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Modeling composition-dependent melt dynamics and defect formation in multi-material additive manufacturing 多材料增材制造中依赖成分的熔体动力学和缺陷形成建模
IF 7.5 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2026-02-01 Epub Date: 2025-12-15 DOI: 10.1016/j.jmatprotec.2025.119185
Arvind Chouhan , Lutz Mädler , Nils Ellendt
Multi-material laser powder bed fusion (PBF-LB/M) enables the fabrication of components with tailored properties for advanced applications. However, large differences in thermophysical behavior between alloys such as Cu and SS316L introduce processing challenges, including lack of fusion, porosity, and thermal cracking at material interfaces. In this study, a coupled Discrete Element Method-Computational Fluid Dynamics (DEM-CFD) framework with a Volume of Fluid (VOF) methodology is developed to investigate melt pool dynamics, interfacial mixing, and solidification in laser powder bed fusion of Cu-SS316L. The model accounts for temperature and composition dependent thermophysical properties, diffusion-driven species transport, and laser–material interaction through a ray-tracing approach. Experimental validation is conducted to support the numerical findings. Simulations reveal that high Cu content results in smaller melt pools and lack of fusion defects due to Cu's high reflectivity and thermal diffusivity, whereas SS316L rich regions produce larger melt pools, reducing fusion defects but increasing keyhole porosity risk. At the Cu-SS316L interface, asymmetric melting and rapid solidification on the Cu side limit mixing, forming sharp diffusion boundaries. Steep thermal gradients across the interface induce differential thermal expansion, leading to thermal crack formation, particularly under high energy input. To mitigate such defects, a material grading strategy is proposed to smooth thermal gradients and reduce residual stresses. The proposed numerical framework offers critical insights into the mixing mechanisms at dissimilar interfaces for optimizing the multi-material PBF-LB/M process.
多材料激光粉末床融合(PBF-LB/M)能够制造具有定制性能的组件,用于高级应用。然而,Cu和SS316L等合金在热物理行为上的巨大差异给加工带来了挑战,包括缺乏熔合、气孔和材料界面的热裂。本研究采用离散元法-计算流体动力学(DEM-CFD)框架和流体体积(VOF)方法,研究了Cu-SS316L激光粉末床熔炼过程中熔池动力学、界面混合和凝固过程。该模型考虑了温度和成分相关的热物理性质、扩散驱动的物质输运以及通过射线追踪方法进行的激光-材料相互作用。实验验证了数值结果。模拟结果表明,由于Cu的高反射率和热扩散系数,高Cu含量导致熔池较小,熔合缺陷较少,而富含SS316L的区域熔池较大,熔合缺陷减少,但增加了锁孔孔隙风险。在Cu- ss316l界面处,Cu侧的不对称熔化和快速凝固限制了混合,形成了尖锐的扩散边界。界面上陡峭的热梯度诱导了不同的热膨胀,导致热裂纹的形成,特别是在高能量输入下。为了减轻这些缺陷,提出了一种材料分级策略,以平滑热梯度和减少残余应力。所提出的数值框架为优化多材料PBF-LB/M工艺提供了不同界面下混合机制的关键见解。
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引用次数: 0
Critical wrinkling analysis under bending-torsion coupled of spatial tubes during free bending forming 自由弯曲成形过程中空间管弯曲-扭转耦合下的临界起皱分析
IF 7.5 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2026-02-01 Epub Date: 2025-12-31 DOI: 10.1016/j.jmatprotec.2025.119192
Hui Wang, Jianjun Wu, Zekun Yang, Long Liu, Mengyuan Wang
Wrinkling instability of spatial tubes caused by inappropriate combinations of process parameters during free bending forming (FBF) severely restricts the forming stability. The correlation mechanism between the critical wrinkling loads (CWL) under bending-torsion coupled and the process window remains unclear, which makes it difficult to effectively control wrinkling defects of spatial tubes FBF. This study establishes a critical wrinkling analysis model under bending-torsion coupled (CWAM-CBT) of spatial tubes to calculate CWL. Based on the energy physical meaning of yielding and combined with the quadratic model of bending-torsion buckling (QM-BTB), approximate upper and lower bounds of buckling strength are proposed as the wrinkling criterion. The effects of load ratio, radius-to-thickness ratio, and tube material properties on the CWL and buckling strength are investigated. The validity of the analysis model is verified through a simplified finite element model. By combining the analysis model with finite element simulation of spatial tubes FBF, the critical wrinkling loading path of spatial tubes is constructed according to the relationship between process parameters and load ratios in the stable forming stage. The critical wrinkling loading path divides the process window into three zones, namely the wrinkling zone, the critical wrinkling zone, and the without wrinkling zone. Experiments on spatial tubes FBF have verified that the critical wrinkling loading path can accurately predict the wrinkling behavior under different process parameters, while further validating the effectiveness of the analytical model. This work enhances the in-depth understanding of the bending-torsion coupled wrinkling mechanism during spatial tubes FBF, thereby providing an effective method for the process optimization of complex spatial tube components.
在自由弯曲成形过程中,由于工艺参数组合不当导致空间管的起皱失稳,严重制约了成形稳定性。弯曲-扭转耦合作用下的临界起皱载荷与工艺窗口之间的相关机制尚不清楚,这给空间管FBF起皱缺陷的有效控制带来了困难。本文建立了弯曲-扭转耦合下空间管的临界起皱分析模型,用于计算空间管的弯曲-扭转耦合下的临界起皱。基于屈服的能量物理意义,结合弯曲-扭转屈曲二次模型(QM-BTB),提出了屈曲强度的近似上下边界作为起皱判据。研究了载荷比、径厚比和管材性能对CWL和屈曲强度的影响。通过简化有限元模型验证了分析模型的有效性。将分析模型与空间管FBF有限元模拟相结合,根据工艺参数与载荷比的关系,构建了空间管稳定成形阶段的临界起皱加载路径。临界起皱加载路径将工艺窗口划分为起皱区、临界起皱区和无起皱区三个区域。空间管FBF实验验证了临界起皱加载路径能够准确预测不同工艺参数下的起皱行为,进一步验证了分析模型的有效性。该工作加深了对空间管FBF弯曲-扭转耦合起皱机理的深入理解,从而为复杂空间管构件的工艺优化提供了有效的方法。
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引用次数: 0
Enhancing strain recovery ratio of NiTi ultrasonic spot welding joints via electric current treatment induced dislocations and precipitates 通过电流处理诱发位错和析出相,提高镍钛超声点焊接头应变恢复率
IF 7.5 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2026-02-01 Epub Date: 2025-12-10 DOI: 10.1016/j.jmatprotec.2025.119182
Zhiyuan Xu, Jinzhe Li, Kuangji Zhu, Yansong Zhang
This study investigates the fundamental effects of electric current treatment (ECT) on the microstructural evolution and functional performance of NiTi shape memory alloy (SMA) ultrasonic spot welding (USW) joints. Under optimal parameters (100 A, 2 min), the joints exhibit the highest recovery ratio during cyclic tensile testing. The enhancement arises from the intrinsic role of the electric current in regulating material performance: Electric current treatment accelerates elemental diffusion and promotes the formation of a high density of fine Ni4Ti3 precipitates at the interface, while the electron wind force lowers the energy barrier for 1/2[111] dislocation slip, generating high-density wavy dislocations. Together, these mechanisms demonstrate controlled microstructural tailoring that directly links processing conditions to dislocation dynamics, precipitate evolution, and functional stability. These findings reveal a fundamental materials-processing strategy for actively controlling microstructure and superelastic performance in NiTi SMAs, advancing understanding beyond conventional thermal or mechanical treatments.
研究了电流处理(ECT)对NiTi形状记忆合金(SMA)超声点焊(USW)接头组织演变和功能性能的影响。在最优参数(100 A, 2 min)下,节理在循环拉伸试验中恢复率最高。这种增强源于电流对材料性能的内在调节作用:电流处理加速了元素的扩散,促进了界面处高密度的Ni4Ti3细晶析出相的形成,而电子风作用力降低了1/2[111]位错滑移的能垒,产生高密度的波浪形位错。总之,这些机制证明了受控的微观结构剪裁,将加工条件与位错动力学、沉淀演化和功能稳定性直接联系起来。这些发现揭示了一种基本的材料加工策略,可以主动控制NiTi sma的微观结构和超弹性性能,超越传统的热处理或机械处理。
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引用次数: 0
Plasma-assisted polishing with silicon and silica plates: Comparison of interaction mechanism and achievement of atomically flat surfaces on single- and polycrystalline diamond 等离子体辅助抛光硅和硅片:单晶和多晶金刚石原子平面的相互作用机制和实现的比较
IF 7.5 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2026-02-01 Epub Date: 2025-12-16 DOI: 10.1016/j.jmatprotec.2025.119187
Jiayuan Dong , Sota Sugihara , Kafumi Fujiwara , Rongyan Sun , Yuji Ohkubo , Junsha Wang , Tadatomo Suga , Kazuya Yamamura
Due to its extreme hardness and chemical stability, diamond poses significant challenges for traditional machining processes. Plasma-assisted polishing (PAP) is a recently developed technique that integrates chemically active species from plasma with mechanical polishing, offering great potential for highly efficient and precise surface finishing of diamond materials. In this study, the polishing characteristics of silicon and silica plates were comprehensively investigated. The results confirmed the superiority of the silicon plate, which produced a smoother diamond surface and achieved a higher material removal rate (MRR) during PAP. To clarify the origin of this difference, the synergistic role of plasma irradiation was examined, as plasma is known to significantly enhance both the MRR and surface quality of diamond. Accordingly, X-ray photoelectron spectroscopy (XPS) measurements combined with density functional theory (DFT) calculations were conducted to gain deeper insights into the underlying mechanisms. The analyses revealed that both the polishing plate material and plasma irradiation play crucial roles in the PAP process. The higher chemical reactivity of silicon promotes bond formation at the tribological interface, thereby facilitating carbon removal. Meanwhile, oxygen radicals generated by plasma participate in interfacial reactions by oxidizing both the diamond and the polishing plate surface, as well as promoting the formation of oxygen-bridge bonds. This process enhances the diamond removal rate but simultaneously accelerates wear of the polishing plate surface. To further evaluate this effect, a long-duration polishing experiment was performed to investigate plate wear. The results showed that as wear progresses, the plate surface becomes smoother, leading to a decline in both polishing accuracy and the MRR of the diamond substrate. To counteract this effect, laser dressing was introduced to restore and sustain surface roughness, and its effectiveness was experimentally confirmed. Finally, PAP was applied to a 2-inch polycrystalline diamond substrate, achieving a grain-boundary step-free surface with a surface roughness (Sa) of approximately 0.3 nm. These findings provide practical guidance for the ultra-precision machining of diamond, deepen the understanding of coupled chemical–mechanical interactions at the tribological interface, and support the advancement of diamond-based components in semiconductor applications.
由于其极高的硬度和化学稳定性,金刚石对传统的加工工艺提出了重大挑战。等离子体辅助抛光(PAP)是最近发展起来的一项技术,它将等离子体中的化学活性物质与机械抛光相结合,为金刚石材料的高效、精确表面抛光提供了巨大的潜力。本文对硅及硅片的抛光特性进行了全面的研究。结果证实了硅板的优越性,它产生了更光滑的金刚石表面,并且在PAP过程中实现了更高的材料去除率(MRR)。为了澄清这种差异的来源,我们研究了等离子体辐照的协同作用,因为等离子体可以显著提高金刚石的MRR和表面质量。因此,x射线光电子能谱(XPS)测量与密度泛函理论(DFT)计算相结合,以深入了解潜在的机制。分析表明,抛光板材料和等离子体辐照在PAP过程中起着至关重要的作用。硅较高的化学反应活性促进了摩擦学界面的键形成,从而促进了碳的去除。同时,等离子体产生的氧自由基通过氧化金刚石和抛光片表面参与界面反应,促进氧桥键的形成。该工艺提高了金刚石的去除率,但同时也加速了抛光板表面的磨损。为了进一步评估这种效果,进行了长时间抛光实验,研究了板的磨损情况。结果表明:随着磨损的加剧,金刚石基体表面变得更加光滑,抛光精度和MRR均有所下降;为了抵消这种影响,引入激光修整来恢复和维持表面粗糙度,并通过实验证实了其有效性。最后,将PAP应用于2英寸的多晶金刚石衬底上,获得了表面粗糙度(Sa)约为0.3 nm的晶界无台阶表面。这些发现为金刚石的超精密加工提供了实践指导,加深了对摩擦学界面上耦合化学-机械相互作用的理解,并支持了金刚石基元件在半导体应用中的进步。
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引用次数: 0
Effect of thickness reduction of strong staggered spinning on the interface microstructure, texture evolution and mechanical properties of Al/Cu composite tubes 强交错纺丝减厚对Al/Cu复合管界面组织、织构演变及力学性能的影响
IF 7.5 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2026-02-01 Epub Date: 2025-12-03 DOI: 10.1016/j.jmatprotec.2025.119165
Huihui Nie , Yangyang Yang , Jinyi Li , Haoran Guo , Wentao Fan , Hongsheng Chen , Jun Zhou , Wenxian Wang
In this work, a novel type of Al/Cu composite tubes were successfully produced by strong staggered spinning with good surface quality, and the effect of thickness reductions on the microstructure and bonding mechanism of interface and the texture evolution of component layers. The results show that the original intermetallics layer in base material (BM) cracks and twists during spinning, and the contact area between fresh Al and Cu increases, resulting in a new diffusion layer containing AlCu, Al2Cu3 and Al4Cu9 phases from Al to Cu matrix, which presents a hardness between Cu and Al and facilitates stress transfer and deformation coordination. Cu atoms show a higher diffusion rate partly because grains, fragments or atomic clusters of Cu are pushed or sheared into Al and partly because abundant GBs and dislocations in Al provide excellent channels for the rapid diffusion of Cu atoms. With the increase of thickness reduction, Cu grains are elongated in S25 % and kinking of deformation zones are formed in S70 %, and the corresponding grain size decreases from 1.45μm to 0.98μm with a {111} < 112 > shear texture. Besides, Cu grains with orientation of < 001 > //AD are more prone to deformation and gradually change their orientation to < 111 > //AD, causing a growth of texture intensity in S70 %. The extent of grain refinement of Al near Cu is larger than that of Al away from the interface owing to the shear effect of interface, and the latter ones change from elongated grains to equiaxial grains as the increase of thickness reduction because of the extensive DRX, resulting Cube {100} < 001 > texture with the highest intensity of 14.1 among the three tubes. Interface delamination is not observed during tensile tests, although the interface microstructure varies. The well-bonded interface, refinement strengthening and work hardening enhance the UTS of S70 % to 172.89 MPa, increasing by 56.7 % compared with that of BM (110.34 MPa).
本文成功制备了一种具有良好表面质量的强交错纺丝新型Al/Cu复合管,研究了厚度减小对界面微观结构、键合机制和组分层织构演化的影响。结果表明:纺丝过程中基材(BM)中原有的金属间化合物层发生断裂和扭转,新Al与Cu之间的接触面积增大,在Al与Cu基体之间形成含有AlCu、Al2Cu3和Al4Cu9相的新扩散层,呈现介于Cu和Al之间的硬度,有利于应力传递和变形协调;Cu原子表现出较高的扩散速率,部分原因是Cu的晶粒、碎片或原子团簇被推入或剪切到Al中,部分原因是Al中丰富的gb和位错为Cu原子的快速扩散提供了良好的通道。随着减薄程度的增加,Cu晶粒在S25 %处拉长,在S70 %处形成扭结变形带,晶粒尺寸从1.45μm减小到0.98μm,呈{111}<; 112 >; 剪切织构。取向为<; 001 >; //AD的Cu晶粒更容易变形,取向逐渐转变为<; ;111 >; //AD,导致织构强度在S70 %处增长。由于界面的剪切作用,靠近Cu的Al晶粒细化程度大于远离界面的Al晶粒细化程度,而后者由于广泛的DRX作用,随着厚度减小的增加,由拉长晶粒转变为等轴晶粒,形成立方{100}<; 001 >; 织构,其强度为14.1,在三管中最高。在拉伸试验中,虽然界面微观结构有所变化,但未观察到界面分层。结合良好的界面、细化强化和加工硬化使S70的UTS提高 %至172.89 MPa,比BM的UTS(110.34 MPa)提高56.7% %。
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引用次数: 0
The mechanism of double pulsed current on improving microstructure and enhancing corrosion resistance of underwater welded 304 stainless steel 双脉冲电流改善304不锈钢水下焊接组织和提高耐蚀性的机理
IF 7.5 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2026-02-01 Epub Date: 2026-01-02 DOI: 10.1016/j.jmatprotec.2026.119196
Haipeng Liao , Peng Chi , Lina You , Jianliang Hu , Liang Cheng , Qin Zhang , Xiangmiao Wu , Lianyong Xu , Zhenmin Wang
To overcome the adverse effects of the uneven composition of the molten pool and the poor growth of columnar crystals caused by rapid cooling underwater during underwater welding on the corrosion performance of underwater welds, this study innovatively proposed a double pulsed current (DPC) waveform modulation technology. The influence of different DPC waveforms on the microstructure evolution and corrosion resistance of local dry underwater welded 304 stainless steel (SUS304) was systematically studied. The results show that DPC induced the periodic oscillation of arc energy distribution, which achieved the stirring effect on the underwater molten pool, thereby refining the grain structure by maximum 54.6 %, increasing the ferrite content by 43.2 % and making it uniformly distributed on the austenite matrix. It promoted the transformation of ferrite morphology from skeleton to lath, and enhanced the uniformity of the molten pool composition. With the decrease of the weak pulse peak current, the stirring effect exhibited a trend of first enhancing and then weakening. The corrosion failure mode of the SUS304 underwater weldment was pitting corrosion. The fine grain structure and higher ferrite content brought by DPC facilitated to form a stable passivation film structure, increasing its thickness by 173.1 %, thereby improving the corrosion resistance of underwater weldment. This work provides a flexible solution and solid foundation for underwater welding quality optimizing of austenitic stainless steel, which promote the application of underwater welding technology in the construction and repair of large underwater structures.
为了克服水下焊接过程中熔池组成不均匀和水下快速冷却导致柱状晶体生长不良对水下焊缝腐蚀性能的不利影响,本研究创新性地提出了双脉冲电流(DPC)波形调制技术。系统研究了不同DPC波形对局部水下干焊304不锈钢(SUS304)显微组织演变及耐蚀性能的影响。结果表明:DPC引起电弧能量分布的周期性振荡,对水下熔池产生搅拌作用,最大细化晶粒组织54.6% %,提高铁素体含量43.2% %,使其均匀分布在奥氏体基体上;促进了铁素体形态由骨架向板条的转变,提高了熔池成分的均匀性。随着弱脉冲峰值电流的减小,搅拌效果呈现先增强后减弱的趋势。SUS304水下焊件的腐蚀失效方式为点蚀。DPC带来的细晶粒组织和较高的铁素体含量有利于形成稳定的钝化膜结构,使其厚度增加173.1 %,从而提高了水下焊件的耐腐蚀性。本工作为奥氏体不锈钢水下焊接质量优化提供了灵活的解决方案和坚实的基础,促进了水下焊接技术在大型水下结构施工和修复中的应用。
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引用次数: 0
Laser polishing of LPBF IN718 forms dislocation cells and enhances high temperature ductility 激光抛光后的lpbfin718可形成位错单元,提高高温延展性
IF 7.5 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2026-02-01 Epub Date: 2025-12-05 DOI: 10.1016/j.jmatprotec.2025.119175
Qirui Zhang , Xing Li , Mingze Xin , Yingchun Guan
The high-temperature performance of current additively manufactured IN 718 alloy is critically limited by synergistic effects of surface-topography-induced stress concentrators, and subcritical porosity, particularly the thermal softening of the γ″ phase and its heterogeneous distribution within grains at 650 °C. Here, we propose a laser polishing treatment strategy that reconstructs both surface and sub-surface architecture of LPBF Inconel 718 alloy. This approach significantly reduces surface roughness from Ra ≥ 10 µm to Ra ≤ 1 µm, eliminates near-surface porosity by up to 65.7 %, and forms a refined, uniform nanometric dislocation cell. High-temperature tensile tests demonstrate plasticity performance nearly doubled at 650 °C with only 3 % yield strength loss. The detailed fractographic and microstructural analyses have confirmed that the enhanced plasticity originates from: (1) stabilized dislocation cell structures that homogenize stress distribution and suppress grain boundary cracking, (2) elimination of columnar grain morphology through dynamic recrystallization, and (3) delayed crack initiation and propagation between 550 and 650 ℃ due to dislocation cell structural confinement. Laser polishing produces a near-surface dislocation-cell structure engineering emerges as a transformative post-processing strategy, enabling additively manufactured IN718 alloy to overcome intrinsic high-temperature limitations through dislocation cell, thus redefining the strength-ductility paradigm at elevated temperatures.
当前增材制造的IN 718合金的高温性能受到表面形貌诱导的应力集中剂的协同作用和亚临界孔隙率的严重限制,特别是γ″相的热软化及其在650℃时晶粒内的非均质分布。在这里,我们提出了一种激光抛光处理策略,重建了LPBF Inconel 718合金的表面和亚表面结构。该方法显著降低了Ra≥ 10 µm至Ra≤ 1 µm的表面粗糙度,消除了高达65.7 %的近表面孔隙率,并形成了精细、均匀的纳米位错单元。高温拉伸试验表明,在650°C时,塑性性能几乎翻了一番,屈服强度损失仅为3 %。详细的断口和显微组织分析证实,塑性的增强源于:(1)稳定的位错胞结构,使应力分布均匀,抑制了晶界开裂;(2)通过动态再结晶消除了柱状晶粒形态;(3)由于位错胞结构限制,在550 ~ 650℃之间延迟了裂纹的萌生和扩展。激光抛光产生的近表面位错细胞结构工程成为一种变革性的后处理策略,使增材制造的IN718合金能够通过位错细胞克服固有的高温限制,从而重新定义高温下的强度-塑性范式。
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引用次数: 0
Generic strategies for suppressing liquation cracking through microstructural design in precipitation-strengthened Ni-based superalloys 通过组织设计抑制析出强化镍基高温合金液化裂纹的一般策略
IF 7.5 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2026-02-01 Epub Date: 2025-12-21 DOI: 10.1016/j.jmatprotec.2025.119188
Qingquan Chu , Shiyang Wang , Renliang Peng , Zhendong Wu , Xingyu Hou , Hongyu Zhang , Hongwei Zhang , Yuan Sun , Yizhou Zhou
Liquation cracking remains a critical challenge in the repair of precipitation-strengthened Ni-based superalloys, and convenient pre-weld heat treatment processes along with corresponding microstructural design principles are still underdeveloped. This study systematically investigates the influence of various pre-weld heat treatment processes on liquation cracking susceptibility in K4951 superalloy using tungsten inert gas welding, Gleeble thermomechanical simulation, and multi-scale characterization. The results provide a general framework correlating grain boundary orientation, precipitate morphology, and segregation behavior with liquation crack initiation. The critical grain boundary misorientation for liquation crack initiation is approximately 13°, with susceptibility reaching its maximum within the 20°–50° range, which stems from the stabilization of the intergranular liquid film at the coalescence temperature due to high grain-boundary energy, thereby leading to the highest cracking susceptibility. An optimized treatment combining solution and short-time aging effectively reduces hardness, tailors γ′ morphology, and alleviates Nb/Mo segregation, thereby suppressing the constitutional liquation of MC carbides and M3B2 borides. These findings demonstrate that the pre-weld heat treatment process represents a viable approach for designing microstructures with enhanced resistance to liquation cracking. The revealed mechanisms and strategies offer transferable guidance for developing crack-resistant repair procedures for various precipitation-strengthened Ni-based superalloys.
液相裂纹是析出强化镍基高温合金修复的关键问题,便捷的焊前热处理工艺及相应的组织设计原则尚不完善。采用钨惰性气体焊接、Gleeble热力学模拟和多尺度表征等方法,系统研究了不同焊前热处理工艺对K4951高温合金液化开裂敏感性的影响。结果提供了一个将晶界取向、析出相形态和偏析行为与液化裂纹起裂联系起来的总体框架。液化裂纹起裂的临界晶界取向偏差约为13°,在20°~ 50°范围内,裂纹敏感性达到最大值,这是由于晶界能高导致晶间液膜在聚结温度下趋于稳定,从而导致裂纹敏感性最高。固溶与短时效相结合的优化处理能有效降低硬度,调整γ′形态,缓解Nb/Mo偏析,从而抑制MC碳化物和M3B2硼化物的组成液化。这些发现表明,焊前热处理工艺是设计具有增强抗液化开裂能力的显微组织的可行方法。揭示的机制和策略为开发各种析出强化镍基高温合金的抗裂纹修复程序提供了可转移的指导。
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引用次数: 0
Uniform aluminum droplet deposition manufacturing in an open environment: Oxidation suppression and stable printing under coaxial shielding gas 开放环境下均匀铝滴沉积制造:同轴保护气体下的抗氧化和稳定印刷
IF 7.5 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2026-02-01 Epub Date: 2025-12-11 DOI: 10.1016/j.jmatprotec.2025.119183
Yi Zhou , Jun Luo , Lin Su , Lehua Qi
Employing opening shielding gas in metal micro-droplet deposition enables lightweight, real-time, eco-friendly manufacturing. However, aluminum alloys, highly sought-after for manufacturing, face challenges in equipment development and experimental research due to their high oxidation reactivity and thermal sensitivity. This study presents a novel approach that combines piezoelectric actuation with dynamic coaxial gas shielding. The method enables stable aluminum droplet printing with micron-level precision in an open environment. Through combined experiments and theoretical models, the impact of oxidation on droplet deposition dynamics, surface morphology, and formation quality was investigated. Results show that even a slight change in the deposition distance would cause significant variations in deposition and oxidation behavior. Increasing the deposition distance not only exacerbates droplet oxidation and dampens droplet oscillation, but also forms oxidation wrinkles on the droplet surface. A higher substrate feed speed also reduces the shielding gas effectiveness. This effect is particularly significant in multi-layer droplet pileup, where heat accumulation delays solidification and exacerbates oxidation in the upper-layer droplets. To address these challenges, a variable-speed printing strategy based on thermal management was proposed. This method suppresses droplet surface oxidation, enabling metallurgical bonding and stable part formation in open environments. This work provides both practical strategies and theoretical insights for oxidation control in high-temperature metal droplet printing under open-environment conditions.
在金属微滴沉积中采用开口保护气体,实现了轻量化、实时、环保的制造。然而,铝合金由于具有较高的氧化反应性和热敏性,在制造业中备受追捧,在设备开发和实验研究方面面临挑战。本文提出了一种将压电驱动与动态同轴气体保护相结合的新方法。该方法可在开放环境下实现微米级精度的稳定铝滴打印。通过实验和理论模型相结合的方法,研究了氧化对液滴沉积动力学、表面形貌和地层质量的影响。结果表明,即使沉积距离的微小变化也会引起沉积和氧化行为的显著变化。增大沉积距离不仅会加剧液滴氧化,抑制液滴振荡,还会在液滴表面形成氧化皱纹。较高的衬底进给速度也会降低保护气体的有效性。这种效应在多层液滴堆积中尤为显著,在多层液滴堆积中,热量积累延迟了凝固并加剧了上层液滴的氧化。为了解决这些问题,提出了一种基于热管理的变速打印策略。这种方法抑制液滴表面氧化,使冶金结合和稳定的零件形成在开放的环境。这项工作为开放环境下高温金属液滴打印氧化控制提供了实践策略和理论见解。
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引用次数: 0
High-efficiency submerged air jet chemical mechanical polishing at the atomic and close-to-atomic scale 在原子和近原子尺度上高效的浸没式空气射流化学机械抛光
IF 7.5 2区 材料科学 Q1 ENGINEERING, INDUSTRIAL Pub Date : 2026-02-01 Epub Date: 2026-01-02 DOI: 10.1016/j.jmatprotec.2025.119195
Zili Zhang , Song Yuan , Chi Fai Cheung , Wei Wu , Ze Li , Kangsen Li , Chunjin Wang
Fluid jet polishing (FJP) has demonstrated significant potential for polishing and figuring of surfaces with complex geometries owing to its flexibility and shape-adaptive capacity, particularly in high-precision optical applications such as X-ray reflectors, extreme ultraviolet lithography, and super-resolution imaging. Despite its advantages, FJP faces two major challenges that hinder its large-scale industrial adoption. The first challenge is the trade-off between surface quality and material removal efficiency. FJP relies solely on the mechanical impacts of abrasives for material removal, leaving erosion pits on the polished surface. Consequently, existing techniques struggle to achieve sub-nanometer precision while maintaining efficient material removal rates. The second challenge arises from the brittle fracture of materials during the FJP process, complicating the achievement of ultra-smooth surfaces with minimal subsurface damage. To address these limitations, this study introduces Submerged Air Jet Chemical Mechanical Polishing (SAJCMP). This method incorporates a novel material removal mechanism, referred to as “nano-reactive-abrasive-laden droplet-induced chemical mechanical removal,” which enables atomic and close-to-atomic precision while significantly improving polishing efficiency. The multi-scale material removal mechanism is elucidated through both experimental investigations and molecular dynamics (MD) simulations. Furthermore, the influence of various polishing parameters on the synergistic effects of chemical and mechanical actions is analyzed using computational fluid dynamics (CFD) simulations, complemented by experimental validation. Polishing experiments conducted on structured arrays and curved surfaces demonstrated that SAJCMP significantly enhances surface quality, preserves form accuracy, and minimizes subsurface damage.
流体射流抛光(FJP)由于其灵活性和形状自适应能力,在复杂几何形状表面的抛光和加工方面显示出巨大的潜力,特别是在高精度光学应用中,如x射线反射器、极紫外光刻和超分辨率成像。尽管有其优势,但FJP面临着阻碍其大规模工业应用的两个主要挑战。第一个挑战是表面质量和材料去除效率之间的权衡。FJP仅依靠磨料的机械冲击去除材料,在抛光表面留下侵蚀坑。因此,现有的技术努力达到亚纳米精度,同时保持有效的材料去除率。第二个挑战来自FJP过程中材料的脆性断裂,使实现超光滑表面和最小亚表面损伤变得复杂。为了解决这些局限性,本研究引入了水下喷气化学机械抛光(SAJCMP)。该方法采用了一种新型的材料去除机制,称为“纳米反应-负载磨料的液滴诱导化学机械去除”,可实现原子和接近原子的精度,同时显着提高抛光效率。通过实验研究和分子动力学模拟,阐明了多尺度材料的去除机理。此外,利用计算流体动力学(CFD)模拟分析了不同抛光参数对化学和机械作用协同效应的影响,并辅以实验验证。在结构阵列和曲面上进行的抛光实验表明,SAJCMP可以显著提高表面质量,保持形状精度,并最大限度地减少亚表面损伤。
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引用次数: 0
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Journal of Materials Processing Technology
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