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Towards offshore hydrogen production via floating wind turbines: a comparative study on main electrolyzer technologies in two Mediterranean case studies 通过浮动风力涡轮机实现海上制氢:两个地中海案例研究中主要电解槽技术的比较研究
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-02-03 DOI: 10.1016/j.jclepro.2026.147653
Riccardo Travaglini, Francesco Superchi, Francesco Papi, Alessandro Bianchini
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引用次数: 0
Incorporating water quality into food-water nexus reveals hidden benefits of technological progress 将水质纳入食物与水的关系揭示了技术进步的潜在好处
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-02-03 DOI: 10.1016/j.jclepro.2026.147724
Hui Li, Zhiyao Ding, Yuhan Liang, Yumeng Li, Gengyuan Liu, Frederick Kwame Yeboah, Xiong Zhou, Sai Liang
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引用次数: 0
Interplay of renewable energy technology R&D, digital technologies, and environmental policy in agricultural emission Mitigation: Theoretical and empirical perspectives 农业减排中可再生能源技术研发、数字技术与环境政策的相互作用:理论与实证视角
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-02-03 DOI: 10.1016/j.jclepro.2026.147709
Jafir Mehmood, Khurshid Ahmad, Noman Arshed
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引用次数: 0
Diagnosing supply–demand coordination in the water–energy–food nexus: A triangle framework for the Mu Us Sandy Land 诊断水-能源-粮食关系中的供需协调:毛乌素沙地的三角框架
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-02-02 DOI: 10.1016/j.jclepro.2026.147684
Shuxin Mao, Ouyang Hui, Jian Xue
The water–energy–food nexus (WEFN) offers an integrative lens for managing interdependent resources, but current models often overlook the systemic constraint that not all subsystem goals can be simultaneously fulfilled due to limited coordination capacity. In this study, we proposed the Impossible Supply Triangle Hypothesis, which formalizes this constraint and introduces the Goal Fulfillment Ratio (GFR) as a normalized metric of subsystem goal attainment. Based on this framework, we conducted a spatiotemporal assessment of WEFN supply, demand, and coordination dynamics in China's Mu Us Sandy Land from 2000 to 2020. The GFR analysis revealed that 10.33 % of the region entered a resource conflict state in 2020 with conflict zones primarily concentrated in the counties of Dingbian, Yijinhuoluo, Yanchi, and Jingbian. Sensitivity analysis confirms the triangle model's validity: as the coordination threshold decreases from 2.2 to 1.8, the conflict ratio rises sharply from 2.98 % to 93.07 %, indicating heightened systemic stress near the threshold. Supply-Demand Match Degree (SDMD) analysis showed average matching degrees in 2020 of 0.0115 (water), 0.0034 (energy), and −0.0038 (food), indicating relative surpluses for water and energy, and deficits for food. Root Mean Square Deviation trade-off assessment identified Jingbian, Hengshan, and Yijinhuoluo as the counties with the highest supply-side imbalances. Scenario simulations showed that a 10 % economic recession increased water SDMD by 13.57 %, while a 10 % population decrease raised energy SDMD by 23.16 %. These findings demonstrate that the Goal Fulfillment Ratio–Supply–Demand Match Degree–Root Mean Square Deviation framework can effectively reveal structural risks and coordination limits in WEFN systems, providing a replicable tool for integrated resource governance.
水-能量-食物关系(WEFN)为管理相互依赖的资源提供了一个综合视角,但目前的模型往往忽视了系统约束,即由于协调能力有限,并非所有子系统目标都可以同时实现。在本研究中,我们提出了不可能供应三角假设,该假设形式化了这一约束,并引入了目标完成率(GFR)作为子系统目标实现的标准化度量。在此基础上,对2000 - 2020年中国毛乌素沙地WEFN供给、需求和协调动态进行了时空评估。GFR分析显示,2020年全区10.33%的区域进入资源冲突状态,冲突区域主要集中在定边县、宜金霍洛县、盐池县和靖边县。敏感性分析证实了三角模型的有效性:随着协调阈值从2.2降低到1.8,冲突率从2.98%急剧上升到93.07%,表明在阈值附近系统压力加剧。供需匹配度(SDMD)分析显示,2020年的平均匹配度为0.0115(水)、0.0034(能源)和- 0.0038(食物),表明水和能源相对过剩,食物短缺。均方根偏差权衡评估结果表明,靖边、衡山和宜金霍洛是供给侧失衡最严重的县。情景模拟表明,经济衰退10%使水SDMD增加13.57%,人口减少10%使能源SDMD增加23.16%。研究结果表明,目标完成率-供需匹配度-均方根偏差框架能够有效揭示WEFN系统的结构性风险和协调限制,为资源综合治理提供了可复制的工具。
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引用次数: 0
Meat production and sustainability: Spanish consumers’ perception 肉类生产和可持续性:西班牙消费者的看法
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-02-02 DOI: 10.1016/j.jclepro.2026.147668
Javier Herrero-Encinas, Cristina López-Cózar-Navarro, Carlos Castro-Gil, Silverio Alarcón
The meat sector is of significant economic importance to Spain. However, it is equally imperative that this sector operates in a manner that is both responsible and environmentally sustainable. The objective of this study was to determine the most valued sustainability attributes of the meat industry by consumers, with a view to enhancing the communication policy of companies. This work reduces the gap in how meat companies can connect their sustainability actions with consumers' concerns. A study was conducted to obtain Spanish consumers' opinions on evaluating thirteen sustainability attributes in the meat industry. This was achieved by means of a questionnaire (n = 505). The results obtained demonstrated a high level of interest in sustainable development. Furthermore, social responsibility aspects, particularly those related to the safety of the workplace, are of particular significance when compared to environmental and corporate sustainability parameters. Kruskal-Wallis test showed a higher concern of sustainable attributes in women compared to men. The segmentation analysis by K-means procedure showed three differentiated groups: proactives, conscious and skeptical. Based on these findings, interesting insights can be applied to communication strategies in meat firms.
肉类行业对西班牙具有重要的经济意义。然而,同样重要的是,该部门必须以负责任和环境可持续的方式运作。本研究的目的是确定消费者最看重的肉类行业的可持续性属性,以加强公司的沟通政策。这项工作缩小了肉类公司如何将其可持续发展行动与消费者关注的问题联系起来的差距。进行了一项研究,以获得西班牙消费者对评估肉类行业的13个可持续性属性的意见。这是通过问卷调查(n = 505)实现的。所取得的结果显示了对可持续发展的高度兴趣。此外,社会责任方面,特别是与工作场所安全有关的方面,与环境和公司可持续性参数相比,具有特别重要的意义。Kruskal-Wallis测试显示,女性比男性更关注可持续属性。K-means分割分析显示主动性、有意识和怀疑性三个不同的群体。基于这些发现,有趣的见解可以应用于肉类公司的沟通策略。
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引用次数: 0
The green logistics maturity model for evaluating sustainable logistics practices 评价可持续物流实践的绿色物流成熟度模型
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-02-02 DOI: 10.1016/j.jclepro.2026.147671
Saverio Ferraro, Leonardo Leoni, Alessandra Cantini, Valentina Di Pasquale, Filippo De Carlo
The growing concern about the environmental impact of industrial processes highlights the need for sustainable practices in supply chain management and logistics. Maturity Models (MMs) are widely used to evaluate the development of entities through continuous improvement, addressing sustainability assessment and enhancements. Literature proposes MMs for evaluating green practices in logistics. However, the MMs available do not follow systematic design, and they lack proper validation and application. This study introduces the Green Logistics Maturity (GreLoM) model to evaluate and improve green logistics practices within organizations. Using structured methodologies for maturity modeling, the five-level GreLoM model is based on four dimensions of resource management, process management, network management, and sustainable reporting, each one with relevant sub-dimensions and items. The model was developed using a hybrid approach that combines analysis of existing logistics MMs and semi-structured interviews with expert practitioners. The GreLoM model was validated through content validity and reliability analysis, assessed by a balanced pool of industry experts and academic researchers. After validation, the GreLoM model was applied descriptively, comparatively, and prescriptively in two case studies using a structured questionnaire weighing respondents' feedback by their knowledge with the process and years of experience. The results demonstrate the utility and practicality of the GreLoM model, suggesting that its adoption can support the transition to a low-emission industry, aligning with global sustainability goals. The model assesses the maturity of green logistics practices and promotes a culture of continuous improvement by comparing model application results with practitioners' perceptions of improvement areas. Thus, the GreLoM model can be a valuable tool for practitioners aiming for low emissions and for researchers focused on green logistics assessment and sustainable maturity modeling.
对工业过程对环境影响的日益关注突出了供应链管理和物流中可持续实践的必要性。成熟度模型(mm)被广泛用于评价实体通过持续改进、可持续性评估和增强的发展。文献提出mm用于评价物流中的绿色实践。然而,现有的mm没有遵循系统设计,并且缺乏适当的验证和应用。本研究引入绿色物流成熟度(GreLoM)模型来评估和改进组织内的绿色物流实践。使用结构化的成熟度建模方法,五级GreLoM模型基于资源管理、流程管理、网络管理和可持续报告的四个维度,每个维度都有相关的子维度和项。该模型是使用混合方法开发的,该方法结合了对现有物流mm的分析和对专家从业者的半结构化访谈。GreLoM模型通过内容效度和信度分析进行了验证,并由行业专家和学术研究人员进行了评估。验证后,GreLoM模型在两个案例研究中被描述性、比较性和规范性地应用,使用结构化问卷来衡量受访者对过程和多年经验的知识反馈。研究结果证明了GreLoM模型的实用性和实用性,表明采用该模型可以支持向低排放行业过渡,与全球可持续发展目标保持一致。该模型评估绿色物流实践的成熟度,并通过比较模型应用结果与从业者对改进领域的看法来促进持续改进的文化。因此,GreLoM模型对于以低排放为目标的实践者和专注于绿色物流评估和可持续成熟度建模的研究人员来说是一个有价值的工具。
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引用次数: 0
Climate-sensitive optimization of autonomous hybrid photovoltaic/battery/hydrogen systems for net-zero energy rural buildings via particle swarm optimization 基于粒子群优化的零能耗农村建筑自主混合光伏/电池/氢系统气候敏感优化
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-02-02 DOI: 10.1016/j.jclepro.2026.147667
Anouar Tribiche, Niima Es-Sakali, Said Laasri, Amine Alaoui Belghiti, Samir Idrissi Kaitouni
To achieve carbon neutrality in the built environment, designers worldwide must prioritize the development of more sustainable buildings, particularly those integrating hybrid solar configurations, to reduce reliance on conventional energy sources. In this context, energy storage systems are quintessential. Although numerous studies have examined the techno-economic performance of hybrid solar Photovoltaic (PV)/battery/hydrogen systems, the substantial potential of hydrogen under different climate zones, load profiles, and parameter variations in the off-grid building stocks remains underexplored. This study seeks to address this gap by comprehensively investigating PV/battery/hydrogen systems through a tailored optimization workflow while accounting for the dynamic interrelation between hourly spatiotemporal variations in solar energy output and energy demand across six different climate zones. In addition to optimizing the number and tilt angle of photovoltaic panels, the battery capacity, and storage modulation coefficient, the workflow optimally sizes the key hydrogen system components, including the electrolyzer, storage tank, and fuel cell. The main objective is to minimize the Levelized Cost of Energy (LCOE) via Particle Swarm Optimization (PSO) and compare it against two other metaheuristic algorithms: Genetic Algorithm (GA) and Ant Colony Optimization (ACO). PSO proved its superiority by providing relatively lower LCOE values of 0.44–0.7 $/kWh, while ensuring the targeted Self-Sufficiency Ratio (SSR) of 100 %. Moreover, incorporating the hydrogen system reduces the LCOE by up to 0.12 $/kWh (15.4 %) in Ifrane, compared to battery-only systems. These findings highlight the importance of climate-sensitive design and hybrid storage strategies in enhancing the economic and energy resilience of off-grid net-zero energy buildings. At an SSR of 90 %, LCOE ranges between 0.28 and 0.37 $/kWh, reflecting a 36.4–54.3 % cost reduction. This shows that fully renewable systems, while feasible, may incur substantially higher costs of electricity. Interestingly, the sensitivity analysis reveals that the optimal configurations are highly sensitive to the discount rate, as a reduction from 5 % to 2 % leads to an LCOE decrease of up to 0.097 $/kWh, followed by the battery's techno-economic parameters. Lastly, the Monte Carlo–based uncertainty analysis further shows that the optimized LCOE values consistently fall within the interquartile range of the probability distributions, confirming the consistency of the optimal solutions.
为了在建筑环境中实现碳中和,世界各地的设计师必须优先考虑开发更具可持续性的建筑,特别是那些集成混合太阳能配置的建筑,以减少对传统能源的依赖。在这种情况下,储能系统是必不可少的。尽管已有大量研究考察了太阳能光伏/电池/氢混合系统的技术经济性能,但氢在不同气候区、负荷概况和离网建筑存量参数变化下的巨大潜力仍未得到充分探索。本研究旨在通过量身定制的优化工作流程,全面研究光伏/电池/氢系统,同时考虑六个不同气候带太阳能输出和能源需求每小时时空变化之间的动态相互关系,从而解决这一差距。除了优化光伏板的数量和倾斜角度、电池容量和存储调制系数外,该工作流程还优化了关键氢系统组件的尺寸,包括电解槽、储罐和燃料电池。主要目标是通过粒子群优化(PSO)最小化平准化能量成本(LCOE),并将其与其他两种元启发式算法:遗传算法(GA)和蚁群优化(ACO)进行比较。PSO的优势在于提供了相对较低的LCOE值(0.44-0.7美元/千瓦时),同时保证了目标自足率(SSR) 100%。此外,与纯电池系统相比,在法国,结合氢系统可将LCOE降低0.12美元/千瓦时(15.4%)。这些发现强调了气候敏感设计和混合存储策略在增强离网净零能耗建筑的经济和能源弹性方面的重要性。在SSR为90%时,LCOE范围在0.28至0.37美元/千瓦时之间,反映了36.4 - 54.3%的成本降低。这表明,虽然完全可再生系统是可行的,但可能会产生更高的电力成本。有趣的是,灵敏度分析表明,最佳配置对贴现率高度敏感,从5%降低到2%导致LCOE降低高达0.097美元/千瓦时,其次是电池的技术经济参数。最后,基于蒙特卡洛的不确定性分析进一步表明,优化后的LCOE值始终落在概率分布的四分位数范围内,证实了最优解的一致性。
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引用次数: 0
Experimental and numerical study on oxygen-enriched NH3/H2/CO/air premixed combustion at elevated temperature and pressure 富氧NH3/H2/CO/空气高温高压预混燃烧实验与数值研究
IF 1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-31 DOI: 10.1016/j.jclepro.2026.147660
Ningning Li, Haoxin Deng, Xiaoping Wen, Fahui Wang, Jun Song, Guoyan Chen
This study investigates the laminar burning velocity (LBV) and instability of NH3/H2/CO ternary mixtures under oxygen-enriched conditions (Ω: 0.21–0.65) at elevated temperatures and pressures. Results show that increasing Ω significantly enhances LBV and shifts peak velocity toward leaner conditions. A novel decoupling method using a virtual species (FN2) reveals that while oxygen enrichment promotes LBV primarily through intensified thermal effects, the physical expanding effect becomes dominant as Ω increases. Notably, an engineering trade-off was identified: while Ω = 0.45 achieves comparable LBV enhancement to preheating at 567 K, its peak NOx emission is approximately 5 times higher due to heightened NNH pathway sensitivity. Regarding stability, increasing Ω elevates the effective Lewis number (Leeff), suppressing thermo-diffusive instability. Conversely, elevated pressure (3 atm) triggers a transition to distinct cellular structures as flame thinning weakens curvature-stabilizing effects, allowing hydrodynamic instability to dominate. Furthermore, a rigorous quantitative framework using Fourier spectral decomposition and fractal analysis was introduced to characterize flame front perturbations.1 By decomposing morphological evolution into specific modal amplitudes, the results quantitatively demonstrate that CO addition and oxygen enrichment suppress thermo-diffusive instabilities by reducing mid-to-high frequency spectral amplitudes (K = 6–20). In contrast, elevated pressure triggers rapid amplification of these modes, marking a shift toward hydrodynamic-dominated instability. This spectral analysis provides a novel diagnostic tool for distinguishing competing effects of fuel composition and operating conditions on flame stability, offering a critical theoretical framework for optimizing high-performance, low-emission ammonia-fueled combustors.
本文研究了富氧条件下(Ω: 0.21-0.65) NH3/H2/CO三元混合物在高温高压下的层流燃烧速度(LBV)和不稳定性。结果表明,增加Ω显著提高了LBV,并使峰值速度向更低的条件移动。一种利用虚种(FN2)的新型解耦方法表明,虽然氧富集主要通过强化热效应促进LBV,但随着Ω的增加,物理膨胀效应成为主导作用。值得注意的是,我们发现了一个工程上的权衡:虽然Ω = 0.45在567 K时实现了与预热相当的LBV增强,但由于NNH路径灵敏度的提高,其峰值NOx排放量大约高出5倍。在稳定性方面,增加Ω提高了有效路易斯数(Leeff),抑制了热扩散不稳定性。相反,升高的压力(3atm)会触发过渡到不同的细胞结构,因为火焰变薄削弱了曲率稳定效应,使流体动力不稳定性占主导地位。此外,采用傅立叶谱分解和分形分析的严格定量框架来表征火焰锋面扰动通过将形态演化分解为特定的模态振幅,结果定量地表明CO添加和氧富集通过降低中高频谱幅值(K = 6-20)来抑制热扩散不稳定性。相反,升高的压力会触发这些模式的快速放大,标志着向流体动力主导的不稳定性转变。这种光谱分析为区分燃料成分和操作条件对火焰稳定性的竞争影响提供了一种新的诊断工具,为优化高性能、低排放的氨燃料燃烧器提供了关键的理论框架。
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引用次数: 0
Divergent above- and below-ground vegetation structures regulate SOC storage of grasslands during woody plant expansion 不同的地上和地下植被结构调节着木本植物扩张过程中草地有机碳的储存
IF 1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-31 DOI: 10.1016/j.jclepro.2026.147662
Jinyue Wang, Xia Hu
A global trend of woody plant expansion is an important ecological issue in arid and semi-arid regions. Knowledge gaps remain regarding alterations in above- and below-ground vegetation structures, and the importance of their regulation on soil organic carbon (SOC) storage during woody plant expansion process. In this study, typical shrub-covered grasslands were selected along the mean annual precipitation (MAP) gradient to investigate the regulatory effects of above- and below-ground vegetation structures on SOC storage, with shrub-uncovered plots used as controls. The results revealed that, woody plant expansion significantly increased root density, surface area density, node density, and branch density. "Bimodal trends" in the root surface area and node density were observed, with peaks at 136 mm and 236 mm MAPs. Woody plant expansion significantly reduced the evenness and Simpson's index in the 132–186 mm MAPs. Woody plant expansion significantly reduced total organic carbon (TOC) storage by 28.52 %, particulate organic carbon (POC) storage by 15.41 %, and mineral-associated organic carbon (MAOC) storage by 22.72 %, and increased dissolved organic carbon (DOC) storage by 30.38 %. With the decreasing MAP gradient, the TOC and MAOC storage in the shrub-covered grasslands tended to decrease, whereas the POC and DOC storage tended to first increase then decrease. During the woody plant expansion process, the key root structure influencing SOC shifted from roots >3 mm to roots <3 mm in diameter. In shrub-covered grasslands, roots with diameters of 1–3 mm were the primary contributors to POC storage, whereas those with diameters <1 mm were the primary contributors to DOC. The main factors influencing SOC storage changed from the combined above- and below-ground structures to the aboveground structure, which explained 84.7 % of the variation. The main factors influencing POC storage changed from climatic factors to belowground structural factors. The main factors influencing DOC storage changed from climatic factors to a combination of above-ground structural and climatic factors. Climatic factors were the main factors influencing TOC and MAOC storage.
全球木本植物扩张趋势是干旱半干旱区重要的生态问题。在木本植物生长过程中,地上和地下植被结构的变化及其对土壤有机碳(SOC)储量的调节作用仍然存在知识空白。本研究以年平均降水量(MAP)梯度为研究区,以灌木覆盖地为对照,研究地表和地下植被结构对土壤有机碳储量的调节作用。结果表明,木本植物扩张显著增加了根密度、表面积密度、节密度和分枝密度。根表面积和节点密度呈“双峰趋势”,在136 mm和236 mm map处达到峰值。木本植物扩张显著降低了132 ~ 186 mm土壤的均匀度和辛普森指数。木本植物扩张使总有机碳(TOC)储量减少28.52%,颗粒有机碳(POC)储量减少15.41%,矿物伴生有机碳(MAOC)储量减少22.72%,溶解有机碳(DOC)储量增加30.38%。随着MAP梯度的减小,灌丛草地TOC和MAOC储量呈减少趋势,POC和DOC储量呈先增加后减少的趋势。在木本植物扩张过程中,影响有机碳的关键根系结构从直径为3 mm的根系向直径为3 mm的根系转移。在灌丛草地上,直径为1 ~ 3mm的根系对POC的贡献最大,而直径为1mm的根系对DOC的贡献最大。影响土壤有机碳储量的主要因素由地上地下复合结构向地上结构转变,占总变化量的84.7%。影响POC储量的主要因素由气候因素转变为地下结构因素。影响DOC储量的主要因子由气候因子转变为地上结构因子与气候因子的组合。气候因子是影响TOC和MAOC储量的主要因素。
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引用次数: 0
Lignite as a multifunctional additive to enhance methanogenesis and digestate humification in anaerobic digestion via facilitated electron transfer 褐煤作为一种多功能添加剂,通过促进电子转移促进厌氧消化过程中的甲烷生成和腐殖化
IF 1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-01-31 DOI: 10.1016/j.jclepro.2026.147602
Kaijun Wang , Yasir Abbas , Muhammad Saqlain Jamil , Fayyaz Ali Shah , Linxuan Li , Pei Liang , Xingpeng Jing , Litong Ma , Weihuang Zhu , Sining Yun
While lignite has been explored as a co-substrate in anaerobic digestion (AD), its role as a multifunctional additive and the underlying mechanisms through which it enhances AD performance and digestate humification remain inadequately studied. This work systematically evaluated the effects of lignite particle size (large, medium, small) and dosage (1.0–8.0 wt%) on biogas production and digestate quality. Lignite amendment significantly improved cumulative biogas yield (289.3–373.8 mL/g VS), cumulative CH4 yield (178.7–243.6 mL/g VS), and anaerobic biodegradability (35.5–48.4 %) compared to the control (234.2 mL/g VS, 129.7 mL/g VS, 25.8 %). CH4 content increased from 55.4 % to 61.8–66.7 %, with a corresponding decrease in CO2. Small-sized lignite at 2.0 wt% exhibited optimal improvement, consistent with its high electron exchange capacity (0.89 μmol e g−1). Graphitized structure and abundant surface functional groups of lignite enhanced electrochemical activity, with limiting current response increasing from −4.4 mA and 1.2 mA to −13.8 mA and 2.5 mA, and solution resistance and charge transfer resistance reducing from 15.6 Ω and 11.9 Ω to 12.4 Ω and 8.5 Ω, respectively. Lignite amendment enriched key microbial populations, elevating the relative abundances of syntrophic bacteria (Firmicutes) and methanogens (Methanobacterium, Methanosarcina, Methanofollis) by 13.4–15.0 % and 11.0–13.0 %, respectively. These synergistic improvements facilitated extracellular electron transfer and promoted CO2 conversion to CH4. Furthermore, lignite addition increased the nutrient (4.07–4.16 %) and humic acid (32.6–41.4 %) content of the digestate, indicating enhanced humification. These findings demonstrate that lignite serves as an effective multifunctional additive to simultaneously boost energy recovery and digestate quality in AD systems, offering a promising strategy for the valorization of low-rank coal in waste-to-bioenergy conversion.
虽然褐煤已被作为厌氧消化(AD)的共底物进行了探索,但其作为多功能添加剂的作用及其提高AD性能和消化腐殖化的潜在机制仍未得到充分研究。本研究系统地评价了褐煤粒径(大、中、小)和投加量(1.0-8.0 wt%)对沼气产量和沼液质量的影响。与对照组(234.2 mL/g VS、129.7 mL/g VS、25.8%)相比,褐煤改性显著提高了累积沼气产率(289.3 ~ 373.8 mL/g VS)、累积CH4产率(178.7 ~ 243.6 mL/g VS)和厌氧生物降解率(33.5 ~ 48.4%)。CH4含量由55.4%增加到61.8 ~ 66.7%,CO2含量相应降低。2.0 wt%的小尺寸褐煤表现出最佳的改善效果,这与它的高电子交换容量(0.89 μmol e−g−1)一致。石墨化结构和丰富的表面官能团增强了褐煤的电化学活性,其极限电流响应从−4.4 mA和1.2 mA增加到−13.8 mA和2.5 mA,溶液电阻和电荷转移电阻分别从15.6 Ω和11.9 Ω降低到12.4 Ω和8.5 Ω。褐煤改良使关键微生物种群丰富,使合成细菌(厚壁菌门)和产甲烷菌(Methanobacterium, Methanosarcina, methanofolis)的相对丰度分别提高13.4% ~ 15.0%和11.0% ~ 13.0%。这些协同改善促进了细胞外电子转移,促进了CO2向CH4的转化。此外,褐煤增加了消化液中营养物质(4.07 - 4.16%)和腐殖酸(32.6 - 41.4%)含量,表明腐殖质化增强。这些发现表明,褐煤作为一种有效的多功能添加剂,可以同时提高AD系统的能量回收率和消化质量,为低阶煤在废物到生物能源转化中的价值化提供了一种有前途的策略。
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Journal of Cleaner Production
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