首页 > 最新文献

International School on Quantum Electronics: Laser Physics and Applications最新文献

英文 中文
Fabrication of Au nanostructures by pulsed laser deposition in air 脉冲激光沉积制备金纳米结构的研究
R. Nikov, A. Dikovska, N. Nedyalkov, P. Atanasov
Results on fabrication of Au nanostructures by laser ablation in open air are presented. The ablation of the Au target is performed in air environment by nanosecond laser pulses delivered by Nd:YAG laser system operated at λ = 355 nm. Due to the high density of the ambient atmosphere, the intensive collisions of the plume spices result in formation of nanoparticles and aggregates by condensation close to the target. The produced nanoagregates are deposited on a quartz substrate where grow in a specific nanostructure. Diagnostics of the laser-generated plasma for the laser fluences used in this study is performed. Study based on change of ambient conditions shows that the increase of the air pressure from 10 Torr to atmospheric one leads to transition from thin film to porous structures. It is found that the surface morphology of the structures produced by pulsed laser deposition (PLD) in open air strongly depends on the substrate-target distance. The electrical properties of the obtained structures are studied by measurement of their electrical resistance. It is found that the conductivity of the structures strongly depends on their morphology. The fabricated structures have potential for application in the field of electronics and sensors.
介绍了露天激光烧蚀法制备金纳米结构的研究结果。利用λ = 355 nm的Nd:YAG激光系统输出的纳秒激光脉冲,在空气环境中对Au靶进行了烧蚀。由于周围大气的高密度,羽状物的强烈碰撞导致纳米粒子和聚集体在目标附近凝结形成。生产的纳米聚集体沉积在石英衬底上,在那里生长成特定的纳米结构。对激光产生的等离子体进行诊断,用于本研究中的激光影响。基于环境条件变化的研究表明,空气压力从10torr增加到大气压力,导致薄膜结构向多孔结构转变。研究发现,露天脉冲激光沉积(PLD)结构的表面形貌与基材与靶材的距离密切相关。通过测量所得结构的电阻来研究其电学性能。研究发现,结构的电导率很大程度上取决于它们的形态。该结构在电子和传感器领域具有潜在的应用前景。
{"title":"Fabrication of Au nanostructures by pulsed laser deposition in air","authors":"R. Nikov, A. Dikovska, N. Nedyalkov, P. Atanasov","doi":"10.1117/12.2262274","DOIUrl":"https://doi.org/10.1117/12.2262274","url":null,"abstract":"Results on fabrication of Au nanostructures by laser ablation in open air are presented. The ablation of the Au target is performed in air environment by nanosecond laser pulses delivered by Nd:YAG laser system operated at λ = 355 nm. Due to the high density of the ambient atmosphere, the intensive collisions of the plume spices result in formation of nanoparticles and aggregates by condensation close to the target. The produced nanoagregates are deposited on a quartz substrate where grow in a specific nanostructure. Diagnostics of the laser-generated plasma for the laser fluences used in this study is performed. Study based on change of ambient conditions shows that the increase of the air pressure from 10 Torr to atmospheric one leads to transition from thin film to porous structures. It is found that the surface morphology of the structures produced by pulsed laser deposition (PLD) in open air strongly depends on the substrate-target distance. The electrical properties of the obtained structures are studied by measurement of their electrical resistance. It is found that the conductivity of the structures strongly depends on their morphology. The fabricated structures have potential for application in the field of electronics and sensors.","PeriodicalId":355156,"journal":{"name":"International School on Quantum Electronics: Laser Physics and Applications","volume":"19 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2017-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128493394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Case study of the ABL height and optical parameters of the atmospheric aerosols over Sofia 索非亚上空气溶胶ABL高度和光学参数的实例研究
T. Evgenieva, N. Kolev, P. Savov, P. Kaleyna, D. Petkov, Ventsislav Danchovski, D. Ivanov, E. Donev
A study of the atmospheric boundary layer (ABL) height and its relation to the variations in the aerosol optical depth (AOD), Ångström coefficients, water vapor column (WVC) and total ozone column (TOC) was carried out in June 2011 and June 2012 at three sites in the city of Sofia (Institute of Electronics, Astronomical Observatory in the Borisova Gradina Park and National Institute of Geophysics, Geodesy and Geography). A ceilometer CHM15k, a sun photometer Microtops II, an ozonometer Microtops II and an automatic meteorological station were used during the experiments. Measurements of the AOD, WVC and TOC were done during the development of the ABL (followed by the ceilometer). In order to access microphysical properties of the aerosols, the Ångström coefficients α and β were retrieved from the spectral AOD data by the Volz method from three wavelength pairs 500/1020nm, 500/675nm and 380/1020nm. Comparison was done between the results obtained. Daily behavior of the AOD, Ångström exponent α and turbidity coefficient β, WVC and TOC are presented. Different types of AOD and WVC behavior were observed. The AOD had maximum values 1-2 h before ABL to reach its maximum height for the day. No significant correlation is found between TOC daily behavior and that of the AOD and WVC.
本文于2011年6月和2012年6月在索非亚市的三个站点(电子学研究所、Borisova Gradina公园天文台和国家地球物理、大地测量和地理研究所)对大气边界层(ABL)高度及其与气溶胶光学深度(AOD)、Ångström系数、水汽柱(WVC)和总臭氧柱(TOC)变化的关系进行了研究。实验使用了CHM15k晴雨仪、Microtops II太阳光度计、Microtops II臭氧计和自动气象站。AOD、WVC和TOC的测量是在ABL的研制过程中进行的(随后是ceilometer)。为了了解气溶胶的微物理性质,利用Volz方法从光谱AOD数据中获取了500/1020nm、500/675nm和380/1020nm三个波长对的Ångström系数α和β。对所得结果进行了比较。给出了AOD、Ångström指数α和浊度系数β、WVC和TOC的日动态。观察不同类型的AOD和WVC行为。AOD在ABL前1 ~ 2 h达到最大值,达到当天最高高度。TOC日行为与AOD、WVC无显著相关。
{"title":"Case study of the ABL height and optical parameters of the atmospheric aerosols over Sofia","authors":"T. Evgenieva, N. Kolev, P. Savov, P. Kaleyna, D. Petkov, Ventsislav Danchovski, D. Ivanov, E. Donev","doi":"10.1117/12.2262587","DOIUrl":"https://doi.org/10.1117/12.2262587","url":null,"abstract":"A study of the atmospheric boundary layer (ABL) height and its relation to the variations in the aerosol optical depth (AOD), Ångström coefficients, water vapor column (WVC) and total ozone column (TOC) was carried out in June 2011 and June 2012 at three sites in the city of Sofia (Institute of Electronics, Astronomical Observatory in the Borisova Gradina Park and National Institute of Geophysics, Geodesy and Geography). A ceilometer CHM15k, a sun photometer Microtops II, an ozonometer Microtops II and an automatic meteorological station were used during the experiments. Measurements of the AOD, WVC and TOC were done during the development of the ABL (followed by the ceilometer). In order to access microphysical properties of the aerosols, the Ångström coefficients α and β were retrieved from the spectral AOD data by the Volz method from three wavelength pairs 500/1020nm, 500/675nm and 380/1020nm. Comparison was done between the results obtained. Daily behavior of the AOD, Ångström exponent α and turbidity coefficient β, WVC and TOC are presented. Different types of AOD and WVC behavior were observed. The AOD had maximum values 1-2 h before ABL to reach its maximum height for the day. No significant correlation is found between TOC daily behavior and that of the AOD and WVC.","PeriodicalId":355156,"journal":{"name":"International School on Quantum Electronics: Laser Physics and Applications","volume":"111 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2017-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116575981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Laser induced optically and thermally reversible birefringence in azopolymers 偶氮聚合物中激光诱导的光学和热可逆双折射
D. Nazarova, L. Nedelchev, D. Ivanov, B. Blagoeva, N. Berberova, E. Stoykova, G. Mateev, D. Kostadinova
Azopolymers are well known organic materials for polarization holographic recording due to the induced anisotropy under illumination with polarized light. They possess all the desirable characteristics of the known polarization-sensitive materials, as high sensitivity and reversibility, but excel them substantially in the magnitude of the photoinduced birefringence. This makes possible to record reversible polarization gratings with high diffraction efficiency. In this paper results of experimental investigations on the reversibility properties of birefringence photoinduced in azopolymers are reported, depending on the conditions of subsequent optical and thermal treatment. Thin films of different polymers were prepared in order to examine the kinetics of multiple recording and erasure of birefringence in different types of azopolymers. The reversibility of the polarization recording has been studied using two different method of erasure – by increased temperature and on illumination with circularly polarized light.
偶氮聚合物在偏振光照射下具有诱导各向异性,是一种用于偏振全息记录的有机材料。它们具有已知偏振敏感材料的所有理想特性,如高灵敏度和可逆性,但在光致双折射的幅度上大大优于它们。这使得记录具有高衍射效率的可逆偏振光栅成为可能。本文报道了偶氮聚合物双折射光致可逆性的实验研究结果,这取决于后续的光学和热处理条件。为了研究不同类型偶氮聚合物双折射的多次记录和擦除动力学,制备了不同类型偶氮聚合物的薄膜。用两种不同的擦除方法——升温擦除和圆偏振光照射擦除,研究了偏振记录的可逆性。
{"title":"Laser induced optically and thermally reversible birefringence in azopolymers","authors":"D. Nazarova, L. Nedelchev, D. Ivanov, B. Blagoeva, N. Berberova, E. Stoykova, G. Mateev, D. Kostadinova","doi":"10.1117/12.2262357","DOIUrl":"https://doi.org/10.1117/12.2262357","url":null,"abstract":"Azopolymers are well known organic materials for polarization holographic recording due to the induced anisotropy under illumination with polarized light. They possess all the desirable characteristics of the known polarization-sensitive materials, as high sensitivity and reversibility, but excel them substantially in the magnitude of the photoinduced birefringence. This makes possible to record reversible polarization gratings with high diffraction efficiency. In this paper results of experimental investigations on the reversibility properties of birefringence photoinduced in azopolymers are reported, depending on the conditions of subsequent optical and thermal treatment. Thin films of different polymers were prepared in order to examine the kinetics of multiple recording and erasure of birefringence in different types of azopolymers. The reversibility of the polarization recording has been studied using two different method of erasure – by increased temperature and on illumination with circularly polarized light.","PeriodicalId":355156,"journal":{"name":"International School on Quantum Electronics: Laser Physics and Applications","volume":"17 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2017-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125105087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
A compact DIAL hygrometer employing paired powerful laser diodes of 0.85–0.9μm wavelengths 采用波长为0.85-0.9μm的大功率激光二极管的紧凑型DIAL湿度计
S. Penchev, V. Pencheva, S. Naboko
The spectral range of 0.85 - 0.9μm wavelengths utilized by laser diode (LD) technology contains a relatively intensive spectrum of third rovibrational overtone of the water molecule, pure of interfering spectra of the other major atmospheric gases. We developed a spectroscopic application of pulsed 100W LDs generally limited by their broad, multimode laser line. In fact, their powerful laser radiation propagating in the atmosphere is modulated significantly by multiple resonance absorption lines. The magnitude of the integral absorption pattern is assessed combining theoretical and experimental calibration and using HITRAN database. The resultant absorption spectrum is found to be unsaturated, providing a great dynamic range of measurement of atmospheric humidity within 15% random error of lidar returns ranging to 2km. The reported DIAL technique which utilizes the advantage of direct detection of the lidar profiles and simple operation is prospective for the framework of atmospheric and climatic monitoring.
激光二极管(LD)技术所利用的0.85 ~ 0.9μm波长的光谱范围包含了相对密集的水分子三振泛音光谱,不受其他主要大气气体的干扰光谱的影响。我们开发了脉冲100W ld的光谱应用,通常受其宽,多模激光线的限制。事实上,它们在大气中传播的强大激光辐射被多条共振吸收线显著调制。结合理论和实验标定,利用HITRAN数据库对积分吸收模式的大小进行了评估。所得的吸收光谱发现是不饱和的,提供了一个很大的动态范围内的大气湿度测量的激光雷达返回15%的随机误差范围到2km。本文报道的DIAL技术具有直接探测激光雷达廓线和操作简单的优点,在大气和气候监测框架中具有应用前景。
{"title":"A compact DIAL hygrometer employing paired powerful laser diodes of 0.85–0.9μm wavelengths","authors":"S. Penchev, V. Pencheva, S. Naboko","doi":"10.1117/12.2262567","DOIUrl":"https://doi.org/10.1117/12.2262567","url":null,"abstract":"The spectral range of 0.85 - 0.9μm wavelengths utilized by laser diode (LD) technology contains a relatively intensive spectrum of third rovibrational overtone of the water molecule, pure of interfering spectra of the other major atmospheric gases. We developed a spectroscopic application of pulsed 100W LDs generally limited by their broad, multimode laser line. In fact, their powerful laser radiation propagating in the atmosphere is modulated significantly by multiple resonance absorption lines. The magnitude of the integral absorption pattern is assessed combining theoretical and experimental calibration and using HITRAN database. The resultant absorption spectrum is found to be unsaturated, providing a great dynamic range of measurement of atmospheric humidity within 15% random error of lidar returns ranging to 2km. The reported DIAL technique which utilizes the advantage of direct detection of the lidar profiles and simple operation is prospective for the framework of atmospheric and climatic monitoring.","PeriodicalId":355156,"journal":{"name":"International School on Quantum Electronics: Laser Physics and Applications","volume":"9 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2017-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131259492","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Laser cleaning of graffiti on stone 激光清洗石头上的涂鸦
V. Atanassova, I. Kostadinov, P. Zahariev, M. Grozeva, I. Miloushev
In present days graffiti is a common problem that many restorers have to deal with due to both its unaesthetic appearance and damaging nature for the surface beneath. We report laser cleaning of graffiti paints (black, white, blue, green and red) on limestone and granite. The efficiency of two laser systems is compared: high repetition rate (20 kHz) Copper Bromide Vapor Laser (CuBrVL) generating wavelength 510.6 nm and low repetition rate (up to 10 Hz) Q-switched Nd:YAG laser generating fundamental wavelength 1064 nm and its second harmonic 532 nm. The surface condition of the stone samples before and after cleaning is evaluated by means of optical microscopy. On that base, suitable working parameters are chosen in order to avoid under- or over-cleaning.
如今,涂鸦是许多修复者不得不处理的一个常见问题,因为它的外观不美观,而且对下面的表面具有破坏性。我们报告激光清洗涂鸦油漆(黑色,白色,蓝色,绿色和红色)在石灰石和花岗岩。比较了两种激光系统的效率:高重复频率(20 kHz)的溴化铜蒸汽激光器(CuBrVL)产生波长510.6 nm,低重复频率(10 Hz)的调q Nd:YAG激光器产生基波1064 nm和次谐波532 nm。利用光学显微镜对清洗前后石样的表面状况进行了评价。在此基础上,选择合适的工作参数,以避免清洗不足或过度。
{"title":"Laser cleaning of graffiti on stone","authors":"V. Atanassova, I. Kostadinov, P. Zahariev, M. Grozeva, I. Miloushev","doi":"10.1117/12.2262668","DOIUrl":"https://doi.org/10.1117/12.2262668","url":null,"abstract":"In present days graffiti is a common problem that many restorers have to deal with due to both its unaesthetic appearance and damaging nature for the surface beneath. We report laser cleaning of graffiti paints (black, white, blue, green and red) on limestone and granite. The efficiency of two laser systems is compared: high repetition rate (20 kHz) Copper Bromide Vapor Laser (CuBrVL) generating wavelength 510.6 nm and low repetition rate (up to 10 Hz) Q-switched Nd:YAG laser generating fundamental wavelength 1064 nm and its second harmonic 532 nm. The surface condition of the stone samples before and after cleaning is evaluated by means of optical microscopy. On that base, suitable working parameters are chosen in order to avoid under- or over-cleaning.","PeriodicalId":355156,"journal":{"name":"International School on Quantum Electronics: Laser Physics and Applications","volume":"29 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2017-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115139774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Nanoparticle Over Mirror plasmonic structures prepared with use of Au colloid produced by laser ablation in water 利用水中激光烧蚀产生的金胶体制备纳米粒子超镜等离子体结构
M. Sawczak, Marcin Zyskowski, J. Karczewski, P. Atanasov, N. Nedyalkov, R. Nikov, N. Stankova, G. Śliwiński
Recently, an intensive research is carried out on plasmonic structures due to their potential application in many areas such as sensing, light harvesting and energy conversion and storage. In particular, a growing interest is observed in the Nanoparticle Over Mirror (NOM) structures for which the lithography and surface chemical functionalization represent the most popular production routes1. However, the application of those techniques is limited by the low efficacy, process complexity and chemical contamination of nanoparticles (NP). In this work, we report the contamination-free and low cost fabrication method of NOMs based on wet coating and ultrasonic-assisted nanocolloid drying process. The glass plates covered with magnetron sputtered 100 nm thick Au film and subsequently with Al2O3 layers (6 – 36 nm) by means of pulsed laser deposition are used as substrates. Au NPs are produced in the form of colloidal suspension by means of laser ablation in water using the 1064 nm, 6 ns Nd:YAG laser. The NOM synthesis is finalized by imposing of the Au NP suspension onto the as prepared Au-Al2O3/glass substrates and dried. To avoid NP agglomeration, the wet coated substrates are sonicated using 20W, 20 kHz ultrasound generator. SEM inspection of the obtained NOM structures confirms the positive sonication effect, i.e. the presence of agglomerate-free, homogenous layers. These consist of NPs (36 nm average diameter) which are characterized by the resonance absorption band at 528 nm. For NOM structures the UV-vis spectra reveal increased infrared activity and peak shift in agreement with theoretical modeling2. The NOM structure characterization is completed by analysis of the SEM and profilometry measurement results.
近年来,由于等离子体结构在传感、光收集、能量转换和存储等领域具有潜在的应用前景,引起了人们的广泛关注。特别是,人们对纳米颗粒Over Mirror (NOM)结构越来越感兴趣,其中光刻和表面化学功能化是最流行的生产途径1。然而,这些技术的应用受到纳米颗粒(NP)效率低、工艺复杂和化学污染的限制。本文报道了一种基于湿涂和超声辅助纳米胶体干燥工艺的无污染低成本纳米材料制备方法。采用脉冲激光沉积的方法,在玻璃板上覆盖磁控溅射100 nm厚的Au薄膜,然后再覆盖6 ~ 36 nm的Al2O3层。采用1064 nm, 6 ns Nd:YAG激光在水中烧蚀制备了胶体悬浮液形式的金纳米粒子。通过将Au NP悬浮液施加到制备好的Au- al2o3 /玻璃基板上并干燥,最终完成了NOM的合成。为了避免NP团聚,采用20W, 20khz超声发生器对湿涂基板进行超声处理。对所获得的NOM结构的SEM检查证实了积极的超声效应,即存在无团块的均匀层。它们由NPs(平均直径36 nm)组成,其特征是在528 nm处的共振吸收带。对于NOM结构,紫外可见光谱显示出增加的红外活性和峰移,这与理论模型一致2。通过对SEM和轮廓测量结果的分析,完成了NOM的结构表征。
{"title":"Nanoparticle Over Mirror plasmonic structures prepared with use of Au colloid produced by laser ablation in water","authors":"M. Sawczak, Marcin Zyskowski, J. Karczewski, P. Atanasov, N. Nedyalkov, R. Nikov, N. Stankova, G. Śliwiński","doi":"10.1117/12.2261918","DOIUrl":"https://doi.org/10.1117/12.2261918","url":null,"abstract":"Recently, an intensive research is carried out on plasmonic structures due to their potential application in many areas such as sensing, light harvesting and energy conversion and storage. In particular, a growing interest is observed in the Nanoparticle Over Mirror (NOM) structures for which the lithography and surface chemical functionalization represent the most popular production routes1. However, the application of those techniques is limited by the low efficacy, process complexity and chemical contamination of nanoparticles (NP). In this work, we report the contamination-free and low cost fabrication method of NOMs based on wet coating and ultrasonic-assisted nanocolloid drying process. The glass plates covered with magnetron sputtered 100 nm thick Au film and subsequently with Al2O3 layers (6 – 36 nm) by means of pulsed laser deposition are used as substrates. Au NPs are produced in the form of colloidal suspension by means of laser ablation in water using the 1064 nm, 6 ns Nd:YAG laser. The NOM synthesis is finalized by imposing of the Au NP suspension onto the as prepared Au-Al2O3/glass substrates and dried. To avoid NP agglomeration, the wet coated substrates are sonicated using 20W, 20 kHz ultrasound generator. SEM inspection of the obtained NOM structures confirms the positive sonication effect, i.e. the presence of agglomerate-free, homogenous layers. These consist of NPs (36 nm average diameter) which are characterized by the resonance absorption band at 528 nm. For NOM structures the UV-vis spectra reveal increased infrared activity and peak shift in agreement with theoretical modeling2. The NOM structure characterization is completed by analysis of the SEM and profilometry measurement results.","PeriodicalId":355156,"journal":{"name":"International School on Quantum Electronics: Laser Physics and Applications","volume":"32 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2017-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125198240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Laser nanostructuring for plasmon enhancement of Ag/ZnO optical characteristics 等离子体增强Ag/ZnO光学特性的激光纳米结构
M. Koleva, N. Nedyalkov, N. Fukata, W. Jevasuwan, S. Amoruso
The experimental and theoretical investigations of the optical characteristics of laser nanostructured Ag nanoparticles (AgNPs) in ZnO medium are of particular interest for this study. The Ag-ZnO nanocomposites are fabricated by room temperature pulsed laser synthesis method. Ag nanoparticles are prepared by laser deposition and subsequent laser annealing of silver thin film. Laser annealing of silver layer is performed at second and third harmonics of the Nd:YAG laser. The morphology of AgNPs differs significantly after the UV and VIS surface modification. The morphology and optical properties of the samples are studied according to the annealing regimes. A comparative study of the measured plasmon resonance properties with the theoretical calculations of the extinction efficiency by generalized multiparticle Mie (GMM) method is carried out. The extinction spectrum is determined as a function of the nanoparticles size distribution and the surrounding ZnO medium. The electromagnetic field intensity enhancement realized in the “hot spots” of AgNPs leads to substantial enhancement of the near band-edge UV photoluminescence (PL) emission of ZnO nanostructures and attenuation of the defect-related deep-level VIS PL signal after annealing at 355 nm and 532 nm.
对激光纳米结构银纳米粒子(AgNPs)在ZnO介质中的光学特性进行实验和理论研究是本研究的重点。采用室温脉冲激光合成方法制备了Ag-ZnO纳米复合材料。采用激光沉积和激光退火的方法制备银纳米粒子。在Nd:YAG激光器的二、三次谐波下对银层进行激光退火。经过UV和VIS表面修饰后,AgNPs的形貌有明显的不同。根据退火制度对样品的形貌和光学性能进行了研究。用广义多粒子Mie法(GMM)计算消光效率,并与测量的等离子体共振特性进行了对比研究。消光谱是纳米颗粒尺寸分布和周围ZnO介质的函数。在AgNPs的“热点”处实现的电磁场强度增强导致ZnO纳米结构的近带边紫外光致发光(PL)发射显著增强,并且在355nm和532nm退火后缺陷相关的深能级VIS PL信号衰减。
{"title":"Laser nanostructuring for plasmon enhancement of Ag/ZnO optical characteristics","authors":"M. Koleva, N. Nedyalkov, N. Fukata, W. Jevasuwan, S. Amoruso","doi":"10.1117/12.2262097","DOIUrl":"https://doi.org/10.1117/12.2262097","url":null,"abstract":"The experimental and theoretical investigations of the optical characteristics of laser nanostructured Ag nanoparticles (AgNPs) in ZnO medium are of particular interest for this study. The Ag-ZnO nanocomposites are fabricated by room temperature pulsed laser synthesis method. Ag nanoparticles are prepared by laser deposition and subsequent laser annealing of silver thin film. Laser annealing of silver layer is performed at second and third harmonics of the Nd:YAG laser. The morphology of AgNPs differs significantly after the UV and VIS surface modification. The morphology and optical properties of the samples are studied according to the annealing regimes. A comparative study of the measured plasmon resonance properties with the theoretical calculations of the extinction efficiency by generalized multiparticle Mie (GMM) method is carried out. The extinction spectrum is determined as a function of the nanoparticles size distribution and the surrounding ZnO medium. The electromagnetic field intensity enhancement realized in the “hot spots” of AgNPs leads to substantial enhancement of the near band-edge UV photoluminescence (PL) emission of ZnO nanostructures and attenuation of the defect-related deep-level VIS PL signal after annealing at 355 nm and 532 nm.","PeriodicalId":355156,"journal":{"name":"International School on Quantum Electronics: Laser Physics and Applications","volume":"29 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2017-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128390157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Qualitative and quantitative laser-induced breakdown spectroscopy analysis of archaeological metal artefacts 考古金属文物的定性和定量激光诱导击穿光谱分析
G. Malcheva, K. Blagoev, M. Grozeva, V. Tankova, V. Steflekova, Stefan Alexandrov, T. Hristova, Georgi Ivanov, G. Nekhrizov
In the present work, we report on the analysis of archaeological metal artefacts from Late Bronze Age, performed by means of Laser Induced Breakdown Spectroscopy (LIBS). The experiment was carried out at ambient air and at 1064 nm of a Nd:YAG laser with pulse durations of 10 ns and energy of 10 mJ. The analytical information obtained by LIBS spectra was used for qualitative determination of the elements in the material used for manufacturing of the investigated objects. Quantitative estimation of the elemental concentration of tin and lead in the bulk of the samples was done after generating calibration curves for a set of four standard samples with a wide range of tin and lead concentrations and with similar matrix composition. The preliminary results of the qualitative and the quantitative analyses gave indications about the manufacturing process of the investigated objects and for their provenance as well.
在本工作中,我们报告了用激光诱导击穿光谱(LIBS)对青铜时代晚期的考古金属文物进行分析。实验采用脉冲持续时间为10 ns、能量为10 mJ的Nd:YAG激光器,在环境空气和1064 nm波长下进行。利用LIBS光谱获得的分析信息,对所研究对象的制造材料中的元素进行定性测定。在生成四组标准样品的校准曲线后,对大部分样品中锡和铅的元素浓度进行了定量估计,这些标准样品的锡和铅浓度范围很广,基质组成相似。定性和定量分析的初步结果对所调查对象的制造过程及其来源也给出了指示。
{"title":"Qualitative and quantitative laser-induced breakdown spectroscopy analysis of archaeological metal artefacts","authors":"G. Malcheva, K. Blagoev, M. Grozeva, V. Tankova, V. Steflekova, Stefan Alexandrov, T. Hristova, Georgi Ivanov, G. Nekhrizov","doi":"10.1117/12.2262447","DOIUrl":"https://doi.org/10.1117/12.2262447","url":null,"abstract":"In the present work, we report on the analysis of archaeological metal artefacts from Late Bronze Age, performed by means of Laser Induced Breakdown Spectroscopy (LIBS). The experiment was carried out at ambient air and at 1064 nm of a Nd:YAG laser with pulse durations of 10 ns and energy of 10 mJ. The analytical information obtained by LIBS spectra was used for qualitative determination of the elements in the material used for manufacturing of the investigated objects. Quantitative estimation of the elemental concentration of tin and lead in the bulk of the samples was done after generating calibration curves for a set of four standard samples with a wide range of tin and lead concentrations and with similar matrix composition. The preliminary results of the qualitative and the quantitative analyses gave indications about the manufacturing process of the investigated objects and for their provenance as well.","PeriodicalId":355156,"journal":{"name":"International School on Quantum Electronics: Laser Physics and Applications","volume":"29 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2017-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125048100","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Spatial intensity distribution of the radiative return from scattering media irradiated by a cw laser beam 连续波激光束辐照散射介质辐射回波的空间强度分布
L. Gurdev, T. Dreischuh, O. Vankov, E. Toncheva, L. Avramov, D. Stoyanov
Experimental measurements and theoretical description have been performed of the spatial intensity distribution of the backward radiative response of tissue-like Intralipid-20% dilutions in distilled water irradiated by a collimated near-infrared cw laser beam. The investigations performed are a first step toward a complete estimation of the feasibility and potentialities of a stationary one-sided linear-strategy biomedical tomography approach to detecting characteristic inclusions (inhomogeneities, say ill places) in homogeneous highly-scattering host media (healthy tissues). The experimental results obtained are in good agreement with the derived theoretical expressions that thus would be of importance for the development and numerical modeling of stationary tomography algorithms ensuring optimally accurate data processing and interpretation.
本文对准直近红外连续波激光束辐照蒸馏水中类组织脂内-20%稀释物后向辐射响应的空间强度分布进行了实验测量和理论描述。所进行的研究是全面评估在均匀的高散射宿主介质(健康组织)中检测特征内含物(不均匀性,如病区)的平稳单侧线性策略生物医学断层扫描方法的可行性和潜力的第一步。得到的实验结果与推导出的理论表达式很好地吻合,因此对于静止层析成像算法的发展和数值模拟具有重要意义,从而确保最精确的数据处理和解释。
{"title":"Spatial intensity distribution of the radiative return from scattering media irradiated by a cw laser beam","authors":"L. Gurdev, T. Dreischuh, O. Vankov, E. Toncheva, L. Avramov, D. Stoyanov","doi":"10.1117/12.2261412","DOIUrl":"https://doi.org/10.1117/12.2261412","url":null,"abstract":"Experimental measurements and theoretical description have been performed of the spatial intensity distribution of the backward radiative response of tissue-like Intralipid-20% dilutions in distilled water irradiated by a collimated near-infrared cw laser beam. The investigations performed are a first step toward a complete estimation of the feasibility and potentialities of a stationary one-sided linear-strategy biomedical tomography approach to detecting characteristic inclusions (inhomogeneities, say ill places) in homogeneous highly-scattering host media (healthy tissues). The experimental results obtained are in good agreement with the derived theoretical expressions that thus would be of importance for the development and numerical modeling of stationary tomography algorithms ensuring optimally accurate data processing and interpretation.","PeriodicalId":355156,"journal":{"name":"International School on Quantum Electronics: Laser Physics and Applications","volume":"41 16","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2017-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"120887539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Lidar measurements of wildfire smoke aerosols in the atmosphere above Sofia, Bulgaria 保加利亚索非亚上空大气中野火烟雾气溶胶的激光雷达测量
Z. Peshev, A. Deleva, T. Dreischuh, D. Stoyanov
Presented are results of lidar measurements and characterization of wildfire caused smoke aerosols observed in the atmosphere above the city of Sofia, Bulgaria, related to two local wildfires raging in forest areas near the city. A lidar systems based on a frequency-doubled Nd:YAG laser operated at 532 nm and 1064 nm is used in the smoke aerosol observations. It belongs to the Sofia LIDAR Station (at Laser Radars Laboratory, Institute of Electronics, Bulgarian Academy of Sciences), being a part of the European Aerosol Lidar Network. Optical, dynamical, microphysical, and geometrical properties and parameters of the observed smoke aerosol particles and layers are displayed and analyzed, such as: range/height-resolved profiles of the aerosol backscatter coefficient; integral aerosol backscattering; sets of colormaps displaying time series of the height distribution of the aerosol density; topologic, geometric, and volumetric properties of the smoke aerosol layers; time-averaged height profiles of backscatter-related Ǻngström exponent (BAE). Obtained results of retrieving and profiling smoke aerosols are commented in their relations to available meteorological and air-mass-transport forecasting and modelling data.
本文介绍了在保加利亚索非亚市上空大气中观测到的野火引起的烟雾气溶胶的激光雷达测量结果和特征,这与城市附近森林地区肆虐的两场当地野火有关。采用双频Nd:YAG激光系统,工作波长分别为532 nm和1064 nm,用于烟雾气溶胶观测。它属于索菲亚激光雷达站(在保加利亚科学院电子研究所激光雷达实验室),是欧洲气溶胶激光雷达网络的一部分。显示和分析了观测到的烟雾气溶胶粒子和层的光学、动力学、微物理和几何特性和参数,例如:气溶胶后向散射系数的距离/高度分辨曲线;积分气溶胶后向散射;显示气溶胶密度高度分布时间序列的几组彩色图;烟雾气溶胶层的拓扑、几何和体积特性;后向散射相关Ǻngström指数(BAE)的时间平均高度剖面。对烟雾气溶胶的检索和分析结果与现有气象和气团输送预报和模拟数据的关系进行了评论。
{"title":"Lidar measurements of wildfire smoke aerosols in the atmosphere above Sofia, Bulgaria","authors":"Z. Peshev, A. Deleva, T. Dreischuh, D. Stoyanov","doi":"10.1117/12.2263103","DOIUrl":"https://doi.org/10.1117/12.2263103","url":null,"abstract":"Presented are results of lidar measurements and characterization of wildfire caused smoke aerosols observed in the atmosphere above the city of Sofia, Bulgaria, related to two local wildfires raging in forest areas near the city. A lidar systems based on a frequency-doubled Nd:YAG laser operated at 532 nm and 1064 nm is used in the smoke aerosol observations. It belongs to the Sofia LIDAR Station (at Laser Radars Laboratory, Institute of Electronics, Bulgarian Academy of Sciences), being a part of the European Aerosol Lidar Network. Optical, dynamical, microphysical, and geometrical properties and parameters of the observed smoke aerosol particles and layers are displayed and analyzed, such as: range/height-resolved profiles of the aerosol backscatter coefficient; integral aerosol backscattering; sets of colormaps displaying time series of the height distribution of the aerosol density; topologic, geometric, and volumetric properties of the smoke aerosol layers; time-averaged height profiles of backscatter-related Ǻngström exponent (BAE). Obtained results of retrieving and profiling smoke aerosols are commented in their relations to available meteorological and air-mass-transport forecasting and modelling data.","PeriodicalId":355156,"journal":{"name":"International School on Quantum Electronics: Laser Physics and Applications","volume":"14 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2017-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126812755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
International School on Quantum Electronics: Laser Physics and Applications
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1