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Systematic review of various activation methods of sulfate radical precursor for the degradation of PFAS in aquatic environments
IF 8 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-24 DOI: 10.1016/j.jenvman.2025.125409
Mahsa Khalili , Ali Behnami , Khaled Zoroufchi Benis , Hazhar Jalal Ali , Ehsan Aghayani , Ali Abdolahnejad , Mojtaba Pourakbar , Reza Dehghanzadeh

Per

and polyfluoroalkyl substance (PFAS), widely used in industrial production, pose significant environmental and health risks due to their stability and persistence. Recent research has highlighted the potential of sulfate radicals for degrading PFAS through the activation of precursors like peroxymonosulfate (PMS) and persulfate (PS) in oxidation processes. The present study systematically reviews various activation methods and corresponding efficiencies in removing PFAS in thermal, ultrasonic, photochemical, catalytic, and electrochemical processes. The review also explores the impact of pH, temperature, precursor concentration, and co-contaminants, on PFAS degradation efficiency. Additionally, it investigates the degradation mechanisms, including defluorination and carbon-carbon bond cleavage, providing insights into the pathways of PFAS breakdown. Despite the promising results, challenges remain on the potential formation of toxic by-products and the energy demands of activation methods. Addressing these issues may involve developing more efficient catalysts, optimizing conditions, and combining treatment processes. This review offers valuable insights for researchers and practitioners, contributing to the advancement of PFAS remediation strategies and ultimately protecting human health and the environment from these persistent pollutants.
{"title":"Systematic review of various activation methods of sulfate radical precursor for the degradation of PFAS in aquatic environments","authors":"Mahsa Khalili ,&nbsp;Ali Behnami ,&nbsp;Khaled Zoroufchi Benis ,&nbsp;Hazhar Jalal Ali ,&nbsp;Ehsan Aghayani ,&nbsp;Ali Abdolahnejad ,&nbsp;Mojtaba Pourakbar ,&nbsp;Reza Dehghanzadeh","doi":"10.1016/j.jenvman.2025.125409","DOIUrl":"10.1016/j.jenvman.2025.125409","url":null,"abstract":"<div><h3>Per</h3><div>and polyfluoroalkyl substance (PFAS), widely used in industrial production, pose significant environmental and health risks due to their stability and persistence. Recent research has highlighted the potential of sulfate radicals for degrading PFAS through the activation of precursors like peroxymonosulfate (PMS) and persulfate (PS) in oxidation processes. The present study systematically reviews various activation methods and corresponding efficiencies in removing PFAS in thermal, ultrasonic, photochemical, catalytic, and electrochemical processes. The review also explores the impact of pH, temperature, precursor concentration, and co-contaminants, on PFAS degradation efficiency. Additionally, it investigates the degradation mechanisms, including defluorination and carbon-carbon bond cleavage, providing insights into the pathways of PFAS breakdown. Despite the promising results, challenges remain on the potential formation of toxic by-products and the energy demands of activation methods. Addressing these issues may involve developing more efficient catalysts, optimizing conditions, and combining treatment processes. This review offers valuable insights for researchers and practitioners, contributing to the advancement of PFAS remediation strategies and ultimately protecting human health and the environment from these persistent pollutants.</div></div>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"383 ","pages":"Article 125409"},"PeriodicalIF":8.0,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143864490","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Progress in MnO2/MnO2-based materials catalytic ozonation process for water and wastewater treatment
IF 8 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-24 DOI: 10.1016/j.jenvman.2025.125493
Jing Liu , Xiangjuan Yuan , Huiyu Dong , Carmen Sans
Heterogeneous catalytic ozonation (HCO) utilizes catalysts to enhance the adsorption and decomposition of ozone (O3), promote the formation of reactive oxygen species (ROS), and improve the removal of organic compounds, thereby overcoming some disadvantages of ozonation. MnO2/MnO2-based materials are widely used as catalysts for HCO due to their multi-valent Mn species, environment friendliness, abundant resources, and high efficiency. This review aims to provide an overview of the advancements in HCO using MnO2/MnO2-based materials, focusing on their preparation, structural characteristics, catalytic performance, and proposed mechanisms. In particular, the effects of MnO2 synthesis methods on the crystalline structure and morphology of catalysts are discussed. Then, the catalytic performances of various catalysts involving different phases, morphologies, and facets are compared. Subsequently, the enhanced applications of MnO2-based catalysts in HCO for water treatment are described, including metals doping, metal oxides combination, and MnO2-carrier. Furthermore, approaches of ROS identification are clarified, and the mechanisms of strengthening catalytic ozonation efficiency by MnO2/MnO2-based catalysts are summarized, containing redox couple theory, oxygen vacancy theory, complexation theory, and surface hydroxyl theory. Finally, the potential applications and perspectives of MnO2/MnO2-based catalysts are proposed. This review plans to bridge the gap between research and practical applications, providing new insights into the application of HCO technologies in water treatment.
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引用次数: 0
Crystallinity- dependent heteroaggregation and co-sedimentation between polystyrene nanoplastics and iron (hydro)oxides
IF 8 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-23 DOI: 10.1016/j.jenvman.2025.125472
Jingyi He , Pingxiao Wu , Leiye Sun , Jiayan Wu , Tianming Wang , Jieyu Liu , Sheng Liu , Nengwu Zhu
Iron (hydro)oxides (IOs) with different crystallinities are widespread in the aquatic environment. They coexist with nanoplastics (NPs) and tend to interact with each other. The properties of minerals can greatly influence the heteroaggregation of minerals and NPs, being manifested not only in the heteroaggregation capacity but also in the interaction mode. This study investigated the heteroaggregation and co-sedimentation between polystyrene nanoplastics (PSNPs) and IOs with different crystallinity. We found that the zeta potential of IOs increased with rising IOs crystallinity. DLVO calculations indicated stronger electrostatic attraction between negatively-charged NPs and highly-crystalline IOs, resulting in greater heteroaggregation capacity. In addition, the heteroaggregation capacity of PSNPs with IOs declined as the pH value and ion strength increased. The Fourier transform infrared spectra (FTIR) and two-dimensional correlation spectroscopy (2D-COS) analyses indicated that there was strong hydrogen bonding between IOs with high crystallinity and PSNPs, contributing to a greater heteroaggregation capacity of PSNPs on highly-crystalline IOs than low-crystalline IOs. Zeta potential measurements revealed that negatively charged PSNPs heteroaggregated on the surface of positively charged IOs, capable of neutralizing or even reversing the surface charge. This, in turn, affected the sedimentation of IOs-PSNPs agglomerates and their fate. These findings elucidated the key role of crystallinity on the heteroaggregation between IOs and PSNPs, and offered insight into their environmental fate.
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引用次数: 0
Assessing climate change impact of blue ammonia via carbon capture and utilization in life cycle modelling 在生命周期模型中通过碳捕获和利用评估蓝氨对气候变化的影响
IF 8 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-23 DOI: 10.1016/j.jenvman.2025.125438
Mutaz Chahrour, Christina Wulf, Petra Zapp
Ammonia production represents a fundamental aspect of the global chemical industry. It is a significant contributor to carbon dioxide (CO2) emissions, and it is necessary that innovative methods be developed to reduce its climate impact. This study assesses the environmental impact of blue ammonia production incorporating carbon capture and utilization (CCU) through a novel Life Cycle Assessment (LCA) approach, based on the latest guidelines from the Together for Sustainability (TfS) initiative. This analysis is centred on three systems: grey ammonia (System A), blue ammonia with in-process carbon capture (System B), and blue ammonia utilizing system expansion via direct air capture (DAC) (System C). The results demonstrate that the production of grey ammonia in Germany generates 3.12 kgCO2eq per kg of ammonia, predominantly due to emissions from steam methane reforming (SMR). The incorporation of in-process CO2 capture in blue ammonia (System B) results in a climate impact of 1.79 kgCO2eq for the functional unit of 1 kg ammonia plus 1.85 kg of succesfully captured CO2. The implementation of system expansion via DAC (System C), as recommended by the TfS guidelines, results in a further reduction of ammonia emissions to 2.64 kgCO2eq, in comparison to System A. This approach also yields a net negative impact of −0.85 kgCO2eq for the captured CO2 co-product, enabling the realization of the shared incentivization objective articulated in the suggested guideline. The regional scenarios convincingly demonstrate that the proposed approach achieves varying levels of success, often leading to more polarized incentivization. The future scenario will significantly enhance the benefits of CCU and the utilization of CO2 as a co-product. However, this will be at the expense of incentivizing the production of blue ammonia. This work advances the methodologies for LCA of multi-functional CCU systems, demonstrating the potential for shared incentives in the transition to a new ammonia generation system as a prime example. Nonetheless, it also highlights limitations in regions where the energy source is dominated by fossil fuels or where the energy source is fully renewable. The current TfS framework methodology proposition is therefore a short-term solution to promote the sustainable production of blue ammonia with CCU applications.
氨生产是全球化学工业的一个基本方面。它是二氧化碳(CO2)排放的重要来源,因此有必要开发创新方法来减少其对气候的影响。本研究以 "携手实现可持续发展"(TfS)倡议的最新指导方针为基础,通过新颖的生命周期评估(LCA)方法,评估了结合碳捕集与利用(CCU)的蓝色氨生产对环境的影响。该分析以三个系统为中心:灰氨(系统 A)、带过程中碳捕集的蓝氨(系统 B)和通过直接空气捕集(DAC)进行系统扩展的蓝氨(系统 C)。结果表明,在德国生产灰氨每千克氨产生 3.12 千克二氧化碳当量,主要是由于蒸汽甲烷转化(SMR)产生的排放。在蓝色氨水(系统 B)中加入过程中二氧化碳捕集,以 1 千克氨水加 1.85 千克成功捕集的二氧化碳为功能单位,对气候的影响为 1.79 千克 CO2eq。根据 TfS 指南的建议,通过 DAC(系统 C)实施系统扩展,与系统 A 相比,氨的排放量进一步减少至 2.64 kgCO2eq。这种方法还产生了捕获的二氧化碳副产品-0.85 kgCO2eq 的净负面影响,实现了建议指南中阐述的共同激励目标。区域方案令人信服地表明,建议的方法取得了不同程度的成功,往往导致激励措施更加两极分化。未来方案将显著提高 CCU 的效益和二氧化碳作为副产品的利用率。然而,这将以激励蓝氨生产为代价。这项工作推进了多功能 CCU 系统的生命周期评估方法,并以过渡到新型合成氨生产系统为例,展示了共享激励措施的潜力。尽管如此,它也凸显了在能源以化石燃料为主或能源完全可再生的地区的局限性。因此,目前的 TfS 框架方法建议是促进利用 CCU 应用可持续生产蓝色氨的短期解决方案。
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引用次数: 0
Avifaunal communities as indicators of silvicultural impacts in mangrove forests
IF 8 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-23 DOI: 10.1016/j.jenvman.2025.125414
Giovanna Wolswijk , Tom Bernard , Jani Sleutel , Lea Fourchault , Jean Hugé , Behara Satyanarayana , Farid Dahdouh-Guebas
Although the Matang Mangrove Forest Reserve (MMFR) in Malaysia is suggested to be a global reference for sustainable silviculture, the impact of greenwood extraction on local biodiversity and ecological functionality remains under-researched. To fill this gap, a rapid biodiversity assessment was conducted using birds as ecological indicators to investigate the effect of mangrove silvicultural management on avian communities. Changes in the diversity of bird species and dietary guilds in response to forest age and management were assessed using the point-count method with visual and auditory observations. This was done in both “productive” forests, consisting of even-aged Rhizophora plantations producing poles and charcoal, and in “protective” forests where extractive activities are prohibited. Remarkably, all avifaunal functional guilds were present in both young “productive” and “protective” forests, however the “productive” forests supported fewer bird assemblages in terms of species richness and total taxonomic diversity compared to the floristically rich and structurally complex “protective” forests. The bird species’ response to silvicultural disturbances also varied, with adverse effects especially occurring in functionally specialized species. Furthermore, back mangroves and transition zones to terrestrial forests were found to support a higher avifaunal diversity, possibly because of the enhanced habitat heterogeneity. Finally, this study highlights the use of bird communities as ecological indicators for assessing the quality of mangrove forests, and emphasises the crucial role of habitat and landscape heterogeneity in supporting diverse avifauna and ecosystem functionality highlighting the need for more research integrating mangroves and adjacent ecosystems.
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引用次数: 0
How a research community constructs and uses naturalness: A case study of the 2023 Lookout Fire and the H.J. Andrews Experimental Forest in Oregon, USA
IF 8 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-23 DOI: 10.1016/j.jenvman.2025.125467
Claire Rapp , Michael Paul Nelson
Wildfire severity is increasing in the western United States. Simultaneously, many recognize that fire is a natural process and advocate for learning to live with fire. Indeed, the naturalness of fire can be an important reason provided to increase the amount of fire on a landscape. However, “naturalness” can be interpreted in incommensurate ways, such as the historic range of variability of a system or the absence of human influence. What makes wildfires feel natural or unnatural to the people who experience them, and how naturalness affects reactions to wildfires is underexplored. Using social representations theory, we examine the 2023 Lookout Fire at the H. J. Andrews Experimental Forest (HJA). We use semi-structured interviews (n = 40) to explore how the research community associated with the HJA mentally constructs and uses naturalness to emotionally process and make meaning from the wildfire. We find even in a community with advanced training in ecology, respondents use a variety of metrics to determine naturalness, including ignition source, fire behavior, and pre-fire landscape characteristics and fire history. Respondents consider a variety of factors, and there was not consensus on whether the Lookout Fire was a “natural” fire. In general, respondents who described the fire as more natural were able to come to a state of acceptance and excitement for future research opportunities sooner than respondents who described the fire as largely unnatural. This has important implications for wildfire risk communication for scientists and practitioners who want to restore fire as a natural process. While fires perceived (or framed) as natural may be more readily accepted, fires perceived as unnatural may take longer to process. Fires perceived as human-caused and especially as climate-exacerbated may be the most difficult for people to process after and during the fire, and may have the most resistance for being managed for purposes other than full suppression.
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引用次数: 0
Multiscale investigation of hydrate pore habits and microscopic seepage mechanisms for optimizing CO2 storage in high-porosity sediments
IF 8 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-23 DOI: 10.1016/j.jenvman.2025.125513
Chao Lyu , Wenyu Lyu , Qiang Sun , Yongping Wu , Panshi Xie , Guoliang Li , Hailiang Jia , Yun Wu
Hydrate-based CO2 storage (HBCS) has emerged as a promising approach within carbon capture and storage (CCS) technologies, offering a potential pathway for mitigating CO2 emissions. The permeability of hydrate-bearing sediments (HBSs) is crucial for predicting the feasibility of HBCS, yet the seepage mechanisms become quite complex during the formation or dissociation of hydrates. The objective of this paper is to investigate the hydrate pore habits and the evolution of key physical properties at both macroscopic and microscopic scales, utilizing an integrated set of methodologies such as CT scan, nuclear magnetic resonance and ultrasonic pulse methods, and present a theoretical equation that correlates P-wave velocity with permeability for HBSs. The results indicate that the theoretical equation effectively explains the correlation between P-wave velocity and permeability. Formations with a lower initial water saturation and a higher proportion of type Ⅱ pores (ranging from 0.1 to 200 μm) were found to promote high-efficiency CO2 storage. During CO2 hydrate formation, the pore structure becomes progressively more complex, and hydrates are initially formed in the pore center at saturations around 0–10 %. The occurrence pattern transitions from a pore-filling pattern to a grain-coating pattern as hydrate saturation increases. The theoretical equation relating P-wave velocity to permeability is useful for assessing the permeability of HBSs. These findings provide valuable insights into HBCS in porous media and contribute to the selection of potential CO2 storage sites.
{"title":"Multiscale investigation of hydrate pore habits and microscopic seepage mechanisms for optimizing CO2 storage in high-porosity sediments","authors":"Chao Lyu ,&nbsp;Wenyu Lyu ,&nbsp;Qiang Sun ,&nbsp;Yongping Wu ,&nbsp;Panshi Xie ,&nbsp;Guoliang Li ,&nbsp;Hailiang Jia ,&nbsp;Yun Wu","doi":"10.1016/j.jenvman.2025.125513","DOIUrl":"10.1016/j.jenvman.2025.125513","url":null,"abstract":"<div><div>Hydrate-based CO<sub>2</sub> storage (HBCS) has emerged as a promising approach within carbon capture and storage (CCS) technologies, offering a potential pathway for mitigating CO<sub>2</sub> emissions. The permeability of hydrate-bearing sediments (HBSs) is crucial for predicting the feasibility of HBCS, yet the seepage mechanisms become quite complex during the formation or dissociation of hydrates. The objective of this paper is to investigate the hydrate pore habits and the evolution of key physical properties at both macroscopic and microscopic scales, utilizing an integrated set of methodologies such as CT scan, nuclear magnetic resonance and ultrasonic pulse methods, and present a theoretical equation that correlates P-wave velocity with permeability for HBSs. The results indicate that the theoretical equation effectively explains the correlation between P-wave velocity and permeability. Formations with a lower initial water saturation and a higher proportion of type Ⅱ pores (ranging from 0.1 to 200 μm) were found to promote high-efficiency CO<sub>2</sub> storage. During CO<sub>2</sub> hydrate formation, the pore structure becomes progressively more complex, and hydrates are initially formed in the pore center at saturations around 0–10 %. The occurrence pattern transitions from a pore-filling pattern to a grain-coating pattern as hydrate saturation increases. The theoretical equation relating P-wave velocity to permeability is useful for assessing the permeability of HBSs. These findings provide valuable insights into HBCS in porous media and contribute to the selection of potential CO<sub>2</sub> storage sites.</div></div>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"383 ","pages":"Article 125513"},"PeriodicalIF":8.0,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143859532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Translocating deadwood in ecological compensation benefits saproxylic beetles, but effects are dependent on substrate density
IF 8 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-23 DOI: 10.1016/j.jenvman.2025.125448
Olov Tranberg , Therese Löfroth , Anne-Maarit Hekkala , Mari Jönsson , Timothy Work , Heloise Gibb , Lukas Holmström , Jörgen Sjögren , Joakim Hjältén
Ecological compensation is increasingly used to offset habitat and biodiversity loss resulting from changes in land use, large infrastructure projects (e.g., roads and railroads) or industrial expansions (e.g., mines, harbours), but the effectiveness of specific compensation strategies remain largely untested. When old-growth forest ecosystems are impacted by such projects, designated compensation areas may also require additional restoration or habitat enrichment. For organisms that rely on habitats that require decades to develop, such as advanced decayed wood, restoration will require novel approaches. We tested whether translocation of deadwood of various decay stages and large dimensions enhance saproxylic beetle communities within compensation areas in a large boreal forest landscape in Sweden. Experimental plots (50 m in diameter) within the compensation zone were enriched with 0, 16, or 48 deadwood substrates. We collected beetles using flight intercept traps prior to translocation and again 1 and 4 years after translocation and compared species richness, abundance and assemblage composition across treatment and over time. We showed that translocation of relatively high densities of deadwood (48 substrates per plot) increased species richness of saproxylic beetles. Increased beetle richness could have occurred from direct transport of beetles in experimental substrates and/or through attraction of beetles to the translocated substrates. Our results indicate that translocation of deadwood can serve as an important tool in ecological compensation and restoration if sufficient amounts of deadwood are translocated. While promising, the long-term success of restoring saproxylic biodiversity through translocation of deadwood depends on whether translocated substrates continue to provide suitable habitat for beetles over time and whether benefits for biodiversity can be enhanced through targeted translocation of specific combinations of deadwood.
{"title":"Translocating deadwood in ecological compensation benefits saproxylic beetles, but effects are dependent on substrate density","authors":"Olov Tranberg ,&nbsp;Therese Löfroth ,&nbsp;Anne-Maarit Hekkala ,&nbsp;Mari Jönsson ,&nbsp;Timothy Work ,&nbsp;Heloise Gibb ,&nbsp;Lukas Holmström ,&nbsp;Jörgen Sjögren ,&nbsp;Joakim Hjältén","doi":"10.1016/j.jenvman.2025.125448","DOIUrl":"10.1016/j.jenvman.2025.125448","url":null,"abstract":"<div><div>Ecological compensation is increasingly used to offset habitat and biodiversity loss resulting from changes in land use, large infrastructure projects (e.g., roads and railroads) or industrial expansions (e.g., mines, harbours), but the effectiveness of specific compensation strategies remain largely untested. When old-growth forest ecosystems are impacted by such projects, designated compensation areas may also require additional restoration or habitat enrichment. For organisms that rely on habitats that require decades to develop, such as advanced decayed wood, restoration will require novel approaches. We tested whether translocation of deadwood of various decay stages and large dimensions enhance saproxylic beetle communities within compensation areas in a large boreal forest landscape in Sweden. Experimental plots (50 m in diameter) within the compensation zone were enriched with 0, 16, or 48 deadwood substrates. We collected beetles using flight intercept traps prior to translocation and again 1 and 4 years after translocation and compared species richness, abundance and assemblage composition across treatment and over time. We showed that translocation of relatively high densities of deadwood (48 substrates per plot) increased species richness of saproxylic beetles. Increased beetle richness could have occurred from direct transport of beetles in experimental substrates and/or through attraction of beetles to the translocated substrates. Our results indicate that translocation of deadwood can serve as an important tool in ecological compensation and restoration if sufficient amounts of deadwood are translocated. While promising, the long-term success of restoring saproxylic biodiversity through translocation of deadwood depends on whether translocated substrates continue to provide suitable habitat for beetles over time and whether benefits for biodiversity can be enhanced through targeted translocation of specific combinations of deadwood.</div></div>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"383 ","pages":"Article 125448"},"PeriodicalIF":8.0,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143859643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correlations between catchment-scale farm infrastructure densities and stocking rate to stream nutrient concentrations in dairy-dominant catchments
IF 8 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-23 DOI: 10.1016/j.jenvman.2025.125431
Jonah Lee Bas , Andrew W. Western , Robert Sargent , Wei Wen Wong , Perran Cook , Anna Lintern
Nitrogen and phosphorus pollution is a critical environmental issue that causes eutrophication of water bodies. High concentrations of these nutrients primarily come from agricultural areas and are driven by catchment characteristics such as climate, hydrology, topography, geology, land use, and land cover. In addition to these factors, specific farming practices – particularly, the use of dairy farm infrastructure and management of stocking rate – also influence stream nutrient concentrations. However, the extent of the influence of specific farming practices and their relative importance in determining nutrient concentrations in waterways remain unknown. In this paper, we used data from an agriculturally-intensive dairy farming region to investigate these relationships. We used statistical analyses and modelling to determine relationships between concentrations of ammonium (NH4+), filterable reactive phosphorus (FRP), nitrogen oxides (NOx), total phosphorus (TP), and total nitrogen (TN) with 26 predictors which include farm infrastructure density and stocking rate. We found that farm infrastructure and operational characteristics such as effluent pond density, dairy shed density, and stocking rate are consistently important predictors that influence concentrations of NH4+, FRP, NOx, TP, and TN during both wet and dry weather periods. This paper has shown that in addition to established factors such as land use and land cover, specific farming practices also play a role in influencing stream nutrient concentrations. By identifying key infrastructure and stocking rate as drivers of stream nutrient concentrations, this research emphasized the need for targeted management strategies to mitigate the impacts of agricultural activities on water quality.
{"title":"Correlations between catchment-scale farm infrastructure densities and stocking rate to stream nutrient concentrations in dairy-dominant catchments","authors":"Jonah Lee Bas ,&nbsp;Andrew W. Western ,&nbsp;Robert Sargent ,&nbsp;Wei Wen Wong ,&nbsp;Perran Cook ,&nbsp;Anna Lintern","doi":"10.1016/j.jenvman.2025.125431","DOIUrl":"10.1016/j.jenvman.2025.125431","url":null,"abstract":"<div><div>Nitrogen and phosphorus pollution is a critical environmental issue that causes eutrophication of water bodies. High concentrations of these nutrients primarily come from agricultural areas and are driven by catchment characteristics such as climate, hydrology, topography, geology, land use, and land cover. In addition to these factors, specific farming practices – particularly, the use of dairy farm infrastructure and management of stocking rate – also influence stream nutrient concentrations. However, the extent of the influence of specific farming practices and their relative importance in determining nutrient concentrations in waterways remain unknown. In this paper, we used data from an agriculturally-intensive dairy farming region to investigate these relationships. We used statistical analyses and modelling to determine relationships between concentrations of ammonium (NH<sub>4</sub><sup>+</sup>), filterable reactive phosphorus (FRP), nitrogen oxides (NOx), total phosphorus (TP), and total nitrogen (TN) with 26 predictors which include farm infrastructure density and stocking rate. We found that farm infrastructure and operational characteristics such as effluent pond density, dairy shed density, and stocking rate are consistently important predictors that influence concentrations of NH<sub>4</sub><sup>+</sup>, FRP, NOx, TP, and TN during both wet and dry weather periods. This paper has shown that in addition to established factors such as land use and land cover, specific farming practices also play a role in influencing stream nutrient concentrations. By identifying key infrastructure and stocking rate as drivers of stream nutrient concentrations, this research emphasized the need for targeted management strategies to mitigate the impacts of agricultural activities on water quality.</div></div>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"383 ","pages":"Article 125431"},"PeriodicalIF":8.0,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143864390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Deep learning-based spatial optimization of green and cool roof implementation for urban heat mitigation
IF 8 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-04-23 DOI: 10.1016/j.jenvman.2025.125398
JiHyun Kim , Suyeon Choi , Mahdi Panahi , Dan Li , Yeonjoo Kim
Intensifying urban heat extremes require efficient mitigation strategies; therefore, we propose a methodological framework for optimizing the implementation of urban green and cool roofs to reduce heat stress while maximizing their cost-effectiveness. In particular, we develop a surrogate model based on the deep learning algorithm Multi-ResNet, which is trained on data generated by the physically-based Weather Research and Forecasting model coupled with an urban canopy model (WRF-UCM). We applied this framework to the Greater Seoul region under the SSP585 climate scenario for 2090–2099 with projected 2100 land cover and evaluated 262,144 scenarios for cool and green roof allocation across 379 urban grids. Our results showed that, at the current cost of green roofs, the Pareto optimal scenario involves implementing cool roofs over 89.2 % of urban areas. This scenario would reduce the total effective heat stress index by 8.8 % compared to the business-as-usual scenario while decreasing costs by 19.6 %. We identified an optimal cost range of 117.4–146.1 $/m over 40 years for green roofs to become cost-effective and more widely adopted. Our approach demonstrates the potential of deep learning techniques to provide efficient quantitative assessments with lower computational demands (from 3561 h with the WRF-UCM to 72 h), potentially supporting climate-resilient urban building planning.
日益加剧的城市极端热量需要高效的缓解策略;因此,我们提出了一个方法框架,用于优化城市绿色凉爽屋顶的实施,以减少热应力,同时最大限度地提高其成本效益。特别是,我们开发了一个基于深度学习算法 Multi-ResNet 的替代模型,该模型是在基于物理的天气研究和预测模型与城市冠层模型(WRF-UCM)结合生成的数据基础上训练而成的。我们将该框架应用于 2090-2099 年 SSP585 气候情景下的大首尔地区,并预测了 2100 年的土地覆盖情况,评估了 379 个城市网格中 262,144 种凉爽屋顶和绿色屋顶的分配方案。结果表明,按照目前的屋顶绿化成本,帕累托最优方案是在 89.2% 的城市区域实施凉爽屋顶。与 "一切照旧 "方案相比,该方案可将总有效热应力指数降低 8.8%,同时将成本降低 19.6%。我们确定了 40 年内 117.4-146.1 美元/米的最佳成本范围,从而使屋顶绿化具有成本效益并得到更广泛的采用。我们的方法证明了深度学习技术的潜力,它能以更低的计算需求(从 WRF-UCM 的 3561 小时降至 72 小时)提供高效的定量评估,从而为具有气候适应能力的城市建筑规划提供潜在支持。
{"title":"Deep learning-based spatial optimization of green and cool roof implementation for urban heat mitigation","authors":"JiHyun Kim ,&nbsp;Suyeon Choi ,&nbsp;Mahdi Panahi ,&nbsp;Dan Li ,&nbsp;Yeonjoo Kim","doi":"10.1016/j.jenvman.2025.125398","DOIUrl":"10.1016/j.jenvman.2025.125398","url":null,"abstract":"<div><div>Intensifying urban heat extremes require efficient mitigation strategies; therefore, we propose a methodological framework for optimizing the implementation of urban green and cool roofs to reduce heat stress while maximizing their cost-effectiveness. In particular, we develop a surrogate model based on the deep learning algorithm Multi-ResNet, which is trained on data generated by the physically-based Weather Research and Forecasting model coupled with an urban canopy model (WRF-UCM). We applied this framework to the Greater Seoul region under the SSP585 climate scenario for 2090–2099 with projected 2100 land cover and evaluated 262,144 scenarios for cool and green roof allocation across 379 urban grids. Our results showed that, at the current cost of green roofs, the Pareto optimal scenario involves implementing cool roofs over 89.2 % of urban areas. This scenario would reduce the total effective heat stress index by 8.8 % compared to the business-as-usual scenario while decreasing costs by 19.6 %. We identified an optimal cost range of 117.4–146.1 $/m over 40 years for green roofs to become cost-effective and more widely adopted. Our approach demonstrates the potential of deep learning techniques to provide efficient quantitative assessments with lower computational demands (from 3561 h with the WRF-UCM to 72 h), potentially supporting climate-resilient urban building planning.</div></div>","PeriodicalId":356,"journal":{"name":"Journal of Environmental Management","volume":"383 ","pages":"Article 125398"},"PeriodicalIF":8.0,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143859642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Journal of Environmental Management
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