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Vulnerability analysis of socio-ecological systems on small islands from the perspective of fisheries and tourism: A case study of Zhoushan Gouqi Island 从渔业和旅游业的角度分析小岛屿社会生态系统的脆弱性:舟山鼓岐岛案例研究
IF 9.7 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-03 DOI: 10.1016/j.jclepro.2024.143550

Small island social-ecological systems are increasingly vulnerable to the combined impacts of human activities and environmental changes, making focused vulnerability analyses critical for sustainable governance. In this study, Gouqi Island, a remote island, was selected as the research site to establish a comprehensive vulnerability assessment framework based on the Vulnerability-Sensitivity-Danger (VSD) model. To account for potential interdependencies among indicators, a fuzzy integration method was employed to quantitatively assess vulnerability trends from 2016 to 2022. The analysis revealed that vulnerability reached its lowest point in 2018, peaked at 0.876 in 2020, and remained above 2016 levels through 2022, despite a slight decline. Additionally, machine learning techniques were used to identify key factors influencing vulnerability, highlighting indicators such as D24 (proportion of fisheries and tourism output), D41 (number of tourists), and D52 (aquaculture production) as particularly significant, though distinct from traditional sensitivity indicators. These findings inform the identification of critical factors affecting the island's sustainable development and lead to the proposal of adaptive governance strategies. The insights from this study provide valuable guidance for promoting sustainable development in similar remote islands.

小岛屿社会生态系统越来越容易受到人类活动和环境变化的综合影响,因此,有针对性的脆弱性分析对于可持续治理至关重要。在本研究中,我们选择了一个偏远岛屿--勾其岛作为研究地点,以建立一个基于脆弱性-敏感性-危险性(VSD)模型的综合脆弱性评估框架。为了考虑指标之间潜在的相互依存关系,研究人员采用模糊综合法对 2016 年至 2022 年的脆弱性趋势进行了定量评估。分析结果显示,脆弱性在 2018 年达到最低点,2020 年达到 0.876 的峰值,到 2022 年,尽管略有下降,但仍高于 2016 年的水平。此外,还利用机器学习技术识别了影响脆弱性的关键因素,突出显示了 D24(渔业和旅游业产出比例)、D41(游客人数)和 D52(水产养殖产量)等指标特别重要,但与传统的敏感性指标不同。这些发现为确定影响岛屿可持续发展的关键因素提供了信息,并提出了适应性治理战略。这项研究的见解为促进类似偏远岛屿的可持续发展提供了宝贵的指导。
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引用次数: 0
Methodology for material flow analysis at the organizational scale 组织规模的物料流分析方法
IF 9.7 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-02 DOI: 10.1016/j.jclepro.2024.143564

Organizations play a crucial role in facilitating the transition to a circular economy. Implementing circular practices often begins with a material flow analysis (MFA) to identify issues and opportunities. However, existing MFA methodologies focus mainly on territorial applications and lack effectiveness at the organizational level. Conducting MFA at this level presents distinct challenges, requiring insights into dynamic material circulation and effective handling of heterogeneous data. Addressing this gap, this study introduces an innovative methodology tailored to organizational contexts. The developed methodology consists of six steps for conducting MFA while proposing an archetype-based approach capable of analyzing extensive and disparate datasets, coupled with bootstrapping and Monte Carlo simulation techniques, that considerably reduces the complexity of MFA execution. Furthermore, this methodology enables a comprehensive understanding of material flows within the system and provides a straightforward method for estimating uncertainty in mass estimations by incorporating confidence level calculations. A case study from a governmental organization is used to illustrate the proposed methodology.

组织在促进向循环经济过渡方面发挥着至关重要的作用。实施循环做法通常从物质流分析(MFA)开始,以确定问题和机遇。然而,现有的物质流分析方法主要侧重于地域应用,缺乏组织层面的有效性。在这一层面开展 MFA 面临着独特的挑战,需要深入了解动态物质循环,并有效处理异构数据。针对这一空白,本研究引入了一种针对组织背景的创新方法。所开发的方法论包括进行 MFA 的六个步骤,同时提出了一种基于原型的方法,能够分析大量不同的数据集,并结合引导和蒙特卡罗模拟技术,大大降低了 MFA 执行的复杂性。此外,这种方法还能全面了解系统内的物质流,并通过置信度计算,提供一种估算质量估算不确定性的直接方法。一个政府组织的案例研究用于说明所提出的方法。
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引用次数: 0
Digital transformation and household energy consumption: Evidence from the “Broadband China” policy 数字化转型与家庭能源消耗:来自 "宽带中国 "政策的证据
IF 9.7 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-02 DOI: 10.1016/j.jclepro.2024.143551

Digital transformation has the potential to significantly impact household energy consumption (HEC) by promoting the adoption of energy-efficient technologies. This paper utilizes the time-varying Difference-in-Differences (DID) model to evaluate the causal effect of digital transformation on HEC within China's households. We find that HEC is positively impacted by digital transformation, as embodied by the "Broadband China" strategy; and the results remain reliable when many robustness tests are taken into account. Specifically, digital transformation has the potential to indirectly increase HEC by consumption upgrade and internet development mechanisms. The heterogeneity analysis reveals that the impact of digital transformation on HEC varies significantly across different household and regional. High-income, low skilled, rural areas, as well as households in areas with higher levels of development and marketization, are more likely to be affected by the digital revolution in production and consumption, which will inevitably lead to an increase in HEC. These insights are crucial for developing effective strategies to reduce HEC and promote sustainable development.

数字化转型通过促进节能技术的采用,有可能对家庭能源消耗(HEC)产生重大影响。本文利用时变差分(DID)模型来评估数字化转型对中国家庭能源消耗的因果效应。我们发现,"宽带中国 "战略所体现的数字化转型会对家庭能源消耗产生积极影响;在考虑了许多稳健性检验后,结果依然可靠。具体而言,数字化转型有可能通过消费升级和互联网发展机制间接提高 HEC。异质性分析表明,数字化转型对 HEC 的影响在不同家庭和地区之间存在显著差异。高收入、低技能、农村地区以及发展水平和市场化程度较高地区的家庭更有可能受到生产和消费领域数字革命的影响,这必然会导致 HEC 的增加。这些认识对于制定有效的战略,减少减少家庭消费支出和促进可持续发展至关重要。
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引用次数: 0
Waste-to-energy technologies: Integrating anaerobic digestion, microbial electrolysis cells, hydrodynamic cavitation, and electrocoagulation 废物变能源技术:整合厌氧消化、微生物电解池、流体动力空化和电凝技术
IF 9.7 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-02 DOI: 10.1016/j.jclepro.2024.143549

This study explores a novel integration of electro-physicochemical technologies to generate energy and treat water from combined food waste (FW) and blackwater (FW-BW), with BW containing waste activated sludge with simulated flush water. The FW-BW substrate was gravity-separated and pretreated with hydrodynamic cavitation (HDC). Solids from gravity separation were used for energy generation via anaerobic digestion (AD) alone or integrated with microbial electrolysis cells (AD-MEC). HDC pretreatment had 51.6% more CH4 production in 5 days (266 mL CH4/g VS) and 63% more in 30 days compared to AD without HDC. The CH4 production after 5 days of digestion with HDC pretreatment (266 mL CH4/g VS) was similar to the amount produced without HDC over 30 days (263 mL CH4/g VS). Using MEC increased CH4 production by 12.7% compared to AD-only. The liquids from gravity separation were treated with electrocoagulation (EC) at 15 V (90 min), which removed 96.2% of the chemical oxygen demand (COD) and 100% of the total suspended solids. The pilot scale design indicates that the AD-MEC and EC units would generate 1.4 times more energy than energy consumed through applying these novel technologies. These findings demonstration the applications of four technologies (HDC, AD, MEC, and EC) in an energy-efficient waste management approach, producing bioenergy and cleaner water for low-tier use, especially in areas lacking traditional waste treatment options.

本研究探索了一种新颖的电-物理-化学一体化技术,用于从食物垃圾(FW)和黑水(FW-BW)中产生能量和处理水,其中黑水含有垃圾活性污泥和模拟冲洗水。FW-BW 基质经重力分离,并用流体动力空化(HDC)进行预处理。重力分离后的固体通过单独的厌氧消化(AD)或与微生物电解池(AD-MEC)相结合的方式用于能源生产。与不使用 HDC 的厌氧消化法相比,HDC 预处理 5 天的甲烷产量(266 mL CH4/g VS)提高了 51.6%,30 天的甲烷产量提高了 63%。经 HDC 预处理的 5 天消化后的 CH4 产量(266 mL CH4/g VS)与不经 HDC 预处理的 30 天内的产量(263 mL CH4/g VS)相近。与纯 AD 相比,使用 MEC 增加了 12.7% 的 CH4 产量。重力分离产生的液体经 15 V(90 分钟)电凝(EC)处理后,可去除 96.2% 的化学需氧量(COD)和 100% 的总悬浮固体。中试规模的设计表明,通过应用这些新技术,AD-MEC 和 EC 装置产生的能量是消耗能量的 1.4 倍。这些研究结果展示了四种技术(HDC、AD、MEC 和 EC)在节能废物管理方法中的应用,特别是在缺乏传统废物处理方案的地区,可生产生物能源和更清洁的水,供低层次使用。
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引用次数: 0
The comparative techno-economic and life cycle assessment for multi-product biorefinery based on microwave and conventional hydrothermal biomass pretreatment 基于微波和传统水热生物质预处理的多产品生物精炼厂的技术经济和生命周期比较评估
IF 9.7 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-02 DOI: 10.1016/j.jclepro.2024.143562

Microwave as an efficient and clean energy, is easy integrated with DES pretreatment and biorefinery process to achieve process intensification for cleaner production and sustainable development. However, there are worries about its economic and environmental feasibility for application in biorefinery plant. This work conducted the techno-economic (TEA) and life cycle assessment (LCA) of the entire biorefinery process based on DES pretreatment by microwave heating (MH) for producing glucose, furfural and lignin from lignocellulose, of which the results were compared with conventional heating (CH). For pretreating equivalent biomass, the total yield of products obtained from MH-assisted process was 8.53% higher than that of CH-assisted process due to microwave intensification effect. From the perspective of cradle-to-gate LCA, the MH-assisted process saved energy demand of 5.82%, reducing the environmental impacts global warming (GW) and fossil resource scarcity (FRS) by 4.85% and 5.69%, respectively, relative to CH-assisted process. The main environmental hotspots of both two processes concentrated on the raw material extraction (RME), followed by product separation and solvent recovery (PSSR) stages. Based on economic evaluation, the specific values of TAC regarding one-ton product for MH- and CH-assisted processes were 3194.35 and 3400.37 $/(y⋅t), respectively. Therefore, the MH-assisted pretreatment possessed certain environmental and economic advantages due to product increasement, energy consumption reduction in the DES pretreatment, and burden reduction for subsequent enzyme hydrolysis. Compared to the single-product biorefinery, the multi-product biorefinery strategy was more sustainable and could maximize the advantages of microwave intensification. However, some issues about the design of microwave reactors and temperature monitoring must be considered to pursue scale-up biorefinery plant.

微波作为一种高效清洁的能源,很容易与 DES 预处理和生物精炼工艺相结合,从而实现工艺集约化,以实现清洁生产和可持续发展。然而,微波在生物精炼厂中应用的经济和环境可行性令人担忧。本研究对基于微波加热(MH)的 DES 预处理从木质纤维素中生产葡萄糖、糠醛和木质素的整个生物精炼工艺进行了技术经济(TEA)和生命周期评估(LCA),并将结果与传统加热(CH)进行了比较。在预处理等量生物质的情况下,由于微波强化效应,MH 辅助工艺获得的产品总产率比 CH 辅助工艺高 8.53%。从 "从摇篮到终点 "生命周期评估的角度来看,MH 辅助工艺比 CH 辅助工艺节约了 5.82% 的能源需求,分别减少了 4.85% 和 5.69% 的全球变暖(GW)和化石资源稀缺(FRS)环境影响。两种工艺的主要环境热点都集中在原料提取(RME)阶段,其次是产品分离和溶剂回收(PSSR)阶段。根据经济评价,MH 辅助工艺和 CH 辅助工艺每吨产品的 TAC 具体值分别为 3194.35 美元/(y⋅t)和 3400.37 美元/(y⋅t)。因此,MH辅助预处理在增加产品、减少DES预处理能耗、减轻后续酶水解负担等方面具有一定的环境和经济优势。与单产品生物精炼相比,多产品生物精炼战略更具可持续性,可最大限度地发挥微波强化的优势。不过,要实现生物精炼厂的规模化生产,还必须考虑微波反应器的设计和温度监测方面的一些问题。
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引用次数: 0
Carbon dioxide emission equivalent calculation and inter-sectoral transfer pattern of different water use terminals in China 中国不同用水终端的二氧化碳排放当量计算及部门间转移模式
IF 9.7 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-02 DOI: 10.1016/j.jclepro.2024.143561

In the context of global climate change, all industries have put forward the requirements for carbon emission reduction. The effective use of water resources is the key to achieving carbon emission reduction, so it is particularly important to review the carbon dioxide emission equivalents of water resource utilization behaviors (CEE-WRUBs) of water users. However, existing research on CEE-WRUBs across various water sectors remains inadequate. Therefore, this study integrates the enhanced CEEA method, LMDI decomposition model, and IOA method to analyze CEE-WRUBs across diverse water use terminals. Then seeks their main driving factors and their transfer pattern among different industries, which are crucial to the realization of the global carbon neutrality objective. The results showed that: (1) China's CEE-WRUBs show a significant downward trend. Industrial water use emerges as the primary source of CEE, but the CEE-WRUBs of most industrial water terminals show a fluctuating downward trend. Grains' water use behavior (WRUBs) absorbed the largest CEE, reaching 14,698 Mt in 2020. (2) the water efficiency effect emerges as the predominant driver behind the increase in CEE-WRUBs most of the time, and holding a prominent position. The carbon emission intensity effect primarily steers the reduction of CEE-WRUBs. (3) the largest net outflow sector of WRUBs embodied carbon in 2007–2020 was transformed from basic material heavy industry (−153.54 Mt in 2007) to agriculture (−128.26 Mt in 2020). Most of the WRUBs embodied carbon of agriculture flows into light industry, while most of the WRUBs embodied carbon of basic material heavy industry flows into finishing heavy industry and construction. The methods and results of this study provide a potential reference for investigating the regional water-carbon relationship and advancing the global carbon neutrality objective.

在全球气候变化的背景下,各行各业都提出了碳减排的要求。水资源的有效利用是实现碳减排的关键,因此对用水户水资源利用行为的二氧化碳排放当量(CEE-WRUBs)进行研究显得尤为重要。然而,现有研究对不同水行业的水资源利用行为二氧化碳排放当量的研究仍然不足。因此,本研究整合了增强型 CEEA 方法、LMDI 分解模型和 IOA 方法,对不同用水终端的 CEE-WRUBs 进行分析。然后寻求其主要驱动因素及其在不同行业间的转移模式,这对实现全球碳中和目标至关重要。研究结果表明(1)中国的 CEE-WRUBs 呈显著下降趋势。工业用水成为 CEE 的主要来源,但大多数工业用水终端的 CEE-WRUBs 呈波动下降趋势。谷物用水行为(WRUBs)吸收了最大的 CEE,2020 年达到 146.98 亿吨。(2) 水效率效应在大多数情况下是 CEE-WRUBs 增长的主要驱动力,并占据突出地位。碳排放强度效应则是中欧和东欧地区用水回合减少的主要驱动力。(3) 2007-2020 年,WRUBs 含碳量的最大净流出部门由基础材料重工业(2007 年-1.5354 亿吨)转变为农业(2020 年-1.2826 亿吨)。农业的WRUBs体现碳大部分流入轻工业,而基础材料重工业的WRUBs体现碳大部分流入精加工重工业和建筑业。本研究的方法和结果为研究区域水碳关系和推进全球碳中和目标提供了潜在参考。
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引用次数: 0
From case study to general principle: An analysis of the development mechanism and policy optimization of mangrove carbon sinks 从个案研究到一般原则:红树林碳汇的开发机制与政策优化分析
IF 9.7 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-02 DOI: 10.1016/j.jclepro.2024.143537

Mangroves, as a crucial coastal ecosystem, possess significant carbon sink functions and play a key role in mitigating global climate change. This paper, based on the Zhanjiang Mangrove Afforestation Project in Guangdong, explores the development mechanisms and economic and ecological benefits of mangrove carbon sink projects through the lens of collective action theory and system dynamics modeling. The study finds that the primary reason for the unsustainable progression of mangrove carbon sink projects is the lack of intrinsic motivation among local villagers to engage in collective action. By constructing a system dynamics model, this paper quantifies the long-term impacts of mangrove carbon sink projects on local socio-economic welfare and proposes policy optimization recommendations. These recommendations include expanding income sources for local villagers, establishing carbon trading and ecological compensation mechanisms, and involving international non-governmental organizations. The findings of this study not only provide guidance for mangrove carbon sink projects in China but also offer valuable insights for the promotion of similar projects globally.

红树林作为重要的海岸生态系统,具有重要的碳汇功能,在减缓全球气候变化方面发挥着关键作用。本文以广东湛江红树林造林项目为基础,通过集体行动理论和系统动力学建模的视角,探讨了红树林碳汇项目的发展机制和经济生态效益。研究发现,红树林碳汇项目无法持续推进的主要原因是当地村民缺乏参与集体行动的内在动力。通过构建系统动力学模型,本文量化了红树林碳汇项目对当地社会经济福利的长期影响,并提出了政策优化建议。这些建议包括扩大当地村民的收入来源、建立碳交易和生态补偿机制以及让国际非政府组织参与进来。本研究的结论不仅为中国的红树林碳汇项目提供了指导,也为在全球推广类似项目提供了宝贵的启示。
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引用次数: 0
Sustainable end-of-life management of abandoned and derelict vessels through the lens of circular economy 从循环经济的角度对废弃和遗弃船只进行可持续的报废管理
IF 9.7 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-02 DOI: 10.1016/j.jclepro.2024.143559

Boats require End-of-Life (EOL) management, especially those built with fibre-reinforced plastic/polymer materials because they are hard to dispose and have negative effects on the environment. The main challenge with EOL boats or abandoned and derelict vessels (ADVs) is the lack of sustainable disposal options for recycling and reusing composite plastics, which should be safe, managed, sustainable, and economically viable. Most efforts have focused on dealing with ADVs in water rather than on land. This study provides a systematic review of 101 studies of End-of-Life Boat (ELB) management and seeks methods to deal with derelict vessels, challenges in their management, potential solutions, and a comparison and assessment of EOL opportunities in terms of sustainability and circular economy. Research gaps were identified, and suggestions for future research directions were proposed. The marine industry faces gaps in practical implementation and understanding of sustainable principles and lacks effective regulations, cost-effective methods, and suitable technologies for sustainable management, particularly for recycling and reusing. The present review highlights the importance of a harmonized approach, financing mechanisms, sustainable dismantling and transport, material reuse and upcycling, industry partnerships, centralized recycling systems, and investments in research and innovation as crucial elements for enhancing the circular economy.

船只需要进行报废(EOL)管理,尤其是那些使用纤维增强塑料/聚合物材料建造的船只,因为它们难以处置,而且会对环境造成负面影响。报废船只或被遗弃和废弃船只(ADV)面临的主要挑战是缺乏回收和再利用复合塑料的可持续处置方案,而这些方案应该是安全、可管理、可持续和经济可行的。大多数工作都集中在处理水中而非陆地上的废弃船舶(ADV)。本研究对 101 项有关报废船只(ELB)管理的研究进行了系统回顾,寻求处理废弃船只的方法、管理中的挑战、潜在的解决方案,并从可持续性和循环经济的角度对报废船只的机遇进行比较和评估。确定了研究缺口,并对未来的研究方向提出了建议。海运业在实际执行和理解可持续原则方面存在差距,缺乏有效的法规、成本效益高的方法和合适的可持续管理技术,特别是回收和再利用技术。本综述强调了统一方法、融资机制、可持续拆解和运输、材料再利用和升级再循环、行业伙伴关系、集中回收系统以及研究和创新投资的重要性,这些都是加强循环经济的关键要素。
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引用次数: 0
Carbon footprint of global rice production and consumption 全球大米生产和消费的碳足迹
IF 9.7 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-02 DOI: 10.1016/j.jclepro.2024.143560

Rice paddies are not only sources of staple food for half of the global population but also account for nearly half of the anthropogenic greenhouse gas emissions (GHGs) of croplands. Carbon footprint (CF) is a key tool for identifying and weighting sources of the GHGs along the food supply chain, promoting the efforts to curb these emissions within the targets of the climatic change protocol of the Paris Agreement. We introduced a comprehensive global quantification of rice CF, including direct and indirect emissions and sinks of the GHGs of inputs production, packaging, transportation, and application, soil and plant systems, farm operations, and uses of the produced biomass until the end of life. Globally, the rice CF was 2430 kg CO2eq. Mg−1 grain in 2020, of which 46% and 42% were sourced from the Gate and Grave stages, respectively, after excluding 3265 kg CO2eq. Mg−1 grain, that is the assimilated C in plant biomass. Net GHGs emissions of soil, biomass mulching and burning, and farm operations accounted for 20, 17, and 63%, respectively of the Gate stage CF. Meanwhile, food consumption contributed to the Grave stage CF by 92%. The rice CF ranged between 14 and 4854 kg CO2eq. Mg−1 grain among countries, wherein, for example, the rice CF values in Indonesia, India, Vietnam, and Russia represented 9, 50, 97, and 122% of the global average. Southeast, South, and East Asia were the major contributors (35, 34 and 18%, respectively) to the atmospheric CO2 load (2.4 Pg CO2eq.) of global rice production and consumption. This CO2 load will increase to 3.1 Pg CO2eq. in 2100, driven by a 32% growth in rice consumption. Here, we suggested an optimistic strategy (green energy use, hybridization, improving use efficiency of the inputs, and reducing food losses) to reduce the CO2 load by 60%.

稻田不仅是全球一半人口的主食来源,也占耕地人为温室气体排放量(GHGs)的近一半。碳足迹(CF)是识别和权衡粮食供应链上温室气体来源的重要工具,有助于在《巴黎协定》气候变化议定书的目标范围内遏制这些排放。我们在全球范围内全面量化了大米 CF,包括投入品生产、包装、运输和应用、土壤和植物系统、农场运营以及所生产生物质的使用(直至生命周期结束)过程中温室气体的直接和间接排放及吸收汇。在全球范围内,2020 年水稻的二氧化碳当量为 2430 千克 CO2eq.Mg-1 谷物,其中 46% 和 42% 分别来自谷门和谷仓阶段,不包括 3265 千克 CO2eq.毫克-1 谷物中的同化碳。土壤、生物质覆盖和焚烧以及农场运营的温室气体净排放量分别占闸门阶段CF的20%、17%和63%。与此同时,食物消耗占坟墓阶段碳吸收总量的 92%。各国水稻的 CF 值介于 14 至 4854 千克 CO2eq.例如,印度尼西亚、印度、越南和俄罗斯的大米 CF 值分别为全球平均值的 9%、50%、97%和 122%。东南亚、南亚和东亚是全球大米生产和消费所产生的大气二氧化碳负荷(2.4 Pg CO2eq.)的主要贡献者(分别为 35%、34% 和 18%)。到 2100 年,这一二氧化碳负荷将增加到 3.1 Pg CO2eq.,大米消费量将增长 32%。在此,我们提出了一个乐观的战略(绿色能源利用、杂交、提高投入品的利用效率、减少粮食损失),以减少 60% 的二氧化碳负荷。
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引用次数: 0
Deciphering the transfer mechanisms for CO2 absorption into binary blended solutions 破解二元混合溶液吸收二氧化碳的转移机制
IF 9.7 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-02 DOI: 10.1016/j.jclepro.2024.143535

A thorough understanding of the mechanisms involved in CO2 chemical absorption is crucial for the development of efficient CO2 capture technologies. Due to the insufficient insight into the interaction mechanism of different components in blended solutions, CO2 absorption reactions were often categorized as unidirectional transfer between absorption products. In this study, the CO2 absorption performance of binary blended solutions, including piperazine (PZ)/n-methyldiethanolamine (MDEA), ethanolamine (MEA)/MDEA, ammonia (NH3)/MDEA, PZ/potassium carbonate (K2CO3), and NH3/K2CO3, was investigated using a combination of experimental and computational methods. The CO2 absorption mechanisms of “competitive reaction”, “transfer reaction” and “parallel reaction” in the binary blended solution system were proposed. Kinetic experiments revealed that different blended solutions had varying impacts on the process of CO2 absorption. Among them, PZ/MDEA and MEA/MDEA solutions reduced the absorption rates by an average of 8% and 25%, respectively, compared to PZ or MEA component solutions. NH3/MDEA and PZ/K2CO3 solutions had absorption rates similar to those of single NH3/PZ component solutions. NH3/K2CO3 solutions, on the other hand, exhibited an average increase of 17% in absorption rates compared to NH3 solutions. Quantum mechanical (QM) methods were employed to evaluate of the absorption products and key processes in terms of kinetics and thermodynamics. Quantitative 13C NMR analyses were conducted to further investigate the interactions between components and the pathways of mass transport in blended solutions, which demonstrated proton transfer and CO2/-COO transfer between adsorption products. This study highlights an accurate description of the transfer mechanisms of various blended systems for the enhanced CO2 capture.

透彻了解一氧化碳化学吸收的机理对于开发高效的一氧化碳捕获技术至关重要。由于对混合溶液中不同成分的相互作用机理了解不够,CO 吸收反应通常被归类为吸收产物之间的单向转移。本研究采用实验和计算相结合的方法,研究了哌嗪(PZ)/正甲基二乙醇胺(MDEA)、乙醇胺(MEA)/MDEA、氨(NH)/MDEA、PZ/碳酸钾(KCO)和 NH/KCO 等二元混合溶液的 CO 吸收性能。提出了二元混合溶液体系中 "竞争反应"、"转移反应 "和 "平行反应 "的 CO 吸收机理。动力学实验表明,不同的混合溶液对 CO 吸收过程有不同的影响。其中,PZ/MDEA 和 MEA/MDEA 溶液与 PZ 或 MEA 组分溶液相比,吸收率平均分别降低了 8%和 25%。NH/MDEA 和 PZ/KCO 溶液的吸收率与单一 NH/PZ 组分溶液相似。另一方面,与 NH 溶液相比,NH/KCO 溶液的吸收率平均提高了 17%。我们采用量子力学(QM)方法从动力学和热力学角度对吸收产物和关键过程进行了评估。定量 C NMR 分析进一步研究了混合溶液中各组分之间的相互作用和质量传输途径,结果表明吸附产物之间存在质子传输和 CO/COO 传输。这项研究突出强调了对各种混合系统的传输机制的准确描述,以增强对 CO 的捕获。
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Journal of Cleaner Production
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