A high-strength hull structural (HSHS) steel was developed based on a low-carbon high-nickel design concept. To evaluate its mechanical properties and weldability, the microstructures and mechanical performance of both the base metal and its heat-affected zones (HAZs)—including the coarse-grained HAZ, fine-grained HAZ, unaltered coarse-grained HAZ, and supercritically reheated coarse-grained HAZ—were systematically investigated under heat inputs of 20 and 50 kJ/cm. The strengthening and toughening mechanisms of the HSHS steel and its HAZs were further elucidated. The results demonstrate that the developed HSHS steel exhibits excellent comprehensive mechanical properties, while its HAZs maintain sufficiently high strength and overall satisfactory toughness at 223 K (−50 °C). The high strength of the developed HSHS steel is primarily attributed to the second phase precipitation and the formation of a tempered bainite-dominated microstructure. In the HAZs, the designed Nb content and the development of a lath-based microstructure are identified as key factors ensuring high strength. The low-temperature toughness of both the base metal and HAZs is predominantly governed by the high Ni content and refined M-A constituents, with secondary contributions from finer effective grain size and microstructural characteristics. Depending on specific conditions, these factors lead to variations in Charpy impact energy. Notably, a comparative analysis with documented data reveals that the mechanical properties of the HAZs in the developed HSHS steel are comparable to those of HSLA-100 steels. Collectively, these findings confirm that the developed HSHS steel possesses good weldability.
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