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Balancing global standards and local needs: Digital technologies, social sustainability, and MSMEs. 平衡全球标准和地方需求:数字技术、社会可持续性和中小微企业。
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-15 DOI: 10.1016/j.jenvman.2025.128305
Surajit Bag, Susmi Routray, Linda L Zhang, Oksana Grebinevych

Literature has shown the benefits of digital technologies, and there is no doubt that they create immense value. However, value creation, such as digitally produced, increased standardized social sustainability practices in micro, small and medium enterprises (MSMEs), can sometimes produce negative outcomes. However, these relationships were rarely examined and discussed by prior researchers. The current study investigates, first, how the adoption of globalized digital technology solutions influences standardized social sustainability practices in MSMEs under the moderating effect of institutional pressures. Second, the study examines the effect of standardizing social sustainability practices on localized social sustainability initiatives in MSMEs. Third, it investigates the role of sustainability innovation in the relationship between standardizing social sustainability practices and focusing on localized, community-specific social sustainability initiatives in MSMEs. The theoretical model is developed using Institutional theory, Resource-based view and Contingency theory. Using 500 survey data sets, the theoretical model is tested. The findings indicate that globalized digital technology solutions have a positive and significant impact on the standardization of social sustainability practices. In addition, institutional pressures moderate the relationship between globalized digital technology solutions positively and significantly influence the standardization of social sustainability practices. The interesting aspect of our study is that the standardization of social sustainability practices has a negative influence on the focus on localized, community-specific social sustainability initiatives in MSMEs. Nonetheless, sustainability innovation acts as a contingency factor and increased sustainability innovation softens the negative effect of standardization on social sustainability initiatives. This study demonstrates that adopting globalized digital solutions can help MSMEs enhance standardized social sustainability practices, particularly when institutional pressures are present. However, standardization can sometimes limit localized, community-focused initiatives. To address this, businesses should prioritize sustainability innovation, reduce these negative effects, and create a better balance between standardized and local sustainability efforts.

文献已经展示了数字技术的好处,毫无疑问,它们创造了巨大的价值。然而,价值创造,如数字化生产,微型,中小型企业(MSMEs)的标准化社会可持续性实践,有时会产生负面结果。然而,这些关系很少被先前的研究人员检查和讨论。本研究首先探讨了在制度压力的调节作用下,全球化数字技术解决方案的采用如何影响中小微企业的标准化社会可持续性实践。其次,研究考察了标准化社会可持续发展实践对中小微企业本地化社会可持续发展举措的影响。第三,研究了可持续发展创新在中小微企业社会可持续发展实践标准化与注重本地化、社区特色的社会可持续发展举措之间的关系中所起的作用。运用制度理论、资源基础理论和权变理论建立了该理论模型。利用500个调查数据集对理论模型进行了检验。研究结果表明,全球化的数字技术解决方案对社会可持续性实践的标准化具有积极而显著的影响。此外,制度压力调节了全球化数字技术解决方案之间的关系,对社会可持续性实践的标准化产生了积极而显著的影响。我们研究的有趣之处在于,社会可持续性实践的标准化对中小微企业对本地化、社区特定社会可持续性倡议的关注产生了负面影响。然而,可持续性创新作为一个偶然性因素,增加的可持续性创新软化了标准化对社会可持续性举措的负面影响。本研究表明,采用全球化数字解决方案可以帮助中小微企业加强标准化的社会可持续性实践,特别是在存在制度压力的情况下。然而,标准化有时会限制本地化的、以社区为中心的举措。为了解决这个问题,企业应该优先考虑可持续性创新,减少这些负面影响,并在标准化和本地可持续性努力之间建立更好的平衡。
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引用次数: 0
Ecological and human-induced factors driving the invasion of Neurada procumbens in a protected coastal dune ecosystem: insights from chorological analysis within an environmental management framework. 在受保护的海岸沙丘生态系统中,生态和人为因素驱动原驼背神经蝗的入侵:来自环境管理框架内的时序分析的见解
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-15 DOI: 10.1016/j.jenvman.2025.128339
Emilio Medina-Lorenzo, Antonio I Hernández-Cordero, Abel Sanromualdo-Collado, Leví García-Romero

The management of invasive alien species represents a major challenge for the administration of protected natural areas. Understanding the factors that influence the spread of such taxa is essential for designing effective control and eradication strategies. This study investigates the interplay between abiotic, biotic, and anthropogenic factors and the increasing distribution and abundance of Neurada procumbens, an invasive psammophilous plant species, within a protected arid aeolian sedimentary system subject to intensive tourist activity. Based on the comparative results of two chorological inventories conducted 16 years apart, we analysed the colonization dynamics of the taxon and contrasted these with the environmental factors considered to influence the colonization success of N. procumbens. Chorological cartography was applied to 417 UTM grid cells, and abundance increases were categorized to support statistical analysis. Eco-anthropic variables were derived from GIS-based zonal statistics, including aeolian sediment transport, vegetation density, and trail density. Correlation analyses revealed that aeolian sedimentary dynamics are the primary limiting factor for the expansion of the species in the Maspalomas dune field (Canary Islands, Spain). Vegetation density also showed a biotic resistance effect, while trail density indicates a propagule dispersal factor, particularly in newly colonized areas near urban access points. Given its dominance in stabilized dune areas and its expansion over 16 years, the inclusion of N. procumbens in the Spanish Catalogue of Invasive Alien Species is recommended. These insights are currently informing management actions for the monitoring and control of this invasive alien species in the Maspalomas Dunes Special Nature Reserve.

外来入侵物种的管理是自然保护区管理面临的一个重大挑战。了解影响这些类群传播的因素对于设计有效的控制和根除策略至关重要。摘要本研究探讨了非生物因素、生物因素和人为因素在受旅游活动影响的干旱风成沉积系统中入侵性沙土植物原棘草(Neurada procumbens)的分布和丰度增加之间的相互作用。根据相隔16年的两次时序调查结果,分析了该分类群的定殖动态,并与影响原驼贝定殖成功的环境因素进行了对比。对417个UTM网格单元进行了时序制图,并对丰度增长进行了分类,以支持统计分析。生态人类变量来源于基于gis的地带性统计,包括风沙输运、植被密度和步道密度。相关分析表明,风成沉积动力学是西班牙加那利群岛Maspalomas沙丘区物种扩展的主要限制因素。植被密度也表现出生物抗性效应,而小径密度则表现出繁殖体扩散因子,特别是在靠近城市接入点的新殖民地区。鉴于其在稳定的沙丘地区的优势地位和16年来的扩张,建议将原驼鹿列入西班牙外来入侵物种目录。这些见解目前正在为马斯帕洛马斯沙丘特殊自然保护区监测和控制这种外来入侵物种的管理行动提供信息。
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引用次数: 0
Co-hydrothermal carbonization of the main components in food wastes: products characteristics and synergistic effects. 餐厨垃圾主要组分的共水热碳化:产品特性及协同效应。
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-15 DOI: 10.1016/j.jenvman.2025.128335
Xiao Wei, Zenghui Ma, Shiguang Jin, Tengfei Wang, Xueqin Li, Yinxue Li, Yongkang Wang, Bohan Zhang, Yanling Yu

This study investigated the product characteristics of (co-)hydrothermal carbonization (HTC) of staple food wastes (SW), vegetable waste (VW), and bone waste (BW) in food wastes (FW) and the potential synergistic effects. The result demonstrate that co-HTC showed a synergistic effect on oil production and antagonistic effects on gas and hydrochar production. Co-HTC further promoted decarboxylation, increased the carbon structure orderliness, and changed the surface chemical properties of hydrochars. Acid compounds were the main components of bio-oil, accounting for more than 50 %, followed by N-containing compounds. For the co-HTC of SW and VW, the decarboxylation of lipids, deoxygenation of carbohydrates, and reformation of cellulose and lipids resulted in the largest synergistic effect on hydrocarbons (interaction parameter, IP = 17.67 %). Aromatic compounds exhibited the largest synergistic effect (IP = 19.65 %) in the co-HTC of SW and BW, and N-containing compounds exhibited the largest synergistic effect (IP = 6.07 %) in the co-HTC of VW and BW. Accordingly, the reaction pathways for synergistic effects during the co-HTC of major FW components were analyzed.

研究了主食垃圾(SW)、蔬菜垃圾(VW)和骨垃圾(BW)在食物垃圾(FW)中(共)水热碳化(HTC)的产物特性及其潜在的协同效应。结果表明,co-HTC对产油具有协同作用,对产气和产烃具有拮抗作用。Co-HTC进一步促进了脱羧,增加了碳结构的有序性,改变了碳氢化合物的表面化学性质。酸性化合物是生物油的主要成分,占50%以上,其次是含氮化合物。对于SW和VW的co-HTC,脂质脱羧、碳水化合物脱氧、纤维素和脂质重组对碳氢化合物的协同效应最大(相互作用参数,IP = 17.67%)。芳香族化合物在SW和BW的co-HTC中具有最大的协同作用(IP = 19.65%),含氮化合物在VW和BW的co-HTC中具有最大的协同作用(IP = 6.07%)。据此,分析了FW主要组分共htc过程中协同效应的反应途径。
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引用次数: 0
Deciphering the microbial response and functional potential involving in cadmium-arsenic co-contaminated paddy soil remediation with silicon-magnetic biochar. 硅磁生物炭修复镉砷共污染水稻土的微生物响应及其功能潜力。
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-15 DOI: 10.1016/j.jenvman.2025.128318
Ji-Zi Wu, Jia-Hao Wang, Yao Chen, Yu Zhang, Lu Wang, Ke-Li Zhao

To remediate cadmium (Cd)-arsenic (As) co-contaminated paddy soils, a novel silicon-magnetic biochar (SBC) was synthesized. Its microbial remediation mechanisms were investigated through a rice pot experiment combined with metagenomics. Results showed SBC significantly improved soil properties, including increased pH and dissolved organic carbon (DOC). This led to a drastic reduction in the rhizosphere bioavailability of Cd (by 69.9 %) and As (by 29.5 %). Consequently, SBC enhanced rice growth, with mature plant height and dry biomass increasing by 25.0 % and 46.7 %, respectively. Crucially, SBC reduced Cd and As accumulation in grains by 38.4 % and 55.6 %. Metagenomics revealed SBC enhanced microbial diversity, stability, and functional potential in both soil and phyllosphere, particularly in cellular processes and genetic information processing. SBC enriched key soil taxa linked to detoxification, such as Geobacter, Gemmatirosa, and Flaviaesturariibacter, and beneficial phyllosphere microbes like Ensifer adhaerens and Rhizobium rosettiformans. Functionally, SBC up-regulated microbial Cd efflux genes, while strong physicochemical adsorption and precipitation (with OH-, Fe, and S2-) further enhanced Cd immobilization. Concurrently, it up-regulated As reduction genes while down-regulating As efflux genes, promoting microbial As(III) sequestration. These findings demonstrate SBC passivates Cd and As through synergistic physicochemical immobilization and microbial pathway modulation, which underscore its significant environmental value for restoring soil health and mitigating contamination.

为了修复镉砷共污染的水稻土,合成了一种新型硅磁性生物炭。通过水稻盆栽试验结合宏基因组学研究了其微生物修复机制。结果表明,SBC显著改善了土壤的理化性质,提高了土壤的pH值和溶解有机碳(DOC)。这导致根际镉和砷的生物利用度急剧下降(分别下降69.9%和29.5%)。因此,SBC促进了水稻生长,成熟株高和干生物量分别提高了25.0%和46.7%。最重要的是,SBC降低了Cd和As在籽粒中的累积量,分别降低了38.4%和55.6%。宏基因组学显示,SBC增强了土壤和层圈微生物的多样性、稳定性和功能潜力,特别是在细胞过程和遗传信息处理方面。SBC丰富了与解毒相关的关键土壤类群,如Geobacter、Gemmatirosa和flaviaesturaribacter,以及有益的根层微生物,如Ensifer adhaerens和Rhizobium rosettiformans。在功能上,SBC上调了微生物Cd外排基因,而强大的物理化学吸附和沉淀(OH-、Fe和S2-)进一步增强了Cd的固定化。同时,上调As还原基因,下调As外排基因,促进微生物As(III)的固存。这些结果表明,SBC通过协同的物理化学固定和微生物途径调节来钝化Cd和As,强调了其在恢复土壤健康和减轻污染方面的重要环境价值。
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引用次数: 0
Effects of grazing activities on ecosystem health in three-river-source national park. 放牧活动对三江源国家公园生态系统健康的影响
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-15 DOI: 10.1016/j.jenvman.2025.128332
Yanqin Wang, Huaju Xue, Ailing Sun, Aiqing Li, Xiaofen Wang, Jinhe Zhang

The Three-River-Source National Park (TNP) represents a vital ecological stronghold for China. Grazing, the primary anthropogenic disturbance activity in the region, is not only vital for sustaining local livelihoods but also a potential risk factor triggering ecosystem health degradation. However, comprehensive and dynamic analyses of grazing impacts on ecosystem health remain limited, hindering the development of strategies that simultaneously promote ecological conservation and community well-being. Based on multi-source data, this study quantified grazing intensity and ecosystem health dynamics in TNP from 2000 to 2020. We applied Geodetector and bivariate spatial autocorrelation analysis to examine the spatiotemporal responses of ecosystem health to grazing intensity. The results indicate that the park's ecosystem health improved overall in 2000-2020, displaying a distinct southeast-to-northwest declining gradient. Grazing intensity initially increased and then decreased, with noticeably intensified grazing hotspots emerging in the eastern region. Grazing activities generally exerted positive ecological effects, yet these benefits diminished marginally as grazing intensity increased. Bivariate Moran's I analysis revealed a spatially heterogeneous relationship characterized by "overall synergy coupled with local conflict" between grazing and ecosystem health. Furthermore, climatic factors, particularly precipitation, regulate the response of ecosystem health to grazing activities. This study offers a scientific basis for formulating spatially targeted grazing management policies that enhance ecological resilience while supporting sustainable livelihoods in the national park.

三江源国家公园(TNP)是中国重要的生态堡垒。放牧是该地区主要的人为干扰活动,不仅对维持当地生计至关重要,而且是引发生态系统健康退化的潜在风险因素。然而,放牧对生态系统健康影响的全面和动态分析仍然有限,阻碍了同时促进生态保护和社区福祉的战略的制定。基于多源数据,对2000 - 2020年青藏高原放牧强度和生态系统健康动态进行了定量分析。利用地理探测器和双变量空间自相关分析,研究了生态系统健康对放牧强度的时空响应。结果表明:2000-2020年,公园生态系统健康总体改善,呈现明显的东南-西北递减梯度;放牧强度先增大后减小,东部地区出现明显强化的放牧热点。放牧活动总体上具有积极的生态效应,但随着放牧强度的增加,这些效应略有减弱。双变量Moran’s I分析揭示了放牧与生态系统健康之间存在“整体协同与局部冲突”的空间异质性关系。此外,气候因子,特别是降水,调节着生态系统健康对放牧活动的响应。该研究为制定具有空间针对性的放牧管理政策提供了科学依据,以增强生态弹性,同时支持国家公园的可持续生计。
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引用次数: 0
Personal air pollution exposure assessment with schoolchildren in rural Wales. 威尔士农村学童的个人空气污染暴露评估。
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-15 DOI: 10.1016/j.jenvman.2025.128291
Shuangyu Wei, Zhiwen Luo, Simon Lannon, Tania Sharmin, Joseph Smith, Hanbin Zhang, Flora Samuel

Children are particularly vulnerable to air pollution. However, most UK exposure studies focus on urban areas, mainly school environments and commutes. Rural settings, where distinct pollution sources and personal exposure patterns can differ, are often overlooked. This study assessed schoolchildren's personal PM2.5 exposure across home, school, and commute settings on the Isle of Anglesey, a rural area in North Wales. Using low-cost sensors and a citizen science approach, it generated first-hand data while engaging children in monitoring. The pilot study involved 53 children from two primary schools, with 94 % providing valid data. Results showed that the average daily mean PM2.5 exposure across all participants was 6.5 μg/m3, though individual daily means reached as high as 43.5 μg/m3. Home environments exhibited the highest and most variable PM2.5 levels, linked to indoor sources such as wood burners and adult smoking reported by the participating students. The placement of sensors within households also significantly influenced exposure measurements. In contrast, levels during school hours and commutes were lower and more stable, with occasional spikes, for instance, during walks (depending on the route) or when exposed to second-hand smoke from adult smoking in cars. Children attending the rural school had slightly higher PM2.5 exposure across all microenvironments when compared to the urban school, potentially tied to higher wood burner use, suggesting links between heating practices, fuel poverty, and socioeconomic factors. Crucially, the findings highlight that parents' behaviours play a more significant role in determining children's exposure levels than the children's own choices.

儿童特别容易受到空气污染的影响。然而,大多数英国的暴露研究集中在城市地区,主要是学校环境和通勤。农村环境中不同的污染源和个人接触方式可能不同,这往往被忽视。这项研究评估了北威尔士农村地区安格尔西岛小学生在家庭、学校和通勤环境中的个人PM2.5暴露情况。它使用低成本传感器和公民科学方法,在让儿童参与监测的同时产生第一手数据。试点研究涉及来自两所小学的53名儿童,其中94%提供了有效数据。结果显示,所有参与者的PM2.5日平均暴露量为6.5 μg/m3,尽管个人日平均暴露量高达43.5 μg/m3。家庭环境显示出最高和最多变的PM2.5水平,这与参与研究的学生报告的室内来源有关,如木材燃烧器和成人吸烟。在家庭内放置传感器也显著影响了暴露测量。相比之下,上学时间和通勤期间的水平更低,也更稳定,偶尔会出现峰值,例如,在步行(取决于路线)或暴露于成人在汽车中吸烟的二手烟时。与城市学校相比,农村学校的儿童在所有微环境中的PM2.5暴露都略高,这可能与较高的木材燃烧器使用有关,这表明供暖方式、燃料贫困和社会经济因素之间存在联系。至关重要的是,研究结果强调,父母的行为比孩子自己的选择在决定孩子的暴露水平方面起着更重要的作用。
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引用次数: 0
Redox-active biochar as insoluble electron acceptors for anaerobic oxidation of ammonium. 氧化活性生物炭作为氨厌氧氧化的不溶性电子受体。
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-15 DOI: 10.1016/j.jenvman.2025.128315
Hao Yue, Jiajia Xu, Xiaohong Guan, Yanwen Shen

Anaerobic ammonium oxidation (anammox) is a promising nitrogen removal process, but its reliance on nitrite presents operational challenges. Here, we demonstrated that redox-active pyrogenic biochar could serve as an insoluble electron acceptor for NH4+ oxidation by anammox consortia. Through batch incubations, over 95 % total nitrogen removal was consistently achieved with biochar as the sole electron acceptor across two consecutive cycles, though at a slower rate (0.77-1.18 mmol-N·d-1 g-1 VSS) compared to conventional anammox reaction. Isotopic tracing confirmed the role of biochar as an electron sink, and electrochemical and spectroscopic analyses illustrated that biochar's electron-accepting capability was attributed to surface quinone-like and pyridinic N groups. High-throughput sequencing and metagenomics revealed the dominance of anammox species Candidatus Brocadia in biochar-driven NH4+ oxidation, with upregulated genes for extracellular electron transfer (EET) associated with c-type cytochromes. Metabolic reconstruction further elucidated the hydroxylamine pathway in biochar-driven anammox, distinctively different from the canonical nitrite-dependent route. These findings underscored biochar geobatteries as an inexpensive, environmentally sustainable electron acceptor, circumventing nitrite supply limitations. This work advances the understanding of EET-mediated anammox, thereby providing the potential for developing energy-efficient nitrogen removal technologies.

厌氧氨氧化(anammox)是一种很有前途的脱氮工艺,但它对亚硝酸盐的依赖存在操作上的挑战。在这里,我们证明了具有氧化活性的热原生物炭可以作为厌氧氨氧化联合体氧化NH4+的不溶性电子受体。通过批量培养,与常规厌氧氨氧化反应相比,生物炭作为唯一的电子受体,在连续两个循环中始终可以达到95%以上的总氮去除率,尽管速率较慢(0.77-1.18 mmol-N·d-1 g-1 VSS)。同位素示踪证实了生物炭作为电子汇的作用,电化学和光谱分析表明,生物炭的电子接受能力归因于表面类醌和吡啶N基团。高通量测序和宏基因组学显示厌氧氨氧化菌Candidatus Brocadia在生物炭驱动的NH4+氧化中占主导地位,与c型细胞色素相关的细胞外电子转移(EET)基因上调。代谢重建进一步阐明了生物炭驱动厌氧氨氧化中的羟胺途径,与典型的亚硝酸盐依赖途径明显不同。这些发现强调了生物炭地理电池作为一种廉价的、环境可持续的电子受体,绕过了亚硝酸盐供应的限制。这项工作促进了对eet介导的厌氧氨氧化的理解,从而为开发节能脱氮技术提供了潜力。
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引用次数: 0
A comprehensive review on bismuth-based ternary heterojunctions in photocatalytic wastewater treatment. 铋基三元异质结在光催化废水处理中的研究进展。
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-14 DOI: 10.1016/j.jenvman.2025.128319
Benjamin O Orimolade, Moses G Peleyeju, Tunde Lewis Yusuf

Bismuth-based ternary heterostructured photocatalysts have emerged as one of the most promising classes of materials for wastewater treatment, owing to their narrow band gaps, high structural versatility, and capacity to facilitate efficient charge carrier separation under solar irradiation. Recent studies demonstrate that integrating Bi2WO6, BiVO4, BiOX, Bi2MoO6, Bi2O3, Bi2S3, or multi-bismuth phases into ternary configurations, particularly Z-scheme, S-scheme, and dual heterojunction architectures, substantially enhances photocatalytic performance by accelerating interfacial electron transport while preserving strong redox potentials. These systems consistently achieve high degradation efficiencies across dyes, pharmaceuticals, antibiotics, pesticides, and emerging contaminants, frequently outperforming binary and single-component counterparts. Key advances include the use of carbonaceous scaffolds to broaden visible-light absorption, magnetic and transition-metal components to strengthen redox cycling, and defect or vacancy engineering to intensify surface reaction kinetics. Comparative evaluation across recent reports reveals that the most efficient ternary systems often couple broad-spectrum light harvesting with strong built-in electric fields that drive directional charge migration. Despite these advances, persistent challenges remain regarding interfacial stability, secondary pollution risks, and scalability of synthesis routes. Overall, the rapidly evolving evidence indicates that bismuth-based ternary heterostructures represent a highly adaptable, high-performance platform for future solar-driven wastewater treatment, with clear opportunities for optimization through targeted band engineering, green synthesis strategies, and improved photonic utilization.

铋基三元异质结构光催化剂由于其窄带隙、高结构通用性以及在太阳照射下促进有效载流子分离的能力而成为最有前途的污水处理材料之一。最近的研究表明,将Bi2WO6, BiVO4, BiOX, Bi2MoO6, Bi2O3, Bi2S3或多铋相整合成三元结构,特别是Z-scheme, S-scheme和双异质结结构,通过加速界面电子传递而大大提高光催化性能,同时保持强氧化还原电位。这些系统在染料、药物、抗生素、农药和新出现的污染物中始终实现高降解效率,通常优于二元和单一组分的对应产品。关键的进展包括使用碳质支架来扩大可见光吸收,磁性和过渡金属成分来加强氧化还原循环,缺陷或空位工程来加强表面反应动力学。最近报告的比较评估表明,最有效的三元体系通常将广谱光收集与驱动定向电荷迁移的强内置电场相结合。尽管取得了这些进展,但在界面稳定性、二次污染风险和合成路线的可扩展性方面仍然存在持续的挑战。总体而言,快速发展的证据表明,铋基三元异质结构代表了未来太阳能驱动废水处理的高适应性、高性能平台,通过有针对性的波段工程、绿色合成策略和提高光子利用率,有明显的优化机会。
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引用次数: 0
Phosphorous and nitrogen recovery from anaerobically digested sludge centrate: Evaluation of vivianite precipitation and membrane contactor. 厌氧消化污泥中磷和氮的回收:钙矾沉淀和膜接触器的评价。
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-14 DOI: 10.1016/j.jenvman.2025.128333
Magdalena Cifuentes-Cabezas, Rocío García-Lopez, Alöis Cuvelier, Silvia Álvarez-Blanco, José Antonio Mendoza-Roca

Nutrient recovery, particularly phosphorus, has gained attention as a sustainable solution to environmental and resource challenges. Wastewater treatment plants are key phosphorus reservoirs, with significant amounts found in sludge. Anaerobically digested sludge centrate (ADSC), rich in both phosphorus and nitrogen, presents an opportunity for nutrient recovery. This study investigates phosphorus recovery from ADSC through precipitation as vivianite (Fe3(PO4)2·8H2O), a promising alternative to struvite. Key factors such as pH, Fe/P molar ratio, stirring conditions, anoxic atmosphere (constant and initial N2 injection), and ion interference were evaluated in a simulated solution. The results showed that both the Fe/P molar ratio and pH influenced vivianite formation, while stirring modes and an anoxic atmosphere provided optimal conditions for vivianite formation. An Fe/P ratio of 1.75 and a pH of 8 were selected as optimal conditions for vivianite formation. These conditions were applied to ADSC, along with an additional nitrogen recovery step using emerging membrane contactor technology. This membrane step was assessed before and after precipitation. It was observed that in both cases, recovery of both nutrients was achieved, showing more feasibility the process with nitrogen separation after vivianite precipitation. Although the presence of other precipitated minerals was detected by FESEM-EDX, vivianite formation was achieved in all cases. This study provides insight into effective strategies for sustainable nutrient recovery in ADSC streams.

养分回收,特别是磷,作为环境和资源挑战的可持续解决方案而受到关注。污水处理厂是关键的磷库,在污泥中发现了大量的磷。厌氧消化污泥浓缩液(ADSC)富含磷和氮,为养分回收提供了机会。本研究探讨了ADSC中磷的沉淀回收方法,即作为鸟粪石的一种很有前途的替代品——vivianite (Fe3(PO4)2·8H2O)。在模拟溶液中考察了pH、Fe/P摩尔比、搅拌条件、缺氧气氛(恒定和初始N2注入)和离子干扰等关键因素。结果表明:Fe/P摩尔比和pH值均影响橄榄石的形成,而搅拌方式和缺氧气氛是橄榄石形成的最佳条件。铁磷比为1.75,pH值为8为形成橄榄石的最佳条件。这些条件适用于ADSC,以及使用新兴膜接触器技术的额外氮回收步骤。在沉淀前后对该膜步骤进行评价。在两种情况下,两种营养物质都得到了回收,这表明在薇薇石沉淀后进行氮分离的工艺更可行。虽然FESEM-EDX检测到其他沉淀矿物的存在,但在所有情况下都形成了橄榄石。该研究为ADSC溪流中可持续养分恢复的有效策略提供了见解。
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引用次数: 0
Integrated and managed grasses shape soil pore networks and carbon processes in tropical agroecosystems: Insights from synchrotron X-ray tomography. 整合和管理的草地在热带农业生态系统中塑造土壤孔隙网络和碳过程:来自同步加速器x射线断层扫描的见解。
IF 8.4 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-13 DOI: 10.1016/j.jenvman.2025.128323
Ricardo O Bordonal, Maoz Dor, Andrey K Guber, Maurício R Cherubin, Alexandre F Nascimento, Sarah Tenelli, Newton La Scala, Carlos E P Cerri, João L N Carvalho, Alexandra N Kravchenko

Integrating well-managed grass into agricultural systems is a management target for enhancing soil carbon (C) storage in tropical agroecosystems. Yet, the mechanisms behind physical protection of soil C are not sufficiently lucid. Here we analyzed pore structure and particulate organic matter (POM) characteristics in structurally intact soil using synchrotron X-ray computed micro-tomography (μCT). We combined these analyses with bulk measurements and CO2 respiration data to explore the interactions between pore structure and soil C characteristics in a mid-term experiment in the Southern Amazon, Brazil. The farming systems were: (i) crop succession (CS) with annual production of soybeans followed by corn; (ii) integrated crop-livestock (ICL) with soybeans and then corn intercropped with palisade grass; and (iii) well-managed pasture (MP) with continuous monoculture of palisade grass. Soils of ICL and MP exhibited higher soil C (18-27 %) and N (27-29 %) contents, along with increased microbial biomass C (25-45 %) compared to CS. Additionally, ICL and MP showed higher μCT-based porosity (26-30 %) than CS and a greater volume of pores in the 70-150 μm range, which are regarded as optimal microbial habitats. Image-determined POM fractions in ICL and MP were 71 % and 51 % higher compared to CS. The spatial distribution patterns of soil pores and POM influenced the magnitude of soil C decomposition. Greater distances to medium pores and to POM fragments in MP are likely associated with lower soil C losses via CO2 emission, suggesting more effective soil C protection. We surmise that the intricacies of pore networks and their association with the spatial distribution of POM dictate C accrual in soils with greater presence of well-managed grass, thus providing the basis for target-oriented development of management strategies to rebuild soil C in Brazilian agriculture.

将管理良好的草地纳入农业系统是加强热带农业生态系统土壤碳(C)储存的一个管理目标。然而,土壤C物理保护背后的机制还不够清楚。利用同步加速器x射线计算机微断层扫描(μCT)分析了结构完好土壤的孔隙结构和颗粒有机质(POM)特征。我们将这些分析与体积测量和二氧化碳呼吸数据相结合,在巴西亚马逊南部进行了一项中期实验,以探索孔隙结构与土壤C特征之间的相互作用。耕作制度为:(i)作物演替(CS),每年生产大豆,然后是玉米;(ii)以大豆和玉米间作栅栏草的作物-牲畜综合种植(ICL);(iii)管理良好的牧场(MP),连续单一栽培围栏草。与CS相比,ICL和MP的土壤C(18- 27%)和N(27- 29%)含量较高,微生物生物量C(25- 45%)增加。此外,ICL和MP的孔隙率(26 ~ 30%)高于CS,且孔隙体积在70 ~ 150 μm范围内较大,为最佳微生物栖息地。与CS相比,ICL和MP的图像测定POM分数分别高71%和51%。土壤孔隙和POM的空间分布格局影响土壤碳分解的幅度。MP中距离中等孔隙和POM碎片的距离越远,通过CO2排放导致的土壤C损失可能越低,这表明土壤C保护更有效。我们推测,孔隙网络的复杂性及其与POM空间分布的关联决定了土壤中碳的积累,而管理良好的草的存在更多,从而为有目标的管理策略的发展提供了基础,以重建巴西农业的土壤C。
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引用次数: 0
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Journal of Environmental Management
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