Pub Date : 2024-10-08DOI: 10.1016/j.jenvman.2024.122795
Y Huaccallo-Aguilar, A Kumar, M Meier, A Lerch, S F Reinecke
Micropollutants (MPs) encompass a range of human-made pollutants present in trace amounts in environmental systems. MPs include pharmaceuticals, personal care products, pesticides, persistent organic pollutants, micro- and nano-plastics, and artificial sweeteners, all posing ecological risks. Conventional municipal wastewater treatment methods often face challenges in completely removing MPs due to their chemical characteristics, stability, and resistance to biodegradation. In this research, an Advanced Oxidation Process, combining hydrodynamic cavitation (HC) with dissolved ozone (O3) and side injection, was employed to efficiently degrade succinic acid (SA), an ozone-resistant compound and common byproduct. The HC/O3 process was run to treat different synthetic effluents, focusing on evaluating the influence of O3-to-total organic carbon (TOC) ratio, cavitation number (Cv) and O3 dosage. Notably, the results from a series of 14 experiments highlighted the critical significance of a low O3-to-TOC ratio value of 0.08 mg/mg and Cv value of 0.056 in HC for achieving efficient SA removal of 41.2% from an initial SA solution (106.3 mg/L). Regarding a series of four proof-of-concept experiments and their replications, the average TOC removal reached 62% when treating wastewater treatment plant effluent spiked with SA. This significant removal rate was achieved under initial conditions: Cv of 0.02, O3-to-TOC ratio set at 0.77 mg/mg, TOC concentration of 47.7 mg/L, 106 mg/L of SA, and a temperature of 25 °C. Notably, the electrical energy per order required for the 62% reduction in TOC was a modest 12.5 kWh/m3/order, indicating the potential of the continuous HC/O3 process as a promising approach for degrading a wide range of MPs.
{"title":"Efficient removal of succinic acid by continuous hydrodynamic cavitation combined with ozone and side influent injection.","authors":"Y Huaccallo-Aguilar, A Kumar, M Meier, A Lerch, S F Reinecke","doi":"10.1016/j.jenvman.2024.122795","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.122795","url":null,"abstract":"<p><p>Micropollutants (MPs) encompass a range of human-made pollutants present in trace amounts in environmental systems. MPs include pharmaceuticals, personal care products, pesticides, persistent organic pollutants, micro- and nano-plastics, and artificial sweeteners, all posing ecological risks. Conventional municipal wastewater treatment methods often face challenges in completely removing MPs due to their chemical characteristics, stability, and resistance to biodegradation. In this research, an Advanced Oxidation Process, combining hydrodynamic cavitation (HC) with dissolved ozone (O<sub>3</sub>) and side injection, was employed to efficiently degrade succinic acid (SA), an ozone-resistant compound and common byproduct. The HC/O<sub>3</sub> process was run to treat different synthetic effluents, focusing on evaluating the influence of O<sub>3</sub>-to-total organic carbon (TOC) ratio, cavitation number (C<sub>v</sub>) and O<sub>3</sub> dosage. Notably, the results from a series of 14 experiments highlighted the critical significance of a low O<sub>3</sub>-to-TOC ratio value of 0.08 mg/mg and C<sub>v</sub> value of 0.056 in HC for achieving efficient SA removal of 41.2% from an initial SA solution (106.3 mg/L). Regarding a series of four proof-of-concept experiments and their replications, the average TOC removal reached 62% when treating wastewater treatment plant effluent spiked with SA. This significant removal rate was achieved under initial conditions: C<sub>v</sub> of 0.02, O<sub>3</sub>-to-TOC ratio set at 0.77 mg/mg, TOC concentration of 47.7 mg/L, 106 mg/L of SA, and a temperature of 25 °C. Notably, the electrical energy per order required for the 62% reduction in TOC was a modest 12.5 kWh/m<sup>3</sup>/order, indicating the potential of the continuous HC/O<sub>3</sub> process as a promising approach for degrading a wide range of MPs.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":null,"pages":null},"PeriodicalIF":8.0,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142387000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-08DOI: 10.1016/j.jenvman.2024.122714
Stefania Mottola, Gianluca Viscusi, Hebat-Allah S Tohamy, Mohamed El-Sakhawy, Giuliana Gorrasi, Iolanda De Marco
This work aims to apply carbon quantum dots (CQDs) from agriculture cellulosic waste (agro wastes), produced via an economically and eco-friendly single-step method, to be used into cellulose acetate composite microfibrous membranes as an innovative solution specifically designed to adsorb methylene blue (MB) and other cationic dyes that are present in various water effluents. Batch adsorption tests were conducted, with variations in contact time (1-24 h), initial MB concentration (25-300 ppm), and adsorbent doses (1-20 g/L). The maximum adsorption capacity of the membrane was 198 mg/g with an initial concentration of 300 ppm at 298 K. Thermodynamic parameters showed that the process is endothermic. Equilibrium experimental data for MB adsorption onto electrospun adsorbent were fitted using different isothermal models, with the Freundlich model showing the best fit. The pseudo-second-order model accurately described the kinetic data with high reliability (R2 > 0.99), and the calculated adsorption capacity was very close to the experimental data. N-CQDs loaded membranes were also tested for removing methyl violet and rhodamine B, demonstrating remarkably high dye removal efficiency. The underlying adsorption mechanism was also reported. Finally, it is worth mentioning that composite adsorbents can be efficiently applied to actual industrial cases because of the possibility of reusing them, opening the route to the fabrication of novel and highly performant adsorbents. These findings underscore N-CQDs' effectiveness in enhancing pollutant removal efficiency from wastewater, highlighting their environmental benefits and promoting a more sustainable approach to water treatment. Therefore, the prepared adsorbent, showing excellent adsorption performance, places them among adsorbents for practical applications in wastewater purification.
{"title":"Application of electrospun N-doped carbon dots loaded cellulose acetate membranes as cationic dyes adsorbent.","authors":"Stefania Mottola, Gianluca Viscusi, Hebat-Allah S Tohamy, Mohamed El-Sakhawy, Giuliana Gorrasi, Iolanda De Marco","doi":"10.1016/j.jenvman.2024.122714","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.122714","url":null,"abstract":"<p><p>This work aims to apply carbon quantum dots (CQDs) from agriculture cellulosic waste (agro wastes), produced via an economically and eco-friendly single-step method, to be used into cellulose acetate composite microfibrous membranes as an innovative solution specifically designed to adsorb methylene blue (MB) and other cationic dyes that are present in various water effluents. Batch adsorption tests were conducted, with variations in contact time (1-24 h), initial MB concentration (25-300 ppm), and adsorbent doses (1-20 g/L). The maximum adsorption capacity of the membrane was 198 mg/g with an initial concentration of 300 ppm at 298 K. Thermodynamic parameters showed that the process is endothermic. Equilibrium experimental data for MB adsorption onto electrospun adsorbent were fitted using different isothermal models, with the Freundlich model showing the best fit. The pseudo-second-order model accurately described the kinetic data with high reliability (R<sup>2</sup> > 0.99), and the calculated adsorption capacity was very close to the experimental data. N-CQDs loaded membranes were also tested for removing methyl violet and rhodamine B, demonstrating remarkably high dye removal efficiency. The underlying adsorption mechanism was also reported. Finally, it is worth mentioning that composite adsorbents can be efficiently applied to actual industrial cases because of the possibility of reusing them, opening the route to the fabrication of novel and highly performant adsorbents. These findings underscore N-CQDs' effectiveness in enhancing pollutant removal efficiency from wastewater, highlighting their environmental benefits and promoting a more sustainable approach to water treatment. Therefore, the prepared adsorbent, showing excellent adsorption performance, places them among adsorbents for practical applications in wastewater purification.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":null,"pages":null},"PeriodicalIF":8.0,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142386966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-08DOI: 10.1016/j.jenvman.2024.122797
Weverton V Oliveira, Mércia C F Silva, Bruno R Araújo, Luciane P C Romão
Glyphosate (GLY), a globally-used organophosphate herbicide, is frequently detected in various environmental matrices, including water, prompting significant attention due to its persistence and potential ecological impacts. In light of this environmental concern, innovative remediation strategies are warranted. This study utilized Serratia sp. AC-11 isolated from a tropical peatland as a biocatalyst in a microbial fuel cell (MFC) coupled with a homogeneous electron-Fenton (EF) process to degrade glyphosate in aqueous medium. After coupling the processes with a resistance of 100 Ω, an output voltage value of 0.64 V was obtained and maintained stable throughout the experiment. A bacterial biofilm of Serratia sp. AC-11 was formed on the carbon felt electrode, confirmed by attenuated total reflectance-Fourier transformed infrared (ATR-FTIR) and scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS). In the anodic chamber, the GLY biodegradation rate was 100% after 48 h of experimentation, with aminomethylphosphonic acid (AMPA) remaining in the solution. In the cathodic chamber, the GLY degradation rate for the EF process was 69.5% after 48 h experimentation, with almost all of the AMPA degraded by the in situ generated hydroxyl radicals. In conclusion, the results demonstrated that Serratia sp. AC-11 not only catalyzed the biodegradation of glyphosate but also facilitated the generation of electrons for subsequent transfer to initiate the EF reaction to degrade glyphosate. This dual functionality emphasizes the unique capabilities of Serratia sp. AC-11, it as an electrogenic microorganism with application in innovative bioelectrochemical processes, and highlighting its role in sustainable strategies for environmental remediation.
{"title":"Assessment of homogeneous electro-Fenton process coupled with microbial fuel cell utilizing Serratia sp. AC-11 for glyphosate degradation in aqueous phase.","authors":"Weverton V Oliveira, Mércia C F Silva, Bruno R Araújo, Luciane P C Romão","doi":"10.1016/j.jenvman.2024.122797","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.122797","url":null,"abstract":"<p><p>Glyphosate (GLY), a globally-used organophosphate herbicide, is frequently detected in various environmental matrices, including water, prompting significant attention due to its persistence and potential ecological impacts. In light of this environmental concern, innovative remediation strategies are warranted. This study utilized Serratia sp. AC-11 isolated from a tropical peatland as a biocatalyst in a microbial fuel cell (MFC) coupled with a homogeneous electron-Fenton (EF) process to degrade glyphosate in aqueous medium. After coupling the processes with a resistance of 100 Ω, an output voltage value of 0.64 V was obtained and maintained stable throughout the experiment. A bacterial biofilm of Serratia sp. AC-11 was formed on the carbon felt electrode, confirmed by attenuated total reflectance-Fourier transformed infrared (ATR-FTIR) and scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS). In the anodic chamber, the GLY biodegradation rate was 100% after 48 h of experimentation, with aminomethylphosphonic acid (AMPA) remaining in the solution. In the cathodic chamber, the GLY degradation rate for the EF process was 69.5% after 48 h experimentation, with almost all of the AMPA degraded by the in situ generated hydroxyl radicals. In conclusion, the results demonstrated that Serratia sp. AC-11 not only catalyzed the biodegradation of glyphosate but also facilitated the generation of electrons for subsequent transfer to initiate the EF reaction to degrade glyphosate. This dual functionality emphasizes the unique capabilities of Serratia sp. AC-11, it as an electrogenic microorganism with application in innovative bioelectrochemical processes, and highlighting its role in sustainable strategies for environmental remediation.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":null,"pages":null},"PeriodicalIF":8.0,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142386967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-08DOI: 10.1016/j.jenvman.2024.122801
Haiying Yu, Wenju Zhao, Lei Ding, Changquan Zhou, Hong Ma
Regulating the coupled relationship among water, nitrogen, and biochar is an effective strategy for increasing production and reducing emissions in greenhouse agriculture. However, a comprehensive evaluation model remains lacking. Toward this end, we aimed to evaluate the emission patterns of greenhouse gases and greenhouse tomato yield during the spring and autumn cultivation seasons as influenced by irrigation water use efficiency, nitrogen fertilizer partial productivity, and soil organic carbon (SOC). We applied three irrigation levels: 100% (W1), 80% (W2), and 60% (W3) of the reference crop evapotranspiration; three nitrogen application levels: 240, 192, and 144 kg ha-1, representing 100% (N1), 80% (N2), and 60% (N3) of the actual local application amount; and four biochar application gradients: B0, B1, B2, and B3 corresponding to 0, 30, 50, and 70 t ha-1, respectively. Interaction experiments were conducted based on the implementation the incomplete multifactorial design, using W1N1B0 as the control. The entropy weight method was used to calculate the main and sub-weights of the evaluation indicators. During the growing season, greenhouse gas emissions have a significant impact. The cumulative emissions of CO2, N2O, and CH4 from soil in spring are 24.4%, 42.18%, and 13.9% higher than those in autumn, respectively. Soil temperature was a key environmental factor influencing soil CO2 emissions, while soil moisture content and nitrogen fertilizer input efficiency were the main factors affecting soil N2O emissions, and the correlation between soil CH4 emissions and soil organic carbon content was most significant. Water-nitrogen-biochar interaction significantly affected yield and GHGI: adding biochar under the same water-nitrogen- and moderately deficient irrigation(W1) under the same nitrogen-biochar application modes increased yield and reduced GHGI. However, moderately reduced nitrogen application decreased(N2) both measures under the same water-biochar application mode. The VIKOR comprehensive evaluation method determined W2N2B2 as the most suitable water-nitrogen-biochar application mode for optimizing yield and GHGI. This study provides a theoretical basis for stable, low-carbon development in green-intensive agriculture.
{"title":"Effects of coordinated regulation of water, nitrogen, and biochar on the yield and soil greenhouse gas emission intensity of greenhouse tomatoes.","authors":"Haiying Yu, Wenju Zhao, Lei Ding, Changquan Zhou, Hong Ma","doi":"10.1016/j.jenvman.2024.122801","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.122801","url":null,"abstract":"<p><p>Regulating the coupled relationship among water, nitrogen, and biochar is an effective strategy for increasing production and reducing emissions in greenhouse agriculture. However, a comprehensive evaluation model remains lacking. Toward this end, we aimed to evaluate the emission patterns of greenhouse gases and greenhouse tomato yield during the spring and autumn cultivation seasons as influenced by irrigation water use efficiency, nitrogen fertilizer partial productivity, and soil organic carbon (SOC). We applied three irrigation levels: 100% (W1), 80% (W2), and 60% (W3) of the reference crop evapotranspiration; three nitrogen application levels: 240, 192, and 144 kg ha<sup>-1</sup>, representing 100% (N1), 80% (N2), and 60% (N3) of the actual local application amount; and four biochar application gradients: B0, B1, B2, and B3 corresponding to 0, 30, 50, and 70 t ha<sup>-1</sup>, respectively. Interaction experiments were conducted based on the implementation the incomplete multifactorial design, using W1N1B0 as the control. The entropy weight method was used to calculate the main and sub-weights of the evaluation indicators. During the growing season, greenhouse gas emissions have a significant impact. The cumulative emissions of CO<sub>2</sub>, N<sub>2</sub>O, and CH<sub>4</sub> from soil in spring are 24.4%, 42.18%, and 13.9% higher than those in autumn, respectively. Soil temperature was a key environmental factor influencing soil CO<sub>2</sub> emissions, while soil moisture content and nitrogen fertilizer input efficiency were the main factors affecting soil N2O emissions, and the correlation between soil CH<sub>4</sub> emissions and soil organic carbon content was most significant. Water-nitrogen-biochar interaction significantly affected yield and GHGI: adding biochar under the same water-nitrogen- and moderately deficient irrigation(W1) under the same nitrogen-biochar application modes increased yield and reduced GHGI. However, moderately reduced nitrogen application decreased(N2) both measures under the same water-biochar application mode. The VIKOR comprehensive evaluation method determined W2N2B2 as the most suitable water-nitrogen-biochar application mode for optimizing yield and GHGI. This study provides a theoretical basis for stable, low-carbon development in green-intensive agriculture.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":null,"pages":null},"PeriodicalIF":8.0,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142386997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-08DOI: 10.1016/j.jenvman.2024.122819
Yang Yu, Yituan Liu
This paper uses firm-level panel data to study the quasi-experiment of China's low carbon city (LCC) pilots and to estimate the dynamic impact of environmental regulations on firms' trade-offs between green innovation and digital innovation. The results indicate that environmental regulations lead to an increase in firms' green innovation in the short run and promote firms' digital transformation in the long run. Moreover, the key factors influencing firms' trade-offs are their size and the pollution levels of their primary businesses, highlighting the importance of both capability and immediacy for firms when making decisions. Furthermore, the event study shows that environmental regulations initially impact firms' profits in heavily polluting industries in the short run. However, environmental regulations can gradually enhance those profits in the long run by reducing marginal costs and upgrading industrial structures in treated regions. This paper provides insights for a deeper understanding of firms' heterogeneous choices and dynamic effects of innovation behaviors.
{"title":"Environmental regulations and firms' trade-offs between innovations: Empirical evidence from the quasi-experiment in China.","authors":"Yang Yu, Yituan Liu","doi":"10.1016/j.jenvman.2024.122819","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.122819","url":null,"abstract":"<p><p>This paper uses firm-level panel data to study the quasi-experiment of China's low carbon city (LCC) pilots and to estimate the dynamic impact of environmental regulations on firms' trade-offs between green innovation and digital innovation. The results indicate that environmental regulations lead to an increase in firms' green innovation in the short run and promote firms' digital transformation in the long run. Moreover, the key factors influencing firms' trade-offs are their size and the pollution levels of their primary businesses, highlighting the importance of both capability and immediacy for firms when making decisions. Furthermore, the event study shows that environmental regulations initially impact firms' profits in heavily polluting industries in the short run. However, environmental regulations can gradually enhance those profits in the long run by reducing marginal costs and upgrading industrial structures in treated regions. This paper provides insights for a deeper understanding of firms' heterogeneous choices and dynamic effects of innovation behaviors.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":null,"pages":null},"PeriodicalIF":8.0,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142387004","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-08DOI: 10.1016/j.jenvman.2024.122786
Min He, Babar Nawaz Abbasi, Zhichao Fan
This study makes a significant contribution to China's ambitious goals of achieving carbon dioxide (CO2) neutrality and transitioning to green economic growth (GEG), and integrating the theoretical framework of the impact, population, affluence, and technology (IPAT) theory, with real-world application to reduce CO2 and promote GEG for sustainable development. Furthermore, the study examines the ongoing theoretical debate on whether an inverted U-shaped environmental Kuznets curve (EKC) exists between technological innovations (TI) in environment-related fields and CO2 emissions in China, using data from 1990 to 2020 and employing the threshold instrumental variable two-stage least-squares (Th-IV2SLS) model. The findings indicate that all the variables representing education contribute to reducing CO2 emissions. The cost-effective levels of these variables to achieve CO2 reduction are as follows: a 93% literacy rate index, 12% education expenditure as a percentage of GDP, and an average of 6 years of schooling. Furthermore, TI also contributes to CO2 reduction, with a cost-effective level of 10.16% of TI. Educational variables promote GEG, with their respective cost-effective levels being 84% of the literacy rate index, 11.9% of education expenditure as a percentage of GDP, and an average of 5.5 years of schooling. In addition, TI promotes GEG, with a cost-effectiveness level of 10.4%. Moreover, there is a synergistic effect between education and TI that reduces CO2 emissions; however, the synergy that promotes GEG is relatively weak. Based on these findings, policy recommendations are provided to enhance the effectiveness of education and TI in reducing CO2 emissions and promoting GEG.
本研究为中国实现二氧化碳(CO2)中和以及向绿色经济增长(GEG)转型的宏伟目标做出了重要贡献,并将影响、人口、富裕程度和技术(IPAT)理论框架与实际应用相结合,以减少二氧化碳排放和促进绿色经济增长,实现可持续发展。此外,本研究还利用 1990 年至 2020 年的数据,采用阈值工具变量两阶段最小二乘法(Th-IV2SLS)模型,探讨了目前理论界关于中国环境相关领域的技术创新(TI)与二氧化碳排放之间是否存在倒 U 型环境库兹涅茨曲线(EKC)的争论。研究结果表明,所有代表教育的变量都有助于减少二氧化碳排放。这些变量实现二氧化碳减排的成本效益水平如下:识字率指数为 93%,教育支出占 GDP 的百分比为 12%,平均受教育年限为 6 年。此外,技术指数也有助于减少二氧化碳排放量,其成本效益水平为技术指数的 10.16%。教育变量可促进全球环境治理,其成本效益水平分别为识字率指数的 84%、教育支出占 GDP 的 11.9%以及平均 5.5 年的受教育时间。此外,技术和创新促进了全球教育增长,其成本效益水平为 10.4%。此外,教育和技术与创新之间存在协同效应,可减少二氧化碳排放;但促进全球环境治理的协同效应相对较弱。基于这些发现,本文提出了政策建议,以提高教育和技术创新在减少二氧化碳排放和促进全球环境治理方面的有效性。
{"title":"Education and technological innovation in mitigating CO<sub>2</sub> emissions and fostering green economic growth in China: Marginal effects and policy threshold analyses.","authors":"Min He, Babar Nawaz Abbasi, Zhichao Fan","doi":"10.1016/j.jenvman.2024.122786","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.122786","url":null,"abstract":"<p><p>This study makes a significant contribution to China's ambitious goals of achieving carbon dioxide (CO<sub>2</sub>) neutrality and transitioning to green economic growth (GEG), and integrating the theoretical framework of the impact, population, affluence, and technology (IPAT) theory, with real-world application to reduce CO<sub>2</sub> and promote GEG for sustainable development. Furthermore, the study examines the ongoing theoretical debate on whether an inverted U-shaped environmental Kuznets curve (EKC) exists between technological innovations (TI) in environment-related fields and CO<sub>2</sub> emissions in China, using data from 1990 to 2020 and employing the threshold instrumental variable two-stage least-squares (Th-IV2SLS) model. The findings indicate that all the variables representing education contribute to reducing CO<sub>2</sub> emissions. The cost-effective levels of these variables to achieve CO<sub>2</sub> reduction are as follows: a 93% literacy rate index, 12% education expenditure as a percentage of GDP, and an average of 6 years of schooling. Furthermore, TI also contributes to CO<sub>2</sub> reduction, with a cost-effective level of 10.16% of TI. Educational variables promote GEG, with their respective cost-effective levels being 84% of the literacy rate index, 11.9% of education expenditure as a percentage of GDP, and an average of 5.5 years of schooling. In addition, TI promotes GEG, with a cost-effectiveness level of 10.4%. Moreover, there is a synergistic effect between education and TI that reduces CO<sub>2</sub> emissions; however, the synergy that promotes GEG is relatively weak. Based on these findings, policy recommendations are provided to enhance the effectiveness of education and TI in reducing CO<sub>2</sub> emissions and promoting GEG.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":null,"pages":null},"PeriodicalIF":8.0,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142386984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-08DOI: 10.1016/j.jenvman.2024.122687
Seyed Abbas Hosseini-Sadabadi, Alain N Rousseau, Isabelle Laurion, Sonja Behmel, Amir Sadeghian, Etienne Foulon, Maxime Wauthy, Anne-Marie Cantin
Lake St. Charles, located north of Quebec City, Canada, is a shallow fluvial lake with two distinct basins bridging rural and urban landscapes. Mainly used as a source of drinking water for 300,000 residents, the lake has faced a steady degradation in water quality due to urbanization and the discharge of domestic wastewater. This study introduces a 3D hydrodynamics and water quality model using the Environmental Fluid Dynamics Code to enhance our understanding of algal bloom dynamics in Lake St. Charles. More specifically, we ran simulations for eight years (i.e., a three-year period for calibration, 2015 to 2017; and a five-year period for validation, 2018 to 2022) to reproduce the complex circulation patterns and dynamics of water quality within the system. The simulation results for chlorophyll-a demonstrate seasonal fluctuations in phytoplankton biomass, closely aligning with in situ observations and achieving Relative Root Mean Square Error (RRMSE) values below 50%. (i) In spring, runoff from snowmelt brought phosphorus into the lake, triggering primary production. Diatom growth was initially predominant in the shallow southern basin, then spread to the deeper northern basin due to favorable environmental conditions, including flow- and wind-induced currents, warmer water temperatures and nutrient availability. (ii) In summer, warm water temperatures stimulated biological activity, leading to the growth of cyanobacteria at the expense of diatoms, as well as a drop in phosphorus. (iii) The cyanobacteria persisted into the fall but began to decline in mid-November. (iv) Winter conditions, including the presence of an ice cover, limited the input of phosphorus and minimized phytoplankton production, but diatoms were observed in low concentrations near Des Hurons River inflow. Overall, during the open-water period, the lake-maintained chlorophyll-a concentrations indicative of mesotrophic conditions, with occasional periods when the biomass increased above the eutrophic threshold. Temperature, nutrient levels, and the fluvial dynamics of the lake are the primary factors influencing phytoplankton formation and distribution in lake St. Charles.
{"title":"Spatiotemporal insights of phytoplankton dynamics in a northern, rural-urban lake using a 3D water quality model.","authors":"Seyed Abbas Hosseini-Sadabadi, Alain N Rousseau, Isabelle Laurion, Sonja Behmel, Amir Sadeghian, Etienne Foulon, Maxime Wauthy, Anne-Marie Cantin","doi":"10.1016/j.jenvman.2024.122687","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.122687","url":null,"abstract":"<p><p>Lake St. Charles, located north of Quebec City, Canada, is a shallow fluvial lake with two distinct basins bridging rural and urban landscapes. Mainly used as a source of drinking water for 300,000 residents, the lake has faced a steady degradation in water quality due to urbanization and the discharge of domestic wastewater. This study introduces a 3D hydrodynamics and water quality model using the Environmental Fluid Dynamics Code to enhance our understanding of algal bloom dynamics in Lake St. Charles. More specifically, we ran simulations for eight years (i.e., a three-year period for calibration, 2015 to 2017; and a five-year period for validation, 2018 to 2022) to reproduce the complex circulation patterns and dynamics of water quality within the system. The simulation results for chlorophyll-a demonstrate seasonal fluctuations in phytoplankton biomass, closely aligning with in situ observations and achieving Relative Root Mean Square Error (RRMSE) values below 50%. (i) In spring, runoff from snowmelt brought phosphorus into the lake, triggering primary production. Diatom growth was initially predominant in the shallow southern basin, then spread to the deeper northern basin due to favorable environmental conditions, including flow- and wind-induced currents, warmer water temperatures and nutrient availability. (ii) In summer, warm water temperatures stimulated biological activity, leading to the growth of cyanobacteria at the expense of diatoms, as well as a drop in phosphorus. (iii) The cyanobacteria persisted into the fall but began to decline in mid-November. (iv) Winter conditions, including the presence of an ice cover, limited the input of phosphorus and minimized phytoplankton production, but diatoms were observed in low concentrations near Des Hurons River inflow. Overall, during the open-water period, the lake-maintained chlorophyll-a concentrations indicative of mesotrophic conditions, with occasional periods when the biomass increased above the eutrophic threshold. Temperature, nutrient levels, and the fluvial dynamics of the lake are the primary factors influencing phytoplankton formation and distribution in lake St. Charles.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":null,"pages":null},"PeriodicalIF":8.0,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142386992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Agricultural soil contamination by potentially toxic elements (PTEs) such as arsenic (As) and cadmium (Cd) poses a serious threat to food security. Immobilization serves as a widely used approach for the remediation of PTEs contaminated soils, nevertheless, the long-term effectiveness for the simultaneous immobilization of both cations and oxyanions remains a challenge. In order to effectively enhance the synergistic immobilization effect of soil As and Cd contaminated by multiple elements and improve the ecological environment of farmland. In this study, a typical polluted tailings area farmland was selected for situ immobilization experiments, and biochar was prepared from cow manure (CMB), rice straw (RSB), and pine wood (PWB) as raw materials. On this basis, the pristine biochar was modified with ferric chloride (F), potassium permanganate (K), magnesium chloride (M), and aluminum chloride (A), respectively. Furthermore, the immobilization effect of modified biochar on As-Cd and the stress effect on soil respiration were investigated. The results showed that CMB and RSB reduced the bioavailability of heavy metals, potassium permanganate has strong oxidizing properties, and the strong oxidability of potassium permanganate stimulated the generation of more oxygen-containing functional groups on the surface of biochar, thereby enhancing the adsorption and complexation effect of modified materials on As and Cd. Among them, the extracted Cd concentration of Diethylenetriamine pentaacetic acid (DTPA) in KCMB and KRSB in 2020 decreased by 8.23-43.12% and 9.67-35.29% compared to other treatments, respectively. Meanwhile, the KCMB and KRSB treatments also reduced the enrichment of As and Cd in plant tissues. In addition, the dissolved organic carbon (DOC) content in KCMB treatment was relatively high, and the carbon stability of the material was weakened. Simultaneously, the soil respiration emission of KCMB treatment was increased by 5.63% and 11.93% compared to KRSB and KPWB treatments, respectively. In addition, the structural equation also shows that DOC has a large positive effect on soil respiration. In summary, the KRSB treatment effectively achieve synergistic immobilization of As-Cd and provide important guiding significance for green and low-carbon remediation of polluted farmland.
{"title":"Engineered biochars for simultaneous immobilization of as and Cd in soil: Field evidence.","authors":"Renjie Hou, Yuxuan Wang, Yanling Deng, Bingyu Zhu, Jian Zhang, Yulu Zhou, Wei Huang","doi":"10.1016/j.jenvman.2024.122764","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.122764","url":null,"abstract":"<p><p>Agricultural soil contamination by potentially toxic elements (PTEs) such as arsenic (As) and cadmium (Cd) poses a serious threat to food security. Immobilization serves as a widely used approach for the remediation of PTEs contaminated soils, nevertheless, the long-term effectiveness for the simultaneous immobilization of both cations and oxyanions remains a challenge. In order to effectively enhance the synergistic immobilization effect of soil As and Cd contaminated by multiple elements and improve the ecological environment of farmland. In this study, a typical polluted tailings area farmland was selected for situ immobilization experiments, and biochar was prepared from cow manure (CMB), rice straw (RSB), and pine wood (PWB) as raw materials. On this basis, the pristine biochar was modified with ferric chloride (F), potassium permanganate (K), magnesium chloride (M), and aluminum chloride (A), respectively. Furthermore, the immobilization effect of modified biochar on As-Cd and the stress effect on soil respiration were investigated. The results showed that CMB and RSB reduced the bioavailability of heavy metals, potassium permanganate has strong oxidizing properties, and the strong oxidability of potassium permanganate stimulated the generation of more oxygen-containing functional groups on the surface of biochar, thereby enhancing the adsorption and complexation effect of modified materials on As and Cd. Among them, the extracted Cd concentration of Diethylenetriamine pentaacetic acid (DTPA) in KCMB and KRSB in 2020 decreased by 8.23-43.12% and 9.67-35.29% compared to other treatments, respectively. Meanwhile, the KCMB and KRSB treatments also reduced the enrichment of As and Cd in plant tissues. In addition, the dissolved organic carbon (DOC) content in KCMB treatment was relatively high, and the carbon stability of the material was weakened. Simultaneously, the soil respiration emission of KCMB treatment was increased by 5.63% and 11.93% compared to KRSB and KPWB treatments, respectively. In addition, the structural equation also shows that DOC has a large positive effect on soil respiration. In summary, the KRSB treatment effectively achieve synergistic immobilization of As-Cd and provide important guiding significance for green and low-carbon remediation of polluted farmland.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":null,"pages":null},"PeriodicalIF":8.0,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142387002","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-08DOI: 10.1016/j.jenvman.2024.122742
Zhengyu Wang, Linhai Ye, Feng Chen, Tao Zhou, Youcai Zhao
Sorting out plastic waste (PW) from municipal solid waste (MSW) by material type is crucial for reutilization and pollution reduction. However, current automatic separation methods are costly and inefficient, necessitating an advanced sorting process to ensure high feedstock purity. This study introduces a Swin Transformer-based model for effectively detecting PW in real-world MSW streams, leveraging both morphological and material properties. And, a dataset comprising 3560 optical images and infrared spectra data was created to support this task. This vision-based system can localize and classify PW into five categories: polypropylene (PP), polyethylene (PE), polyethylene terephthalate (PET), polyvinyl chloride (PVC), and polystyrene (PS). Performance evaluations reveal an accuracy rate of 99.75% and a mean Average Precision (mAP50) exceeding 91%. Compared to popular convolutional neural network (CNN)-based models, this well-trained Swin Transformer-based model offers enhanced convenience and performance in five-category PW detection task, maintaining a mAP50 over 80% in the real-life deployment. The model's effectiveness is further supported by visualization of detection results on MSW streams and principal component analysis of classification scores. These results demonstrate the system's significant effectiveness in both lab-scale and real-life conditions, aligning with global regulations and strategies that promote innovative technologies for plastic recycling, thereby contributing to the development of a sustainable circular economy.
{"title":"Multi-category sorting of plastic waste using Swin Transformer: A vision-based approach.","authors":"Zhengyu Wang, Linhai Ye, Feng Chen, Tao Zhou, Youcai Zhao","doi":"10.1016/j.jenvman.2024.122742","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.122742","url":null,"abstract":"<p><p>Sorting out plastic waste (PW) from municipal solid waste (MSW) by material type is crucial for reutilization and pollution reduction. However, current automatic separation methods are costly and inefficient, necessitating an advanced sorting process to ensure high feedstock purity. This study introduces a Swin Transformer-based model for effectively detecting PW in real-world MSW streams, leveraging both morphological and material properties. And, a dataset comprising 3560 optical images and infrared spectra data was created to support this task. This vision-based system can localize and classify PW into five categories: polypropylene (PP), polyethylene (PE), polyethylene terephthalate (PET), polyvinyl chloride (PVC), and polystyrene (PS). Performance evaluations reveal an accuracy rate of 99.75% and a mean Average Precision (mAP<sup>50</sup>) exceeding 91%. Compared to popular convolutional neural network (CNN)-based models, this well-trained Swin Transformer-based model offers enhanced convenience and performance in five-category PW detection task, maintaining a mAP<sup>50</sup> over 80% in the real-life deployment. The model's effectiveness is further supported by visualization of detection results on MSW streams and principal component analysis of classification scores. These results demonstrate the system's significant effectiveness in both lab-scale and real-life conditions, aligning with global regulations and strategies that promote innovative technologies for plastic recycling, thereby contributing to the development of a sustainable circular economy.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":null,"pages":null},"PeriodicalIF":8.0,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142386978","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
With Advanced oxidation processes (AOPs) widely promoted, MnCe-based catalysts have received extensive attention under the advantages of high efficiency, stability and economy for refractory organic pollutants present in urban wastewater. Driven by multiple factors such as environmental pollution, technological development, and policy promotion, a systematic review of MnCe-based catalysts is urgently needed in the current research situation. This research provides a critical review of MnCe-based catalysts for removal of organic pollutants in urban wastewater by AOPs. It is found that co-precipitation and sol-gel methods are more appropriate methods for catalyst preparation. Among a host of influence factors, catalyst composition and pH are crucial in the catalytic oxidation processes. The synergistic effect of the free radical pathway and surface catalysis results in better pollutants degradation. It is more valuable to utilize multiple systems for oxidation (e.g., photo-Fenton technology) to improve the catalytic efficiency. This review provides theoretical guidance for MnCe-based catalysts and offers a reference direction for future research in the AOPs of organic pollutants removal from urban wastewater.
{"title":"MnCe-based catalysts for removal of organic pollutants in urban wastewater by advanced oxidation processes - A critical review.","authors":"Yuting Wang, Jiaqing Wang, Zeqing Long, Zhi Sun, Longyi Lv, Jinsong Liang, Guangming Zhang, Pengfei Wang, Wenfang Gao","doi":"10.1016/j.jenvman.2024.122773","DOIUrl":"https://doi.org/10.1016/j.jenvman.2024.122773","url":null,"abstract":"<p><p>With Advanced oxidation processes (AOPs) widely promoted, MnCe-based catalysts have received extensive attention under the advantages of high efficiency, stability and economy for refractory organic pollutants present in urban wastewater. Driven by multiple factors such as environmental pollution, technological development, and policy promotion, a systematic review of MnCe-based catalysts is urgently needed in the current research situation. This research provides a critical review of MnCe-based catalysts for removal of organic pollutants in urban wastewater by AOPs. It is found that co-precipitation and sol-gel methods are more appropriate methods for catalyst preparation. Among a host of influence factors, catalyst composition and pH are crucial in the catalytic oxidation processes. The synergistic effect of the free radical pathway and surface catalysis results in better pollutants degradation. It is more valuable to utilize multiple systems for oxidation (e.g., photo-Fenton technology) to improve the catalytic efficiency. This review provides theoretical guidance for MnCe-based catalysts and offers a reference direction for future research in the AOPs of organic pollutants removal from urban wastewater.</p>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":null,"pages":null},"PeriodicalIF":8.0,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142398987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}