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Strengthening and toughening of developed high-strength hull structural steel and its heat-affected zones 已开发的高强度船体结构钢及其热影响区的强化和增韧
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-22 DOI: 10.1016/j.msea.2026.149793
Deng-Bang Gao , Xuan-Wei Lei , Hai-Tao Jian , Chun-Long Jiang , Zhi Cheng , Ji-Hua Huang
A high-strength hull structural (HSHS) steel was developed based on a low-carbon high-nickel design concept. To evaluate its mechanical properties and weldability, the microstructures and mechanical performance of both the base metal and its heat-affected zones (HAZs)—including the coarse-grained HAZ, fine-grained HAZ, unaltered coarse-grained HAZ, and supercritically reheated coarse-grained HAZ—were systematically investigated under heat inputs of 20 and 50 kJ/cm. The strengthening and toughening mechanisms of the HSHS steel and its HAZs were further elucidated. The results demonstrate that the developed HSHS steel exhibits excellent comprehensive mechanical properties, while its HAZs maintain sufficiently high strength and overall satisfactory toughness at 223 K (−50 °C). The high strength of the developed HSHS steel is primarily attributed to the second phase precipitation and the formation of a tempered bainite-dominated microstructure. In the HAZs, the designed Nb content and the development of a lath-based microstructure are identified as key factors ensuring high strength. The low-temperature toughness of both the base metal and HAZs is predominantly governed by the high Ni content and refined M-A constituents, with secondary contributions from finer effective grain size and microstructural characteristics. Depending on specific conditions, these factors lead to variations in Charpy impact energy. Notably, a comparative analysis with documented data reveals that the mechanical properties of the HAZs in the developed HSHS steel are comparable to those of HSLA-100 steels. Collectively, these findings confirm that the developed HSHS steel possesses good weldability.
基于低碳高镍设计理念,开发了一种高强度船体结构钢。为了评估其力学性能和可焊性,在20和50 kJ/cm的热输入下,系统地研究了母材及其热影响区(HAZ)的组织和力学性能,包括粗晶HAZ、细晶HAZ、未改变的粗晶HAZ和超临界再加热的粗晶HAZ。进一步阐明了HSHS钢及其haz的强化增韧机理。结果表明:制备的HSHS钢具有优良的综合力学性能,在223 K(- 50℃)温度下,haz仍能保持足够高的强度和令人满意的整体韧性。发展的HSHS钢的高强度主要归因于第二相的析出和回火贝氏体主导组织的形成。在haz中,设计的Nb含量和板基微观结构的发展被认为是确保高强度的关键因素。母材和haz的低温韧性主要受高Ni含量和细化的M-A成分的影响,其次受更细的有效晶粒尺寸和微观组织特征的影响。根据具体情况,这些因素会导致夏比撞击能量的变化。值得注意的是,与文献数据的比较分析表明,开发的HSHS钢中的haz的机械性能与HSLA-100钢的机械性能相当。结果表明,所研制的HSHS钢具有良好的可焊性。
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引用次数: 0
Synergistic strength and ductility enhancement of lightweight AlTiVCr eutectic high entropy alloys with controlled Al/Ti atomic ratios 控制Al/Ti原子比的轻质AlTiVCr共晶高熵合金的协同强度和塑性增强
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-21 DOI: 10.1016/j.msea.2026.149817
Dong Seong Hong , Sung Hwan Hong , Yu Jin Lee , Ga Eun Jo , Dilshodbek Yusupov , Muhammad Aoun Abbas , Gyeol Chan Kang , Hae Jin Park , Jürgen Eckert , Kiran P. Shinde , Ki Buem Kim
Eutectic high entropy alloys (EHEAs) based on the AlTiVCr system offer a promising combination of high strength and ductility, making them attractive for advanced structural applications. In the present work, a simple and effective strategy of varying two constituent elements Al and Ti was proposed to design EHEA. AlxTi80-xV15Cr5 (x = 35, 40, 45 at.%) alloy compositions were prepared by arc suction casting. The Al35Ti45V15Cr5 alloy exhibited a single B2 phase structure. With increasing Al content, the microstructure of Al40Ti40V15Cr5 evolved to a dual-phase structure composed of a high amount of B2 matrix with locally distributed HCP phase, and the Al45Ti35V15Cr5 alloy formed as a eutectic structure consisting of B2 and HCP phases. The Al45Ti35V15Cr5 EHEA composition demonstrates a high yield strength of 1864 MPa and excellent compressive ductility of 14.3 %, attributed to the suppression of shear band propagation at the phase boundaries, and it exhibited a low density of 3.97 g/cm3, leading to a superior specific strength of 469.22 MPa cm3/g. The stable intermetallic-based eutectic microstructures were achieved by tuning the composition in accordance with the strong negative mixing enthalpy between Al and Ti. The formation of a eutectic dual-phase microstructure consisting of B2 and HCP phases significantly enhances the mechanical performance. These findings give a new pathway for designing lightweight, high-performance eutectic high entropy alloys.
基于AlTiVCr系统的共晶高熵合金(EHEAs)提供了高强度和延展性的良好组合,使其在高级结构应用中具有吸引力。在本工作中,提出了一种简单有效的改变两种组成元素Al和Ti的策略来设计EHEA。alxti80 - x15cr5 (x = 35, 40, 45 at)采用电弧吸铸法制备了%)合金成分。Al35Ti45V15Cr5合金表现为单一B2相组织。随着Al含量的增加,Al40Ti40V15Cr5的组织演变为由大量B2基体和局部分布的HCP相组成的双相组织,Al45Ti35V15Cr5合金形成由B2相和HCP相组成的共晶组织。Al45Ti35V15Cr5 EHEA组合物屈服强度高达1864 MPa,抗压塑性优异,达到14.3%,这主要归功于相界处剪切带传播受到抑制,其密度低至3.97 g/cm3,比强度达到469.22 MPa cm3/g。根据Al和Ti之间的强负混合焓调节成分,获得了稳定的金属间共晶组织。形成由B2相和HCP相组成的共晶双相组织,显著提高了材料的力学性能。这些发现为设计轻量化、高性能共晶高熵合金提供了新的途径。
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引用次数: 0
Effect of serrated grain boundaries on mechanical anisotropy in L-PBF fabricated GH4099 alloy 锯齿晶界对L-PBF制备GH4099合金力学各向异性的影响
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-21 DOI: 10.1016/j.msea.2026.149815
Ruihang Xu , Shuya Zhang , Haiou Yang , Chunwen Guo , Hongliang Zhao , Yuheng Fan , Xianglei Dong
Nickel-based superalloy GH4099 fabricated via laser powder bed fusion (L-PBF) inevitably develops pronounced microstructural anisotropy and columnar grains aligned with the build direction due to rapid solidification and steep thermal gradients, which compromises structural stability and reliability in service. To address this, we propose and validate a reproducible heat-treatment window (slow cooling followed by aging) that induces stable serrated grain boundaries (SGB) in L-PBF-built GH4099. Compared with the as-deposited (AD) and conventional solution treated and aged (STA) states, the SGB condition yields equiaxed grains with pronounced boundary undulations and uniformly dispersed M23C6 along boundaries, while preserving a fine and consistent intragranular γ′ population (∼20–21 nm). Texture intensity decreased from 4.60 to 3.06, suggesting a reduction in plastic anisotropy. Quantitatively, boundary curvature increases from 0.099 μm−1 to 0.128 μm−1 (vertical direction), and the SGB-H attains a superior strength–ductility balance with YS of 797.1 MPa, UTS of 1227.1 MPa, and elongation of 44.8 %, compared with AD-H (YS 588 MPa, UTS 989 MPa, elongation 47.8 %). Cyclic loading–unloading analysis shows that SGB-H presents a smaller hysteresis loop area at cycle 9, dropping from 9.114 to 7.337 kJ/m3 compared with STA-H. The back stress is reduced by roughly 60–73 MPa and the friction stress by about 100 MPa, resulting in a σbflow ratio of 0.48–0.53 rather than above 0.56. These data indicate SGB effectively disperses GND pile-ups and lowers local interfacial friction, improving deformation compatibility and cyclic stability.
激光粉末床熔合(L-PBF)制备的镍基高温合金GH4099由于凝固速度快、热梯度大,不可避免地会产生明显的组织各向异性和柱状晶粒沿构建方向排列,从而影响组织的稳定性和使用可靠性。为了解决这个问题,我们提出并验证了一个可重复的热处理窗口(缓慢冷却后老化),该窗口可在l - pbf构建的GH4099中诱导稳定的锯齿晶界(SGB)。与沉积态(AD)和常规固溶时效态(STA)相比,SGB条件产生具有明显边界波动和沿边界均匀分散的M23C6的等轴晶粒,同时保留了细小且一致的晶内γ′族(~ 20-21 nm)。织构强度从4.60降低到3.06,表明塑性各向异性降低。边界曲率从0.099 μm−1(垂直方向)增加到0.128 μm−1,SGB-H的YS为797.1 MPa, UTS为1227.1 MPa,延伸率为44.8%,而AD-H的YS为588 MPa, UTS为989 MPa,延伸率为47.8%。循环加卸载分析表明,SGB-H在第9循环时滞回线面积较小,由9.114 kJ/m3降至7.337 kJ/m3。背应力减小约60 ~ 73 MPa,摩擦应力减小约100 MPa, σb/σ流动比为0.48 ~ 0.53,而不是0.56以上。这些数据表明,SGB有效地分散了GND堆积,降低了局部界面摩擦,提高了变形相容性和循环稳定性。
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引用次数: 0
Engineered ωiso phase enable deformation-induced mechanisms strength and plasticity synergy in a novel Ti-531 metastable β titanium alloy 在一种新型的Ti-531亚稳β钛合金中,工程ω - iso相实现了变形诱导机制的强度和塑性协同作用
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.msea.2026.149806
Irfan Ali Abro , Lin Yang , Qunbo Fan , Kamal Mustafa
Metastable β-Ti alloys are known for their high strain hardening rates and excellent plasticity through the combined effects of transformation induced plasticity (TRIP) and twinning induced plasticity (TWIP) effects, yet their relatively low yield strength restrict structural applications. Improving yield strength without sacrificing ductility is thus a key challenge in these alloys. To address this long-standing strength-plasticity dilemma, we designed a novel metastable β-Ti alloy, Ti-5Mo-3Cr-1Zr (Ti-531), guided by d-electron theory, average electron-to-atom ratio (e/a) and atomic radius difference (Δr) criteria. By engineering nanoscale ωiso phase precipitations, a strategy is demonstrated to concurrently strengthen the yield response and preserve high ductility in the Ti-531 alloy. The results show that these ωiso particles substantially strengthen the alloy and activate a synergistic deformation-induced strengthening mechanism. This mechanism involves a sandwich-type composite twin/stress-induced ω (SIω) structures, interactions between twin/SIM (α”), and development of dislocation channels largely devoid of ωiso phase synergistically accommodate localized strain. These dislocation channels facilitate to accelerate dislocation accumulation, promote forest hardening and suppress the impeding effect of ωiso phase. As a result, the alloy aged at 423 K (A423) outperforms the hot-rolled solution-treated alloy (R1123) in yield strength (∼642 MPa, ∼28 % higher) with merely a slight (∼1.1 %) reduction in elongation, thus combining high strength with largely preserved ductility. This work introduces instability-control paradigm that harmonizes twin/ SIω/SIM-assisted deformation and dislocation channels strengthening to engineer high performance metastable β-Ti alloys.
亚稳态β-Ti合金具有较高的应变硬化率和优异的相变诱导塑性(TRIP)和孪晶诱导塑性(TWIP)效应,但其相对较低的屈服强度限制了其在结构中的应用。因此,在不牺牲延展性的情况下提高屈服强度是这些合金面临的关键挑战。为了解决这一长期存在的强度-塑性难题,我们设计了一种新型亚稳态β-钛合金,Ti-5Mo-3Cr-1Zr (Ti-531),以d-电子理论为指导,以平均电子原子比(e/a)和原子半径差(Δr)为标准。通过工程纳米级ω等相析出,提出了一种同时增强Ti-531合金屈服响应和保持高延展性的策略。结果表明,ω - iso颗粒显著强化合金,并激活了一种协同变形强化机制。该机制涉及三明治型复合孪晶/应力诱导的ω (SIω)结构,孪晶/SIM (α”)之间的相互作用,以及在很大程度上缺乏ω等相的位错通道的发展,从而协同适应局部应变。这些位错通道有利于加速位错积累,促进林硬化,抑制ωiso相的阻碍作用。结果,在423 K时效的合金(A423)在屈服强度(~ 642 MPa,高~ 28%)方面优于热轧固溶处理合金(R1123),而伸长率仅略有(~ 1.1%)下降,从而将高强度与基本保留的延展性结合在一起。这项工作引入了不稳定控制范式,协调双/ SIω/ sim辅助变形和位错通道强化,以设计高性能亚稳β-钛合金。
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引用次数: 0
Design strategy for enhancing mechanical properties and magnetocaloric effect of eutectic Ni-Mn-Sn-Fe alloy via laser powder bed fusion 激光粉末床熔合提高共晶Ni-Mn-Sn-Fe合金力学性能和磁热效应的设计策略
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.msea.2026.149795
Rongzhi Li , Peter K. Liaw , Jianzhong Jiang , Lin Deng , Yong Zhang
Environmental concerns from conventional refrigerants highlight the urgent need for solid-state cooling materials that combine structural robustness with strong magnetocaloric performance. Here, we design a dual-phase Ni50Mn32Sn10Fe8 Heusler alloy using Fe alloying in conjunction with optimized laser powder bed fusion (L-PBF) and homogenization annealing. The resulting ultrafine eutectic structure (∼650 nm lamellar spacing) with semi-coherent Kurdjumov–Sachs interfaces effectively integrates mechanical strength and functional performance. The alloy exhibits high compressive strength (1692.8 MPa), good ductility (10.5 %), and a stable modulus (∼113 GPa) with ∼1.4 % recoverable superelastic strain after 50 cycles. Functionally, it achieves a magnetic entropy change of 10.04 J kg−1 K−1 and a refrigerant capacity of 184 J/kg under a 5 T magnetic field. This work establishes a composition–processing design strategy for multifunctional magnetocaloric materials, providing a pathway toward robust, high-performance alloys for solid-state cooling, flexible actuators, and biomedical devices.
传统制冷剂的环境问题凸显了对固体冷却材料的迫切需求,这种材料结合了结构坚固性和强磁热性能。本文采用Fe合金化、激光粉末床熔合(L-PBF)和均匀化退火相结合的方法,设计了一种双相Ni50Mn32Sn10Fe8 Heusler合金。由此产生的超细共晶结构(片层间距约650 nm)具有半相干Kurdjumov-Sachs界面,有效地集成了机械强度和功能性能。该合金具有较高的抗压强度(1692.8 MPa)、良好的延性(10.5%)和稳定的模量(~ 113 GPa),经过50次循环后具有~ 1.4%的可恢复超弹性应变。在5t磁场下,制冷剂的磁熵变化为10.04 J kg−1 K−1,制冷量为184 J/kg。这项工作建立了多功能磁热材料的成分加工设计策略,为固态冷却、柔性致动器和生物医学设备提供了坚固、高性能合金的途径。
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引用次数: 0
Heterogeneous deformation and strengthening mechanism in TC4 coaxial laser wire-based directed energy deposition for repairing Ti80 TC4同轴激光线基定向能沉积修复Ti80的非均质变形及强化机理
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.msea.2026.149800
Xiaohong Zhan , Jinsheng Ji , Chaoqi Qi , Xiong Zhang , Deliang Lei , Jianfeng Wang
Laser additive manufacturing technology holds great potential for repairing titanium alloys. In this study, coaxial laser wire-based directed energy deposition (CLW-DED) using TC4 alloy was first applied to repair forged Ti80 alloy, with a focus on investigating the regional microstructural variations and synergistic deformation behavior of the repaired specimens. Additionally, the strengthening effects of dual annealing treatments were explored. The results revealed that the microstructure of the repaired specimens transitioned from fine α′ martensite in the repaired zone to the equiaxed α phase in the substrate. Heat treatment induced martensite decomposition and facilitated element diffusion, contributing to the stabilization of the microstructure. The repaired sample demonstrated superior strength to the substrate material with substantially reduced plasticity. The mismatch in strength and ductility was primarily attributed to strain concentration and differences in strain hardening rates at the interface between the repaired layer and the substrate. Dislocation slip served as the primary deformation mechanism, while twinning was activated as a secondary deformation mechanism in the repaired layer. Heat treatment enhanced the tensile strength of the specimens to ∼982 MPa and improved ductility to ∼5.2 % by reducing dislocation density and promoting dislocation slip. This study confirms the feasibility of CLW-DED for titanium alloy repair and provides theoretical insights into the mechanical performance of the heterostructured metallic components.
激光增材制造技术在钛合金修复方面具有巨大的潜力。本研究首次将TC4合金同轴激光线基定向能沉积(CLW-DED)技术应用于Ti80锻造合金的修复,重点研究了修复试样的区域显微组织变化和协同变形行为。此外,还探讨了双退火处理的强化效果。结果表明,修复试样的显微组织由修复区细小的α′马氏体转变为基体中的等轴α相。热处理诱发马氏体分解,促进元素扩散,有利于组织稳定。修复后的样品显示出比基体材料更强的强度,但塑性大大降低。强度和延性的不匹配主要是由于修复层和基体之间界面的应变集中和应变硬化率的差异。在修复层中,位错滑移是主要的变形机制,孪生是次要的变形机制。热处理通过降低位错密度和促进位错滑移,使试样的抗拉强度提高到~ 982 MPa,塑性提高到~ 5.2%。本研究证实了CLW-DED用于钛合金修复的可行性,并为异质结构金属部件的力学性能提供了理论见解。
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引用次数: 0
Microstructure, texture evolution and mechanical properties of Mg-4Y-2Nd-2Sm-0.5Zr alloy under different hot extrusion ratios 不同热挤压比下Mg-4Y-2Nd-2Sm-0.5Zr合金的组织、织构演变及力学性能
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-20 DOI: 10.1016/j.msea.2026.149810
Zheng Wu , Xiaoya Chen , Jian Zeng , Kang Yao , Dongzhen Wang , Quanan Li
Achieving a significant enhancement in the mechanical properties of Mg-Y-RE (WE) alloys is critical for broadening their application prospects. This study systematically examines and discusses the dynamic recrystallization (DRX) and dislocation behavior of WE alloys under different extrusion ratios. Examination of the microstructure of the extruded alloys reveals that varying hot extrusion ratios influence recrystallization behavior, with grain refinement being highly correlated with particle stimulated nucleation (PSN) and continuous/discontinuous dynamic recrystallization (CDRX/DDRX) mechanisms. Furthermore, an increase in the extrusion ratio enhances dynamic precipitation, thereby promoting the formation of fine and uniform precipitates. At an extrusion ratio of 9.4, the yield strength (YS) reaches 312 MPa and the elongation (EL) improves to 11.1 %. The observed enhancements can be primarily linked to the processes of grain refinement and the activation of pyramidal slip. This approach allows for a deeper comprehension of the intricate interplay between microstructural characteristics and the mechanical properties inherent to Mg alloys. Moreover, it serves as a significant reference point for the industrial manufacturing of high-performance extruded Mg-Y series alloys, optimizing their overall performance in practical applications.
实现Mg-Y-RE (WE)合金力学性能的显著提高是拓宽其应用前景的关键。本研究系统地考察和讨论了不同挤压比下WE合金的动态再结晶(DRX)和位错行为。对挤压合金微观组织的研究表明,不同的热挤压比影响再结晶行为,晶粒细化与颗粒激发成核(PSN)和连续/不连续动态再结晶(CDRX/DDRX)机制高度相关。此外,挤压比的增加增强了动态析出,从而促进了细而均匀的析出相的形成。挤压比为9.4时,屈服强度达到312 MPa,伸长率达到11.1%。观察到的增强主要与晶粒细化和锥体滑移的激活过程有关。这种方法允许更深入地理解微观结构特征和镁合金固有的机械性能之间复杂的相互作用。为Mg-Y系列高性能挤压合金的工业化制造提供了重要的参考依据,在实际应用中优化其整体性能。
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引用次数: 0
Temperature-dependent deformation mechanisms and strengthening behavior of a novel Ni-based superalloy with bimodal γ′ precipitate distribution 一种具有双峰γ′析出相分布的新型镍基高温合金的温度变形机制和强化行为
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-19 DOI: 10.1016/j.msea.2026.149784
Xinyu Meng , Chao Tang , Shaomin Lyu , Xingfei Xie , Jian Jia , Jinglong Qu
High-temperature tensile performance is a critical indicator of the mechanical reliability of Ni-based superalloys. In this study, a newly designed Ni-based superalloy was systematically investigated from room temperature to 900 °C to elucidate the coupling between microstructural characteristics, mechanical response, and deformation mechanisms. Fine-grained (10.7 μm) and coarse-grained (97 μm) microstructures were obtained through multi-stage heat treatments. The FG alloy exhibits superior yield and tensile strength below 750 °C, reaching 1340 MPa and 1740 MPa at room temperature and retaining 1208 MPa and 1267 MPa at 750 °C, which is primarily attributed to its higher grain boundary density and enhanced grain-boundary-mediated strengthening. However, the FG alloy shows a pronounced ductility drop at 815 °C, with the elongation decreasing to 9 %. In contrast, the CG alloy demonstrates enhanced strength retention at elevated temperatures, maintaining an ultimate tensile strength and yield strength of 801 MPa and 770 MPa at 900 °C, corresponding to a tensile strength retention of 54 % (compared with 38 % for the FG alloy), together with a stable elongation of 8.5 %. This superior high-temperature stability is associated with a lower grain boundary density and a higher fraction of Σ3 special boundaries (42.6–55.9 %). Microstructural analysis reveals a bimodal γ′ precipitate distribution in both microstructures, with fine secondary γ′ precipitates (FG: 82 nm, 48 %; CG: 92 nm, 57 %) dominating strengthening through short-range dislocation–precipitate interactions, and coarse primary γ′ precipitates (FG: 1.54 μm, 7.6 %; CG: 3.19 μm, 0.5 %) facilitating deformation accommodation by pinning grain boundary migration, thereby enabling a synergistic balance between strength and ductility over a wide temperature range. Transmission electron microscopy and critical resolved shear stress analysis demonstrate a temperature-dependent transition in deformation mechanisms from γ′ shearing to Orowan looping in the range of 815–900 °C. In addition, Co/Ti solute segregation at twin interfaces reduces interfacial energy and suppresses defect migration, further stabilizing the γ/γ′ microstructure and enhancing high-temperature strength. These findings provide mechanistic insight for the microstructural design of advanced Ni-based superalloys.
高温拉伸性能是衡量镍基高温合金力学可靠性的重要指标。在本研究中,系统地研究了一种新设计的镍基高温合金,从室温到900°C,以阐明微观组织特征,力学响应和变形机制之间的耦合。通过多段热处理得到细晶(10.7 μm)和粗晶(97 μm)组织。FG合金在750℃以下表现出优异的屈服强度和抗拉强度,室温下达到1340 MPa和1740 MPa, 750℃时保持1208 MPa和1267 MPa,这主要归因于其较高的晶界密度和晶界介导强化的增强。但在815℃时,FG合金的延展性明显下降,伸长率降至9%。相比之下,CG合金在高温下表现出增强的强度保持,在900°C时保持801 MPa和770 MPa的极限抗拉强度和屈服强度,对应于54%的抗拉强度保持(而FG合金为38%),以及8.5%的稳定伸长率。这种优异的高温稳定性与较低的晶界密度和较高的Σ3特殊晶界比例(42.6 - 55.9%)有关。显微组织分析表明,两种显微组织均呈双峰型γ′相分布,其中细小的次生γ′相(FG: 82 nm, 48%; CG: 92 nm, 57%)主导着通过短程位错-析出相互作用强化的过程,而粗的初生γ′相(FG: 1.54 μm, 7.6%;CG: 3.19 μm, 0.5%)通过固定晶界迁移促进变形调节,从而在宽温度范围内实现强度和延性之间的协同平衡。透射电镜和临界分解剪切应力分析表明,在815-900°C范围内,变形机制从γ′剪切到Orowan环的转变依赖于温度。此外,Co/Ti在孪晶界面处的溶质偏析降低了界面能,抑制了缺陷迁移,进一步稳定了γ/γ′微观组织,提高了高温强度。这些发现为先进镍基高温合金的微观组织设计提供了机理见解。
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引用次数: 0
Modulated precipitation of dispersoids and strength-ductility synergy via multi-step pre-treatments in an Al-Mg-Mn-Fe-Zr-Cr-Si alloy Al-Mg-Mn-Fe-Zr-Cr-Si合金多步预处理中分散体的调制析出和强度-塑性协同作用
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-19 DOI: 10.1016/j.msea.2026.149809
Ziyan Hu , Feng Qian , Jinyue Li , Chunan Li , Zijian Wang , Yang Li , Chun Guo , Shiwei Pan , Xingwang Cheng
Conventional 5xxx Al-Mg alloys are typically non-heat-treatable, with their strength limited by solid solution and work hardening. Dispersion strengthening is a potent strategy to overcome this limitation, but its effectiveness is often hindered by the sluggish and insufficient precipitation of thermally stable dispersoids. To promote dispersion kinetics, this work introduced a multi-step pre-treatment, integrating pre-aging (PA, 300 °C/8 h) and pre-straining (PS, 10 % cold rolling), in a novel Al-Mg-Mn-Fe-Zr-Cr-Si alloy. This PA + PS protocol constructed a unique composite microstructure, featuring Mn-rich solute clusters, β-Mg2Si nanoparticles and a high density of dislocations. Upon subsequent aging at 400 °C, the dislocation networks strongly interacted with β-Mg2Si to cooperatively facilitate the heterogeneous nucleation of Mn-rich dispersoids, while the residual Mn-rich solute clusters in Al-matrix progressively transformed into dispersoids. This dual precipitation pathway effectively accelerated the aging kinetics and enhanced the spatial uniformity of dispersoids, thus drastically minimizing dispersoid-free zones (DFZs). Consequently, samples subjected to PA + PS exhibited a superior strength-ductility synergy after aging at 400 °C for 12 h, with yield strength, ultimate strength and elongation increased by 34 %, 40 % and 23 % over the as-cast counterpart. Furthermore, it demonstrated exceptional thermal stability, with negligible loss of strength even after prolonged 400 °C aging until 200 h, overwhelming the PS pre-treated and as-cast samples. This work establishes a transformative dispersion-strengthening paradigm mediated by the synergy of pre-aging and pre-straining, providing foundational insights for developing advanced, thermally stable 5xxx alloys with high strength-ductility synergy.
传统的5xxx铝镁合金通常是不可热处理的,其强度受固溶体和加工硬化的限制。色散强化是克服这一限制的有效策略,但其有效性往往受到热稳定色散缓慢和不充分沉淀的阻碍。为了促进弥散动力学,本研究引入了一种新型Al-Mg-Mn-Fe-Zr-Cr-Si合金的多步骤预处理,将预时效(PA, 300°C/8 h)和预应变(PS, 10%冷轧)结合起来。这种PA + PS方案构建了独特的复合微观结构,具有富mn溶质团簇、β-Mg2Si纳米颗粒和高密度位错。在随后的400℃时效过程中,位错网络与β-Mg2Si强烈相互作用,共同促进富mn弥散体的非均相成核,而al基体中残余的富mn溶质团簇逐渐转变为弥散体。这种双重沉淀途径有效地加速了时效动力学,增强了弥散体的空间均匀性,从而大大减少了无弥散区(DFZs)。因此,经过PA + PS处理的样品在400℃时效12 h后表现出优异的强度-塑性协同效应,其屈服强度、极限强度和延伸率比铸态分别提高了34%、40%和23%。此外,它表现出优异的热稳定性,即使在400°C时效至200小时后,强度损失也可以忽略不计,超过PS预处理和铸态样品。这项工作建立了一种由预时效和预应变协同作用介导的变异性弥散强化范式,为开发具有高强度-塑性协同作用的先进、热稳定的5xxx合金提供了基础见解。
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引用次数: 0
Simultaneous enhancement of strength and ductility in Al-Cu-Li alloys with a moderate Cu/Li ratio via minor pre-deformation 适度Cu/Li比的Al-Cu-Li合金,通过少量的预变形,强度和延展性同时增强
IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-19 DOI: 10.1016/j.msea.2026.149807
Fengjiao Niu , Haiyang Liu , Ruyu Cheng , Haoran Yang , Yixuan Hao , XiuBo Yang , Yajie Guo
The microstructure evolution and mechanical properties of a new Al-3.2Cu-0.9Li-0.4 Mg (wt.%) alloy with a moderate Cu/Li ratio of 3.5:1 under T8 treatment (incorporating 6 % pre-deformation followed by artificial aging) were systematically investigated. Compared to the T6 condition (direct artificial aging), the T8-treated alloy achieved a simultaneous enhancement in strength and elongation. Quantitative analysis of strengthening mechanisms reveals that precipitation strengthening provides the dominant contribution, which is significantly enhanced in the T8 state due to a refined and homogeneous distribution of T1 (Al2CuLi) and δ′/θ'/δ′ (Al2Cu/Al3Li/Al2Cu) composite phases, promoted by the high-density dislocations from pre-deformation. This pre-deformation also facilitates the morphological transition of S phase (Al2CuMg) from rod-like to lath-like and substantially narrows the grain boundary precipitate-free zones (PFZs) from 324 nm to 50 nm. The strengthening calculations further confirm the auxiliary roles of grain boundary and dislocation strengthening, while the contribution from solid solution strengthening remains comparable between the T6 and T8 states. These microstructural optimizations enhance intragranular strength and alleviate grain boundary brittleness, ultimately resulting in a 16 % increase in yield strength, a 12 % increase in tensile strength, and a 15 % improvement in elongation.
系统研究了Cu/Li比为3.5:1的Al-3.2Cu-0.9Li-0.4 Mg (wt.%)新型合金在T8处理(预变形6%后人工时效)下的组织演变和力学性能。与T6条件(直接人工时效)相比,t8处理的合金在强度和伸长率方面同时得到了提高。强化机制的定量分析表明,析出强化起主导作用,在T8状态下,由于预变形引起的高密度位错促进了T1 (Al2CuLi)和δ '/ θ'/δ ' (Al2Cu/Al3Li/Al2Cu)复合相的细化和均匀分布,强化作用显著增强。这种预变形还促进了S相(Al2CuMg)从棒状到板状的形态转变,并使晶界无析出带(PFZs)从324 nm大幅缩小到50 nm。强化计算进一步证实了晶界强化和位错强化的辅助作用,而固溶体强化的贡献在T6和T8状态之间保持相当。这些微观结构优化提高了晶内强度,缓解了晶界脆性,最终使屈服强度提高16%,抗拉强度提高12%,伸长率提高15%。
{"title":"Simultaneous enhancement of strength and ductility in Al-Cu-Li alloys with a moderate Cu/Li ratio via minor pre-deformation","authors":"Fengjiao Niu ,&nbsp;Haiyang Liu ,&nbsp;Ruyu Cheng ,&nbsp;Haoran Yang ,&nbsp;Yixuan Hao ,&nbsp;XiuBo Yang ,&nbsp;Yajie Guo","doi":"10.1016/j.msea.2026.149807","DOIUrl":"10.1016/j.msea.2026.149807","url":null,"abstract":"<div><div>The microstructure evolution and mechanical properties of a new Al-3.2Cu-0.9Li-0.4 Mg (wt.%) alloy with a moderate Cu/Li ratio of 3.5:1 under T8 treatment (incorporating 6 % pre-deformation followed by artificial aging) were systematically investigated. Compared to the T6 condition (direct artificial aging), the T8-treated alloy achieved a simultaneous enhancement in strength and elongation. Quantitative analysis of strengthening mechanisms reveals that precipitation strengthening provides the dominant contribution, which is significantly enhanced in the T8 state due to a refined and homogeneous distribution of T<sub>1</sub> (Al<sub>2</sub>CuLi) and δ′/θ'/δ′ (Al<sub>2</sub>Cu/Al<sub>3</sub>Li/Al<sub>2</sub>Cu) composite phases, promoted by the high-density dislocations from pre-deformation. This pre-deformation also facilitates the morphological transition of S phase (Al<sub>2</sub>CuMg) from rod-like to lath-like and substantially narrows the grain boundary precipitate-free zones (PFZs) from 324 nm to 50 nm. The strengthening calculations further confirm the auxiliary roles of grain boundary and dislocation strengthening, while the contribution from solid solution strengthening remains comparable between the T6 and T8 states. These microstructural optimizations enhance intragranular strength and alleviate grain boundary brittleness, ultimately resulting in a 16 % increase in yield strength, a 12 % increase in tensile strength, and a 15 % improvement in elongation.</div></div>","PeriodicalId":385,"journal":{"name":"Materials Science and Engineering: A","volume":"953 ","pages":"Article 149807"},"PeriodicalIF":7.0,"publicationDate":"2026-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146023556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Materials Science and Engineering: A
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