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Utility-scale photovoltaic carbon footprint evaluation from a spatio-temporal dynamic life cycle perspective: A case study of China 基于时空动态生命周期视角的公用事业规模光伏碳足迹评价——以中国为例
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-20 DOI: 10.1016/j.jclepro.2026.148002
Zhuoyang Xie, Xueying Bao, Jingle Liu, Haiwen Li, Zhongshuai Shen
As China accelerates its transition toward carbon neutrality, evaluating the life-cycle carbon and energy performance of photovoltaic systems is critical to defining the real pathway toward a low-carbon energy future. Previous studies have faced three major limitations: they failed to integrate temporal dynamics and spatial heterogeneity, lacked systematic assessments at a national scale with city-level resolution, and overlooked the impact of actual grid absorption on carbon accounting. This study develops a spatio-temporal dynamic life-cycle assessment (ST-DLCA) model that integrates multi-source data across temporal, spatial, and process dimensions to quantify the evolving carbon, energy, and techno-economic performance of utility-scale photovoltaic systems in China. The ST-DLCA results reveal clear spatio-temporal patterns and continuous improvement in both environmental and economic performance. From 2015 to 2024, the average life-cycle carbon intensity (CI) declined from 45.7 to 25.4 g CO2e/kWh, the energy payback time (EPBT) shortened from 4.36 to 2.86 years, the energy return on investment (EROI) rose from about 5.5 to 8.0, and the levelized cost of electricity (LCOE) decreased from 0.465 to 0.182 CNY/kWh. Overall, this study provides a comprehensive evaluation of the spatio-temporal evolution of carbon intensity, energy performance, and techno-economic indicators of China's utility-scale PV systems. The findings deepen understanding of how technological progress, grid decarbonization, and regional resource endowment jointly shape PV decarbonization potential, offering scientific guidance for optimizing deployment strategies and supporting China's long-term carbon neutrality transition.
随着中国加速向碳中和转型,评估光伏系统的生命周期碳和能源性能对于确定通往低碳能源未来的真正途径至关重要。以往的研究存在三个主要的局限性:未能整合时间动态和空间异质性,缺乏在国家尺度上具有城市分辨率的系统评估,忽略了实际网格吸收对碳核算的影响。本研究开发了一个时空动态生命周期评估(ST-DLCA)模型,该模型集成了跨时间、空间和过程维度的多源数据,以量化中国公用事业规模光伏系统的碳、能源和技术经济绩效的演变。ST-DLCA结果揭示了清晰的时空格局和环境和经济绩效的持续改善。从2015年到2024年,平均生命周期碳强度(CI)从45.7 g CO2e/kWh下降到25.4 g CO2e/kWh,能源回收期(EPBT)从4.36年缩短到2.86年,能源投资回报率(EROI)从5.5左右上升到8.0,平准化电力成本(LCOE)从0.465元/kWh下降到0.182元/kWh。总体而言,本研究对中国公用事业规模光伏发电系统的碳强度、能源性能和技术经济指标的时空演变进行了综合评估。研究结果加深了对技术进步、电网脱碳和区域资源禀赋如何共同影响光伏脱碳潜力的理解,为优化部署策略和支持中国长期碳中和转型提供了科学指导。
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引用次数: 0
Evaluating sustainability in innovation ecosystems: monitoring indicators and the role of business incubatos 评估创新生态系统的可持续性:监测指标和企业孵化器的作用
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-19 DOI: 10.1016/j.jclepro.2026.148036
Milena Maredmi Corrêa Teixeira, Clarissa Stefani Teixeira, Deoclécio Junior Cardoso da Silva, Luis Felipe Dias Lopes
This study investigates the role of business incubators in promoting sustainability within innovation ecosystems by proposing and validating monitoring indicators aimed at strengthening management practices and supporting public policy formulation. The fuzzy Delphi and random forest importance techniques were applied to assess the relevance and prioritization of indicators across three dimensions: Legal, Organizational, and Managerial Structure, Services, and Strategic Interactions. The findings show that strategic interactions are the most decisive factor for the long-term sustainability of incubators, followed by the services dimension, which includes mentoring, consultancy, and technical support that are essential for the consolidation of incubated startups. The Legal, Organizational, and Managerial dimension had a relatively lower impact but remains a fundamental support base. These results highlight the need for monitoring tools that capture the interdependence between institutional, operational, and relational factors. The study advances the literature by proposing a robust evaluation model applicable to different contexts and aligned with the Sustainable Development Goals 8, 9, and 17, while offering practical insights for incubator managers and policymakers to foster innovation and sustainable competitiveness.
本研究通过提出和验证旨在加强管理实践和支持公共政策制定的监测指标,探讨了企业孵化器在促进创新生态系统可持续性方面的作用。应用模糊德尔菲和随机森林重要性技术评估了三个维度指标的相关性和优先级:法律、组织和管理结构、服务和战略互动。研究结果显示,战略互动是孵化器长期可持续性的最决定性因素,其次是服务维度,包括指导、咨询和技术支持,这对孵化的初创企业的整合至关重要。法律、组织和管理维度的影响相对较低,但仍然是基本的支持基础。这些结果突出了对监测工具的需求,这些工具可以捕捉机构、操作和关系因素之间的相互依赖关系。该研究提出了一个适用于不同背景的稳健评估模型,并与可持续发展目标8、9和17保持一致,从而推进了文献研究,同时为孵化器管理者和政策制定者提供了促进创新和可持续竞争力的实践见解。
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引用次数: 0
Pre-cultivation of nitrifying biofilms for rapid start-up of biofilm reactors: Manipulation by the biocarrier packing mode and fluid conditions 生物膜反应器快速启动的硝化生物膜预培养:生物载体填料方式和流体条件的操作
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-19 DOI: 10.1016/j.jclepro.2026.148024
Ying-yu Li, Pei Wang, Guiyun Chen, Lin Lin, Xiao-yan Li
The slow enrichment of autotrophic nitrifying biofilms remains a critical bottleneck restricting the rapid start-up of biofilm technologies for low-strength wastewater treatment. In this study, quartz crystal microbalance with dissipation monitoring (QCM-D) and Bayesian SourceTracker analysis were integrated to establish a microscale, process-oriented framework for deciphering how hydrodynamic conditions and carrier packing patterns regulate the biofilm formation in three distinct reactor systems: moving-bed biofilm reactor (MBBR), packed-bed biofilm reactor (PBBR), and trickling filter (TF). Among these, PBBR, characterized by reduced fluid turbulence, exhibited markedly enhanced biofilm development. During the initial cultivation phase, QCM-D revealed that microbial communities adhered more rapidly to the carrier surfaces and formed highly viscoelastic biolayers (|ΔD/Δf| = 0.379) in the PBBR. Within 7 days, the biofilm density reached 231.1 mg SS/m2, and the specific growth rate was more than 10 times higher than that in the MBBR and TF. SourceTracker analysis further revealed that more than 70% of biofilm accumulation was driven by the self-proliferation of pre-existing colonies rather than continuous planktonic adhesion, thereby enabling a semi-quantitative assessment of suspended sludge contribution and providing mechanistic support for commonly applied sludge reduction strategies. Furthermore, biofilms pre-cultivated in the PBBR maintained high ammonium oxidation rates (>98%) after its transition to a more dynamic MBBR condition. These findings validate the feasibility of employing PBBR as an effective means of biofilm pre-cultivation and offer a practical strategy for achieving rapid start-up and stable operation of high-performance biofilm reactors for wastewater treatment.
自养硝化生物膜富集缓慢是制约低强度废水处理生物膜技术快速启动的关键瓶颈。在这项研究中,石英晶体微平衡与耗散监测(QCM-D)和贝叶斯SourceTracker分析相结合,建立了一个微尺度的、面向过程的框架,用于解读流体动力条件和载体填充模式如何调节三种不同反应器系统中的生物膜形成:移动床生物膜反应器(MBBR)、填充床生物膜反应器(PBBR)和滴滤(TF)。其中,PBBR以减少流体湍流为特征,显著促进了生物膜的发育。在初始培养阶段,QCM-D显示微生物群落在PBBR中更快地粘附在载体表面并形成高粘弹性生物层(|ΔD/Δf| = 0.379)。在7 d内,生物膜密度达到231.1 mg SS/m2,比生长速度比MBBR和TF提高了10倍以上。SourceTracker分析进一步显示,超过70%的生物膜积累是由已有菌落的自我增殖驱动的,而不是连续的浮游生物粘附,从而可以半定量地评估悬浮污泥的贡献,并为常用的污泥减少策略提供机制支持。此外,在PBBR中预培养的生物膜在过渡到更动态的MBBR条件后保持了较高的氨氧化率(>98%)。研究结果验证了PBBR作为生物膜预培养有效手段的可行性,为实现污水处理高性能生物膜反应器的快速启动和稳定运行提供了切实可行的策略。
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引用次数: 0
Multi-input and multi-output prediction of influent water quality in wastewater treatment plants based on active deep learning 基于主动深度学习的污水处理厂进水水质多输入多输出预测
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-19 DOI: 10.1016/j.jclepro.2026.148067
Zifei Wang, Huaqing Qi, Song Hu, Xiaoyu Wu, Yulin Han, Yi Man
As environmental protection standards become increasingly stringent, wastewater treatment plants (WWTPs) must precisely control aeration volumes and chemical additions to achieve improved effluent quality. The accurate and rapid prediction of water pollutant loads is becoming increasingly urgent. An efficient multi-input, multi-output water-quality prediction model has become a practical necessity for WWTPs. However, the multi-input multi-output model needs to capture the complex interactions between input and output variables, as well as the hidden temporal characteristics of the water quality sequence. It often requires a complex model design and a large amount of training data to achieve good prediction results. The complex model design and extensive data training entail high time and computational resource costs, which will limit the model's applicability. Based on this, this study proposes an active deep learning framework. This framework first queries high-value samples in the data using an active learning module, and then learns the hidden, complex relationships within them using a multi-module fusion deep learning architecture. While ensuring the accuracy of the model's predictions, it significantly reduces the cost of training and the model's computational resource usage. This study uses a municipal WWTP as a case study to predict influent COD and NH3-N loads. The results show that, compared with the traditional passive deep learning model, the active deep learning framework proposed in this study can achieve a prediction effect similar to that of passive learning while reducing the model's time cost by 39.8% and the model's computational resource usage by 18.4%.
随着环保标准的日益严格,污水处理厂必须精确控制曝气量和化学添加量,以提高出水质量。准确、快速地预测水体污染物负荷已成为当务之急。高效的多输入、多输出水质预测模型已成为污水处理厂建设的现实需要。然而,多输入多输出模型需要捕捉输入和输出变量之间复杂的相互作用,以及隐藏的水质序列的时间特征。通常需要复杂的模型设计和大量的训练数据才能获得良好的预测结果。复杂的模型设计和大量的数据训练需要耗费大量的时间和计算资源,这限制了模型的适用性。基于此,本研究提出了一个主动深度学习框架。该框架首先使用主动学习模块查询数据中的高价值样本,然后使用多模块融合深度学习架构学习其中隐藏的复杂关系。在保证模型预测准确性的同时,显著降低了训练成本和模型的计算资源使用。本研究以某城市污水处理厂为例,预测其COD和NH3-N负荷。结果表明,与传统被动深度学习模型相比,本文提出的主动深度学习框架可以达到与被动学习相似的预测效果,同时将模型的时间成本降低39.8%,模型的计算资源使用降低18.4%。
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引用次数: 0
Pathways for clean energy transition in rural China: Natural gas vs. photovoltaic power 中国农村清洁能源转型之路:天然气与光伏发电
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-19 DOI: 10.1016/j.jclepro.2026.148013
Chunying Liu, Qi Liao, Renfu Tu, Xiaomeng Bai, Kaikai Lu, Likun Peng, Yongtu Liang, Haoran Zhang
Accelerating the clean energy transition in vast rural areas still heavily reliant on traditional energy sources is critical for achieving carbon neutrality. To address regional heterogeneity and avoid one-size-fits-all solutions, this study proposes a unified multi-objective optimization framework integrating spatial clustering and Mixed-Integer Linear Programming (MILP) to coordinate provincial-level transition pathways. By dynamically coupling coal-to-gas and county-wide photovoltaic (PV) policies, the model achieves the synergistic optimization of regional transition strategies and natural gas pipeline network expansion. A case study of Liaoning Province demonstrates that under the baseline scenario, the coordinated approach yields a clean energy share of 44.92% and reduces annual emissions by 28.62%. Multi-scenario analyses with varying emission reduction targets and subsidy schemes identify the 40% emission reduction target as the strategic inflection point for the transition from a gas-dominant approach to a gas-PV complementary framework. However, overlapping aggressive subsidies under deep decarbonization push government abatement costs up to 2.25 kCNY/t, cautioning against fiscally unsustainable dual-incentive policies. Furthermore, sensitivity analysis on natural gas prices and PV penetration rates explicitly quantifies the trade-offs between household economic burdens, government transition costs, and environmental performance. The results show that raising the PV penetration limit from 20% to 60% decreases the government's average abatement cost by 30.1%, while a 20% reduction in natural gas prices lowers household transition burdens by 18.5%. These quantitative insights provide a robust decision-support tool for formulating differentiated policies and coordinating infrastructure planning across large-scale rural regions.
在仍严重依赖传统能源的广大农村地区加快清洁能源转型,对实现碳中和至关重要。为了解决区域异质性问题,避免一刀切的解决方案,本研究提出了一个统一的多目标优化框架,结合空间聚类和混合整数线性规划(MILP)来协调省级过渡路径。该模型通过对煤制气和县域光伏政策的动态耦合,实现了区域转型战略和天然气管网扩张的协同优化。以辽宁省为例研究表明,在基线情景下,协调方法的清洁能源份额为44.92%,年排放量减少28.62%。通过不同减排目标和补贴方案的多情景分析,将40%的减排目标确定为从天然气主导方式向天然气-光伏互补框架过渡的战略拐点。然而,深度脱碳下重叠的激进补贴将政府减排成本推高至每吨2.25克朗,这对财政上不可持续的双重激励政策提出了警告。此外,对天然气价格和光伏渗透率的敏感性分析明确量化了家庭经济负担、政府转型成本和环境绩效之间的权衡。结果表明,将光伏渗透率上限从20%提高到60%,政府的平均减排成本降低了30.1%,而天然气价格降低20%,家庭转型负担降低了18.5%。这些定量见解为制定差异化政策和协调大规模农村地区的基础设施规划提供了强有力的决策支持工具。
{"title":"Pathways for clean energy transition in rural China: Natural gas vs. photovoltaic power","authors":"Chunying Liu, Qi Liao, Renfu Tu, Xiaomeng Bai, Kaikai Lu, Likun Peng, Yongtu Liang, Haoran Zhang","doi":"10.1016/j.jclepro.2026.148013","DOIUrl":"https://doi.org/10.1016/j.jclepro.2026.148013","url":null,"abstract":"Accelerating the clean energy transition in vast rural areas still heavily reliant on traditional energy sources is critical for achieving carbon neutrality. To address regional heterogeneity and avoid one-size-fits-all solutions, this study proposes a unified multi-objective optimization framework integrating spatial clustering and Mixed-Integer Linear Programming (MILP) to coordinate provincial-level transition pathways. By dynamically coupling coal-to-gas and county-wide photovoltaic (PV) policies, the model achieves the synergistic optimization of regional transition strategies and natural gas pipeline network expansion. A case study of Liaoning Province demonstrates that under the baseline scenario, the coordinated approach yields a clean energy share of 44.92% and reduces annual emissions by 28.62%. Multi-scenario analyses with varying emission reduction targets and subsidy schemes identify the 40% emission reduction target as the strategic inflection point for the transition from a gas-dominant approach to a gas-PV complementary framework. However, overlapping aggressive subsidies under deep decarbonization push government abatement costs up to 2.25 kCNY/t, cautioning against fiscally unsustainable dual-incentive policies. Furthermore, sensitivity analysis on natural gas prices and PV penetration rates explicitly quantifies the trade-offs between household economic burdens, government transition costs, and environmental performance. The results show that raising the PV penetration limit from 20% to 60% decreases the government's average abatement cost by 30.1%, while a 20% reduction in natural gas prices lowers household transition burdens by 18.5%. These quantitative insights provide a robust decision-support tool for formulating differentiated policies and coordinating infrastructure planning across large-scale rural regions.","PeriodicalId":349,"journal":{"name":"Journal of Cleaner Production","volume":"14 1","pages":""},"PeriodicalIF":11.1,"publicationDate":"2026-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147492483","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Understanding taxi and ridesourcing drivers’ continuance intention to use battery swapping services 了解的士及专车司机持续使用换电池服务的意向
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-19 DOI: 10.1016/j.jclepro.2026.148053
Kangli Yan, Yuntao Guo, Xinwu Qian, Shuai Zhang, Can Liu, Xinghua Li, Jie Yang
Battery swapping services (BSS) reduce downtime, alleviate range anxiety, and enhance operational efficiency for electric taxi and ridesourcing service (ETRS) drivers. However, drivers' preferences and the key factors shaping their continuance intention to use BSS remain underexplored. Previous studies have largely relied on stated preference surveys constrained by restricted analytical scope and by BSS-inexperienced participants, reducing findings' reliability. To address this gap, we propose an extended Technology Acceptance Model that incorporates social influence, battery quality assessment, service expectation, BSS experience, shift patterns, and sociodemographic attributes, and estimate it using a Multiple Indicators Multiple Causes framework. Based on offline survey data from approximately 1000 ETRS drivers with BSS experience in Shanghai, China, the results show that the proposed model demonstrates improved model fit and explanatory power compared to baseline models (over 10% increase compared to the base model in terms of explained variance). Among the examined factors, battery quality assessment and perceived usefulness emerge as the primary determinants of drivers’ intention to continue using BSS. Perceived ease of use and service expectation also significantly influence attitudes and intentions. In contrast, social influence exerts limited direct effects. Multi-group analysis further demonstrates heterogeneity across time sensitivity and operational shift patterns: double-shift and high time-pressure drivers are more sensitive to service reliability and convenience. The findings offer empirical evidence to support BSS policy and service design.
电池交换服务(BSS)减少了停机时间,缓解了里程焦虑,并提高了电动出租车和打车服务(ETRS)司机的运营效率。然而,司机的偏好和影响他们继续使用BSS意愿的关键因素仍未得到充分研究。以前的研究很大程度上依赖于陈述偏好调查,受限于有限的分析范围和缺乏bss经验的参与者,降低了研究结果的可靠性。为了解决这一差距,我们提出了一个扩展的技术接受模型,该模型结合了社会影响、电池质量评估、服务期望、BSS体验、转移模式和社会人口统计学属性,并使用多指标多原因框架对其进行估计。基于对中国上海约1000名具有BSS经验的ETRS司机的离线调查数据,结果表明,与基线模型相比,所提出的模型具有更好的模型拟合和解释力(在解释方差方面比基本模型提高了10%以上)。在研究的因素中,电池质量评估和感知有用性成为司机继续使用BSS的主要决定因素。感知易用性和服务期望也显著影响态度和意图。相比之下,社会影响的直接影响有限。多组分析进一步揭示了时间敏感性和操作班次模式的异质性:双班和高时间压力司机对服务可靠性和便利性更敏感。研究结果为支持BSS政策和服务设计提供了实证证据。
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引用次数: 0
Synergistic effects of the dual pilot policy on pollution reduction and carbon mitigation: The role of data empowerment and market mechanisms 减少污染和减少碳排放双重试点政策的协同效应:数据赋权和市场机制的作用
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-19 DOI: 10.1016/j.jclepro.2026.148031
Qingfeng Luo, Fenfen Wang, Can Wang, Xinyang Dong
In the face of escalating climate change and environmental pollution, this study examines whether the combination of national big data pilot zones and carbon emissions trading can generate synergistic effects on pollution and carbon reduction. Using city-level panel data and a difference-in-differences model, the results show that the dual pilot programs significantly reduce pollution and carbon emissions, with stronger effects than single-policy implementations. These policies enhance environmental outcomes through intercity collaboration, green innovation, improved productivity, and cleaner production. Heterogeneity analysis shows stronger effects in high-emission cities, those with stringent regulations, developed green finance, and larger urban scales. Spatial analysis reveals spillover benefits in neighboring cities, while border cities experience weaker effects due to the gray border effect. This study provides theoretical insights for local governments seeking to leverage the complementary effects of data-driven and market-based policies to achieve coordinated pollution reduction, carbon mitigation, and sustainable development.
面对日益加剧的气候变化和环境污染,本研究考察了国家大数据试验区与碳排放权交易相结合是否能够产生污染减排的协同效应。利用城市层面的面板数据和差中差模型,结果表明,双试点方案显著降低了污染和碳排放,且效果强于单一政策实施。这些政策通过城际合作、绿色创新、提高生产率和清洁生产来改善环境。异质性分析表明,在高排放、监管严格、绿色金融发达、城市规模较大的城市中,影响更强。空间分析结果显示,相邻城市具有溢出效应,而边境城市由于灰色边界效应,溢出效应较弱。本研究为地方政府寻求利用数据驱动和市场驱动政策的互补效应来实现协调的污染减排、碳减排和可持续发展提供了理论见解。
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引用次数: 0
Green purification of FCC slurry oil to ultra-low ash via acid-modified biomass filter 酸改性生物质滤池对FCC浆油进行超低灰分绿色净化
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-19 DOI: 10.1016/j.jclepro.2026.148040
Jinxuan Wu, Libo Zhang, Songtao Liu, Xiaoli He, Zhenjiang Chen, Hui Wang, Qinzhen Fan
The efficient removal of solid fines and metal impurities from fluid catalytic cracking (FCC) slurry oil remains a critical challenge for its high-value utilization in petroleum refining. Conventional separation techniques often suffer from high energy consumption, low fine-particle retention, secondary pollution, and elevated operational costs. Herein, we propose a green and tunable filtration strategy using chemically modified biomass as a sustainable filter medium. Biomass filter powder was treated with hydrochloric acid (HCl) and a NaOH/Na2SO3 mixed system to tailor its surface chemistry and pore structure. Systematic investigations revealed that acid-modified 180-mesh biomass (PA-180) exhibits superior performance under optimized conditions (1 wt% dosage, 135 °C, −100.13 kPa), reducing the ash content of slurry oil from 3599.9 μg/g to 37 μg/g (98.97% removal) while achieving >99% removal of Si and Al. Characterization studies demonstrate that acid treatment enhances surface polarity, creates a hierarchical porous structure, and introduces abundant oxygen-containing functional groups, which collectively promote the capture of sub-micron particles and polar asphaltenes via a synergistic “bridging effect” and chemisorption. This biomass-based approach operates without chemical additives, offering an energy-efficient, environmentally benign, and effective route for the ultra-cleaning of FCC slurry oil, aligning with the principles of cleaner production and sustainable resource utilization in the petrochemical industry.
如何有效去除催化裂化(FCC)油中的固体细粒和金属杂质,仍然是其在石油炼制中高价值利用的关键挑战。传统的分离技术往往存在能耗高、细颗粒保留率低、二次污染和操作成本高等问题。在此,我们提出了一种绿色可调的过滤策略,使用化学修饰的生物质作为可持续的过滤介质。用盐酸(HCl)和NaOH/Na2SO3混合体系处理生物质过滤粉,以调整其表面化学和孔隙结构。系统研究表明,酸改性180目生物质(PA-180)在优化条件(1 wt%投加量,135℃,- 100.13 kPa)下表现出优异的性能,将浆油的灰分含量从3599.9 μg/g降至37 μg/g(去除率98.97%),同时实现了99%的硅和铝去除率。表征研究表明,酸处理增强了表面极性,形成了层次化的多孔结构,并引入了丰富的含氧官能团。它们通过协同的“桥接效应”和化学吸附共同促进亚微米颗粒和极性沥青质的捕获。这种基于生物质的方法不含化学添加剂,为FCC浆油的超清洁提供了一种节能、环保、有效的途径,符合石化行业清洁生产和可持续资源利用的原则。
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引用次数: 0
A coupled Monte Carlo–Pareto approach for sustainable asphalt mix optimization: Life cycle insights into green hydrogen and reclaimed materials 可持续沥青混合料优化的蒙特卡罗-帕累托耦合方法:绿色氢和再生材料的生命周期洞察
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-18 DOI: 10.1016/j.jclepro.2026.148042
Manouchehr Shokri, Marzia Traverso, Rose Nangah Mankaa
The decarbonization of transport infrastructure is pivotal for achieving climate neutrality and advancing Circular Economy (CE) goals. Conventional asphalt production, heavily reliant on energy-intensive methods and virgin materials, contributes significantly to greenhouse gas emissions. Integrating alternative materials and low-emission energy sources could offer a viable pathway to minimizing environmental impacts while preserving pavement performance and optimizing Life Cycle Costs (LCC). This study developed a multi-objective optimization model that combines Monte Carlo simulation with Pareto front analysis to identify optimal asphalt mixtures by jointly evaluating LCC, Global Warming Potential (GWP), and product quality. The model incorporated various parameters including mix design, Reclaimed Asphalt Pavement (RAP) content, bitumen, fuel types, heating energy, transport distance, and other influencing factors. The results reveal substantial variability in environmental and economic performance, with GWP ranging from 9.17 to 97.72 kg CO2-eq per ton and LCC between 2.75 and 13.67 €/ton, primarily driven by the type and amount of fuel consumed, with green hydrogen playing a particularly notable role despite its higher cost. Pareto-optimal solutions achieved average reductions of 35.7% in GWP and 11.7% in LCC, respectively. Analysis of Pareto-optimal solutions demonstrates that achieving low GWP does not inherently require high costs or reduced quality, nor does cost minimization necessarily lead to increased emissions or compromised performance. Overall, this research establishes a practical framework for simultaneously balancing economic, environmental, and technical criteria in asphalt production, thereby enabling more informed and sustainable decision-making in real-world applications.
交通基础设施的脱碳对于实现气候中和和推进循环经济(CE)目标至关重要。传统的沥青生产严重依赖能源密集型方法和原始材料,对温室气体排放有很大贡献。整合替代材料和低排放能源可以提供可行的途径,以尽量减少对环境的影响,同时保持路面性能和优化生命周期成本(LCC)。本研究开发了一个多目标优化模型,将蒙特卡罗模拟与帕累托前分析相结合,通过联合评估LCC、全球变暖潜势(GWP)和产品质量来确定最佳沥青混合物。该模型考虑了混合料设计、再生沥青路面(RAP)含量、沥青、燃料类型、加热能量、运输距离等多种影响因素。结果显示,在环境和经济绩效方面存在显著差异,GWP在9.17 - 97.72 kg co2当量/吨之间,LCC在2.75 - 13.67欧元/吨之间,主要受燃料消耗类型和数量的影响,其中绿色氢的作用尤为显著,尽管其成本较高。帕累托最优方案实现了GWP和LCC分别平均降低35.7%和11.7%。对帕累托最优解的分析表明,实现低全球升温潜能值并不必然需要高成本或降低质量,成本最小化也不一定会导致排放增加或性能降低。总体而言,本研究为同时平衡沥青生产中的经济、环境和技术标准建立了一个实用框架,从而在实际应用中实现更明智和可持续的决策。
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引用次数: 0
Revisit the improvement of coagulation pretreatment on ozonation performance: The critical roles of HO• and O3 for effluent organic matter transformation and micropollutant degradation 再谈混凝预处理对臭氧氧化性能的改善:HO•和O3在出水有机物转化和微污染物降解中的关键作用
IF 11.1 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2026-03-18 DOI: 10.1016/j.jclepro.2026.147988
Rui Hu, Hao-Tong Zheng, Boxi Tang, Jialing Tu, Yu-Hong Cui, Xuedong Zhai, Gang Wen, Zheng-Qian Liu
Effluent organic matter (EfOM) from municipal wastewater treatment plants is an emerging concern because of its refractory and potential risk to ecological environment. Herein, this investigation comprehensively evaluated the effects of HO and O3 exposures on EfOM transformation and micropollutant degradation under different pre-coagulation operating conditions during ozonation. Compared to coagulation and ozonation alone, coupling two processes could effectively reduce total organic carbon, color and UV254 of effluent. Fe-based coagulant was easier to combine with OH to generate floc in bulk than Al-based coagulant for EfOM capture, which could decrease total scavenging capacities of effluents as well as increase the exposures of O3 and HO during ozonation, enhancing ozonation efficiency for EfOM degradation. EfOM from membrane bioreactor treatment was more difficult to capture during pre-coagulation but more easily degraded during ozonation than that from conventional activated sludge treatment due to its lower molecular weight distribution and higher contents of humic-like and tryptophan-like substances. Parallel factor analysis shows that coagulation combined with ozonation breaks the fluorescent groups of humic-like and tryptophan-like substances effectively. Molecular weight distribution determination indicates that coupling two processes could more effectively remove humic-like substances, organic colloids and polysaccharides compared to coagulation or ozonation alone. Furthermore, micropollutants with higher energy of highest occupied molecular orbital were degraded more efficiently during ozonation. The investigation reveals that O3 utilization efficiency for micropollutant degradation can be significantly improved by pre-coagulation, offering new ideas for reducing energy consumption during advanced ozonation treatment and ensuring the safety of effluent and sustainable water reuse.
城市污水处理厂出水有机物因其难降解性和对生态环境的潜在危害而日益受到人们的关注。本研究综合评价了不同预混凝操作条件下,HO•和O3暴露对臭氧化过程中EfOM转化和微污染物降解的影响。与单独混凝和臭氧氧化相比,两种工艺的耦合处理能有效降低出水的总有机碳、色度和UV254。与al基混凝剂相比,fe基混凝剂更容易与OH−结合形成大块絮凝体,从而降低了出水的总清除能力,增加了臭氧化过程中O3和HO•的暴露量,提高了臭氧化降解EfOM的效率。膜生物反应器处理的EfOM在预混凝过程中更难捕获,但在臭氧化过程中比传统活性污泥处理的EfOM更容易降解,因为它的分子量分布更小,腐植酸样物质和色氨酸样物质的含量更高。平行因子分析表明,混凝结合臭氧化可有效破坏腐植酸类和色氨酸类物质的荧光基团。分子量分布测定结果表明,与单独混凝或臭氧氧化相比,两种耦合处理能更有效地去除腐殖质样物质、有机胶体和多糖。此外,臭氧化过程中,最高占据分子轨道能量越高的微污染物降解效率越高。研究表明,预混凝可显著提高O3对微污染物降解的利用效率,为深度臭氧化处理过程中降低能耗、保证出水安全和水的可持续回用提供了新的思路。
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Journal of Cleaner Production
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