix. The thermogravimetry (TGA) results showed that the membrane exhibited high thermal stability which would adjust the membrane for the desalination process. The desalination test indicated the removal of NaCl salt by the membrane, as shown by the EDS and 1H NMR spectroscopy results. The membrane exhibited good antibacterial and antifungal properties.
对羧基苯基氨基马来酰亚胺(CHM)与醋酸纤维素(CA)反应生成改性醋酸纤维素聚合物(MCA),并用紫外/可见光谱、1H NMR和13C NMR对其进行了表征。反应的活性位点为(CHM)的-NH基团和CA的OAc基团。以过氧化苯甲酰为引发剂,将(CHM)接枝在CA的主链上建立支链。1H NMR和13C NMR结果表明,聚合物基体中存在(CHM)基团。采用相变技术制备了(CA-g-CHM) ZrO2薄膜。讨论了ZrO2含量对水通量的影响。利用SEM/EDS对膜的内容物和形态进行了表征。膜的形貌显示接枝部分,能谱分析证实了聚合物基质中存在氮原子。热重(TGA)测试结果表明,该膜具有较高的热稳定性,可以调节膜在脱盐过程中的性能。脱盐试验表明,膜对NaCl盐有脱盐作用,EDS和1H NMR结果表明膜对NaCl盐有脱盐作用。该膜具有良好的抗菌和抗真菌性能。
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引用次数: 0
Synthesis, characterization, and performance of chitosan/nylon 6/polyurethane blend for the removal of chromium (VI) and lead (II) ions from aqueous solutions for enhanced kinetic adsorption studies 壳聚糖/尼龙6/聚氨酯共混物的合成、表征和性能用于从水溶液中去除铬(VI)和铅(II)离子以增强动力学吸附研究
IF 4.5 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-06-07 DOI: 10.2166/wrd.2023.019
S. Jayakumar, S. Sudarsan, B. Sridhar, E. Parthiban, A. Jerwin Prabu, S. Jha
Adsorption is vital for the elimination of Cr6+ and Pb2+ ions in the contaminated solution medium. A ternary blend made up of chitosan, nylon 6 and polyurethane foam (CS/Ny 6/PUF) blend in the ratio of 2:1:1 has been investigated. These blends are used as an adsorbent due to the insoluble nature in acidic and basic medium. The adsorption efficacy was analyzed by modifying pH, contact time, and adsorbent dosage. The maximum uptake of metal ions has been exhibited in the pH range 5. An equilibrium adsorption statistic indicated that adsorption isotherm follows the Freundlich model. The adsorption kinetic parameters specified that the adsorption of chromium has shown pseudo-second-order and lead pseudo-first-order reaction.
吸附对于去除污染溶液介质中的Cr6+和Pb2+离子至关重要。研究了由壳聚糖、尼龙6和聚氨酯泡沫(CS/Ny6/PUF)按2:1:1的比例共混而成的三元共混物。由于在酸性和碱性介质中的不溶性,这些混合物被用作吸附剂。通过改变pH、接触时间和吸附剂用量来分析吸附效果。金属离子的最大吸收已经在pH范围5中表现出来。平衡吸附统计表明,吸附等温线符合Freundlich模型。吸附动力学参数表明,铬的吸附表现出拟二级反应和铅的拟一级反应。
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引用次数: 0
Organics and inorganics in flow back and produced water from shale gas operations: treatment and identification of glycols using gas chromatography–mass spectrometry 页岩气作业回流水和采出水中的有机物和无机物:使用气相色谱-质谱法处理和鉴定二醇
IF 4.5 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-05-22 DOI: 10.2166/wrd.2023.025
Seongyun Kim, Pinar Omur-Ozbe, K. Carlson, Sangchul Lee, Eun-Sik Kim, Min-Jin Hwang, Ji-Hee Son, Woo-jun Kang
This study investigated the efficiency of different water treatment processes in reducing propylene glycol (PG), ethylene glycol (EG), ethylene glycol monobutyl ether (EGME), and other water quality parameters in flow back/produced water from a shale gas well operation. EG, PG, and EGME are the most widely used chemicals in hydraulic fracturing; however, limited investigations on these chemicals have been performed to date. Granular activated carbon (GAC) removed PG and EG to acceptable drinking water levels. Electrocoagulation was effective at decreasing turbidity (85%) as well as total petroleum hydrocarbons (TPH) (80%), while ultrafiltration removed 90% of the turbidity and TPH. GAC further removed approximately 95% of benzene, toluene, ethylbenzene, and xylene (BTEX), total organic carbon, dissolved organic carbon, and glycols but only removed 16% of total dissolved solids (TDS). Reverse osmosis removed approximately 90% of TDS (2,550 mg/L); however, this level remained high for certain purposes. Although some water quality parameters remained above the reusability threshold for most purposes, the treated water could be used on tolerant plants and permeable soils. In-depth knowledge and understanding of flow back/produced water quality characteristics, prior and post water treatment processes, can improve water treatment process strategies, reduce wastewater discharge, and improve treated water's reusability.
本研究调查了不同水处理工艺在降低页岩气井返排/采出水中丙二醇(PG)、乙二醇(EG)、乙醇单丁醚(EGME)和其他水质参数方面的效率。EG、PG和EGME是水力压裂中使用最广泛的化学品;然而,迄今为止,对这些化学品的调查有限。颗粒活性炭(GAC)将PG和EG去除至可接受的饮用水水平。电絮凝能有效降低浊度(85%)和总石油烃(TPH)(80%),而超滤能去除90%的浊度和TPH。GAC进一步去除了约95%的苯、甲苯、乙苯和二甲苯(BTEX)、总有机碳、溶解有机碳和二醇,但仅去除了16%的总溶解固体(TDS)。反渗透去除了约90%的TDS(2550 mg/L);然而,出于某些目的,这一水平仍然很高。尽管在大多数情况下,一些水质参数仍高于可重复使用阈值,但处理过的水可以用于耐受性植物和渗透性土壤。深入了解回流/采出水水质特征、水处理前后流程,可以改进水处理工艺策略,减少废水排放,提高处理水的可重复使用性。
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引用次数: 0
Quantitative study of biofilm yield and biomass distribution of a multi-stage moving-bed biofilm system 多级移动床生物膜系统生物膜产量及生物量分布的定量研究
4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-05-22 DOI: 10.2166/wrd.2023.009
Ning Chen, Xiaodong Wang, Mei Huang, Zakhar Maletskyi, Harsha Ratnaweera, Xuejun Bi
Abstract A multi-stage anoxic/oxic (A/O) moving-bed biofilm reactor (MBBR) system with multiple chambers was established for municipal wastewater treatment. The active biomass quantity, bioactivity, and biomass yield of a pilot-scale multi-stage MBBR were investigated in this study. The microbial activity and heterotrophic yield coefficients (YH) were measured using respirometric techniques in each chamber at different temperature conditions. Meanwhile, the growth, nitrification, and denitrification rates of functional biomass were also quantified as specific respiration rate (SOUR). The total active biomass in the multi-stage A/O-MBBR system was 0.71–1.68 g COD/m2 for the aerobic reactor and 0.39–1.44 g COD/m2 for the anoxic reactor at 10–19 °C. The YH values for the anoxic reactors were 0.61–0.69, which were comparable to the recommended value of the activated sludge model (ASM1). The correlation coefficient between Nitrospira and the autotrophic specific respiration rate (SOURA) was 0.82. Meanwhile, denitrifying genera showed a significant correlation with the heterotrophic specific respiration rate (SOURH) and the active heterotrophic biomass (XH). This study provided insights into biomass distribution and the corresponding kinetic parameters for the multi-stage MBBR systems, which may serve as a reference for process design and trouble shooting.
摘要建立了多级厌氧/氧(A/O)多室移动床生物膜反应器(MBBR)处理城市污水系统。研究了中试多级MBBR反应器的有效生物量、生物活性和生物量产量。在不同温度条件下,采用呼吸法测定了各室微生物活性和异养产率系数(YH)。同时,将功能生物量的生长速率、硝化速率和反硝化速率也量化为比呼吸速率(SOUR)。在10-19℃条件下,好氧反应器的总活性生物量为0.71 ~ 1.68 g COD/m2,缺氧反应器的总活性生物量为0.39 ~ 1.44 g COD/m2。厌氧反应器的YH值为0.61 ~ 0.69,与活性污泥模型(ASM1)的推荐值相当。硝基螺旋体与自养特定呼吸速率(SOURA)的相关系数为0.82。反硝化属与异养特定呼吸速率(SOURH)和活性异养生物量(XH)呈极显著相关。该研究为多级MBBR系统的生物量分布和相应的动力学参数提供了依据,可为工艺设计和故障排除提供参考。
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引用次数: 0
Economic analysis based on saline water treatment using renewable energy system and microgrid architecture 基于可再生能源系统和微电网架构的咸水处理经济分析
IF 4.5 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-05-17 DOI: 10.2166/wrd.2023.013
N. Bhavani, K.R. Harne, Satendar Singh, Ostonokulov Azamat Abdukarimovich, V. Balaji, Bharat Singh, K. Vengatesan, Sachi Nandan Mohanty
Reverse osmosis desalination facilities operating on microgrids (MGs) powered by renewable energy are becoming more significant. A leader-follower structured optimization method underlies the suggested algorithm. The desalination plant is divided into components, each of which can be operated separately as needed. MGs are becoming an important part of smart grids, which incorporate distributed renewable energy sources (RESs), energy storage devices, and load control strategies. This research proposes novel techniques in economic saline water treatment based on MG architecture integrated with a renewable energy systems. This study offers an optimization framework to simultaneously optimize saline as well as freshwater water sources, decentralized renewable and conventional energy sources to operate water-energy systems economically and efficiently. The radial Boltzmann basis machine is used to analyse the salinity of water. Data on water salinity were used to conduct the experimental analysis, which was evaluated for accuracy, precision, recall, and specificity as well as computational cost and kappa coefficient. The proposed method achieved 88% accuracy, 65% precision, 59% recall, 65% specificity, 59% computational cost, and 51% kappa coefficient.
利用可再生能源驱动的微电网运行的反渗透海水淡化设施正变得越来越重要。该算法的基础是一种主从结构优化方法。海水淡化厂分为几个部分,每个部分都可以根据需要单独运行。MGs正成为智能电网的重要组成部分,智能电网包含分布式可再生能源(RES)、储能设备和负载控制策略。本研究提出了基于MG架构和可再生能源系统相结合的经济盐水处理新技术。这项研究提供了一个优化框架,可以同时优化盐水和淡水水源、分散的可再生能源和传统能源,以经济高效地运行水能系统。径向玻尔兹曼基机用于分析水的盐度。使用盐度数据进行实验分析,评估准确性、精密度、召回率和特异性,以及计算成本和kappa系数。所提出的方法实现了88%的准确率、65%的精密度、59%的召回率、65%特异性、59%的计算成本和51%的kappa系数。
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引用次数: 0
Removal of antibiotics with different charges in water by graphene oxide membranes 氧化石墨烯膜去除水中不同电荷的抗生素
IF 4.5 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-05-06 DOI: 10.2166/wrd.2023.084
Zimeng Liang, Xin Zhao, Weiqi Huang, Huabiao Qi, Can Wang
Antibiotics are a large group of emerging organic pollutants with low concentration levels in the water. The presence of antibiotics will affect the ecological environment and human health. The removal of trace organic compounds by graphene oxide (GO) membranes has attracted extensive attention. This study investigated the removal of three differently charged antibiotics by GO membranes and the influence of water quality on the removal of antibiotics. It showed that a crosslinked ethylenediamine-GO (EDA-GO) membrane had better stability and higher antibiotic removal performance than a non-crosslinked GO membrane. Among the three antibiotics, penicillin (PNC) was negatively charged and had the highest removal efficiency due to steric effect and electrostatic repulsion. A low concentration (10 mmol L−1) of Na+ in water could increase the membrane flux but had no significant effect on the removal of antibiotics. Ca2+ could reduce the membrane flux and improve the removal of chloramphenicol (CAP) and PNC. The removal efficiencies of low-concentration antibiotics (500 μg L−1) were higher than those of high-concentration antibiotics (10 mg L−1). Furthermore, the removal of antibiotics under the condition of actual wastewater quality was higher than those in solutions prepared with ultrapure water. The EDA-GO membrane has great potential in the removal of antibiotics in wastewater.
抗生素是一大类新出现的水中低浓度有机污染物。抗生素的存在将影响生态环境和人类健康。氧化石墨烯(GO)膜对痕量有机化合物的去除引起了人们的广泛关注。本研究考察了GO膜对三种不同电荷抗生素的去除作用以及水质对抗生素去除的影响。结果表明,与非交联GO膜相比,交联乙二胺GO膜具有更好的稳定性和更高的抗生素去除性能。在三种抗生素中,青霉素(PNC)带负电荷,由于空间效应和静电排斥,其去除效率最高。水中低浓度(10 mmol L−1)的Na+可以增加膜通量,但对抗生素的去除没有显著影响。Ca2+可降低膜通量,提高对氯霉素(CAP)和PNC的去除率。低浓度抗生素(500μg L-1)的去除率高于高浓度抗生素(10 mg L-1)。此外,在实际废水质量条件下,抗生素的去除率高于用超纯水制备的溶液。EDA-GO膜在去除废水中的抗生素方面具有很大的潜力。
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引用次数: 1
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Water Reuse
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