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Magnetic and magnetocaloric properties of polycrystalline Pr0.3Gd0.3Ca0.4MnO3 compound 多晶Pr0.3Gd0.3Ca0.4MnO3化合物的磁性和磁热性
IF 3 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-15 Epub Date: 2026-02-05 DOI: 10.1016/j.jmmm.2026.173905
Rishav De , Dipak Mazumdar , Amanulla Karikar , Kalipada Das , I. Das
We report a comprehensive study of the magnetic and magnetocaloric properties of polycrystalline Pr0.3Gd0.3Ca0.4MnO3, a rare-earth mixed manganite synthesized via the sol–gel method. Temperature-dependent magnetization data reveal an antiferromagnetic (AFM) transition near T100  K, followed by the emergence of a ferrimagnetic-like state below T50  K, without any apparent charge ordering up to 300 K. Isothermal magnetization and Arrott plot analyses confirm a second-order-like magnetic phase transition. The magnetic entropy change (ΔS), derived from isothermal MH curves, shows a broad peak around 100 K corresponding to the AFM transition, and a sharp increase below 50 K, reaching a maximum of approximately 5.9 J kg−1 K−1 at T=7.5  K for ΔH=070 kOe. A power-law analysis reveals that the exponent n in the relation ΔSMHn remains nearly constant (n1.8) over a wide temperature and field range, indicating field- and temperature-independent magnetocaloric behavior. This behavior enabled the successful construction of a universal master curve of ΔS without rescaling the temperature axis. The collapse of entropy curves under high magnetic fields further supports the presence of inverse magnetocaloric-like universal scaling, despite the system exhibiting conventional MCE features. These findings highlight the role of rare-earth site disorder in stabilizing complex spin states and enhancing low-temperature magnetocaloric performance.
研究了溶胶-凝胶法制备的稀土混合锰矿多晶Pr0.3Gd0.3Ca0.4MnO3的磁性和磁热性。温度相关的磁化数据显示,在T≈100 K附近出现反铁磁(AFM)跃迁,随后在T≈50 K以下出现类铁磁态,在300 K以下没有任何明显的电荷有序。等温磁化和Arrott图分析证实了二阶磁相变。从等温M-H曲线得到的磁熵变化(−ΔS)显示,在100 K左右出现一个宽峰,对应于AFM转变,在50 K以下急剧增加,在T=7.5 K时达到最大值,约为5.9 J kg−1 K−1,ΔH= 0-70 kOe。幂律分析表明,在较宽的温度和场范围内,关系ΔSM∝Hn中的指数n几乎保持恒定(n≈1.8),表明与场和温度无关的磁热行为。这种行为使−ΔS的通用主曲线的成功构建没有重新缩放温度轴。在高磁场下熵曲线的坍缩进一步支持了逆类磁热的普遍标度的存在,尽管系统表现出传统的MCE特征。这些发现突出了稀土位点无序在稳定复杂自旋态和增强低温磁热性能方面的作用。
{"title":"Magnetic and magnetocaloric properties of polycrystalline Pr0.3Gd0.3Ca0.4MnO3 compound","authors":"Rishav De ,&nbsp;Dipak Mazumdar ,&nbsp;Amanulla Karikar ,&nbsp;Kalipada Das ,&nbsp;I. Das","doi":"10.1016/j.jmmm.2026.173905","DOIUrl":"10.1016/j.jmmm.2026.173905","url":null,"abstract":"<div><div>We report a comprehensive study of the magnetic and magnetocaloric properties of polycrystalline Pr<sub>0.3</sub>Gd<sub>0.3</sub>Ca<sub>0.4</sub>MnO<span><math><msub><mrow></mrow><mrow><mn>3</mn></mrow></msub></math></span>, a rare-earth mixed manganite synthesized via the sol–gel method. Temperature-dependent magnetization data reveal an antiferromagnetic (AFM) transition near <span><math><mrow><mi>T</mi><mo>≈</mo><mn>100</mn></mrow></math></span> <!--> <!-->K, followed by the emergence of a ferrimagnetic-like state below <span><math><mrow><mi>T</mi><mo>≈</mo><mn>50</mn></mrow></math></span> <!--> <!-->K, without any apparent charge ordering up to 300<!--> <!-->K. Isothermal magnetization and Arrott plot analyses confirm a second-order-like magnetic phase transition. The magnetic entropy change (<span><math><mrow><mo>−</mo><mi>Δ</mi><mi>S</mi></mrow></math></span>), derived from isothermal <span><math><mi>M</mi></math></span>–<span><math><mi>H</mi></math></span> curves, shows a broad peak around 100 K corresponding to the AFM transition, and a sharp increase below 50 K, reaching a maximum of approximately 5.9<!--> <!-->J<!--> <!-->kg<sup>−1</sup> <!-->K<sup>−1</sup> at <span><math><mrow><mi>T</mi><mo>=</mo><mn>7</mn><mo>.</mo><mn>5</mn></mrow></math></span> <!--> <!-->K for <span><math><mrow><mi>Δ</mi><mi>H</mi><mo>=</mo><mn>0</mn><mtext>–</mtext><mn>70</mn></mrow></math></span> kOe. A power-law analysis reveals that the exponent <span><math><mi>n</mi></math></span> in the relation <span><math><mrow><mi>Δ</mi><msub><mrow><mi>S</mi></mrow><mrow><mi>M</mi></mrow></msub><mo>∝</mo><msup><mrow><mi>H</mi></mrow><mrow><mi>n</mi></mrow></msup></mrow></math></span> remains nearly constant (<span><math><mrow><mi>n</mi><mo>≈</mo><mn>1</mn><mo>.</mo><mn>8</mn></mrow></math></span>) over a wide temperature and field range, indicating field- and temperature-independent magnetocaloric behavior. This behavior enabled the successful construction of a universal master curve of <span><math><mrow><mo>−</mo><mi>Δ</mi><mi>S</mi></mrow></math></span> without rescaling the temperature axis. The collapse of entropy curves under high magnetic fields further supports the presence of inverse magnetocaloric-like universal scaling, despite the system exhibiting conventional MCE features. These findings highlight the role of rare-earth site disorder in stabilizing complex spin states and enhancing low-temperature magnetocaloric performance.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"642 ","pages":"Article 173905"},"PeriodicalIF":3.0,"publicationDate":"2026-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185898","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Relation between magnetic and magnetocaloric properties near the phase transition point in the LaFe11.1Mn0.1Co0.7Si1.1 alloy LaFe11.1Mn0.1Co0.7Si1.1合金相变点附近磁性能与磁热能的关系
IF 3 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-15 Epub Date: 2026-01-24 DOI: 10.1016/j.jmmm.2026.173865
Adler Gamzatov , Petr Igoshev , Nurizhat Abdulkadirova , Anvar Kadirbardeev
The results of measurements of magnetization, magnetostriction and magnetocaloric effect and their correlation analysis near the critical temperature TC of the ferromagnet–paramagnet phase transition of the LaFe11.1Mn0.1Co0.7Si1.1 alloy are presented. In finite magnetic field the character of magnetization M dependence of magnetostriction λ exhibits strong temperature dependence in the vicinity of critical temperature TC: in the vicinity of critical temperature T = TC standard quadratic dependence of λ(M) is insufficient to explain experimental data, instead we find λ = AM2 + BM4, in a qualitative agreement with the self-consistent spin renormalization theory by Moriya and Takahashi, where A and B are temperature dependent coefficients and A vanishes near critical temperature but not exactly at T = TC. Correlation analysis of temperature dependences of magnetocaloric effect ΔSM and longitudinal magnetostriction λ|| showed that in magnetic fields of 18, 40 and 80 kOe near ТС a linear relationship is observed between ΔSM and λ||, ΔSM = - κλ||, with proportionality coefficient κ=9.52⋅103 J/kg K. Within the framework of the Heisenberg model taking into account magnetostriction the value of proportionality coefficient between ΔSM and λ|| is estimated.
给出了LaFe11.1Mn0.1Co0.7Si1.1合金铁磁-顺磁相变临界温度TC附近磁化、磁致伸缩和磁热效应的测量结果及其相关性分析。在有限磁场中,磁致伸缩λ的磁化强度M依赖性在临界温度TC附近表现出强烈的温度依赖性;在临界温度T = TC附近,λ(M)的标准二次依赖关系不足以解释实验数据,相反,我们发现λ = AM2 + BM4,在定性上与Moriya和Takahashi的自洽自旋重整化理论一致,其中a和B是温度相关系数,a在临界温度附近消失,但在T = TC不完全消失。磁热效应ΔSM与纵向磁致伸缩λ||温度依赖性的相关分析表明,在ТС附近18、40和80 kOe的磁场中,ΔSM与λ||呈线性关系,ΔSM = - κλ||,比例系数κ=9.52⋅103 J/kg k。在考虑磁致伸缩的Heisenberg模型框架内,估计了ΔSM与λ||之间的比例系数值。
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引用次数: 0
Ad hoc approach for identifying permeability tensors for numerical simulation of grain-oriented electrical steels 晶粒取向电工钢数值模拟中磁导率张量识别的特殊方法
IF 3 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-15 Epub Date: 2026-01-16 DOI: 10.1016/j.jmmm.2026.173845
O. Messal, A. Benabou
In this article, an ad hoc method to identify adequate full permeability tensors of grain oriented electrical steels (GOES) is proposed for implementation in finite element method (FEM) simulation. The tensors are obtained from dedicated measurements requiring only unidirectional excitation field. This method relies, on the one hand, on Enokizono's approach which was originally established based on measurements under rotating field and, on the other hand, on Fiorillo's model of magnetization processes in GOES. The derived full permeability tensors have been tested for different angle orientations of applied field to the rolling direction. The identified tensors have been used in a 3D FEM simulation of the Epstein frame and the results have been compared to experimental measurements. The proposed approach demonstrates a potential advantage over a conventional diagonal tensor-based approach, based on the results presented.
本文提出了一种识别晶粒取向电工钢(GOES)充分全磁导率张量的特殊方法,用于有限元模拟。张量是由只需要单向激励场的专用测量得到的。该方法一方面依赖于Enokizono的方法,该方法最初是基于旋转场下的测量而建立的,另一方面依赖于Fiorillo的GOES磁化过程模型。推导出的全磁导率张量在外加磁场与滚动方向的不同角度下进行了测试。所识别的张量已用于Epstein框架的三维有限元模拟,并与实验测量结果进行了比较。根据提出的结果,提出的方法比传统的基于对角张量的方法具有潜在的优势。
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引用次数: 0
A first-principles study of bcc chromium beyond the generalized gradient approximation (GGA) 超越广义梯度近似(GGA)的bcc铬第一性原理研究
IF 3 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-15 Epub Date: 2026-01-22 DOI: 10.1016/j.jmmm.2026.173847
Alma Partos , Igor Di Marco , Shivalika Sharma
The study of magnetism in transition metals is a cornerstone in understanding complex electronic and magnetic interactions in condensed matter systems. Among transition metal elements, body-centered cubic (bcc) chromium stands out because of its spin-density wave (SDW) ground state, posing a long-standing challenge for density functional theory (DFT). Conventional functionals, such as the generalized-gradient approximation (GGA) and the local-density approximation (LDA), fail to predict this experimentally observed incommensurate SDW as the ground state. In this study, we present a comprehensive DFT analysis of bcc Cr employing GGA and a variety of meta-GGA functionals. We evaluated total energies, structural parameters, and magnetic properties across a wide range of SDW wave vectors. Our results show that all meta-GGA functionals overestimate the local magnetic moments and enhance the nodal magnetic frustration, destabilizing the SDW state relative to the commensurate antiferromagnetic (AF) configuration. Tao–Perdew–Staroverov–Scuseria (TPSS) yields results closest to those of the GGA, thus providing the most adequate description of bcc Cr among the meta-GGA functionals. These results emphasize the need for the further development of non-local or hybrid functionals tailored for complex magnetic systems.
过渡金属的磁性研究是理解凝聚态体系中复杂的电子和磁性相互作用的基石。在过渡金属元素中,体心立方(bcc)铬因其自旋密度波(SDW)基态而脱颖而出,这对密度泛函理论(DFT)提出了长期的挑战。传统的泛函,如广义梯度近似(GGA)和局部密度近似(LDA),不能预测这种实验观察到的不相称的SDW作为基态。在这项研究中,我们采用GGA和各种元GGA功能对bcc Cr进行了全面的DFT分析。我们在大范围的SDW波矢量上评估了总能量、结构参数和磁性。我们的研究结果表明,所有的meta-GGA泛函数都高估了局部磁矩,增强了节点磁挫败,相对于相应的反铁磁(AF)结构,破坏了SDW状态的稳定。Tao-Perdew-Staroverov-Scuseria (TPSS)的结果与GGA的结果最接近,从而提供了meta-GGA中bcc Cr最充分的描述。这些结果强调需要进一步开发适合复杂磁系统的非局部或混合泛函。
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引用次数: 0
Spin-transfer switching at ambient temperature in an antiferromagnetically coupled two-macrospin model system 反铁磁耦合双自旋模型系统室温下的自旋转移开关
IF 3 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-15 Epub Date: 2026-02-09 DOI: 10.1016/j.jmmm.2026.173923
J.Z. Sun
Spin-torque switching of nanomagnets in tunnel junction based random access memory requires understanding of finite temperature statistics beyond simple macrospin-limit. The next simplest model beyond macrospin is a two-macrospin coupled system. We extend an earlier two-moment finite temperature study to a two-moment antiferromagnetically coupled model system. In a limited region of spin-current, antiferromagnetic coupling allows for faster spin-torque switching at lower threshold spin-current compared to the same moments coupled ferromagnetically. However, spin-torque switching in antiferromagnetically coupled case is more complex. There is only a narrow window in spin-current for reliable switching. At higher spin-current, a 2nd instability threshold emerges, above which the switching error-rate rises. This is associated with the forced alignment towards spin-polarization direction for both moments under spin-torque, due to precession induced dynamic coupling between the two moments. It results in occupation of higher energy intermediate states under spin-torque, resembling a pumped spin system’s “negative temperature”-like state-population inversion. These moment-near-parallel intermediate states upon spin-torque withdrawal relax back into antiferromagnetic alignment with a finite probability of settling into the “wrong” moment orientations. We discuss this behavior through finite temperature numerical modeling and by comparing numerical results with analytical estimates of linear instability thresholds. This simple model demonstrates the importance of internal degrees of freedom in coupled magnetic moment systems under spin-torque, especially in antiferromagnetic or non-collinear configurations. For fast switching speeds well below 10 ns to reach deep write-error floors, it may require higher exchange strength than demonstrated so far.
基于隧道结随机存取存储器的纳米磁体自旋转矩开关需要理解有限温度统计,而不是简单的宏自旋限制。下一个最简单的模型是双宏观自旋耦合系统。我们将先前的两矩有限温度研究扩展到两矩反铁磁耦合模型系统。在自旋电流的有限区域内,与铁磁耦合的相同力矩相比,反铁磁耦合允许在较低阈值自旋电流下更快地进行自旋转矩转换。然而,反铁磁耦合情况下的自旋转矩切换更为复杂。为了实现可靠的开关,自旋电流只有一个很窄的窗口。在较高的自旋电流下,出现了第2个不稳定阈值,超过该阈值开关错误率上升。这与在自旋力矩作用下,由于进动诱导的两个力矩之间的动态耦合,两个力矩被迫向自旋极化方向对齐有关。它导致在自旋扭矩作用下占据高能中间态,类似于泵浦自旋系统的“负温度”态-居数反转。这些力矩接近平行的中间状态在自旋力矩退出后放松回反铁磁排列,并有有限的概率陷入“错误”的力矩方向。我们通过有限温度数值模拟和比较数值结果与线性不稳定阈值的分析估计来讨论这种行为。这个简单的模型证明了内部自由度在自旋力矩耦合磁矩系统中的重要性,特别是在反铁磁或非共线结构中。对于远低于10ns的快速开关速度,以达到深度写入错误层,可能需要比目前所展示的更高的交换强度。
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引用次数: 0
Spin wave focusing and reconfigurable routing in a magnetic nanodot array 磁纳米点阵列中的自旋波聚焦与可重构布线
IF 3 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-15 Epub Date: 2026-02-05 DOI: 10.1016/j.jmmm.2026.173901
Zhang-lin Zhu , Zhi-wu Xie , Qiang Fu, Ying-jie Qin, Lu-lu Zeng, Zhi-xiong Li, Guang-hua Guo, Xi-guang Wang
We proposed and theoretically demonstrated a spin-wave (SW) focusing based on a periodic ferromagnetic nanodot array. By exploiting the periodic anisotropic dispersion and the resulting SW caustics, the array concentrates propagating SW power and injects it into an attached nanostripe waveguide. Micromagnetic simulations reveal that the SW caustics generate a pronounced SW focus region in the sub-micrometer scale. The focal position and frequency are tunable via the nanodot geometric shape and external bias magnetic fields. Attaching a narrow nanostripe to the focal region, the concentrated SW is efficiently coupled into the stripe and excites guided SW mode. Furthermore, by transversely shifting the focal point via a bias field, we selectively route SW to different attached nanostripes and even entirely suppress the injection, without modifying the structure. Our results enable sub-micrometer SW focusing, efficient injection, and dynamically reconfigurable multi-port routing within a compact nanodot array platform.
我们提出并从理论上证明了一种基于周期性铁磁纳米点阵列的自旋波聚焦。通过利用周期性各向异性色散和由此产生的SW焦散,该阵列将传播的SW功率集中并注入到附加的纳米条纹波导中。微磁模拟结果表明,在亚微米尺度下,SW焦散产生了明显的SW聚焦区。通过纳米点的几何形状和外部偏置磁场可调节焦点位置和频率。在聚焦区域上附着一个窄的纳米条纹,集中的微波有效地耦合到条纹中,激发引导微波模式。此外,通过偏压场横向移动焦点,我们选择性地将SW引入不同的附着纳米条纹,甚至完全抑制注入,而不改变结构。我们的研究结果在一个紧凑的纳米点阵列平台上实现了亚微米级的SW聚焦、高效注入和动态可重构的多端口路由。
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引用次数: 0
Non-resetting spin logics based on non-hysteretic spin-orbit torque switching induced by the lateral interface 基于横向界面诱导的非滞后自旋-轨道转矩切换的非复位自旋逻辑
IF 3 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-15 Epub Date: 2026-01-29 DOI: 10.1016/j.jmmm.2026.173873
Yanru Li , Meiyin Yang , Peiyue Yu , Shuaiyu Gong , Shuo Xu , Jingsong Huang , Baoshan Cui , Jinbiao Liu , Jun Luo
Spin-orbit-torque devices offer inherent advantages for reconfigurable and energy-efficient computing. However, spin logic schemes rely on hysteretic switching loops and therefore require state resetting, incurring additional power and area costs. Here, we demonstrate the non-resetting reconfigurable spin-orbit torque logic gates, including XOR, NOT, AND, OR and NAND logics. These logic gates are realized by non-hysteretic magnetization switching, which results from symmetry breaking, current induced Néel domain wall motion and all-linear magnetization switching mechanism at designed 0° and 90° lateral interfaces between ion implantation and non-implantation zones. Thanks to the non-hysteresis relationship between output and input during the current-induced magnetic switching, the proposed device in this work do not require resetting before each operation. This non-resetting reconfigurable SOT device holds great potential for high speed, low energy consumption and area-efficient logic-in-memory computation.
自旋轨道扭矩装置为可重构和节能计算提供了固有的优势。然而,自旋逻辑方案依赖于滞后开关回路,因此需要状态复位,从而产生额外的功率和面积成本。在这里,我们展示了非复位可重构自旋轨道转矩逻辑门,包括异或,非或,与,或和NAND逻辑。这些逻辑门是通过离子注入区和非离子注入区之间的0°和90°侧向界面上的对称破缺、电流诱导的n畴壁运动和全线性磁化开关机制实现的。由于在电流感应磁开关过程中,输出和输入之间不存在迟滞关系,因此本工作中提出的器件在每次操作前都不需要复位。这种非复位可重构的SOT器件在高速、低能耗和面积高效的内存逻辑计算方面具有巨大的潜力。
{"title":"Non-resetting spin logics based on non-hysteretic spin-orbit torque switching induced by the lateral interface","authors":"Yanru Li ,&nbsp;Meiyin Yang ,&nbsp;Peiyue Yu ,&nbsp;Shuaiyu Gong ,&nbsp;Shuo Xu ,&nbsp;Jingsong Huang ,&nbsp;Baoshan Cui ,&nbsp;Jinbiao Liu ,&nbsp;Jun Luo","doi":"10.1016/j.jmmm.2026.173873","DOIUrl":"10.1016/j.jmmm.2026.173873","url":null,"abstract":"<div><div>Spin-orbit-torque devices offer inherent advantages for reconfigurable and energy-efficient computing. However, spin logic schemes rely on hysteretic switching loops and therefore require state resetting, incurring additional power and area costs. Here, we demonstrate the non-resetting reconfigurable spin-orbit torque logic gates, including XOR, NOT, AND, OR and NAND logics. These logic gates are realized by non-hysteretic magnetization switching, which results from symmetry breaking, current induced Néel domain wall motion and all-linear magnetization switching mechanism at designed 0° and 90° lateral interfaces between ion implantation and non-implantation zones. Thanks to the non-hysteresis relationship between output and input during the current-induced magnetic switching, the proposed device in this work do not require resetting before each operation. This non-resetting reconfigurable SOT device holds great potential for high speed, low energy consumption and area-efficient logic-in-memory computation.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"642 ","pages":"Article 173873"},"PeriodicalIF":3.0,"publicationDate":"2026-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetic properties of electron-irradiated BaFe11Ti0.5Al0.5O19 hexaferrite 电子辐照BaFe11Ti0.5Al0.5O19六铁氧体的磁性能
IF 3 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-15 Epub Date: 2026-01-29 DOI: 10.1016/j.jmmm.2026.173885
A.D. Lobanov , Yu.V. Korkh , S.A. Maslova , D.A. Shishkin , N.A. Zhivulina , V.E. Zhivulin , S.A. Gudkova , D.A. Vinnik , E.I. Patrakov , S.G. Titova , M.N. Sarychev , R.G. Chumakov , V.Yu. Ivanov , T.V. Kuznetsova
In this work, the BaFe11Ti0.5Al0.5O19 single crystals synthesized by spontaneous crystallization from solution were studied by scanning electron microscopy, X-ray powder diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, magnetic force microscopy, vibration magnetometry before and after 10 MeV electron irradiation with fluence of 1017 cm−2. It was found that irradiation leads to an insignificant relative increase in Fe2+ ions compared to Fe3+ ions. The modification of chemical bonds mainly on the surface of the BaFe11Ti0.5Al0.5O19 sample led to the distortion of the magnetic domain structure and an increase in magnetic anisotropy. This led to an increase in magnetic susceptibility in the range from 80 to 11,000 Oe, in the case when the magnetic field is directed along the sample surface. However, the modification of chemical bonds on the sample surface did not lead to changes in such parameters as saturation magnetization, coercivity, and remanent magnetization. Thus, significant degradation of the magnetic properties of the studied material BaFe11Ti0.5Al0.5O19 with electron irradiation is not observed.
本文采用扫描电镜、x射线粉末衍射、拉曼光谱、x射线光电子能谱、磁力显微镜、振动磁强计等方法,对溶液自发结晶合成的BaFe11Ti0.5Al0.5O19单晶进行了1017 cm−2辐照前后的研究。结果表明,与Fe3+离子相比,辐照导致Fe2+离子的相对增加不明显。化学键的修饰主要发生在BaFe11Ti0.5Al0.5O19样品表面,导致其磁畴结构发生畸变,磁各向异性增大。这导致磁化率在80到11000欧的范围内增加,当磁场沿着样品表面方向时。然而,对样品表面化学键的修饰并没有导致饱和磁化、矫顽力和剩余磁化等参数的变化。因此,所研究的材料BaFe11Ti0.5Al0.5O19的磁性能在电子辐照下没有明显的退化。
{"title":"Magnetic properties of electron-irradiated BaFe11Ti0.5Al0.5O19 hexaferrite","authors":"A.D. Lobanov ,&nbsp;Yu.V. Korkh ,&nbsp;S.A. Maslova ,&nbsp;D.A. Shishkin ,&nbsp;N.A. Zhivulina ,&nbsp;V.E. Zhivulin ,&nbsp;S.A. Gudkova ,&nbsp;D.A. Vinnik ,&nbsp;E.I. Patrakov ,&nbsp;S.G. Titova ,&nbsp;M.N. Sarychev ,&nbsp;R.G. Chumakov ,&nbsp;V.Yu. Ivanov ,&nbsp;T.V. Kuznetsova","doi":"10.1016/j.jmmm.2026.173885","DOIUrl":"10.1016/j.jmmm.2026.173885","url":null,"abstract":"<div><div>In this work, the BaFe<sub>11</sub>Ti<sub>0.5</sub>Al<sub>0.5</sub>O<sub>19</sub> single crystals synthesized by spontaneous crystallization from solution were studied by scanning electron microscopy, X-ray powder diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, magnetic force microscopy, vibration magnetometry before and after 10 MeV electron irradiation with fluence of 10<sup>17</sup> cm<sup>−2</sup>. It was found that irradiation leads to an insignificant relative increase in Fe<sup>2+</sup> ions compared to Fe<sup>3+</sup> ions. The modification of chemical bonds mainly on the surface of the BaFe<sub>11</sub>Ti<sub>0.5</sub>Al<sub>0.5</sub>O<sub>19</sub> sample led to the distortion of the magnetic domain structure and an increase in magnetic anisotropy. This led to an increase in magnetic susceptibility in the range from 80 to 11,000 Oe, in the case when the magnetic field is directed along the sample surface. However, the modification of chemical bonds on the sample surface did not lead to changes in such parameters as saturation magnetization, coercivity, and remanent magnetization. Thus, significant degradation of the magnetic properties of the studied material BaFe<sub>11</sub>Ti<sub>0.5</sub>Al<sub>0.5</sub>O<sub>19</sub> with electron irradiation is not observed.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"642 ","pages":"Article 173885"},"PeriodicalIF":3.0,"publicationDate":"2026-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185934","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Towards absolute measurements of magnetic losses by the rotational single sheet tester (RSST): an interlaboratory comparison 通过旋转单片测试仪(RSST)实现磁损耗的绝对测量:实验室间的比较
IF 3 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-15 Epub Date: 2026-01-23 DOI: 10.1016/j.jmmm.2026.173856
Carlo Appino , Enzo Ferrara , Nicoleta Banu , Clementine Delaunay , Fabien Sixdenier , Charles Joubert , Carlo Ragusa , Song Huang , Luigi Solimene , Olivier de la Barrière , Fausto Fiorillo
A comparison of the magnetic energy loss measurement in non-oriented Fe–Si sheets under alternating and rotational polarization has been accomplished by four European laboratories using different Rotational Single-Sheet Tester (RSST) setups and different sample shapes. The measurements, performed in the frequency and polarization intervals 5 Hz ≤ f ≤ 200 Hz, 1.0 T ≤ Jp ≤ 1.5 T, aimed at providing a benchmark test for these special measurements, looking for a connection between the RSST outcomes and absolute loss values, obtained by a combination of IEC 60404-2 Epstein data and precise local measurements. The laboratory-averaged RSST alternating loss values are found to range in a ±5% interval around the reference values, with the lab-to-lab discrepancies chiefly descending from the heterogeneous variety of the employed magnetic circuits. Numerical analysis highlights the critical role of the effective field and its uniformity across the RSST sensing area. The statistical assessment of the laboratories' best estimates provides the empirical standard deviations s = 4.5% and s = 3.6% for the alternating and rotational loss figures, respectively, thereby showing a significantly reduced dispersion of the results compared with a previous international comparison launched in the ‘90s. It additionally points to the circular geometry for both sample and magnetizer as best suited for the prospective standardization of 2D measurements.
比较了四个欧洲实验室使用不同的旋转单片测试仪(RSST)装置和不同的样品形状,在交变极化和旋转极化条件下无取向铁硅片的磁能损耗测量结果。在5 Hz≤f≤200 Hz, 1.0 T≤Jp≤1.5 T的频率和极化区间进行测量,旨在为这些特殊测量提供基准测试,寻找RSST结果与绝对损耗值之间的联系,这些数据是通过IEC 60404-2 Epstein数据和精确的本地测量相结合获得的。实验室平均RSST交变损耗值在参考值周围±5%的范围内,实验室与实验室之间的差异主要是由于所采用磁路的异质性。数值分析强调了有效场及其在RSST传感区域内的均匀性的关键作用。对实验室最佳估计的统计评估为交替损失和旋转损失数据分别提供了s = 4.5%和s = 3.6%的经验标准偏差,从而表明与上世纪90年代启动的先前国际比较相比,结果的分散性显著降低。它还指出,样品和磁化器的圆形几何形状最适合于二维测量的未来标准化。
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引用次数: 0
The impact of bi-phasic crystal structure on the magnetic and transport properties of single crystalline NdBaMn2O5+δ 双相晶体结构对NdBaMn2O5+δ单晶磁性和输运性能的影响
IF 3 3区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-03-15 Epub Date: 2026-02-06 DOI: 10.1016/j.jmmm.2026.173912
H. Fabrelli , C. Macchiutti , J.R. Jesus , D.A. Mayoh , G. Balakrishnan , L. Bufaiçal , E.M. Bittar
The LnBaMn2O5 (Ln = rare-earth) manganites have attracted considerable recent interest due to their potential for use as oxygen storage materials and as solid oxide fuel cells. However, there is scarce data on the magnetic properties of some prototypical materials. Here, we report the synthesis of a single-crystalline NdBaMn2O5+δ compound by the floating-zone method and investigate its structural, electronic, and magnetic properties. The structural data indicate that, at room temperature, the material consists of a mixture of a NdBaMn2O5 phase with a layered arrangement of the Nd/Ba ions (space group P4/nmm) and a NdBaMn2O6 phase with a disordered distribution of Nd/Ba (space group Imma). Measurements of magnetization performed with the magnetic field applied at distinct crystallographic directions reveal a rich magnetic diagram, which is compared with that of similar rare-earth manganites. A peculiar anisotropy is observed between the c axis and the ab plane of the NdBaMn2O5 phase, suggesting a G-type magnetic structure in which the Mn moments are oriented along the ab planes. The electrical transport data show a pronounced magnetoresistance, which is discussed in terms of the system’s crystal structure and the presence of mixed-valent Mn.
LnBaMn2O5 (Ln =稀土)锰近来因其作为储氧材料和固体氧化物燃料电池的潜力而引起了相当大的兴趣。然而,关于一些原型材料的磁性的数据很少。本文报道了用浮区法合成了一种单晶NdBaMn2O5+δ化合物,并研究了其结构、电子和磁性能。结构数据表明,在室温下,材料由Nd/Ba离子层状排列的NdBaMn2O5相(空间群P4/nmm)和Nd/Ba无序分布的NdBaMn2O6相(空间群Imma)组成。在不同的晶体方向上施加磁场进行磁化测量,显示出丰富的磁图,这与类似的稀土锰矿相比较。在NdBaMn2O5相的c轴和ab面之间观察到一种特殊的各向异性,表明其存在一种Mn矩沿ab面取向的g型磁结构。电输运数据显示出明显的磁阻,这是根据系统的晶体结构和混合价Mn的存在来讨论的。
{"title":"The impact of bi-phasic crystal structure on the magnetic and transport properties of single crystalline NdBaMn2O5+δ","authors":"H. Fabrelli ,&nbsp;C. Macchiutti ,&nbsp;J.R. Jesus ,&nbsp;D.A. Mayoh ,&nbsp;G. Balakrishnan ,&nbsp;L. Bufaiçal ,&nbsp;E.M. Bittar","doi":"10.1016/j.jmmm.2026.173912","DOIUrl":"10.1016/j.jmmm.2026.173912","url":null,"abstract":"<div><div>The LnBaMn<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O<sub>5</sub> (Ln = rare-earth) manganites have attracted considerable recent interest due to their potential for use as oxygen storage materials and as solid oxide fuel cells. However, there is scarce data on the magnetic properties of some prototypical materials. Here, we report the synthesis of a single-crystalline NdBaMn<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O<span><math><msub><mrow></mrow><mrow><mn>5</mn><mo>+</mo><mi>δ</mi></mrow></msub></math></span> compound by the floating-zone method and investigate its structural, electronic, and magnetic properties. The structural data indicate that, at room temperature, the material consists of a mixture of a NdBaMn<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O<sub>5</sub> phase with a layered arrangement of the Nd/Ba ions (space group <span><math><mrow><mi>P</mi><mn>4</mn><mo>/</mo><mi>n</mi><mi>m</mi><mi>m</mi></mrow></math></span>) and a NdBaMn<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O<sub>6</sub> phase with a disordered distribution of Nd/Ba (space group <span><math><mrow><mi>I</mi><mi>m</mi><mi>m</mi><mi>a</mi></mrow></math></span>). Measurements of magnetization performed with the magnetic field applied at distinct crystallographic directions reveal a rich magnetic diagram, which is compared with that of similar rare-earth manganites. A peculiar anisotropy is observed between the <span><math><mi>c</mi></math></span> axis and the <span><math><mrow><mi>a</mi><mi>b</mi></mrow></math></span> plane of the NdBaMn<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>O<span><math><msub><mrow></mrow><mrow><mn>5</mn></mrow></msub></math></span> phase, suggesting a G-type magnetic structure in which the Mn moments are oriented along the <span><math><mrow><mi>a</mi><mi>b</mi></mrow></math></span> planes. The electrical transport data show a pronounced magnetoresistance, which is discussed in terms of the system’s crystal structure and the presence of mixed-valent Mn.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"642 ","pages":"Article 173912"},"PeriodicalIF":3.0,"publicationDate":"2026-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146185798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Journal of Magnetism and Magnetic Materials
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