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Manufacturing technologies of steel seamless tubes for production of hard-to-recover hydrocarbons 难回收烃类生产用无缝钢管制造技术
Q3 Materials Science Pub Date : 2018-12-24 DOI: 10.17073/0368-0797-2018-11-866-875
A. Shiryaev, S. Chetverikov, S. G. Chikalov, I. Pyshmintsev, P. V. Krylov
The review contains main directions in the development of modern steelmaking, hot rolling technologies and heat treatment aimed to follow increased requirements to seamless tubes for production of oil and gas under severe conditions. New targets of PJSC “Gazprom” in development of new resources have determined new technical requirements to pipes for low temperature application, resistant to hydrogen sulfide and carbon dioxide corrosion. Basic metal science approaches are given to develop new chemical compositions of high quality steels containing minimum of sulfur, phosphorous and solute gases. Corresponding heat treatment routes are determined for formation of martensitic microstructure in full wall section during quenching with subsequent high tempering for required combination of high strength and ductility. It was shown that optimal combination of high strength and toughness at 60 °C below zero can be achieved by alloying of chromium-molybdenum steel containing about 0.25 wt. % of carbon with strong carbon forming elements such as vanadium and niobium. Sustainability of these steels to stress sulfide cracking was achieved through grain refinement with microalloying by molybdenum in concentrations corresponding to strength grades that gives high hardenability and retards tempering of martensite. New compositions of corrosion resistant martensitic 13 % chromium steel were carried out that was resulted in required resistance to carbon dioxide environments with improved low temperature toughness and high strength. The authors present results of reconstruction of steel making and hot rolling production lines at JSC “Volzhskii Pipe Plant” providing the required quality of new products from continuously cast steel billets to finished tubes.
该综述包含了现代炼钢、热轧技术和热处理发展的主要方向,旨在满足在恶劣条件下生产石油和天然气所需的无缝管的日益增长的要求。PJSC“Gazprom”在开发新资源方面的新目标确定了对低温应用管道的新技术要求,耐硫化氢和二氧化碳腐蚀。基础金属科学的方法,以开发新的化学成分的优质钢含有最少的硫,磷和溶质气体。确定了相应的热处理路线,以便在淬火过程中形成全壁截面的马氏体组织,然后进行高回火,以获得所需的高强度和高延展性的结合。结果表明,含碳量约为0.25 wt. %的铬钼钢与钒、铌等强成碳元素合金化可以在零下60℃时获得高强度和高韧性的最佳组合。这些钢对应力硫化物开裂的可持续性是通过与强度等级相对应的浓度的钼微合金化晶粒来实现的,从而获得高淬透性和延缓马氏体回火。研究了耐腐蚀马氏体13%铬钢的新成分,提高了低温韧性和高强度,达到了所需的耐二氧化碳环境性能。作者介绍了JSC“Volzhskii管材厂”的炼钢和热轧生产线的改造结果,提供了从连铸钢坯到成品管的新产品的要求质量。
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引用次数: 0
Исследование комплексного влияния параметров выплавки рельсовой электростали на качество рельсовой продукции и технико-экономические показатели ее производства 研究钢轨电镀对钢轨产品质量和生产技术经济指标的综合影响
Q3 Materials Science Pub Date : 2018-12-24 DOI: 10.17073/0368-0797-2018-11-876-883
А. А. Уманский, Л. В. Думова
Analysis of literature and production data has shown that despite the significant improvement in quality of domestic rail products, achieved in the last decade due to fundamental technical re-equipment of rail production, there is a problem of increased rejection of rails for surface defects. Based on studies of influence of rail steel chemical composition on quality of rails produced by «EVRAZ ZSMK», there was established a significant effect of increasing copper content in the range of 0.07 - 0.15 % and of sulfur - in the range of 0.006 - 0.011 % in E76KhF steel to increase rejection caused by rail surface defects. Mechanism of the influence of these elements concentration in rail steel on finished rails quality was revealed. Decisive influence of ratio of pig iron and scrap in metal charge on copper and sulfur content in rail steel was evidenced - higher rate of cast iron in metal charge within 20 - 50 % contributes to decrease of copper concentration and increase of sulfur content. To justify optimal composition of the charge for rail steel melting in regard to rail products quality and technical and economic indicators of production, study of the effect of cast iron (liquid and solid) to scrap ratio in metal charge on basic parameters of furnaces’ operation was conducted. As a result, it was found that with an increase in share of both liquid and solid iron in metal charge, there are linear decrease in specific electricity consumption, increase in specific oxygen consumption according to parabolic law and a linear decrease in manganese content in furnace output. The obtained dependences of melting duration on ratio of charge components in metal charge indicates presence of prominent minimum, when using liquid iron in the range of 35 - 40 %, and when using solid iron - in the range of 30 - 35 %. Based on the regression equations, statistical model was constructed for the influence of metal charge composition on technical and economic performance of the melt charge in rail steel smelting, in which optimization parameters are: total cost, depending on the metal stock composition and performance of the shop for suitable billets produced by continuous casting. Application of the obtained model allows to develop reasonable recommendations on the optimal proportion of iron in the metal for current level of prices for materials and energy used in electric smelting, taking into account changes in the shop productivity.
对文献和生产数据的分析表明,尽管在过去十年中,由于钢轨生产的基本技术装备的重新装备,国内钢轨产品的质量有了显着提高,但由于表面缺陷而导致的钢轨退货率上升的问题仍然存在。通过研究钢轨钢化学成分对«EVRAZ ZSMK»生产的钢轨质量的影响,确定了在E76KhF钢中增加0.07 - 0.15%范围内的铜含量和0.006 - 0.011%范围内的硫含量对增加钢轨表面缺陷引起的废品率有显著影响。揭示了钢轨钢中这些元素含量对成品钢轨质量影响的机理。金属料中生铁与废铁的比例对钢轨钢中铜、硫含量有决定性影响,金属料中铸铁的比例在20 ~ 50%之间,有利于降低铜浓度,提高硫含量。为了从钢轨产品质量和生产技术经济指标出发,确定钢轨炼钢炉料的最佳配比,研究了金属炉料中铸铁(液、固)废比对炉体运行基本参数的影响。结果发现,随着金属炉料中液态铁和固态铁比重的增加,比电耗呈抛物线规律线性下降,比耗氧量呈抛物线规律上升,炉产量锰含量呈线性下降。所得到的熔化持续时间与金属炉料中电荷组分比率的关系表明,当使用液态铁时,在35 - 40%的范围内,当使用固体铁时,在30 - 35%的范围内,存在显著的最小值。在回归方程的基础上,建立了钢轨钢冶炼中金属料成分对钢轨钢熔体技术经济性能影响的统计模型,其中优化参数为:总成本,取决于金属料成分和车间的性能,以获得合适的连铸钢坯。应用所获得的模型,考虑到车间生产率的变化,可以根据当前冶炼所用材料和能源的价格水平,对金属中铁的最佳比例提出合理建议。
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引用次数: 0
Изменение фазового состава сидеритов Бакальского месторождения при нагреве 加热时巴库油田相成分变化
Q3 Materials Science Pub Date : 2018-12-24 DOI: 10.17073/0368-0797-2018-11-891-897
O. Y. Sheshukov, M. A. Mikheenkov, E. A. Vyaznikova, A. S. Bykov, L. B. Vedmid
The article presents the results of a study of formation mechanism of magnesia-ferrite when heated siderites of the Bakal deposit with different iron oxide content in an inert and oxidizing atmosphere. It was established that in the case of firing in an inert atmosphere, the decomposition of siderite with high iron content begins at a lower temperature and the enthalpy of such decomposition is less. This effect can be explained by the different phase composition of the samples. The main phases formed under conditions of oxidative firing are hematite and magnesia-ferrite. The amount of hematite and magnesia-ferrite produced in the samples with different iron oxide content during firing in an oxidizing atmosphere is different. Siderite with high content of iron oxides contains more hematite in the firing products than magnesia-ferrite, and siderite with a low content of iron oxides contains more magnesia-ferrite in the firing products than hematite. Formed under conditions of oxidative firing magnesia-ferrites are solid solutions and differ in the degree of substitution of iron and magnesium ions. In siderites with high content of iron oxides, the degree of substitution of magnesium ions with iron ions is greater than in samples with a low content of iron oxides. Since the siderites of the Bakal deposit are poor ore formations, the considerable amount of magnesia-ferrite formed in them during firing makes it difficult to separate silicate and iron-oxide firing products by traditional enrichment methods. Wustite in the products of oxidative firing is not detected, because under these conditions it is in a metastable state and in the presence of a weakly oxidizing atmosphere is converted into magnetite. The scientific novelty is the explanation of the mechanism of siderite decomposition and the description of products of such decomposition. Understanding of the mechanism of decomposition of siderite from the Bakal deposit made it possible to develop the technology of reductive firing of siderite to facilitate separation of its products, and which consists in the regulation of the phase composition of silicate products of reductive firing, ensuring the collapse of magnesia-ferrite and output of iron oxide in a separate phase. The developed technology can be used to provide high-quality enrichment of siderite from the Bakal deposit.
本文介绍了在惰性氧化气氛中对不同氧化铁含量的Bakal矿床的菱铁矿进行加热,研究了镁铁氧体的形成机理。结果表明,在惰性气氛中烧制时,高铁含量菱铁矿的分解温度较低,分解焓较小。这种影响可以用样品相组成的不同来解释。氧化烧成条件下形成的主要相为赤铁矿和镁铁氧体。不同氧化铁含量的试样在氧化气氛下烧制时产生的赤铁矿和镁铁氧体的量不同。氧化铁含量高的菱铁矿烧成产物中含有较多的赤铁矿,氧化铁含量低的菱铁矿烧成产物中含有较多的镁铁氧体。氧化镁铁氧体是在氧化烧制条件下形成的固溶体,铁和镁离子的取代程度不同。氧化铁含量高的菱铁矿中,镁离子被铁离子取代的程度大于氧化铁含量低的菱铁矿。由于Bakal矿床的菱铁矿为贫矿,在焙烧过程中形成了大量的镁铁氧体,使得传统的富集方法难以分离硅酸盐和氧化铁的焙烧产物。氧化烧成产物中的浮士体是检测不到的,因为在这些条件下,它处于亚稳态,在弱氧化气氛的存在下转化为磁铁矿。科学的新颖性在于对菱铁矿分解机理的解释和对分解产物的描述。对Bakal矿床菱铁矿分解机理的认识,为开发有利于其产物分离的还原焙烧菱铁矿技术提供了可能,其关键在于调控还原焙烧硅酸盐产物的相组成,保证镁铁氧体的崩解和氧化铁的分离。所开发的技术可为巴加尔矿床提供高质量的菱铁矿富集。
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引用次数: 0
Structure and properties of 17G1S-U low-carbon pipe steel microalloyed by boron 硼微合金化17G1S-U低碳管钢的组织与性能
Q3 Materials Science Pub Date : 2018-11-14 DOI: 10.17073/0368-0797-2018-10-774-779
A. Babenko, V. Zhuchkov, Natalia Sel’menskikh, A. G. Upolovnikova
The results of analysis of the influence of boron microalloying on structure and properties of 17G1S-U pipe steel are given in the paper. Studies of metal structure were performed by electron microscopy and local X-ray spectral analysis. It has been established that metal containing 0.006 % of boron is characterized by an increased volume concentration to 0.029 % of oxide (OS) and oxysulfide (OSB) inclusions, whose content in metal without boron reaches 0.006 %. Separate sulphide inclusions (CB), whose concentration does not exceed 0.004 % against 0.029 % in a metal without boron, containing 0.01 % S is practically absent in the metal with boron containing 0.003 % S. The microalloying of pipe steel by boron has ensured the preferential formation of small nonmetallic inclusions, evenly distributed in the volume of metal. The proportion of nonmetallic inclusions with size less than 2 (rm is 76.1 %, whereas in steel without boron it is only 58.5 %. In this case, large nonmetallic inclusions of more than 10 rm are practically absent in the sample with boron. Their share does not exceed 0.6 %, which is 22 times less than their amount in the sample without boron. The structure of the sample without boron consists mainly of ferrite and a small amount of perlite, and the sample with boron is represented by a dispersed ferritic-bainitic structure. Increasing the microhardness of both ferrite and pearlite 80 and 100 HV10, respectively, is observed by adding boron to steel. The mechanical properties of 10 mm hot rolled metal from boron-containing 17G1S-U pipe steel are characterized by increased strength properties with preservation of plastic characteristics, due to the formation of predominantly small nonmetallic inclusions and a finely dispersed ferritic-bainitic structure. The absolute values of the yield stress and the time resistance of pipe steel containing in mass %: 0.006 B and 0.003 S are achieved without heat treatment at 585 and 685 MPa, respectively, and meet the X80 strength class, while retaining sufficiently high plastic characteristics. The pipe steel without boron containing 0.01 % of S belongs to the X70 strength class and is characterized by tensile strength lowered to 540 and 610 MPa and a temporary resistance, respectively.
本文给出了硼微合金化对17G1S-U管钢组织和性能影响的分析结果。通过电子显微镜和局部x射线光谱分析对金属结构进行了研究。结果表明,含硼量为0.006%的金属,其氧化物(OS)和硫氧化物(OSB)包裹体的体积浓度增加至0.029%,而不含硼的金属的氧化物和硫氧化物包裹体的体积浓度达到0.006%。单独的硫化物夹杂物(CB)在含0.01% S的不含硼金属中不超过0.004%,而在含0.01% S的不含硼金属中不超过0.029%,在含0.003% S的含硼金属中几乎不存在。硼对管钢的微合金化保证了较小的非金属夹杂物的优先形成,均匀地分布在金属体积中。尺寸小于2 (rm)的非金属夹杂物比例为76.1%,而在不含硼的钢中这一比例仅为58.5%。在这种情况下,含硼样品中几乎不存在大于10rm的大型非金属夹杂物。它们的含量不超过0.6%,比不含硼的样品中的含量少22倍。无硼试样主要由铁素体和少量珍珠岩组成,含硼试样以分散的铁素体-贝氏体结构为代表。在钢中加入硼后,铁素体和珠光体的显微硬度分别提高了80和100 HV10。含硼17G1S-U管钢10mm热轧金属的力学性能表现为:由于形成了主要的小的非金属夹杂物和精细分散的铁素体-贝氏体组织,在保持塑性特性的同时增强了强度性能。质量%:0.006 B和0.003 S的管材在585和685 MPa下无需热处理,屈服应力绝对值和耐时应力绝对值分别达到了X80强度等级,同时保持了足够高的塑性特性。含硫0.01%的无硼管钢强度等级为X70,抗拉强度降至540 MPa,抗拉强度降至610 MPa,暂时性抗拉强度降低。
{"title":"Structure and properties of 17G1S-U low-carbon pipe steel microalloyed by boron","authors":"A. Babenko, V. Zhuchkov, Natalia Sel’menskikh, A. G. Upolovnikova","doi":"10.17073/0368-0797-2018-10-774-779","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-10-774-779","url":null,"abstract":"The results of analysis of the influence of boron microalloying on structure and properties of 17G1S-U pipe steel are given in the paper. Studies of metal structure were performed by electron microscopy and local X-ray spectral analysis. It has been established that metal containing 0.006 % of boron is characterized by an increased volume concentration to 0.029 % of oxide (OS) and oxysulfide (OSB) inclusions, whose content in metal without boron reaches 0.006 %. Separate sulphide inclusions (CB), whose concentration does not exceed 0.004 % against 0.029 % in a metal without boron, containing 0.01 % S is practically absent in the metal with boron containing 0.003 % S. The microalloying of pipe steel by boron has ensured the preferential formation of small nonmetallic inclusions, evenly distributed in the volume of metal. The proportion of nonmetallic inclusions with size less than 2 (rm is 76.1 %, whereas in steel without boron it is only 58.5 %. In this case, large nonmetallic inclusions of more than 10 rm are practically absent in the sample with boron. Their share does not exceed 0.6 %, which is 22 times less than their amount in the sample without boron. The structure of the sample without boron consists mainly of ferrite and a small amount of perlite, and the sample with boron is represented by a dispersed ferritic-bainitic structure. Increasing the microhardness of both ferrite and pearlite 80 and 100 HV10, respectively, is observed by adding boron to steel. The mechanical properties of 10 mm hot rolled metal from boron-containing 17G1S-U pipe steel are characterized by increased strength properties with preservation of plastic characteristics, due to the formation of predominantly small nonmetallic inclusions and a finely dispersed ferritic-bainitic structure. The absolute values of the yield stress and the time resistance of pipe steel containing in mass %: 0.006 B and 0.003 S are achieved without heat treatment at 585 and 685 MPa, respectively, and meet the X80 strength class, while retaining sufficiently high plastic characteristics. The pipe steel without boron containing 0.01 % of S belongs to the X70 strength class and is characterized by tensile strength lowered to 540 and 610 MPa and a temporary resistance, respectively.","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76169799","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermodynamic modeling of nickel and iron reduction from multicomponent silicate melt in bubbling process. Report 2. Reducing agent – a mixture OF Н2 – Н2О 多组分硅酸盐熔体鼓泡还原镍铁的热力学模拟。报告2。还原剂- Н2 - Н2О的混合物
Q3 Materials Science Pub Date : 2018-11-14 DOI: 10.17073/0368-0797-2018-10-794-799
A. Vusikhis, L. Leont’ev, D. Z. Kudinov, E. Selivanov
A number of technologies in ferrous and non-ferrous metallurgy  are based on bubbling processes. For prediction of melting parameters  including the reduction of metals from oxide melt by a reducing gas  in a bubbling layer in industrial aggregates, a thermodynamic modeling technique is proposed based on calculation of the equilibrium in  oxide-melt-metal-gas system. Originality of the technique is that equilibrium is determined for each unit dose of gas introduced into the  working body, with the contents of oxides of metals being reduced in  each subsequent design cycle equal to the equilibrium in the previous  one. For the analysis NiO (1.8  %) – FeO (17.4  %) – CaO (13.5  %)  –  MgO  (1.9  %) – SiO2 (58.0  %) – Al2O3 (7.4  %) oxide system was  taken, closely corresponding to composition of oxidized nickel ore.  The ratio of Н2О/Н2 in gas mixture varies between 0 and 1.0. (1823  K),  amount and composition of formed metal (ferronickel), as well as the  indices (the ratio of slag and metal, the degree of reduction of metals)  are important in implementation of the process under commodity conditions. The increase in hydrogen consumption monotonously reduces  the content of nickel oxide in the melt, while the content of iron oxide  initially increases, and then decreases.  When H2 is introduced in an  amount of about 50 m3 per ton of the melt, the content of nickel oxide  in it is reduced to 0.017  %, and of iron oxide to 16.7  %. Resulting ferronickel contains 61  % Ni, ratio of slag and metal – 42  units. Further  increase in H2 consumption leads to preferential iron reduction. An increase in H2O/H2 ratio worsens the results of reduction of metals from  the melt: decrease in degree of reduction of nickel and iron, increase  in nickel content in the alloy, and the ratio of slag and metal. However,  even with a H2 / H2O ratio of 1.0, which corresponds to 50  % of H2O  in the gas mixture, reduction process does not stop. For comparison,  the work presents data on change in content of nickel and iron oxides,  when metals are restored from similar melts with carbon monoxide.  At a nickel recovery rate of 98  %, indicators are close in case of using  both H2 and CO. However, to achieve them, it is required 2.5  times less hydrogen, and 1.36 times less mixture in which H2O/H2  =  0.11  (H2  –  90  %) than carbon monoxide.
在黑色金属和有色金属冶金中,许多技术都是以鼓泡法为基础的。为了预测工业集料鼓泡层中氧化物熔体中金属的还原性,提出了一种基于氧化物-熔体-金属-气体系统平衡计算的热力学建模技术。该技术的创新之处在于,对每一单位剂量的气体引入工作体,都确定了平衡,在随后的每一个设计周期中,金属氧化物的含量都与前一个设计周期的平衡量相等,分析采用NiO (1.8%) - FeO (17.4%) - CaO (13.5%) - MgO (1.9%) - SiO2 (58.0%) - Al2O3(7.4%)氧化物体系,与氧化镍矿的组成密切相关。混合气体中Н2О/Н2的比值在0 ~ 1.0 (1823 K)之间变化,形成的金属(镍铁)的数量和组成,以及指标(渣与金属的比例,金属的还原程度)对于在商品条件下实施该工艺很重要。随着耗氢量的增加,熔体中氧化镍含量单调降低,而氧化铁含量先升高后降低。当每吨熔体加入50 m3左右的H2时,其氧化镍含量降至0.017%,氧化铁含量降至16.7%,镍铁含镍61%,渣金比为- 42单位。H2用量的进一步增加导致铁的优先还原。H2O/H2比的增大使熔体中金属的还原效果恶化:镍和铁的还原程度降低,合金中镍的含量增加,渣金比增大。然而,即使H2 / H2O比为1.0,即气体混合物中H2O含量为50%,还原过程也不会停止。为了进行比较,这项工作提供了镍和铁氧化物含量变化的数据,当金属从与一氧化碳相似的熔体中恢复时。在镍回收率为98%的情况下,同时使用H2和CO的指标接近,但要达到这一目标,所需的氢气比一氧化碳少2.5倍,H2O/H2 = 0.11 (H2 - 90%)的混合物比一氧化碳少1.36倍。
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引用次数: 1
Evaluation of uneven distribution of charge materials at blast furnace 高炉炉料分布不均匀的评价
Q3 Materials Science Pub Date : 2018-11-14 DOI: 10.17073/0368-0797-2018-10-766-773
S. K. Sibagatullin, A. S. Kharchenko, L. D. Devyatchenko
In various industries, the uneven distribution of material and  energy resources significantly affects stability of the technological  process and reduces the quality of products. In particular, in the blastfurnace production, the uneven distribution of charge materials and  the temperature of gases significantly affect technical and economic  performance of the furnace. The analysis of bibliographic sources  has shown that for the estimation of unevenness various coefficients  were generally used, taking into account the variability of material and  ener gy resources in the production process, the coefficient of variation  introduced by K. Pierson in 1895 was the most widespread. It was determined the relation between the square of the coefficient of variation of V2 and the value  X2= (n(N-1))/N*V2according to which the random  variable V2 has  X2k a distribution with k degrees of freedom, k  =  N  –  1,  where n  =  n1 + n2 + … + nN, ni is the value of the i-th measurement,  i = 1, N – is the number of measurements. The proposed method  for estimating the unevenness is based on statistics  X2k,  and X2also  introduced by K. Pearson in 1901 and 1904, respectively. The latter  was intended to test the H0-correspondence of the empirical and statistical distribution. The method for determining the circumferential  irregularity in the distribution of materials and gases in a blast furnace  is based on the consistency of X2k and X2 of Pearson statistics, using  the so-called quantile factor q, if in calculations of X2 the valu es   of the ,physical quantities themselves are used, by analogy, not the frequency  of the measured quantities. In this method, X2-statistic after correction  was used to determine the measure of deviation  (p) from the uniform  distribution, i.e. the unevenness coefficientp = p(X2/k), p  є  (0; 1 – α),   X2k =  X2max= qX2 was calculated. In order to reconcile X2 and  X2k statistics with the measurements of the physical quantities (temperature,  pressure) or materials (granular, gaseous), the X2-statistic must be adjusted so that  qX2max≈ X2k(α), X2max с(X21,..., Х2M )where M – is the  number of experiments for which the values   of X2-statics were determined,  X2k(α) – the upper α-quantile of  X2k statistic, q – the quantile multiplier, introduced for the correction of the X2-statistic values,  X2max–  the maximum value of X2-statistic is admissible for determining the  measure of non-uniformity.The method was tested to evaluate the relative non-uniformity of the loaded charge components and the distribution of peripheral temperature at blast furnaces of OJSC “MMK” with  volume of 2014 and 1370 m3. The influence of the sequence of a set of  charge components in the hopper of a bell-less charging device of the  furnace on the coefficient of circumferential unevenness (p) and the  technical and economic parameters of melting was revealed.
在各个行业中,材料和能源的不均匀分布严重影响了工艺过程的稳定性,降低了产品的质量。特别是在高炉生产中,炉料分布不均匀和气体温度明显影响炉膛的技术经济性能。对文献资料的分析表明,考虑到生产过程中材料和能源的可变性,对于不均匀度的估计一般采用各种系数,其中以Pierson于1895年引入的变异系数最为广泛。确定了V2变异系数的平方与X2= (n(n -1))/ n *V2的关系,据此,随机变量V2具有k个自由度的X2k分布,k = n -1,其中n = n1 + n2 +…+ nN, ni为第i次测量值,i = 1, n -为测量次数。提出的估计不均匀度的方法是基于统计数据X2k,而x2也分别由K. Pearson在1901年和1904年引入。后者旨在检验经验分布和统计分布的h0对应关系。确定高炉内物料和气体分布的周向不规则性的方法是根据皮尔逊统计的X2k和X2的一致性,使用所谓的分位数因子q,如果在X2的计算中类比地使用物理量本身的值,而不是测量量的频率。该方法利用修正后的X2统计量来确定与均匀分布的偏差度量(p),即计算不均匀系数p = p(X2/k), p _ (0; 1 - α), X2k = X2max= qX2。为了使X2和X2k统计量与物理量(温度,压力)或材料(颗粒,气体)的测量相一致,必须调整X2统计量,使qX2max≈X2k(α), X2max (X21,…, Х2M),其中M -为确定x2统计量值的实验数,X2k(α) - X2k统计量的上α分位数,q -为校正x2统计量值而引入的分位数乘数,X2max -确定非均匀性度量所允许的x2统计量的最大值。采用该方法对2014年和1370 m3的OJSC“MMK”高炉的载药组分相对不均匀性和外围温度分布进行了测试。揭示了炉内无钟装料装置料斗内一组料元排列顺序对圆周不均匀系数p和熔化工艺经济参数的影响。
{"title":"Evaluation of uneven distribution of charge materials at blast furnace","authors":"S. K. Sibagatullin, A. S. Kharchenko, L. D. Devyatchenko","doi":"10.17073/0368-0797-2018-10-766-773","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-10-766-773","url":null,"abstract":"In various industries, the uneven distribution of material and  energy resources significantly affects stability of the technological  process and reduces the quality of products. In particular, in the blastfurnace production, the uneven distribution of charge materials and  the temperature of gases significantly affect technical and economic  performance of the furnace. The analysis of bibliographic sources  has shown that for the estimation of unevenness various coefficients  were generally used, taking into account the variability of material and  ener gy resources in the production process, the coefficient of variation  introduced by K. Pierson in 1895 was the most widespread. It was determined the relation between the square of the coefficient of variation of V2 and the value  X2= (n(N-1))/N*V2according to which the random  variable V2 has  X2k a distribution with k degrees of freedom, k  =  N  –  1,  where n  =  n1 + n2 + … + nN, ni is the value of the i-th measurement,  i = 1, N – is the number of measurements. The proposed method  for estimating the unevenness is based on statistics  X2k,  and X2also  introduced by K. Pearson in 1901 and 1904, respectively. The latter  was intended to test the H0-correspondence of the empirical and statistical distribution. The method for determining the circumferential  irregularity in the distribution of materials and gases in a blast furnace  is based on the consistency of X2k and X2 of Pearson statistics, using  the so-called quantile factor q, if in calculations of X2 the valu es   of the ,physical quantities themselves are used, by analogy, not the frequency  of the measured quantities. In this method, X2-statistic after correction  was used to determine the measure of deviation  (p) from the uniform  distribution, i.e. the unevenness coefficientp = p(X2/k), p  є  (0; 1 – α),   X2k =  X2max= qX2 was calculated. In order to reconcile X2 and  X2k statistics with the measurements of the physical quantities (temperature,  pressure) or materials (granular, gaseous), the X2-statistic must be adjusted so that  qX2max≈ X2k(α), X2max с(X21,..., Х2M )where M – is the  number of experiments for which the values   of X2-statics were determined,  X2k(α) – the upper α-quantile of  X2k statistic, q – the quantile multiplier, introduced for the correction of the X2-statistic values,  X2max–  the maximum value of X2-statistic is admissible for determining the  measure of non-uniformity.The method was tested to evaluate the relative non-uniformity of the loaded charge components and the distribution of peripheral temperature at blast furnaces of OJSC “MMK” with  volume of 2014 and 1370 m3. The influence of the sequence of a set of  charge components in the hopper of a bell-less charging device of the  furnace on the coefficient of circumferential unevenness (p) and the  technical and economic parameters of melting was revealed.","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74386341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Model of thermomechanical behavior of structures reinforced by fibrous plastic 纤维塑料增强结构的热力学行为模型
Q3 Materials Science Pub Date : 2018-11-14 DOI: 10.17073/0368-0797-2018-10-824-826
V. Kaledin, K. V. Tagil’tsev-Galeta, A. D. Ul’yannov
Dependence of tensile strength of CFR with fiber reinforcement circuit 45°/0/-45° on maximum heating temperature is considered. This dependence is constructed according to the results of field experiment. The relation between excess of glass transition temperature and ultimate strength of the sample was established. It was concluded that it is possibile to make equilibrium equations for numerical modeling of structures made of polymer composite materials under joint force and multiple temperature effects, at temperatures slightly higher than glass transition temperature.
{"title":"Model of thermomechanical behavior of structures reinforced by fibrous plastic","authors":"V. Kaledin, K. V. Tagil’tsev-Galeta, A. D. Ul’yannov","doi":"10.17073/0368-0797-2018-10-824-826","DOIUrl":"https://doi.org/10.17073/0368-0797-2018-10-824-826","url":null,"abstract":"Dependence of tensile strength of CFR with fiber reinforcement circuit 45°/0/-45° on maximum heating temperature is considered. This dependence is constructed according to the results of field experiment. The relation between excess of glass transition temperature and ultimate strength of the sample was established. It was concluded that it is possibile to make equilibrium equations for numerical modeling of structures made of polymer composite materials under joint force and multiple temperature effects, at temperatures slightly higher than glass transition temperature.","PeriodicalId":35527,"journal":{"name":"Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76700072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of the interrelations of blowing parameters, options of electric influence and nature of liquid spraying by physical modeling 通过物理建模研究了喷吹参数的相互关系、电影响的选择和液体喷淋的性质
Q3 Materials Science Pub Date : 2018-11-14 DOI: 10.17073/0368-0797-2018-10-755-759
S. Semykin, T. Golub, E. V. Semykina, S. Dudchenko, V. Vakulchuk
The main and decisive factor of blowing in oxygen converters  is interaction of high-speed oxygen jet with a molten bath. The features of this interaction determine hydrodynamics and level of metal  losses with slopping and spitting. Their study is most accessible with  cold modeling. The paper presents results of laboratory studies on the  physical model of a 160 ton converter manufactured at a scale of 1:30  to study the influence of blowing modes on character of liquid spraying.  It is blown through a lance with five nozzle tips at 10 horizons in model  height on three zones of working volume of converter model: area near  lance, area near the wall and out-of-model area. That in practice corresponds to intensity of formation of skull on the lance, on converter  mouth and on elements of the fume gas collecting system. It was found  that the total amount of liquid sprays carried out of the model is extreme  and depends on level of lance position, with a noticeable decrease in  the amount of sprays at zero height above the liquid, and above certain  values. The possibility of reducing of the intensity of splashing formation and the level of liquid loss within the investigated zones was  determined by applying a low-voltage electric potential: with negative  polarity in the area near the lance and near the walls, and with positive  polarity – out of the model.  It was revealed that beginning of practical  influence of the potential and the maximum value of “useful” power  allocated in the sublance zone is determined by specific combination of  pressure before the nozzle and the level of tip of the lance: the higher  the pressure in front of the nozzle is, the higher lance position is needed  to reach maximum values of “useful” power. The experiments, conducted on physical model during blowing of saline solutions with gases  at using of electric potentials, have shown possibility of extending the  scope of developed method to processes not related to metallurgy.
高速氧射流与熔池的相互作用是决定转炉吹气的主要因素。这种相互作用的特征决定了水动力学和金属随倾倒和吐槽的损失水平。他们的研究最容易用冷模型进行。本文介绍了160吨转炉按1:30比例制造的物理模型的实验室研究结果,研究了吹风方式对液体喷涂特性的影响。在转炉模型工作体积的三个区域:近枪区、近壁区和模型外区,在模型高度的10个视距上通过一个有5个喷嘴头的喷枪吹气。在实践中,这与喷枪上、转炉口上和烟气收集系统元件上的颅骨形成强度相对应。研究发现,该模型的液体喷射总量是极端的,并且取决于喷枪位置的高低,在液体以上的零高度和超过一定数值时,喷雾量明显减少。降低飞溅形成强度和研究区域内液体损失水平的可能性是通过施加低压电势来确定的:在靠近喷枪和壁面的区域具有负极性,而在模型之外具有正极性。结果表明,在副平衡区分配的“有用”功率的电位和最大值的实际影响开始是由喷嘴前压力和喷枪尖端水平的特定组合决定的:喷嘴前压力越高,需要越高的喷枪位置才能达到“有用”功率的最大值。在利用电势用气体吹盐溶液的物理模型上进行的实验表明,有可能将已开发方法的范围扩展到与冶金无关的过程。
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引用次数: 0
Benefits and risks of blast furnaces with high intensity 高强度高炉的效益与风险
Q3 Materials Science Pub Date : 2018-11-14 DOI: 10.17073/0368-0797-2018-10-760-765
S. Zagainov, S. Filatov, S. V. Myasoedov, L. Gileva, V. Titov
Increase in the intensity of blast furnace smelting at NLMK JSC is achieved by improving quality of coke and iron ore materials, by increasing pressure under the blast furnace mouth and by oxygen enrichment. It is accompanied by an increase in the rate of wustite indirect reduction and decrease in specific heat losses with cooling water. However, the risks of burden yield problems are significantly lower with high intensity. It has been established that with the change in quality of charge materials, reason for burden yield problems can be also the variation in ore load ratio along the furnace radius. A new method for diagnosing causes of burden yield problems was developed. Using method of mathematical modeling, effect of change in ore load and size of iron-ore materials on peripheral gases temperature change and the degree of CO use were analyzed. The method is based on analysis of joint change in gas temperature and degree of CO use in peripheral area. Analysis of peripheral gases temperature variation and degree of CO use makes it possible to identify reasons of pressure drops along the furnace height. As a result of analysis of pressure drops dynamics changes along the furnace height, there have been found signs that can be used to judge the probability of burden yield problems. The possibility of reducing pressure drops due to redistribution of ore load along the furnace radius and the amount of gases is considered. It is shown that various methods of reducing the amount of gases are accompanied by different changes in coke consumption and furnace productivity. Mathematical model has been developed to select the best combination of parameters changing of the fuel-enriched blast in specific conditions.
通过提高焦炭和铁矿石原料的质量,增加高炉口下压力和富氧,实现了NLMK JSC高炉冶炼强度的提高。它伴随着使用冷却水时浮氏体间接还原速率的增加和比热损失的减少。然而,在高强度下,负荷屈服问题的风险明显降低。随着炉料质量的变化,导致炉料屈服问题的原因也可能是沿炉膛半径的载矿比的变化。提出了一种诊断负荷产率问题原因的新方法。采用数学建模的方法,分析了矿石载荷和铁矿物料粒度变化对外围气体温度变化和CO利用程度的影响。该方法是基于对周边地区燃气温度变化和CO利用程度的联合分析。通过对周边气体温度变化和CO利用程度的分析,可以找出沿炉高方向压力下降的原因。通过对压降沿炉体高度的动态变化进行分析,发现了判断炉料屈服概率的标志。考虑了由于矿负荷沿炉膛半径和气体量的重新分配而降低压降的可能性。结果表明,不同的减气量方法会引起焦炭消耗量和炉效率的不同变化。建立了在特定条件下选择富燃料爆炸参数变化的最佳组合的数学模型。
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引用次数: 0
Effect of titanium on oxygen solubility IN Ni - Co - Cr melts 钛对Ni - Co - Cr熔体氧溶解度的影响
Q3 Materials Science Pub Date : 2018-11-14 DOI: 10.17073/0368-0797-2018-10-827-831
A. Aleksandrov, V. Dashevskii
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引用次数: 0
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Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya
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