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Machine Learning in Analyses of the Relationship between Japanese Sake Physicochemical Features and Comprehensive Evaluations 机器学习在日本清酒理化特征与综合评价关系分析中的应用
Q4 Engineering Pub Date : 2020-03-15 DOI: 10.11301/jsfe.19560
Satoru Shimofuji, Motoko Matsui, Yukari Muramoto, Hironori Moriyama, Reina Kato, Yoshiro Hoki, H. Uehigashi
We investigated the contributions of physicochemical features to a comprehensive evaluation of the Japanese sake known as ‘ Junmai Ginjo ’ by applying machine learning. We used 173 samples of the commercial Japanese sake. The sensory evaluation was conducted by 35 panelists. The panel conducted the evaluation of each sample using five statements for the comprehensive evaluation of the sample. General analysis, substance-related nucleic acid, volatile components and simplified analyses were measured as physicochemical analyses. We performed regression analyses using a multiple regression analysis (MRA), partial least squares regression (PLS) and machine learning employing a support vector machine (SVM), an artificial neural network (ANN), and random forest (RF). The results of these five analysis methods have demonstrated that machine learning (especially RF) provides comparable or higher prediction accuracy and better fitting than MRA. We also discuss the contribution of each physicochemical feature to the evaluation scores based on the regression coefficients obtained by MRA and the features’ importance obtained in RF. The analysis of the individual scores indicated that ethyl caproate and isoamyl acetate make large contributions to influence the sake evaluation.
我们通过应用机器学习,研究了理化特征对日本清酒“Junmai Ginjo”综合评价的贡献。我们使用了173个商业日本清酒样品。感官评估由35名小组成员进行。该小组对每个样本进行了评估,使用了五种陈述对样本进行综合评估。一般分析、物质相关核酸、挥发性成分和简化分析被测量为物理化学分析。我们使用多元回归分析(MRA)、偏最小二乘回归(PLS)和使用支持向量机(SVM)、人工神经网络(ANN)和随机森林(RF)的机器学习进行了回归分析。这五种分析方法的结果表明,机器学习(尤其是RF)提供了与MRA相当或更高的预测精度和更好的拟合。基于MRA获得的回归系数和RF中获得的特征重要性,我们还讨论了每个物理化学特征对评估分数的贡献。个人得分分析表明,己酸乙酯和乙酸异戊酯对清酒评价有较大影响。
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引用次数: 3
Preparation of Powdered Seasoning with Shrimp-like Flavor from the Aqueous Residue of Isada Krill by Subcritical Water Treatment and Spray-drying 用亚临界水处理和喷雾干燥法从伊萨达磷虾的水渣中制备虾味粉状调味料
Q4 Engineering Pub Date : 2019-12-15 DOI: 10.11301/jsfe.19562
S. Adachi, J. A. Jiménez, H. D. Ariyanto, Y. Miyagawa, H. Yoshii
The aqueous residue formed after the recovery of oil-soluble functional components in Isada krill caught on the Sanriku coast in 2018 was treated under subcritical water conditions at 140 ℃ . Maltodextrins (MDs) with different dextrose equivalents (DEs) were added to the residue, and the mixtures were spray-dried to produce the powdered seasonings. Sensory evaluation of the odor of the powdered seasonings was conducted by a panel of volunteers. The DE of MD was found to affect palatability, and MDs with larger DEs exhibited higher preference scores. GC-MS analysis revealed that all the powdered seasonings contained pyrazines related to shrimp-like flavor, although no pyridines were detected.
在140℃的亚临界水条件下,对2018年在三陆海岸捕获的伊萨达磷虾油溶性功能成分回收后形成的水性残留物进行了处理。将具有不同葡萄糖当量(DE)的麦芽糊精(MD)添加到残留物中,并将混合物喷雾干燥以生产粉状调味料。一个志愿者小组对粉状调味料的气味进行了感官评估。MD的DE被发现会影响适口性,具有较大DE的MD表现出更高的偏好得分。GC-MS分析显示,所有粉状调味料都含有与虾味有关的吡嗪,但未检测到吡嗪。
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引用次数: 0
Methods for Thermodynamic Analysis of Temperature Dependence of Distribution Coefficients in Chromatography Separations 色谱分离中分配系数温度依赖性的热力学分析方法
Q4 Engineering Pub Date : 2019-09-15 DOI: 10.11301/jsfe.19550t
João M. S. Cardoso, N. Yoshimoto, Shuichi Yamamoto
Thermodynamic analysis of chromatography separation is important not only for optimization of separation but also development of new separation media and processes. In this study temperature dependence in the separation of two model components (polyphenols) by polymer-based chromatography with ethanol-water mobile phase was analyzed by van’t Hoff plots and isothermal titration calorimeter (ITC). The distribution coef ficient K obtained by the isocratic elution of chromatography was employed both for van’t Hoff plots and for the calculation of adsorbed amount in the ITC measurements. Enthalpy values obtained by both methods were similar. As ITC is not able to predict separation behavior, it is recommended to use chromatography experiments as a complimentary method for analyzing the temperature dependence of separation.
色谱分离的热力学分析不仅对分离的优化,而且对开发新的分离介质和分离工艺具有重要意义。本研究采用范霍夫图和等温滴定量热计(ITC)分析了乙醇-水流动相聚合物基色谱法分离两种模型组分(多酚)时的温度依赖性。等温洗脱得到的分布系数K既用于范霍夫图,也用于ITC测量中吸附量的计算。两种方法得到的焓值相似。由于ITC不能预测分离行为,因此建议使用色谱实验作为分析分离温度依赖性的补充方法。
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引用次数: 0
Concentration of Aqueous Residue from Isada Krill Using Freezing-Thawing Technique 冷冻解冻技术浓缩磷虾水分残留
Q4 Engineering Pub Date : 2019-09-15 DOI: 10.11301/jsfe.19558t
S. Adachi, Y. Miyagawa, H. Yoshii
The concentrated aqueous residues from the recovery process of useful oil-soluble components from Isada krill were examined by freezing-thawing technique. The aqueous residue was completely frozen into spheres or cuboids of different sizes at - 20 ℃ or - 80 ℃ , and then thawed at room temperature (26 ± 2 ℃ ). The concentration index was defined as the ratio of the Brix concentration of the melted solution to that of the original solution. The changes in the cumulative fraction and concentration index of melted solution during the thawing process were measured. The freezing temperature had no significant effect on the thawing process. For all the frozen samples, the relationship between the cumulative fraction and concentration index of the melted solution was roughly represented by a single straight line, and the concentration index of the solution obtained by thawing half of the frozen sample was about 1.4. It was shown that the original solution could be concentrated twice when the freezing-thawing operation was repeated twice. However, further repeated operation had no effect on concentration.
采用冻融技术对磷虾有用油溶性成分回收过程中产生的浓缩水渣进行了检测。将水渣在- 20℃或- 80℃下完全冷冻成不同大小的球体或长方体,然后在室温(26±2℃)下解冻。浓度指数定义为熔化溶液的白锐度浓度与原溶液的白锐度浓度之比。测定了融化过程中融化溶液的累积分数和浓度指数的变化。冻结温度对解冻过程无显著影响。对于所有冻结样品,融化溶液的累积分数与浓度指数之间的关系大致为一条直线,解冻一半冻结样品得到的溶液浓度指数约为1.4。结果表明,当重复两次冻融操作时,原溶液可以浓缩两次。然而,进一步的重复操作对浓度没有影响。
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引用次数: 0
Simplified Mechanistic Models for Food Processes-Drying and Chromatography 食品加工的简化机理模型——干燥和色谱
Q4 Engineering Pub Date : 2019-09-15 DOI: 10.11301/jsfe.19557c
Shuichi Yamamoto
Mechanistic modeling/simulation is quite important and useful for understanding, designing and operating various food processes. However, the rigorous mathematical/mechanistic models are complicated. It is also difficult and time-consuming to determine the parameter values needed for the simulation. Simplified mechanistic models are useful both for the process understanding and for the parameter value determination. In this paper, simplified mechanistic models for two food processes, drying of liquid foods and chromatography of proteins and food materials, are presented. Both of them are dif fusion-controlled processes. A short-cut method for determining the waterconcentration dependent dif fusion coefficient from isothermal drying rates is described. Factors affecting the drying rates and the inactivation of enzyme are explained based on the simplified model. For chromatography separation processes, a method for determining HETP from linear gradient elution (LGE) curves is explained. Then, how to tune separation performance in LGE is described based on the non-dimensional group (Yamamoto number). The productivity calculation methods based on the simplified model is also explained. The usefulness of a non-dimensional group for describing the dynamic binding capacity of the breakthrough curve for capture chromatography is also discussed.
机械建模/模拟对于理解、设计和操作各种食品过程非常重要和有用。然而,严格的数学/机械模型是复杂的。确定模拟所需的参数值也是困难和耗时的。简化的机械模型对理解过程和确定参数值都很有用。本文提出了两种食品过程的简化机理模型,即液体食品的干燥和蛋白质和食品材料的色谱。这两个过程都是dif融合控制的过程。介绍了一种从等温干燥速率中确定与水浓度相关的差融合系数的快捷方法。基于简化模型解释了影响干燥速率和酶失活的因素。对于色谱分离过程,解释了从线性梯度洗脱(LGE)曲线测定HETP的方法。然后,基于无量纲群(Yamamoto数)描述了如何调整LGE中的分离性能。并对基于简化模型的生产率计算方法进行了说明。还讨论了无量纲基团在描述捕获色谱穿透曲线的动态结合能力方面的有用性。
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引用次数: 0
Preparation of Seasoning with Shrimp-like Flavor from the Aqueous Residue of Isada Krill under Subcritical Water Conditions 亚临界水条件下用伊萨达磷虾水渣制备虾香调味料
Q4 Engineering Pub Date : 2019-09-15 DOI: 10.11301/jsfe.19559
S. Adachi, Y. Miyagawa, H. Yoshii
Conditions were examined to prepare a seasoning with shrimp-like flavor from the aqueous residues formed after the recovery of oil-soluble functional components in Isada krill caught from the Sanriku coast in 2017 and 2018 upon treatment under subcritical water conditions. Treatment at 160 ℃ increased the amount of insoluble material and decreased the concentration of soluble matter. The color of the aqueous residue depended on the year of the catch, and the color after treatment under subcritical water conditions was also different. However, when treated under subcritical water conditions, both aqueous residues obtained from the 2017 and 2018 catches showed a decrease in the fishy odor and an increase in fragrant and burnt aromas. The preference score obtained for the residue obtained from the 2017 catch increased after the treatment process. On the other hand, the aqueous residue obtained from the 2018 catch, which did not show any improvement in the preference score upon treatment, was improved when diluted 2 or 4 times after the treatment process. GC-MS analysis revealed that pyridines and pyrazines related to shrimp-like flavor were produced in both aqueous residues obtained from the 2017 and 2018 catches upon treatment under subcritical water conditions.
考察了从2017年和2018年从三陆海岸捕获的伊萨达磷虾在亚临界水条件下处理后回收油溶性功能成分后形成的水残留物中制备具有虾样风味的调味料的条件。160℃处理增加了不溶性物质的含量,降低了可溶性物质的浓度。含水残留物的颜色取决于捕获年份,在亚临界水条件下处理后的颜色也不同。然而,当在亚临界水条件下处理时,2017年和2018年捕获的两种水性残留物都显示出腥味减少,芳香和焦香增加。处理过程后,对2017年捕获的残留物的偏好得分有所增加。另一方面,从2018年捕获物中获得的水性残留物在处理时没有显示出任何偏好得分的改善,当在处理过程后稀释2或4次时,其得到了改善。GC-MS分析显示,在亚临界水条件下处理后,2017年和2018年捕获的两种水性残留物中都产生了与虾样风味有关的吡啶和吡嗪。
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引用次数: 1
Application of IoT to the Analysis of Food Constituents and Sensing Using a Sigle-Board Computer 物联网在食品成分分析和Sigle Board计算机传感中的应用
Q4 Engineering Pub Date : 2019-09-15 DOI: 10.11301/jsfe.19553
Takashi Kobayashi
Analog output from the HPLC detector was digitized using a single-board computer (SBC), and the processed data were distributed through a local area network by using the SBC as a web server. Results for the HPLC analysis of coconut oil was recorded on a client computer (PC). The output from two SBCs could be processed simultaneously in real time using a single PC. This system was also applied to the recording of temperature and relative humidity at a remote location. Data were acquired through the internet using a slower connection. Temperature and humidity could be recorded without their loss for three months by setting the acquisition interval longer.
使用单板计算机(SBC)对HPLC检测器的模拟输出进行数字化,并使用SBC作为网络服务器通过局域网分发处理后的数据。椰子油的HPLC分析结果记录在客户计算机(PC)上。两个SBC的输出可以使用一台PC同时实时处理。该系统也适用于远程位置的温度和相对湿度记录。数据是通过较慢的连接通过互联网获取的。通过设置更长的采集间隔,可以在三个月内记录温度和湿度而不会丢失。
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引用次数: 0
Freeze–thaw-induced Structural Destruction and Generation of γ-aminobutyric Acid in Water-soaked Soybeans 冻融对浸泡大豆结构的破坏及γ-氨基丁酸的产生
Q4 Engineering Pub Date : 2019-06-15 DOI: 10.11301/JSFE.19548
S. Ueno, Natsuko Iryo, S. Sasao, Hsiuming Liu, K. Atsuzawa, Y. Kaneko, R. Shimada
In this study, we investigated the effects of freezing and subsequent storage on γ-aminobutyric acid (GABA) accumulation in soybean (Glycine max) cotyledons. According to direct observations and an indirect analysis with Cole-Cole plots of soybeans, the membrane structure in freeze–thawed soybeans was partially destroyed and the degree of destruction increased with a decrease in the freezing temperature. GABA generation in freeze–thawed soybeans was accelerated during storage after thawing. The optimum pH for GABA generation reaction was investigated; the decrease in pH in stored soybeans was found to result in an increase in GABA generation. The higher GABA accumulation after freeze–thawing of soybeans may have been caused by the freeze–thaw-induced structural destruction, which improved substrate transfer and enzymatic reactions.
在本研究中,我们研究了冷冻和随后的贮藏对大豆(Glycine max)子叶中γ-氨基丁酸(GABA)积累的影响。根据对大豆Cole-Cole图的直接观察和间接分析,冻融大豆的膜结构被部分破坏,破坏程度随着冷冻温度的降低而增加。冷冻-解冻大豆中GABA的产生在解冻后的储存过程中加速。研究了GABA生成反应的最适pH值;发现储存大豆中pH值的降低导致GABA产生的增加。大豆冻融后GABA积累较高可能是由冻融诱导的结构破坏引起的,这改善了底物转移和酶促反应。
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引用次数: 1
Preference Evaluation Method by Using Viscoelastic Properties and Sensory Evaluated Scores for Japanese Soup Stock “Dashi” Flavored Jelly 日本汤料“大石”风味果冻的粘弹性和感官评价评分偏好评价方法
Q4 Engineering Pub Date : 2019-06-15 DOI: 10.11301/JSFE.19545
Airi Morita
The correlations between physical properties and sensory evaluated scores of Japanese soup stock (Dashi) added jelly were analyzed using statistical analysis methods. Five kinds of sample jellies were tested for their viscoelastic properties by texture test to obtain 3 parameters of hardness[Pa], cohesiveness [-] and adhesiveness[J/m]. Sensory evaluation by 29 female student panelists were conducted to obtain sensory evaluated scores of preference, hardness of jelly, aroma and taste intensity of Dashi, cohesiveness, ease of swallowing and persistence in mouth. High correlations were found between sensory preference, hardness of jelly, aroma and taste intensity of Dashi by partial correlation analysis. Partial Least Square (PLS) regression analysis were conducted to preference and sensory evaluated scores which assumed to having a linear relationship, and then successfully obtained a regression equation showing R=0.99. From the ranking of Variable Impor tance in Projection (VIP) values obtained from PLS, it was found that preference of the jelly has a higher contribution to taste and aroma terms than terms related to its mouthfeel. However, in the case of a data set in a nonlinear relationship, it was considered necessary to examine the statistical analysis which having flexibility to model the nonlinear relationship and the substitution parameters.
采用统计分析方法,对添加果冻的日本高汤的理化性质与感官评定得分之间的相关性进行了分析。通过结构试验对5种样品果冻的粘弹性进行了测试,得到了硬度[Pa]、内聚性[-]和粘附性[J/m]3个参数。29名女生小组成员进行了感官评估,以获得偏好、果冻硬度、大食的香气和味觉强度、内聚性、易吞咽性和口腔持久性的感官评估分数。偏相关分析发现,大食的感官偏好、果冻硬度、香气和味觉强度之间存在高度相关性。对假设具有线性关系的偏好和感官评价得分进行偏最小二乘(PLS)回归分析,然后成功地获得了R=0.99的回归方程。从PLS获得的投影中的可变影响(VIP)值的排名中发现,果冻的偏好对味道和香气的贡献高于与口感相关的术语。然而,在数据集处于非线性关系的情况下,有必要检查统计分析,该分析具有对非线性关系和替代参数建模的灵活性。
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引用次数: 0
Study of Moisture Transfer and Reaction Kinetics in Food Processing 食品加工过程中水分传递与反应动力学研究
Q4 Engineering Pub Date : 2019-06-15 DOI: 10.11301/JSFE.19549
M. Fukuoka
Insufficient heating causes decreased digestibility, or increased growth of microorganisms while excessive heating (overcooking) not only impairs the usual texture, or eating-quality, of various food including starchy food and meat/fish meat, but also leads to the generation of hazardous factors such as acrylamide and heterocyclic amine. Consequently, it is important to describe various changes in the physical properties of food materials that occur during thermal processing, based on the heat transfer phenomenon in order to determine optimal values for heating. In this article, (1) study of moisture transfer and reaction in starchy food during cooking, and (2) reaction kinetics of thermal denaturation of protein are described.
加热不足会导致消化率下降或微生物生长增加,而过度加热(过度烹饪)不仅会损害各种食物(包括淀粉类食物和肉/鱼肉)的通常质地或食用质量,还会导致丙烯酰胺和杂环胺等有害因素的产生。因此,根据传热现象,描述食品材料在热加工过程中发生的物理性质的各种变化,以确定加热的最佳值,这一点很重要。本文对淀粉类食品在蒸煮过程中的水分传递和反应进行了研究;对蛋白质热变性的反应动力学进行了研究。
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引用次数: 0
期刊
Japan Journal of Food Engineering
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