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TiC nanoparticles tune phase stability and deformation mechanisms in directed energy deposition processed Fe60Co15Ni15Cr10 medium-entropy alloy composites TiC纳米颗粒调节定向能沉积制备Fe60Co15Ni15Cr10中熵合金复合材料的相稳定性和变形机制
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-27 DOI: 10.1016/j.msea.2026.149839
Soung Yeoul Ahn , Eun Seong Kim , Sang Guk Jeong , Stefanus Harjo , Takuro Kawasaki , Wu Gong , Hyun-Joong Kim , Soon-Jik Hong , Sun Ig Hong , Hyeonseok Kwon , Jung Gi Kim , Hyoung Seop Kim
Additive manufacturing (AM) of particle-reinforced metal matrix composites (MMCs) offers opportunities not only for mechanical strengthening but also for tailoring matrix phase stability and deformation behavior. In this study, TiC (2 wt%) nanoparticles were incorporated into Fe60Co15Ni15Cr10 (at%) medium-entropy alloy (MEA) using directed energy deposition (DED) process. Despite the severe thermal conditions of the DED process, a substantial fraction of TiC remained, while partial decomposition released C and Ti elements into the matrix. This chemical modification stabilized the γ-austenite matrix phase and suppressed deformation-induced martensitic transformation (DIMT), which is typically active in the Fe60Co15Ni15Cr10 MEA. Instead, the composite exhibited a transition toward slip-dominated deformation. Microstructural observation revealed that dispersed and semi-coherent TiC particles, together with solute partitioning from decomposed nanoparticles, altered grain boundary morphology and promoted distributed plastic flow. In-situ neutron diffraction accompanied with tensile test confirmed enhanced dislocation activity in the early stage of deformation, supporting the deformation mechanism shift from DIMT-assisted hardening to dislocation-mediated slip. These results highlight the critical role of nanoparticle-induced phase stability variation in governing deformation mechanisms, offering new insights into designing AM-processed MMCs beyond conventional strength-oriented strategies.
颗粒增强金属基复合材料(MMCs)的增材制造(AM)不仅提供了机械强化的机会,而且还提供了定制基体相稳定性和变形行为的机会。在本研究中,采用定向能沉积(DED)工艺将TiC (2 wt%)纳米颗粒掺入Fe60Co15Ni15Cr10 (at%)中熵合金(MEA)中。尽管DED过程的热条件恶劣,但仍有相当一部分TiC残留,而部分分解将C和Ti元素释放到基体中。该化学改性稳定了γ-奥氏体基体相,抑制了形变诱导马氏体相变(DIMT),该相变在Fe60Co15Ni15Cr10 MEA中具有典型的活性。相反,复合材料表现出向滑移主导变形的转变。显微组织观察表明,TiC颗粒分散、半共融,分解后溶质分块,改变了晶界形态,促进了分布塑性流动。原位中子衍射和拉伸试验证实变形初期位错活动性增强,支持变形机制由dimt辅助硬化向位错介导滑移转变。这些结果强调了纳米颗粒诱导的相稳定性变化在控制变形机制中的关键作用,为设计am加工的mmc提供了超越传统强度导向策略的新见解。
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引用次数: 0
Influence of single- and double-step solution and aging treatments on the microstructure, texture, and mechanical properties of cold-rolled Al–Cu–Li alloy sheets (Cu/Li ratios 2 and 4) produced via squeeze casting 单步、双步固溶和时效处理对挤压铸造冷轧Al-Cu-Li合金板材(Cu/Li比2和4)组织、织构和力学性能的影响
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-25 DOI: 10.1016/j.msea.2026.149828
S. Manojkumar, Yogesh Singh, K.K. Mehta
Squeeze-cast Al–Cu–Li alloys, SC1 (Cu/Li ≈ 2, Li ≈ 1.28 wt%) and SC2 (Cu/Li ≈ 4, Li ≈ 0.53 wt%), studied in three heat-treatment conditions: H1 (single-step solution → quenching → double-aging), H2 (double-step solution → quenching → double aging), and H3 (double-step solution → quenching → single aging). Cold rolling of SC1 developed pronounced crystallographic textures, strongly influenced by the Cu/Li ratio and Li-content. Nearly double the Li in SC1 led to a fourfold increase in texture intensity compared to SC2, mainly from strong Copper ({112}111) component. Heat treatment markedly influenced the strength–ductility trade-off. In SC1, the H1 condition achieved nearly twice the strength of H3 but incurred a twofold reduction in ductility, attributed to a higher fraction of T1 (Al2CuLi) precipitates formed during double aging. SC2 displayed superior ductility but limited strength, particularly under H3 treatment. Mechanical performance was governed by the combined effects of solution treatment, controlling grain size and texture, and aging treatment, regulating precipitation. The superior strength of SC1 in H1 condition arose from the synergistic effect of refined grains with strong Cube texture and enhanced T1 precipitation. Conversely, low Li content in SC2 restricted T1 precipitation, limiting strengthening. H3 triggers dislocation looping and serrations in stress–strain curves via T2 (Al6CuLi3) precipitates, while H1 (SC1) suppresses serrations by depleting Cu and Li through high T1 precipitation. Constitutive modeling using the Voce's-relationship and KM-model showed excellent agreement with experiments, providing a robust framework for optimizing heat-treatment routes for Al–Cu–Li alloys.
研究了挤压铸造Al-Cu-Li合金SC1 (Cu/Li≈2,Li≈1.28 wt%)和SC2 (Cu/Li≈4,Li≈0.53 wt%)在三种热处理条件下:H1(单步固溶→淬火→双时效)、H2(双步固溶→淬火→双时效)和H3(双步固溶→淬火→单时效)。受Cu/Li比和Li含量的影响,SC1冷轧后形成明显的结晶织构。与SC2相比,SC1中Li的近两倍导致纹理强度增加四倍,主要来自强铜({112}⟨111⟩)成分。热处理对强度-塑性平衡有显著影响。在SC1中,H1状态的强度几乎是H3的两倍,但塑性却降低了两倍,这是由于在二次时效过程中形成了更高比例的T1 (Al2CuLi)析出物。SC2表现出较好的延展性,但强度有限,特别是在H3处理下。固溶处理(控制晶粒尺寸和织构)和时效处理(调节析出)的共同作用决定了合金的力学性能。在H1条件下,SC1的优异强度是由于具有强立方体织构的细化晶粒和增强的T1析出的协同作用所致。相反,SC2中较低的Li含量限制了T1的析出,限制了强化。H3通过T2 (Al6CuLi3)析出触发位错环和应力-应变曲线锯齿形,而H1 (SC1)通过高T1析出耗尽Cu和Li抑制锯齿形。利用Voce关系和km模型建立的本构模型与实验结果吻合良好,为优化铝铜锂合金热处理路线提供了可靠的框架。
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引用次数: 0
Effects of Al-5Ti-1B-xCe refiners on microstructure and tensile properties of Al-5.0Mg-3.0Zn-1.0Cu alloy at different cooling rates 不同冷却速率下Al-5Ti-1B-xCe细化剂对Al-5.0Mg-3.0Zn-1.0Cu合金组织和拉伸性能的影响
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-22 DOI: 10.1016/j.msea.2026.149820
Shenshen Cui , Qiang Lu , Dezhi Li , Haiyan Jiang , Qudong Wang , Huisheng Cai
In this investigation, the effects of Al-5Ti-1B-xCe (x = 0, 4, 8, 12 wt%) refiners on the grain size, microstructure, and mechanical properties of the Al-5.0Mg-3.0Zn-1.0Cu alloy under different cooling rates were investigated. The results showed that, within the cooling rate range of 9.5–33.6 °C/s, the Al-5Ti-1B-xCe (x = 4, 8, 12) refiners exhibit superior refinement effects on the secondary dendrite arm spacing (SDAS), the width of the Mg32(AlCuZn)49 phase, and the size of the Al3Fe phase in the Al-5.0Mg-3.0Zn-1.0Cu alloy compared with the Al-5Ti-1B refiner, and the Al-5Ti-1B-4Ce refiner exhibits the strongest grain-refining effect. Moreover, as the cooling rate increases, the grain size, SDAS, the width of the Mg32(AlCuZn)49 phase, and the size of the Al3Fe phase are refined, while in the aged condition, the precipitation-free zone (PFZ) width and the size of precipitates is reduced. Compared with the alloy refined by the Al-5Ti-1B refiner, the alloys refined by Al-5Ti-1B-xCe (x = 4, 8, 12) exhibit a reduced sensitivity of grain size to cooling rate; therefore, as the cooling rate increases, the extent of grain size reduction in the alloys refined by Al-5Ti-1B-xCe (x = 4, 8, 12) becomes smaller. The precipitate diameter shows a unimodal distribution when the alloy is refined by the Al-5Ti-1B refiner, while a bimodal distribution is observed after refinement by the Al-5Ti-1B-xCe (x = 4, 12) refiners. Compared with the alloy refined by the Al-5Ti-1B refiner, the aged Al-5.0Mg-3.0Zn-1.0Cu alloy refined by the Al-5Ti-1B-4Ce and Al-5Ti-1B-8Ce refiners exhibit higher strength and elongation. For alloys refined by the same refiner, the strength and elongation of the aged Al-5.0Mg-3.0Zn-1.0Cu alloy increase with increasing cooling rate.
研究了不同冷却速率下Al-5Ti-1B-xCe (x = 0、4、8、12 wt%)细化剂对Al-5.0Mg-3.0Zn-1.0Cu合金晶粒尺寸、组织和力学性能的影响。结果表明,在9.5 ~ 33.6℃/s的冷却速率范围内,Al-5Ti-1B- xce (x = 4、8、12)细化剂对Al-5.0Mg-3.0Zn-1.0Cu合金的二次枝晶臂间距(SDAS)、Mg32(AlCuZn)49相宽度和Al3Fe相尺寸的细化效果优于Al-5Ti-1B细化剂,其中Al-5Ti-1B- 4ce细化效果最强。随着冷却速度的增加,晶粒尺寸、SDAS、Mg32(AlCuZn)49相宽度和Al3Fe相尺寸均有所细化,而时效状态下,无析出区宽度和析出相尺寸均有所减小。与Al-5Ti-1B细化剂相比,Al-5Ti-1B- xce (x = 4,8,12)细化的合金晶粒尺寸对冷却速率的敏感性降低;因此,随着冷却速率的增加,Al-5Ti-1B-xCe (x = 4,8,12)细化合金的晶粒尺寸减小程度越小。经Al-5Ti-1B细化后,析出物直径呈单峰分布,经Al-5Ti-1B- xce (x = 4,12)细化后,析出物直径呈双峰分布。与Al-5Ti-1B细化剂细化的合金相比,Al-5Ti-1B- 4ce和Al-5Ti-1B- 8ce细化的时效Al-5.0Mg-3.0Zn-1.0Cu合金具有更高的强度和延伸率。对于相同细化剂的合金,时效态Al-5.0Mg-3.0Zn-1.0Cu合金的强度和伸长率随冷却速度的增加而增加。
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引用次数: 0
Strengthening and toughening of developed high-strength hull structural steel and its heat-affected zones 已开发的高强度船体结构钢及其热影响区的强化和增韧
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-22 DOI: 10.1016/j.msea.2026.149793
Deng-Bang Gao , Xuan-Wei Lei , Hai-Tao Jian , Chun-Long Jiang , Zhi Cheng , Ji-Hua Huang
A high-strength hull structural (HSHS) steel was developed based on a low-carbon high-nickel design concept. To evaluate its mechanical properties and weldability, the microstructures and mechanical performance of both the base metal and its heat-affected zones (HAZs)—including the coarse-grained HAZ, fine-grained HAZ, unaltered coarse-grained HAZ, and supercritically reheated coarse-grained HAZ—were systematically investigated under heat inputs of 20 and 50 kJ/cm. The strengthening and toughening mechanisms of the HSHS steel and its HAZs were further elucidated. The results demonstrate that the developed HSHS steel exhibits excellent comprehensive mechanical properties, while its HAZs maintain sufficiently high strength and overall satisfactory toughness at 223 K (−50 °C). The high strength of the developed HSHS steel is primarily attributed to the second phase precipitation and the formation of a tempered bainite-dominated microstructure. In the HAZs, the designed Nb content and the development of a lath-based microstructure are identified as key factors ensuring high strength. The low-temperature toughness of both the base metal and HAZs is predominantly governed by the high Ni content and refined M-A constituents, with secondary contributions from finer effective grain size and microstructural characteristics. Depending on specific conditions, these factors lead to variations in Charpy impact energy. Notably, a comparative analysis with documented data reveals that the mechanical properties of the HAZs in the developed HSHS steel are comparable to those of HSLA-100 steels. Collectively, these findings confirm that the developed HSHS steel possesses good weldability.
基于低碳高镍设计理念,开发了一种高强度船体结构钢。为了评估其力学性能和可焊性,在20和50 kJ/cm的热输入下,系统地研究了母材及其热影响区(HAZ)的组织和力学性能,包括粗晶HAZ、细晶HAZ、未改变的粗晶HAZ和超临界再加热的粗晶HAZ。进一步阐明了HSHS钢及其haz的强化增韧机理。结果表明:制备的HSHS钢具有优良的综合力学性能,在223 K(- 50℃)温度下,haz仍能保持足够高的强度和令人满意的整体韧性。发展的HSHS钢的高强度主要归因于第二相的析出和回火贝氏体主导组织的形成。在haz中,设计的Nb含量和板基微观结构的发展被认为是确保高强度的关键因素。母材和haz的低温韧性主要受高Ni含量和细化的M-A成分的影响,其次受更细的有效晶粒尺寸和微观组织特征的影响。根据具体情况,这些因素会导致夏比撞击能量的变化。值得注意的是,与文献数据的比较分析表明,开发的HSHS钢中的haz的机械性能与HSLA-100钢的机械性能相当。结果表明,所研制的HSHS钢具有良好的可焊性。
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引用次数: 0
Synergistic strength and ductility enhancement of lightweight AlTiVCr eutectic high entropy alloys with controlled Al/Ti atomic ratios 控制Al/Ti原子比的轻质AlTiVCr共晶高熵合金的协同强度和塑性增强
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-21 DOI: 10.1016/j.msea.2026.149817
Dong Seong Hong , Sung Hwan Hong , Yu Jin Lee , Ga Eun Jo , Dilshodbek Yusupov , Muhammad Aoun Abbas , Gyeol Chan Kang , Hae Jin Park , Jürgen Eckert , Kiran P. Shinde , Ki Buem Kim
Eutectic high entropy alloys (EHEAs) based on the AlTiVCr system offer a promising combination of high strength and ductility, making them attractive for advanced structural applications. In the present work, a simple and effective strategy of varying two constituent elements Al and Ti was proposed to design EHEA. AlxTi80-xV15Cr5 (x = 35, 40, 45 at.%) alloy compositions were prepared by arc suction casting. The Al35Ti45V15Cr5 alloy exhibited a single B2 phase structure. With increasing Al content, the microstructure of Al40Ti40V15Cr5 evolved to a dual-phase structure composed of a high amount of B2 matrix with locally distributed HCP phase, and the Al45Ti35V15Cr5 alloy formed as a eutectic structure consisting of B2 and HCP phases. The Al45Ti35V15Cr5 EHEA composition demonstrates a high yield strength of 1864 MPa and excellent compressive ductility of 14.3 %, attributed to the suppression of shear band propagation at the phase boundaries, and it exhibited a low density of 3.97 g/cm3, leading to a superior specific strength of 469.22 MPa cm3/g. The stable intermetallic-based eutectic microstructures were achieved by tuning the composition in accordance with the strong negative mixing enthalpy between Al and Ti. The formation of a eutectic dual-phase microstructure consisting of B2 and HCP phases significantly enhances the mechanical performance. These findings give a new pathway for designing lightweight, high-performance eutectic high entropy alloys.
基于AlTiVCr系统的共晶高熵合金(EHEAs)提供了高强度和延展性的良好组合,使其在高级结构应用中具有吸引力。在本工作中,提出了一种简单有效的改变两种组成元素Al和Ti的策略来设计EHEA。alxti80 - x15cr5 (x = 35, 40, 45 at)采用电弧吸铸法制备了%)合金成分。Al35Ti45V15Cr5合金表现为单一B2相组织。随着Al含量的增加,Al40Ti40V15Cr5的组织演变为由大量B2基体和局部分布的HCP相组成的双相组织,Al45Ti35V15Cr5合金形成由B2相和HCP相组成的共晶组织。Al45Ti35V15Cr5 EHEA组合物屈服强度高达1864 MPa,抗压塑性优异,达到14.3%,这主要归功于相界处剪切带传播受到抑制,其密度低至3.97 g/cm3,比强度达到469.22 MPa cm3/g。根据Al和Ti之间的强负混合焓调节成分,获得了稳定的金属间共晶组织。形成由B2相和HCP相组成的共晶双相组织,显著提高了材料的力学性能。这些发现为设计轻量化、高性能共晶高熵合金提供了新的途径。
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引用次数: 0
Engineered ωiso phase enable deformation-induced mechanisms strength and plasticity synergy in a novel Ti-531 metastable β titanium alloy 在一种新型的Ti-531亚稳β钛合金中,工程ω - iso相实现了变形诱导机制的强度和塑性协同作用
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.msea.2026.149806
Irfan Ali Abro , Lin Yang , Qunbo Fan , Kamal Mustafa
Metastable β-Ti alloys are known for their high strain hardening rates and excellent plasticity through the combined effects of transformation induced plasticity (TRIP) and twinning induced plasticity (TWIP) effects, yet their relatively low yield strength restrict structural applications. Improving yield strength without sacrificing ductility is thus a key challenge in these alloys. To address this long-standing strength-plasticity dilemma, we designed a novel metastable β-Ti alloy, Ti-5Mo-3Cr-1Zr (Ti-531), guided by d-electron theory, average electron-to-atom ratio (e/a) and atomic radius difference (Δr) criteria. By engineering nanoscale ωiso phase precipitations, a strategy is demonstrated to concurrently strengthen the yield response and preserve high ductility in the Ti-531 alloy. The results show that these ωiso particles substantially strengthen the alloy and activate a synergistic deformation-induced strengthening mechanism. This mechanism involves a sandwich-type composite twin/stress-induced ω (SIω) structures, interactions between twin/SIM (α”), and development of dislocation channels largely devoid of ωiso phase synergistically accommodate localized strain. These dislocation channels facilitate to accelerate dislocation accumulation, promote forest hardening and suppress the impeding effect of ωiso phase. As a result, the alloy aged at 423 K (A423) outperforms the hot-rolled solution-treated alloy (R1123) in yield strength (∼642 MPa, ∼28 % higher) with merely a slight (∼1.1 %) reduction in elongation, thus combining high strength with largely preserved ductility. This work introduces instability-control paradigm that harmonizes twin/ SIω/SIM-assisted deformation and dislocation channels strengthening to engineer high performance metastable β-Ti alloys.
亚稳态β-Ti合金具有较高的应变硬化率和优异的相变诱导塑性(TRIP)和孪晶诱导塑性(TWIP)效应,但其相对较低的屈服强度限制了其在结构中的应用。因此,在不牺牲延展性的情况下提高屈服强度是这些合金面临的关键挑战。为了解决这一长期存在的强度-塑性难题,我们设计了一种新型亚稳态β-钛合金,Ti-5Mo-3Cr-1Zr (Ti-531),以d-电子理论为指导,以平均电子原子比(e/a)和原子半径差(Δr)为标准。通过工程纳米级ω等相析出,提出了一种同时增强Ti-531合金屈服响应和保持高延展性的策略。结果表明,ω - iso颗粒显著强化合金,并激活了一种协同变形强化机制。该机制涉及三明治型复合孪晶/应力诱导的ω (SIω)结构,孪晶/SIM (α”)之间的相互作用,以及在很大程度上缺乏ω等相的位错通道的发展,从而协同适应局部应变。这些位错通道有利于加速位错积累,促进林硬化,抑制ωiso相的阻碍作用。结果,在423 K时效的合金(A423)在屈服强度(~ 642 MPa,高~ 28%)方面优于热轧固溶处理合金(R1123),而伸长率仅略有(~ 1.1%)下降,从而将高强度与基本保留的延展性结合在一起。这项工作引入了不稳定控制范式,协调双/ SIω/ sim辅助变形和位错通道强化,以设计高性能亚稳β-钛合金。
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引用次数: 0
Design strategy for enhancing mechanical properties and magnetocaloric effect of eutectic Ni-Mn-Sn-Fe alloy via laser powder bed fusion 激光粉末床熔合提高共晶Ni-Mn-Sn-Fe合金力学性能和磁热效应的设计策略
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.msea.2026.149795
Rongzhi Li , Peter K. Liaw , Jianzhong Jiang , Lin Deng , Yong Zhang
Environmental concerns from conventional refrigerants highlight the urgent need for solid-state cooling materials that combine structural robustness with strong magnetocaloric performance. Here, we design a dual-phase Ni50Mn32Sn10Fe8 Heusler alloy using Fe alloying in conjunction with optimized laser powder bed fusion (L-PBF) and homogenization annealing. The resulting ultrafine eutectic structure (∼650 nm lamellar spacing) with semi-coherent Kurdjumov–Sachs interfaces effectively integrates mechanical strength and functional performance. The alloy exhibits high compressive strength (1692.8 MPa), good ductility (10.5 %), and a stable modulus (∼113 GPa) with ∼1.4 % recoverable superelastic strain after 50 cycles. Functionally, it achieves a magnetic entropy change of 10.04 J kg−1 K−1 and a refrigerant capacity of 184 J/kg under a 5 T magnetic field. This work establishes a composition–processing design strategy for multifunctional magnetocaloric materials, providing a pathway toward robust, high-performance alloys for solid-state cooling, flexible actuators, and biomedical devices.
传统制冷剂的环境问题凸显了对固体冷却材料的迫切需求,这种材料结合了结构坚固性和强磁热性能。本文采用Fe合金化、激光粉末床熔合(L-PBF)和均匀化退火相结合的方法,设计了一种双相Ni50Mn32Sn10Fe8 Heusler合金。由此产生的超细共晶结构(片层间距约650 nm)具有半相干Kurdjumov-Sachs界面,有效地集成了机械强度和功能性能。该合金具有较高的抗压强度(1692.8 MPa)、良好的延性(10.5%)和稳定的模量(~ 113 GPa),经过50次循环后具有~ 1.4%的可恢复超弹性应变。在5t磁场下,制冷剂的磁熵变化为10.04 J kg−1 K−1,制冷量为184 J/kg。这项工作建立了多功能磁热材料的成分加工设计策略,为固态冷却、柔性致动器和生物医学设备提供了坚固、高性能合金的途径。
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引用次数: 0
Heterogeneous deformation and strengthening mechanism in TC4 coaxial laser wire-based directed energy deposition for repairing Ti80 TC4同轴激光线基定向能沉积修复Ti80的非均质变形及强化机理
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.msea.2026.149800
Xiaohong Zhan , Jinsheng Ji , Chaoqi Qi , Xiong Zhang , Deliang Lei , Jianfeng Wang
Laser additive manufacturing technology holds great potential for repairing titanium alloys. In this study, coaxial laser wire-based directed energy deposition (CLW-DED) using TC4 alloy was first applied to repair forged Ti80 alloy, with a focus on investigating the regional microstructural variations and synergistic deformation behavior of the repaired specimens. Additionally, the strengthening effects of dual annealing treatments were explored. The results revealed that the microstructure of the repaired specimens transitioned from fine α′ martensite in the repaired zone to the equiaxed α phase in the substrate. Heat treatment induced martensite decomposition and facilitated element diffusion, contributing to the stabilization of the microstructure. The repaired sample demonstrated superior strength to the substrate material with substantially reduced plasticity. The mismatch in strength and ductility was primarily attributed to strain concentration and differences in strain hardening rates at the interface between the repaired layer and the substrate. Dislocation slip served as the primary deformation mechanism, while twinning was activated as a secondary deformation mechanism in the repaired layer. Heat treatment enhanced the tensile strength of the specimens to ∼982 MPa and improved ductility to ∼5.2 % by reducing dislocation density and promoting dislocation slip. This study confirms the feasibility of CLW-DED for titanium alloy repair and provides theoretical insights into the mechanical performance of the heterostructured metallic components.
激光增材制造技术在钛合金修复方面具有巨大的潜力。本研究首次将TC4合金同轴激光线基定向能沉积(CLW-DED)技术应用于Ti80锻造合金的修复,重点研究了修复试样的区域显微组织变化和协同变形行为。此外,还探讨了双退火处理的强化效果。结果表明,修复试样的显微组织由修复区细小的α′马氏体转变为基体中的等轴α相。热处理诱发马氏体分解,促进元素扩散,有利于组织稳定。修复后的样品显示出比基体材料更强的强度,但塑性大大降低。强度和延性的不匹配主要是由于修复层和基体之间界面的应变集中和应变硬化率的差异。在修复层中,位错滑移是主要的变形机制,孪生是次要的变形机制。热处理通过降低位错密度和促进位错滑移,使试样的抗拉强度提高到~ 982 MPa,塑性提高到~ 5.2%。本研究证实了CLW-DED用于钛合金修复的可行性,并为异质结构金属部件的力学性能提供了理论见解。
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引用次数: 0
Microstructure, texture evolution and mechanical properties of Mg-4Y-2Nd-2Sm-0.5Zr alloy under different hot extrusion ratios 不同热挤压比下Mg-4Y-2Nd-2Sm-0.5Zr合金的组织、织构演变及力学性能
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.msea.2026.149810
Zheng Wu , Xiaoya Chen , Jian Zeng , Kang Yao , Dongzhen Wang , Quanan Li
Achieving a significant enhancement in the mechanical properties of Mg-Y-RE (WE) alloys is critical for broadening their application prospects. This study systematically examines and discusses the dynamic recrystallization (DRX) and dislocation behavior of WE alloys under different extrusion ratios. Examination of the microstructure of the extruded alloys reveals that varying hot extrusion ratios influence recrystallization behavior, with grain refinement being highly correlated with particle stimulated nucleation (PSN) and continuous/discontinuous dynamic recrystallization (CDRX/DDRX) mechanisms. Furthermore, an increase in the extrusion ratio enhances dynamic precipitation, thereby promoting the formation of fine and uniform precipitates. At an extrusion ratio of 9.4, the yield strength (YS) reaches 312 MPa and the elongation (EL) improves to 11.1 %. The observed enhancements can be primarily linked to the processes of grain refinement and the activation of pyramidal slip. This approach allows for a deeper comprehension of the intricate interplay between microstructural characteristics and the mechanical properties inherent to Mg alloys. Moreover, it serves as a significant reference point for the industrial manufacturing of high-performance extruded Mg-Y series alloys, optimizing their overall performance in practical applications.
实现Mg-Y-RE (WE)合金力学性能的显著提高是拓宽其应用前景的关键。本研究系统地考察和讨论了不同挤压比下WE合金的动态再结晶(DRX)和位错行为。对挤压合金微观组织的研究表明,不同的热挤压比影响再结晶行为,晶粒细化与颗粒激发成核(PSN)和连续/不连续动态再结晶(CDRX/DDRX)机制高度相关。此外,挤压比的增加增强了动态析出,从而促进了细而均匀的析出相的形成。挤压比为9.4时,屈服强度达到312 MPa,伸长率达到11.1%。观察到的增强主要与晶粒细化和锥体滑移的激活过程有关。这种方法允许更深入地理解微观结构特征和镁合金固有的机械性能之间复杂的相互作用。为Mg-Y系列高性能挤压合金的工业化制造提供了重要的参考依据,在实际应用中优化其整体性能。
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引用次数: 0
Temperature-dependent deformation mechanisms and strengthening behavior of a novel Ni-based superalloy with bimodal γ′ precipitate distribution 一种具有双峰γ′析出相分布的新型镍基高温合金的温度变形机制和强化行为
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-19 DOI: 10.1016/j.msea.2026.149784
Xinyu Meng , Chao Tang , Shaomin Lyu , Xingfei Xie , Jian Jia , Jinglong Qu
High-temperature tensile performance is a critical indicator of the mechanical reliability of Ni-based superalloys. In this study, a newly designed Ni-based superalloy was systematically investigated from room temperature to 900 °C to elucidate the coupling between microstructural characteristics, mechanical response, and deformation mechanisms. Fine-grained (10.7 μm) and coarse-grained (97 μm) microstructures were obtained through multi-stage heat treatments. The FG alloy exhibits superior yield and tensile strength below 750 °C, reaching 1340 MPa and 1740 MPa at room temperature and retaining 1208 MPa and 1267 MPa at 750 °C, which is primarily attributed to its higher grain boundary density and enhanced grain-boundary-mediated strengthening. However, the FG alloy shows a pronounced ductility drop at 815 °C, with the elongation decreasing to 9 %. In contrast, the CG alloy demonstrates enhanced strength retention at elevated temperatures, maintaining an ultimate tensile strength and yield strength of 801 MPa and 770 MPa at 900 °C, corresponding to a tensile strength retention of 54 % (compared with 38 % for the FG alloy), together with a stable elongation of 8.5 %. This superior high-temperature stability is associated with a lower grain boundary density and a higher fraction of Σ3 special boundaries (42.6–55.9 %). Microstructural analysis reveals a bimodal γ′ precipitate distribution in both microstructures, with fine secondary γ′ precipitates (FG: 82 nm, 48 %; CG: 92 nm, 57 %) dominating strengthening through short-range dislocation–precipitate interactions, and coarse primary γ′ precipitates (FG: 1.54 μm, 7.6 %; CG: 3.19 μm, 0.5 %) facilitating deformation accommodation by pinning grain boundary migration, thereby enabling a synergistic balance between strength and ductility over a wide temperature range. Transmission electron microscopy and critical resolved shear stress analysis demonstrate a temperature-dependent transition in deformation mechanisms from γ′ shearing to Orowan looping in the range of 815–900 °C. In addition, Co/Ti solute segregation at twin interfaces reduces interfacial energy and suppresses defect migration, further stabilizing the γ/γ′ microstructure and enhancing high-temperature strength. These findings provide mechanistic insight for the microstructural design of advanced Ni-based superalloys.
高温拉伸性能是衡量镍基高温合金力学可靠性的重要指标。在本研究中,系统地研究了一种新设计的镍基高温合金,从室温到900°C,以阐明微观组织特征,力学响应和变形机制之间的耦合。通过多段热处理得到细晶(10.7 μm)和粗晶(97 μm)组织。FG合金在750℃以下表现出优异的屈服强度和抗拉强度,室温下达到1340 MPa和1740 MPa, 750℃时保持1208 MPa和1267 MPa,这主要归因于其较高的晶界密度和晶界介导强化的增强。但在815℃时,FG合金的延展性明显下降,伸长率降至9%。相比之下,CG合金在高温下表现出增强的强度保持,在900°C时保持801 MPa和770 MPa的极限抗拉强度和屈服强度,对应于54%的抗拉强度保持(而FG合金为38%),以及8.5%的稳定伸长率。这种优异的高温稳定性与较低的晶界密度和较高的Σ3特殊晶界比例(42.6 - 55.9%)有关。显微组织分析表明,两种显微组织均呈双峰型γ′相分布,其中细小的次生γ′相(FG: 82 nm, 48%; CG: 92 nm, 57%)主导着通过短程位错-析出相互作用强化的过程,而粗的初生γ′相(FG: 1.54 μm, 7.6%;CG: 3.19 μm, 0.5%)通过固定晶界迁移促进变形调节,从而在宽温度范围内实现强度和延性之间的协同平衡。透射电镜和临界分解剪切应力分析表明,在815-900°C范围内,变形机制从γ′剪切到Orowan环的转变依赖于温度。此外,Co/Ti在孪晶界面处的溶质偏析降低了界面能,抑制了缺陷迁移,进一步稳定了γ/γ′微观组织,提高了高温强度。这些发现为先进镍基高温合金的微观组织设计提供了机理见解。
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Materials Science and Engineering: A
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