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THE INVESTIGATION OF USING ZIRCONIUM OXIDE MICROSPHERES IN PAPER COATING 氧化锆微球在纸张涂布中的应用研究
Pub Date : 2018-11-01 DOI: 10.24867/GRID-2018-P15
Y. Sesli, Zafer Ozomay, Emine Arman Kandirmaz, Arif Ozcan
Paper and cardboard are the raw materials frequently used in the printing industry. Pulp structure in papermaking process, surface roughness, and strength of electricity, moisture, thickness, thermal conductivity and optical properties are important parameter that influences printing quality. The surface structure of paper and cardboard needs to be improved for the quality prints. Among the methods of reducing paper surface roughness, sizing, coating and calendering processes can be counted. In the surface coating process, fillers are added to the formulations differently from sizing. While these fillers increase absorption, they also affect colour, opacity, gloss, surface roughness, contact angle etc. Materials containing zirconium oxide; due to the increase of strength, unaffected by chemical agents, high opacity and whiteness, it finds different usage area. In this study sizing and surface coating processes have been carried out in order to improve the surface properties of the paper, to improve the gloss, yellowness, whiteness, absorbency and contact angle of the paper. For this purpose, cationic starch and zirconium oxide coating formulations were prepared and applied onto paper with a paper coating tester under laboratory conditions. In addition, surface sizing with cationic starch has been done as a reference. Coated, sized and standard office type base papers were printed with IGT C1 offset printing test with magenta ink. The colour and gloss values of all printed and unprinted samples were measured. Printed samples, coated papers, surface sized papers and base papers were subjected to lightfastness test according to BS4321 and colour and gloss changes were examined with blue wool scale. The contact angle, absorbency and surface energies of all the obtained surfaces were determined. As a result, it has been found that zirconium oxide-added paper coatings have less glossy but lower contact angle and higher absorbency than surface sizing. It has been determined that the coated paper have worst yellowness and gloss changes with light aging. As a result, the addition of zirconium oxide to the coating improves printability.
纸和纸板是印刷工业中经常使用的原材料。纸浆在造纸过程中的结构、表面粗糙度、电强度、水分、厚度、导热性和光学性能是影响印刷质量的重要参数。纸张和纸板的表面结构需要改进,以获得高质量的印刷品。降低纸张表面粗糙度的方法包括施胶、涂布和压延等。在表面涂覆过程中,填料加入到配方中与施胶不同。当这些填料增加吸收率时,它们也会影响颜色、不透明度、光泽度、表面粗糙度、接触角等。含氧化锆的材料;由于强度增加,不受化学药剂的影响,透明度和白度高,因此有不同的使用领域。为了改善纸张的表面性能,提高纸张的光泽度、黄度、白度、吸收性和接触角,本研究进行了施胶和表面涂布工艺。为此,制备了阳离子淀粉和氧化锆涂层配方,并在实验室条件下使用纸张涂层测试仪将其涂在纸上。此外,还对阳离子淀粉的表面施胶进行了研究,作为参考。采用IGT C1胶印试验,用品红油墨对涂布、浆料和标准办公型原纸进行印刷。测量了所有印刷和未印刷样品的颜色和光泽值。印刷样品、铜版纸、表面施胶纸和原纸根据BS4321进行耐光性测试,并用蓝色羊毛标度检查颜色和光泽变化。测定了所得表面的接触角、吸光度和表面能。结果表明,与表面施胶相比,添加氧化锆的纸张涂料光泽度较低,但接触角较低,吸收性较高。经测定,光老化后铜版纸的黄度和光泽度变化最严重。因此,在涂层中加入氧化锆可改善印刷适性。
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引用次数: 1
POLY[(VINYL ALCOHOL) - (STEARIC ACID)] SYNTHESIS AND USE IN LAVENDER OIL CAPSULATION 聚乙烯醇-硬脂酸的合成及其在薰衣草油胶囊中的应用
Pub Date : 2018-11-01 DOI: 10.24867/GRID-2018-P23
Arif Ozcan, Emine Arman Kandirmaz
Block polymers are used frequently in medicine, nanotechnology, paint, cosmetic and many other fields. Generally, one of the blocks produced is hydrophilic and the other hydrophobic. With amphiphilic polymers, molecules in the lipophilic structure can be encapsulated. Encapsulation is being used industrially for the reason that it is easier to transport a substance chemically without deterioration and is less affected by environmental effects. Amphiphilic block copolymers composed of hydrophilic and hydrophobic monomer units are used in micellization. Copolymers can form different morphological structures, which can be repeated under controlled conditions, depending on the composition of the block copolymer in the aqueous medium, the concentration of the copolymer in the medium, the interactions between the hydrophilic chains forming the shell, the addition of the acid, base or salt, the organic solvent used, the polarity of the solvent used and the relative solubilities of the blocks in the solvent. In these systems, while the core acts as a repository that allows the active substances to be dissolved, the shell part provides the hydrophilic property to the whole system. With amphiphilic polymers, molecules in the lipophilic structure can be encapsulated. In the first part of this work, stearic acid substituted polyvinyl alcohol-hydrophilic lipophilic polymer was synthesized with acidic esterification reaction and the chemical structure of the polymer enlightened with ATR-FTIR. 1H-NMR method was used to determine the composition ratio of the polymer. In the second part of the study, lavender oil was added to the obtained polymer system and encapsulation was carried out after the interaction of the lavender oil and lipophilic end of polymer. The obtained capsule size analysis was performed by SEM. At the end of the work, paper coating formulations were prepared with microcapsules containing lavender oil and coated on standard office paper. The color and gloss properties of the coatings are measured. The results showed that the stearic acid substitute PVA polymer could be used in lavender oil encapsulation and made a suitable encapsulation for paper coatings.
嵌段聚合物广泛应用于医药、纳米技术、涂料、化妆品等领域。通常,产生的一种块是亲水的,另一种是疏水的。使用两亲性聚合物,亲脂结构的分子可以被封装。封装在工业上被使用的原因是它更容易在化学上运输物质而不变质,并且受环境影响的影响更小。由亲水和疏水单体单元组成的两亲嵌段共聚物用于胶束化。共聚物可以形成不同的形态结构,可以在控制条件下重复,这取决于嵌段共聚物在水介质中的组成,共聚物在介质中的浓度,形成壳的亲水链之间的相互作用,酸,碱或盐的添加,所使用的有机溶剂,所使用的溶剂的极性以及嵌段在溶剂中的相对溶解度。在这些系统中,虽然核心充当了允许活性物质溶解的储存库,但外壳部分为整个系统提供了亲水性。使用两亲性聚合物,亲脂结构的分子可以被封装。本文第一部分采用酸性酯化反应合成了硬脂酸取代聚乙烯醇-亲水亲脂聚合物,并用ATR-FTIR对聚合物的化学结构进行了揭示。采用1H-NMR法测定了聚合物的组成比。在第二部分的研究中,将薰衣草油加入到得到的聚合物体系中,并将薰衣草油与聚合物的亲脂端相互作用后进行包封。用扫描电镜对所得胶囊大小进行分析。在工作结束时,用含有薰衣草油的微胶囊制备了纸张涂层配方,并涂在标准办公纸上。测定了涂层的颜色和光泽性能。结果表明,硬脂酸替代聚乙烯醇聚合物可用于薰衣草精油的包封,并可作为纸张涂料的包封材料。
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引用次数: 2
DEVELOPING AUGMENTED REALITY APP FOR SMART PACKAGING 为智能包装开发增强现实应用
Pub Date : 2018-11-01 DOI: 10.24867/grid-2018-p53
S. Đurđević, D. Novaković, S. Adamović, Frank Boadu, Adriana Rodríguez Lezaca, Ž. Zeljković
Augmented Reality technology is increasingly present smart packaging feature. This paper presents the development of the smart packaging application that will provide information on the state of the product in packaging using the Augmented reality technology as a result. In order to control the product state, freshness control labels were printed with stimuli-responsive dyes in the form of specific code. These dyes are conceivable for all environmentally sensitive goods during storage and transport such as food, seeds, pharmaceuticals, cosmetics, electronics etc. These dyes are very useful for controlling the product freshness because they do not require an additional power supply and they can be monitored optically via the smart device camera. Stimuli-responsive dyes can report different environmental influences such as water/moisture, temperature, light, pressure, pH, etc. in a one-bit binary state or in gradually changing optical properties. The aim of the paper is the development of the application that will provide product freshness information based on packaging design (product type) and different environmental influences.
增强现实技术日益呈现出智能包装的特点。本文介绍了智能包装应用程序的发展,该应用程序将使用增强现实技术提供有关包装产品状态的信息。为了控制产品状态,鲜度控制标签上以特定编码的形式印有刺激反应染料。这些染料适用于所有在储存和运输过程中对环境敏感的商品,如食品、种子、药品、化妆品、电子产品等。这些染料对于控制产品新鲜度非常有用,因为它们不需要额外的电源,并且可以通过智能设备摄像头进行光学监控。刺激响应染料可以报告不同的环境影响,如水/湿度、温度、光、压力、pH值等,以一位二进制状态或逐渐变化的光学性质。本文的目的是开发基于包装设计(产品类型)和不同环境影响的产品新鲜度信息的应用程序。
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引用次数: 0
INVESTIGATION OF COLOR REPRODUCTION ACCURACY OF DIFFERENT INK JET AND ELECTROPHOTOGRAPHICAL PRINTING SYSTEMS 不同喷墨和电子照相印刷系统色彩再现精度的研究
Pub Date : 2018-11-01 DOI: 10.24867/GRID-2018-P36
R. Boeva, I. Spiridonov, S. Yordanov, T. Bozhkova, Z. Ivanov
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引用次数: 0
LCD DISPLAY LEGIBILITY INFLUENCED BY TYPEFACES AND COLOUR CONTRASTS 液晶显示器易读性受字体和色彩对比的影响
Pub Date : 2018-11-01 DOI: 10.24867/GRID-2018-P67
G. Franken, Maruša Pangerc, K. Možina
The evolution of high resolution displays, especially liquid crystal displays (LCD) that are among the most commonly used ones, has contributed to a larger circle of display readers. Despite high resolutions, problems in the legibility of typefaces still occur. Many typefaces may well be readable in print, but cause more difficulties when being read on displays. The aim of this study was to examine the influence of colour contrast on the legibility on LCDs to establish which type style is appropriate for a coloured text to be legible. Two different, specially designed typefaces for display use (one transitional, i.e. Georgia, and one sans-serif, i.e. Verdana) were tested in a satisfactory light-dark contrast of three different colour combinations involving five colours, i.e. dark grey (#1A1A1A) on white (#FFFFFF), dark blue (#142451) on light grey (#D9D9D9) and red (#C62026) on light grey. The reading speed and fixations were analysed with an eye-tracking device Tobii 120X. Different texts in both typefaces at 12 pt (16 px), in 130% leading and all colour combinations were displayed on a 24-inch LCD display. The forty tested individuals were between 19 and 22 years old. The results showed that the selection of a particular colour combination and contrast greatly affects the speed of reading and legibility. Less visible colour combinations of text and background were read more slowly than the more contrasting or visible ones at both typefaces. At both typefaces, it was seen that at a slower reading speed, more fixations were needed and vice-versa. It might also be concluded that the transitional typeface Georgia is more legible than the sans-serif typeface Verdana. Nevertheless, it appears that different colour combinations had different reading speeds at different typefaces (transitional vs sans-serif). An appropriate contrast and colour combination can facilitate legibility on displays.
高分辨率显示器的发展,特别是液晶显示器(LCD)是最常用的显示器之一,使得显示阅读器的圈子更大。尽管分辨率很高,但字体的易读性仍然存在问题。许多字体在印刷时可能很好读,但在显示器上阅读时会遇到更多困难。本研究的目的是检查颜色对比对lcd易读性的影响,以确定哪种类型的风格适合彩色文本易读。两种不同的,专门设计用于显示的字体(一种过渡字体,如Georgia,一种无衬线字体,如Verdana)在三种不同的颜色组合中进行了令人满意的明暗对比测试,涉及五种颜色,即深灰色(#1A1A1A)在白色(#FFFFFF)上,深蓝色(#142451)在浅灰色(#D9D9D9)上,红色(#C62026)在浅灰色上。用Tobii 120X眼动追踪仪分析阅读速度和注视。在24英寸的液晶显示器上显示了两种字体的不同文本,字体字号为12字号(16像素),字体前导率为130%,所有颜色组合。接受测试的40个人年龄在19到22岁之间。结果表明,特定颜色组合和对比度的选择极大地影响了阅读速度和易读性。在两种字体中,较不明显的文字和背景颜色组合的阅读速度要慢于对比鲜明或明显的文字和背景。在两种字体中,阅读速度较慢时,需要更多的注视,反之亦然。也可以得出结论,过渡字体Georgia比无衬线字体Verdana更易读。然而,不同的颜色组合在不同的字体(过渡字体和无衬线字体)下有不同的阅读速度。适当的对比度和颜色组合可以提高显示器的可读性。
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引用次数: 1
THE USE OF THE GREEN CHEMISTRY CONCEPT IN THE SYNTHESIS OF PACKAGING MATERIAL BASED ON POLYLACTIDE 绿色化学理念在聚乳酸基包装材料合成中的应用
Pub Date : 2018-11-01 DOI: 10.24867/GRID-2018-P35
N. Vukić, T. Erceg, V. Teofilović, L. Nikolić, S. Cakić, B. Simendić, I. Ristić
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引用次数: 0
GLYCEROL DERIVATIVES AS A MODERN PLASTICIZERS FOR STARCH FILMS 甘油衍生物作为淀粉薄膜的现代增塑剂
Pub Date : 2018-11-01 DOI: 10.24867/GRID-2018-P27
Zuzanna Żołek-Tryznowska, Ł. Cichy
Due ecological reasons there is a considerable interest in biodegradable films made from renewable and natural polymers, such as starch. Starch films are not meant to totally replace conventional packaging polymer films, but they might be a competition in several application, where traditional packaging cannot function. Moreover, starch as a raw material exhibit many benefits, such as relatively low price, abundant, biodegradable, and edible. Films prepared from starches are isotropic, odourless, tasteless, colourless, non-toxic and biodegradable. Finally, they are nutritious and safe, so they are used in the marketing of food. Unfortunately, the starch films present poor tensile properties and sensitivity to moisture content. In order to modify starch films properties the addition of various plasticizers is used. Commonly as a plasticizer water and glycerine is used. In this work, we use glycerol derivatives as a modern plasticizers for starch films obtained from potato starch by the tape casting technique, which allows to obtained films with constant thickness and 20 cm length. The influence of the ratio of various plasticizers: glycerol, pentaerythiolethoxylate, glycerol ethoxylate and Poligliceryn-3 on the mechanical properties and surface free energy was investigated. The plasticizers selected by us are characterized by a large number of functional hydroxyl groups. The starch films with the mixture of plasticisers reveal better usable properties and higher mechanical properties than with only one plasticizer. However, glycerol derivatives they cannot be used without the addition of glycerol. Furthermore, surface free energy was determinate by OwensWendt and van Oss-Chaudhury-Good method. The values of SFE are in the range 50–60 mJ/m2 and higher than values of typical plastic films, which are used in packaging industry. Obtained starch films are characterized by quite high polar component of SFE, with may be related with the influence of hydroxyl groups. Our results support the use of glycerol derivatives as modern plasticizers for biodegradable films and may open up new possibilities for applications of these compounds.
由于生态方面的原因,人们对由可再生和天然聚合物(如淀粉)制成的可生物降解薄膜非常感兴趣。淀粉薄膜并不意味着完全取代传统的包装聚合物薄膜,但它们可能在传统包装无法发挥作用的几个应用中成为竞争对手。此外,淀粉作为原料具有价格相对低廉、储量丰富、可生物降解、可食用等优点。由淀粉制备的薄膜具有各向同性、无臭、无味、无色、无毒、可生物降解等特点。最后,它们营养丰富且安全,因此它们被用于食品营销。不幸的是,淀粉薄膜表现出较差的拉伸性能和对水分含量的敏感性。为了改变淀粉薄膜的性能,加入了各种增塑剂。通常使用水和甘油作为增塑剂。在这项工作中,我们使用甘油衍生物作为现代增塑剂,通过胶带铸造技术从马铃薯淀粉中获得淀粉膜,该技术可以获得厚度恒定,长度为20厘米的薄膜。研究了不同增塑剂(甘油、季戊基硫乙氧基酸酯、甘油乙氧基酸酯和聚甘油-3)的配比对其力学性能和表面自由能的影响。我们选择的增塑剂的特点是含有大量的官能团。与单一增塑剂相比,混合增塑剂制备的淀粉膜具有更好的使用性能和更高的机械性能。然而,甘油衍生物,他们不能使用没有添加甘油。用OwensWendt法和van oss - chaudury - good法测定了表面自由能。SFE值在50-60 mJ/m2范围内,高于包装工业中使用的典型塑料薄膜的值。制备的淀粉膜具有较高的SFE极性组分,这可能与羟基的影响有关。我们的研究结果支持甘油衍生物作为生物可降解薄膜的现代增塑剂的使用,并可能为这些化合物的应用开辟新的可能性。
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引用次数: 3
THE IMPLEMENTATION OF GAMIFICATION IN MOBILE APPLICATION 游戏化在移动应用中的实现
Pub Date : 2018-11-01 DOI: 10.24867/GRID-2018-P71
Anamarija Šišić, L. Mandić, A. Agić, A. Poljicak
The aim of this research was to design mobile application that engages and motivates the end user to be physically active by promoting healthy habits. More and more services and mobile applications have begun to implement game elements. Competing application analysis found that the implementation of gamification should be unobtrusive recurring task cycle. The application was designated for young people and the results shown that implementation of gamification motivated them to be more active.
这项研究的目的是设计一个移动应用程序,通过促进健康的习惯来吸引和激励最终用户进行体育锻炼。越来越多的服务和手机应用开始植入游戏元素。竞争应用程序分析发现,游戏化的实现应该是不显眼的重复任务循环。该应用程序是为年轻人设计的,结果表明,游戏化的实施激励了他们更加活跃。
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引用次数: 0
FUTURE DEVELOPMENT OF SECURITY PRINTING AND RFID MARKS 安全印刷和rfid标识的未来发展
Pub Date : 2018-11-01 DOI: 10.24867/GRID-2018-P8
I. Spiridonov, K. Shterev, T. Bozhkova
In the current research are described various ways to protect secure documents, labels and packages, and the different security printing techniques applied today and the way they will evolve in future. Security end products constitute a wide variety of different types of documents, packages, labels and cards. The degree to which these need protection from counterfeiters, forgers and terrorists depends upon how deleterious their illegal procurement and misuse is to human welfare and financial stability. In order to reduce forgery and counterfeiting, the printing industry uses a big range of variable security methods and via different combinations, a high security document is achieved. Security printing devices are often categorized as overt, covert and machine-readable. Another advantage that the security printer has today is the ability to produce security documents on nontraditional, nonporous substrates such as plastic and polymer biaxially oriented polypropylene. Due to this complexity in its chemical structure documents and banknotes have a greater abrasion resistance and lower rate of tampering. Our research will aim not only to configure well known methods of security printing arts, but as well get a deeper view of what is coming up next and how for example could the RFID marks become an affordable and reliable security features of our future production.
在目前的研究中,描述了保护安全文件,标签和包装的各种方法,以及今天应用的不同安全印刷技术及其未来发展的方式。安防终端产品包括各种不同类型的文件、包装、标签和卡片。这些产品在多大程度上需要免受造假者、伪造者和恐怖分子的侵害,取决于它们的非法采购和滥用对人类福利和金融稳定的危害程度。为了减少伪造和伪造,印刷业使用了大量可变的安全方法,并通过不同的组合,实现了高安全性的文件。安全打印设备通常分为显性、隐性和机器可读三种。如今,安全打印机的另一个优势是能够在非传统的、无孔的基材上打印安全文件,如塑料和聚合物双轴定向聚丙烯。由于其化学结构的复杂性,文件和钞票具有更大的耐磨性和更低的篡改率。我们的研究不仅旨在配置众所周知的安全印刷艺术方法,而且还将深入了解下一步将会发生什么,例如RFID标记如何成为我们未来生产中负担得起且可靠的安全功能。
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引用次数: 5
REPEATABILITY AND REPRODUCTION ACCURACY IN ELECTROPHOTOGRAPHY FOR COLOR DIFFERENCE EVALUATIONS 电照相色差评价的重复性和再现精度
Pub Date : 2018-11-01 DOI: 10.24867/GRID-2018-P38
S. Dedijer, Ivana Tomic, Magdolna Pál, I. Jurič, Ž. Pavlović, N. Milic
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引用次数: 0
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Proceedings of 9th International Symposium on Graphic Engineering and Design
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