Journal of Environmental Management最新文献

D-limonene extracted from citrus peels possesses an inhibitory effect on methanogenic archaea. This study is aimed to bridge the research gap on the influence of D-limonene on volatile fatty acids (VFA) production from waste activated sludge (WAS) and to address the low VFA yield in standalone anaerobic fermentation of WAS. When the initial pH was not controlled, 1.00 g/g TSS D-limonene resulted in a VFA accumulation of 1175.45 ± 101.36 mg/L (174.45 ± 8.13 mgCOD/gVS). When the initial pH was controlled at 10 and the D-limonene concentration was 0.50 g/g TSS, the VFA accumulation reached 2707.44 ± 183.65 mg/L (445.51 ± 17.10 mgCOD/gVS). The pH-regulated D-limonene treatment enhanced solubilization and acidification, slightly inhibited hydrolysis, and significantly suppressed methanogenesis. D-limonene under alkaline conditions can increase the relative abundance of Clostridium_sensu_stricto, significantly enhancing acidification. Moreover, it markedly inhibited methanogenesis by particularly reducing the relative abundance of Methanothrix that was responsible for acetate consumption, thus favoring the accumulation of VFA. The research reveals the potential mechanism of pH regulation and D-limonene on anaerobic fermentation acid production, providing a theoretical basis for improving the acid production performance of the anaerobic fermentation of WAS.

Wastewater represents an alternative source of nutrients in which to grow microalgae, whilst improving the quality of the wastewater, and reducing the downstream treatment required. However, commercialisation of microalgal cultures for such duties faces a number of challenges, predominantly high cost and low productivity. Suspended-solid reactors (ssPBR) can reduce the operational costs, while promoting attached and suspended microalgae growth. In the present study, a novel approach was developed by integrating microalgal wastewater treatment with carrier systems to favour the growth of both attached and suspended cells of T. obliquus. This study found that T. obliquus was able to uptake nutrients from municipal wastewater, achieving removals of 99.3-99.9 % NH₃-N, 54.5-88.5 % PO₄^3- and 92.8-94.5 % DTC. The addition of a 12.5 % volumetric fill ratio of carriers in ssPBRs produced higher microalgal cell productivity (1.2·10⁶ ± 2.5·10⁵ cell ml^-1 d^-1) than the control (4.3·10⁵ ± 2.8·10⁵ cell ml^-1 d^-1). MinION nanopore sequencing was conducted to assess the impact of microalgal and carrier treatment on wastewater bacterial communities. It was found not only that bacterial communities had changed after the treatment but also the ones attached differed from the ones suspended. Untreated wastewater was characterised by the abundance of sewer bacteria genera such as Aliarcobacter and Arcobacter, whilst, after treatment, microbial communities were characterised by the presence of photosynthetic freshwater (Limnococcus, Stanieria) and bioremediation-like bacteria genera (Pseudomonas, Rheinheimera). In conclusion, the addition of 12.5 % fill carrier ratio increased microalgal productivity, while stimulating changes in the algal microbiome, and creating distinctly different populations in the free and attached environments.

Vanadium (V) contamination posed a significant environmental challenge, while phytoremediation offered a sustainable solution. Phytoremediation performance was often limited by the slow growth cycles of traditional plants. A novel approach to enhancing V phytoremediation by integrating coffee grounds with fast-growing plants such as barley grass, wheat grass, and ryegrass was investigated in this study. The innovative use of coffee grounds leveraged not only their nutrient-rich composition but also their ability to reduce oxidative stress in plants, thereby significantly boosting phytoremediation efficiency. Notably, ryegrass achieved 48.7% V⁵⁺ removal within 6 d with initial 20 mg/L V⁵⁺ (0.338 mg/L·d·g ryegrass). When combined with coffee grounds, V⁵⁺ removal by using wheat grass increased substantially, rising from 30.51% to 62.91%. Gradient Boosting and XGBoost models, trained with optimized parameters including a learning rate of 0.1, max depth of 3, and n_estimators of 300, were employed to predict and optimize V⁵⁺ concentrations in the phytoremediation process. These models were evaluated using mean squared error (MSE) and coefficient of determination (R²) metrics, achieving high predictive accuracy (R² = 0.95, MSE = 1.20). Feature importance analysis further identified the initial V⁵⁺ concentration and experimental duration as the most significant factors influencing the model's predictions. The addition of coffee grounds not only mitigated the stress of heavy metals on ryegrass, leading to significant reductions in CAT (87.2%), POD (98.8%), and SOD (39.2%) activities in ryegrass roots, but also significantly altered the microbial community abundance in the plant roots. This research provided an innovative enhancement to traditional phytoremediation methods, and established a new paradigm for using machine learning to predict and optimize V⁵⁺ remediation outcomes. The effectiveness of this technology in multi-metal polluted environments warrants further investigation in the future.

The rice industry is of great importance worldwide and within the cereal industrialization process, rice husk is obtained as waste, a by-product with various alternative uses, among others, the obtaining of amorphous silica, a covalent oxide with chemical, structural and textural properties suitable for use as catalytic support. This review shows the potential of rice husk silica in the synthesis of heterogeneous catalysts with transition metals for the oxidation of different polluting molecules present in water, as well as the limitations of the catalytic system and the way to overcome them through new synthesis routes, to obtain single atom catalysts - SACs. The main preparation strategies applied for aqueous phase systems are summarized, as well as the studies of single atom catalysts in oxidation reactions of recalcitrant compounds using silica as support and, finally, the perspectives and opportunities regarding this novel topic.

Carbon dioxide removal is considered by many as an essential piece to achieve global net zero targets which was also mentioned by the third working group of Intergovernmental Panel on Climate Change. On top of this, green hydrogen is badly needed to achive carbon-free society long-term sustainability. This study proposes a new five-step sodium hydroxide thermochemical cycle for simultaneous hydrogen production and carbon dioxide removal, which is driven by the heat at least 400 °C. The proposed integrated cycle can be driven by clean energy sources that can be utilized to generate heat at required temperatures. The proposed system is designed and analyzed by using energy and exergy approaches of thermodynamics. A case study is also developed in order to understand the effects of changing parameters on system performance. A thermochemical hydrogen production cycle is designed with an unequilibrium reaction where the respective heat capacity calculation models are employed. According to the calculations, more than half of the energy content of process heat can be converted into hydrogen, where maximum energy and exergy efficiencies of the thermochemical cycle are found as 50.05% and 76.61% when the separation reaction is carried out at 400 °C. According to the case study results, a parabolic trough collector type concentrated solar energy system with 295 kW of heat sink capacity, can generate 5216.65 kg of hydrogen and capture 19,991.97 kg of carbon dioxide in a location where 1500.11 kWh of solar energy is reached per m² of area in a typical year.

Due to industrial development, expansion of communities, and attention to sustainable development, sustainable energy supply has become a big challenge for communities. In this regard, the development and use of Renewable Energy (RE) are considered due to reducing the harmful environmental effects of fossil fuels. Improving the efficiency of the Renewable Energy Supply Chain (RESC) is important for using RE. To improve the performance and efficiency of RESC, it is necessary to use emerging technologies such as the Internet of Things (IoT) and its integration with the principles of the Circular Economy (CE). Therefore, this study proposes integrating IoT and CE for sustainable development and resource management in RESC. Also, this research provides a hybrid decision framework to assess the challenges of IoT and CE in the RESC of Iran. The CRiteria Importance Through Intercriteria Correlation (CRITIC) technique is used to specify the importance of the criteria. The Fuzzy Evaluation Based on Distance from Average Solution (FEDAS) technique ranks the challenges. The findings indicated that considering the cost of investment, the rate of return on investment, and the productivity rate were the most important sub-criteria with values of 0.149, 0.129, and 0.106 respectively. Then, the sensitivity of the results is examined and the validation of the findings is analyzed with decision-making methods. The results indicate the high priority of the challenge related to transparency in the implementation procedures of IoT and RE projects and information dissemination protocols, the development of guidelines for the integration of IoT in other systems in the information network, and the amount of investment and lack of access to financial resources. This study provided practical insights for RE development based on IoT and CE capabilities for energy planning.

Soil contamination with heavy metals (HMs) is still a global issue. The maintenance of long-term stability of HMs in soil during immobilization remediation is a challenge. Microwave (MW) technology can promote the immobilization of HMs in the form of crystals and minerals, thus enhancing their resistance of corrosion. This review provides a comprehensive introduction to the basics of MW irradiation through 177 papers, and reviews the research progress of MW involvement in the immobilization of soil HMs in 10 years. The effects of MW parameter settings, absorber/fixative types and soil physicochemical properties on immobilized HMs are investigated. The immobilization mechanisms of HMs are discussed, high-temperature physical encapsulation and chemical stabilization are the two basic mechanisms in the immobilization process. MW has a unique heating method to achieve efficient remediation by shortening remediation time, reducing the activation energy of reactions and promoting the transformation of stabilization products. Finally, the current limitations of MW in the remediation of HMs contaminated soils are systematically discussed and the corresponding proposed solutions are presented which may provide directions for further laboratory studies. There are still serious problems in taking the results obtained in the laboratory to the full scale. Thus, process optimization, scale-up, design and demonstration are strongly desired. In summary, this review may help new researchers to seize the research frontier in MW and can serve as a reference for future development of MW technology in soil remediation.

Environmental estrogens are currently a significant research topic, and poultry manure serves as a crucial source. This study investigated the degradation characteristics and effect mechanisms of six estrogens (E1, 17α-E2, 17β-E2, E3, 17α-EE2, and DES) during the aerobic composting of chicken manure. An orthogonal test comprising four factors (aeration rate, calcium-magnesium-phosphorus fertilizer (Ca-Mg-P fertilizer), coconut shell biochar, initial moisture content) and three levels of aerobic composting was conducted over a 45-day period to monitor the changes in estrogens and basic parameters. The results indicated that the factors influencing the estrogen degradation rate ranked as: initial moisture content (MC) > Ca-Mg-P fertilizer > aeration rate > coconut shell biochar. These factors significantly influenced the abundance of estrogen-degrading genera. Optimal composting conditions for estrogen degradation were identified as the addition of 10% coconut shell biochar, maintaining an initial moisture content of 60%, and using an aeration rate of 0.08 L min^-1∙kg^-1DM (dry matter), with an average degradation rate of 86.88% for the six estrogens under these conditions. During the composting process under various treatments, five known estrogen-degrading genera were observed with high relative abundance (max 31.08%), and the predominant genera were Staphylococcus and Brachybacterium for 17α-E2, 17β-E2, E3, 17α-EE2, and DES, and Pusillimonas for E1. The composition of microbial community structure changed significantly, and the dominated environment factors effecting the composition and succession of these genera were carbon to nitrogen ratio (C/N) and MC. The research results can provide both a theoretical basis and practical reference for the effective degradation of estrogens during the composting of chicken manure.

Biochar is widely used due to its potential in direct or indirect soil carbon sequestration. However, there is a lack of comprehensive studies on the changes in the physicochemical properties of biochar after long-term application in different types of soils and the effects on CO₂ emissions. In this study, paddy soil and fluvisol were selected as typical acidic and alkaline soils. Rice biochar (RB) and maize biochar (MB) were incorporated into paddy soil and fluvisol for one year, and characterizations (e.g., SEM-EDS, FTIR, 3D-EEM, and TG-DTG) of pristine and aged biochars were analyzed. Incubation experiments were conducted to assess the impact of aged biochar on CO₂ emissions from paddy soil and fluvisol. Results indicated consistent trends in the physicochemical properties of biochar after one year of aging in both acidic and alkaline soils. Aged biochars exhibited significant structural degradation, increased specific surface area, and increased oxygen-containing functional groups. The DOM fluorescence intensity of biochar decreased and the thermal stability increased after aging. Compared to pristine biochar, aged biochar promoted soil carbon sequestration, resulting in varied reductions in cumulative CO₂ emissions from paddy soil and fluvisol in the short term. Spearman's correlation coefficient analysis and PCA loading plot revealed that field-aged biochar primarily influenced CO₂ emissions from soil and carbon sequestration by reducing biochar DOC release and bioavailability of DOM, while enhancing the humification of biochar DOM. These findings suggest that aged biochar favors soil carbon sequestration in the short term, both in acidic and alkaline soils.

Arachis hypogaea L. (peanut) is an economic crop with abundant biomass and remarkable capacity for cadmium (Cd) uptake. In a two-year field experiment, the translocation and accumulation mechanisms of Cd in peanuts were investigated following inoculation of Bacillus megaterium (BM) and Trichoderma harzianum (TH). The results demonstrated that inoculating BM and TH enhanced both biomass and Cd concentration in peanut roots and shoots compared with those of the CK treatment. There was no statistically significant difference observed in kernel biomass between peanut plants inoculated with TH and the CK treatment. The inoculation of BM and TH increased the Cd concentration in the soluble fraction of peanut roots by 24.36% and 102.78%, thus promoting Cd translocation from roots to shoots. Additionally, inoculating BM and TH resulted in a 31.75% and 52.88% elevation in Cd concentration within the leaf cell walls, thereby facilitating the accumulation of Cd within the shoots. Simultaneously, inoculating BM and TH enhanced the concentration of highly bioavailable Cd forms in peanuts. The accumulation of Cd in shoots is the primary factor determining the phytoextraction capacity in peanut, and inoculation of TH resulted in a 16.35-54.54% increase in shoot biomass and an enhancement of 99.10-99.95% in shoot Cd concentration. Therefore, inoculating TH can enhance the phytoextraction capacity for Cd in peanuts, particularly the production of economically valuable components (kernels), without compromising production.