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INVESTIGATION OF STRUCTURE AND SEVERAL PROPERTIES OF CARBON STEEL OF GRADE 50 DEFORMED BY DRAWING 50级碳钢拉拔变形后的组织及各项性能研究
Q3 Materials Science Pub Date : 2018-07-28 DOI: 10.17073/0368-0797-2018-7-572-578
M. V. Chukin, М. Polyakova, K. Pivovarova, Yu. Yu. Efi¬mova, A. Gulin
The continuous method of deformational nanostructuring is pre­sented. It consists of simultaneous applying of the tensile deformation by drawing, bending deformation while going via the rolls system and twisting deformation to the continuously moving wire. Combination of different kinds of deformation makes it possible to change in a wide range its mechanical properties matching high strength and ductility. The advantage of this scheme of deformational processing consists in arranging together tools which are used in metal ware manufacturing industrial processes as well as its simplicity and compatibility with rates at coarse and middle drawing processes. The scheme of the labo­ratory unit for the method implementation is considered. Wire from medium carbon steel of grade 50 was chosen as the object for inves­tigation because it is considered to be the needed kind of metal ware product. Chemical composition and mechanical properties of this wire are described. Experiments on investigation of the possibility for ultra­fine-grained structure formation effectiveness in carbon steel wire were conducted using the developed laboratory unit. Deformation modes and drawing route are given. Microstructure of the wire from medium carbon steel of grade 50 was studied after different kinds of deforma­tional processing in longitudinal and transversal cross-sections. Dur­ing experimental researches the effect of deformational processing on carbon steel wire microstructure was specified as well as its anisotropy in the cross section. The mechanical properties of the wire of grade 50 steel were studied after different kinds of deformational processing. The verification of these properties was carried out in accordance with the demands in current national wire standards. It was proved that car­bon steel wire mechanical properties matches well with norms set in GOST17305-91. Investigation results of microstructure and mechani­cal properties of the wire from medium carbon steel of grade 50 after different kinds of deformational processing show the perceptiveness of the chosen direction for combination of different kinds of deformation for ultrafine-grained structure formation in carbon steel wire.
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引用次数: 2
CHALLENGES AND OPPORTUNITIES OF UTILIZATION OF ASH AND SLAG WASTE OF TPP (THERMAL POWER PLANT). PART 1 火电厂灰渣废弃物利用的挑战与机遇。第1部分
Q3 Materials Science Pub Date : 2018-07-28 DOI: 10.17073/0368-0797-2018-6-439-446
G. S. Podgorodetskii, V. Gorbunov, E. А. Agapov, T. V. Erokhov, O. N. Kozlova
 The further development of the Russian coal industry, especially in the regions of Siberia and the Far East, in line with the  Energy Strategy, predetermines the need to address the problem of  utilization of ash and slag wastes in newly implemented projects.  The total amount of ash and slag in the ash dumps in Russia is more  than 1.5  billion tons, and the area occupied by fly ash and slag wastes  (FASW) is more than 220 km2. At the same time, the degree of FASW  use does not exceed 10  %. It is shown that the main solutions for the  recycling of the industrial solid waste generated by thermal power  plants are their use in the production of building materials, road construction, or the complex processing of FASW with the extraction  of metals and the production of building mate rials either. Some fly  ash can be used in agriculture. The physicochemical properties of  fly ash and slag wastes and, accordingly, the directions of their use,  as well as the choice of technology, are determined by the mineral  part of the fossil coals and the way they are burned. To use fly ash in  the construction industry, it is necessary to transfer the ash removal  system to the dry method, accompanied, on the one hand, by a large  volume of capital investments in equipment and facilities for storage,  classification, crushing and grinding, the transfer of new physical and  chemical properties to fly ash and slag waste, and on the other side,  an increase in organizational and transport barriers. Examples of proposed technologies for utilization of ash and slag wastes in the form of metal recovery and production of building materials are given. To  obtain iron-containing concentrates, one-stage magnetic separation  is used, but the quality of the concentrate does not meet modern requirements. The most technologically effective for the extraction of  metals from ash and slag wastes are technologies based on flotation  methods. At the same time, it follows from the provided data that  their application can be limited to economic, organizational factors  and the emergence of new environmental risks. The conclusion is  made on the possibility of using the above technologies for existing  coal-fired power plants only with state support.
根据能源战略进一步发展俄罗斯的煤炭工业,特别是在西伯利亚和远东地区的煤炭工业,预先决定了必须在新执行的项目中解决利用灰烬和炉渣废物的问题。俄罗斯各灰场的灰渣总量超过15亿吨,飞灰渣废弃物(FASW)占地面积超过220平方公里。同时,FASW的使用程度不超过10%。研究表明,火电厂产生的工业固体废物的回收利用的主要解决方案是将其用于生产建筑材料和道路建设,或将FASW与金属提取和建筑材料生产结合起来进行综合处理。有些粉煤灰可用于农业。粉煤灰和矿渣废物的物理化学性质,以及它们的使用方向和技术的选择,是由化石煤的矿物成分和燃烧方式决定的。要在建筑行业中使用粉煤灰,必须将除灰系统转移到干法,同时,一方面需要大量的资金投入用于存储、分类、破碎和研磨的设备设施,将新的物理和化学性质转移到粉煤灰和矿渣废物中,另一方面,组织和运输障碍的增加。提出了以金属回收和生产建筑材料的形式利用灰烬和炉渣废物的拟议技术的例子。采用一段磁选法获得含铁精矿,但精矿质量不符合现代要求。从灰渣废物中提取金属的最有效技术是基于浮选方法的技术。同时,从所提供的数据可以看出,它们的应用可能仅限于经济、组织因素和新环境风险的出现。结论是,只有在国家支持下,现有燃煤电厂才有可能采用上述技术。
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引用次数: 3
THERMODYNAMICS OF OXYGEN SOLUTIONS IN ALUMINUM-CONTAINING Ni – Cr MELTS 含铝镍铬熔体中氧溶液的热力学
Q3 Materials Science Pub Date : 2018-07-28 DOI: 10.17073/0368-0797-2018-6-490-493
V. Dashevskii, A. Alexandrov
Thermodynamic analysis of the effect of aluminum on the solubility of oxygen in Ni – Cr melts has been carried out. Aluminum at  very low levels practically does not affect the concentration of oxygen  in the melt, which is determined by the chromium content. When the  aluminum content is above ~0.01  % for all alloys, it already determines the solubility of oxygen in the melt. The minimum values of  the oxygen concentration are achieved with an aluminum content of  ~0.2  %. With the increase of chromium content in the melt, the minimum oxygen concentration increases. For Ni – 10 % Cr, Ni – 20 %  Cr and Ni – 30 % Cr alloys, it is 2·10–3, 7·10–3 and 10–2, respectively.
本文对铝对镍铬熔体中氧溶解度的影响进行了热力学分析。极低水平的铝实际上并不影响熔体中氧的浓度,这是由铬含量决定的。当所有合金的铝含量高于~ 0.01%时,它已经决定了氧在熔体中的溶解度。当铝含量为~ 0.2%时,氧浓度达到最小值,随着熔体中铬含量的增加,氧浓度也随之增加。Ni - 10%铬、镍铬合金- 20%铬和镍- 30%,它是2·三分,分别为7·三分和10 - 2。
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引用次数: 0
THERMODYNAMICS OF THE PROCESSES OF INTERACTION OF LIQUID METAL COMPONENTS IN Fe – Mg – Al – La – O SYSTEM Fe - Mg - Al - La - O体系中液态金属组分相互作用过程的热力学
Q3 Materials Science Pub Date : 2018-07-28 DOI: 10.17073/0368-0797-2018-6-460-465
G. G. Mikhailov, L. Makrovets, L. Smirnov
At the present time, rare-earth elements in metallurgy are used in  the form of mischmetal – a rare-earth elements natural mixture (with  atomic numbers from 57 to 71). It contains about 50  wt.  % of cerium.  The remaining elements are mainly lanthanum and niobium. The specific composition is determined by the ore deposit. Inconstant composition of the modifier containing rare-earth metals (REM) can significantly reduce its efficiency. Experimentally, for every branded steels  composition the ratio of various REMs can’t be selected because of the  high costs of obtaining technically pure rare-earth metals. The task of  determining the each rare earth element optimum concentrations and  complex ligature composition can be solved by thermodynamic modeling. In the framework of thermodynamic modeling, the interaction  between magnesium, aluminum and lanthanum with oxygen in liquid  iron is presented. And the thermodynamic model of steel deoxidation  by these active metals composition is considered. On the basis of available literature data on the phase diagrams of the systems MgO – Al2O3 ,  MgO – La2O3 and La2O3 – Al2O3 , the coordinates of the invariant equilibria points in the system MgO – La2O3 – Al2O3 were determined. The  phase diagram of the system MgO – La2O3 – Al2O3 was constructed. It  made possible to establish all phase equilibria realized in the process  of deoxidation of steel with magnesium, lanthanum and aluminum and  to describe these phase equilibria by chemical reactions equations. The  activity of the components in liquid oxide melts was determined using  the theory of subregular ionic solutions, which takes into account the  dependence of the coordination number of cations on the composition  of the oxide melt. The activity of components in metal melts conjugated with oxide systems were determined by Wagner’s theory using the  parameters of the first order interaction. Equilibrium constants values  for the steel deoxidation reactions are installed indirectly by thermodynamic calculations. On the basis of the obtained data the components  solubility surface in the metal melts of Fe – Mg – Al – La – O system  was constructed, which allowed to determine the liquid metal composition regions associated with the corresponding oxide phase.
目前,稀土元素在冶金中以混合稀土的形式使用,混合稀土是一种稀土元素的天然混合物(原子序数从57到71),它含有约50%的铈。剩余元素以镧和铌为主,具体组成由矿床决定,含稀土金属(REM)的改性剂组成不稳定会显著降低其效率。在实验上,由于获得纯稀土金属的技术成本高,因此无法选择每种牌号钢成分的各种稀土元素的比例。确定各种稀土元素的最佳浓度和复杂的结合力组成的任务可以通过热力学建模来解决。在热力学模型的框架下,给出了铁液中镁、铝和镧与氧的相互作用。并考虑了这些活性金属成分对钢进行脱氧的热力学模型。根据MgO - Al2O3、MgO - La2O3和La2O3 - Al2O3体系相图的文献资料,确定了MgO - La2O3 - Al2O3体系中不变量平衡点的坐标。构造了MgO - La2O3 - Al2O3体系的相图。建立了用镁、镧、铝对钢进行脱氧过程中所有的相平衡,并用化学反应方程来描述这些相平衡。采用亚规则离子溶液理论确定了液态氧化物熔体中各组分的活性,该理论考虑了阳离子配位数对氧化物熔体组成的依赖性。采用瓦格纳理论,利用一阶相互作用参数确定了金属熔体中与氧化物体系共轭的组分的活度。钢脱氧反应的平衡常数值是通过热力学计算间接确定的。在此基础上,构建了Fe - Mg - Al - La - O体系中各组分在金属熔体中的溶解度面,从而确定了相应氧化相对应的液态金属组成区域。
{"title":"THERMODYNAMICS OF THE PROCESSES OF INTERACTION OF LIQUID METAL COMPONENTS IN Fe – Mg – Al – La – O SYSTEM","authors":"G. G. Mikhailov, L. Makrovets, L. Smirnov","doi":"10.17073/0368-0797-2018-6-460-465","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-6-460-465","url":null,"abstract":"At the present time, rare-earth elements in metallurgy are used in  the form of mischmetal – a rare-earth elements natural mixture (with  atomic numbers from 57 to 71). It contains about 50  wt.  % of cerium.  The remaining elements are mainly lanthanum and niobium. The specific composition is determined by the ore deposit. Inconstant composition of the modifier containing rare-earth metals (REM) can significantly reduce its efficiency. Experimentally, for every branded steels  composition the ratio of various REMs can’t be selected because of the  high costs of obtaining technically pure rare-earth metals. The task of  determining the each rare earth element optimum concentrations and  complex ligature composition can be solved by thermodynamic modeling. In the framework of thermodynamic modeling, the interaction  between magnesium, aluminum and lanthanum with oxygen in liquid  iron is presented. And the thermodynamic model of steel deoxidation  by these active metals composition is considered. On the basis of available literature data on the phase diagrams of the systems MgO – Al2O3 ,  MgO – La2O3 and La2O3 – Al2O3 , the coordinates of the invariant equilibria points in the system MgO – La2O3 – Al2O3 were determined. The  phase diagram of the system MgO – La2O3 – Al2O3 was constructed. It  made possible to establish all phase equilibria realized in the process  of deoxidation of steel with magnesium, lanthanum and aluminum and  to describe these phase equilibria by chemical reactions equations. The  activity of the components in liquid oxide melts was determined using  the theory of subregular ionic solutions, which takes into account the  dependence of the coordination number of cations on the composition  of the oxide melt. The activity of components in metal melts conjugated with oxide systems were determined by Wagner’s theory using the  parameters of the first order interaction. Equilibrium constants values  for the steel deoxidation reactions are installed indirectly by thermodynamic calculations. On the basis of the obtained data the components  solubility surface in the metal melts of Fe – Mg – Al – La – O system  was constructed, which allowed to determine the liquid metal composition regions associated with the corresponding oxide phase.","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80738713","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
ASSESSMENT OF THE EFFICIENCY OF USING BLIND FEEDERS OF VARIOUS GEOMETRY BASED ON MATHEMATICAL SIMULATION RESULTS 基于数学仿真结果的不同几何形状盲馈线的效率评价
Q3 Materials Science Pub Date : 2018-07-28 DOI: 10.17073/0368-0797-2018-7-543-550
A. Fedosov, G. Chumachenko, M. А. Khodarev, V. V. Golomeev
A short analysis of existing methods for reducing the feeders’ volume is carried out. Their advantages and disadvantages are singled out. The area of application of optimization methods of the feeders’ form is substantiated with the purpose of increasing the casting yield. The actual location of shrinkage defects in variously designed feeders is considered. The patterns of location and shape of shrinkage cavity are shown depending on the shape of the feeder upper section. This allowed to distinguish four groups of feeders and noted the differences in the effectiveness of their work. To clarify the mechanism of shrinkage defects formation in feeders with a different form of the upper section and to estimate the effectiveness of their work, it is proposed to use methods of mathematical modeling. The appropriateness of using mathematical modeling methods is emphasized, by means of the pos­sibility of idealizing external influencing factors on thermal processes in the form that is difficult to achieve in real conditions of foundry pro­duction. The SOLIDCast application is used as the modeling means. The initial and boundary conditions for mathematical modeling were identical for all types of feeders. The results of the shrinkage cavities prediction are presented as isosurfaces diagrams, the sizes were used for estimation of the feeders work efficiency. The method of estima­tion of variously designed feeders’ effectiveness is proposed on the basis of mathematical modeling results. Characteristics of shrinkage defects location in feeders’ volume are proposed to use for estima­tion of feeder’s effectiveness. Its calculation for the feeders of equal size but having differently designed top part is shown. The introduced efficiency index has a good adjustment with geometric module (ratio between volume and surface of feeder). Increasing feeder’s geometric module increases its thermal efficiency. It is shown that the use of a notch allows to increase feeder’s efficiency. The explanation of mecha­nism of notch thermal behavior and its influence on shrinkage defects location is offered on the basis of analysis of isothermal lines in feed­ers’ cross section. Recommendations towards maximization of casting yield are substantiated due to the change in feeder top part design. The opportunity of increasing of casting yield up to 4% and reducing casting defects by optimization feeder’s upper section shape is shown.
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引用次数: 0
СОВЕРШЕНСТВОВАНИЕ ВИБРАЦИОННЫХ ПИТАТЕЛЕЙ-ГРОХОТОВ ДЛЯ ГОРНО-МЕТАЛЛУРГИЧЕСКОЙ ПРОМЫШЛЕННОСТИ 改善高山冶金工业的振动鼓风机
Q3 Materials Science Pub Date : 2018-07-28 DOI: 10.17073/0368-0797-2018-6-470-477
Василий Иванович Ляшенко, В. З. Дятчин, Всеволод Петрович Франчук
The main scientific and practical results of the improvement of  vibrating feeders-screens for mining and metallurgical industry are  presented on the basis of dynamic calculation of the vibrating feederscreen with two differently directed self-balancing vibrators. Methods  of theoretical generalizations are described using mathematical statistics, physical and mathematical modeling, computation and feasibility studies, laboratory and full-scale experimental studies, industrial  tests in the conditions of operating enterprises using standard and new  methods. Mathematical modeling and calculation of the parameters of  a vibrating feeder of the PVG type are proposed. It is recommended  when choosing dynamic parameters of the feeder, to use the vibration  transmission coefficient, which is taken within the limits (1.5  –  3.5)g,   and in heavy loading modes, is up to 5g. It is shown that during preparation of breeze coke in the crushing body, from 10 to 50  % of fine  material is received from its bunker with a particle size of 0  –  3  mm,  which is additionally re-milled, reducing the quality of coke. A vibrating feeder-screen with a spatial oscillation of the working element will  increase the efficiency of screening of the material by 15  –  20  % and  will improve the self-cleaning of the screen. The driving forces of the  exciters are directed at different angles of 15 and 45° to the screening surfaceand are attached from each other at a distance equal to half  width of the box, i.e. 600  mm. It is established that in the resonance  mode at a constant amplitude with increasing frequency the coefficient  of the vibro-displacement regime increases according to a quadratic  dependence, at a working frequency of 100 rad/s it also increases from  the loading edge of the feeder to the unloading and from one side to  another, the value of which varies within 2.62  –  2.84.
通过对采用两种不同方向自平衡振动器的给料振动筛进行动态计算,给出了对矿用冶金工业给料振动筛进行改进的主要科学和实用结果。运用数理统计、物理和数学建模、计算和可行性研究、实验室和全尺寸实验研究、采用标准方法和新方法在经营企业条件下进行工业试验来描述理论推广的方法。提出了PVG型振动给料机的数学建模和参数计算方法。在选择给料器的动态参数时,建议使用振动传递系数,该系数在(1.5 - 3.5)g范围内,在重载模式下,最高可达5g。研究表明,在破碎体制备风焦过程中,10 ~ 50%的细粒物料从其料仓中接收,粒度为0 ~ 3mm,这些细粒物料被再磨,降低了焦炭的质量。具有工作元件空间振荡的振动给料筛,可使物料的筛分效率提高15 - 20%,并可提高筛的自洁性。激振器的驱动力分别以15°和45°的不同角度指向筛面,并以等于箱体半宽度的距离(即600mm)相互连接。结果表明,在恒幅谐振模式下,随着频率的增加,振动-位移区系数呈二次相关关系增大,在100 rad/s工作频率下,从给料机的加载边缘到卸料边缘,从一侧到另一侧,其值在2.62 ~ 2.84之间变化。
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引用次数: 1
OXYGEN SOLUBILITY IN VANADIUM-CONTAINING Fe – Co – Cr MELTS 在含钒铁-钴-铬熔体中的氧溶解度
Q3 Materials Science Pub Date : 2018-07-28 DOI: 10.17073/0368-0797-2018-7-579-583
A. Aleksandrov, V. Dashevskii
Thermodynamic analysis of the effect of vanadium on the solu­bility of oxygen in Fe – Co – Cr melts has been carried out. Vanadium in Fe – Co – Cr melts at low contents increases oxygen concentration, which is determined by the chromium content. With a higher content of vanadium after changing the mechanism of the interaction process of chromium and vanadium with oxygen, when vanadium already de­termines the solubility of oxygen in the melt, the oxygen concentration initially decreases, and then, after passing through the minimum point, increases.
{"title":"OXYGEN SOLUBILITY IN VANADIUM-CONTAINING Fe – Co – Cr MELTS","authors":"A. Aleksandrov, V. Dashevskii","doi":"10.17073/0368-0797-2018-7-579-583","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-7-579-583","url":null,"abstract":"Thermodynamic analysis of the effect of vanadium on the solu­bility of oxygen in Fe – Co – Cr melts has been carried out. Vanadium in Fe – Co – Cr melts at low contents increases oxygen concentration, which is determined by the chromium content. With a higher content of vanadium after changing the mechanism of the interaction process of chromium and vanadium with oxygen, when vanadium already de­termines the solubility of oxygen in the melt, the oxygen concentration initially decreases, and then, after passing through the minimum point, increases.","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80278885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
FRACTURE RESISTANCE OF “TRANSITION” AREA IN THREE-LAYER STEEL/VANADIUM ALLOY/STEEL COMPOSITE AFTER THERMOMECHANICAL TREATMENT 三层钢/钒合金/钢复合材料热处理后“过渡”区的抗断裂性能
Q3 Materials Science Pub Date : 2018-07-28 DOI: 10.17073/0368-0797-2018-6-447-453
T. A. Nechaikina, S. Nikulin, S. Rogachev, V. Turilina, A. Baranova
The creation of new structural materials for cladding tubes  of fast neutron reactors is an urgent task of modern nuclear power  engineering. A three-layer radiation-resistant and corrosion-resistant material based on vanadium alloy and stainless steel, intended  for work under extreme conditions (high temperatures, radiation  and aggressive environment) of operation of fast neutron reactor  cladding tubes has been developed in recent years. The most important aspect determining the operability of this material during  operation is the quality of the joining of different materials layers  among themselves, determined by the modes of thermomechanical treatment. The effect of the annealing on the chemical composition, structure, and fracture resistance of the “steel/vanadium  alloy” interface in the steel/vanadium alloy/steel three-layer tube,  obtained by hot co-extrusion of three-layer tube billet at 1100  °C  was studied. The 20Kh13 (AISI 420 type) steel for the outer layers and V – 4Ti – 4Cr vanadium alloy for the core were used as the  components of the tube. The structure and chemical composition  in the layer joining zone were studied using the optical microscopy and electron microscopy with X-ray microspectral analysis.  The fracture resistance of the “steel/vanadium alloy” interface was  evaluated by a compression test of a three-layer ring sample with  notch using an acoustic emission (AE) measurement. It is shown  that after co-extrusion a “transition” area of diffusion interaction  having a variable chemical composition with a width of 10–15 μm  is formed between vanadium alloy and steel, which represents the  continuous series of solid solutions, without precipitation of brittle  phases, providing a strong bonding between vanadium alloy and  steel in the three-layer material. No voids, delaminations or defects were detected at the “steel/vanadium alloy” interface. However, a  crack is formed in the steel layer during the compression tests of  the notched semi-ring three-layer samples after hot co-extrusion.  Annealing favorably influences the formation of the “transition”  area due to the increase in the width of the diffusion interaction  area. No cracks or delaminations at the boundary between steel and  vanadium layers were observed in the three-layer tube samples after annealing, and the three-layer material behaves like a monolith  material during testing.
研制新型快中子堆包壳管结构材料是现代核电工程的一项紧迫任务。近年来研制出了一种以钒合金和不锈钢为基础的三层抗辐射耐腐蚀材料,用于快中子堆包壳管在极端条件下(高温、辐射和侵蚀环境)的运行。在操作过程中,决定这种材料的可操作性的最重要的方面是不同材料层之间的连接质量,这取决于热机械处理的方式。以20Kh13 (AISI 420型)钢为外层材料,V - 4Ti - 4Cr钒合金为芯材,在1100℃高温共挤压三层管坯,研究了退火对钢/钒合金/钢三层管中“钢/钒合金”界面化学成分、组织和抗断裂性能的影响。利用光学显微镜和电子显微镜结合x射线显微光谱分析研究了层连接区的结构和化学成分。采用声发射(AE)测量方法对带缺口的三层环形试样进行压缩试验,评价了“钢/钒合金”界面的抗断裂性能。结果表明:共挤压后,钒合金与钢之间形成了一个宽度为10 ~ 15 μm、化学成分变化较大的扩散相互作用过渡区,为连续系列固溶体,未析出脆性相,使三层材料中钒合金与钢结合牢固,在“钢/钒合金”界面处未发现空洞、分层和缺陷。然而,缺口半环形三层试样在热共挤压后的压缩试验中,钢层出现裂纹。由于扩散相互作用区域宽度的增加,退火有利于“过渡”区域的形成。退火后的三层管样在钢和钒层交界处未观察到裂纹和分层现象,在测试过程中三层材料表现为整体材料。
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引用次数: 1
MATHEMATICAL MODELING OF OPERATION OF THE PALLET CARS’ GRATE BARS MADE OF STEEL 40Kh24N12SL 40Kh24N12SL钢托盘车篦栅运行的数学建模
Q3 Materials Science Pub Date : 2018-07-28 DOI: 10.17073/0368-0797-2018-7-536-542
D. Ivanov, A. A. Kozhukhov, V. А. Sklyar
To determine the reasons that decrease life of the grate bars of pellet cars from steel 40Kh24N12SL during the operation, a compara­tive analysis of the results of macro-investigations of the grate bars af­ter operation with the results of modeling the operating conditions for the grate was performed. The modeling of the operating conditions was carried out using the finite element method, which allowed achieving high reliability of the obtained results. For the reliability of the model­ing results, the maximum possible number of boundary modeling con­ditions was obtained, obtained from both macro-examples conducted earlier and from the scientific literature. The application of the finite element method made it possible to determine that a high temperature gradient with local overheating zones is formed along the section of the component. It is shown that the nature of overheating is predictable and is related to the conditions of the coolant supply to the working area during operation of the part. It is established that zones with large values of internal stresses and deformations are locally formed during operation. The regularity of appearance of these zones is shown, which highly dependents on the presence of inhomogeneities in the structure of the part, and is also supposedly related to geometric complexity of the casting. It is also established that in the presence of shrinkage shells, all values of stresses and deformations increase sharply, espe­cially in local maximums. In this case, the distribution of local zones with high stresses and deformations in the presence of shrinkage shells remains practically unchanged. An analysis of the location of zones with high stresses and strains made it possible to explain the existing principle of the destruction of the grate by cracking during operation. It is proved that one of the main causes of buckling, cracking and fracture of the grates of the pellet cars made of steel 40Kh24N12SL is the pres­ence of shrinkage shells in the metal structure. As a result of modeling the operating conditions, mechanism of the occurrence of buckling, cracking and fracture of the grates of steel 40Kh24N12SL during op­eration is described, which completely coincides with the results of macro-investigations and observations obtained during operation.
为确定40Kh24N12SL钢颗粒车篦条在运行过程中寿命下降的原因,对运行后篦条的宏观调查结果与篦条运行工况建模结果进行了对比分析。采用有限元方法对工况进行建模,使所得结果具有较高的可靠性。为了保证建模结果的可靠性,从前面进行的宏观算例和科学文献中获得了边界建模条件的最大可能数。有限元方法的应用使得确定沿构件截面形成具有局部过热区的高温梯度成为可能。结果表明,过热的性质是可预测的,并且与零件运行时工作区域的冷却剂供应条件有关。结果表明,在运行过程中局部形成了较大的内应力和变形区。这些区域外观的规律性被显示出来,这高度依赖于零件结构中不均匀性的存在,并且也被认为与铸造的几何复杂性有关。还确定,在存在收缩壳的情况下,应力和变形的所有值都急剧增加,特别是在局部最大值处。在这种情况下,在存在收缩壳的情况下,具有高应力和变形的局部区域的分布几乎保持不变。对高应力应变区位置的分析,可以解释炉篦在运行过程中开裂破坏的现有原理。结果表明,40Kh24N12SL钢颗粒车格栅屈曲、开裂、断裂的主要原因之一是金属结构中存在缩孔壳。通过对运行工况的模拟,描述了40Kh24N12SL钢格栅在运行过程中发生屈曲、开裂和断裂的机理,与运行过程中的宏观调查和观察结果完全吻合。
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引用次数: 0
ПЕРЕРАСПРЕДЕЛЕНИЕ АТОМОВ УГЛЕРОДА В ДИФФЕРЕНЦИРОВАННО ЗАКАЛЕННЫХ РЕЛЬСАХ ПРИ ДЛИТЕЛЬНОЙ ЭКСПЛУАТАЦИИ 长期运行时,将碳原子重新分配为微淬火轨道
Q3 Materials Science Pub Date : 2018-07-27 DOI: 10.17073/0368-0797-2018-6-454-459
Виктор Евгеньевич Громов, А. А. Юрьев, Ю.Ф. Иванов, В. А. Гришунин, С.В. Коновалов
Using  transmission  electron  microscopy  methods  at  various  distances from the rolling surface along the central axis, changes in  structure, phase composition, and defective substructure of the head  of differentially hardened rails were studied after passed tonnage of  691.8  million tons of gross weight. It is confirmed that prolonged  operation of rails is accompanied by two simultaneous processes of  transformation of structure and phase composition of plate-pearlite  colonies: cutting of cementite plates and dissolution of cementite  plates. The first process is carried out by mechanism of cutting carbide  particles and removing their fragments, accompanied only by change  in their linear dimensions and morphology. The second process of  dest ruction of the cementite plates of perlite colonies is carried out by  leaving carbon atoms from crystalline lattice of cementite on dislocation, as a result of which phase transformation of rails metal is possible. This is due to a noticeable relaxation of mean energy of carbon  atom  s binding to dislocations (0.6  eV) and to iron atoms in cementite  lattice (0.4  eV). The stages of transformation of cementite plates are  considered: enveloping the plates with sliding dislocations and then  splitting them into weakly oriented fragments; penetration of sliding  dislocations from ferrite lattice into lattice of cementite; dissolution of  cementite and formation of nanoscale particles. The presence of nanosized cementite particles in ferrite matrix is noted due to their removal  during dislocation slide. Using expressions of modern physical materials science and X-ray diffraction analysis, influence of content of  carbon atoms on structural elements of rail steel was estimated. It is  shown that prolonged operation of rails is accompanied by a significant  redistribution of carbon atoms in surface layer. In the initial state, the  main quantity of carbon atoms is concentrated in cementite particles,  and after a long operation of rails, along with cementite particles, carbon is located in defects of crystal structure of steel (dislocation, grain  boundaries and subgrains), and in the surface layer of steel atoms carbon is also found in crystal lattice based on α-iron.
采用透射电镜方法,在距轧制面不同距离沿中轴线,研究了差硬钢轨总重通过吨位后,其头部组织、相组成及缺陷亚结构的变化。结果表明,钢轨的长时间运行伴随着渗碳体的切割和渗碳体的溶蚀两个同时发生的板-珠光体菌落组织和相组成的变化过程。第一个过程是通过切削硬质合金颗粒并去除其碎片的机制进行的,仅伴随其线性尺寸和形态的变化。第二种破坏渗碳体板的方法是将渗碳体晶格中的碳原子留在位错上,从而使轨道金属的相变成为可能。这是由于碳原子与位错(0.6 eV)和渗碳体晶格中铁原子(0.4 eV)结合的平均能明显弛豫所致。考虑了渗碳体板的相变阶段:被滑移位错包裹并分裂成弱取向碎片;滑移位错从铁素体晶格渗透到渗碳体晶格中;渗碳体溶解并形成纳米级颗粒。铁素体基体中存在纳米渗碳体颗粒,由于它们在位错滑动过程中被去除。利用现代物理材料学的表达式和x射线衍射分析,估计了碳原子含量对钢轨钢结构元素的影响。结果表明,钢轨的长时间运行伴随着表层碳原子的重分布。在初始状态下,碳原子的主要数量集中在渗碳体颗粒中,在钢轨长期运行后,碳与渗碳体颗粒一起分布在钢的晶体结构缺陷(位错、晶界和亚晶)中,在钢原子的表层,碳也存在于以α-铁为基的晶格中。
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引用次数: 1
期刊
Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya
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