Pub Date : 2026-01-06DOI: 10.1016/j.jmmm.2026.173812
Arash Vaghef-Koodehi , Mahmoud Nikoufard , Yaser Bahari
We present a theoretical investigation of moiré magneto-excitonic polaritons in twisted bilayer transition-metal dichalcogenide heterostructures interfaced with two-dimensional ferromagnets. By combining a full electromagnetic simulation based on time-domain finite-difference (FDTD) calculations with a microscopic exciton–magnon Hamiltonian derived from tight-binding theory, we reveal the emergence of strong hybridization between excitonic and magnonic modes mediated by the moiré superlattice potential. The coupling strength exhibits Rabi splitting up to ≈ 8 meV under moderate magnetic fields and maintains coherent hybridization up to 180 K for CrI₃ and 230 K for Fe₃GeTe₂ substrates. The hybrid mode shows pronounced valley-selective behavior with an intensity ratio of ∼8:1 (K:K′) and an ultrafast oscillation period in the terahertz (THz) range, corresponding to light–matter–spin coherence on the picosecond scale. These results uncover a controllable pathway to engineer moiré-assisted exciton–magnon coupling governed by twist angle, magnetic exchange, and gate bias, thereby providing a physical foundation for tunable spin-polarized quantum photonic and opto-magnonic devices. Beyond its fundamental implications for correlated moiré physics, this study delineates a realistic route toward THz-bandwidth, nonreciprocal, and valley-selective photonic interfaces operating at elevated temperatures—establishing moiré magneto-excitonics as a credible frontier for next-generation hybrid quantum materials.
{"title":"Twist-tunable moiré magneto-Excitonic Polaritons at 2D ferromagnetic interfaces","authors":"Arash Vaghef-Koodehi , Mahmoud Nikoufard , Yaser Bahari","doi":"10.1016/j.jmmm.2026.173812","DOIUrl":"10.1016/j.jmmm.2026.173812","url":null,"abstract":"<div><div>We present a theoretical investigation of moiré magneto-excitonic polaritons in twisted bilayer transition-metal dichalcogenide heterostructures interfaced with two-dimensional ferromagnets. By combining a full electromagnetic simulation based on time-domain finite-difference (FDTD) calculations with a microscopic exciton–magnon Hamiltonian derived from tight-binding theory, we reveal the emergence of strong hybridization between excitonic and magnonic modes mediated by the moiré superlattice potential. The coupling strength exhibits Rabi splitting up to ≈ 8 meV under moderate magnetic fields and maintains coherent hybridization up to 180 K for CrI₃ and 230 K for Fe₃GeTe₂ substrates. The hybrid mode shows pronounced valley-selective behavior with an intensity ratio of ∼8:1 (K:K′) and an ultrafast oscillation period in the terahertz (THz) range, corresponding to light–matter–spin coherence on the picosecond scale. These results uncover a controllable pathway to engineer moiré-assisted exciton–magnon coupling governed by twist angle, magnetic exchange, and gate bias, thereby providing a physical foundation for tunable spin-polarized quantum photonic and opto-magnonic devices. Beyond its fundamental implications for correlated moiré physics, this study delineates a realistic route toward THz-bandwidth, nonreciprocal, and valley-selective photonic interfaces operating at elevated temperatures—establishing moiré magneto-excitonics as a credible frontier for next-generation hybrid quantum materials.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"641 ","pages":"Article 173812"},"PeriodicalIF":3.0,"publicationDate":"2026-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145975213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-06DOI: 10.1016/j.jmmm.2026.173814
Manikandan Dhamodaran , Rahul Kumar Yadav , N. Raja , Ramesh Karuppannan , Rajeev Gupta
We examine the impact of iron and manganese co-doping on the local atomic environment in hydrothermally synthesized In2O3 using synchrotron X-ray absorption spectroscopy analysis, correlating the findings with the observed magnetic properties. The results revealed that manganese is mainly present in the +3-valence state with a dilute contribution from the +4 state. These oxidation states indicate the formation of oxygen vacancies resulting from charge imbalance. The effective co-substitution of iron and manganese atoms in the In2O3 was established, accompanied by specific changes in bond lengths. Additionally, the bond length of MnO slightly increased for In1.94Fe0.02Mn0.04O3, and subsequently, decreased for the higher Mn-doped samples. Density functional theory calculations revealed that the FeO bond length decreases from 2.194 to 2.141 Å upon the introduction of oxygen vacancies, indicating enhanced FeO interactions. Conversely, the MnO bond increased from 2.140 to 2.210 Å, reflecting the weakened local bonding environment and reduced lattice integration of Mn atoms. Magnetic investigations revealed a room-temperature ferromagnetism in In1.94Fe0.02Mn0.04O3, characterized by an enhanced coercivity and saturation magnetization. Density functional theory calculations show that oxygen vacancy formation stabilizes the high magnetic moments 3.85 μB for Fe and 4.23 μB for Mn, driven by FeO and MnO hybridization and increased d-electron localization around the transition metal centers. These findings offer new insights into the local micro-environment and magnetic characteristics of iron and manganese-codoped indium oxide.
{"title":"Probing the local atomic structure and magnetism in Iron and manganese co-doped indium oxide Nanocubes using XAS and DFT","authors":"Manikandan Dhamodaran , Rahul Kumar Yadav , N. Raja , Ramesh Karuppannan , Rajeev Gupta","doi":"10.1016/j.jmmm.2026.173814","DOIUrl":"10.1016/j.jmmm.2026.173814","url":null,"abstract":"<div><div>We examine the impact of iron and manganese co-doping on the local atomic environment in hydrothermally synthesized In<sub>2</sub>O<sub>3</sub> using synchrotron X-ray absorption spectroscopy analysis, correlating the findings with the observed magnetic properties. The results revealed that manganese is mainly present in the +3-valence state with a dilute contribution from the +4 state. These oxidation states indicate the formation of oxygen vacancies resulting from charge imbalance. The effective co-substitution of iron and manganese atoms in the In<sub>2</sub>O<sub>3</sub> was established, accompanied by specific changes in bond lengths. Additionally, the bond length of Mn<img>O slightly increased for In<sub>1.94</sub>Fe<sub>0.02</sub>Mn<sub>0.04</sub>O<sub>3</sub>, and subsequently, decreased for the higher Mn-doped samples. Density functional theory calculations revealed that the Fe<img>O bond length decreases from 2.194 to 2.141 Å upon the introduction of oxygen vacancies, indicating enhanced Fe<img>O interactions. Conversely, the Mn<img>O bond increased from 2.140 to 2.210 Å, reflecting the weakened local bonding environment and reduced lattice integration of Mn atoms. Magnetic investigations revealed a room-temperature ferromagnetism in In<sub>1.94</sub>Fe<sub>0.02</sub>Mn<sub>0.04</sub>O<sub>3</sub>, characterized by an enhanced coercivity and saturation magnetization. Density functional theory calculations show that oxygen vacancy formation stabilizes the high magnetic moments 3.85 μ<sub>B</sub> for Fe and 4.23 μ<sub>B</sub> for Mn, driven by Fe<img>O and Mn<img>O hybridization and increased d-electron localization around the transition metal centers. These findings offer new insights into the local micro-environment and magnetic characteristics of iron and manganese-codoped indium oxide.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"641 ","pages":"Article 173814"},"PeriodicalIF":3.0,"publicationDate":"2026-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145941222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-03DOI: 10.1016/j.jmmm.2025.173797
S. Naveen Rajkumar , Akshaya Senthilkumar , D. Arvindha Babu , M. Manivel Raja , Elangovan Hemaprabha
In this study, the effect of Dy and Tb addition on structural, thermal and magnetic properties of Nd33Fe67 melt spun ribbons was studied with an aim to stabilize Nd5Fe17 phase and increase coercivity. Dy and Tb addition led to the formation of partial amorphous phase along with crystalline phases of Nd2Fe17 and Nd(Fe) solid solution phases at low concentrations (up to Dy = Tb = 4 at.%) and DyFe2/TbFe2 phases also form beyond Dy = Tb = 6 at.%. While annealing at 350 °C results in partial formation of the equilibrium Nd5Fe17 phase along with other existing phases i.e. amorphous, Nd2Fe17 and Nd(Fe) solid solution, annealing at 670 °C results in only equilibrium Nd5Fe17, Nd(Fe) solid solution, and DyFe2/TbFe2 phases. The Curie temperature of amorphous phase increases with increasing Dy/Tb content for low concentration of Dy/Tb and it decreases for high Dy/Tb concentration. Presence of Dy/Tb atoms in the amorphous phase causes FeFe distance to change and influences the exchange interaction thereby affecting the Curie temperature. Presence of amorphous phase having large random anisotropy, Nd2Fe17 phase having high anisotropy and DyFe2/TbFe2 having high anisotropy in Dy/Tb added as spun alloys result in increased coercivity as compared to the alloy having no Dy/Tb. Annealing at 350 °C showed a trend of increasing coercivity with Dy/Tb due to the presence of three hard magnetic phases i.e. amorphous, Nd2Fe17 and DyFe2/TbFe2 phases along with soft magnetic Nd5Fe17 phase. Annealing at 670 °C resulted in the formation of soft magnetic Nd5Fe17 phase along with hard magnetic DyFe2/TbFe2 phases which showed lowest coercivity observed across all alloys. Dy/Tb addition decreases magnetization in all samples due to their anti-parallel interaction with the amorphous matrix and the ferrimagnetic contribution of DyFe2/TbFe2 phases.
{"title":"Effect of Dy and Tb addition on the structural, thermal and magnetic properties of Nd33Fe67 melt spun alloys","authors":"S. Naveen Rajkumar , Akshaya Senthilkumar , D. Arvindha Babu , M. Manivel Raja , Elangovan Hemaprabha","doi":"10.1016/j.jmmm.2025.173797","DOIUrl":"10.1016/j.jmmm.2025.173797","url":null,"abstract":"<div><div>In this study, the effect of Dy and Tb addition on structural, thermal and magnetic properties of Nd<sub>33</sub>Fe<sub>67</sub> melt spun ribbons was studied with an aim to stabilize Nd<sub>5</sub>Fe<sub>17</sub> phase and increase coercivity. Dy and Tb addition led to the formation of partial amorphous phase along with crystalline phases of Nd<sub>2</sub>Fe<sub>17</sub> and Nd(Fe) solid solution phases at low concentrations (up to Dy = Tb = 4 at.%) and DyFe<sub>2</sub>/TbFe<sub>2</sub> phases also form beyond Dy = Tb = 6 at.%. While annealing at 350 °C results in partial formation of the equilibrium Nd<sub>5</sub>Fe<sub>17</sub> phase along with other existing phases i.e. amorphous, Nd<sub>2</sub>Fe<sub>17</sub> and Nd(Fe) solid solution, annealing at 670 °C results in only equilibrium Nd<sub>5</sub>Fe<sub>17</sub>, Nd(Fe) solid solution, and DyFe<sub>2</sub>/TbFe<sub>2</sub> phases. The Curie temperature of amorphous phase increases with increasing Dy/Tb content for low concentration of Dy/Tb and it decreases for high Dy/Tb concentration. Presence of Dy/Tb atoms in the amorphous phase causes Fe<img>Fe distance to change and influences the exchange interaction thereby affecting the Curie temperature. Presence of amorphous phase having large random anisotropy, Nd<sub>2</sub>Fe<sub>17</sub> phase having high anisotropy and DyFe<sub>2</sub>/TbFe<sub>2</sub> having high anisotropy in Dy/Tb added as spun alloys result in increased coercivity as compared to the alloy having no Dy/Tb. Annealing at 350 °C showed a trend of increasing coercivity with Dy/Tb due to the presence of three hard magnetic phases i.e. amorphous, Nd<sub>2</sub>Fe<sub>17</sub> and DyFe<sub>2</sub>/TbFe<sub>2</sub> phases along with soft magnetic Nd<sub>5</sub>Fe<sub>17</sub> phase. Annealing at 670 °C resulted in the formation of soft magnetic Nd<sub>5</sub>Fe<sub>17</sub> phase along with hard magnetic DyFe<sub>2</sub>/TbFe<sub>2</sub> phases which showed lowest coercivity observed across all alloys. Dy/Tb addition decreases magnetization in all samples due to their anti-parallel interaction with the amorphous matrix and the ferrimagnetic contribution of DyFe<sub>2</sub>/TbFe<sub>2</sub> phases.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"641 ","pages":"Article 173797"},"PeriodicalIF":3.0,"publicationDate":"2026-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145975216","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Magnetic properties of biomorphic carbon-based materials obtained from birch-wood pyrolysis products using carbonization temperature of 700 °C with and without subsequent activation at 970 °C have been studied in a wide temperature range of 2–300 K in magnetic fields up to 140 kOe. It was found that biocarbon samples purified from volatile wood decomposition product (tar) during pyrolysis demonstrate diamagnetic behavior of magnetization at room temperature and paramagnetic at low temperatures, while in biocarbon samples with residual or specially introduced pyrolysis tar, a ferromagnetic component of magnetization is observed at room temperature. The analysis showed that ferromagnetism appears as a result of the formation of carbon magnetic nanoparticles during the carbonization of binding tar in the biocarbon. The magnitude of magnetization of such nanoparticles is comparable to the magnetization of nanoparticles formed by ferromagnetic metals that opens way to obtain porous magnetic biocarbon materials without ferromagnetic metal inclusions.
{"title":"Magnetic carbon-nanoparticles behavior of biomorphic pyrolytic carbons","authors":"V.V. Popov , T.S. Orlova , A.A. Spitsyn , D.A. Kirilenko , K.V. Dyakonov","doi":"10.1016/j.jmmm.2026.173811","DOIUrl":"10.1016/j.jmmm.2026.173811","url":null,"abstract":"<div><div>Magnetic properties of biomorphic carbon-based materials obtained from birch-wood pyrolysis products using carbonization temperature of 700 °C with and without subsequent activation at 970 °C have been studied in a wide temperature range of 2–300 K in magnetic fields up to 140 kOe. It was found that biocarbon samples purified from volatile wood decomposition product (tar) during pyrolysis demonstrate diamagnetic behavior of magnetization at room temperature and paramagnetic at low temperatures, while in biocarbon samples with residual or specially introduced pyrolysis tar, a ferromagnetic component of magnetization is observed at room temperature. The analysis showed that ferromagnetism appears as a result of the formation of carbon magnetic nanoparticles during the carbonization of binding tar in the biocarbon. The magnitude of magnetization of such nanoparticles is comparable to the magnetization of nanoparticles formed by ferromagnetic metals that opens way to obtain porous magnetic biocarbon materials without ferromagnetic metal inclusions.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"640 ","pages":"Article 173811"},"PeriodicalIF":3.0,"publicationDate":"2026-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145922965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-02DOI: 10.1016/j.jmmm.2025.173809
Yong Gong , Zhubing Yan , Francesco Cugini , Fengjiao Qian , Jiawei Lai , Xuefei Miao , Jun Liu , Zhixiang Qi , Yuanyuan Gong , Feng Xu , Luana Caron
The 〈001〉 − oriented (Mn,Fe)2(P,Si)/epoxy composites were fabricated via magnetic field-assisted dynamic self-assembly. These textured composites demonstrate remarkable adaptability for diverse applications that require either substantial coefficients (αl) of negative thermal expansion (NTE) or broad NTE temperature windows (ΔTNTE). A two-dimensional NTE with a colossal αl of −144.37 × 10−6 K−1 is realized between 280 and 360 K in the composite displaying a first-order phase transition (FOPT). The ΔTNTE can be significantly extended to 190 K (120−310K) in the composite exhibiting a second-order phase transition (SOPT), while preserving a large αl of −23.89 × 10−6 K−1. Besides that, anisotropic MCE is observed in the textured composites. The FOPT composite exhibits a maximum entropy change of 7.18 Jkg−1 K−1 under a magnetic field of 1 T applied perpendicular to the texture direction, which is 34 % higher than the parallel field configuration. Consequently, our study demonstrates that grain-orientation engineering can be effectively employed to explore NTE and achieve anisotropic magnetocaloric properties.
{"title":"Grain-orientation engineering enables dual-functionality in (Mn,Fe)2(P,Si)/epoxy composites: Colossal negative thermal expansion and anisotropic magnetocaloric effect","authors":"Yong Gong , Zhubing Yan , Francesco Cugini , Fengjiao Qian , Jiawei Lai , Xuefei Miao , Jun Liu , Zhixiang Qi , Yuanyuan Gong , Feng Xu , Luana Caron","doi":"10.1016/j.jmmm.2025.173809","DOIUrl":"10.1016/j.jmmm.2025.173809","url":null,"abstract":"<div><div>The 〈001〉 − oriented (Mn,Fe)<sub>2</sub>(P,Si)/epoxy composites were fabricated via magnetic field-assisted dynamic self-assembly. These textured composites demonstrate remarkable adaptability for diverse applications that require either substantial coefficients (<em>α</em><sub><em>l</em></sub>) of negative thermal expansion (NTE) or broad NTE temperature windows (Δ<em>T</em><sub>NTE</sub>). A two-dimensional NTE with a colossal <em>α</em><sub><em>l</em></sub> of −144.37 × 10<sup>−6</sup> K<sup>−1</sup> is realized between 280 and 360 K in the composite displaying a first-order phase transition (FOPT). The Δ<em>T</em><sub>NTE</sub> can be significantly extended to 190 K (120−310<em>K</em>) in the composite exhibiting a second-order phase transition (SOPT), while preserving a large <em>α</em><sub><em>l</em></sub> of −23.89 × 10<sup>−6</sup> K<sup>−1</sup>. Besides that, anisotropic MCE is observed in the textured composites. The FOPT composite exhibits a maximum entropy change of 7.18 Jkg<sup>−1</sup> K<sup>−1</sup> under a magnetic field of 1 T applied perpendicular to the texture direction, which is 34 % higher than the parallel field configuration. Consequently, our study demonstrates that grain-orientation engineering can be effectively employed to explore NTE and achieve anisotropic magnetocaloric properties.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"641 ","pages":"Article 173809"},"PeriodicalIF":3.0,"publicationDate":"2026-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145941257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-31DOI: 10.1016/j.jmmm.2025.173795
Zhengzhong Zhang , Han Hu , Runze Zhu , Yanzong Wang , Hao Liu
We theoretically investigate the inelastic electron transport process in a molecular spin-valve, which consists of a single-molecule magnet weakly coupled between a pair of ferromagnetic electrodes. Owing to the influence of the spin moment of the molecule on itinerant electrons, the tunneling magnetoresistance of this device exhibits two distinct phenomena: when the molecular magnetism is parallel to that of both FM electrodes, the magnetoresistance is enhanced; otherwise, it is suppressed, leading to a negative magnetoresistance phenomenon. We discuss the analytical expression of magnetoresistance under low temperature condition and find that both types of phenomena depend mainly on the spin polarization of the ferromagnetic electrodes. Based on the intrinsic magnetism of molecule, these two types of magnetoresistance can be prepared, preserved and detected under near zero magnetic field conditions. This molecular electrical device can be realized with current technologies and may have practical use in magnetic structures combined with molecular magnets, such as magnetic molecular spin-valve structures.
{"title":"Tunneling magnetoresistance anomalies in a single-molecule magnet spin valve","authors":"Zhengzhong Zhang , Han Hu , Runze Zhu , Yanzong Wang , Hao Liu","doi":"10.1016/j.jmmm.2025.173795","DOIUrl":"10.1016/j.jmmm.2025.173795","url":null,"abstract":"<div><div>We theoretically investigate the inelastic electron transport process in a molecular spin-valve, which consists of a single-molecule magnet weakly coupled between a pair of ferromagnetic electrodes. Owing to the influence of the spin moment of the molecule on itinerant electrons, the tunneling magnetoresistance of this device exhibits two distinct phenomena: when the molecular magnetism is parallel to that of both FM electrodes, the magnetoresistance is enhanced; otherwise, it is suppressed, leading to a negative magnetoresistance phenomenon. We discuss the analytical expression of magnetoresistance under low temperature condition and find that both types of phenomena depend mainly on the spin polarization of the ferromagnetic electrodes. Based on the intrinsic magnetism of molecule, these two types of magnetoresistance can be prepared, preserved and detected under near zero magnetic field conditions. This molecular electrical device can be realized with current technologies and may have practical use in magnetic structures combined with molecular magnets, such as magnetic molecular spin-valve structures.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"640 ","pages":"Article 173795"},"PeriodicalIF":3.0,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145882802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-30DOI: 10.1016/j.jmmm.2025.173792
M.A.R. Martinez , F.F.H. Aragón , L. León Félix , J. Mantilla , M.H. Sousa , M.C. Mathpal , J.F. Felix , J.A.H. Coaquira
In this study, Fe50Ni50 powder alloys were synthesized successfully using the sol–gel method, followed by systematic thermal treatments up to 1000 °C in a reducing atmosphere (Ar-H). Synchrotron X-ray diffraction patterns indicate that the data are well modeled by face-centered cubic (FCC) FeNi phase. The stability of this phase was studied, revealing that as the temperature is increased, the unit cell volume changes, suggesting an enhancement in the migration of iron atoms. This migration alters the stoichiometry of the FeNi alloy, potentially shifting it beyond its nominal 50/50 composition. High-resolution TEM demonstrated the formation of the FeNi phase, which is in good agreement with the results obtained by XRD. Additionally, only a slight increase in crystalline particle size was observed. Magnetic characterization shows that thermal annealing strongly influences the magnetization. In particular, the sample annealed at 700 °C exhibits the highest magnetization and a Curie temperature 805 K, highlighting the role of thermal treatments in tuning the magnetic response. Zero-field cooling and field cooling measurements in the range 5–380 K further reveal irreversibilities above room temperature, attributed to the small particle size and strong interparticle interactions, which significantly affect the coercive field and overall magnetic behavior. These FeNi nanoparticles were characterized as magnetically soft materials. Mössbauer spectroscopy confirms the ferromagnetic behavior of the cubic FeNi phase as shown by XRD. Increasing the treatment temperature produces an increase in the hyperfine magnetic field, while the IS becomes more negative, which is primarily attributed to modifications in the s-electron density at the iron nuclei resulting from thermally induced electronic redistribution.
{"title":"Phase stability and tunable structural, hyperfine, and magnetic properties of Sol–Gel FeNi nanoparticles","authors":"M.A.R. Martinez , F.F.H. Aragón , L. León Félix , J. Mantilla , M.H. Sousa , M.C. Mathpal , J.F. Felix , J.A.H. Coaquira","doi":"10.1016/j.jmmm.2025.173792","DOIUrl":"10.1016/j.jmmm.2025.173792","url":null,"abstract":"<div><div>In this study, <span><math><mo>∼</mo></math></span>Fe<sub>50</sub>Ni<sub>50</sub> powder alloys were synthesized successfully using the sol–gel method, followed by systematic thermal treatments up to 1000 °C in a reducing atmosphere (Ar-H<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>). Synchrotron X-ray diffraction patterns indicate that the data are well modeled by face-centered cubic (FCC) FeNi phase. The stability of this phase was studied, revealing that as the temperature is increased, the unit cell volume changes, suggesting an enhancement in the migration of iron atoms. This migration alters the stoichiometry of the FeNi alloy, potentially shifting it beyond its nominal 50/50 composition. High-resolution TEM demonstrated the formation of the FeNi phase, which is in good agreement with the results obtained by XRD. Additionally, only a slight increase in crystalline particle size was observed. Magnetic characterization shows that thermal annealing strongly influences the magnetization. In particular, the sample annealed at 700 °C exhibits the highest magnetization and a Curie temperature <span><math><mo>∼</mo></math></span>805 K, highlighting the role of thermal treatments in tuning the magnetic response. Zero-field cooling and field cooling measurements in the range 5–380 K further reveal irreversibilities above room temperature, attributed to the small particle size and strong interparticle interactions, which significantly affect the coercive field and overall magnetic behavior. These FeNi nanoparticles were characterized as magnetically soft materials. Mössbauer spectroscopy confirms the ferromagnetic behavior of the cubic FeNi phase as shown by XRD. Increasing the treatment temperature produces an increase in the hyperfine magnetic field, while the IS becomes more negative, which is primarily attributed to modifications in the s-electron density at the iron nuclei resulting from thermally induced electronic redistribution.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"640 ","pages":"Article 173792"},"PeriodicalIF":3.0,"publicationDate":"2025-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145922966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-30DOI: 10.1016/j.jmmm.2025.173796
S. Roy , A. Solignac , N. Montblanc , T. Maroutian , A. Di Pietro , D. Ravelosona , G. Durin , L. Herrera Diez , G. Agnus
This study investigates how piezoelectric strain influences magnetic domain-wall (DW) motion in perpendicularly magnetized Ta/CoFeB/MgO ultrathin films grown on PMN-PT (011) substrates. Applying a gate voltage along the out-of-plane direction of the PMN-PT (011) substrate induces a non-volatile electrical polarization, producing a stable strain state (the poled state), which was confirmed using piezoresponse force microscopy. In this configuration, polar magneto-optical Kerr effect (P-MOKE) measurements reveal that this voltage-controlled remanent strain in the PMN-PT substrate can modulate DW dynamics and magnetic properties relative to the unpoled (as-grown) state. This response can be linked not only to a strain-controlled magnetic anisotropy but also to a strain-controlled change in the homogeneity of the magnetic landscape. The multiple polarization directions of the domains in the unpoled state of the PMN-PT can result in a wider anisotropy distribution in the magnetic system compared to the poled state. This can significantly affect DW nucleation/depinning fields, highlighting the role of piezoelectric strain in controlling DW dynamics. These results are of interest for the development of DW based magnetic memory applications with a reduced energy consumption.
{"title":"Piezoelectric strain influenced modulation of magnetic domain wall motion in hybrid PMN-PT (011)/CoFeB heterostructures with perpendicular magnetic anisotropy","authors":"S. Roy , A. Solignac , N. Montblanc , T. Maroutian , A. Di Pietro , D. Ravelosona , G. Durin , L. Herrera Diez , G. Agnus","doi":"10.1016/j.jmmm.2025.173796","DOIUrl":"10.1016/j.jmmm.2025.173796","url":null,"abstract":"<div><div>This study investigates how piezoelectric strain influences magnetic domain-wall (DW) motion in perpendicularly magnetized Ta/CoFeB/MgO ultrathin films grown on PMN-PT (011) substrates. Applying a gate voltage along the out-of-plane direction of the PMN-PT (011) substrate induces a non-volatile electrical polarization, producing a stable strain state (the poled state), which was confirmed using piezoresponse force microscopy. In this configuration, polar magneto-optical Kerr effect (P-MOKE) measurements reveal that this voltage-controlled remanent strain in the PMN-PT substrate can modulate DW dynamics and magnetic properties relative to the unpoled (as-grown) state. This response can be linked not only to a strain-controlled magnetic anisotropy but also to a strain-controlled change in the homogeneity of the magnetic landscape. The multiple polarization directions of the domains in the unpoled state of the PMN-PT can result in a wider anisotropy distribution in the magnetic system compared to the poled state. This can significantly affect DW nucleation/depinning fields, highlighting the role of piezoelectric strain in controlling DW dynamics. These results are of interest for the development of DW based magnetic memory applications with a reduced energy consumption.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"640 ","pages":"Article 173796"},"PeriodicalIF":3.0,"publicationDate":"2025-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145922520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-30DOI: 10.1016/j.jmmm.2025.173788
Tingting Fan , Lizi Pan , Chenbo Zhao, Qingfang Liu, Jianbo Wang
Cobalt-based amorphous toroidal core are used to fabricate a giant magneto impedance current sensor in this work. By adjusting the bias current, a high sensitivity of 31.6 V/A is obtained, which can realize weak current detection. The core losses are then measured and calculated to analyze the noise level. The results shows that the core loss characteristics dominate the sensor's noise, besides that, the excitation current and DC bias current also affect the noise performance. Based on optimized parameters, a current threshold alarm is realized, achieving current threshold detection and alarm functionality. This study provides theoretical and experimental guidance for low-noise design optimization in current sensing.
{"title":"Investigation of loss and noise in toroidal core current sensors","authors":"Tingting Fan , Lizi Pan , Chenbo Zhao, Qingfang Liu, Jianbo Wang","doi":"10.1016/j.jmmm.2025.173788","DOIUrl":"10.1016/j.jmmm.2025.173788","url":null,"abstract":"<div><div>Cobalt-based amorphous toroidal core are used to fabricate a giant magneto impedance current sensor in this work. By adjusting the bias current, a high sensitivity of 31.6 V/A is obtained, which can realize weak current detection. The core losses are then measured and calculated to analyze the noise level. The results shows that the core loss characteristics dominate the sensor's noise, besides that, the excitation current and DC bias current also affect the noise performance. Based on optimized parameters, a current threshold alarm is realized, achieving current threshold detection and alarm functionality. This study provides theoretical and experimental guidance for low-noise design optimization in current sensing.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"640 ","pages":"Article 173788"},"PeriodicalIF":3.0,"publicationDate":"2025-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145882791","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-12-30DOI: 10.1016/j.jmmm.2025.173805
L.F.S. Azeredo , H.S. Acosta , A.M.H. de Andrade , J. Geshev
Magnetic anisotropy is a key characteristic of magnetic materials and is a prerequisite for magnetic hysteresis. In thin magnetic films, it is usually induced by applying magnetic field either during growth or in the course of a post-deposition treatment. This study presents a comparative study of different methods — in-field sputtering deposition, annealing and ion irradiation — for inducing uniaxial magnetic anisotropy and even changing its easy-magnetization direction in polycrystalline Co films presenting collapsed hard-magnetization axes. The latter stands for the presence of prominent peaks in the angular variations of the remanent magnetization and coercivity centered ninety degrees off of the easy axis. The advantages, disadvantages and limitations of the three different techniques used to induce magnetic anisotropy are evaluated and discussed.
{"title":"Inducing and/or redirecting magnetic anisotropy in Co films with collapsed hard-magnetization axes","authors":"L.F.S. Azeredo , H.S. Acosta , A.M.H. de Andrade , J. Geshev","doi":"10.1016/j.jmmm.2025.173805","DOIUrl":"10.1016/j.jmmm.2025.173805","url":null,"abstract":"<div><div>Magnetic anisotropy is a key characteristic of magnetic materials and is a prerequisite for magnetic hysteresis. In thin magnetic films, it is usually induced by applying magnetic field either during growth or in the course of a post-deposition treatment. This study presents a comparative study of different methods — in-field sputtering deposition, annealing and ion irradiation — for inducing uniaxial magnetic anisotropy and even changing its easy-magnetization direction in polycrystalline Co films presenting collapsed hard-magnetization axes. The latter stands for the presence of prominent peaks in the angular variations of the remanent magnetization and coercivity centered ninety degrees off of the easy axis. The advantages, disadvantages and limitations of the three different techniques used to induce magnetic anisotropy are evaluated and discussed.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"640 ","pages":"Article 173805"},"PeriodicalIF":3.0,"publicationDate":"2025-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145882792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}