首页 > 最新文献

Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya最新文献

英文 中文
THE USE OF KALMAN FILTER IN AUTOMATIC CONTROL OF INDICATORS OF IRON ORES MAGNETIC CONCENTRATION 卡尔曼滤波在铁矿石磁选指标自动控制中的应用
Q3 Materials Science Pub Date : 2018-06-01 DOI: 10.17073/0368-0797-2018-5-372-377
N. V. Osipova
The paper presents the current state of the problems of automation and control data of wet magnetic concentration for iron ore mining and processing plants. Data on the measurement errors of modern analyzers and material composition of the pulp are considered. The possibility of using Kalman filter in order to obtain the most accurate information about the content of valuable component in concentrate and tailings of magnetic separator products is shown. The mathematical description of the dynamics of concentration indicators is given in state coordinates in the form of differential equations system. The author has selected maximum allowable and nominal values of the water flow in the separator bath and the rotation frequency of its drum as well as the corresponding data for the mass fraction of iron in magnetite concentrate and tailings, based on the reference information. With MATLAB program of computer simulation the nonlinear static characteristics were composed, reflecting the dependence of technological parameters of the magnetic concentration from control actions. The linearization dynamic model of the system is held using expansion in Taylor series in the neighborhood of the points, corresponding to a nominal operation mode. The transfer functions of control valve of water flow rate of induction motor rotating the drum were calculated. Standard deviations of control parameters affecting the separation process were determined. The calculated ratio are obtained for determining the covariance matrices of the system noise, describing dynamics of indicators of magnetic concentration, and the noise of their measurement by devices that control the content of magnetite iron in concentrate and tails. The presented algorithm of estimating the coordinates of the Kalman filter state consists of two stages: prediction of the system state and adjustment of the state vector. Simulation results of the MATLAB programming environment are presented in the form of time diagrams reflecting the dynamics of technological indicators of concentration, the evaluation of the Kalman filter and measurement error. The system has been considered in case of random changes of control actions. At the end of the article, the results are summed up, where it is reported that the Kalman filter should be used in tasks of automation and control of the iron ore concentration process.
{"title":"THE USE OF KALMAN FILTER IN AUTOMATIC CONTROL OF INDICATORS OF IRON ORES MAGNETIC CONCENTRATION","authors":"N. V. Osipova","doi":"10.17073/0368-0797-2018-5-372-377","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-5-372-377","url":null,"abstract":"The paper presents the current state of the problems of automation and control data of wet magnetic concentration for iron ore mining and processing plants. Data on the measurement errors of modern analyzers and material composition of the pulp are considered. The possibility of using Kalman filter in order to obtain the most accurate information about the content of valuable component in concentrate and tailings of magnetic separator products is shown. The mathematical description of the dynamics of concentration indicators is given in state coordinates in the form of differential equations system. The author has selected maximum allowable and nominal values of the water flow in the separator bath and the rotation frequency of its drum as well as the corresponding data for the mass fraction of iron in magnetite concentrate and tailings, based on the reference information. With MATLAB program of computer simulation the nonlinear static characteristics were composed, reflecting the dependence of technological parameters of the magnetic concentration from control actions. The linearization dynamic model of the system is held using expansion in Taylor series in the neighborhood of the points, corresponding to a nominal operation mode. The transfer functions of control valve of water flow rate of induction motor rotating the drum were calculated. Standard deviations of control parameters affecting the separation process were determined. The calculated ratio are obtained for determining the covariance matrices of the system noise, describing dynamics of indicators of magnetic concentration, and the noise of their measurement by devices that control the content of magnetite iron in concentrate and tails. The presented algorithm of estimating the coordinates of the Kalman filter state consists of two stages: prediction of the system state and adjustment of the state vector. Simulation results of the MATLAB programming environment are presented in the form of time diagrams reflecting the dynamics of technological indicators of concentration, the evaluation of the Kalman filter and measurement error. The system has been considered in case of random changes of control actions. At the end of the article, the results are summed up, where it is reported that the Kalman filter should be used in tasks of automation and control of the iron ore concentration process.","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82666716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
INFLUENCE OF WHEEL BILLET STAMPING SCHEMES ON POWER MODES OF FORMING PRESS OPERATION AND ON WEAR OF THE DEFORMATION TOOL 车轮小方坯冲压方案对成形压力机动力模式及变形刀磨损的影响
Q3 Materials Science Pub Date : 2018-06-01 DOI: 10.17073/0368-0797-2018-5-385-392
S. Snitko, A. V. Yakovchenko, A. Sotnikov
Ensuring the stability of the dimensions of the stamped-rolled railway wheels, the rational power modes of the press operation and durability of the metal deformation tool parts, as well as reduction of the initial billets mass, are actual scientific and technical tasks. This durability largely determines the costs associated with the choice of steel grade for dies, technology of their manufacture and process lubrication. In the present work, based on the results of finite element modeling, the analysis of the influence of stamping schemes of wheel billets on the power modes of operation of a forming press and on wear of the deformation tool was made in relation to modern press rolling lines. It is shown that the stamping schemes, which provide for the regulated distribution of metal between the central and peripheral parts of the billet delivered to the stamps, are characterized by a  rational power mode of the forming press. The average force in this case is 63  –  70  % of the average force when stamping out of the billets, sagged by smooth slabs. Elimination of premature filling of the hub contributes to a decrease in the average (by the upper and lower stamps) of the wear of molding dies by 20  –  24  %. It was established that in the process of metal reduction in the disk zone, as the earlier formation of the resistance to flow of metal from the side of the molding ring is formed, the smaller slip of the deformable metal relative to the surface of the molding dies is in the zones of their most intense wear (the transition from the disk to the rim) and, as a consequence, less wear amount appears. It has also been found that the metal deformation scheme in molding dies ensuring filling of the flange during axial metal reduction in the rim zone, decrease the metal slippage relatively to the surface of the molding dies at the zones of transition from the disc to the rim. The additional decrease of wear in this case is 27  –  33  %. Ensuring the dimensions stability of the stamped-rolled railway wheels is possible on the basis of stamping schemes, providing a regulated distribution of metal between the central and peripheral parts of the billet and its self-centering in molding dies. This will reduce the weight of the initial billet by 7  –  10  kg.
{"title":"INFLUENCE OF WHEEL BILLET STAMPING SCHEMES ON POWER MODES OF FORMING PRESS OPERATION AND ON WEAR OF THE DEFORMATION TOOL","authors":"S. Snitko, A. V. Yakovchenko, A. Sotnikov","doi":"10.17073/0368-0797-2018-5-385-392","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-5-385-392","url":null,"abstract":"Ensuring the stability of the dimensions of the stamped-rolled railway wheels, the rational power modes of the press operation and durability of the metal deformation tool parts, as well as reduction of the initial billets mass, are actual scientific and technical tasks. This durability largely determines the costs associated with the choice of steel grade for dies, technology of their manufacture and process lubrication. In the present work, based on the results of finite element modeling, the analysis of the influence of stamping schemes of wheel billets on the power modes of operation of a forming press and on wear of the deformation tool was made in relation to modern press rolling lines. It is shown that the stamping schemes, which provide for the regulated distribution of metal between the central and peripheral parts of the billet delivered to the stamps, are characterized by a  rational power mode of the forming press. The average force in this case is 63  –  70  % of the average force when stamping out of the billets, sagged by smooth slabs. Elimination of premature filling of the hub contributes to a decrease in the average (by the upper and lower stamps) of the wear of molding dies by 20  –  24  %. It was established that in the process of metal reduction in the disk zone, as the earlier formation of the resistance to flow of metal from the side of the molding ring is formed, the smaller slip of the deformable metal relative to the surface of the molding dies is in the zones of their most intense wear (the transition from the disk to the rim) and, as a consequence, less wear amount appears. It has also been found that the metal deformation scheme in molding dies ensuring filling of the flange during axial metal reduction in the rim zone, decrease the metal slippage relatively to the surface of the molding dies at the zones of transition from the disc to the rim. The additional decrease of wear in this case is 27  –  33  %. Ensuring the dimensions stability of the stamped-rolled railway wheels is possible on the basis of stamping schemes, providing a regulated distribution of metal between the central and peripheral parts of the billet and its self-centering in molding dies. This will reduce the weight of the initial billet by 7  –  10  kg.","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72569825","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
STRUCTURE FEATURES OF THE Fe –Cu–Nb–Si–B BASED NANOCRYSTALLINE ALLOY RIBBON PRODUCED BY THE MELT SPINNING METHOD 熔体纺丝法制备Fe -Cu-Nb-Si-B基纳米晶合金带的结构特征
Q3 Materials Science Pub Date : 2018-06-01 DOI: 10.17073/0368-0797-2018-5-393-398
P. Kuznetsov, V. Klimov, D. Kirilenko, M. Yagovkina, E. A. Samodelki
Amorphous and nanocrystal magnetic soft Fe-based alloys are widely used for the shielding materials production, which are effective in the wide range of magnetic and electromagnetic fields. These alloys are obtained in ribbons by an ultra-quick quenching of the melt flow on the high-speed rotating refrigerator-disk. During the amorphous ribbons production process, melted in the high-frequency inductor metal is fed through the dye on the surface of the quenching disk, wherein the surface layers, contacted with the refrigerator-disk, of the forming amorphous ribbon are cooled quicker than the top ones, which are not in contact with the refrigerator-disk. As the result on the “contact” side of the ribbon the residual compression stresses can occur, wherein on the “free” side – the tension stresses. All these can lead to the structure anisotropy along the ribbon thickness, therefore also to the properties anisotropy during the further heat treatment. In the present paper, the results of the TEM structure analysis (planar geometry and transversal cut geometry) along the ribbon thickness of the AMAG200 alloy (Fe – Nb – Cu – Si – B system), obtained by the spinning method, are presented. The relation between the structure changes in the amorphous AMAG-200 alloy (Fe – Nb – Cu – Si – B system), which occurred during the process of the controlled crystallization, with the structure features of the amorphous ribbon, obtained by the ultra-quick quenching of the melt (with the cooling speed up to 106 K/s) is determined, explaining the structure anisotropy along the ribbon thickness. It is stated that the heat treatment under 530 °С forms high magnetic properties and lowers the destruction energy by the formation of the optimal amorphous-nanocrystallline structure in part of grains volume fraction and size. Using the SEM the fracture appearance analysis was performed, connected to the structure obtained during the ultra-quick quenching from the melt and after the heat treatment under 530  °С. It is stated that the fracture surface at the as-build state provide viscous type and after heat treatment-completely brittle type.
{"title":"STRUCTURE FEATURES OF THE Fe –Cu–Nb–Si–B BASED NANOCRYSTALLINE ALLOY RIBBON PRODUCED BY THE MELT SPINNING METHOD","authors":"P. Kuznetsov, V. Klimov, D. Kirilenko, M. Yagovkina, E. A. Samodelki","doi":"10.17073/0368-0797-2018-5-393-398","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-5-393-398","url":null,"abstract":"Amorphous and nanocrystal magnetic soft Fe-based alloys are widely used for the shielding materials production, which are effective in the wide range of magnetic and electromagnetic fields. These alloys are obtained in ribbons by an ultra-quick quenching of the melt flow on the high-speed rotating refrigerator-disk. During the amorphous ribbons production process, melted in the high-frequency inductor metal is fed through the dye on the surface of the quenching disk, wherein the surface layers, contacted with the refrigerator-disk, of the forming amorphous ribbon are cooled quicker than the top ones, which are not in contact with the refrigerator-disk. As the result on the “contact” side of the ribbon the residual compression stresses can occur, wherein on the “free” side – the tension stresses. All these can lead to the structure anisotropy along the ribbon thickness, therefore also to the properties anisotropy during the further heat treatment. In the present paper, the results of the TEM structure analysis (planar geometry and transversal cut geometry) along the ribbon thickness of the AMAG200 alloy (Fe – Nb – Cu – Si – B system), obtained by the spinning method, are presented. The relation between the structure changes in the amorphous AMAG-200 alloy (Fe – Nb – Cu – Si – B system), which occurred during the process of the controlled crystallization, with the structure features of the amorphous ribbon, obtained by the ultra-quick quenching of the melt (with the cooling speed up to 106 K/s) is determined, explaining the structure anisotropy along the ribbon thickness. It is stated that the heat treatment under 530 °С forms high magnetic properties and lowers the destruction energy by the formation of the optimal amorphous-nanocrystallline structure in part of grains volume fraction and size. Using the SEM the fracture appearance analysis was performed, connected to the structure obtained during the ultra-quick quenching from the melt and after the heat treatment under 530  °С. It is stated that the fracture surface at the as-build state provide viscous type and after heat treatment-completely brittle type.","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80393381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ТЕХНОЛОГИЯ CВС КОМПОЗИЦИОННЫХ ФЕРРОСПЛАВОВ ЧАСТЬ I. МЕТАЛЛУРГИЧЕСКИЙ СВС ПРОЦЕСС. СИНТЕЗ НИТРИДОВ ФЕРРОВАНАДИЯ И ФЕРРОХРОМА
Q3 Materials Science Pub Date : 2018-06-01 DOI: 10.17073/0368-0797-2018-5-339-347
М. Х. Зиатдинов, И. М. Шатохин, Леопольд Игоревич Леонтьев
The article presents research findings in the development of a  specialized SHS technology for composite ferrous alloys for steel melting and blast furnace iron-making. To resolve the principle goal of creating metallurgical production lines it was developed a new approach to practical implementation of the SHS method – a metallurgical SHS process. The metallurgical version of SHS is based on using different metallurgical alloys as the main raw stock; those include dust-type wastes of ferrite alloys production. In this case, the process of synthesis by combustion is implemented via exothermic exchange reactions. Here, composite materials form; they are based on inorganic compositions bound with iron and/or an alloy based on iron. It has been shown that depending on the aggregate state of source reagents, metallurgical SHS processes can be gasless, gasabsorbing or gas-yielding. Combustion modes for these processes largely differ. To arrange for metallurgical SHS process in weakly exothermic systems, one can use different versions of the thermal bonding principle. The authors have investigated self-propagating high-temperature synthesis of nitrided ferrovanadium and ferrochrome. It has been shown that the phase composition of the source alloy has strong impact on the consistent behaviors of the combustion flow and the combustion mechanism of ferrovanadium (if combustion is taking place in nitrogen atmosphere). In the course of nitriding σ-(Fe – V), process activation takes place; the activation is related to the transformation of the intermetallide into α-solid solution when the phase transition temperature is reached (~1200  °C). The composition structure of ferrovanadium nitride products is formed by the confluence of solid-liquid droplet-particles that consist of molten Fe and solid vanadium nitride. A 3-phase mechanism of ferrochrome interaction with nitrogen facilitates the achievement of a high degree of nitriding. It was shown that the combustion rates of ferrochrome (and chrome) during nitriding in coflow filtration mode increase as the nitrogen flow rate is increased. Here, the degree of ferrochrome nitriding during forced filtration (4.7  –  7.5  %  N) is much less than that during non-forced filtration (8.8  –  14.2  %  N).
本文介绍了炼钢和高炉炼铁用复合铁合金专用SHS技术开发的研究成果。为解决建立冶金生产线的主要目标,开发了一种新的SHS方法的实际实施方法——冶金SHS过程。SHS的冶金版本是基于使用不同的冶金合金作为主要原料;其中包括铁氧体合金生产中产生的粉尘废物。在这种情况下,燃烧合成的过程是通过放热交换反应实现的。在这里,复合材料形成;它们是基于与铁结合的无机组合物和/或基于铁的合金。研究表明,根据源试剂的聚集状态,冶金SHS过程可以是无气、吸气或产气的。这些过程的燃烧模式差别很大。为了安排弱放热系统中的冶金SHS过程,可以使用不同版本的热键合原理。研究了氮化钒铁和铬铁的自蔓延高温合成。研究表明,源合金的相组成对钒铁燃烧流的一致性和燃烧机理有很大影响(如果在氮气气氛中燃烧)。在渗氮σ-(Fe - V)过程中,发生了过程活化;当相变温度达到(~1200℃)时,金属间化物转变为α-固溶体。氮化钒铁产品的组成结构是由熔融铁和固体氮化钒组成的固液液滴颗粒汇合形成的。铬铁与氮相互作用的三相机制有助于实现高氮化。结果表明,在共流过滤模式下,随着氮流量的增加,氮化过程中铬铁(和铬)的燃烧速率增加。在这里,强制过滤(4.7 - 7.5% N)时铬铁氮化程度远小于非强制过滤(8.8 - 14.2% N)时。
{"title":"ТЕХНОЛОГИЯ CВС КОМПОЗИЦИОННЫХ ФЕРРОСПЛАВОВ ЧАСТЬ I. МЕТАЛЛУРГИЧЕСКИЙ СВС ПРОЦЕСС. СИНТЕЗ НИТРИДОВ ФЕРРОВАНАДИЯ И ФЕРРОХРОМА","authors":"М. Х. Зиатдинов, И. М. Шатохин, Леопольд Игоревич Леонтьев","doi":"10.17073/0368-0797-2018-5-339-347","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-5-339-347","url":null,"abstract":"The article presents research findings in the development of a  specialized SHS technology for composite ferrous alloys for steel melting and blast furnace iron-making. To resolve the principle goal of creating metallurgical production lines it was developed a new approach to practical implementation of the SHS method – a metallurgical SHS process. The metallurgical version of SHS is based on using different metallurgical alloys as the main raw stock; those include dust-type wastes of ferrite alloys production. In this case, the process of synthesis by combustion is implemented via exothermic exchange reactions. Here, composite materials form; they are based on inorganic compositions bound with iron and/or an alloy based on iron. It has been shown that depending on the aggregate state of source reagents, metallurgical SHS processes can be gasless, gasabsorbing or gas-yielding. Combustion modes for these processes largely differ. To arrange for metallurgical SHS process in weakly exothermic systems, one can use different versions of the thermal bonding principle. The authors have investigated self-propagating high-temperature synthesis of nitrided ferrovanadium and ferrochrome. It has been shown that the phase composition of the source alloy has strong impact on the consistent behaviors of the combustion flow and the combustion mechanism of ferrovanadium (if combustion is taking place in nitrogen atmosphere). In the course of nitriding σ-(Fe – V), process activation takes place; the activation is related to the transformation of the intermetallide into α-solid solution when the phase transition temperature is reached (~1200  °C). The composition structure of ferrovanadium nitride products is formed by the confluence of solid-liquid droplet-particles that consist of molten Fe and solid vanadium nitride. A 3-phase mechanism of ferrochrome interaction with nitrogen facilitates the achievement of a high degree of nitriding. It was shown that the combustion rates of ferrochrome (and chrome) during nitriding in coflow filtration mode increase as the nitrogen flow rate is increased. Here, the degree of ferrochrome nitriding during forced filtration (4.7  –  7.5  %  N) is much less than that during non-forced filtration (8.8  –  14.2  %  N).","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77145414","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
INFLUENCE OF BENDING EFFORTS OF WORKING ROLLS ON WIDENING OF THE THIN STEEL STRIP DURING HOT ROLLING 热轧过程中工作辊弯曲力对薄带钢加宽的影响
Q3 Materials Science Pub Date : 2018-06-01 DOI: 10.17073/0368-0797-2018-5-348-356
T. Koinov, S. M. Bel’skii, Y. A. Mukhin, V. B. Chuprov
Based on the Jourdain variation principle, a mathematical model of the process of free widening in hot rolling of thin sheet metal is developed. The principle applies to rigid-plastic materials and for the cinematically admissible area of speeds. As a functional of the variational equation, sum of the powers of internal resistances, frictional forces, shear forces, front and back tension was used. When solving the Jourdain variational equation for the case of rolling with tension, the Ritz method was applied. The Jourdain variational equation was transformed into a system of homogeneous equations, the left side of each represented a derivative with respect to a varying parameter. Varying parameters were the exponent of the kinematic condition, general widening in the plastic deformation zone and the widening in its neutral section. The developed model allows to study the distribution of the widening on length of the deformation zone depending on the parameters of rolling process and sheet metal. To test the adequacy of the developed free-widening model, experimental studies were carried out on a two-roll cold rolling mill. Lead samples were rolled, the measured widening values of which coincided with the theoretical calculated with an accuracy of less than 10%. Cold rolling of lead samples simulates hot rolling. Theoretical analysis of the influence of tension on the process of free widening when applying tension is consistent with the practical results presented in the literature. It is shown that the unevenness of tensile stresses in the input and output sections of the deformation zone arising from the application of tension causes the appearance of additional powers in the power balance equation, leading to a decrease in magnitude of the widening. The resulting unevenness of the tensile stresses can be used to control magnitude of the widening in thin-sheet rolling. In turn, unevenness of the tensile stresses along the width of rolled strip can be increased or decreased by means of the bending forces of work rolls of the rolling stand. The article presents a scheme for controlling the value of the rolling band widening during hot rolling with the help of bending forces of work rolls.
基于jourain变分原理,建立了薄板热轧自由加宽过程的数学模型。该原理适用于刚塑性材料和电影允许的速度范围。作为变分方程的泛函,采用内阻、摩擦力、剪力、前后张力的幂和。在求解带张力滚动的jourain变分方程时,采用了Ritz方法。Jourdain变分方程被转化为齐次方程组,每个方程的左侧表示对变化参数的导数。变化参数为运动条件的指数、塑性变形区的一般加宽和中性区加宽。建立的模型可以研究变形区宽度随轧制工艺参数和板料参数的分布。为了验证所建立的自由加宽模型的有效性,在一台二辊冷轧机上进行了试验研究。对铅试样进行轧制,测得的增宽值与理论计算值吻合,精度小于10%。铅样品的冷轧模拟了热轧。在施加张力时,张力对自由加宽过程影响的理论分析与文献中给出的实际结果一致。结果表明,由于拉伸作用引起的变形区输入和输出段拉应力的不均匀性,导致在功率平衡方程中出现额外的功率,导致加宽的幅度减小。由此产生的拉伸应力的不均匀性可以用来控制薄板轧制中加宽的大小。反过来,沿轧制带材宽度的拉伸应力的不均匀性可以通过轧制机架工作辊的弯曲力来增加或减少。本文提出了一种利用工作辊弯曲力控制热轧带钢加宽值的方案。
{"title":"INFLUENCE OF BENDING EFFORTS OF WORKING ROLLS ON WIDENING OF THE THIN STEEL STRIP DURING HOT ROLLING","authors":"T. Koinov, S. M. Bel’skii, Y. A. Mukhin, V. B. Chuprov","doi":"10.17073/0368-0797-2018-5-348-356","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-5-348-356","url":null,"abstract":"Based on the Jourdain variation principle, a mathematical model of the process of free widening in hot rolling of thin sheet metal is developed. The principle applies to rigid-plastic materials and for the cinematically admissible area of speeds. As a functional of the variational equation, sum of the powers of internal resistances, frictional forces, shear forces, front and back tension was used. When solving the Jourdain variational equation for the case of rolling with tension, the Ritz method was applied. The Jourdain variational equation was transformed into a system of homogeneous equations, the left side of each represented a derivative with respect to a varying parameter. Varying parameters were the exponent of the kinematic condition, general widening in the plastic deformation zone and the widening in its neutral section. The developed model allows to study the distribution of the widening on length of the deformation zone depending on the parameters of rolling process and sheet metal. To test the adequacy of the developed free-widening model, experimental studies were carried out on a two-roll cold rolling mill. Lead samples were rolled, the measured widening values of which coincided with the theoretical calculated with an accuracy of less than 10%. Cold rolling of lead samples simulates hot rolling. Theoretical analysis of the influence of tension on the process of free widening when applying tension is consistent with the practical results presented in the literature. It is shown that the unevenness of tensile stresses in the input and output sections of the deformation zone arising from the application of tension causes the appearance of additional powers in the power balance equation, leading to a decrease in magnitude of the widening. The resulting unevenness of the tensile stresses can be used to control magnitude of the widening in thin-sheet rolling. In turn, unevenness of the tensile stresses along the width of rolled strip can be increased or decreased by means of the bending forces of work rolls of the rolling stand. The article presents a scheme for controlling the value of the rolling band widening during hot rolling with the help of bending forces of work rolls.","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88987222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ON THE USE OF KOVDOR IRON ORE IN SINTERING PROCESS 科夫多尔铁矿在烧结工艺中的应用
Q3 Materials Science Pub Date : 2018-06-01 DOI: 10.17073/0368-0797-2018-5-413-415
T. Malysheva, S. A. Pisarev, A. R. Makavetskas, Yu. Yu. Fishchenko
Recently, the demand for iron ore concentrates of the Kovdor deposit has been maintained, despite the complexity of their use for the production of man-made raw materials. Magnetite of Kovdor ore has a heterogeneous structure and its iron does not participate in melt formation processes during sintering of agglomerates. Therefore, up to the basicity of 2.0, a silicate glass phase is a binder of ore grains of the finished product. With the increase in basicity above 2.0, the mineral composition and microstructure of the agglomerates change. Magnetite is oxidized to hematite, an alumino-siliciferite appears on the hematite contact with the high-calcium melt, the residual melt crystallizes to form a titanium-containing silicate.
{"title":"ON THE USE OF KOVDOR IRON ORE IN SINTERING PROCESS","authors":"T. Malysheva, S. A. Pisarev, A. R. Makavetskas, Yu. Yu. Fishchenko","doi":"10.17073/0368-0797-2018-5-413-415","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-5-413-415","url":null,"abstract":"Recently, the demand for iron ore concentrates of the Kovdor deposit has been maintained, despite the complexity of their use for the production of man-made raw materials. Magnetite of Kovdor ore has a heterogeneous structure and its iron does not participate in melt formation processes during sintering of agglomerates. Therefore, up to the basicity of 2.0, a silicate glass phase is a binder of ore grains of the finished product. With the increase in basicity above 2.0, the mineral composition and microstructure of the agglomerates change. Magnetite is oxidized to hematite, an alumino-siliciferite appears on the hematite contact with the high-calcium melt, the residual melt crystallizes to form a titanium-containing silicate.","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79824862","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
EFFECT OF TECHNOLOGICAL ERRORS ON FORCE PARAMETERS OF PIPES COLD ROLLING 工艺误差对钢管冷轧受力参数的影响
Q3 Materials Science Pub Date : 2018-06-01 DOI: 10.17073/0368-0797-2018-5-416-417
G. Orlov, A. A. Malanov, A. G. Orlov
The results of numerical experiments on studying of influence of technological errors on the vertical and horizontal forces of rolling are given. A full factorial computational experiment was performed by varying factors: initial wall thickness variation of pipes, feed and friction factor. The regression equations were obtained by the vertical and horizontal forces from these factors. It was found that the force values obtained when the maximum values of the factors are much higher than the values obtained at minimum values of factors: the vertical force varies by more than 2 times, and the axial force – more than 8 times. It was concluded that the errors of setup rolling parameters can cause a multiple increase in the forces of rolling, especially, in the horizontal component. Therefore, for stable rolling mills operation the observance of procedures discipline and control the initial wall thickness variation of pipes are necessary.
给出了工艺误差对轧制纵向力和水平力影响的数值试验结果。对管道初始壁厚变化、进料和摩擦因素进行了全因子计算实验。根据这些因素的垂直力和水平力得到回归方程。结果发现,在各因素达到最大值时得到的力值远高于各因素达到最小值时得到的力值:竖向力变化2倍以上,轴向力变化8倍以上。分析结果表明,设置轧制参数的误差会导致轧制力的成倍增大,特别是在水平分量上。因此,为了保证轧机的稳定运行,必须遵守规程、纪律和控制管材的初始壁厚变化。
{"title":"EFFECT OF TECHNOLOGICAL ERRORS ON FORCE PARAMETERS OF PIPES COLD ROLLING","authors":"G. Orlov, A. A. Malanov, A. G. Orlov","doi":"10.17073/0368-0797-2018-5-416-417","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-5-416-417","url":null,"abstract":"The results of numerical experiments on studying of influence of technological errors on the vertical and horizontal forces of rolling are given. A full factorial computational experiment was performed by varying factors: initial wall thickness variation of pipes, feed and friction factor. The regression equations were obtained by the vertical and horizontal forces from these factors. It was found that the force values obtained when the maximum values of the factors are much higher than the values obtained at minimum values of factors: the vertical force varies by more than 2 times, and the axial force – more than 8 times. It was concluded that the errors of setup rolling parameters can cause a multiple increase in the forces of rolling, especially, in the horizontal component. Therefore, for stable rolling mills operation the observance of procedures discipline and control the initial wall thickness variation of pipes are necessary.","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83127144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
КОНЦЕПЦИЯ ОПТИМАЛЬНОЙ КАЛИБРОВКИ СОРТОПРОКАТНЫХ ВАЛКОВ. СООБЩЕНИЕ 3. ПРОСТРАНСТВО СХЕМ КАЛИБРОВОК 最佳轧辊校准的概念。信息3。校准电路空间
Q3 Materials Science Pub Date : 2018-06-01 DOI: 10.17073/0368-0797-2018-5-364-371
А. М. Михайленко, Данил Леонидович Шварц
Based on the system approach and on the experience accumulated at theoretical data, design and industrial development of bar rolling, the Chair “Metal Forming” of Ural Federal University develops the universal “Concept of optimum calibration”. The general ideology of roll pass design optimization is stated in article “The concept of optimal bar roll pass design. Report 1. Basic statements”. In the article “The concept of optimal bar roll pass design. Report 2. Calibers space” the structure, appointment and maintenance of the information block reflecting so-called “calibers space” are considered. According to the general concept of optimization, the following task that needs to be solved is the problem of creation of information block so-called “space of schemes of roll pass design” which will be used further as the first space of optimization. The concept “space of schemes of roll pass design of a bar-rolling mill” is considered as the space containing all possible virtual schemes of rolling of a concrete profile on the concrete rolling mill. For formation of the space of schemes of rail calibrations it is necessary to generate separate virtual schemes and to consistently fill this space with them. Thus, the space of calibrations schemes is formed of separate unique calibrations schemes. For formation of this space from separate calibers, it is offered to use the specialized algorithms which are “generators of schemes of roll pass design”. As an example, the structure of the generator prepared for creation of such space for rolling of railway rails is considered. It is revealed that all known rail calibrations can be presented in the form of essentially the same block structure which is used as the central element of the schemes generator of rail calibrations. Usage of described and similar generators in relation to rolling process of a concrete profile on the concrete rolling mill allows obtaining spaces of acceptable schemes of calibrations. Such spaces are necessary for the subsequent optimizing procedures for search of the best calibration scheme from all possible calibrations. The considered approach for creation of calibrations schemes space can be used during creation of computer-aided engineering systems and optimization of calibrations of rolling rolls.
乌拉尔联邦大学“金属成形”教授基于系统方法和在棒材轧制理论数据、设计和工业发展方面积累的经验,提出了通用的“最佳校准概念”。摘要“棒材辊型优化设计的概念”阐述了辊型优化设计的一般思想。报告1。基本语句”。文中提出了棒材辊孔型优化设计的概念。报告2。考虑了反映所谓“口径空间”的信息块的结构、约定和维护。根据优化的一般概念,接下来需要解决的任务是创建信息块的问题,即所谓的“辊道设计方案空间”,这将进一步用作优化的第一个空间。“棒材轧机轧辊孔型设计方案空间”的概念被认为是包含混凝土轧机上所有可能的混凝土型材轧制虚拟方案的空间。为了形成钢轨标定方案空间,必须生成单独的虚拟方案,并将其连续地填充在该空间中。因此,标定方案的空间是由独立的唯一标定方案组成的。为了从不同的口径形成这个空间,提供了使用专门的算法,这些算法是“辊型设计方案的生成器”。作为一个例子,考虑了为制造这样的轨道滚动空间而准备的发电机的结构。结果表明,所有已知的钢轨标定都可以以基本相同的块结构形式表示,该块结构用作钢轨标定方案发生器的中心元件。在混凝土轧机上使用所描述的和类似的与混凝土型材轧制过程有关的发电机,可以获得可接受的校准方案的空间。这些空间对于从所有可能的校准中搜索最佳校准方案的后续优化程序是必要的。所考虑的标定方案空间的创建方法可用于计算机辅助工程系统的创建和轧辊标定的优化。
{"title":"КОНЦЕПЦИЯ ОПТИМАЛЬНОЙ КАЛИБРОВКИ СОРТОПРОКАТНЫХ ВАЛКОВ. СООБЩЕНИЕ 3. ПРОСТРАНСТВО СХЕМ КАЛИБРОВОК","authors":"А. М. Михайленко, Данил Леонидович Шварц","doi":"10.17073/0368-0797-2018-5-364-371","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-5-364-371","url":null,"abstract":"Based on the system approach and on the experience accumulated at theoretical data, design and industrial development of bar rolling, the Chair “Metal Forming” of Ural Federal University develops the universal “Concept of optimum calibration”. The general ideology of roll pass design optimization is stated in article “The concept of optimal bar roll pass design. Report 1. Basic statements”. In the article “The concept of optimal bar roll pass design. Report 2. Calibers space” the structure, appointment and maintenance of the information block reflecting so-called “calibers space” are considered. According to the general concept of optimization, the following task that needs to be solved is the problem of creation of information block so-called “space of schemes of roll pass design” which will be used further as the first space of optimization. The concept “space of schemes of roll pass design of a bar-rolling mill” is considered as the space containing all possible virtual schemes of rolling of a concrete profile on the concrete rolling mill. For formation of the space of schemes of rail calibrations it is necessary to generate separate virtual schemes and to consistently fill this space with them. Thus, the space of calibrations schemes is formed of separate unique calibrations schemes. For formation of this space from separate calibers, it is offered to use the specialized algorithms which are “generators of schemes of roll pass design”. As an example, the structure of the generator prepared for creation of such space for rolling of railway rails is considered. It is revealed that all known rail calibrations can be presented in the form of essentially the same block structure which is used as the central element of the schemes generator of rail calibrations. Usage of described and similar generators in relation to rolling process of a concrete profile on the concrete rolling mill allows obtaining spaces of acceptable schemes of calibrations. Such spaces are necessary for the subsequent optimizing procedures for search of the best calibration scheme from all possible calibrations. The considered approach for creation of calibrations schemes space can be used during creation of computer-aided engineering systems and optimization of calibrations of rolling rolls.","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76755221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
RESEARCH OF THE BEHAVIOR OF MACROSTRUCTURE DEFECTS OF THE PRE-DEFORMED CONTINUOUS CAST BILLETS DURING ROLLING 预变形连铸坯轧制过程中宏观组织缺陷行为的研究
Q3 Materials Science Pub Date : 2018-06-01 DOI: 10.17073/0368-0797-2018-5-399-406
E. Smirnov, V. Sklyar, O. E. Smirnov, V. Belevitin, R. E. Pivovarov
{"title":"RESEARCH OF THE BEHAVIOR OF MACROSTRUCTURE DEFECTS OF THE PRE-DEFORMED CONTINUOUS CAST BILLETS DURING ROLLING","authors":"E. Smirnov, V. Sklyar, O. E. Smirnov, V. Belevitin, R. E. Pivovarov","doi":"10.17073/0368-0797-2018-5-399-406","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-5-399-406","url":null,"abstract":"","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75378809","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
INFLUENCE OF THE METHOD OF NATURAL GAS SUPPLYING ON GAS DYNAMICS AND HEAT TRANSFER IN AIR TUYERE OF BLAST FURNACE 天然气供气方式对高炉风口气体动力学及传热的影响
Q3 Materials Science Pub Date : 2018-06-01 DOI: 10.17073/0368-0797-2018-5-357-363
I. A. Levitskii, A. Radyuk, A. Titlyanov, T. Sidorova
. The use of natural gas reduces the amount of coke to produce pig iron. The flow of hot blast pushes natural gas to the surface of blowing channel in the conventional tuyere. Natural gas is poorly mixed with natural gas. This causes incomplete natural gas combus-363 tion and pyro lysis. Therefore, the problem of the completeness of combustion of natural gas is relevant. One way to improve the mixing of natural gas and hot blast is the gas pipe in the blow channel. However, dynamics and change of the thermal state of the tuyere are understudied for this option. The possibility of ignition of natural gas inside tuyeres must also be taken into account. The authors have in-vestigated the infl uence of the method of natural gas supplying on gas dynamics and heat transfer in air tuyere of a blast furnace with the help of modeling in ANSYS Fluent 15.0.7. Simplifying assumptions were adopted. Only fluid inside the blowing channel is considered as the modeling zone, and the processes of heat transfer to the water of cooling system are considered in the extended boundary conditions. A simplified diagram of the compu tational domain was created in DesignModeler and a computational mesh – in AnsysMeshing. The boundary conditions were set for blowing, natural gas, and also for the border of the fluid with copper walls. The calculations were carried out for half of the tuyere. It is shown that under the given conditions of flow of air and natural gas, combustion inside tuyere with extended to mid-channel gas blowing nozzle does not occur, and natural gas is mixed with the hot air. Improving the mixing of natural gas and hot air, one side, reduces heat flow at the exit of the blowing channel and the average temperature of the gas mixture, on the other side, creates conditions for complete combustion of natural gas outside the tuyere.
。天然气的使用减少了生产生铁所需的焦炭量。热风气流将天然气推向常规风口的吹气通道表面。天然气与天然气的混合很差。这导致天然气不完全燃烧-363和热解。因此,天然气燃烧的完全性问题是相关的。改善天然气与热风混合的一种方法是在吹气通道中加装煤气管。然而,对于这个方案,动力学和风口热态的变化还没有得到充分的研究。还必须考虑到天然气在风口内着火的可能性。利用ANSYS Fluent 15.0.7软件进行建模,研究了天然气供气方式对高炉风口气体动力学和传热的影响。采用简化假设。只考虑吹气通道内的流体作为建模区,在扩展边界条件下考虑冷却系统向水的传热过程。在DesignModeler中创建了计算域的简化图,并在ansys中创建了计算网格。设定了吹气、天然气以及铜壁流体边界的边界条件。对一半的风口进行了计算。结果表明,在给定的空气和天然气流量条件下,扩展到中通道吹气喷嘴的风口内不发生燃烧,天然气与热空气混合。一方面,改善天然气和热空气的混合,减少了吹风通道出口的热流和气体混合物的平均温度,另一方面,为风口外天然气的完全燃烧创造了条件。
{"title":"INFLUENCE OF THE METHOD OF NATURAL GAS SUPPLYING ON GAS DYNAMICS AND HEAT TRANSFER IN AIR TUYERE OF BLAST FURNACE","authors":"I. A. Levitskii, A. Radyuk, A. Titlyanov, T. Sidorova","doi":"10.17073/0368-0797-2018-5-357-363","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-5-357-363","url":null,"abstract":". The use of natural gas reduces the amount of coke to produce pig iron. The flow of hot blast pushes natural gas to the surface of blowing channel in the conventional tuyere. Natural gas is poorly mixed with natural gas. This causes incomplete natural gas combus-363 tion and pyro lysis. Therefore, the problem of the completeness of combustion of natural gas is relevant. One way to improve the mixing of natural gas and hot blast is the gas pipe in the blow channel. However, dynamics and change of the thermal state of the tuyere are understudied for this option. The possibility of ignition of natural gas inside tuyeres must also be taken into account. The authors have in-vestigated the infl uence of the method of natural gas supplying on gas dynamics and heat transfer in air tuyere of a blast furnace with the help of modeling in ANSYS Fluent 15.0.7. Simplifying assumptions were adopted. Only fluid inside the blowing channel is considered as the modeling zone, and the processes of heat transfer to the water of cooling system are considered in the extended boundary conditions. A simplified diagram of the compu tational domain was created in DesignModeler and a computational mesh – in AnsysMeshing. The boundary conditions were set for blowing, natural gas, and also for the border of the fluid with copper walls. The calculations were carried out for half of the tuyere. It is shown that under the given conditions of flow of air and natural gas, combustion inside tuyere with extended to mid-channel gas blowing nozzle does not occur, and natural gas is mixed with the hot air. Improving the mixing of natural gas and hot air, one side, reduces heat flow at the exit of the blowing channel and the average temperature of the gas mixture, on the other side, creates conditions for complete combustion of natural gas outside the tuyere.","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76334252","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
期刊
Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1