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Well-to-Wake greenhouse gas emissions of sustainable aviation fuels: Implications from South Korean case for energy-importing countries with fuel production capacity 可持续航空燃料从井到井的温室气体排放:韩国案例对具有燃料生产能力的能源进口国的启示
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-21 DOI: 10.1016/j.jclepro.2026.148030
Hyo Young Kim, Yujin Jung, Wonjae Choi
The expansion of sustainable aviation fuel (SAF) is vital for achieving net-zero in the aviation sector. Some major aviation fuel-producing countries with advanced SAF production capabilities remain highly dependent on imported energy resources, which substantially complicates SAF supply chains, increases greenhouse gas (GHG) emissions from SAF production, and requires a differentiated analytical approach. This study examines the implications of such conditions by selecting South Korea as a representative case. To assess the implications of energy import dependence on SAF's life cycle GHG emissions, a Well-to-Wake assessment is conducted for three representative SAF production pathways: used cooking oil (UCO), tallow, and e-fuel. In energy-importing countries, SAF derived from UCO and e-fuels generates up to 66.7% and 44.0% higher life cycle GHG emissions, respectively, compared to energy-self-sufficient nations, primarily due to differences in hydrogen supply pathways. UCO- and tallow-based SAF achieve life cycle GHG emissions more than 77% lower than those of conventional jet fuel (82.71 kg-CO2-eq./GJ) across all hydrogen and electricity production pathways, whereas e-fuel-based SAF achieves lower emissions only when green or yellow hydrogen imported in the form of ammonia is utilized. Policymakers should position UCO-based SAF as the core component of the SAF mix, while for e-fuel-based SAF, they should prioritize the pathways of hydrogen as the key variable to establish a roadmap that minimizes uncertainty. These results are applicable to other countries that rely on energy imports for fuel production.
可持续航空燃料(SAF)的推广对于航空业实现净零排放至关重要。一些拥有先进SAF生产能力的主要航空燃料生产国仍然高度依赖进口能源,这大大复杂化了SAF供应链,增加了SAF生产中的温室气体(GHG)排放,需要采用差异化的分析方法。本研究选取韩国作为代表性案例,探讨这种情况的影响。为了评估能源进口依赖对SAF生命周期温室气体排放的影响,对三种代表性的SAF生产途径进行了从油井到wake的评估:用过的食用油(UCO)、牛脂和电子燃料。在能源进口国,与能源自给国家相比,来自UCO和电子燃料的SAF产生的生命周期温室气体排放量分别高出66.7%和44.0%,这主要是由于氢供应途径的差异。UCO和牛油基SAF的生命周期温室气体排放量比传统航空燃料(82.71千克-二氧化碳当量)低77%以上。/GJ)适用于所有氢气和电力生产途径,而基于电子燃料的SAF只有在利用以氨形式进口的绿色或黄色氢气时才能实现更低的排放。政策制定者应将基于ucf的SAF定位为SAF组合的核心组成部分,而对于基于e燃料的SAF,他们应优先考虑氢的途径,将其作为关键变量,以建立路线图,最大限度地减少不确定性。这些结果也适用于其他燃料生产依赖能源进口的国家。
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引用次数: 0
Tailoring hydrogen bond acceptors in deep eutectic solvents for efficient hydrothermal production and biphasic recovery of 5-methylfurfural from waste activated sludge 在深度共晶溶剂中定制氢键受体,用于高效水热生产和从废活性污泥中双相回收5-甲基糠醛
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-21 DOI: 10.1016/j.jclepro.2026.148060
Cheng Huang, Xiaoping Liu, Yunbo Zhai, Hongkui He, Changlan Hou, Jian Hu, Yin Zhou, Tao Liu
This study innovatively developed a series of functionalized oxalic acid-based deep eutectic solvents (DESs) and achieved efficient conversion of waste activated sludge (WAS) into high-value 5-methylfurfural (5-MF) chemical through systematic modulation of functional groups (-Cl, -COOH, -CH3, -C=C, -OH) in hydrogen bond acceptors (HBAs). For the first time, the structure-activity relationship between DES functional group characteristics and catalytic performance was elucidated through an integrated experimental and theoretical analysis, revealing that -Cl modified DES markedly enhanced sludge conversion efficiency (5-MF yield: 10.51‰) due to its unique electronic effects and hydrogen bonding interactions. The DES effectively disrupted the extracellular polymeric substances (EPS) network of sludge through hydrogen bonding, facilitating the release of biomacromolecules (proteins, polysaccharides) and key metal ions (Mn, Cr, Mg, etc.). Further investigation demonstrated that the DES-metal synergistic catalytic system markedly promoted the isomerization-dehydration pathway of sludge carbohydrate, while DES itself participated in subsequent esterification/hydrogenolysis reactions as a proton carrier, enabling HMF conversion to 5-MF. Notably, this study innovatively established a DES/organic solvent biphasic reaction system, which not only increased the 5-MF yield to 14.89‰ through in situ extraction strategy but also improved product separation efficiency, demonstrating economically viable benefits (1.17 $/t WAS). This work provides an integrated "solvent design-catalysis-separation" strategy for sludge valorization, offering mechanistic insights and foundational knowledge for future scale-up studies.
本研究创新性地开发了一系列功能化草酸基深度共晶溶剂(DESs),通过系统调节氢键受体(HBAs)中的官能团(-Cl、-COOH、-CH3、-C=C、-OH),实现了废活性污泥(WAS)高效转化为高价值5-甲基糠醛(5-MF)化学品。首次通过实验与理论的综合分析,阐明了DES官能团特征与催化性能之间的构效关系,揭示了-Cl改性DES由于其独特的电子效应和氢键相互作用,显著提高了污泥转化率(5-MF产率:10.51‰)。DES通过氢键有效破坏污泥胞外聚合物质(EPS)网络,促进生物大分子(蛋白质、多糖)和关键金属离子(Mn、Cr、Mg等)的释放。进一步研究表明,DES金属协同催化体系显著促进了污泥碳水化合物的异构化-脱水途径,而DES本身作为质子载体参与了后续的酯化/氢解反应,使HMF转化为5-MF。值得注意的是,本研究创新性地建立了DES/有机溶剂双相反应体系,通过原位提取策略,不仅将5-MF收率提高到14.89‰,而且提高了产品分离效率,具有经济可行性(1.17美元/吨WAS)。这项工作为污泥增值提供了一个综合的“溶剂设计-催化-分离”策略,为未来的大规模研究提供了机制见解和基础知识。
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引用次数: 0
Corporate social responsibility, community resilience, and quality of life in mining communities: Moderating roles of green mining and governance 矿业社区的企业社会责任、社区弹性和生活质量:绿色采矿和治理的调节作用
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-21 DOI: 10.1016/j.jclepro.2026.148039
Wilhelmina Seyome Ahiaku, Yusheng Kong
Mining remains vital to Ghana's economy but continues to cause environmental degradation and social inequality in host communities. Although mining firms increasingly implement Corporate Social Responsibility (CSR) initiatives, their effects on community well-being remain uncertain. This study examines how CSR dimensions influence residents' quality of life (QoL) through community resilience and the mediating role of the Social License to Operate (SLO). It further explores how green mining practices and government involvement moderate these relationships. Guided by stakeholder and resilience theories, data were collected from 1120 respondents across five mining communities in the Ashanti and Western Regions of Ghana. Using Partial Least Squares Structural Equation Modeling (PLS-SEM) and Artificial Neural Networks (ANN), the study identifies both linear and non-linear associations. Results show that environmental CSR has the strongest positive effect on QoL, while community adaptation is the most influential resilience factor. SLO partially mediates the CSR–QoL relationship, and both green mining and government involvement strengthen these effects. The findings provide theoretical and practical insights for aligning CSR initiatives with resilience-building and sustainable community development goals.
采矿业对加纳经济仍然至关重要,但在东道国社区继续造成环境恶化和社会不平等。虽然矿业公司越来越多地实施企业社会责任(CSR)倡议,但它们对社区福祉的影响仍然不确定。本研究探讨了企业社会责任维度如何通过社区弹性和社会经营许可证(SLO)的中介作用影响居民生活质量。它进一步探讨了绿色采矿实践和政府参与如何调节这些关系。在利益相关者和弹性理论的指导下,从加纳阿散蒂和西部地区五个采矿社区的1120名受访者中收集了数据。利用偏最小二乘结构方程模型(PLS-SEM)和人工神经网络(ANN),研究确定了线性和非线性关联。结果表明,环境社会责任对生活质量的正向影响最大,而群落适应是影响最大的复原力因子。SLO在企业社会责任与生活质量的关系中起部分中介作用,绿色开采和政府参与都强化了这一作用。研究结果为将企业社会责任倡议与韧性建设和可持续社区发展目标相结合提供了理论和实践见解。
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引用次数: 0
Surfactant life cycle assessment: The environmental performance of surfactin produced by Bacillus Subtilis 表面活性剂生命周期评价:枯草芽孢杆菌生产表面活性剂的环境性能
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-21 DOI: 10.1016/j.jclepro.2026.148034
Óliver Silva Costa Barreto, Edna dos Santos Almeida, Diego Lima Medeiros
Surfactants are used in a variety of industries due to their surface tension reduction properties. This study aims to evaluate the environmental performance of surfactin, from raw material extraction to the factory gate at an industrial scale, using Life Cycle Assessment (LCA) according to ISO 14040/44 standards. The OpenLCA 2.0.0 software and Ecoinvent 3.8 database were used for this analysis. The production of 1 kg of 89% w/w purified surfactin was assessed across seven scenarios, varying the fermentation medium and surfactin concentration, considering six environmental categories. Contribution analyses highlighted that utility consumption (electricity, air pumping, and steam), the carbon source used as a substrate, and surfactin yield, which ranged from 5 to 26% w/w, were the most significant variables for the assessed categories. Alternative scenarios were proposed, including the use of residual carbon sources, 16% w/w substrate-to-surfactin optimal conversion rate, and electricity supplier substitution from grid to photovoltaic power plants. These combined proposals demonstrated favorable results for the majority of the assessed categories, reducing fossil energy consumption (72%), global warming (72%), ozone depletion (51%), water consumption (40%), and ecotoxicity (3%) compared to the most favorable of the seven base scenarios. Expanding the system boundary to compare multiproduct scenarios for the production of Linear Alkylbenzene Sulfonate (LAS) surfactant and waste disposal versus surfactin production from residual carbon sources revealed that the carbon footprint of surfactin can be lower than that of the multiproduct LAS scenario. Thus, the findings highlight viable pathways for mitigating the environmental impacts associated with the life cycle of surfactin production.
表面活性剂由于其降低表面张力的特性而被广泛应用于各种工业中。本研究旨在根据ISO 14040/44标准,使用生命周期评估(LCA)来评估表面素在工业规模下从原料提取到工厂大门的环境性能。采用OpenLCA 2.0.0软件和Ecoinvent 3.8数据库进行分析。考虑到六种环境类别,在不同的发酵培养基和表面素浓度下,评估了1千克89% w/w纯化表面素的产量。贡献分析强调,公用事业消耗(电力、空气泵送和蒸汽)、用作基质的碳源和表面素产量(范围从5%到26% w/w)是评估类别中最重要的变量。提出了可替代方案,包括利用剩余碳源,16% w/w基质到表面素的最佳转化率,以及从电网到光伏电站的电力供应商替代。与七个基本情景中最有利的情景相比,这些综合方案在大多数评估类别中显示出有利的结果,减少了化石能源消耗(72%)、全球变暖(72%)、臭氧消耗(51%)、水消耗(40%)和生态毒性(3%)。扩大系统边界,比较多产品生产线性烷基苯磺酸盐(LAS)表面活性剂和废物处理与从残余碳源生产表面锡的情况,发现表面锡的碳足迹可能低于多产品LAS情景。因此,研究结果强调了减轻与表面素生产生命周期相关的环境影响的可行途径。
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引用次数: 0
Optimal operation strategy for energy saving and cost reduction in variable-speed pumping stations: A bi-level multi-objective closed-loop control method coupling water-volume decomposition with intraday operation 变速泵站节能降耗优化运行策略:水量分解与日内运行耦合的双层多目标闭环控制方法
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-21 DOI: 10.1016/j.jclepro.2026.148044
Song Qing, Gang Zhang, Haipeng Nan, Tuo Xie, Huan Wang, Xiaonan Dang
Under the time-varying coupling of time-of-use electricity tariffs and water-demand patterns, variable-speed pumping stations often exhibit a mismatch between water-volume allocation and unit operation, constraining energy- and water-saving performance. This study proposes a two-level multi-objective closed-loop framework of “water-volume decomposition–intra-day operation–feedback correction” to coordinate the trade-offs among operating cost, efficiency, and water spillage. At the upper level, a price–efficiency-driven water-volume decomposition model allocates the daily water demand into hourly discharges aligned with the high-efficiency region of the pump units, avoiding “low-price yet low-efficiency” configurations. At the lower level, an intra-day unit-scheduling model incorporating operating cost, overall efficiency, and daily water spillage is solved using the Non-dominated Sorting Genetic Algorithm III, and a pseudo-weight method is used to extract executable unit on/off and speed schedules. A feedback mechanism based on pattern recognition of excess discharge and convex penalty functions treats discharge violations as soft constraints coupled with time-of-use price period weights and specific energy consumption, thereby dynamically revising the upper-level allocation and forming a “decomposition–execution–feedback–reconstruction” loop. A case study of an intake pumping station serving a large irrigation district in Northwest China shows that, while ensuring water-supply security, the proposed method reduces daily operating cost by about 0.56 %, decreases daily water spillage by 48 %, and increases average daily operating efficiency by 1.13 % compared with empirical dispatch. Relative to a single-level optimization benchmark, the closed-loop framework further improves overall performance and provides a scalable pathway for cost-effective and cleaner operation of variable-speed pumping stations under time-of-use price conditions.
在分时电价和水需求模式的时变耦合下,变速泵站往往表现出水量分配和机组运行之间的不匹配,限制了节能和节水性能。本文提出了“水量分解-日间运行-反馈修正”两级多目标闭环框架,以协调运行成本、效率和溢水之间的权衡。在上层,一个价格效率驱动的水量分解模型将每天的用水需求分配到每小时的排放量,与水泵单元的高效率区域一致,避免了“低价格低效率”的配置。在下层,采用非支配排序遗传算法III求解了考虑运行成本、总效率和日溢水量的日内机组调度模型,并采用伪权法提取可执行机组开/关和速度调度。基于超量排放模式识别和凸罚函数的反馈机制,将排放违规行为作为软约束,与分时电价周期权重和比能耗相耦合,动态修正上层分配,形成“分解-执行-反馈-重构”循环。以西北某大型灌区取水泵站为例研究表明,与经验调度相比,该方法在保证供水安全的前提下,日运行成本降低约0.56%,日溢水量减少48%,日平均运行效率提高1.13%。相对于单级优化基准,闭环框架进一步提高了整体性能,并为变速泵站在分时价格条件下的成本效益和更清洁的运行提供了可扩展的途径。
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引用次数: 0
Development and application of a CRISPR/Cas9n system for deleting multiple secretion-related protein genes in Bacillus amyloliquefaciens to facilitate industrial enzymes clean production CRISPR/Cas9n系统的开发与应用,用于删除解淀粉芽孢杆菌中多个分泌相关蛋白基因,促进工业酶的清洁生产
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-21 DOI: 10.1016/j.jclepro.2026.147950
Maojun Wang, Xinlong Wei, Jiawei Ding, Fuping Lu, Ramon Gonzalez, Aiqin Shi, Yu Li
GRAS-certified Bacillus amyloliquefaciens TCCC 111018 (B.amyloliquefaciens TCCC 111018) has food industry potential for enzyme production, but its clean production is limited by excessive non-target extracellular proteins, raising purification costs and wastewater organics. Here, we developed a dual-plasmid CRISPR/Cas9n system in BA1 (a derivative of B.amyloliquefaciens TCCC 111018) and achieved 93% single-gene deletion efficiency, 40% gene cluster deletion efficiency, and 80% chromosomal insertion efficiency for a 1.06-kb alkaline protease gene. Mass spectrometry analysis of BA5 (a derivative of BA1) fermentation supernatants identified native extracellular proteins, enabling targeted knockout to generate strain BA15. Introduction of plasmid pLY-3-aprE into BA5 and BA15 yielded BA17 and BA24. Compared to BA17, BA24 demonstrated a 29.13% increase in alkaline protease activity. Furthermore, using the split green fluorescent protein (split-GFP) system combined with fluorescence resonance energy transfer (FRET) analysis, excessive heterologous protein secretion was identified as the rate-limiting step. Strain BA15 was employed to express sucrose isomerase and aminopeptidase, respectively. The activity of sucrose isomerase reached 1.78-fold that of the control strain, while that of aminopeptidase was 2.06-fold. Additionally, both the turbidity and protein content of the fermentation supernatant were significantly decreased. Systematic knockout of extracellular non-target proteins not only boosts target enzyme yields but also reduces organic matter in fermentation wastewater. This approach mitigates the environmental footprint of enzyme manufacturing and offers a viable technical pathway for clean production in the industrial enzyme sector.
grass认证的解淀粉芽胞杆菌TCCC 111018 (b.a myyloliquefaciens TCCC 111018)具有食品工业生产酶的潜力,但其清洁生产受到过量非靶细胞外蛋白、提高净化成本和废水有机物的限制。在此,我们在BA1 (b.a myyloliquefaciens TCCC 111018的衍生物)中建立了双质粒CRISPR/Cas9n系统,对1.06 kb的碱性蛋白酶基因实现了93%的单基因缺失效率,40%的基因集群缺失效率和80%的染色体插入效率。BA5 (BA1的衍生物)发酵上清液的质谱分析鉴定出天然的细胞外蛋白,使靶向敲除产生菌株BA15。将pLY-3-aprE质粒导入BA5和BA15,得到BA17和BA24。与BA17相比,BA24的碱性蛋白酶活性提高了29.13%。此外,利用分裂绿色荧光蛋白(split- gfp)系统结合荧光共振能量转移(FRET)分析,鉴定过量的外源蛋白分泌为限速步骤。菌株BA15分别表达蔗糖异构酶和氨基肽酶。蔗糖异构酶活性为对照菌株的1.78倍,氨基肽酶活性为对照菌株的2.06倍。发酵上清液的浊度和蛋白质含量均显著降低。系统敲除细胞外非靶蛋白不仅能提高靶酶产量,还能减少发酵废水中的有机物。这种方法减轻了酶制造的环境足迹,并为工业酶部门的清洁生产提供了可行的技术途径。
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引用次数: 0
Geospatial optimization of compost distribution for cropland under California’s organic waste diversion strategy 加州有机废物分流策略下农田堆肥分布的地理空间优化
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-21 DOI: 10.1016/j.jclepro.2026.148075
Siyu Luo, Yihsu Chen, Liliana Xochi Hinojoza, J. Elliott Campbell
Composting has emerged as a key methane mitigation strategy. California has enacted one of the world’s most ambitious organic waste diversion mandates (SB 1383), requiring a 75% reduction in landfill disposal by 2025 compared to 2014 waste disposal levels. While previous studies have demonstrated the climate benefits of this unprecedented regional shift to composting, limited attention has been given to the logistical feasibility of delivering compost to croplands under real-world infrastructure. A critical knowledge gap remains in understanding the spatial alignment between waste generation, processing capacity, and cropland demand. Here we develop a geospatial optimization model that simulates statewide compost logistics using detailed road routing and facility-level data. The model estimates mass-weighted average haul distances of 46 km for organic waste and 80 km for compost, capturing regional variation in supply and demand. Results show that minimizing cost and emissions while meeting diversion targets requires distributing compost from coastal cities to inland agricultural regions. Nearly 70% of compost is allocated to Southern California and the San Joaquin Valley — regions prioritized for soil restoration. These findings provide a system-level foundation for planning compost infrastructure to support California’s climate and waste diversion goals.
堆肥已成为一种关键的甲烷减排策略。加州颁布了世界上最雄心勃勃的有机废物转移指令之一(SB 1383),要求到2025年,与2014年的废物处置水平相比,垃圾填埋场处置减少75%。虽然之前的研究已经证明了这种前所未有的地区转向堆肥对气候的好处,但在现实世界的基础设施下,将堆肥运送到农田的物流可行性却受到了有限的关注。在理解废物产生、处理能力和农田需求之间的空间一致性方面,仍然存在一个关键的知识缺口。在这里,我们开发了一个地理空间优化模型,使用详细的道路路线和设施级数据模拟全州堆肥物流。该模型估计,有机废物的质量加权平均运输距离为46公里,堆肥的平均运输距离为80公里,从而捕捉到了供需的区域差异。结果表明,在满足导流目标的同时,要实现成本和排放的最小化,需要将堆肥从沿海城市分配到内陆农业地区。近70%的堆肥被分配到南加州和圣华金河谷——优先恢复土壤的地区。这些发现为规划堆肥基础设施提供了系统级基础,以支持加州的气候和废物转移目标。
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引用次数: 0
Agri-environmental schemes reduce variable input costs: Evidence from Slovenian farms 农业环境计划减少可变投入成本:来自斯洛文尼亚农场的证据
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-21 DOI: 10.1016/j.jclepro.2026.148054
Štefan Bojnec, Imre Fertő
Agri-environmental schemes (AES) are central policy instruments designed to promote environmentally friendly agricultural practices by financially supporting the adoption of sustainable land management. While a substantial body of research examines how AES influence environmental outcomes and overall farm performance, far less is known about their direct effects on farm-level variable input costs, particularly in terms of energy, fertilizer, and crop protection expenditures. Existing studies typically analyse eco-efficiency or broad economic-environmental indicators, leaving a critical empirical gap regarding whether and how AES reshape the cost structure of farms during and after adoption. This study addresses this gap by estimating the causal impact of AES participation on key variable input costs using Slovenian Farm Accountancy Data Network data and a Differences-in-Differences (DID) design with staggered adoption, supported by robustness and sensitivity analyses. The findings indicate that AES participation leads to significant reductions in pesticide and energy costs, while fertilizer expenditures tend to increase in the short term before stabilizing or declining over time. These patterns suggest that AES trigger structural adjustments in production—such as reduced tillage intensity and transitions to organic or biological inputs—that can initially raise some input costs but contribute to longer-term sustainability. The study therefore offers new empirical evidence on the cost implications of AES, improving understanding of how environmental policy instruments affect farm-level economic decisions. These insights are essential for designing AES that support both environmental objectives and the economic viability of farmers, particularly in regions where sustainability transitions may involve short-term trade-offs.
农业环境计划(AES)是中央政策工具,旨在通过财政支持采用可持续土地管理来促进环境友好型农业做法。虽然大量的研究考察了农业生产技术如何影响环境结果和整体农场绩效,但对其对农场一级可变投入成本的直接影响知之甚少,特别是在能源、肥料和作物保护支出方面。现有的研究通常分析生态效率或广泛的经济环境指标,在采用AES期间和之后是否以及如何重塑农场的成本结构方面留下了关键的经验空白。本研究利用斯洛文尼亚农场会计数据网络数据和交错采用的差异中差异(DID)设计,通过鲁棒性和敏感性分析来估计AES参与对关键可变投入成本的因果影响,从而解决了这一差距。研究结果表明,AES的参与导致农药和能源成本的显著降低,而肥料支出往往在短期内增加,然后随着时间的推移趋于稳定或下降。这些模式表明,自然环境污染引发生产结构调整,如减少耕作强度和向有机或生物投入过渡,这在最初可能会提高一些投入成本,但有助于长期可持续性。因此,该研究为AES的成本影响提供了新的经验证据,提高了对环境政策工具如何影响农场一级经济决策的理解。这些见解对于设计既支持环境目标又支持农民经济可行性的AES至关重要,特别是在可持续性转型可能涉及短期权衡的地区。
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引用次数: 0
Structural resilience and synergistic nexus in China's embodied water-energy-carbon footprints flow networks 中国水-能源-碳足迹流动网络的结构弹性与协同关系
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-21 DOI: 10.1016/j.jclepro.2026.148062
Delong Liu, Yunxing Wu, Youzhu Zhao, Mo Li, Qiuxiang Jiang, Zilong Wang
Rapid economic growth intensifies risks in water-energy-carbon (W-E-C) systems. To address existing research gaps in the comprehensive evaluation of the risk resilience of W-E-C systems, this study proposes a novel analytical framework from a complex network perspective to assess the structural resilience of water-energy-carbon systems. Using China as a case study, an empirical analysis is conducted to demonstrate the applicability of the proposed framework. The study employs a multi-regional input-output (MRIO) model combined with water-energy-carbon footprint data to quantify embodied W-E-C footprint flows at both provincial and sectoral levels and to construct corresponding flow networks. Network structural resilience is assessed using indicators of hierarchy, assortativity, transmissivity, and clustering. The results indicated: (1) Embodied W-E-C footprints exhibit contrasting evolutionary transfer patterns. Spatially, flows generally shift from western and northern regions to eastern and southern regions. Over time, embodied water footprints transition from cross-regional to adjacent transfers, whereas embodied energy-carbon footprints show an opposite trend. At the sectoral level, agriculture is the main outflow sector for embodied water footprints, while the chemical industry and metal products manufacturing dominate embodied energy-carbon outflows, with construction and services acting as major inflow sectors. (2) Clear differences in synergy exist between provincial and sectoral levels: provincial W-E-C synergies strengthen during 2002-2017 with an emerging north-south divergence, whereas intersectoral synergies remain insignificant. (3) Structural resilience improves in interprovincial W-E-C networks but shows limited change in intersectoral energy-carbon networks, while a gradual decline is observed in intersectoral water footprint networks. The core contribution of this study lies in providing, for the first time, a methodological framework for assessing the resilience of coupled resource systems within the context of economic transition. Its empirical findings can offer data-driven and policy-relevant insights for optimising resource trade patterns, enhancing the risk resilience of the W-E-C systems, and advancing sustainable development.
快速的经济增长加剧了水-能源-碳(W-E-C)系统的风险。针对水-能-碳系统风险弹性综合评价的研究空白,本文提出了一种基于复杂网络视角的水-能-碳系统结构弹性评价分析框架。本文以中国为例,进行了实证分析,以证明该框架的适用性。本研究采用多区域投入产出(MRIO)模型,结合水-能源-碳足迹数据,在省级和部门层面量化具体的水-e -c足迹流动,并构建相应的流动网络。网络结构弹性评估使用层次,分类,传递性和聚类指标。结果表明:(1)W-E-C足迹具有不同的进化转移模式。空间上,流动总体由西部和北部地区向东部和南部地区转移。随着时间的推移,隐含水足迹从跨区域转移向相邻转移转变,而隐含能源碳足迹则呈现相反的趋势。在部门层面,农业是隐含水足迹的主要流出部门,而化学工业和金属制品制造业主导隐含能源-碳流出,建筑和服务业是主要流入部门。(2)省际和部门间协同效应存在明显差异:2002-2017年,省域W-E-C协同效应增强,且呈现南北差异,而部门间协同效应不显著。(3)水足迹网络的结构弹性在省际水足迹网络中呈上升趋势,但在省际能源碳网络中变化有限,而在省际水足迹网络中则呈逐渐下降趋势。本研究的核心贡献在于首次提供了一个评估经济转型背景下耦合资源系统弹性的方法框架。其实证研究结果可以为优化资源贸易模式、增强世界经济和社会体系的风险抵御能力以及促进可持续发展提供数据驱动和政策相关的见解。
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引用次数: 0
“Two-in-one” luminescent MOFs/sodium alginate aerogel beads for sensitive detection of Al3+ and efficient enrichment of Pb2+ in water “二合一”发光mof /海藻酸钠气凝胶珠灵敏检测水中Al3+和高效富集Pb2+
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-21 DOI: 10.1016/j.jclepro.2026.148057
Jihao Li, Jiantong Zheng, Yang Gu, Lu Wang, Peipei Zhang, Huixiang Zhang, Rongyang Fan, Ai-Yun Ni, Haijun Tan
Accurate detection and efficient removal of metal ions from wastewater are critical for environmental protection. However, existing materials often face challenges in integrating the dual functions of highly sensitive detection and efficient adsorption. In this study, a bifunctional aerogel bead, designated as SA@UiO-66-(OH)2/(COOH)2, was successfully prepared by incorporating the metal-organic framework (MOFs) UiO-66-(OH)2/(COOH)2, which contains abundant functional groups, into a sodium alginate (SA) matrix. This composite simultaneously achieves rapid and highly sensitive fluorescence detection of Al3+, with a response time of 30 s and a detection limit of 0.79 μM, and high-capacity adsorption of Pb2+, exhibiting a maximum adsorption capacity of 335.8 mg/g. These results overcome the limitations of single-function materials. Moreover, by encapsulating the powder within SA-based aerogel beads, the material was converted into macroscopic beads that are easily recoverable and exhibit good mechanical strength. This approach effectively addresses key practical bottlenecks in water treatment, namely difficulties in material separation and poor stability. Based on experimental and characterization data, the mechanisms underlying detection and adsorption were thoroughly investigated. Furthermore, when applied to practical water samples such as tap water, lake water, and river water, the aerogel beads maintained high recovery rates for Pb2+. In summary, this work presents a material capable of efficiently detecting Al3+ and effectively removing Pb2+ from water, offering a promising strategy for the synergistic management of multiple pollutants in real-world water treatment scenarios.
准确检测和高效去除废水中的金属离子对环境保护至关重要。然而,现有材料在整合高灵敏度检测和高效吸附双重功能方面往往面临挑战。本研究将含有丰富官能团的金属-有机骨架(mof) UiO-66-(OH)2/(COOH)2加入海藻酸钠(SA)基质中,成功制备了双功能气凝胶珠SA@UiO-66-(OH)2/(COOH)2。该复合材料同时实现了对Al3+的快速、高灵敏度的荧光检测,响应时间为30 s,检出限为0.79 μM;同时实现了对Pb2+的高容量吸附,最大吸附量为335.8 mg/g。这些结果克服了单一功能材料的局限性。此外,通过将粉末包封在sa基气凝胶珠内,将材料转化为易于回收且具有良好机械强度的宏观微球。这种方法有效地解决了水处理的关键实际瓶颈,即物质分离困难和稳定性差。基于实验和表征数据,深入研究了检测和吸附的机制。此外,当应用于自来水、湖水和河水等实际水样时,气凝胶珠对Pb2+保持了较高的回收率。总之,这项工作提出了一种能够有效检测水中Al3+并有效去除水中Pb2+的材料,为现实世界水处理场景中多种污染物的协同管理提供了一种有前途的策略。
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引用次数: 0
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Journal of Cleaner Production
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