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Gas-sensing properties of metal-oxide nanostructures produced by PLD PLD制备的金属氧化物纳米结构的气敏性能
A. Dikovska, N. Nedyalkov, T. Dilova, G. Atanasova, Georgi Avdeev, Plamen Stefanov
We report the fabrication of gas sensor elements by pulsed laser deposition in air at atmospheric pressure. We focused our attention on metal-oxide semiconductors, namely, SnO2, TiO2 and MoO3 and studied the samples’ structure and morphology. The deposition technology applied leads to the formation of nanostructures composed of nanoparticles and nano-aggregates. We report preliminary results on the gas-sensing properties of the metal-oxide nanostructures. The sensors were exposed to CO, acetone and ethanol, with the TiO2 nanostructure demonstrating the highest response to CO exposure.
本文报道了用脉冲激光在常压下在空气中沉积气体传感器元件的制备方法。我们重点研究了金属氧化物半导体,即SnO2, TiO2和MoO3,并研究了样品的结构和形貌。应用沉积技术可以形成由纳米颗粒和纳米聚集体组成的纳米结构。我们报告了金属氧化物纳米结构气敏性能的初步结果。将传感器暴露于CO、丙酮和乙醇中,TiO2纳米结构对CO暴露的响应最高。
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引用次数: 2
Parametric four-photon mixing: exact analytical solutions in Jacobi functions 参数化四光子混合:雅可比函数的精确解析解
A. Dakova, D. Dakova, V. Slavchev, L. Kovachev, S. Milenkova, Z. Kasapeteva
The problem with generating of new frequencies (signal and idler waves) in parametric four-photon processes without including the Raman scatter was solved only in approximation for a constant electric field or a constant intensity of the pump wave. The overall task which includes the change in intensity and the phase of the pump wave has not been studied in detail in the literature up to now. The main idea of present work is to solve the more general problem in which we have energy exchange between pump wave, signal and idler waves.
在不包括拉曼散射的参数化四光子过程中产生新频率(信号和空闲波)的问题仅在恒定电场或恒定泵浦波强度的近似情况下解决。迄今为止,文献中还没有对泵浦波的强度变化和相位变化等总体任务进行详细的研究。本工作的主要思想是解决更普遍的泵浦波、信号和闲散波之间的能量交换问题。
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引用次数: 3
Application of paired powerful laser diodes for detection and reconnaissance of atmospheric methane 配对大功率激光二极管在大气甲烷探测和侦察中的应用
Stoyan Penchev, V. Pencheva
Differential absorption lidar (DIAL) feasible to detect methane is developed on a pair of powerful pulsed (10μJ) laser diodes emitting on 1,56μm -1,66μm wavelengths. Methane is a potent greenhouse gas that is responsible for the present enhancement of the greenhouse effect. The spectral range of wavelengths utilized by the laser diodes matches an intensive second overtone of the methane molecule pure of interfering spectra of the other major atmospheric gases. Spectroscopic applications of the powerful laser diodes were generally limited by their broad laser line. Though spectrally unresolved, multiple resonance absorption lines modulate the laser radiation propagating in the atmosphere. The intensity of integral absorption is assessed combining the linestrengths taken from HITRAN database with the laser spectral line. The resultant absorption spectrum is immune to pressure variation, while the dependence on temperature is found to be within 10% error. The reported DIAL technique utilizes the advantage of simple operation within lidar ranges of 0.5- 5km prospective for reconnaissance of atmospheric methane and climatic monitoring.
利用波长为1,56μm -1,66μm的大功率脉冲(10μJ)激光二极管,研制了一种可用于甲烷探测的差分吸收激光雷达(DIAL)。甲烷是一种强效温室气体,是目前温室效应增强的原因。激光二极管利用的波长光谱范围与甲烷分子强烈的第二泛音相匹配,不受其他主要大气气体的干扰光谱的影响。大功率激光二极管的光谱线较宽,限制了其光谱学应用。虽然光谱无法分辨,但多条共振吸收线调制了在大气中传播的激光辐射。结合从HITRAN数据库获取的谱线强度和激光谱线评估了积分吸收强度。所得的吸收光谱不受压力变化的影响,而对温度的依赖误差在10%以内。报道的DIAL技术利用了操作简单的优势,在0.5- 5公里的激光雷达范围内进行大气甲烷侦察和气候监测。
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引用次数: 0
Laser removal of chlorine from historical metallic objects 激光去除历史金属物品中的氯
V. Atanassova, P. Penkova, I. Kostadinov, S. Karatodorov, G. Avdeev
This study is focused on the selective laser removal of chlorine-containing corrosion products from artificially corroded samples of copper, brass and steel. Its goal is to find an efficient methodology for laser cleaning of historical metallic objects. The laser treatment is done with two laser sources: Q switched Nd:YAG laser generating nanosecond pulses at 1 Hz repetition rate in the IR (1064 nm) and the green (510.6 nm) spectral range, and copper bromide vapor laser (CuBrVL) generating nanosecond pulses at 20 kHz repetition rate in the green (510.6 nm) spectral range. The cleaning is performed in dry and wet conditions. The surfaces before and after the treatment are characterized using optical microscopy (OM), x-ray fluorescence spectroscopy (XRF), x-ray diffraction spectroscopy (XRD), and laser-induced breakdown spectroscopy (LIBS).
本研究的重点是选择性激光去除人工腐蚀铜、黄铜和钢样品中的含氯腐蚀产物。它的目标是找到一种有效的方法来激光清洗历史金属物体。激光治疗采用两种激光源:Q开关Nd:YAG激光在红外(1064 nm)和绿色(510.6 nm)光谱范围内产生重复频率为1 Hz的纳秒脉冲,溴化铜蒸气激光器(CuBrVL)在绿色(510.6 nm)光谱范围内产生重复频率为20 kHz的纳秒脉冲。清洁在干燥和潮湿的条件下进行。采用光学显微镜(OM)、x射线荧光光谱(XRF)、x射线衍射光谱(XRD)和激光诱导击穿光谱(LIBS)对处理前后的表面进行了表征。
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引用次数: 5
Asymmetric frequency-tuning behavior of the D1 line hyperfine spectrum of Rb vapor contained in high quality paraffin coated optical cell 优质石蜡包覆光学电池中Rb蒸气D1线超精细光谱的非对称频率调谐行为
K. Nasyrov, S. Gateva, R. K. Nasyrov, N. Petrov, S. Tsvetkov, A. Krasteva, S. Cartaleva
Significant modification of the spectrum of the D1 line of 85Rb in optical cells with high quality antirelaxation coating on the walls is studied experimentally and theoretically analyzed. The spectral profiles of hyperfine transitions are found to be significantly dependent on the velocity and the direction of the laser frequency scanning. A physical explanation is proposed for the observed features, which is confirmed by numerical simulations. The effect of small magnetic field on hyperfine spectrum is also discussed.
通过实验和理论分析,研究了高质量抗弛缓涂层对光学细胞内85Rb D1谱线的显著改变。发现超精细跃迁的光谱分布与激光频率扫描的速度和方向有显著的关系。对观测到的特征提出了物理解释,并通过数值模拟得到了证实。讨论了小磁场对超精细谱的影响。
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引用次数: 0
Light induced atomic desorption for spectroscopy of optically thick Rb atomic vapor 光学厚Rb原子蒸气光谱的光诱导原子解吸
S. Tsvetkov, S. Gateva
We report some preliminary results on experimental investigation of the potential of Light Induced Atomic Desorption (LIAD) applications for density control in antirelaxation coated cells and coherent spectroscopy. LIAD is a non-thermal process whereby atoms adsorbed on a surface are released under illumination. It is applied mostly to implementing optical atomic dispensers in the cases when high atomic density at low temperature is needed - for example, for loading atomic devices as atomic magnetometers, atomic clocks, atomic traps and their miniaturization. An advantage of the light control is that it is faster than the temperature control. More than an order of increase of the density with LIAD is obtained. Some peculiarities in the 780 nm absorption and fluorescence spectra registered in dense Rb vapor are registered. The absorption and fluorescence spectra in Rb vapors controlled by temperature and LIAD are compared.
本文报道了光诱导原子脱附(LIAD)在抗松弛涂层细胞和相干光谱学中密度控制应用潜力的初步实验研究结果。LIAD是一种非热过程,即在照射下释放表面上吸附的原子。它主要应用于在低温下需要高原子密度的情况下实现光学原子分配器-例如,用于装载原子装置,如原子磁力计,原子钟,原子阱及其小型化。光控制的一个优点是它比温度控制快。在LIAD的作用下,密度增加了一个数量级以上。在致密Rb蒸气中记录了780 nm吸收光谱和荧光光谱的一些特性。比较了温度控制和LIAD控制下Rb蒸气的吸收光谱和荧光光谱。
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引用次数: 0
Comparative study on the bio-activity of hemoglobin and myoglobin as recognition materials in biosensors 血红蛋白与肌红蛋白作为生物传感器识别材料生物活性的比较研究
G. Dyankov, Ch. Kisov, E. Belina, E. Pavlova, E. Borisova, A. Gisbrecht, D. Ivanov
Apart from the huge physiological importance of hemo-, myo- globin and hemin, they play also an important role as robust and effective recognition agents in chemical and biological sensors. In this aspect the key factor in developing a reliable biosensor is the immobilization on the transducer. Usually immobilization can be produced by chemical methods, but there is frequently a need for homogeneous films of well-controlled thickness or films which can be deposited in a dry environment. The film thickness is of main importance for the optical transducer detected by Surface Plasmon Resonance (SPR) what is used in our study. Hundreds of immobilization protocols have been developed in an effort to ensure high performance sensing. All of them are focused on finding and deposition of appropriate matrices in which the recognition medium can be incorporated. However, the matrix always deteriorates the effectiveness of recognition. It seems that the best approach is to perform direct immobilization of the recognition medium. However, this is not always possible regarding the organic materials – the problem is whether the deposition retains the bioactivity of the recognition agent. On the other hand, the type of the transducer also imposes constrains. For example, the direct immobilization of the proteins is not possible for electrochemical sensors, because of the distance between the redox center and electrodes is too long. Evaluating the pros and cons of organic (protein) film deposition we have considered to study the possibility for direct immobilization of myoglobin, hemoglobin and hemin on SPR transducer. To best of our knowledge, SPR biochip with immobilized myoglobin, hemoglobin and hemin has never been constructed before. We have used spin coating, for direct immobilization and matrix-assisted pulsed-laser evaporation (MAPLE) for elaboration of the SPR biochip. The performance of both SPR chips – direct and MAPLE immobilized, was studied by SPR registration of the binding activity of myo- and hemo- globin ligands with carbon monoxide (CO), carbon dioxide (CO2) and nitride oxide (NO).
除了血红蛋白、肌球蛋白和血红蛋白具有巨大的生理意义外,它们在化学和生物传感器中也扮演着强大而有效的识别剂的重要角色。在这方面,开发可靠的生物传感器的关键因素是传感器的固定化。通常可以用化学方法固定,但通常需要厚度控制良好的均匀膜或可以在干燥环境中沉积的膜。薄膜厚度对我们研究中使用的表面等离子体共振(SPR)检测光学换能器至关重要。为了确保高性能传感,已经开发了数百种固定方案。所有这些都集中在寻找和沉积合适的基质,其中可以纳入识别介质。然而,矩阵的存在往往会降低识别的有效性。似乎最好的方法是直接固定识别介质。然而,对于有机材料来说,这并不总是可能的——问题是沉积是否保留了识别剂的生物活性。另一方面,换能器的类型也施加了限制。例如,电化学传感器不可能直接固定蛋白质,因为氧化还原中心和电极之间的距离太长。评价有机(蛋白)膜沉积的利弊,我们考虑研究肌红蛋白、血红蛋白和血红蛋白直接固定在SPR传感器上的可能性。据我们所知,固定化肌红蛋白、血红蛋白和血红蛋白的SPR生物芯片以前从未被构建过。我们使用自旋涂层直接固定和基质辅助脉冲激光蒸发(MAPLE)来制备SPR生物芯片。通过SPR标记研究了肌球蛋白和血红蛋白配体与一氧化碳(CO)、二氧化碳(CO2)和氮氧化物(NO)的结合活性,研究了直接SPR芯片和MAPLE固定化SPR芯片的性能。
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引用次数: 3
Simultaneous vertical LIDAR profiling of Saharan dust layers and high-altitude cirrus clouds in the troposphere 对流层中撒哈拉沙尘层和高空卷云的同时垂直激光雷达剖面
A. Deleva, Z. Peshev, E. Krasteva, T. Dreischuh
Mineral dust and cirrus clouds are recognized to be among the major modulators of the atmospheric energy budget. Sahara Desert is the Earth’s largest source of mineral dust of natural origin. Saharan dust intrusions in the atmosphere over Europe are frequently accompanied by a parallel occurrence of cirrus clouds. Studies on the vertical aerosol distribution in such cases are important in providing a better understanding of the radiative effects of aerosols and clouds, and for the development of more accurate climate models. Lidars are considered as one of the leading techniques for conducting such studies, due to their high range/time resolution and sensitivity to optically-thin aerosol layers and clouds. In this work, we present results of lidar observations of the simultaneous presence of Saharan dust layers and cirrus clouds in the troposphere, with regard to their possible interaction, particularly in cases when the Saharan dust particles act as nuclei in cirrus cloud formation. Accordingly, experimental data derived from the regular long-term lidar investigations of Saharan dust loadings above Sofia, Bulgaria, are described and analyzed. The aerosol measurements were carried out by an elastic-backscatter lidar based on a frequency-doubled Nd:YAG laser. The experimental results are presented as color maps of the aerosol density distribution dynamics and by time-averaged vertical profiles of the aerosol backscatter coefficient. The process of cirrus cloud nucleation on desert dust particles is detected and analyzed in its development and evolution.
矿物粉尘和卷云被认为是大气能量收支的主要调节器。撒哈拉沙漠是地球上最大的天然矿物粉尘来源。撒哈拉沙尘侵入欧洲上空的大气,经常伴随着卷云的平行出现。在这种情况下,对气溶胶垂直分布的研究对于更好地了解气溶胶和云的辐射效应和发展更准确的气候模式具有重要意义。激光雷达被认为是进行这类研究的主要技术之一,因为它具有高距离/时间分辨率和对光学薄气溶胶层和云的灵敏度。在这项工作中,我们介绍了对流层中同时存在的撒哈拉沙尘层和卷云的激光雷达观测结果,以及它们之间可能的相互作用,特别是在撒哈拉沙尘颗粒在卷云形成过程中充当核的情况下。因此,本文描述和分析了保加利亚索非亚上空撒哈拉沙尘负荷的定期长期激光雷达调查所得的实验数据。气溶胶测量由基于倍频Nd:YAG激光器的弹性后向散射激光雷达进行。实验结果用气溶胶密度分布动态的彩色图和气溶胶后向散射系数的时间平均垂直剖面来表示。对沙漠沙尘颗粒上卷云成核的发展演变过程进行了探测和分析。
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引用次数: 1
Dark matter search by laser spectroscopy 用激光光谱学研究暗物质
G. Carugno, C. Braggio, F. Chiossi, M. Guarise, A. Dainelli, R. Calabrese, A. Khanbekyan, E. Luppi, L. Tomassetti, C. Marinelli, E. Mariotti
Dark matter (DM) represents one of the most intriguing challenges of modern physics, both for the theoretical predictions and for the experimental setups. The search for the possible DM component candidates regards a wide range of objects and of energy values. In order to detect processes related to very weak interactions, as expected in these cases, it is necessary to improve the performances of the available detectors making them more efficient in terms of energy threshold and mass. Here we present a research activity aimed at the development of a novel type of detector based on laser interrogation of atomic energy levels for species that have been loaded in a solid matrix of a non interacting material at very low temperatures. The laser assisted transitions are only promoted when an incident particle is absorbed in the material, releasing its energy to the embedded atoms. The detection can be obtained via both optical and electronic methods.
暗物质(DM)代表了现代物理学中最有趣的挑战之一,无论是理论预测还是实验设置。寻找可能的DM候选组件涉及范围广泛的对象和能量值。为了检测与非常弱相互作用相关的过程,如在这些情况下所期望的那样,有必要改进现有探测器的性能,使它们在能量阈值和质量方面更有效。在这里,我们提出了一项研究活动,旨在开发一种新型探测器,该探测器基于激光对在极低温度下装载在非相互作用材料的固体基质中的物种的原子能水平进行探测。只有当入射粒子被材料吸收时,激光辅助的跃迁才会被促进,并将其能量释放给嵌入的原子。可以通过光学和电子两种方法进行检测。
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引用次数: 0
Quantum dot array built into a nanoscale vibration detection scheme and the comparison with microlasers-based devices 量子点阵列内置于纳米级振动检测方案,并与基于微激光的器件进行比较
V. Serkin, A. Ramírez, A. Zehe
The sciences of physics and quantum electronics are currently in the beginning of the second quantum revolution. If the main goal of the first quantum revolution can be formulated as the understanding of our physical world and its atomic and nuclear structures, today, during the second quantum revolution, we are able not only explain the Nature, but we are actively applying our understanding of the quantum world, for example, to create new artificial atoms (quantum dots) and develop new technologies and nanoscale quantum electronic devices based on the quantum dot (QD) arrays like QD lasers, QD memories, and quantum-dot cellular automata. The main objective of our work is to demonstrate that nanoscale cold electron emission schemes may offer an intriguing new technical methodology for compact fast vibration sensors. We propose an electronic displacement device by positioning a vibrating anode toward a special field electron emitter. Cold field electron emission from an array of quantum dots grown on SiC is applied, where the distance between the tip of emitting mounds and the counter-electrode (anode) is controlled by the moving object under study. To that end, field emission electron sources are built on a flexible substrate, which can take up and transfer the oscillations of a vibrating moving system into a change of the spacing distance between emitter and anode, and by this modulate the emission current density. As is derived from Fowler-Nordheim equations, sensitivity down to a few nanometers of vibration amplitude is possible. In conclusion, we compare our vibration detection scheme based on the quantum dot array with modern micro- and nano-photonic and laser-based devices.
物理学和量子电子学目前正处于第二次量子革命的开端。如果第一次量子革命的主要目标可以被表述为理解我们的物理世界及其原子和核结构,那么今天,在第二次量子革命中,我们不仅能够解释自然,而且我们正在积极地应用我们对量子世界的理解,例如,创造新的人造原子(量子点),开发基于量子点(QD)阵列的新技术和纳米级量子电子设备,如QD激光器,QD存储器,还有量子点细胞自动机。我们工作的主要目的是证明纳米级冷电子发射方案可能为紧凑型快速振动传感器提供一种有趣的新技术方法。我们提出了一种电子位移装置,通过定位一个振动阳极对一个特殊的场电子发射器。利用生长在SiC上的量子点阵列进行冷场电子发射,其中发射丘尖端与对电极(阳极)之间的距离由所研究的运动物体控制。为此,在柔性衬底上建立场发射电子源,它可以吸收振动运动系统的振荡并将其转化为发射极与阳极间距的变化,从而调制发射电流密度。根据Fowler-Nordheim方程,灵敏度低至几纳米的振动幅度是可能的。最后,我们将基于量子点阵列的振动检测方案与现代基于微纳米光子和激光的器件进行了比较。
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引用次数: 0
期刊
International School on Quantum Electronics: Laser Physics and Applications
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