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Determination of Different Forms of Phosphorus in Waters of the Wastewater Treatment Plant in Durres, Before and After Treatment 杜拉斯污水处理厂污水处理前后不同形态磷的测定
V. Hoxha, A. Jano, K. Vaso, Enkela Poro
- The purpose of this article is to present the results of a study on the water of the wastewater treatment plant in Durrës. For this, a study was conducted during the months of May, June and July 2021 which was based on the determination of the different forms of phosphorus in water, as one of the main nutrients, and responsible for the eutrophication of waters. Representative sampling was done before treatment, after treatment and in wetlands. Storage and transport of samples, based on recommended standard methods. Four different forms of phosphorus were identified (orthophosphate, total phosphorus, condensed phosphorus and organic phosphorus). The selection of standard analysis methods was made by APHA and DIN and for each of them the performance parameters of the method were defined (sensitivity, dictation limit and linear area of measurements). The results obtained were processed and compared with "On permissible discharge rates and zoning criteria for aquatic receiving environments", and EU Directive 91/271 / EEC. The results obtained from the study, showed the higher concentrations of different forms of phosphorus at the station before treatment, but only the values of total phosphorus concentration resulted outside the allowed norms. At the post-treatment station or in wetlands it is noticed that the concentrations of the studied of different forms of phosphorus are within the allowed norms, with the exception of the total phosphorus concentration. Therefore, for the reduction and recovery of phosphorus from water of wastewater treatment plants, the forms of phosphorus that are present must be considered.
-本文的目的是介绍Durrës污水处理厂水的研究结果。为此,在2021年5月、6月和7月期间进行了一项研究,其基础是确定水中不同形式的磷,磷是导致水体富营养化的主要营养物质之一。分别在处理前、处理后和湿地进行了代表性采样。样品的储存和运输,基于推荐的标准方法。鉴定出四种不同形态的磷(正磷酸盐、全磷、凝聚磷和有机磷)。采用APHA法和DIN法进行标准分析方法的选择,并对每种方法的性能参数(灵敏度、听写极限和测量线性面积)进行了定义。对所得结果进行了处理,并与“关于水生接收环境的允许排放率和分区标准”和欧盟指令91/271 / EEC进行了比较。研究结果表明,处理前该站不同形态的磷浓度较高,但只有总磷浓度超出允许的标准。在后处理站或湿地,除了总磷浓度外,所研究的不同形态磷的浓度都在允许的标准范围内。因此,为了从污水处理厂的水中减少和回收磷,必须考虑存在的磷的形式。
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引用次数: 0
Analysis of Carbopol And Triethanolamine Concentration in The Viscoplastic Properties of Aqueous Solution 卡泊尔和三乙醇胺浓度对水溶液粘塑性性能的影响
D. M. Iceri, J. L. Biazussi, C. Geest, R. Thompson, M. Castro
Materials with viscoplastic characteristics have being widely studied due to their applicability in industries, but also because of their common presence in nature. Fluids with such characteristic can be modelled by the equation known as Herschel-Bulkley. This type of fluid has a yield stress property, which is extremely important to characterize it. Carbopol solution is the most common fluid used for experimental studies involving this type of fluid. However, the Carbopol solution needs a neutralizing agent, which acts as a pH regulator, prevents the formation of fungus, but it also affects the yield stress. In the present work, measurements of the yield stress from flow curve tests, performed in a rheometer, were made for different combinations of Carbopol and Triethanolamine (neutralizing agent) concentrations. The yield stress increased with the increment in the concentration of both, Carbopol and Triethanolamine (TEA), in addition, it was observed that TEA concentrations must be greater than 500 ppm to avoid the formation of fungi and less than 700 ppm to obtain a homogeneous solution.
具有粘塑性特性的材料由于其在工业中的适用性以及它们在自然界中的普遍存在而受到广泛的研究。具有这种特性的流体可以用赫歇尔-巴尔克利方程来模拟。这种类型的流体具有屈服应力特性,这对表征它非常重要。卡波波尔溶液是涉及这类液体的实验研究中最常用的液体。然而,Carbopol溶液需要一种中和剂,它作为pH调节器,防止真菌的形成,但它也会影响屈服应力。在本工作中,通过流变仪进行的流动曲线试验测量了卡波波尔和三乙醇胺(中和剂)浓度的不同组合的屈服应力。屈服应力随卡波波尔和三乙醇胺(TEA)浓度的增加而增加,另外,TEA浓度必须大于500 ppm才能避免真菌的形成,小于700 ppm才能获得均匀的溶液。
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引用次数: 1
Laboratory Investigation of Hybrid Nanoparticles Injection for Enhanced Oil Recovery Process 混合纳米颗粒注入提高采收率的实验室研究
M. Hashmet, Peyman Peyman, Yernur Satay
- Nanoparticles due to their unique characteristics are gaining attraction for enhanced oil recovery (EOR) applications. Nanoparticles during the EOR process may activate many mechanisms, particularly wettability alteration, and thus improve the recovery factor. Silica nanoparticle has been largely testified for EOR. The effect of alumina nanoparticles for EOR is also being investigated recently. Their combination may enhance their performance in wettability alteration. In this research, we studied the wettability alteration and recovery performance of the hybrid nanoparticles. A series of experiments were conducted starting from zeta potential and contact angle measurement to determine optimum concentrations of silica, alumina, and hybrid nanoparticles. After dispersing nanoparticles (alone and hybrid), solutions were homogenized using ultrasonic homogenizer. The zeta potential results showed that the silica nanofluid could stay stable for at least 3 days without the need for a stabilizer. However, a stabilizer (SDBS) is required to prepare stable alumina and hybrid nanofluid. Baseline experiments were conducted with the stabilizer to quantify the performance of the stabilizer. Later, contact angles were measured (at room temperature and 80 °C) to analyze the effect of the nanofluid on rock/oil/brine systems and to determine the optimal nanofluid concentration. The results of contact angle experiments prove that, for both temperatures (room and 80 °C), maximum alteration in wettability was shown by the hybrid nanoparticle mixture (0.1wt%silica+0.05wt%Alumina), 29° and 33°, respectively. Finally, coreflooding tests were conducted to study the performance of the optimal nanofluid in enhancing oil recovery. The coreflood experiment was conducted with optimum hybrid nanofluid at 80 °C. The recovery factor recorded with Caspian Seawater was 42%, and silica nanofluid improved the recovery to 46%. The injection was followed by a hybrid nanofluid, which increased the recovery factor to 73%. The results presented in this study prove that hybrid nanoparticle injection improves the performance as compared to standalone nanoparticles.
纳米颗粒由于其独特的特性,在提高石油采收率(EOR)应用中越来越受欢迎。纳米颗粒在提高采收率过程中可以激活多种机制,特别是润湿性改变,从而提高采收率。纳米二氧化硅在提高采收率方面得到了广泛的应用。氧化铝纳米颗粒在提高采收率方面的作用最近也在研究中。它们的组合可以提高润湿性变化的性能。在本研究中,我们研究了杂化纳米颗粒的润湿性变化和采收率。从zeta电位和接触角测量开始,进行了一系列实验,以确定二氧化硅、氧化铝和混合纳米颗粒的最佳浓度。分散纳米颗粒(单独和混合)后,使用超声波均质机对溶液进行均质。zeta电位结果表明,在不需要稳定剂的情况下,二氧化硅纳米流体可以保持至少3天的稳定。然而,制备稳定的氧化铝和杂化纳米流体需要稳定剂(SDBS)。为了量化稳定器的性能,对稳定器进行了基线实验。随后,测量了接触角(室温和80℃),以分析纳米流体对岩石/油/盐水体系的影响,并确定最佳纳米流体浓度。接触角实验结果表明,在室温和80℃两种温度下,混合纳米颗粒混合物(0.1wt%二氧化硅+0.05wt%氧化铝)的润湿性变化最大,分别为29°和33°。最后,进行了岩心驱油试验,研究了最佳纳米流体提高采收率的性能。在80℃条件下,采用最佳混合纳米流体进行岩心驱替实验。里海海水的采收率为42%,二氧化硅纳米流体将采收率提高到46%。随后注入混合纳米流体,将采收率提高到73%。本研究的结果证明,与单独的纳米颗粒相比,混合纳米颗粒注入提高了性能。
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引用次数: 0
Analysis Of An Accident In The Mining Sector Using The Feyer and Williamson Method 用Feyer和Williamson方法分析一起矿业事故
L. Sanmiquel, M. Bascompta, Nor Sidki, J. Vives, J. Lopez
Extended Abstract This research presents the case of the analysis of an accident in an aggregate processing plant through the Feyer & Williamson method [1,2]. This method was designed to allow the coding of a time sequence of up to 3 events that have preceded a given accident. These events are called Preceding Events and are characterised as determining factors for the genesis of the accident. In addition, causal factors can also be identified, which are considered to have influenced the accident but not in such a decisive way as the events. The method makes it possible to identify 4 types of events and 8 types of causal factors, as well as different types of human error that have directly influenced the origin of the accident. Results: Once all the causes and factors that directly or indirectly influence the origin of the accident analysed according to the method indicated have been identified and classified, all of them are organised graphically, which allows a quick and simple understanding of the circumstances of the accident.
本研究采用Feyer & Williamson方法对某骨料加工厂的事故进行分析[1,2]。这种方法被设计成允许在给定事故发生之前对多达3个事件的时间序列进行编码。这些事件被称为前事件,并被定性为事故发生的决定性因素。此外,还可以确定因果因素,这些因素被认为影响了事故,但不像事件那样具有决定性的影响。该方法可以识别4种类型的事件和8种类型的因果因素,以及直接影响事故起源的不同类型的人为错误。结果:一旦确定和分类了所有直接或间接影响事故起因的原因和因素,并根据所述方法进行了分析,所有这些原因和因素都以图形形式组织起来,从而可以快速而简单地了解事故的情况。
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引用次数: 0
Modeling a Large Thermal Energy Storage System Using RANS Turbulence Models and High-Resolution Measurement Data 基于RANS湍流模型和高分辨率测量数据的大型热能存储系统建模
B. Krüger, F. Dammel, P. Stephan
– A novel approach to model sensible Thermal Energy Storage (TES) Systems has been developed. Three separate models are used to model the overall system. High-resolution isothermal models are used to simulate the flow around the inlet and outlet diffusers. Velocity data is then used to provide accurate boundary conditions for a simplified non-isothermal model to model the temperature distribution and flow in the main body of the TES. In this short paper, a laminar model is compared with 2 turbulent models and measurement data. Analysis shows the need for further work as the thermocline width increases much faster in all numerical models than seen in the measurement data.
-开发了一种新的方法来模拟显热储能(TES)系统。三个独立的模型用于对整个系统建模。采用高分辨率等温模型模拟进出口扩散器周围的流动。然后利用速度数据为简化的非等温模型提供精确的边界条件,以模拟TES主体内的温度分布和流动。本文将层流模型与两种湍流模型及实测数据进行了比较。分析表明需要进一步的工作,因为所有数值模型中的温跃层宽度增加的速度比测量数据中看到的要快得多。
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引用次数: 0
Acoustic Emissions Monitoring In Soil Compressibility Laboratory Tests 土壤压缩性实验室试验中的声发射监测
Danny Xavier Villalva-León, G. García-Ros, J. Sánchez-Pérez, E. Castro-Rodríguez,, María Rosa Mena-Requena, M. Conesa
Extended Abstract The detection and monitoring of acoustic emissions in soil mechanics is a study technique still little developed and investigated, although the applications that can be derived from this new discipline are very numerous. Among these, the most interesting from the geotechnical point of view are the study of soil compressibility [1] and the ground shear strength [2]. For this reason, in the Geotechnics Laboratory of the Universidad Politécnica de Cartagena (UPCT) an investigation that aims to delve into this discipline has been started, in order to find trends or correlations between the compressibility and shear parameters of the soil and the characteristics of the acoustic emissions generated by the relative movement of grains. The research is in its initial phase, although all the necessary equipment to carry it out is already available: in addition to the classic laboratory equipment (oedometric bench; uniaxial loading cell for simple compression; direct shear equipment), there is a multi-channel acoustic emission capture equipment (Vallen AMSY-6), to which a pair of low-frequency sensors (with sensitivity between 10-100 kHz) and another pair of medium-high-frequency (with sensitivity < 900 kHz) are connected.
土力学中声发射的探测和监测是一项尚未得到充分发展和研究的研究技术,尽管这门新学科的应用范围非常广泛。其中,从岩土力学的角度来看,最有趣的是对土壤压缩性[1]和地面抗剪强度[2]的研究。出于这个原因,在卡塔赫纳波利特-卡塔赫纳大学(UPCT)的岩土工程实验室,一项旨在深入研究这一学科的研究已经开始,目的是找到土壤的压缩性和剪切参数与颗粒相对运动产生的声发射特征之间的趋势或相关性。这项研究还处于初始阶段,尽管所有必要的设备都已经具备:除了经典的实验室设备(测径台;用于简单压缩的单轴加载单元;直接剪切设备),有多通道声发射捕获设备(valallen AMSY-6),连接一对低频传感器(灵敏度在10- 100khz之间)和另一对中高频传感器(灵敏度< 900khz)。
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引用次数: 0
Heat Transfer and Velocity Measurement of Laminar Pipe Flow Induced by Ultrasound Released along Mainstream Direction 主流方向超声诱导层流管道流动的传热与速度测量
Teerapat Thungthong, Kanet Katchasuwanmanee, Jirachai Mingbunjerdsuk, W. Chaiworapuek, K. Khaothong
In this paper, heat transfer characteristics of laminar pipe flow using low frequency ultrasound released along the mainstream direction were investigated experimentally. The test section was a square duct with an inner cross-sectional area of 60 mm2 and a length of 1500 mm. The Reynolds number ranged between 400 and 1,600. A heater with a power of 400 W was installed at the bottom wall to heat the water at 23 °C. Thermocouples were used to measure the wall temperature at a distance of 0.16-0.58 m with an interval of 0.07 m. The ultrasonic transducer with a frequency of 28-80 kHz was set at the entrance to release the waves in a streamwise direction. In addition, the flow behaviour of the water flow induced by ultrasound was illustrated by Particle Image Velocimetry (PIV). The results showed that the heat transfer enhancement factor (HTEF) was increased when the heating wall was close to the ultrasonic transducer position. In particular, acoustic streaming was found to convect the heat transfer by swerving from the entrance to the heating wall. The maximum HTEF of 163.04% was achieved using 28 kHz ultrasonic waves at Reynold number of 400. These results would clearly demonstrate the potential of ultrasonic waves to improve heat transfer in a thermal system in the future.
实验研究了沿主流方向释放的低频超声对层流管道流动传热特性的影响。试验断面为方形风管,内截面积为60mm2,长度为1500mm。雷诺数在400到1600之间。底部壁面安装功率为400w的加热器,将水加热至23℃。用热电偶测量距离为0.16-0.58 m的壁面温度,间隔为0.07 m。在入口处设置频率为28- 80khz的超声波换能器,以顺流方向释放声波。此外,利用粒子图像测速技术(PIV)对超声诱导水流的流动特性进行了表征。结果表明,当加热壁靠近超声换能器位置时,传热增强因子(HTEF)增大;特别地,发现声流通过从入口转向加热壁来对流传热。在雷诺数为400的条件下,使用28 kHz的超声波,最大HTEF为163.04%。这些结果将清楚地表明,超声波的潜力,以改善传热系统在未来。
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引用次数: 0
Recovery of Particle Reinforced Composite 3D Printing Filament from Recycled Industrial Polypropylene and Glass Fibre Waste 从工业聚丙烯和玻璃纤维废料中回收颗粒增强复合材料3D打印长丝
Omid Sam-Daliri, T. Flanagan, P. Ghabezi, W. Finnegan, Sinéad Mitchell, N. Harrison
Extended Abstract The use of fibre-reinforced polymer composites has increased in recent years across various industries, such as aircraft, energy, sports, infrastructure, medical, defence, electronics, and automobile industries [1]. In particular, carbon fibre reinforced polymers (CFRP) and glass fibre reinforced polymers (GFRP) [1, 2] regularly demonstrate favourable strength-to-weight ratios at multiple size scales. Until recently, these materials have been readily adopted without complete consideration of the environmental impacts of the entire life cycle of the product- from raw material extraction, production, use and end-of-life outcome. In addition, composite waste occurs during production processes. Thus, finding efficient, commercially viable and effective reuse, remanufacturing and recycling routes is now of crucial importance to ensure sustainable continued use of composites. In addition, it is imperative that every effort be made to reduce the amount of waste material that is either
近年来,纤维增强聚合物复合材料在飞机、能源、体育、基础设施、医疗、国防、电子和汽车等各个行业的应用都有所增加[1]。特别是,碳纤维增强聚合物(CFRP)和玻璃纤维增强聚合物(GFRP)[1,2]在多种尺寸尺度下通常表现出良好的强度-重量比。直到最近,这些材料都是在没有充分考虑产品整个生命周期对环境的影响的情况下被采用的——从原材料的提取、生产、使用到生命周期结束的结果。此外,在生产过程中也会产生复合废弃物。因此,寻找高效、商业上可行和有效的再利用、再制造和回收路线对于确保复合材料的可持续持续使用至关重要。此外,尽一切努力减少垃圾的数量是至关重要的
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引用次数: 10
Conjugated Phonon and Hot Carrier Transport in 2D Materials 二维材料中的共轭声子和热载流子输运
Xinwei Wang
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引用次数: 0
Pseudospectral Modelling For Flow past a Long Flexible Cylinder 长柔性圆柱体流动的伪谱模拟
M. Chern, Jhe-Ming Lin
Extended Abstract The current study aims to simulate the complex oscillation of a long flexible cylinder. This fluid-structure interaction problem is important in ocean engineering, civil engineering and so on. For instance, a riser in ocean has to interact with the current. Another example is a cable of a bridge, which vibrates due to coming wind. An in-house numerical model was developed using pseudopsectral methods [1] coupled with the direct-forcing immersed boundary (DFIB) method [2] to investigate this phenomenon. The model was validated first by simulations of flow through a fixed cylinder in a free stream. Drag coefficients obtained by the proposed model and other publications were compared and good agreement was found. The preciseness and convergence analysis are presented in the validation section. A solid body can be identified more precisely using the adopted PSME-DFIB model. The proposed numerical model was used to simulate the flow-induced vibration of an elastically mounted rigid cylinder. The variation of vibration frequency and maximum amplitude with respect to Reynolds number and reduced velocity was investigated in the lock-in region and compared against published literature. When solids move through grids, the coordinate transformation can eliminate noise in the resultant force, as determined by the numerical integral. In addition, the in-house PSME-DFIB model was used to investigate the flow-induced vibration of an infinitely long flexible cylinder at various wavelengths, cylinder tensions at low Reynolds numbers. A short-wavelength cylinder was considered due to the feasibility of simulations. The effects of cylinder vibration on the flow patterns were also explored in detail. Given the initial displacement, the cylinder vibration was produced a stable standing wave response in the early stage, and gradually turned into
本研究的目的是模拟一个长柔性圆柱的复杂振荡。流固耦合问题在海洋工程、土木工程等领域具有重要意义。例如,海洋中的立管必须与洋流相互作用。另一个例子是一座桥的缆绳,它会因为来风而振动。利用伪谱方法[1]和直接强迫浸入边界(DFIB)方法[2]建立了内部数值模型来研究这一现象。该模型首先通过自由流中固定圆柱的流动模拟进行了验证。将该模型得到的阻力系数与其他文献得到的阻力系数进行了比较,结果吻合较好。验证部分给出了算法的精确性和收敛性分析。采用pme - dfib模型可以更精确地识别实体。采用所建立的数值模型对弹性安装刚性圆柱的流激振动进行了数值模拟。研究了锁紧区振动频率和最大振幅随雷诺数和减速速度的变化,并与已发表的文献进行了比较。当固体穿过网格时,坐标变换可以消除合力中的噪声,这是由数值积分决定的。此外,利用自制的pme - dfib模型研究了无限长柔性圆柱体在不同波长下的流激振动和低雷诺数下的圆柱体张力。考虑到模拟的可行性,我们考虑了短波长的圆柱体。还详细探讨了圆柱振动对流态的影响。在给定初始位移的情况下,圆柱振动在初期产生稳定的驻波响应,并逐渐转变为
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引用次数: 0
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Proceedings of the 8th World Congress on Mechanical, Chemical, and Material Engineering
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