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CARBON-BASED CATHODE CATALYSTS USED IN MICROBIAL FUEL CELLS FOR WASTEWATER TREATMENT AND ENERGY RECOVERY 碳基阴极催化剂用于微生物燃料电池的废水处理和能量回收
Pub Date : 2021-12-15 DOI: 10.32006/eeep.2021.3.2433
R. Boukoureshtlieva, T. Stankulov, A. Momchilov
In the past 20 years Microbial fuel cells (MFCs) have been extensively studied regarding the possibility of transforming organic waste directly into electricity. There are significant differences between MFCs and conventional low temperature Fuel Cells (FCs), which make MFCs attractive: biotic catalyst at the anode; the anodic fuel is complex organic waste; MFCs operate under mild reaction conditions (neutral pH, temperature and pressure), close to ambient levels as optimum.Like chemical fuel cells, MFCs are composed of anode and cathode. Oxygen is an ideal electron acceptor for MFCs because of its high redox potential, availability, and sustainability. However, the Oxygen Reduction Reaction (ORR) is kinetically sluggish, resulting in a large proportion of potential loss. Also, working conditions are quite different because of the type of complex media in which MFCs operate. In order to overcome these limitations, catalysts are often used to lower the overpotentials and accelerate the kinetics of the oxygen reduction reaction. One of the main challenges is the development of efficient and stable cathode catalysts for MFCs. By far, Pt and Pt-based catalysts (PGMs) have been extensively used, due to their catalytic efficiency in gas-diffusion electrodes. But the high cost and low durability have significantly lowered their utilization in MFCs.A variety of non-precious metal catalysts have been developed for MFC applications including carbon-based catalysts, carbon supported composite catalysts, Me-based catalysts and biocatalysts. It is supposed that the ORR catalyst used for wastewater treatment in MFCs is simple to synthesize, cost-effective, durable after long-term operation in wastewater, tolerant to poisoning and able to restore catalytic activity after cleaning. In this regard carbon-based catalyst may be the most promising candidate for practical applications. This study reviews different carbon-based ORR catalysts for MFC applications for wastewater treatment and energy recovery.
在过去的20年里,微生物燃料电池(MFCs)在将有机废物直接转化为电能的可能性方面得到了广泛的研究。mfc与传统的低温燃料电池(FCs)有显著的区别,这使得mfc具有吸引力:阳极有生物催化剂;阳极燃料是复杂的有机废物;mfc在温和的反应条件下运行(中性pH值、温度和压力),接近环境水平为最佳。与化学燃料电池一样,mfc也由阳极和阴极组成。氧是mfc理想的电子受体,因为它具有高氧化还原电位、可用性和可持续性。然而,氧还原反应(ORR)动力学迟缓,导致很大比例的潜在损失。此外,由于mfc操作的复杂介质类型,工作条件也大不相同。为了克服这些限制,通常使用催化剂来降低过电位并加速氧还原反应的动力学。其中一个主要的挑战是开发高效和稳定的mfc阴极催化剂。到目前为止,Pt和Pt基催化剂(PGMs)由于其在气体扩散电极中的催化效率而得到了广泛的应用。但高成本和低耐久性大大降低了其在mfc中的利用率。各种非贵金属催化剂已被开发用于MFC应用,包括碳基催化剂、碳负载复合催化剂、me基催化剂和生物催化剂。认为mfc中用于废水处理的ORR催化剂合成简单、成本低廉、在废水中长期运行后耐久、耐中毒、清洗后能恢复催化活性。在这方面,碳基催化剂可能是最有希望实际应用的候选者。本文综述了不同碳基ORR催化剂在MFC废水处理和能源回收中的应用。
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引用次数: 0
EXTREMUM SEEKING CONTROL OF TWO-STAGE ANAEROBIC DIGESTION SYSTEM: A MINI REVIEW 极值寻求控制的两级厌氧消化系统:一个小回顾
Pub Date : 2021-11-20 DOI: 10.32006/eeep.2021.2.1225
N. Christov, Haoping Wang, I. Simeonov
Anaerobic digestion (AD) is a biotechnological process, in which microorganisms degrade organic matter under anaerobic conditions to produce biogas. It has long been known that the two main species (acidogenic and methanogenic) in the community of microorganisms in AD differ in many aspects and the optimal conditions for their growth and development are different. Therefore, in AD in a single bioreactor (BR) (single-phase process), the optimal conditions are selected taking into account the slow-growing methanogens at the expense of fast-growing acidogens, which affects the efficiency of the whole process. This has led in recent years to the development of two-stage AD (TSAD), in which processes are divided into a cascade of two separate BRs. It is known that this division of the processes into two consecutive BRs leads to significantly higher energy yields for the two-phase system (H2 + CH4), compared to the traditional single-stage CH4 production process.In our previous studies different mathematical models of the TSAD have been developed. It was shown that in both BRs the input-output characteristics have a clear maximum, which allows the yields to increase significantly if operations are provided around the maximum points. However, in order to maintain the sustainability of the biogas plants work, it is necessary to introduce automatic control with sophisticated extremum seeking control (ESC) algorithms.This paper presents the pioneering research on ESC of AD process with production of hydrogen and methane. This research has been realized by the Department of Biotechnology at The Stephan Angeloff Institute of Microbiology (SAIM) and the French-Chinese Laboratory on Automatic Control and Signal Processing (LaFCAS), in collaboration with the Laboratory of Signals and Systems (L2S) at the French National Center of Scientific Research CNRS.
厌氧消化(AD)是微生物在厌氧条件下降解有机物产生沼气的生物技术过程。人们早就知道,AD中微生物群落的两个主要种类(产酸菌和产甲烷菌)在许多方面存在差异,它们生长发育的最佳条件也不同。因此,在单生物反应器(BR)的AD(单相工艺)中,以牺牲快速生长的产酸菌为代价,考虑生长缓慢的产甲烷菌,选择最优条件,会影响整个工艺的效率。这导致了近年来两阶段AD (TSAD)的发展,其中过程被划分为两个单独的br级联。众所周知,与传统的单阶段CH4生产工艺相比,将过程划分为两个连续的BRs可以显著提高两相系统(H2 + CH4)的能量产量。在我们以往的研究中,已经建立了不同的TSAD数学模型。结果表明,在两个BRs中,输入输出特性都有一个明显的最大值,如果在最大值附近提供操作,则可以显着增加产量。然而,为了保持沼气厂工作的可持续性,有必要引入复杂的极值寻求控制(ESC)算法的自动控制。本文介绍了AD制氢制甲烷工艺的ESC的开创性研究。这项研究是由Stephan Angeloff微生物研究所(SAIM)生物技术系、法中自动控制与信号处理实验室(LaFCAS)与法国国家科学研究中心(CNRS)信号与系统实验室(L2S)合作完成的。
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引用次数: 1
IMPROVEMENT OF BIOGAS PRODUCTION IN ANAEROBIC DIGESTION PROCESS 厌氧消化过程沼气产量的改进
Pub Date : 2021-11-15 DOI: 10.32006/eeep.2021.2.2631
Abdelhani Chaabna, S. Semcheddine
The production of biogas enables environmental preservation and sustainable development of rural areas and landlocked regions, as well as diversification of renewable energy resources. This paper is a contribution to improving the production of biogas by Sliding Mode Control (SMC).In the literature there are many models describing the behaviour of reactions during anaerobic digestion and used for control design. The AM2 model is one of the simplest models and can be exploited easily for the control design purposes. In this paper, the reduced model AM2 was exploited to develop and testing by simulations the robust control law SMC.The results obtained have proved the effectiveness of the control method proposed in this paper. A study of the robustness for monitoring and disturbances rejection demonstrated the great interest of this method, which is a non-linear technique and gives very good results in terms of robustness but it presents the problem of chattering. In practice, the chattering of the control action can cause premature wear of the actuators or parts of the system due to heavy oscillations. The chattering phenomenon is caused by the discontinuous term which appears in the control signal. This paper presents a solution to the chattering problem by replacing the discontinuous term with a continuous one. Different Simulations and comparisons are presented and interpreted with satisfactory results.
沼气的生产有助于农村地区和内陆地区的环境保护和可持续发展,以及可再生能源的多样化。本文为利用滑模控制(SMC)提高沼气产量做出了贡献。在文献中有许多模型描述厌氧消化过程中的反应行为,并用于控制设计。AM2模型是最简单的模型之一,可以很容易地用于控制设计目的。本文利用简化模型AM2开发了鲁棒控制律SMC,并进行了仿真测试。实验结果证明了本文所提出的控制方法的有效性。对监测和干扰抑制的鲁棒性研究表明了该方法的巨大兴趣,该方法是一种非线性技术,在鲁棒性方面取得了很好的结果,但它存在抖振问题。在实际操作中,控制动作的抖振会导致执行器或系统部件由于剧烈振荡而过早磨损。颤振现象是由控制信号中出现的不连续项引起的。本文提出了一种用连续项代替不连续项来解决颤振问题的方法。给出了不同的模拟和比较,并解释了令人满意的结果。
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引用次数: 2
PROBLEMS AND PERSPECTIVES IN ORGANIC CULTIVATION OF CEREALS – OVERVIEW 谷物有机栽培的问题与展望综述
Pub Date : 2021-11-15 DOI: 10.32006/eeep.2021.2.6675
Milen Chanev
In this study, an overview is made and a comparative analysis of articles, reports and materials dealing with organic farming of LWC, in the period 1970 to 2021 is performed. After analysing the literature, the following conclusions are made:Cereals occupy a particularly important place in organic farming, the main advantages of their cultivation are easy farming techniques, relatively easy mechanical weed control, disease control through rational crop rotation, opportunities for biological control of major pests.The soils in organic farming are better structured than those in conventional agriculture. Organic farming practices are related to improving soil properties, including the addition of organic matter to the soil, increasing the population of earthworms, biodiversity, soil fertility and more. Biological management provides a more stable soil structure. The larger pores observed in biological management have a beneficial effect on the physical properties of the soil, such as water flow and water capacity. The greater porosity of the soil provides a good habitat for soil microorganisms. Organic farming contributes to creating a better soil structure.Organic farming systems have traditionally been based on crop rotation. The aim of organic farming is to achieve a balance between crops that reduce soil fertility and crops that restore fertility. Crop rotation is the main tool that integrates the maintenance and development of soil fertility with various aspects of plant production in biological systems.Specialised selection programmes for creating varieties suitable for organic farming are too few due to the small number of users and high costs. The most common practise includes testing the suitability of conventional varieties in biological conditions, propagation and distribution of the best in the biological sector.Sowing norms directly control the sowing density, as well as the nutrient area of each plant. Changing sowing rates is also an excellent method for controlling weeding in biological fields.Concerning yields from organic and conventional agriculture, organic farms are less productive than conventional ones and their productivity is lower. But if environmental variables are taken into account, organic farms show the same or higher efficiency.A major problem facing organic farming in the future is the protection of fields from pollution by genetically modified organisms. An option for protecting biological fields is to maintain a buffer zone between the farm and the neighbouring conventional fields to prevent accidental contamination with GMOs.
在本研究中,对1970年至2021年期间与LWC有机农业有关的文章、报告和材料进行了概述和比较分析。通过对文献的分析,得出以下结论:谷物在有机农业中占有特别重要的地位,其种植的主要优点是耕作技术简单,机械除草相对容易,通过合理的轮作控制病害,生物防治主要害虫的机会。有机农业的土壤比传统农业的土壤结构更好。有机农业实践与改善土壤特性有关,包括向土壤中添加有机物、增加蚯蚓数量、生物多样性、土壤肥力等。生物管理提供了更稳定的土壤结构。在生物管理中观察到的较大孔隙对土壤的物理性质,如水流和水容量有有益的影响。土壤孔隙度越大,为土壤微生物提供了良好的栖息地。有机农业有助于创造更好的土壤结构。有机农业系统传统上以作物轮作为基础。有机农业的目标是在降低土壤肥力的作物和恢复土壤肥力的作物之间取得平衡。在生物系统中,作物轮作是将土壤肥力的维持和发展与植物生产的各个方面结合起来的主要工具。由于用户数量少、成本高,培育适合有机农业品种的专门选择项目太少。最常见的做法包括测试常规品种在生物条件下的适宜性,在生物部门繁殖和分配最好的品种。播种规范直接控制着播种密度,以及每株的养分面积。改变播量也是生物田间控制杂草的一种很好的方法。在有机农业和传统农业的产量方面,有机农场的产量低于传统农场,生产率也较低。但如果把环境因素考虑在内,有机农场的效率是一样的,甚至更高。未来有机农业面临的一个主要问题是保护农田免受转基因生物的污染。保护生物农田的一种选择是在农场和邻近的传统农田之间保持一个缓冲区,以防止转基因生物意外污染。
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引用次数: 0
PRODUCTION OF LACTIC ACID WORT-BASED BEVERAGES WITH MINT ESSENTIAL OIL ADDITION 添加薄荷精油的乳酸麦汁饮料的生产
Pub Date : 2021-11-15 DOI: 10.32006/eeep.2021.2.0511
Magdalena Trendafilova, B. Goranov, V. Shopska, Rositsa Denkova-Kostova, V. Lyubenova, Gergi Kostov
Lactic acid wort-based beverages are functional, non-alcoholic, with low pH value and produced by the fermentation of wort by lactic acid bacteria. They are not well accepted by consumers because of their poor sensory characteristics. Therefore, 0.025 and 0.05 % (v/v) mint (Mentha piperita) essential oil was used as a tool for improvement of lactic acid wort-based beverages organoleptic profile. Wort was produced by 60% Pilsen malt, 20% Vienna malt, and 20% Caramel Munich ІІ malt. It was inoculated with probiotic lactic acid bacteria Lactobacillus casei ssp. rhamnosus LBRC11 at a concentration of 107 cells/ml and fermentation was carried out at constant temperature of 25°C. The dynamics of pH, concentration of viable cells, phenolic compounds and antioxidant activity were monitored and the beverages obtained were evaluated by a tasting panel. The results showed that addition of mint essential oil in concentration of 0.025 and 0.05 % (v/v) inhibited lactic acid fermentation but improved the sensory profile of the beverage obtained only when 0.025% mint essential oil was added. Mint essential oil addition led to an increase in the total phenolic compounds concentration, phenolic acids and flavonoid phenolic compounds, measured by Folin–Ciocalteu and modified Glories method but resulted in a decrease in the antioxidant activity, measured by the DPPH radical scavenging assay, cupric reducing antioxidant power (CUPRAC) and ferric reducing antioxidant power (FRAP). The antioxidant activity measured by the ABTS radical scavenging assay was almost equal for the beverages with and without mint essential oil addition. The results obtained will be used for modeling of lactic acids fermentation with addition of mint essential oil for the production of functional wort-based beverages.
乳酸菌麦汁饮料是一种功能性、无酒精、低pH值的饮料,由乳酸菌发酵麦汁而成。由于它们的感官特性较差,因此不被消费者所接受。因此,以0.025和0.05% (v/v)薄荷精油作为改善乳酸麦汁饮料感官特征的工具。麦芽汁由60%的比尔森麦芽,20%的维也纳麦芽和20%的焦糖慕尼黑ІІ麦芽生产。用益生菌干酪乳杆菌(Lactobacillus casei ssp)接种。鼠李糖LBRC11浓度为107个细胞/ml, 25℃恒温发酵。监测了pH值、活细胞浓度、酚类化合物和抗氧化活性的动态变化,并由品尝小组对所得饮料进行了评估。结果表明,添加0.025%和0.05% (v/v)薄荷精油对乳酸发酵有抑制作用,但仅添加0.025%薄荷精油时,饮料的感官特性得到改善。薄荷精油的添加导致总酚类化合物浓度、酚酸和类黄酮酚类化合物(Folin-Ciocalteu和改良Glories法)的升高,但导致抗氧化活性(DPPH自由基清除试验、铜还原抗氧化能力(CUPRAC)和铁还原抗氧化能力(FRAP)的降低。用ABTS法测定添加和不添加薄荷精油饮料的抗氧化活性基本相等。所得结果将用于添加薄荷精油的乳酸发酵建模,用于生产功能性麦汁饮料。
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引用次数: 0
ACHIEVEMENTS IN SPACE EXPLORATIONS OF SPACE RESEARCH AND TECHNOLOGY INSTITUTE AT THE BULGARIAN ACADEMY OF SCIENCES 保加利亚科学院空间研究和技术研究所的空间探索成就
Pub Date : 2021-11-15 DOI: 10.32006/eeep.2021.2.4455
D. Borisova, G. Jelev, G. Sotirov
The paper is devoted to the achievements in space explorations of the Space Research and Technology Institute at the Bulgarian Academy of Sciences. There are considered the research activities and shown the projects and perspective directions for work and their applications.
这篇论文专门论述保加利亚科学院空间研究和技术研究所在空间探索方面取得的成就。对研究活动进行了考虑,并展示了工作的项目和前景方向及其应用。
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引用次数: 0
METHODS FOR IDENTIFICATION AND VISUALIZATION OF MUNICIPAL WASTE DISPOSAL SITES USING AEROSPACE DATA 利用航空航天数据识别和可视化城市垃圾处理场的方法
Pub Date : 2021-11-15 DOI: 10.32006/eeep.2021.2.5660
A. Dancheva
With the increase of temperatures in the summer, the danger of self-ignition of landfills for household waste increases, because of the biochemical processes that take place inside them. The most recent example is the municipal landfill for non-hazardous waste near the town of Dupnitsa. The self-ignition started on July 23, 2021 and continued to smolder for almost a week, which led to a great danger of burning the area around it or poisoning the population. It is believed that one of the main reasons is the great depth of the accumulated waste. There is an urgent need to do quality control of most of the landfills for municipal waste in our country. Some of them are located next to major river arteries or international roads. Non-compliance with the requirements for maintenance, management and operation hides a serious potential for an ecological catastrophe. It is essential that stricter measures are taken and that these landfills are monitored. The aim of the present work is to reveal the possibilities and potential of aerospace data and to show different methods for processing, interpretation, and visualization. They can easily identify, map, and survey a waste disposal site. Optical images of the multispectral instrument (MSI) of the Sentinel 2 platform and radar (SAR) data from the Sentinel 1 platform of the Copernicus program of the European Space Agency were used. Thermal bands from the Landsat 5 - 7 (ETM) and Landsat 8 (OLI/TIRS) sensors of the Landsat program were used to calculate the land surface temperature. Satellite images have been orthogonized, and composite images between optical and radar data have been created for better visualization.
随着夏季气温的升高,生活垃圾填埋场自燃的危险也在增加,因为其中发生了生化过程。最近的一个例子是杜普尼察镇附近的市政垃圾填埋场。自燃始于2021年7月23日,持续闷烧近一周,导致周围地区燃烧或毒害人口的极大危险。人们认为,其中一个主要原因是堆积的垃圾很深。我国大部分城市垃圾填埋场都迫切需要进行质量控制。其中一些位于主要河流干线或国际公路旁边。不遵守维护、管理和运营的要求,隐藏着严重的生态灾难的潜在危险。必须采取更严格的措施,并对这些堆填区进行监测。本工作的目的是揭示航空航天数据的可能性和潜力,并展示处理、解释和可视化的不同方法。他们可以很容易地识别、绘制和调查一个废物处理场。使用了Sentinel 2平台多光谱仪器(MSI)的光学图像和欧洲航天局哥白尼计划Sentinel 1平台的雷达(SAR)数据。利用Landsat项目Landsat 5 - 7 (ETM)和Landsat 8 (OLI/TIRS)传感器的热波段计算地表温度。卫星图像已被正交化,光学和雷达数据之间的合成图像已被创建,以更好地可视化。
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引用次数: 0
RADIATION SHIELDING AND DOSE ASSESSMENT OF THE CYCLOTRON FACILITY AT INRNE-BAS 内巴斯回旋加速器设施的辐射屏蔽及剂量评估
Pub Date : 2021-11-15 DOI: 10.32006/eeep.2021.2.6165
A. Demerdjiev, D. Tonev, Nikolai Goutev
The Institute for Nuclear Research and Nuclear Energy at the Bulgarian Academy of Sciences is working on the construction of a cyclotron centre. The facility is on a design level. At this stage of the project, an important task is the radiation shielding assessment of the facility. Nowadays, the Monte Carlo transport codes have become the tool of choice for solving this type of problem. In the current paper, the transport code FLUKA is used for the calculations. It is widely applied for shielding design and analysis of accelerators and their components. The distributions of the radiation fields inside and outside the cyclotron bunker are presented in this paper. Both different irradiation scenarios and bunker configurations are considered in the conducted Monte Carlo simulations. These results will be used as a guidance in site planning.
保加利亚科学院的核研究和核能研究所正在建造一个回旋加速器中心。该设施处于设计水平。在工程的这一阶段,一项重要的任务是对设施的辐射屏蔽评估。如今,蒙特卡洛运输代码已成为解决这类问题的首选工具。本文采用传输码FLUKA进行计算。它广泛应用于加速器及其部件的屏蔽设计和分析。本文给出了回旋加速器掩体内外辐射场的分布。在进行的蒙特卡罗模拟中,考虑了不同的辐照情景和掩体结构。这些结果将作为场地规划的指导。
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引用次数: 0
FOREST FIRES IN 2020 - ECONOMIC AND SOCIAL CONSEQUENCES 2020年的森林火灾——经济和社会后果
Pub Date : 2021-11-15 DOI: 10.32006/eeep.2021.2.3236
H. Tsakov, A. Alexandrov, Dafina Zoteva, O. Roeva
The continuing climatic anomalies and the changed social realities caused by the global COVID-19 pandemic impose new responsibilities and new solutions for the management and use of forests.Experts have proved that overexploitation of the forests and the annual burning of huge forest areas seriously jeopardize food security on a regional and global scale, the economic stability of communities reduces, and the environmental degradation increases.The fiery hell in Australia in 2020 is one of the worst wildlife disasters in modern history. There are more than 115,000 square kilometers of bushes and forests devastated, thousands of homes destroyed, people and over three million wild animals killed.In 2020, 499 fires were registered in the forest territories of Bulgaria with total area of 52455 dka. Deciduous and coniferous vegetation, grasses, border farmland and infrastructure are affected.The paper summarizes the financial damage and resources used to extinguish the fires in the forests of Bulgaria in 2020, regardless of their ownership.
全球COVID-19大流行造成的持续的气候异常和社会现实的变化给森林的管理和利用带来了新的责任和新的解决方案。专家证明,森林的过度开发和每年大面积的森林焚烧严重危及区域和全球范围内的粮食安全,降低了社区的经济稳定性,加剧了环境退化。2020年澳大利亚的火热地狱是现代历史上最严重的野生动物灾难之一。超过11.5万平方公里的灌木丛和森林遭到破坏,成千上万的房屋被毁,人类和300多万只野生动物死亡。2020年,保加利亚森林地区共发生499起火灾,总面积为52455平方公里。落叶和针叶林植被、草地、边境农田和基础设施受到影响。本文总结了2020年保加利亚森林火灾灭火的经济损失和资源,无论其所有权如何。
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引用次数: 1
ESTIMATION OF INDUSTRIAL MATERIAL FLOW PRODUCED BY „DEVNYA CEMENT“AD FOR REMEDIATION OF ACID SPILS “devnya水泥”所产生的工业物料流估算及酸泄漏修复
Pub Date : 2021-11-15 DOI: 10.32006/eeep.2021.2.3743
S. Marinova, E. Zlatareva
The issues of acidity and liming of soils were raised in Bulgaria more than 60-70 years ago. „Devnya Cement“ produces the Restart product, as an integral part of the process in the installation of cement clinker in a dry way and contains a high amount of calcium oxide (lime material). The aim of the study is to establish the effect of the studied product RESTART and possibilities for its use as an ameliorant on acid soils. A vegetation experiment was performed with a test crops of corn with different percentages of ameliorant. The chemical and physico-mechanical parameters of the treated soil were studied and the changes in the degree of soil acidity were established. Preliminary consumption rates of the ameliorant have been determined, when it is used for amelioration of acid soils. The chemical characteristics of the plant samples show, that the values of the chemical elements are in optimal concentrations and cannot have a harmful effect, when used as animal feed. To correct the acidity of soils with similar acidic properties as in the Devnya region, it may be recommended to apply about 1-2t/daa of the studied ameliorant.
保加利亚在六七十多年前就提出了土壤酸化和石灰化的问题。”Devnya水泥公司生产的Restart产品,作为干燥方式安装水泥熟料过程中不可或缺的一部分,含有大量的氧化钙(石灰材料)。本研究的目的是确定所研究产品RESTART的效果及其作为酸性土壤改良剂使用的可能性。以玉米为试验作物,用不同比例的改良剂进行了植被试验。研究了处理后土壤的化学和物理力学参数,确定了土壤酸度的变化规律。测定了该改良剂用于酸性土壤改良时的初步消耗率。植物样品的化学特性表明,当用作动物饲料时,化学元素的值处于最佳浓度,不会产生有害影响。为了纠正与Devnya地区类似的酸性土壤的酸度,可能建议使用所研究的改良剂约1-2t/d。
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引用次数: 0
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Ecological Engineering and Environment Protection
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