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Development of an MRI Chemical Transport Model for the Study of Stratospheric Chemistry 平流层化学研究核磁共振化学输运模型的建立
Q4 Earth and Planetary Sciences Pub Date : 2005-01-01 DOI: 10.2467/MRIPAPERS.55.75
K. Shibata, M. Deushi, T. Sekiyama, Hiromasa Yoshimura
A three-dimensional chemical transport model(CTM) was developed at the Meteorological Research Institute by coupling a chemical module with the MJ98 general circulation model (dynamical module) for the study of stratospheric chemistry.This model, MJ98-CTM, ran for approximately 15 years and the simulated chemical species were investigated, focusing on the time-mean fields. The chemical module was based on the family method and contains major stratospheric species, i.e., 34 long-lived species including 7 families and 15 short-lived species with 79 gas phase reactions and 34 photodissociations. Two types (I and II) of polar stratospheric clouds (PSCs) and sulfate aerosols were included with six heterogeneous reactions on PSCs and three heterogeneous reactions on sulfate aerosols. MJ98-CTMs of T21L45 and T42L45 versions were integrated using climatological monthly mean values of sea-surface temperature and ozone for the dynamical module, and fixed values at the surface for surface-origin species in the chemical module. Radiatively active gases such as ozone, methane, and nitrous oxide were not treated interactively between the two modules. Horizontal resolutions were 5.6°(∼600 km) for the T21 model and 2.8°(∼300 km) for the T42 model. The vertical resolution L45 had a vertical spacing of about 2 km in the stratosphere with a top at 0.01 hPa (80km).   Qualitatively, MJ98-CTM suitably reproduced the temporal and spatial features of observed ozone and other chemical species in the middle atmosphere. However, the lower stratosphere held crucial errors for the distributions of chemical species, particularly ozone, yielding positive errors for column ozone. A major cause of these errors can be ascribed to the errors associated with transport: one based on the wind field bias produced by MJ98, and the other from the coarse vertical resolution.
气象研究所将化学模组与MJ98环流模组(动力模组)耦合,建立了平流层化学的三维化学输运模式(CTM)。该模型MJ98-CTM运行了大约15年,并对模拟的化学物质进行了研究,重点是时间平均场。化学模块基于科法,包含平流层主要物种,即34个长寿命物种,包括7个科和15个短寿命物种,有79个气相反应和34个光解作用。包括极性平流层云(PSCs)和硫酸盐气溶胶两种类型,在PSCs上有6个非均相反应,在硫酸盐气溶胶上有3个非均相反应。T21L45和T42L45版本的MJ98-CTMs在动力模块中采用海温和臭氧的气候月平均值,在化学模块中采用地表源物种的固定值。辐射活性气体,如臭氧、甲烷和氧化亚氮在两个模块之间不进行交互处理。T21模式的水平分辨率为5.6°(~ 600 km), T42模式的水平分辨率为2.8°(~ 300 km)。垂直分辨率L45在平流层的垂直间距约为2 km,顶部为0.01 hPa (80km)。MJ98-CTM在定性上较好地再现了观测到的大气中臭氧和其他化学物质的时空特征。然而,平流层下层对化学物质的分布,特别是臭氧的分布具有关键误差,对臭氧柱产生正误差。造成这些误差的主要原因是与输运有关的误差:一个是基于MJ98产生的风场偏差,另一个是来自粗垂直分辨率。
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引用次数: 76
Methane standard gases for atmospheric measurements at the MRI and JMA and intercomparison experiments 甲烷标准气体的大气测量在核磁共振和JMA和相互比较实验
Q4 Earth and Planetary Sciences Pub Date : 2004-01-01 DOI: 10.2467/MRIPAPERS.54.91
H. Matsueda, Y. Sawa, A. Wada, H. Inoue, K. Suda, Yoshiaki Hirano, K. Tsuboi, S. Nishioka
A calibration system of standard gases for atmospheric methane measurements using a gas chromatograph equipped with a flame ionization detector was developed at the Meteorological Research Institute (MRI) in 1993 and later at the Japan Meteorological Agency (JMA) in 2000. Calibration results for the two systems exhibited good agreement. Although the primary standard gases of the MRI and JMA were prepared independently using the gravimetric method, their methane standard scales were quite similar, (a difference of less than 1 ppb). A comparison of gravimetric standards prepared by several Japanese gas companies showed a methane scale difference within ∼5 ppb relative to the primary standards of the MRI. These gravimetric-scale differences were primarily caused by methane impurities in the diluent air used for standard gas preparation. Long-term storage experiments indicated that the methane contents of standard gases were stable in high-pressure cylinders for 8-9 years. No significant drift of methane was found in any of the standard gases in the MRI; however, to evaluate the stability of the JMA standards, data collected over a longer period of time is required. We evaluated the differences between the methane scales of the MRI and other laboratories based on the previous intercomparison experiments. The differences found in the standard scales used by different laboratories were largely due to the diverse origins of the primary standard gases.
气象学研究所(MRI)于1993年开发了一套标准气体校准系统,用于使用配备火焰电离检测器的气相色谱仪进行大气甲烷测量,后来在2000年由日本气象厅(JMA)开发。两种系统的标定结果吻合良好。虽然MRI和JMA的主要标准气体是使用重量法独立制备的,但它们的甲烷标准尺度非常相似(差异小于1 ppb)。由几家日本天然气公司准备的重量标准的比较显示,相对于MRI的主要标准,甲烷尺度差异在~ 5 ppb内。这些重量尺度的差异主要是由用于标准气体制备的稀释空气中的甲烷杂质引起的。长期储存实验表明,标准气体甲烷含量在高压气瓶中可保持8 ~ 9年的稳定。在核磁共振成像的任何标准气体中都没有发现明显的甲烷漂移;然而,为了评估JMA标准的稳定性,需要在较长一段时间内收集数据。在前人对比实验的基础上,我们评估了MRI与其他实验室甲烷尺度的差异。在不同实验室使用的标准尺度中发现的差异主要是由于主要标准气体的来源不同。
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引用次数: 14
The New Meteorological Research Institute Coupled GCM ( MRI-CGCM 2 )---Model Climate and Variability 新气象研究所耦合GCM (MRI-CGCM 2)—模式气候和变率
Q4 Earth and Planetary Sciences Pub Date : 2004-01-01 DOI: 10.2467/mripapers.51.47
A. Noda, M. Sugi, Y. Kitamura, M. Hosaka, K. Shibata, S. Maeda
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引用次数: 130
Impact of the SH major stratospheric warming on the Hadley circulation : A case study SH大平流层变暖对哈德利环流的影响:一个实例研究
Q4 Earth and Planetary Sciences Pub Date : 2004-01-01 DOI: 10.2467/MRIPAPERS.54.111
K. Kodera, Kazutaka Yamada
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引用次数: 20
Application of statistical models to geoelectric variations with a long electrode span to detect anomalous changes 统计模型在长电极跨度地电变化中的应用
Q4 Earth and Planetary Sciences Pub Date : 2003-08-29 DOI: 10.2467/MRIPAPERS.54.1
H. Takayama
We examined two techniques for eliminating components induced by variations of the geomagnetic field to accurately and quickly detect anomalous changes in the geoelectric field, which would enable us to identify crustal signals,. One method is based on a multiple regression model, where any geoelectric variation is presented as a linear combination of the past, present, and future values of geomagnetic variations. The induced geoelectric variation is estimated as a convolution of the geomagnetic variations and the parameters of the obtained regression model. The other method uses BAYTAP-G, by which the observed geoelectric data are separated into four components: 1) tidal, 2) electromagnetically induced, 3) trend, and 4) irregular components. Signals due to volcanic and/or seismic activity may be detected since the trend and the irregular component indicate variations of the self-potential of the crust and/or noise, provided that the amplitudes exceed that of the typical variation. The geomagnetic field at the Kakioka Magnetic Observatory was used as associated data for both methods. These methods were applied to geoelectric variations in the Numazu group, which are contaminated by artificial noise but show anomalous changes. The multiple regression method can apparently eliminate daily variations and telluric storms and can clarify anomalous changes that are not obvious in the original data. However, the gain and phase characteristics calculated from the estimated parameters of the model do not yield information on the underground resistivity structure since the estimated impulse responses do not correctly reflect relationships between the inducing geomagnetic field and the induced geoelectric field due to the presence of excessive artificial noise. BAYTAP-G separates daily variations due to artificial noise as the tidal component and the responses to geomagnetic variations. Anomalous changes are identified in the trend and the irregular component.We investigated the relationship of the tidal component of geoelectric variations estimated by BAYTAP-G with the tidal current and the tide. The correlation between the tidal component of geoelectric variations and tidal currents could not be clarified since simultaneous data of tidal currents with geoelectric variations were not available. Temporal variations of the amplitudes of geoelectric variations of KSM-MTO and tides at OAR for O1 and M2 constituents were not correlated despite their high coherencies.
我们研究了两种消除由地磁场变化引起的分量的技术,以准确、快速地探测地电场的异常变化,从而使我们能够识别地壳信号。一种方法是基于多元回归模型,其中任何地电变化都被表示为过去、现在和未来地磁变化值的线性组合。感应地电变化被估计为地磁变化和得到的回归模型参数的卷积。另一种方法使用BAYTAP-G,将观测到的地电数据分为4个分量:1)潮汐分量,2)电磁感应分量,3)趋势分量,4)不规则分量。由于火山和/或地震活动的信号可以被检测到,因为趋势和不规则成分表明地壳的自电位和/或噪声的变化,只要振幅超过典型的变化。Kakioka地磁观测站的地磁场被用作这两种方法的关联数据。这些方法应用于Numazu群的地电变化,该群受人工噪声污染,但表现出异常变化。多元回归方法能明显地消除日变化和大地风暴,并能澄清原始资料中不明显的异常变化。然而,由于存在过多的人工噪声,估计的脉冲响应不能正确反映感应地磁场和感应地电场之间的关系,因此,根据模型估计参数计算的增益和相位特性不能提供有关地下电阻率结构的信息。BAYTAP-G将人工噪声引起的日变化作为潮汐分量和对地磁变化的响应分开。在趋势和不规则分量中发现了异常变化。我们研究了BAYTAP-G估算的地电变化的潮汐分量与潮流和潮汐的关系。地电变化的潮汐分量与潮流之间的相关性尚不明确,因为没有潮汐与地电变化的同步数据。KSM-MTO的地电变化幅度与O1和M2组分在OAR的潮汐的时间变化不相关,尽管它们具有高相干性。
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引用次数: 0
Estimating apparent resistivity and phase at low frequencies using telegraphic facilities 用电报设备估计低频视电阻率和相位
Q4 Earth and Planetary Sciences Pub Date : 2003-08-29 DOI: 10.2467/MRIPAPERS.54.47
H. Takayama
We propose a time-domain method for estimating the apparent resistivity and phase. The method utilizes a multiple regression model where the order is determined by minimizing the AIC (Akaike Information Criterion). The method is superior to conventional frequency-domain methods based on spectral analysis, since the data length necessary for the latter methods is several times longer than that for the former in estimating the apparent resistivity at the same low frequency. Therefore, applying this method to shorter length data having long wavelengths like those in a magnetic storm, we can estimate apparent resistivities and phases at low frequencies with little effect of the finite wavelength of the inducing geomagnetic field. This method was applied to geoelectric field data observed by means of telegraphic facilities and geomagnetic field data at the Kakioka Magnetic Observatory, which is the standard observatory in Japan, located in the observation network of the geoelectric field. The geoelectric field data are very stable over a long time period because the electrodes are buried to a depth of more than 5 meters and have a contact resistance of less than 2 ohms. Furthermore, the geoelectric data had a high signal-to-noise ratio (signal is induced variations), because the lengths of observation lines ranging from 18.8 to 27.4 km were much longer than that of ordinary observations and the greater part of geoelectric variations were induced by geomagnetic variations. Apparent resistivity and phase in the low-frequency range from 3.3 × 10-5 to 10 × 1.0-3 Hz (corresponding to periods of 512 to 16 minutes) were estimated. Since the time span of the data used in the analysis was within the period of a large-scale magnetic storm, the estimates were unlikely to be affected by the finite wavelength of the inducing geomagnetic field.
我们提出了一种时域估计视电阻率和相位的方法。该方法利用多元回归模型,其中通过最小化AIC(赤池信息准则)来确定顺序。该方法比传统的基于谱分析的频域方法在估计相同低频视电阻率时所需的数据长度要长几倍。因此,将该方法应用于磁暴中波长较长的短长度数据,可以估计低频时的视电阻率和相位,而感应地磁场有限波长的影响很小。将该方法应用于地电场观测网中日本标准观测站Kakioka地磁观测站利用电报设施观测到的地电场数据和地磁场数据。地电场数据在很长一段时间内非常稳定,因为电极埋在5米以上的深度,接触电阻小于2欧姆。此外,由于18.8 ~ 27.4 km的观测线长度比普通观测线长得多,且大部分地电变化是由地磁变化引起的,因此地电数据具有较高的信噪比(信号为诱发变化)。在3.3 × 10-5 ~ 10 × 1.0-3 Hz的低频范围内(对应512 ~ 16 min周期)估计了视电阻率和相位。由于分析中使用的数据的时间跨度是在大规模磁暴期间,因此估计不太可能受到诱导地磁场有限波长的影响。
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引用次数: 0
Implication of POC/T[lc]h-234 ratios in oceanic particulate matter: An approach to particle aggregation 海洋颗粒物中POC/T[lc]h-234比值的意义:一种粒子聚集的方法
Q4 Earth and Planetary Sciences Pub Date : 2003-03-31 DOI: 10.2467/MRIPAPERS.53.109
K. Hirose, 勝己 廣瀬
234Th has been widely applied as a tracer of particulate organic carbon (POC) fluxes in the upper ocean. Fundamental to this approach is the determination of 234Th fluxes from water column measurements of the 234Th-238U disequilibria, and the conversion of 234Th flux to POC export, using the measured POC/234Th ratio on particles. As such, POC/234Th ratios are one of the most critical factors in quantifying the carbon export flux in ocean interior when using this approach. However, the POC/234Th ratios show significant temporal and spatial variations, but cannot be predicted at this time. Therefore, it is important to elucidate factors controlling the variations of the POC/234Th ratios. To achieve this purpose, we should understand the chemical interactions between POC and 234Th. In the open ocean, POC/234Th ratios have been determined together with other oceanographic parameters. We examined here the relationship between POC/234Th and primary production. The POC/234Th ratios were linearly related to logarithmic values of primary production. Taken into account the complexation between surface ligand on particulate organic matter (POM) and 234Th, a complexation model suggests that the size of particles adsorbing 234Th is related to primary production; in the equatorial Pacific, the size of particles adsorbing 234Th apparently decreases with increasing primary production, whereas opposite phenomenon occurs in the North Atlantic. Since the POC/234Th ratios were determined in filtered particulate matter, this finding suggests that aggregation of small particles would be dominant in the equatorial Pacific, which can be explained by a chemical aggregation model.
234作为海洋上层颗粒有机碳(POC)通量的示踪剂已得到广泛应用。该方法的基础是从水柱测量的234Th- 238u不平衡中确定234通量,并使用测量的POC/234对颗粒的比值将234通量转换为POC输出。因此,当使用该方法时,POC/234比率是量化海洋内部碳输出通量的最关键因素之一。然而,POC/234比值呈现显著的时空变化,但目前无法预测。因此,阐明控制POC/234比值变化的因素具有重要意义。为了达到这个目的,我们应该了解POC和234之间的化学相互作用。在公海中,POC/234比值已与其他海洋学参数一起确定。本文研究了POC/234与初级产量之间的关系。POC/234比值与初级产量的对数呈线性相关。考虑颗粒有机物(POM)表面配体与234的络合作用,该络合模型表明,吸附234的颗粒大小与初级产量有关;在赤道太平洋,随着初级生产量的增加,吸附234的颗粒尺寸明显减小,而在北大西洋则相反。由于POC/234比值是在过滤颗粒物质中测定的,这一发现表明,小颗粒的聚集在赤道太平洋中占主导地位,这可以用化学聚集模型来解释。
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引用次数: 1
MASINGAR, a global tropospheric aerosol chemical transport model coupled with MRI/JMA98 GCM: Model description 与MRI/JMA98 GCM耦合的全球对流层气溶胶化学输送模式MASINGAR:模式描述
Q4 Earth and Planetary Sciences Pub Date : 2003-03-31 DOI: 10.2467/mripapers.53.119
Y. Tanaka, Kotaro Orito, T. Sekiyama, K. Shibata, M. Chiba, Hiroshi L. Tanaka, 泰宙 田中, 折戸 光太郎, 剛 関山, 清孝 柴田, 長 千葉, 浩 田中
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引用次数: 75
Structure of an Atypical Midsummer Tropical Cyclone in the East China Sea and the Environmental Effects on It. 东海一个非典型仲夏热带气旋的结构及其环境影响。
Q4 Earth and Planetary Sciences Pub Date : 2002-11-30 DOI: 10.2467/MRIPAPERS.53.59
北畠 尚子
Some tropical cyclones in the western North Pacific have particular characteristics, classified as the SH pattern by the Japan Meteorological Agency (1990). One such cyclone, Tropical Storm Bolaven (0006), which took an irregular track in the East China Sea in midsummer, was examined. It did not attain typhoon intensity, and had associated deep convective clouds only in the south and dry air in the middle and upper troposphere in the north of the cyclone. The northern dry region was warmer than the southern moist region, and therefore the cyclone was associated with baroclinicity in the middle troposphere. However, the surface wind field was similar to that of a typical tropical cyclone.   We also examined the relation of the structure of Bolaven and its environment using the objective analysis dataset of JMA. Bolaven was located southeast of a prominent Tibetan high in the early stage of its lifecycle. In the upper troposphere, a strong northerly wind on the eastern fringe of the Tibetan high converged in the north of Bolaven, and an easterly flow diverged in the south of Bolaven. It is inferred that regional differences in the curvature of the geopotential height field associated with the Tibetan high and the cyclone, and the consequent inertial stability, contributed to the flow and the distribution of horizontal divergence. In the middle troposphere, zonal temperature gradients were generated by the warm continental air mass in the western North Pacific, where the circulation of Bolaven generated horizontal temperature advection. These contributed to the asymmetric distribution of the vertical motion near the cyclone and to the irregular movement of the cyclone.   In the later stage of its lifecycle, Bolaven had the structure of a meridionally reversed baroclinic disturbance in the middle troposphere, although the large-scale environment changed significantly in the upper troposphere. This suggests that an asymmetric tropical cyclone organized in a particular environment could be maintained by midtropospheric frontogenesis through the tilting effect for some period.
北太平洋西部的一些热带气旋具有特殊的特征,日本气象厅(1990)将其归类为SH型。其中一个这样的气旋,热带风暴Bolaven(0006),在仲夏在东中国海的不规则轨道上进行了研究。它没有达到台风强度,只在南部有深层对流云,在气旋北部对流层中高层有干燥空气。北部干燥区较南部潮湿区偏暖,因此气旋与对流层中部斜压有关。然而,地面风场与典型的热带气旋相似。我们还利用JMA客观分析数据集考察了Bolaven的结构与环境的关系。Bolaven在其生命周期的早期阶段位于一个突出的西藏高压的东南部。对流层上层,西藏高压东缘的一股偏北风在Bolaven北部辐散,一股偏东气流在Bolaven南部辐散。推断与青藏高原和气旋相关的位势高度场曲率的区域差异,以及由此产生的惯性稳定性,促成了气流和水平辐散的分布。在对流层中部,北太平洋西部温暖大陆气团产生纬向温度梯度,Bolaven环流产生水平温度平流。这些都导致了气旋附近垂直运动的不对称分布和气旋的不规则运动。Bolaven在其生命周期后期具有对流层中层经向反转斜压扰动的结构,但对流层上层大尺度环境发生了显著变化。这表明在特定环境下形成的不对称热带气旋可以通过对流层中锋生的倾斜效应维持一段时间。
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引用次数: 0
Fabricating Thermocouple Micro Psychrometers by the Bonding-Cellulose Method. 用纤维素键合法制备热电偶微干湿计。
Q4 Earth and Planetary Sciences Pub Date : 2002-11-30 DOI: 10.2467/mripapers.53.85
Nobuyuki Kinoshita
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引用次数: 0
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Papers in Meteorology and Geophysics
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