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Divergent key driving factors of soil salinity in Tarim River Basin, Northwest China 塔里木河流域土壤盐分关键驱动因素的发散性
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-31 DOI: 10.1016/j.jenvman.2026.128762
Yuanli Qin , Honghong Ma , Chengrui Wang , Min Peng , Fugui Zhang , Zheng Yang , Yu Zhao , Zhenyu Chen , Lingling Ma , Yang Shao , Chen Zhao , Hangxin Cheng
Soil salinization threatens agricultural sustainability and economic welfare, challenging global food production and sustainable agricultural development. Understanding the interactions between soil salinity and covariates is essential for advancing the understanding of salinization processes and informing land management decisions in salt-affected regions. This study examines the middle and lower reaches of the Tarim River Basin (TRB) in southern Xinjiang, leveraging machine learning-based data to identify key factors contributing to salinization evolution, while quantifying interactions among variables using the SHapley Additive exPlanations (SHAP) algorithm and analyzing causal relationships through structural equation model (SEM). The results reveal significant spatial heterogeneity in soil salinity across the middle and lower reaches of the TRB, increasing from northwest to southeast. Key driving factors include Silica-Alumina ratio (Sa), SiO2, Fe2O3, annual potential evapotranspiration (Pet), elevation (DEM), Normalized Difference Vegetation Index (NDVI), land use (LU) and soil texture (Texture), with their complex interactions contributing to this heterogeneity. What's more, this paper leverages SHAP dependency plots to elucidate interactions among factors influencing soil salinity from the perspectives of soil formation, climate and environment. To better understand the relationships between soil salinity and the influencing variables, the causal relationships between these factors and soil salinity are quantified in the SEM. The findings can provide valuable insights for managing soil salinization and promoting sustainable agricultural development in arid regions.
土壤盐渍化威胁着农业可持续性和经济福利,对全球粮食生产和农业可持续发展构成挑战。了解土壤盐分和协变量之间的相互作用对于促进对盐渍化过程的理解和为受盐影响地区的土地管理决策提供信息至关重要。本研究以南疆塔里木河流域中下游为研究对象,利用基于机器学习的数据识别影响盐渍化演变的关键因素,同时使用SHapley加性解释(SHAP)算法量化变量之间的相互作用,并通过结构方程模型(SEM)分析因果关系。结果表明:青藏高原中下游土壤盐分具有显著的空间异质性,呈现由西北向东南递增的趋势;主要驱动因子包括硅铝比(Sa)、SiO2、Fe2O3、年潜在蒸散量(Pet)、海拔(DEM)、归一化植被指数(NDVI)、土地利用(LU)和土壤质地(texture),它们之间的复杂相互作用导致了这种异质性。利用SHAP依赖关系图,从土壤形成、气候和环境等角度阐明土壤盐分影响因素之间的相互作用。为了更好地理解土壤盐度与影响变量之间的关系,在SEM中量化了这些因素与土壤盐度之间的因果关系。研究结果可为干旱区管理土壤盐渍化和促进农业可持续发展提供有价值的见解。
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引用次数: 0
Biodegradation of perfluorooctanoic acid and perfluorooctanesulfonic acid by a marine microalga Chaetoceros calcitrans MZB-1: kinetic analysis, removal pathways, and effects of environmental factors. 海洋微藻角化毛藻MZB-1对全氟辛酸和全氟辛烷磺酸的生物降解:动力学分析、去除途径和环境因素的影响。
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-31 DOI: 10.1016/j.jenvman.2026.128783
Wenlu Li, Fanping Meng, Wenjia Sun

This study investigated the removal efficiency and pathways of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) at environmentally relevant concentrations by marine diatom Chaetoceros calcitrans MZB-1, with a particular emphasis on kinetic analysis and optimization of environmental factors. In presence of alga MZB-1, the removal efficiencies of PFOA and PFOS at an initial concentration of 100 μg/L were 24.65 % and 29.35 %, respectively, within 15 d. The removal kinetics followed first-order models, with removal rate constants (k) of 0.014-0.019 d-1 for PFOA and 0.023-0.042 d-1 for PFOS, corresponding to the half-lives (t1/2) of 36.48-49.51 d and 16.50-30.14 d, respectively. By moderately increasing the microalgal inoculation density, the removal efficiencies of PFOA and PFOS could be improved, and the optimal initial inoculation density was 105 cells/mL. They were mainly removed through biodegradation processes, followed by biosorption and bioaccumulation. Single-factor experiments showed that the optimal growth conditions for the alga were temperature 25 °C, salinity 15 psμ, pH 8, and light intensity 60 μmol/(m2·s), while the maximum removal of PFOA and PFOS occurred at 25 °C, salinity 30 psμ, pH 8, and light intensity 200 μmol/(m2·s). The findings contributed to understanding the removal ability and pathways of marine microalgae towards per- and polyfluoroalkyl substances (PFASs), providing support for the application of microalgae in the bioremediation of PFASs-contaminated seawater.

本研究研究了海洋硅藻caetoceros calcitrans MZB-1对环境相关浓度的全氟辛酸(PFOA)和全氟辛烷磺酸(PFOS)的去除效率和途径,重点研究了环境因素的动力学分析和优化。在初始浓度为100 μg/L时,MZB-1对PFOA和PFOS的去除率在15 d内分别为24.65%和29.35%。去除动力学符合一阶模型,PFOA和PFOS的去除率常数(k)分别为0.014 ~ 0.019 d-1和0.023 ~ 0.042 d-1,半衰期(t1/2)分别为36.48 ~ 49.51 d和16.50 ~ 30.14 d。适度提高微藻接种密度可提高对PFOA和PFOS的去除效率,最佳初始接种密度为105个细胞/mL。它们主要通过生物降解过程去除,然后是生物吸附和生物积累。单因素实验结果表明,藻体的最佳生长条件为温度25℃、盐度15 pso μ、pH 8、光强60 μmol/(m2·s),对PFOA和PFOS的去除效果最好的条件为温度25℃、盐度30 pso μ、pH 8、光强200 μmol/(m2·s)。研究结果有助于了解海洋微藻对全氟烷基和多氟烷基物质(PFASs)的去除能力和途径,为微藻在全氟烷基污染海水生物修复中的应用提供支持。
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引用次数: 0
Land suitability assessment for wind farm development in Romania: Policy and GIS–AHP integration 罗马尼亚风电场发展的土地适宜性评估:政策与GIS-AHP整合
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-31 DOI: 10.1016/j.jenvman.2026.128777
Odelin Talabă , Alexandra Vrînceanu , Monica Dumitraşcu , Ines Grigorescu , Bianca Mitrică
In the context of climate change, Romania is actively advancing its transition to renewable energy, contributing to the European Green Deal goals of zero greenhouse gas emissions by 2050 and 45 % renewable energy share by 2030. Romania's onshore wind potential is estimated at 14,000 MW, with an existing installed capacity of around 3000 MW, concentrated mainly in the Dobrogea region. The National Energy Strategy 2022–2030 forecasts an additional 2302 MW capacity increase. This study develops a spatial suitability model for wind farm siting using the Fuzzy Analytic Hierarchy Process (FAHP) combined with GIS-based analysis. Eight criteria were evaluated and weighted based on expert judgment. Factors considered include wind speed, slope, altitude, land use, distance to transmission lines, settlements, roads and protected areas. Using GIS Weighted Overlay analysis, land was classified into five suitability classes. Results show that 51.1 % of Romania's territory is suitable for wind energy projects, especially in the eastern and southeastern counties of Tulcea, Constanța, Brăila, Galați, Călăraşi, and Vaslui. Validation against existing wind farm locations showed a 69.9 % spatial match within areas classified a ‘Very High’ suitability, and over 80 % within the combined ‘High’ and ‘Very High’ classes. Discrepancies are mainly due to protected area zoning and spatial data resolution. The findings deliver quantitative evidence to optimize wind farm siting and support data-driven decisions for policymakers and investors in line with EU decarbonization objectives.
在气候变化的背景下,罗马尼亚正在积极推进向可再生能源的过渡,为实现到2050年零温室气体排放和到2030年可再生能源占比达到45%的欧洲绿色协议目标做出贡献。罗马尼亚的陆上风电潜力估计为14000兆瓦,现有装机容量约为3000兆瓦,主要集中在多布罗吉亚地区。《2022-2030年国家能源战略》预测,中国将再增加2302兆瓦的装机容量。本研究采用模糊层次分析法(FAHP)和基于gis的分析相结合,建立了风电场选址的空间适宜性模型。根据专家的判断,对8个标准进行了评价和加权。考虑的因素包括风速、坡度、海拔、土地利用、与输电线路的距离、定居点、道路和保护区。利用GIS加权叠加分析,将土地划分为5个适宜性等级。结果表明,罗马尼亚51.1%的领土适合风能项目,特别是在图尔恰、Constanța、brurila、Galați、curlurra和Vaslui的东部和东南部县。对现有风电场位置的验证表明,在“非常高”适宜性区域内,有69.9%的空间匹配,超过80%的空间匹配属于“高”和“非常高”类别。差异主要由保护区分区和空间数据分辨率造成。研究结果为优化风电场选址提供了定量证据,并为政策制定者和投资者提供了符合欧盟脱碳目标的数据驱动决策。
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引用次数: 0
Clipping-and-burning alters carbon and nitrogen cycling through bacterial fixation pathways in the key Chinese karst region 在中国喀斯特重点地区,采伐燃烧通过细菌固定途径改变了碳氮循环
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-31 DOI: 10.1016/j.jenvman.2026.128721
Ansa Rebi , Guan Wang , Tao Yang , Irsa Ejaz , Adnan Mustafa , Jasper Kanomanyanga , Mohsin Mahmood , Xinglei Cui , Jinxing Zhou
Clip-and-burn is a forestry and land management technique common in China and other tropical regions worldwide to clear land for agriculture or to manage vegetation. However, the dynamics of carbon and nitrogen in karst regions following clip-and-burn practices remain largely unknown. Here, we evaluate the impact of clip-and-burn management practices on carbon and nitrogen cycling in the Karst region of China. The treatments included high-intensity fire (HIF), low-intensity fire (LIF), clipping and fire (CF), clipping (CP), and control (CK). Soil samples were collected one year after treatment application. Clipping-and-burning significantly influenced soil organic carbon (SOC), total nitrogen (TN), nitrate (NO3), and ammonium (NH4+) levels compared to the control. Clipping-and-burning treatments significantly (p < 0.05) reduced SOC, soil organic matter, TN, and NO3- compared to CK. In contrast, NH4+ content increased substantially under clip-and-burn treatments compared to CK, suggesting it potentially affects soil fertility and the recovery of plant life in the post-fire environment. Clipping-and-burning treatments showed higher Acidobacteria and Proteobacteria, likely driving C and N cycling, with Proteobacteria involved in N transformations. The higher bacterial diversity in LIF indicates more active nutrient cycling, with Actinobacteria indicating the importance of organic matter availability and nutrient balance. Moreover, CP significantly (p < 0.05) enhanced the metabolic potential for various N cycle processes, including N fixation, N uptake, and assimilatory NO3- reduction. On the other hand, CP also showed higher gene levels for N fixation than other treatments, indicating its effectiveness in promoting N assimilation in the soil. In addition, microbial biomass C, microbial biomass N, and microbial biomass P were significantly (p < 0.05) increased (by 10.70 %, 11.90 %, 25.60 % respectively) under CP treatment compared to CK. The changes in bacterial composition and diversity could have important implications for soil fertility, nutrient availability, and ecosystem functioning, particularly in terms of C sequestration and N availability in plants in the karst landscape. It suggests that careful fire management and selective clipping could enhance soil health and ecosystem productivity.
刈烧是中国和世界其他热带地区常见的一种林业和土地管理技术,用于清理农业用地或管理植被。然而,喀斯特地区的碳和氮在修剪和燃烧后的动态仍然很大程度上未知。本研究以喀斯特地区为研究对象,评价了刈烧管理方式对碳氮循环的影响。处理包括高强度火灾(HIF)、低强度火灾(LIF)、修剪和火灾(CF)、修剪(CP)和对照(CK)。施用处理后一年采集土壤样品。与对照相比,修剪和焚烧显著影响了土壤有机碳(SOC)、全氮(TN)、硝态氮(NO3−)和铵态铵(NH4+)水平。与对照相比,修剪和焚烧处理显著(p < 0.05)降低了土壤有机碳、土壤有机质、TN和NO3-。与对照相比,刈烧处理下NH4+含量显著增加,表明刈烧处理可能影响火灾后土壤肥力和植物生命恢复。修剪和焚烧处理显示出较高的酸杆菌和变形菌群,可能驱动C和N循环,变形菌群参与N转化。LIF中较高的细菌多样性表明更活跃的养分循环,放线菌表明有机质有效性和养分平衡的重要性。此外,CP显著(p < 0.05)增强了各N循环过程的代谢潜能,包括N固定、N吸收和同化性NO3-还原。另一方面,CP处理的固氮基因水平也高于其他处理,表明其促进土壤氮素同化的有效性。此外,与对照相比,CP处理显著提高了微生物生物量C、微生物生物量N和微生物生物量P (P < 0.05),分别提高了10.70%、11.90%和25.60%。细菌组成和多样性的变化可能对土壤肥力、养分有效性和生态系统功能具有重要意义,特别是在喀斯特景观中植物的碳固存和氮有效性方面。这表明,谨慎的火灾管理和选择性修剪可以提高土壤健康和生态系统生产力。
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引用次数: 0
Co-smouldering combustion of food waste and coal gasification slag: Synergistic effects on reaction characteristics and fuel gas properties. 食物垃圾与煤气化渣共阴燃:对反应特性和燃料气体特性的协同效应。
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-31 DOI: 10.1016/j.jenvman.2026.128790
Zhen Hu, Jingchun Huang, Yuhao Zhong, Xiaolong An, Pengfei Qin, Maolong Zhang, Qianshi Song, Yu Qiao

Co-smouldering is a promising way to improve the value of products and smouldering performance, while the detailed synergistic effects between various feedstocks are still unknown. This study provides novel insights into the synergistic effects on reaction characteristics and gas production during the co-smouldering of food waste and gasification slag, which have contrasting volatile and fixed carbon contents. The results demonstrated that blending 30 % gasification slag with food waste increased the maximum allowable moisture content to 75 %. For feedstocks with comparable low heating value (6.67-6.85 MJ/kg), high fixed carbon to volatile matter ratio significantly elevated the average peak temperature from 691.0 °C to 992.6 °C and increased the CO yield from 1.00 % to 6.87 %. Volatile-derived radicals from food waste promoted the formation of disordered carbon structures and C-O functional groups on the surface of gasification slag, leading to the enhancement formation of CO and the reduction of heavy condensable components (e.g., heterocyclic compounds). Additionally, catalytically active calcium species from food waste formed oxygen-containing complexes (e.g., C-O-M) with the gasification slag char matrix, which facilitated the gasification reactions (e.g., the Boudouard reaction) and increased smouldering velocity by 24.46 %-64.23 % compared to gasification slag alone. These findings provide valuable insights for developing efficient waste-to-energy strategies, highlighting the potential of co-smouldering for fuel gas production.

共阴燃是一种很有前途的提高产品价值和阴燃性能的方法,但各种原料之间的具体协同效应尚不清楚。本研究对具有不同挥发性碳和固定碳含量的食物垃圾和气化渣共阴烧过程中反应特性和产气的协同效应提供了新的见解。结果表明,将30%的气化渣掺入餐厨垃圾中,最大允许含水率提高到75%。对于热值较低(6.67 ~ 6.85 MJ/kg)的原料,高固定碳/挥发物比显著地将平均峰值温度从691.0℃提高到992.6℃,将CO产率从1.00%提高到6.87%。食物垃圾的挥发性自由基促进了气化渣表面无序碳结构和C-O官能团的形成,促进了CO的形成,减少了重可冷凝成分(如杂环化合物)。此外,食物垃圾中的催化活性钙与气化渣炭基体形成含氧配合物(如C-O-M),促进了气化反应(如Boudouard反应),焖烧速度比单独气化渣提高了24.46% ~ 64.23%。这些发现为制定有效的废物转化为能源战略提供了有价值的见解,突出了共阴燃用于燃料气体生产的潜力。
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引用次数: 0
Spatiotemporal prediction and attribution of groundwater storage anomaly using enhanced hybrid deep learning modeling with uncertainty quantification 基于不确定性量化的增强型混合深度学习模型的地下水储量异常时空预测与归因
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-30 DOI: 10.1016/j.jenvman.2026.128766
Jina Yin , Xinyao Hu , Tongchao Nan , Chunhui Lu
Large-scale groundwater prediction inherently involves data characterized by strong spatial and temporal heterogeneity as well as high dimensionality. Conventional data-driven approaches often struggle to effectively capture the complex and nonlinear groundwater dynamics, leading to great challenges in terms of accuracy and reliability. To achieve transparent and trustworthy predictions, this study proposes advanced hybrid deep learning modeling methods that integrate groundwater prediction, attribution analysis and uncertainty quantification within a cohesive framework. Two hybrid models with distinct architectures are constructed to effectively capture spatial patterns and temporal dependencies: CNN-Attention-LSTM (CAL) and Transformer-LSTM (TL). Intrinsic contributors are interpreted through SHapley Additive exPlanations. Stein Variational Gradient Descent (SVGD) is incorporated to quantify uncertainty and produce probabilistic predictions by capturing complex posterior distributions. Effectiveness of the methodology is well demonstrated through its application to groundwater storage anomaly (GWSA) prediction across the Yangtze River basin, China. Results show that both CAL and TL models deliver accurate GWSA distributions of spatiotemporal heterogeneity over the basin, with average R2 above 0.90. The CAL model outperforms in localized GWSA prediction. Meteorological factors predominantly contribute to GWSA, accounting for 80.66 % in the middle and lower basin. Furthermore, interactions among features and their synergistic impact on GWSA behave sensitive to feature ranges. SVGD significantly enhances predictive reliability, with major observations falling within 95 % confidence intervals. The modeling signifies a promising advancement for accurate GWSA prediction and risk-informed decision-making, while improving interpretability of outcomes. Our method has broad applicability and scalability by flexibly updating feature data in other environmental tasks.
大尺度地下水预测所涉及的数据具有较强的时空异质性和高维性。传统的数据驱动方法往往难以有效捕获复杂的非线性地下水动态,这在准确性和可靠性方面带来了巨大挑战。为了实现透明和可信的预测,本研究提出了先进的混合深度学习建模方法,将地下水预测、归因分析和不确定性量化整合在一个内聚框架内。为了有效捕获空间模式和时间依赖关系,构建了两种结构不同的混合模型:CNN-Attention-LSTM (CAL)和Transformer-LSTM (TL)。通过SHapley加性解释来解释内在因素。斯坦变分梯度下降(SVGD)被纳入量化不确定性和产生概率预测捕获复杂的后验分布。通过对长江流域地下水库存量异常(GWSA)的预测,验证了该方法的有效性。结果表明,CAL和TL模型均能较准确地反映流域的GWSA时空异质性,平均R2均在0.90以上。CAL模型在局部GWSA预测方面优于CAL模型。气象因子对GWSA的贡献最大,在中下游流域占80.66%。此外,特征之间的相互作用及其对GWSA的协同影响对特征范围敏感。SVGD显著提高了预测可靠性,主要观测值落在95%的置信区间内。该模型表明,在提高结果可解释性的同时,在准确预测GWSA和风险知情决策方面取得了有希望的进展。该方法可灵活地在其他环境任务中更新特征数据,具有广泛的适用性和可扩展性。
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引用次数: 0
Towards sustainable desertification control: A manufacturing method for porosity-controlled upright reed sand fences 走向沙漠化的可持续控制:一种控制孔隙度的直立芦苇沙栅栏的制造方法
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-30 DOI: 10.1016/j.jenvman.2026.128763
Manyu Jin , Yijiang Zheng , Yun Ge , Baojian Ma , Jiangyu Zhang , Rui An , Jianjun Cheng
Porosity is a critical factor affecting the windbreak and sand-fixing performance of upright reed sand fences. However, achieving consistent porosity control is challenging due to variations in reed bundle morphology and manufacturing complexities. This paper presents an intelligent system that integrates deep learning with real-time control to accurately regulate porosity. A lightweight instance segmentation model, Reed-YOLOv8n-SSAS, was developed for machine vision-based monitoring. Compared to the baseline YOLOv8n-seg, it achieved 98.6 % precision and 98.7 % [email protected], while reducing the model size, parameter count, and computational cost by 51.5 %, 55.4 %, and 40.0 %, respectively. A mask relocation algorithm was proposed to estimate the equivalent feed diameter during the transition from dispersed to bundled reeds. This enables real-time adjustment of the forming machine's parameters via a closed-loop control strategy. Field tests demonstrated that the system reliably maintained porosity near the target 45 %. Validation along the Xinjiang He-Ruo Railway showed that mechanically produced fences exhibited high structural integrity (straightness deviation ≤3°) and consistent porosity (44.8 ± 1.2 %), with significantly higher production efficiency compared to manual methods. This study provides a viable technical pathway for the green, efficient, and intelligent manufacturing of materials for desertification control.
孔隙度是影响直立芦苇沙栅防风固沙性能的重要因素。然而,由于芦苇束形态和制造复杂性的变化,实现一致的孔隙度控制是具有挑战性的。本文提出了一种将深度学习与实时控制相结合的智能系统,以精确调节孔隙度。针对基于机器视觉的监测,开发了轻量级实例分割模型Reed-YOLOv8n-SSAS。与基线的YOLOv8n-seg相比,它达到了98.6%的精度和98.7% [email protected],同时将模型大小、参数数量和计算成本分别减少了51.5%、55.4%和40.0%。提出了一种掩模重定位算法,用于估计分散芦苇向捆扎芦苇过渡时的等效进料直径。这样可以通过闭环控制策略实时调整成型机的参数。现场测试表明,该系统可靠地将孔隙度保持在45%的目标附近。新疆河若铁路沿线的验证结果表明,机械生产的围栏结构完整性高(直线度偏差≤3°),孔隙率一致(44.8±1.2%),生产效率显著高于手工方法。本研究为防沙治沙材料的绿色、高效、智能制造提供了一条可行的技术途径。
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引用次数: 0
Application of XGBoost using data from the oxygen reduction reaction of carbonaceous materials for H2O2 electrosynthesis XGBoost利用碳质材料氧还原反应数据在H2O2电合成中的应用
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-30 DOI: 10.1016/j.jenvman.2026.128770
Augusto D. Alvarenga, Marcos R.V. Lanza
Carbon-based materials, such as carbon black, have emerged as prominent candidates for the cathodic electrosynthesis of H2O2 due to their low cost, durability, and ease of chemical modification. While recent advances in catalyst design and parameter optimization have improved the electroasynthesis efficiency, the large number of interdependent features introduces complexity and unpredictability in the development of the system. In this context, machine learning (ML) algorithms have demonstrated great potential when used in interpreting complex datasets and deriving meaningful insights in diverse areas, including electrochemistry. While the selectivity and efficiency of metal-free carbon-based catalysts are strongly influenced by their surface functional groups, having a precise control over these functional groups remains a challenging task, and this affects the interpretation of experimental results. In this study, the XGBoost algorithm was used to analyze literature data on experimental conditions for H2O2 electrosynthesis, physicochemical characterizations, and the application of materials and their influence on H2O2 production efficiency. XPS analysis, Raman spectroscopy, BET surface area analysis, contact angle measurements, and electrical property analyses were used to characterize the electrocatalysts. The developed model demonstrated strong generalization capabilities, even when tested on external datasets not included in the training program. Furthermore, hyperparameter optimization analysis was used to refine the database, where the most relevant catalyst features were identified. This analysis enabled the creation of a more efficient model with reduced computational demands. Finally, thorough discussions were put forth regarding the challenges involving the construction of a robust database from fragmented experimental literature. This work provides useful contributions and insights into the application of ML in H2O2 electrosynthesis from experimental data, the construction of a structured database of carbonaceous catalysts, and the systematic interpretation of modeling results, paving the way for the rational design of new materials.
碳基材料,如炭黑,由于其低成本、耐用性和易于化学改性,已成为阴极电合成H2O2的重要候选材料。虽然催化剂设计和参数优化的最新进展提高了电合成效率,但大量相互依存的特征给系统的开发带来了复杂性和不可预测性。在这种背景下,机器学习(ML)算法在解释复杂数据集和在包括电化学在内的不同领域获得有意义的见解时显示出了巨大的潜力。虽然无金属碳基催化剂的选择性和效率受到其表面官能团的强烈影响,但对这些官能团的精确控制仍然是一项具有挑战性的任务,这影响了实验结果的解释。本研究采用XGBoost算法对H2O2电合成实验条件、理化表征、材料应用及其对H2O2生产效率的影响等文献数据进行分析。采用XPS分析、拉曼光谱分析、BET表面积分析、接触角测量和电学性能分析对电催化剂进行了表征。开发的模型显示出强大的泛化能力,即使在不包括在训练计划中的外部数据集上进行测试时也是如此。此外,使用超参数优化分析来优化数据库,其中确定了最相关的催化剂特征。这种分析可以创建更高效的模型,减少计算需求。最后,深入讨论了从支离破碎的实验文献中构建一个强大的数据库所面临的挑战。本工作从实验数据、碳质催化剂结构化数据库的构建、建模结果的系统解释等方面为机器学习在H2O2电合成中的应用提供了有益的贡献和见解,为新材料的合理设计铺平了道路。
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引用次数: 0
Socioeconomic inequality in flood exposure and compound urban flood risk: A multistage assessment across 30,000 towns in China 洪涝风险中的社会经济不平等和城市洪涝风险:中国3万个城镇的多阶段评估
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-30 DOI: 10.1016/j.jenvman.2026.128769
Zhen He , Jinghao Hei , Zhiqiang Wu , Otthein Herzog , Lan Li , Ting Yang , Xiang Li
Increases in precipitation extremes and rapid urbanization are globally reshaping urban flood risks. However, few studies jointly assess within-city exposure inequalities and green-gray infrastructure capacities at national scale. A multistage framework integrating statistical modeling with machine learning is employed to analyze flood exposure of over 30,000 towns across 303 Chinese cities in 2000–2018. Flood hazard is derived from satellite-based inundation footprints, while population, development, greenness, and a gray-infrastructure proxy are compiled from remote-sensing and statistical sources. First, two within-city flood-exposure patterns are identified, the High-Development-skewed exposure pattern (HD) and the Low-Development-skewed exposure pattern (LD), with risk ratios around 1.4 for both skews. These patterns cluster spatially and show divergent town- and city-level drivers across socioeconomic and green-gray indicators. Secondly, a comparison of green-gray infrastructure capacity deficits reveals that green under-capacity is pattern-invariant, indicating a baseline requirement across cities. Gray infrastructure shortfalls are more prevalent under LD, by about 6 %. Thirdly, hazard, exposure, and vulnerability are integrated into a compound city-level risk index and modulated by an inequality factor, capturing both physical risk and distributional burden. Across China, risk hotspots align along four belts, the Sichuan-Chongqing-Yunnan corridor, the southeastern seaboard, the middle-lower Yangtze corridor, and parts of Northeast China. This result reflects hazard clustering in the humid south and southwest, concentrated exposure along coastal and inland corridors, and an eastward increasing vulnerability. This integrated framework provides an equity-aware, interpretable risk decomposition that supports transferable, resource-efficient flood mitigation prioritization in China and other regions worldwide.
极端降水的增加和快速城市化正在全球范围内重塑城市洪水风险。然而,很少有研究在全国范围内联合评估城市内部暴露不平等和绿灰色基础设施能力。采用统计建模与机器学习相结合的多阶段框架,分析了2000-2018年中国303个城市3万多个城镇的洪水暴露情况。洪水灾害数据来自基于卫星的淹没足迹,而人口、发展、绿化和灰色基础设施代理数据则来自遥感和统计来源。首先,确定了两种城市内部洪水暴露模式,即高发展倾斜暴露模式(HD)和低发展倾斜暴露模式(LD),两种倾斜的风险比都在1.4左右。这些模式在空间上聚集,并在社会经济和绿灰色指标上显示出不同的城镇和城市级驱动因素。其次,对绿灰色基础设施产能赤字的比较表明,绿色基础设施产能不足是模式不变的,表明了各个城市的基线要求。灰色基础设施不足在LD下更为普遍,约为6%。第三,将危害、暴露和脆弱性整合成一个复合城市级风险指数,并通过不平等因子进行调节,同时捕捉物理风险和分配负担。在全国范围内,风险热点沿着川渝滇走廊、东南沿海、长江中下游走廊和东北部分地区四个地带排列。这一结果反映了灾害在潮湿的南部和西南部聚集,沿海和内陆走廊集中暴露,以及向东增加的脆弱性。这个综合框架提供了一个公平的、可解释的风险分解,支持中国和世界其他地区可转移的、资源高效的洪水缓解优先级。
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引用次数: 0
Distribution characteristics of microplastics in fish of the Tibetan plateau and its physiological effects on Schizothorax davidi 微塑料在青藏高原鱼类中的分布特征及其对大裂胸鱼的生理影响
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-30 DOI: 10.1016/j.jenvman.2026.128758
Dan Wang , Le Zhang , Wenqin Wu , Hui Cai , Yuanlong Sun , Xiaoning Liu , Zhaowei Zhang , Zhi-Quan Tian
Microplastic (MP) pollution in aquatic organisms poses a critical threat to aquatic ecosystem health and human food safety, however, the MP abundance, composition, and toxicological effects in cold fish from the Tibetan Plateau remain poorly understood. Microplastic pollution has emerged as a potential ecological threat to native fish species inhabiting the Tibetan Plateau. Field surveys revealed widespread MP ingestion, with a higher occurrence in farmed fish (61.9 %, 1.50–3.88 MPs/individual) compared to wild populations (44.4 %, 1.33–7.60 MPs/individual). The 30-day exposure experiment revealed dose-dependent PS-MPs accumulation in S. davidi (up to 1.37 μg/mg), accompanied by oxidative stress responses. Although glutathione levels increased as a compensatory defense, lipid peroxidation occurred at the highest exposure concentration (250 μg/L), with malondialdehyde levels reaching 2.1-fold of controls. Physical swimming ability was reduced, with a 45 % increase in induced velocity and a 37 % reduction in critical swimming speed. Chronic PS-MPs exposure also caused pronounced dysbiosis of gut microbiota, including a 5267 % proliferation of Cetobacterium and resurgence of pathogenic Aeromonas. Collectively, these effects resulted in a 28–37 % decline in migratory swimming capacity and multiple physiological disruptions. The results indicated that PS-MPs induced the oxidative stress, neurobehavioral impairment, and gut microbial imbalance, thereby threatening the survival and migratory fitness of Tibetan Plateau fish.
水生生物中的微塑料污染对水生生态系统健康和人类食品安全构成严重威胁,但对青藏高原冷鱼中微塑料的丰度、组成和毒理学效应的研究尚不充分。微塑料污染已成为青藏高原本地鱼类的潜在生态威胁。实地调查显示,MP摄食广泛存在,养殖鱼类的摄食率(61.9%,1.50-3.88 MP /个体)高于野生种群(44.4%,1.33-7.60 MP /个体)。30 d暴露实验显示,PS-MPs在大鼠体内呈剂量依赖性积累(最高可达1.37 μg/mg),并伴有氧化应激反应。虽然谷胱甘肽水平作为代偿性防御增加,但在最高暴露浓度(250 μg/L)下发生脂质过氧化,丙二醛水平达到对照的2.1倍。物理游泳能力下降,诱导速度增加45%,临界游泳速度降低37%。慢性PS-MPs暴露也会引起肠道微生物群明显的生态失调,包括胃杆菌的5267%的增殖和致病性气单胞菌的死灰复燃。总的来说,这些影响导致了28 - 37%的迁徙游泳能力下降和多种生理破坏。结果表明,PS-MPs可诱导氧化应激、神经行为损伤和肠道微生物失衡,从而威胁青藏高原鱼类的生存和洄游适应性。
{"title":"Distribution characteristics of microplastics in fish of the Tibetan plateau and its physiological effects on Schizothorax davidi","authors":"Dan Wang ,&nbsp;Le Zhang ,&nbsp;Wenqin Wu ,&nbsp;Hui Cai ,&nbsp;Yuanlong Sun ,&nbsp;Xiaoning Liu ,&nbsp;Zhaowei Zhang ,&nbsp;Zhi-Quan Tian","doi":"10.1016/j.jenvman.2026.128758","DOIUrl":"10.1016/j.jenvman.2026.128758","url":null,"abstract":"<div><div>Microplastic (MP) pollution in aquatic organisms poses a critical threat to aquatic ecosystem health and human food safety, however, the MP abundance, composition, and toxicological effects in cold fish from the Tibetan Plateau remain poorly understood. Microplastic pollution has emerged as a potential ecological threat to native fish species inhabiting the Tibetan Plateau. Field surveys revealed widespread MP ingestion, with a higher occurrence in farmed fish (61.9 %, 1.50–3.88 MPs/individual) compared to wild populations (44.4 %, 1.33–7.60 MPs/individual). The 30-day exposure experiment revealed dose-dependent PS-MPs accumulation in <em>S. davidi</em> (up to 1.37 μg/mg), accompanied by oxidative stress responses. Although glutathione levels increased as a compensatory defense, lipid peroxidation occurred at the highest exposure concentration (250 μg/L), with malondialdehyde levels reaching 2.1-fold of controls. Physical swimming ability was reduced, with a 45 % increase in induced velocity and a 37 % reduction in critical swimming speed. Chronic PS-MPs exposure also caused pronounced dysbiosis of gut microbiota, including a 5267 % proliferation of <em>Cetobacterium</em> and resurgence of pathogenic <em>Aeromonas</em>. Collectively, these effects resulted in a 28–37 % decline in migratory swimming capacity and multiple physiological disruptions. The results indicated that PS-MPs induced the oxidative stress, neurobehavioral impairment, and gut microbial imbalance, thereby threatening the survival and migratory fitness of Tibetan Plateau fish.</div></div>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"400 ","pages":"Article 128758"},"PeriodicalIF":8.4,"publicationDate":"2026-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146075835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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Journal of Environmental Management
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